CN101543672B - Extinguish material, preparation method and application thereof - Google Patents
Extinguish material, preparation method and application thereof Download PDFInfo
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- CN101543672B CN101543672B CN2009100612312A CN200910061231A CN101543672B CN 101543672 B CN101543672 B CN 101543672B CN 2009100612312 A CN2009100612312 A CN 2009100612312A CN 200910061231 A CN200910061231 A CN 200910061231A CN 101543672 B CN101543672 B CN 101543672B
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- 239000000463 material Substances 0.000 title claims abstract description 75
- 238000002360 preparation method Methods 0.000 title claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 50
- 239000003063 flame retardant Substances 0.000 claims abstract description 7
- 239000003921 oil Substances 0.000 claims abstract description 7
- 239000004094 surface-active agent Substances 0.000 claims abstract description 6
- 239000006096 absorbing agent Substances 0.000 claims abstract description 5
- 239000013530 defoamer Substances 0.000 claims abstract description 5
- 239000002270 dispersing agent Substances 0.000 claims abstract description 5
- -1 large buildings Substances 0.000 claims abstract description 4
- 239000002002 slurry Substances 0.000 claims description 22
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 12
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 11
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 10
- 235000019355 sepiolite Nutrition 0.000 claims description 10
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 9
- 239000011734 sodium Substances 0.000 claims description 8
- 239000004604 Blowing Agent Substances 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 7
- 229910052708 sodium Inorganic materials 0.000 claims description 7
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 7
- 239000000839 emulsion Substances 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 6
- 235000019353 potassium silicate Nutrition 0.000 claims description 6
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 6
- 239000010425 asbestos Substances 0.000 claims description 5
- 239000004568 cement Substances 0.000 claims description 5
- 239000003292 glue Substances 0.000 claims description 5
- 239000011490 mineral wool Substances 0.000 claims description 5
- 229910052895 riebeckite Inorganic materials 0.000 claims description 5
- 229920002545 silicone oil Polymers 0.000 claims description 5
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 4
- 235000012241 calcium silicate Nutrition 0.000 claims description 4
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 4
- 239000004927 clay Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000004079 fireproofing Methods 0.000 claims description 4
- 229920005610 lignin Polymers 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229920002401 polyacrylamide Polymers 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical class O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 229920002554 vinyl polymer Polymers 0.000 claims description 4
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 3
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 239000004113 Sepiolite Substances 0.000 claims description 3
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 3
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 3
- 238000005187 foaming Methods 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 229910052624 sepiolite Inorganic materials 0.000 claims description 3
- 229960005137 succinic acid Drugs 0.000 claims description 3
- LWEAHXKXKDCSIE-UHFFFAOYSA-M 2,3-di(propan-2-yl)naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S([O-])(=O)=O)=C(C(C)C)C(C(C)C)=CC2=C1 LWEAHXKXKDCSIE-UHFFFAOYSA-M 0.000 claims description 2
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- NTWZYMJGDYYGNL-UHFFFAOYSA-N [Na].C[Si] Chemical compound [Na].C[Si] NTWZYMJGDYYGNL-UHFFFAOYSA-N 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 2
- 239000004359 castor oil Substances 0.000 claims description 2
- 238000005660 chlorination reaction Methods 0.000 claims description 2
- NOLXQSVNNIIHMV-UHFFFAOYSA-L disodium;2,2-diethyl-3-hexyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCC(C([O-])=O)(S(O)(=O)=O)C(CC)(CC)C([O-])=O NOLXQSVNNIIHMV-UHFFFAOYSA-L 0.000 claims description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 239000012237 artificial material Substances 0.000 claims 2
- XVVZSEXTAACTPS-UHFFFAOYSA-N 5-[hydroxy-(4-nitrophenoxy)phosphoryl]pentanoic acid Chemical compound OC(=O)CCCCP(O)(=O)OC1=CC=C([N+]([O-])=O)C=C1 XVVZSEXTAACTPS-UHFFFAOYSA-N 0.000 claims 1
- 239000004115 Sodium Silicate Substances 0.000 claims 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims 1
- 235000019438 castor oil Nutrition 0.000 claims 1
- 229910052570 clay Inorganic materials 0.000 claims 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims 1
- 239000000391 magnesium silicate Substances 0.000 claims 1
- 235000019792 magnesium silicate Nutrition 0.000 claims 1
- 229910052919 magnesium silicate Inorganic materials 0.000 claims 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims 1
- 235000019795 sodium metasilicate Nutrition 0.000 claims 1
- 229910052911 sodium silicate Inorganic materials 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 16
- 238000004519 manufacturing process Methods 0.000 abstract description 11
- 230000008901 benefit Effects 0.000 abstract description 8
- 238000003860 storage Methods 0.000 abstract description 5
- 239000004088 foaming agent Substances 0.000 abstract description 2
- 230000005484 gravity Effects 0.000 abstract description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract 1
