CN101286452A - Method for manufacturing metal oxide semiconductor transistor element - Google Patents
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- Metal-Oxide And Bipolar Metal-Oxide Semiconductor Integrated Circuits (AREA)
Abstract
Description
技术领域 technical field
本发明涉及一种制作金属氧化物半导体(metal-oxide-semiconductor,MOS)晶体管元件的方法,尤指一种利用具有双应力(binary-stress)的应力覆盖层来制作N型与P型金属氧化物半导体晶体管元件的方法。本发明的特征在于利用惰性气体处理来改变的应力覆盖层的应力值,使N型或P型金属氧化物半导体晶体管元件可以同时具有较高的饱和漏极电流,由此改善半导体晶体管元件的操作效能。The present invention relates to a method for manufacturing metal-oxide-semiconductor (metal-oxide-semiconductor, MOS) transistor elements, in particular to a method for making N-type and P-type metal oxides by utilizing a stress covering layer with binary-stress. method for semiconductor transistor devices. The present invention is characterized in that the stress value of the stress covering layer is changed by inert gas treatment, so that the N-type or P-type metal oxide semiconductor transistor element can have a higher saturation drain current at the same time, thereby improving the operation of the semiconductor transistor element efficacy.
背景技术 Background technique
随着半导体工艺进入深亚微米时代,对于晶体管元件的效能与稳定性的需求日益提高,而具有应变硅(strained silicon)的金属氧化物半导体晶体管元件也应运而生。当硅的能带结构(band structure)发生改变,可造成载流子移动性增加,因此沟道区域采用应变硅结构的元件可获得1.5倍甚至高达8倍左右的速度增益。目前形成应变硅金属氧化物半导体晶体管的方法主要可分为两种方式。其一是利用硅锗层的晶格常数与硅不同的原理,使硅外延在硅锗上时产生结构上应变。其二是在晶体管结构上形成一种具有应力的应力覆盖层,利用应力覆盖层的应力来改变晶体管元件的沟道区域的晶格结构。As the semiconductor technology enters the deep sub-micron era, the demand for the performance and stability of the transistor device is increasing, and the metal oxide semiconductor transistor device with strained silicon (strained silicon) has also emerged. When the band structure of silicon is changed, the mobility of carriers can be increased. Therefore, devices with strained silicon structure in the channel region can obtain a speed gain of 1.5 times or even up to 8 times. Currently, methods for forming strained silicon metal oxide semiconductor transistors can be mainly divided into two methods. One is to use the principle that the lattice constant of the silicon germanium layer is different from that of silicon to cause structural strain when silicon is epitaxy on silicon germanium. The second is to form a stress covering layer with stress on the transistor structure, and use the stress of the stress covering layer to change the lattice structure of the channel region of the transistor element.
