CN101244903A - A high-temperature anti-explosion and normal-temperature anti-crack mineral admixture and its preparation method - Google Patents
A high-temperature anti-explosion and normal-temperature anti-crack mineral admixture and its preparation method Download PDFInfo
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Abstract
Description
技术领域 technical field
本发明属于建筑材料技术领域,具体涉及一种高温抗爆常温抗裂矿物掺合料及其制备方法。The invention belongs to the technical field of building materials, and in particular relates to a high-temperature anti-explosion and normal-temperature anti-crack mineral admixture and a preparation method thereof.
背景技术 Background technique
在最近100多年的历史中,混凝土作为主要的建筑结构材料广泛地应用于建筑工程领域。虽然混凝土本身具有不燃烧与导热系数低的特点,但随着受火温度的增加,混凝土自身将发生物理与化学的变化,最终导致其原有性能的劣化,从而影响到钢筋混凝土结构的稳定性与耐久性。例如,英法海底隧道发生的火灾造成隧道内表面高强混凝土爆裂,造成了隧道大面积的受损区域。In the history of more than 100 years, concrete has been widely used in the field of construction engineering as the main building structure material. Although concrete itself has the characteristics of non-combustibility and low thermal conductivity, as the fire temperature increases, the concrete itself will undergo physical and chemical changes, which will eventually lead to the deterioration of its original performance, thus affecting the stability of reinforced concrete structures. and durability. For example, a fire in the Channel Tunnel in England and France caused the high-strength concrete on the inner surface of the tunnel to burst, causing extensive damage to the tunnel.
HSC/HPC组成结构和物理化学性质的特点决定了其自身在高温作用下的劣化表现形式,这些劣化主要包括爆裂、承受载荷能力下降等。The compositional structure and physical and chemical properties of HSC/HPC determine its own degradation manifestations under high temperature, and these degradations mainly include bursting, load-bearing capacity decline, etc.
爆裂是指混凝土在高温(火灾)作用下,达到一定温度时,在没有任何预兆的情况下混凝土表面突然发生崩裂的现象,一般发生于300℃-500℃,但也有相关文献表明,爆裂温度在100℃-250℃。混凝土的高温爆裂对混凝土结构的破坏性较强,这种破坏将使钢筋表面的混凝土保护层剥落,钢筋则直接暴露于高温环境中发生破坏,最终导致混凝土结构完整性的丧失。混凝土爆裂的特征表现为无预兆,突然发生;爆裂深度深浅不一;同一组试件并不是所有的试件都爆裂,具有一定的随机性。Bursting refers to the phenomenon that the concrete surface suddenly cracks without any warning when the concrete reaches a certain temperature under the action of high temperature (fire). 100°C-250°C. The high temperature bursting of concrete is very destructive to the concrete structure. This kind of damage will cause the concrete protective layer on the surface of the steel bar to peel off, and the steel bar will be directly exposed to high temperature environment to be damaged, which will eventually lead to the loss of the integrity of the concrete structure. The characteristics of concrete bursting are sudden occurrence without warning; the depth of bursting is different; not all the specimens of the same group burst, which has a certain randomness.
迄今混凝土高温爆裂的机理存在各种观点,其中有两种观点令人瞩目,即蒸汽压机理(the vapor pressure build-up mechanism)与热应力机理(the thermal stress mechanism)。蒸汽压机理指致密的硬化水泥浆在高温下阻止水蒸气的逸出,从而产生了内部蒸汽压,当蒸汽压达到一定数值时,即引发高温爆裂。热应力机理指高温环境在混凝土结构内外产生了温度梯度,伴随温度梯度而产生的热应力最终引发了爆裂。此外,爆裂亦有可能是这两种机理同时发生作用。So far, there are various viewpoints on the mechanism of high-temperature cracking of concrete, among which two viewpoints attract attention, namely, the vapor pressure build-up mechanism and the thermal stress mechanism. The vapor pressure mechanism refers to the fact that the dense hardened cement slurry prevents the escape of water vapor at high temperature, thereby generating internal vapor pressure. When the vapor pressure reaches a certain value, it will cause high-temperature bursting. The mechanism of thermal stress means that the high temperature environment produces a temperature gradient inside and outside the concrete structure, and the thermal stress generated with the temperature gradient eventually leads to bursting. In addition, it is also possible that the bursting is due to the simultaneous action of these two mechanisms.