- 239000003245 coal Substances 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 229910052909 inorganic silicate Inorganic materials 0.000 abstract 1
- 238000000197 pyrolysis Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 37
- 229910052751 metal Inorganic materials 0.000 description 24
- 239000002184 metal Substances 0.000 description 24
- 238000003756 stirring Methods 0.000 description 18
- 239000002283 diesel fuel Substances 0.000 description 17
- 239000007788 liquid Substances 0.000 description 16
- 239000006260 foam Substances 0.000 description 15
- 239000000843 powder Substances 0.000 description 14
- 238000007689 inspection Methods 0.000 description 8
- 238000005086 pumping Methods 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 7
- 238000002485 combustion reaction Methods 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 5
- 230000009471 action Effects 0.000 description 5
- 229910010272 inorganic material Inorganic materials 0.000 description 5
- 239000011147 inorganic material Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 238000009834 vaporization Methods 0.000 description 5
- 230000007812 deficiency Effects 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 230000008016 vaporization Effects 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000007865 diluting Methods 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000002737 fuel gas Substances 0.000 description 2
- 235000014380 magnesium carbonate Nutrition 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000010893 paper waste Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 241001062472 Stokellia anisodon Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000010883 coal ash Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000003915 liquefied petroleum gas Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 235000015927 pasta Nutrition 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000009527 percussion Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000002207 thermal evaporation Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Fireproofing Substances (AREA)
- Fire-Extinguishing Compositions (AREA)
Abstract
The invention provides a high-efficiency extinguish material for a major fire source, which comprises the following components by weight portion: 1 to 50 portions of component A, 1 to 2 portions of component B, 2 to 1,000 portions of component C, and 0 to 200 portions of component D. The component A is an inorganic silicate material; the component B comprises a foaming agent, a surfactant and a dispersing agent; the component C is water; and the component D comprises a defoamer, a fireproof material, a material generating flame-retardant gas through pyrolysis, a water absorber, a colloidal material and a filling material. The high-efficiency extinguish material overcomes the defects that the prior art has high production and using cost, fast running-off, low service efficiency, severer pollution and high residual quantity, has the advantages of low cost, controllable specific gravity, higher viscosity, difficult seepage, loose storage conditions, fast production, convenient use, safe performance and the like, and can achieve large batches of long-distance transportation. The high-efficiency extinguish material is applicable for large-scale fire extinguishing of oil products, flammable chemicals, large buildings, coal mines, forests and the like, other fire source control and the like.
Description
Technical field
The present invention relates to a kind of high-effect fire-extinguishing material that is used for great burning things which may cause a fire disaster, be specially adapted to the fire extinguishing of large-sized fires such as oil product, ignition control compound, building, colliery, forest and other burning things which may cause a fire disaster control etc.
Background technology
Existing extinguish material mainly contains following several:
(1) water.Water is non-flammable fluid, and it is most widely used in fire extinguishing, is the most cheap extinguishing chemical.The effect one of water fire extinguishing is cooling: 1 ℃ of heat that absorbs 1 kilocalorie of temperature rising of per kilogram water; And the vaporization of per kilogram steam the time will absorb 539.9 kilocalories heat; The 2nd, water has diluting effect to oxygen: water runs into that vaporization produces a large amount of steam behind the red-hot comburant, can stop air to enter the combustion zone, and simultaneously, the content of oxygen in the dilute combustion district, the oxygen that makes the combustion zone reduce gradually and weakens combustion intensity.The 3rd, the percussion of water: after fire pump pressurization, be input to water flow pressure that hydraulic giant ejects and can reach tens or the pressure of meter water columns up to a hundred, have very big kinetic energy impulsive force; The 4th, water is to the diluting effect of water-soluble flammable flammable liquid.The deficiency of its existence is that loss speed is fast, and service efficiency is low, and poor adhesive force infiltrates into undergroundly easily, and the less inflammable thing of proportions such as oil product are not had the fire extinguishing effect, causes easily because of using the excessive pollution in wide area that causes.
(2) paste materials such as clay slurry, yellow mud, coal ash pulp.Go out principle and advantage and water of these materials is near, exists because of the solid composition is arranged, and adhesive force is good slightly, but possesses the shortcoming of water simultaneously.