请参考图1至图3,其绘示的是传统上制作N型金属氧化物半导体晶体管元件10与P型金属氧化物半导体晶体管元件110的方法剖面示意图。首先,如图1所示,首先,提供半导体基底16,半导体基底16上定义有第一晶体管区域1与第二晶体管区域2。第一与第二晶体管区域1、2上分别包含有栅极介电层14、114位于半导体基底16上,以及栅极12、112位于栅极介电层14、114上,其中栅极12、112一般包含有多晶硅,而相对应的栅极12、112与栅极介电层14、114可各合称为栅极结构。半导体基底16在第一晶体管区域1中具有源极区域18与漏极区域20,分别位于栅极12两侧的半导体基底16中。半导体基底16在第二晶体管区域2中具有源极区域118与漏极区域120,分别位于栅极112两侧的半导体基底16中。源极区域18和漏极区域20之间通过沟道区域22互相分隔,而源极区域118和漏极区域120之间通过沟道区域122互相分隔。根据传统技术,半导体基底16通常另包含有浅结源极延伸17、117以及浅结漏极延伸19、119。Please refer to FIG. 1 to FIG. 3 , which illustrate schematic cross-sectional views of conventional methods for fabricating the
在图1中,N型金属氧化物半导体晶体管元件10的源极区域18以及漏极区域20为注入砷、锑或磷的N+掺杂区域,N型金属氧化物半导体晶体管元件10的沟道区域22则为P型掺杂区域。P型金属氧化物半导体晶体管元件110的源极区域118以及漏极区域120为P+掺杂区域,P型金属氧化物半导体晶体管元件110的沟道区域122则为N型掺杂区域。In FIG. 1, the
在栅极12、112的侧壁上形成有由氮化硅构成的侧壁子32、132。在侧壁子32、132与栅极12、112的侧壁之间为衬垫层30、130,其通常为二氧化硅所构成。N型金属氧化物半导体晶体管元件10及P型金属氧化物半导体晶体管元件110的裸露硅表面,包括栅极12、112、源极区域18、118与漏极区域20、120,皆形成有硅化金属层(silicide layer)42,以与后续形成的接触插塞相接。由于制作如图1中的半导体结构的工艺为本领域技术人员的通常知识,因此其详细制作程序在此不予赘述。
如图2所示,在完成图1中的N型金属氧化物半导体晶体管元件10及P型金属氧化物半导体晶体管元件110之后,通常会接着在半导体基底16上沉积氮化硅的应力覆盖层46,其中应力覆盖层46覆盖硅化金属层42以及侧壁子32、132,而其厚度通常介于200至400埃左右。沉积应力覆盖层46的目的一方面是改变N型金属氧化物半导体晶体管元件10的沟道区域22的晶格结构,另一方面是在使后续的接触洞蚀刻能有明显的蚀刻终点,也就是用来作为接触蚀刻停止层(contact etch stop layer,CESL)。在沉积应力覆盖层46之后,接着再进行退火(anneal)工艺,强化应力覆盖层46的应力。As shown in FIG. 2, after the
如图3所示,接着沉积介电层48,例如硅氧层等,通常介电层48较应力覆盖层46厚许多。之后再利用传统的光刻以及蚀刻工艺,在介电层48与应力覆盖层46中形成接触洞52。As shown in FIG. 3 , a
然而,前述的传统技术仍存在有待克服的缺点。应力覆盖层46沉积在一整面芯片上,因此同时增加了N型金属氧化物半导体晶体管元件10与P型金属氧化物半导体晶体管元件110的伸张应力。虽然N型金属氧化物半导体晶体管元件10的效能会因此提升,然而P型金属氧化物半导体晶体管元件110的效能却反而会因此下降,顾此失彼。However, the aforementioned conventional techniques still have disadvantages to be overcome. The
为了能同时提升N型金属氧化物半导体晶体管元件与P型金属氧化物半导体晶体管元件的运作效能,应力覆盖层46的工艺中也采用另一种称为选择性应力系统(selective strain scheme,SSS)的已知技术。在已知技术中,先全面沉积具有伸张应力的应力覆盖层在半导体基底上,覆盖在N型金属氧化物半导体晶体管元件与P型金属氧化物半导体晶体管元件上方。接着,利用图案化工艺来去除P型金属氧化物半导体晶体管元件上方的伸张应力覆盖层。之后,再全面沉积具有压缩应力的应力覆盖层在半导体基底上,覆盖在伸张应力覆盖层与P型金属氧化物半导体晶体管元件上方。接着,再利用另一图案化工艺来去除N型金属氧化物半导体晶体管元件上方的压缩应力覆盖层。In order to improve the operating performance of the NMOS transistor and the PMOS transistor at the same time, the process of the
虽然这种SSS的已知技术可以同时提升N型金属氧化物半导体晶体管元件与P型金属氧化物半导体晶体管元件的运作效能,但是其制作过程却非常繁复,不但耗费冗长的时间,同时也需要付出较为庞大的成本。此外,其繁复的制作过程还可能会增加产品的缺陷。Although the known technology of this SSS can simultaneously improve the operating performance of N-type metal-oxide-semiconductor transistors and P-type metal-oxide-semiconductor transistors, its manufacturing process is very complicated, which not only takes a long time, but also requires a lot of effort. relatively large cost. In addition, its complicated manufacturing process may also increase product defects.