(3) fire foam.Foam fire-fighting is by the effect by chemistry, physics of the aqueous solution of fire foam, fills the countless minute bubbles of formation behind a large amount of gas.The specific gravity range 0.001～0.5 of bubble much smaller than the proportion of flammable flammable liquid, can cover liquid surface, forms foam blanket.The mechanism of action of foam fire-fighting has: (1) foam has formed foam blanket on the comburant surface, can make comburant surface and air isolated.(2) froth bed has sealed the comburant surface, can interdict the heat radiation of flame, stops the evaporation of comburant itself and near combustible.(3) the clear liquid that goes out of foam cools off burning surface.(4) foam is subjected to the steam of thermal evaporation generation can reduce near the concentration of the oxygen of comburant.The deficiency of its existence is: product cost is higher, and use cost is also high; Closely connect only and separate burning things which may cause a fire disaster, bigger to user's security threat; Dosage is generally less, is not suitable for large-sized fire.
(4) powder extinguishing agent.(1) dry-chemical fire extinguishing principle powder extinguishing agent is stored in dry powder extinguisher or the dry-chemical fire extinguishing equipment at ordinary times.Depend on gas-pressurized (CO during fire extinguishing
2Or N
2) pressure dry powder is penetrated from nozzle, form one vaporific powder that clips gas-pressurized stream, the directive comburant.Dry powder contacts a series of physical-chemical reaction principles of generation with flame as follows:
Sodium acid carbonate is decomposed by high temperature action in the dry powder, and its chemical equation is: 2NaHCO
3=Na
2CO
3+ H
2O+CO
2This reaction is the endothermic reaction, and a large amount of carbon dioxide and water are emitted in reaction, and water is heated and becomes steam and absorb a large amount of heats, plays the effect of cooling, dilution fuel gas; After dry powder enters flame,, reduce evaporation of liquid speed because the absorption and the scattering process of dry powder reduce the heat radiation of flame to fuel.(2) scope of application powder extinguishing agent mostly is contained in the fire extinguisher, is mainly used in the fire of the various water-insoluble and water-soluble flammable flammable liquids of putting out a fire to save life and property, and the fire of the fire of fuel gas such as natural gas and liquefied petroleum gas or general charging equipment.The phosphate powder extinguishing chemical can also put out solid fire.The non-water-soluble liquid fire can be effectively put out in phosphate powder and fluoroprotein foam or aqueous film forming foam coupling.The agent of going out of pluses and minuses and foam is similar, though dosage is big slightly, the burning things which may cause a fire disaster object is polluted bigger, the residual quantity height.
(5) solid incombustible such as glass cloth, asbestos quilt, ceramic fiber cloth, river sand, clay, cement.Mainly, intercept air, thereby play the effect of fire extinguishing by burning things which may cause a fire disaster is covered.Advantage: wide material sources, be easy to keeping, easy operating, use cost is low, and some is reusable, and shortcoming is only suitable small size fire, and continuity is carried in a large number, also closely operation only is bigger to fire fighter's life security threat, can't play effect when fire location is higher.
(6) inert gas agent such as carbon dioxide.CO
2Itself do not burn, not combustion-supporting, easily manufactured, be easy to liquefaction, be convenient to tinning and storage, be a kind of good extinguishing chemical.CO
2Be the gas that a kind of colourless nothing is smelt, it is 1.5 to the proportion of air, and common form is a gas, and the way with the cooling pressurization makes its liquefaction usually, is loaded in the steel cylinder; Solid-state CO
2Being called dry ice, is a kind of good refrigerant.Fire-fighting principle: CO
2Extinguishing chemical is to pressurize with the form of liquid state to fill in fire extinguisher, because CO
2The equilibrium vapor pressure height, cylinder valve one is opened, liquid is immediately by siphon pipe, conduit and nozzle and through the ejection of spray tube, liquid CO
2Vaporization rapidly, and from surrounding air, absorb a large amount of heat, (the liquid CO of per kilogram
2Need 138 kilocalories of heats during vaporization.) but because the spray tube has completely cut off heat conduction to external world, so CO
2During liquid the vaporization, can only absorb the heat of self.Cause the moisture of liquid own sharply to reduce, when its temperature drops to-78.5 ℃ (sublimation point), tiny flakes CO is just arranged
2Solid occurs.So that eject from extinguishing chemical is the CO of very low gas of temperature and solid
2Although, CO
2Temperature is very low, and comburant is had certain cooling effect, yet this effect far is not enough to stamp out the flames.Its fire extinguishing effect mainly be increase in the air do not burn, not combustion-supporting composition, airborne oxygen content is reduced, experiment shows: concentration of oxygen in the air of combustion zone≤12%, CO
2Concentration at 30%～35% o'clock, most burnings all can be extinguished.Though almost be applicable to any burning things which may cause a fire disaster, safety and environmental protection, the deficiency of its existence is: production and use cost are higher, keeping requires high, when running into large-sized fire, is difficult to allocate large number quipments, working condition is comparatively complicated, can't in time produce in a large number. and the user of service has relatively high expectations.