发明内容 Contents of the invention
因此,本发明的主要目的在提供一种利用具有双应力的应力覆盖层来制作N型与P型金属氧化物半导体晶体管元件的方法,其具有较佳的操作效能。Therefore, the main objective of the present invention is to provide a method for fabricating N-type and P-type MOS transistors with a stress capping layer having dual stresses, which has better operating performance.
根据本发明的一个优选实施例,本发明提供一种制作金属氧化物半导体晶体管元件的方法。首先提供半导体基底、栅极介电层位于半导体基底上,以及栅极位于栅极介电层上。半导体基底具有源极区域与漏极区域,源极区域与漏极区域分别位于栅极两侧的半导体基底中。之后,在半导体基底上形成应力覆盖层并覆盖栅极、源极区域与漏极区域。接着,进行惰性气体处理,以改变应力覆盖层的应力值。According to a preferred embodiment of the present invention, the present invention provides a method for fabricating a metal oxide semiconductor transistor device. First, a semiconductor substrate is provided, a gate dielectric layer is located on the semiconductor substrate, and a gate is located on the gate dielectric layer. The semiconductor substrate has a source region and a drain region, and the source region and the drain region are respectively located in the semiconductor substrate on both sides of the gate. Afterwards, a stress covering layer is formed on the semiconductor substrate and covers the gate, the source region and the drain region. Next, an inert gas treatment is performed to change the stress value of the stress covering layer.
根据本发明的另一优选实施例,本发明另提供一种制作金属氧化物半导体晶体管元件的方法。首先提供半导体基底,半导体基底上定义有第一晶体管区域与第二晶体管区域。第一与第二晶体管区域上分别包含有栅极结构,各栅极结构相对两侧的半导体基底中具有源极区域与漏极区域。之后,在第一与第二晶体管区域中的半导体基底上形成应力覆盖层,应力覆盖层覆盖在栅极结构、源极区域与漏极区域上。接着,在应力覆盖层上形成图案化硬掩模,图案化硬掩模覆盖在第二晶体管区域中的应力覆盖层上,而暴露出第一晶体管区域中的应力覆盖层,再进行惰性气体处理,以改变未被图案化硬掩模所覆盖的应力覆盖层的应力值。然后,去除图案化硬掩模。According to another preferred embodiment of the present invention, the present invention further provides a method for manufacturing a metal oxide semiconductor transistor device. First, a semiconductor substrate is provided, and a first transistor region and a second transistor region are defined on the semiconductor substrate. The first and second transistor regions respectively include a gate structure, and the semiconductor substrate on opposite sides of each gate structure has a source region and a drain region. Afterwards, a stress covering layer is formed on the semiconductor substrate in the first and second transistor regions, and the stress covering layer covers the gate structure, the source region and the drain region. Next, a patterned hard mask is formed on the stress covering layer, the patterned hard mask covers the stress covering layer in the second transistor region, and exposes the stress covering layer in the first transistor region, and then an inert gas treatment is performed , to change the stress value of the stress capping layer not covered by the patterned hard mask. Then, the patterned hard mask is removed.
为了更近一步了解本发明的特征及技术内容,请参阅以下有关本发明的详细说明与附图。然而附图仅供参考与辅助说明用,并非用来对本发明加以限制。In order to further understand the features and technical content of the present invention, please refer to the following detailed description and accompanying drawings of the present invention. However, the drawings are only for reference and auxiliary description, and are not intended to limit the present invention.
附图说明 Description of drawings
图1至图3绘示的是传统上制作N型金属氧化物半导体晶体管元件与P型金属氧化物半导体晶体管元件的方法剖面示意图。1 to 3 are schematic cross-sectional views of conventional methods for fabricating N-type MOS transistors and P-type MOS transistors.