(7) other novel organic extinguish material, as: 1211 (difluorochlobromo-methanes).This class extinguishing chemical interrupts burning mainly by suppressing the chemical reaction process of burning, reaches the purpose of fire extinguishing.Its effect is to finish by the activity material in the combustion chain reaction of taking away, and this process is called chain breaking process and process of inhibition, and is similar to the powder extinguishing agent effect.And other extinguishing chemical mostly is physical processes such as cooling and dilution.Because compound itself contains the composition of fluorine etc., thereby has heat endurance and chemical inertness preferably, never degenerate convenient the use.Also be with nitrogen, CO when using as extinguishing chemical
2Or fluorine Lyons--12 are pressed into container, owing to the pressure effect, with vaporific ejection, become extinction using vapour from nozzle rapidly under the effect of the combustion heat during use.Advantage is applied widely, low-residual; Deficiency is that production, use cost are higher, may produce toxic gas under the condition of high temperature, and social storage level is little, and production, storage facilities are had relatively high expectations, and the large tracts of land fire can't be promoted the use of, and also only is applicable to simultaneously closely to use.
Summary of the invention
The object of the present invention is to provide a kind of cheaply, the viscosity height runs off, seepage velocity is slow, and proportion is controlled, and speed of production is fast, and is easy to use, and performance safety can realize the remote extinguish material of carrying.
The object of the present invention is to provide above-mentioned extinguish material preparation method and application.
Technical program of the present invention lies in: the composition of extinguish material (weight portion) is: component A is 1～50, and component B is 1～2; Component C is 2～1000; Component D is 0～200;
Component A is the inorganic silicic acid salt material;
Component B is at least a in blowing agent, surfactant, the dispersant;
Component C is a water;
Component D is a kind of, multiple in defoamer, fire proofing material, the pyrolytic material that produces fire-retardant gas, water absorbing agent, colloidal materials, the inserts or does not have.
The said inorganic silicic acid salt material of component A of the present invention is the framework material of this material of preparation, itself has fire-retardant or anti-fire action.As: alumina silicate fibre.
Component B said (1) blowing agent: the proportion of lightening material, improve utilization efficiency of material, in the face of burning things which may cause a fire disaster such as oil products the time, material can be floated on pasta, carry out fire-retardant, as cement blowing agent.(2) surfactant: with inorganic material from block, powdery or fibrously become glue or pulpous state after adding water, dispersion of materials or connection can be changed material tension, increase the viscosity and the adhesive force of material, strengthen the intermiscibility of inorganic material and water, as: butanedioic acid di-sec-octyl sodium sulfonate.(3) dispersant: inorganic material is dispersed into less state, promotes the effect of surfactant, also can disperse tackified finish to inorganic material separately, as: Sodium Polyacrylate.
The said water of component C: be the shank of this material, utilize water the characteristic of fire to be played the effect of cooling, fire-retardant, diluent air.
Component D is auxiliary material: (1), colloidal materials mainly are the absorption affinities that increases material, be convenient to material and be adsorbed on inflammable surface and play the covering effect, as: white glue with vinyl.(2), the pyrolytic material mainly is to produce decomposition reaction under the condition of high temperature, the gas that is generated can produce diluting effect to air, as carbonic hydroammonium.(3), water absorbing agent, increase suction, thickening, the moisture-retaining capacity of material, improve the viscosity and the water content of material, as polyacrylamide.(4), fire proofing material is the main anti-fire action that rises, improve the product resistance to elevated temperatures, as ammonium polyphosphate.(5), inserts mainly rises increases material proportion, improve transporting velocity and less important absorption and iris action, as clay.(6), mainly to act on be control material proportion such as methyl-silicone oil emulsion to defoamer.
Fire-fighting principle of the present invention is: 1, control ignition point: water content reaches as high as 98% above 35% among the present invention, takes away a large amount of heats during because of water evaporates, thereby ignition temperature is played inhibitory action.With traditional water identical effect is arranged.2, combustible is wrapped to form does not fire layer: the present invention is in the combustible overwrite procedure; combustible is formed protective layer; under the situation of the complete evaporate to dryness of moisture content; the remaining incombustible material that is mainly; inorganic material generally can be more than high temperature resistant 200 degree; even run into high temperature, can not burn yet, still can form not flame-proofing protective layer on right thing surface.3, air-isolation: in oil product ignition control compound fire extinguishing, because this material proportion can control, so when controlling to proportion less than the fluent material of required fire extinguishing, it can float at liquid surface, thereby plays the air insulating effect, plays the fire extinguishing effect.4, the non-flammable compressive gas that a large amount of water vapour and other inserts discharged under high-temperature condition also can play certain dilution, buffer action to air.
The prepared material of the present invention is slurry or colloid, can adopt direct conveying of pump housing materials such as underflow pump, gear pump or manpower to splash; Also can adopt concrete delivery truck to transport at a distance; Carry and the high-altitude conveying with pump truck is remote; Fire fighting truck sprays; Spray in the aircraft high-altitude or mode such as high-altitude delivery is delivered near the burning things which may cause a fire disaster or in the burning things which may cause a fire disaster.
The present invention compared with prior art has the following advantages:
(1) with traditional water ratio, the present invention has following characteristics: (1) is difficult for infiltration.The present invention is sticking shape foaming paste materials, and flowability is relatively poor relatively, and penetration is relatively low simultaneously, a large amount of losses of short time can not occur and be penetrated into underground situation in a large number in fire extinguishing procedure, thereby guarantee the service efficiency of material.(2) adhesive force is higher.The present invention is because it is the characteristics of wet stock body material, so adhesive force obviously is better than water, and can add colloidal materials in the material, further strengthened the adhesive force of material, so under building, forest fire situation, all can improve the fire extinguishing effect greatly under the dry and wet state attached to the combustible surface.(3) proportion is controlled between 0.2～1.2 ton every cubic metre; The I of the present invention's proportion under wet body state reaches 0.2 ton every cubic metre.Under the condition of high temperature, the bubble that produces during along with the loss of moisture content and moisture content and other material at high temperature enlarges volume, I reaches 0.015 ton every cubic metre under the stem body materials behavior, because bigger volume can be brought into play better fire extinguishing effect under the situation of equivalent weight; Can float when oil product, liquid chemical fire and on liquid level, air effectively be intercepted.
(2) compare with fire foam, powder extinguishing agent and 1211 extinguishing chemicals, the present invention has drawn the above-mentioned material advantage, and conveniently (nothing is pressed to have keeping, be not afraid of and make moist), advantages such as production and use cost are low, most importantly can carry by the common pump housing, even pump truck (China's pump truck delivery head can reach more than 70 meters) conveying, fire fighter's life security threat reduced widely by remote fire extinguishing.Also widen the source channel of Fire extinguisher for large-sized fire, realized delivered simultaneously.
(3) other advantage: production equipment of the present invention and production technology are simple, speed of production is fast, can adopt the raw material storage mode to lay in, after the fire suppression, as long as to collect the stem body or the wet body material of returning all recyclable, remove impurity and add chemical assistant again before the use and water can reuse in next time.
The specific embodiment
Embodiment 1
Get alumina silicate fibre 10 grams, sepiolite 20 grams, water 800 grams, Sodium Polyacrylate 5 grams, lauryl sodium sulfate 6 grams are put into stirred vessel (12 centimetres of diameters, high 20 centimetres) in, stir and finished slurry making (1400 rpms of speeds of agitator) in 5 minutes, promptly get product of the present invention.
Effect explanation: get 95% industrial alcohol, 2000 grams and put in the iron ware (20 centimetres of diameters, high 30 centimetres), light with lighter.Add 400 milliliters of slurries after 2 minutes, the flames of anger after 1 minute, fire extinguishes fully after 3 minutes.
Embodiment 2
Get 5 kilograms of alumina silicate fibres, 5 kilograms of sepiolites, 15 kilograms of shepardites, 600 kilograms in water, 10 kilograms of butanedioic acid di-sec-octyl sodium sulfonates, 1 kilogram of waterglass, 1 kilogram in urea, 0.2 kilogram of high molecular weight sodium polyacrylate, 1 kilogram of clay is put into stirring pool (120 centimetres of diameters, high 150 centimetres) in, pull an oar and finished slurrying work in 50 minutes, (900 rpms of speeds of agitator) makes product of the present invention.
Effect explanation: cover with the meadow of weeds winter in January, 2009, the same day is calm substantially, the slurry of accomplishing fluently is poured on equably underground along 15 meters circles of diameter, and width is about 35～50 centimetres, hay is lighted at central point with lighter.Hay promptly burnt each limit at about 12 minutes, and naked light extinguishes all that fire all extinguishes after .25 minute after 15 minutes, and nowhere the outer hay of test circle is lighted.
Embodiment 3
Water intaking cement foaming agent (Zhengzhou City wall body material factory forever provides) 1 kilogram, water foams with foaming machine for 10 kilograms; Get 10 kilograms of alumina silicate fibres, 8 kilograms of sepiolites, 1 kilogram in asbestos, 80 kilograms in water, 4 kilograms of neopelexes, 5 kilograms of Sodium Polyacrylates, put into stirred vessel (60 centimetres of diameters, high 110 centimetres) in, pulled an oar 265 minutes, add again and send out foam good, ammonium polyphosphate 30 grams, dodecyl chlorination ammonium 15 gram, polyvinyl alcohol emulsion 100 grams stir and finished slurrying work (110 rpms of speeds of agitator) in 15 minutes and make product of the present invention.