图4至图11绘示的是本发明的第一优选实施例N型金属氧化物半导体晶体管元件与P型金属氧化物半导体晶体管元件的方法剖面示意图。4 to 11 are schematic cross-sectional diagrams illustrating the method of the NMOS transistor device and the PMOS transistor device according to the first preferred embodiment of the present invention.
图12至图17,其绘示的是本发明的第二优选实施例N型金属氧化物半导体晶体管元件与P型金属氧化物半导体晶体管元件的方法剖面示意图。FIG. 12 to FIG. 17 are schematic cross-sectional views showing the methods of the NMOS transistor device and the PMOS transistor device according to the second preferred embodiment of the present invention.
图18绘示的是本发明的应力覆盖层的伸张应力值的直条示意图。FIG. 18 is a bar diagram showing the tensile stress values of the stress covering layer of the present invention.
附图标记说明Explanation of reference signs
1 第一晶体管区域 2 第二晶体管区域1
10 NMOS晶体管元件 12 栅极10
14 栅极介电层 16 半导体基底14
17 浅结源极延伸 18 源极区域17 shallow
19 浅结漏极延伸 20 漏极区域19 shallow
22 沟道区域 30 衬垫层22
32 侧壁子 42 硅化金属层32
46 应力覆盖层 48 介电层46
52 接触洞 68 掩模层52
78 掩模层 98 光刻胶78
110 PMOS晶体管元件 112 栅极110
114 栅极介电层 117 浅结源极延伸114 Gate
118 源极区域 119 浅结漏极延伸118
120 漏极区域 122 沟道区域120
130 衬垫层 132 侧壁子130
188 图案化硬掩模 212 数值188 patterned hardmask 212 value
214 数值 216 数值214
222 数值 224 数值
226 数值 232 数值226
234 数值 236 数值
242 数值 244 数值
246 数值 252 数值
254 数值 256 数值
262 数值 264 数值
266 数值 301 第一晶体管区域
302 第二晶体管区域 310 NMOS晶体管元件302
312 栅极 314 栅极介电层312
316 半导体基底 317 浅结源极延伸
318 源极区域 319 浅结漏极延伸318
320 漏极区域 322 沟道区域320
330 衬垫层 332 侧壁子330
342 硅化金属层 346 应力覆盖层342
348 介电层 352 接触洞348 dielectric layer 352 contact hole
410 PMOS晶体管元件 412 栅极410
414 栅极介电层 417 浅结源极延伸414
418 源极区域 419 浅结漏极延伸418
420 漏极区域 422 沟道区域420
430 衬垫层 432 侧壁子430
具体实施方式 Detailed ways
请参考图4至图11,其绘示的是本发明的第一优选实施例N型金属氧化物半导体晶体管元件310与P型金属氧化物半导体晶体管元件410的方法剖面示意图,其中相同的元件或部位仍沿用相同的符号来表示。需注意的是图式仅以说明为目的,并未依照原尺寸作图。此外,在图4至图11中对于与本发明有关的部分的光刻及蚀刻工艺由于为本领域技术人员所熟知,因此并未明示于图示中。Please refer to FIG. 4 to FIG. 11 , which are schematic cross-sectional diagrams illustrating the method of the N-type metal-oxide-