Effect explanation: take away one in mouthful metal bucket, put into 100 kilograms of No. 0 diesel oil, place outside 40 meters of the stirring pools, get one of underflow pump, link to each other with the deckered stock chest outlet with 20 meters rubber tubes, link to each other with the underflow pump outlet with 20 meters rubber tubes, the underflow pump outlet rubber tube other end connects about 6 meters long galvanized pipes, be placed on opening metal bucket top, light diesel oil in the metal bucket at a distance.Add slurry with pump after 3 minutes, slurry overflows after half a minute, and termination of pumping is after 5 minutes, and fire extinguishes fully on inspection.
Embodiment 4
Get 3 kilograms of sepiolites, 1 kilogram of calcium silicates, 70 kilograms in water, 1 kilogram of neopelex, Sodium Polyacrylate 50 grams, NPE 500 grams are put in the stirred vessel (60 centimetres of diameters, high 110 centimetres), pulled an oar 145 minutes, add methyl-silicone oil 10 grams again, stir and finished slurrying work (600 rpms of speeds of agitator) in 5 minutes, make product of the present invention.
Effect explanation: take away one in mouthful metal bucket, put into 100 kilograms of No. 0 diesel oil, place outside 40 meters of the stirring pools, get one of underflow pump, link to each other with the deckered stock chest outlet with 20 meters rubber tubes, link to each other with the underflow pump outlet with 20 meters rubber tubes, the underflow pump outlet rubber tube other end connects about 6 meters long galvanized pipes, be placed on opening metal bucket top, light diesel oil in the metal bucket at a distance.Add slurry with pump after 3 minutes, slurry overflows after half a minute, and termination of pumping is after 5 minutes, and fire extinguishes fully on inspection.
Embodiment 5
10 kilograms of water intaking magnesites, 1 kilogram of sepiolite, 1 kilogram of calcium silicates, 1 kilogram of mineral wool, 1 kilogram of modified lignin resin sodium sulfonate, 1 kilogram of cement blowing agent (Zhengzhou City wall body material factory forever provides), 50 kilograms in water, put into stirred vessel (60 centimetres of diameters, high 110 centimetres) in, pulled an oar 115 minutes, add Boratex 10 grams again, carbonic hydroammonium 10 gram stirs and finished slurrying work (700 rpms of speeds of agitator) in 3 minutes and make product of the present invention.
Effect explanation: take away one in mouthful metal bucket, put into 100 kilograms of No. 0 diesel oil, place outside 40 meters of the stirring pools, get one of underflow pump, link to each other with the deckered stock chest outlet with 20 meters rubber tubes, link to each other with the underflow pump outlet with 20 meters rubber tubes, the underflow pump outlet rubber tube other end connects about 6 meters long galvanized pipes, be placed on opening metal bucket top, light diesel oil in the metal bucket at a distance.Add slurry with pump after 3 minutes, slurry overflows after half a minute, and termination of pumping is after 5 minutes, and fire extinguishes fully on inspection.
Embodiment 6
Get 1 kilogram of alumina silicate fibre, 1 kilogram of shepardite, 1.2 kilograms in sulfosuccinic acid double tridecyl ester sodium, 60 kilograms in water.Put in the stirred vessel (60 centimetres of diameters, high 110 centimetres), pulled an oar 145 minutes, add 5 kilograms of sodium acid carbonates again, polyacrylamide 20 grams, 1 kilogram of shepardite, modified lignin resin sodium sulfonate 500 grams stir the slurrying work (750 rpms of speeds of agitator) of finishing in 15 minutes.
Effect explanation: take away one in mouthful metal bucket, put into 100 kilograms of No. 0 diesel oil, place outside 40 meters of the stirring pools, get one of underflow pump, link to each other with the deckered stock chest outlet with 20 meters rubber tubes, link to each other with the underflow pump outlet with 20 meters rubber tubes, the underflow pump outlet rubber tube other end connects about 6 meters long galvanized pipes, be placed on opening metal bucket top, light diesel oil in the metal bucket at a distance.Add slurry with pump after 3 minutes, slurry overflows after half a minute, and termination of pumping is after 5 minutes, and fire extinguishes fully on inspection.
Embodiment 7
Get 2 kilograms of alumina silicate fibres, 16 kilograms of sepiolites, 4 kilograms of waterglass, 1 kilogram of mineral wool, 1 kilogram of Sodium Polyacrylate, 6 kilograms of neopelexes, 40 kilograms in water, put in the stirred vessel (60 centimetres of diameters, high 110 centimetres) and pulled an oar 150 minutes, finish slurrying work (400 rpms of speeds of agitator).