本发明涉及一种制作集成电路中具有应变硅的金属氧化物半导体晶体管元件或互补式金属氧化物半导体(complementarymetal-oxide-semiconductor,CMOS)晶体管元件的方法。为简化说明,图4至图11中特别以CMOS晶体管工艺作为说明。如图4所示,先提供半导体基底316。半导体基底316上定义有第一晶体管区域301与第二晶体管区域302,其中第一晶体管区域301乃用以制作N型金属氧化物半导体晶体管元件的区域,而第二晶体管区域302则用以制作P型金属氧化物半导体晶体管元件。半导体基底316可以是硅基底或者是绝缘体上硅(silicon-on-insulator,SOI)基板等。首先,在第一晶体管区域301内的半导体基底316上同时形成栅极介电层314与位于栅极介电层314上的栅极312。另一方面,在第二晶体管区域302内的半导体基底316上同时形成栅极介电层414与位于栅极介电层414上的栅极412。相对应的栅极312与栅极介电层314可合称为栅极结构,相对应的栅极412与栅极介电层414合称为栅极结构。栅极312及412通常包含有多晶硅或金属硅化物等导电材料。在本实施例中,栅极介电层314及414可由二氧化硅所构成。然而,在本发明的另一实施例中,栅极介电层314及414亦可由高介电常数(high-k)等绝缘材料所构成。The present invention relates to a method of fabricating metal-oxide-semiconductor transistor elements or complementary metal-oxide-semiconductor (CMOS) transistor elements with strained silicon in integrated circuits. To simplify the description, in FIG. 4 to FIG. 11 , the CMOS transistor technology is used for illustration. As shown in FIG. 4 , a
之后,利用栅极结构作为注入掩模,在第一晶体管区域301内的半导体基底316中同时形成浅结源极延伸317以及浅结漏极延伸319,浅结源极延伸317以及浅结漏极延伸319之间为沟道区域322。接着,在第二晶体管区域302内的半导体基底316中形成浅结源极延伸417以及浅结漏极延伸419,浅结源极延伸417以及浅结漏极延伸419之间为沟道区域422。After that, using the gate structure as an implantation mask, a shallow
接着,利用沉积及回蚀刻工艺,在栅极312及412的侧壁上形成由氮化硅所构成的侧壁子332与432,并同时形成介于栅极与侧壁子之间的衬垫层330以及430。衬垫层330以及430通常为L型且厚度约在30至120埃之间,可以为氧化硅所构成。除此的外,在本发明的另一实施例中,衬垫层330以及430亦可以为偏移侧壁子(offset spacer)。Next, using deposition and etch-back processes, sidewalls 332 and 432 made of silicon nitride are formed on the sidewalls of the
如图5所示,在形成侧壁子332及432之后,利用如光刻胶等材料的掩模层68将第二晶体管区域302覆盖住。接着进行离子注入工艺,将N型掺杂剂物种,例如砷、锑或磷等注入第一晶体管区域301内的半导体基底316中,由此形成N型金属氧化物半导体晶体管元件的源极区域318以及漏极区域320。完成前述的离子注入工艺之后,掩模层68随即被剥除。As shown in FIG. 5 , after forming the
如图6所示,接着在第一晶体管区域301上利用掩模层78将其覆盖。接着进行另一离子注入工艺,将P型掺杂剂物种,例如硼等注入第二晶体管区域302内的半导体基底316中,由此形成P型金属氧化物半导体晶体管元件的源极区域418以及漏极区域420。完成前述的离子注入工艺之后,掩模层78随即被移除。已知该项技术的人员应理解前述如图5以及图6中所示的注入顺序可以颠倒。换言之,可以先进行第二晶体管区域302内的P型掺杂,然后再进行第一晶体管区域301内的N型掺杂。此外,在完成漏极源极的掺杂后,半导体基底316通常可以进行退火(annealing)或活化(activation)掺杂剂的热工艺,此步骤亦为本领域技术人员的通常知识,不再加以陈述。As shown in FIG. 6 , the
此外,已知该领域者应理解,本发明另可结合选择性外延成长(selectiveepitaxial growth,简称为SEG)工艺,而在半导体基底中填入硅锗(SiGe)外延层或碳化硅(SiC)外延层作为源极区域与漏极区域。In addition, those who know this field should understand that the present invention can also be combined with a selective epitaxial growth (SEG) process to fill the semiconductor substrate with a silicon germanium (SiGe) epitaxial layer or a silicon carbide (SiC) epitaxial layer. layer as the source and drain regions.
如图7所示,根据本发明优选实施例,接着在半导体基底316上均匀沉积应力覆盖层346,作为多晶硅应力层(poly stressor)。应力覆盖层346覆盖在源极区域318、418、漏极区域320、420与栅极312、412上,其厚度约介于30至2000埃之间。根据本发明,应力覆盖层346在沉积时为伸张应变(tensile-stressed)状态,其初始沉积(as-deposition)的应力大小约介于5亿帕(0.5Giga pascals,0.5GPa)与2.5GPa之间。其后,本发明亦可再对应力覆盖层346进行表面处理,例如紫外线硬化(UV curing)工艺、高温峰值退火(thermal spikeanneal)工艺、激光退火(laser anneal)工艺或电子束(e-beam)处理等等,以提升应力覆盖层346的应力大小。As shown in FIG. 7 , according to a preferred embodiment of the present invention, a
如图8所示,接着,在半导体基底316上均匀沉积掩模层,将应力覆盖层346覆盖住。在本实施例中,掩模层的材料可以为氧化物或是同时包含有氧化物与光刻胶等等与应力覆盖层346具有较佳蚀刻选择比的物质。随后再进行图案化工艺,利用光刻胶98作为蚀刻掩模来去除第二晶体管区域302中的掩模层,形成图案化硬掩模188。图案化硬掩模188覆盖在第一晶体管区域301中的应力覆盖层346上,而暴露出第二晶体管区域302中的应力覆盖层346。此外,在本发明的另一实施例中,亦可直接以具有适当厚度的光刻胶材料作为图案化硬掩模188。若图案化硬掩模188为光刻胶材料,则可省略制作光刻胶98的步骤。As shown in FIG. 8 , then, a mask layer is uniformly deposited on the
接着,如图9所示,随后去除光刻胶98,进行惰性气体处理(inert gastreatment),以改变未被图案化硬掩模188所覆盖的应力覆盖层346的应力值。惰性气体处理可在化学气相沉积(chemical vapor deposition,CVD)设备或是在物理气相沉积(physical vapor deposition,PVD)设备之中进行,惰性气体处理是利用氩气与其他惰性气体,且处理功率(treatment power)介于0.1千瓦(kilo-watts,KW)与10千瓦之间。此外,惰性气体处理亦选用一种或一种以上的氦气、氪气、氮气、氧气或其他惰性气体。Next, as shown in FIG. 9 , the
惰性气体处理可以大幅减少未被图案化硬掩模188覆盖的应力覆盖层346的伸张应力。通过处理功率与处理时间等工艺参数的控制,本发明可以调整应力覆盖层346的应力值。换句话说,在完成惰性气体处理之后,覆盖在半导体基底316上的应力覆盖层346具有双应力的结构,亦即位于N型金属氧化物半导体晶体管元件310上方的应力覆盖层346具有较大的伸张应力,而位于P型金属氧化物半导体晶体管元件410上方的应力覆盖层346的伸张应力较小。随着惰性气体处理的时间愈长,以及处理功率愈大等工艺参数的控制,伸张应力值的下降幅度也就愈大,甚至可以直接消除P型金属氧化物半导体晶体管元件410上方的应力覆盖层346的伸张应力。The inert gas treatment can substantially reduce the tensile stress of the
接着,如图10所示,先去除图案化硬掩模188,再进行快速热处理工艺(rapid thermal processing,RTP),以将应力覆盖层346的应力状态存储入N型金属氧化物半导体晶体管元件310与P型金属氧化物半导体晶体管元件410之中。之后,如图11所示,去除应力覆盖层346,形成具有应变硅的互补式金属氧化物半导体晶体管元件。Next, as shown in FIG. 10 , the patterned hard mask 188 is first removed, and then a rapid thermal processing (rapid thermal processing, RTP) is performed to store the stress state of the
完成前述互补式金属氧化物半导体晶体管元件之后,可再进行硅化金属(salicide)、介电层沉积、接触洞蚀刻等工艺,在此不予赘述。After the aforementioned CMOS transistor device is completed, processes such as salicide, dielectric layer deposition, and contact hole etching can be performed, which will not be repeated here.