Effect explanation: take away one in mouthful metal bucket, put into 100 kilograms of No. 0 diesel oil, place outside 40 meters of the stirring pools, get one of underflow pump, link to each other with the deckered stock chest outlet with 20 meters rubber tubes, link to each other with the underflow pump outlet with 20 meters rubber tubes, the underflow pump outlet rubber tube other end connects about 6 meters long galvanized pipes, be placed on opening metal bucket top, light diesel oil in the metal bucket at a distance.Add slurry with pump after 3 minutes, slurry overflows after half a minute, and termination of pumping is after 5 minutes, and fire extinguishes fully on inspection.
Embodiment 8
Get 6 kilograms of sepiolites, 1 kilogram in asbestos, mineral wool 900 grams, 1 kilogram of Sodium Polyacrylate, 1 kilogram of lauryl sodium sulfate, 1 kilogram of octyl phenol APEO, 40 kilograms in water, 1 kilogram of waterglass, 1 kilogram of polyvinyl alcohol emulsion, high molecular weight sodium polyacrylate 30 grams, put into stirred vessel (60 centimetres of diameters, high 110 centimetres) in, pulled an oar 150 minutes, finish slurrying work (400 rpms of speeds of agitator).
Effect explanation: take away one in mouthful metal bucket, put into 100 kilograms of No. 0 diesel oil, place outside 40 meters of the stirring pools, get one of underflow pump, link to each other with the deckered stock chest outlet with 20 meters rubber tubes, link to each other with the underflow pump outlet with 20 meters rubber tubes, the underflow pump outlet rubber tube other end connects about 6 meters long galvanized pipes, be placed on opening metal bucket top, light diesel oil in the metal bucket at a distance.Add slurry with pump after 3 minutes, slurry overflows after half a minute, and termination of pumping is after 5 minutes, and fire extinguishes fully on inspection.
Embodiment 9
25 kilograms of rock wools, 45 kilograms in water, 1 kilogram of HP95 (secondary alkyl sulfonic acid compound derivatives) puts in the stirred vessel (60 centimetres of diameters, high 110 centimetres), pulled an oar 125 minutes, add 10 kilograms of precipitated calcium carbonates again, 2 kilograms of carboxymethyl celluloses, white glue with vinyl 40 grams, methyl silicon sodium alcoholate 5 grams stir the slurrying work (750 rpms of speeds of agitator) of finishing in 18 minutes.
Effect explanation: get the seasoned wood double centner, drink No. 0 diesel oil that takes a morsel and light, will prepare material with gear pump after 15 minutes and add in the fire from top to bottom.The flames of anger after 2 minutes was all extinguished after 25 minutes.
Embodiment 10
Get 1 kilogram of alumina silicate fibre, 9 kilograms of sepiolites, 1 kilogram in asbestos, 50 kilograms in water, 4 kilograms of sulfonated castor oils, 1 kilogram of modified lignin resin sodium sulfonate is put into stirred vessel (60 centimetres of diameters, high 110 centimetres) in, pulled an oar 125 minutes, and added 0.5 kilogram of polyacrylamide again, 1 kilogram of carboxymethyl cellulose, 1 kilogram of white glue with vinyl stirs the slurrying work (550 rpms of speeds of agitator) of finishing in 8 minutes.
Effect explanation: take away one in mouthful metal bucket, put into 100 kilograms of No. 0 diesel oil, place outside 40 meters of the stirring pools, get one of underflow pump, link to each other with the deckered stock chest outlet with 20 meters rubber tubes, link to each other with the underflow pump outlet with 20 meters rubber tubes, the underflow pump outlet rubber tube other end connects about 6 meters long galvanized pipes, be placed on opening metal bucket top, light diesel oil in the metal bucket at a distance.Add slurry with pump after 3 minutes, slurry overflows after half a minute, and termination of pumping is after 5 minutes, and fire extinguishes fully on inspection.
Embodiment 11
Get 6 kilograms of alumina silicate fibres, 11 kilograms of sepiolites, 4 kilograms of mineral wools, 40 kilograms in water, 20 kilograms of sodium sulfate of polyethenoxy ether of fatty alcohol, 1 kilogram of nekal is put into stirred vessel (60 centimetres of diameters, high 110 centimetres) in, pulled an oar 50 minutes, and added 5 kilograms of waterglass, 5 kilograms of calgons, continue stirring and add methyl-silicone oil emulsion 100 grams after 30 minutes again, stir the slurrying work (1200 rpms of speeds of agitator) of finishing in 7 minutes.