请参考图12至图17,其绘示的是本发明的第二优选实施例N型金属氧化物半导体晶体管元件310与P型金属氧化物半导体晶体管元件410的方法剖面示意图,其中相同的元件或部位仍沿用相同的符号来表示。如图12所示,先提供半导体基底316。半导体基底316上定义有第一晶体管区域301与第二晶体管区域302。在第一晶体管区域301内包含有栅极介电层314位于半导体基底上316、栅极312位于栅极介电层314上,以及源极区域318与漏极区域320分别位于栅极312两侧的半导体基底316中。源极区域318与漏极区域320之间为N型沟道区域322。另一方面,在第二晶体管区域302内包含有栅极介电层414位于半导体基底上316、栅极412位于栅极介电层414上,以及源极区域418与漏极区域420分别位于栅极412两侧的半导体基底316中。源极区域418与漏极区域420之间为P型沟道区域422。栅极312的侧壁上具有侧壁子332与衬垫层330,而栅极412的侧壁上具有侧壁子432与衬垫层430。Please refer to FIG. 12 to FIG. 17 , which are schematic cross-sectional diagrams showing the method of the N-type metal oxide
同理,本实施例亦可结合选择性外延成长工艺,而在半导体基底中填入硅锗外延层或碳化硅外延层作为源极区域与漏极区域。Similarly, this embodiment can also be combined with the selective epitaxial growth process, and the silicon germanium epitaxial layer or the silicon carbide epitaxial layer is filled in the semiconductor substrate as the source region and the drain region.
如图13所示,接着进行硅化金属工艺,在源极区域318、418、漏极区域320、420与栅极312、412上形成如硅化镍等硅化金属层342。如图14所示,接着在半导体基底316上均匀沉积应力覆盖层346,且应力覆盖层346覆盖在源极区域318、418、漏极区域320、420与栅极312、412上。应力覆盖层346在沉积时为伸张应变状态,其初始沉积的应力大小约介于0.5GPa与2.5GPa之间。其后,本发明亦可再对应力覆盖层346进行表面处理,例如紫外线硬化工艺、高温峰值退火工艺、激光退火工艺或电子束处理等等,以提升应力覆盖层346的应力大小。As shown in FIG. 13 , a metal silicide process is then performed to form a
如图15所示,接着,在半导体基底316上均匀沉积掩模层,将应力覆盖层346覆盖住。掩模层的材料可以为氧化物、光刻胶,或是包含有氧化物与光刻胶等等,与应力覆盖层346具有较佳蚀刻选择比的物质。随后再进行图案化工艺,利用光刻胶98作为蚀刻掩模来去除第二晶体管区域302中的掩模层,形成图案化硬掩模188。图案化硬掩模188覆盖在第一晶体管区域301中的应力覆盖层346上,而暴露出第二晶体管区域302中的应力覆盖层346。As shown in FIG. 15 , next, a mask layer is uniformly deposited on the
接着,如图16所示,随后去除光刻胶98,进行惰性气体处理,以改变未被图案化硬掩模188所覆盖的应力覆盖层346的应力值。惰性气体处理可在化学气相沉积设备或是在物理气相沉积设备之中进行,其是利用氩气与其他惰性气体,且处理功率介于0.1千瓦与10千瓦之间。惰性气体处理可以大幅减少未被图案化硬掩模188覆盖的应力覆盖层346的伸张应力。换句话说,在完成惰性气体处理之后,位于N型金属氧化物半导体晶体管元件310上方的应力覆盖层346具有较大的伸张应力,而位于P型金属氧化物半导体晶体管元件410上方的应力覆盖层346的伸张应力较小,甚至是无伸张应力状态。Next, as shown in FIG. 16 , the
接着,如图17所示,先去除图案化硬掩模188,接着在半导体基底上沉积介电层348,覆盖住第一晶体管区域301及第二晶体管区域302内的应力覆盖层346。介电层348可以为氧化硅、掺杂氧化硅等等低介电常数材料。接着进行光刻以及蚀刻工艺,在介电层348以及应力覆盖层346中形成接触洞352,分别通达源极区域318、418、漏极区域320、420与栅极312、412上。在其它实施例中,亦可仅形成通达源极区域318、418与漏极区域320、420的接触洞,但在图式中并未明示。根据本发明的精神,应力覆盖层346在接触洞干蚀刻工艺中可当作接触蚀刻停止层。Next, as shown in FIG. 17 , the patterned hard mask 188 is first removed, and then a dielectric layer 348 is deposited on the semiconductor substrate to cover the
请参考图18,其绘示的是本发明的应力覆盖层346的伸张应力值的直条示意图,其中垂直坐标轴显示的是伸张应力值。图中标示了六组应力覆盖层的应力值,每一组应力覆盖层皆经过至少三次的量测,其中数值212、222、232、242、252、262为应力覆盖层沉积后所量测的应力值,数值214、224、234、244、254、264为应力覆盖层经过紫外线硬化工艺后所量测的应力值,而数值216、226、236、246、256、266为应力覆盖层经过惰性气体处理后所量测的应力值。图中六组应力覆盖层彼此的差别在于惰性气体处理的处理功率不同,其处理功率从左至右分别为2千瓦、3千瓦、4千瓦、5千瓦、6千瓦与7千瓦。前述六组惰性气体处理的处理时间皆为10秒钟,然而本发明不限于此。如图18所示,随着处理功率的提高,伸张应力值的下降幅度也随的增加。当处理功率大于5千瓦时,惰性气体处理后的应力覆盖层的应力值甚至低于沉积后的应力覆盖层的应力值。Please refer to FIG. 18 , which is a schematic diagram showing the tensile stress values of the
本发明的特征在于利用惰性气体处理来改变的应力覆盖层的应力值,让应力覆盖层成为具有双应力的结构。有鉴于此,高伸张应力部分的应力覆盖层可以改变N型金属氧化物半导体晶体管元件的沟道区域的晶格结构,使N型金属氧化物半导体晶体管元件可以具有较高的饱和漏极电流,进而改善半导体晶体管元件的操作效能。另一方面,覆盖在P型金属氧化物半导体晶体管元件上的应力覆盖层仅具有低伸张应力,可避免应力覆盖层降低P型金属氧化物半导体晶体管元件的操作效能。有鉴于此,本发明使N型或P型金属氧化物半导体晶体管元件可以同时具有较高的饱和漏极电流,由此改善半导体晶体管元件的操作效能。The present invention is characterized in that the stress value of the stress covering layer is changed by inert gas treatment, so that the stress covering layer becomes a structure with double stress. In view of this, the stress covering layer of the high tensile stress part can change the lattice structure of the channel region of the NMOS transistor element, so that the NMOS transistor element can have a higher saturation drain current, Further, the operating efficiency of the semiconductor transistor device is improved. On the other hand, the stress covering layer covering the PMOS transistor device has only low tensile stress, which can prevent the stress covering layer from degrading the operation performance of the PMOS transistor device. In view of this, the present invention enables the N-type or P-type MOS transistor device to have a higher saturation drain current, thereby improving the operating performance of the semiconductor transistor device.
以上所述仅为本发明的优选实施例,凡依本发明权利要求所做的均等变化与修饰,皆应属本发明专利的涵盖范围。The above descriptions are only preferred embodiments of the present invention, and all equivalent changes and modifications made according to the claims of the present invention shall fall within the scope of the patent of the present invention.
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| CN102969231A (en) * | 2011-09-01 | 2013-03-13 | 中芯国际集成电路制造(上海)有限公司 | Manufacturing method of metal gate |
| CN104517846A (en) * | 2013-09-27 | 2015-04-15 | 中芯国际集成电路制造(上海)有限公司 | Manufacturing method of semiconductor device |
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| CN102969231A (en) * | 2011-09-01 | 2013-03-13 | 中芯国际集成电路制造(上海)有限公司 | Manufacturing method of metal gate |
| CN102969231B (en) * | 2011-09-01 | 2015-11-25 | 中芯国际集成电路制造(上海)有限公司 | A kind of manufacture method of metal gate |
| CN104517846A (en) * | 2013-09-27 | 2015-04-15 | 中芯国际集成电路制造(上海)有限公司 | Manufacturing method of semiconductor device |
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