Effect explanation: take away one in mouthful metal bucket, put into 100 kilograms of No. 0 diesel oil, place outside 40 meters of the stirring pools, get one of underflow pump, link to each other with the deckered stock chest outlet with 20 meters rubber tubes, link to each other with the underflow pump outlet with 20 meters rubber tubes, the underflow pump outlet rubber tube other end connects about 6 meters long galvanized pipes, be placed on opening metal bucket top, light diesel oil in the metal bucket at a distance.Add slurry with pump after 3 minutes, slurry overflows after half a minute, and termination of pumping is after 5 minutes, and fire extinguishes fully on inspection.
Embodiment 12
4 kilograms of water intaking magnesites, 600 kilograms in water, sodium diethylhexyl sulfosuccinate is put in the stirred vessel (120 centimetres of diameters, high 150 centimetres) for 1 kilogram, pulled an oar 25 minutes, add 0.5 kilogram of waterglass, 2 kilograms of high molecular weight sodium polyacrylates, 3 kilograms of carboxymethyl celluloses, 0.5 kilogram of calcium silicates, 5 kilograms in magnesia, 5 kilograms in magnesium chloride, pull an oar again 10 minutes (1000 rpms of speeds of agitator).
Effect explanation: get 200 kilograms in dried waste paper, 300 kilograms of waste plastic products are lighted the waste plastic product that ignites behind the waste paper.Upwards add with pump after 6 minutes and made slurry, after 25 minutes, fire all extinguishes.
Claims (4)
1. extinguish material, it is characterized in that: the weight of extinguish material consists of: component A is 1～50 part; Component B is 1～2 part; Component C is 2～1000 parts; Component D is 0～200 part;
Component A is the inorganic silicic acid salt material; The said inorganic silicic acid salt material of component A is at least a in sodium metasilicate, calcium silicates, magnesium silicate, alumina silicate and natural, the artificial material that contains silicate;
Component B is at least a in blowing agent, surfactant, the dispersant; The said blowing agent of component B, surfactant, dispersant is a cement blowing agent, lauryl sodium sulfate, butanedioic acid di-sec-octyl sodium sulfonate, neopelex, dodecyl chlorination ammonium, sulfosuccinic acid double tridecyl ester sodium, secondary alkyl sulfonic acid compound derivatives, sulfonated castor oil, sodium sulfate of polyethenoxy ether of fatty alcohol, nekal, NPE, sodium diethylhexyl sulfosuccinate, octyl phenol APEO, calgon, the modified lignin resin sodium sulfonate, Sodium Polyacrylate;
Component C is a water;
Component D is material, water absorbing agent, colloidal materials, the inserts that defoamer, fire proofing material, pyrolytic produce fire-retardant gas; Material, water absorbing agent, colloidal materials, inserts that the said defoamer of component D, fire proofing material, pyrolytic produce fire-retardant gas are methyl-silicone oil, methyl-silicone oil emulsion, methyl silicon sodium alcoholate, ammonium polyphosphate, Boratex, sodium acid carbonate, carbonic hydroammonium, urea, polyacrylamide, high molecular weight sodium polyacrylate, carboxymethyl cellulose, polyvinyl alcohol emulsion, white glue with vinyl, aluminum phosphate, precipitated calcium carbonate, clay, magnesia, magnesium chloride.
2. extinguish material according to claim 1 is characterized in that: natural, the artificial material that contain silicate are: alumina silicate fibre, sepiolite, shepardite, asbestos, rock wool, mineral wool or waterglass.
3. the preparation method of the described extinguish material of claim 1 is characterized in that: each component is put into container according to the above ratio, pulled an oar 3～300 minutes, 100～2000 rpms of speeds of agitator become foaming slurry or colloidal state with mixture.
4. the application of the described extinguish material of claim 1 in oil product, ignition control compound, building, colliery, forest and the control of other burning things which may cause a fire disaster.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103274730A (en) * | 2013-06-12 | 2013-09-04 | 许庆华 | Cement compound type flame-retardant foaming agent |
| CN103274755A (en) * | 2013-06-12 | 2013-09-04 | 许庆华 | Coal ash composite type flame-retardant foaming agent |
| CN103274755B (en) * | 2013-06-12 | 2014-07-23 | 许庆华 | Coal ash composite type flame-retardant foaming agent |
| CN103274730B (en) * | 2013-06-12 | 2014-07-23 | 许庆华 | Cement compound type flame-retardant foaming agent |
| RU2757302C1 (en) * | 2019-01-21 | 2021-10-13 | Шаньдун Юниверсити Оф Сайенс Энд Текнолоджи | Ecologically friendly foamed gel for preventing spontaneous combustion of coal and fight against such spontaneous combustion |
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| Publication number | Publication date |
|---|---|
| CN101543672A (en) | 2009-09-30 |
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