混凝土在高温作用后承载能力的劣化主要是混凝土自身物理化学性质经受高温作用而发生的负面变化。混凝土升温到100℃左右时,水泥砂浆和骨料中的自由水分逐步蒸发排出;在300℃左右时,混凝土中结晶水开始散失,水化物开始分解;当温度达到500℃之后时,结晶水几乎全部丧失,水泥水化物分解殆尽,骨料亦开始脱水,混凝土表面出现明显裂纹,水泥石已不存在连续的或大块的水化产物凝胶体,代之是尺寸更小的分散相颗粒,骨料表面亦出现大量互相贯通的微裂纹,混凝土整体结构已变酥,骨料与水泥石之间出现较大的贯通裂缝,破坏时主要是沿界面和水泥石破坏]此外,硅质骨料在573℃时,α型SiO2转变为β型体积膨胀0.82%;经历700℃的受火温度之后,结晶水完全丧失,水泥水化物已不存在,混凝土表面裂纹明显而且相互连通;在温度达到800℃左右时,混凝土中钙质骨料开始出现碳酸盐的分解。The deterioration of the bearing capacity of concrete after high temperature is mainly due to the negative changes in the physical and chemical properties of concrete itself when subjected to high temperature. When the temperature of the concrete rises to about 100°C, the free water in the cement mortar and aggregate gradually evaporates and discharges; at about 300°C, the crystallization water in the concrete begins to dissipate, and the hydrate begins to decompose; when the temperature reaches 500°C, the crystallization water is almost All of them are lost, the cement hydrates are completely decomposed, the aggregates also begin to dehydrate, and obvious cracks appear on the concrete surface. There is no continuous or large hydration product gel in the cement stone, and it is replaced by smaller dispersed phase particles. , a large number of interpenetrating micro-cracks also appeared on the surface of the aggregate, the overall structure of the concrete has become crisp, and there are large through-cracks between the aggregate and the cement stone, and the damage is mainly along the interface and the cement stone] In addition, the siliceous bone When the material is at 573°C, the α-type SiO 2 transforms into β-type with a volume expansion of 0.82%; after experiencing the fire temperature of 700°C, the crystal water is completely lost, the cement hydrate no longer exists, and the cracks on the concrete surface are obvious and interconnected; When the temperature reaches about 800°C, the calcareous aggregate in the concrete begins to decompose the carbonate.
发明内容 Contents of the invention
本发明的目的在于提供一种高温抗爆常温抗裂矿物掺合料及其制备方法,该矿物掺合料在常温具有较好体积稳定性、耐久性,高温时具有抗爆裂能力。The object of the present invention is to provide a high temperature anti-explosion and normal temperature anti-cracking mineral admixture and its preparation method. The mineral admixture has good volume stability and durability at normal temperature and has anti-explosion ability at high temperature.
为了实现上述目的,本发明的技术方案是:一种高温抗爆常温抗裂矿物掺合料,其特征是它由体积稳定组分、抗爆增韧组分和高温成孔矿物外加剂混合而成,各组分所占质量份数为:高温成孔矿物外加剂∶体积稳定组分为1∶0.001~0.01,高温成孔矿物外加剂∶抗爆增韧组分为1∶0.5~1.5;In order to achieve the above object, the technical solution of the present invention is: a high-temperature anti-explosion and normal temperature anti-cracking mineral admixture, which is characterized in that it is composed of a volume stabilization component, an anti-explosion toughening component and a high-temperature pore-forming mineral admixture. The mass fraction of each component is: high-temperature pore-forming mineral admixture: volume-stabilizing component is 1:0.001-0.01, high-temperature pore-forming mineral admixture: anti-knock toughening component is 1:0.5-1.5;
所述的体积稳定组分由长度为3~8mm的有机纤维和长度为10~19mm的有机纤维组成,有机纤维直径为15~30μm,长度为3~8mm的有机纤维占体积稳定组分体积的30~70%;The volume stabilizing component is composed of organic fibers with a length of 3 to 8 mm and organic fibers with a length of 10 to 19 mm. The diameter of the organic fibers is 15 to 30 μm, and the organic fibers with a length of 3 to 8 mm account for 10% of the volume of the volume stabilizing component. 30-70%;
所述的抗爆增韧组分为金属纤维,金属纤维长度为15~30mm,长径比为15~50;The anti-explosion toughening component is a metal fiber, the length of the metal fiber is 15-30 mm, and the aspect ratio is 15-50;
所述的高温成孔矿物外加剂为具有达到1200℃以上的热历史、玻璃体含量达到50%以上、比表面积达到4000~4500cm2/g、性能应符合GB/T 18736-2002标准规定的物质。The high-temperature pore-forming mineral admixture is a material with a thermal history above 1200°C, a vitreous body content of more than 50%, a specific surface area of 4000-4500 cm 2 /g, and properties that meet the requirements of the GB/T 18736-2002 standard.
所述的有机纤维熔点为150~190℃,燃点为500~600℃。The melting point of the organic fiber is 150-190°C, and the ignition point is 500-600°C.
所述的有机纤维为聚丙烯(PP)纤维、聚酰胺(PA)纤维、聚乙烯醇缩甲醛(PVA)纤维、高强高模量聚乙烯(PE)纤维中的任意一种或任意二种以上的混合,任意二种以上混合时为任意配比。The organic fiber is any one or two or more of polypropylene (PP) fibers, polyamide (PA) fibers, polyvinyl formal (PVA) fibers, and high-strength and high-modulus polyethylene (PE) fibers The mixing of any two or more kinds is arbitrary proportioning.
所述的高温成孔矿物外加剂为炉渣、钢渣、矿粉、粉煤灰中的任意一种或任意二种以上的混合,任意二种以上混合时为任意配比。The high-temperature pore-forming mineral additive is any one or a mixture of any two or more of slag, steel slag, mineral powder, and fly ash, and any two or more of them are mixed in any ratio.
上述一种高温抗爆常温抗裂矿物掺合料的制备方法,其特征是它包括如下步骤:The preparation method of the above-mentioned high temperature anti-explosion normal temperature anti-cracking mineral admixture is characterized in that it comprises the following steps:
1)体积稳定组分的制备:选取长度为3~8mm的有机纤维和长度为10~19mm的有机纤维,混合,得体积稳定组分;其中,有机纤维直径为15~30μm,长度为3~8mm的有机纤维占体积稳定组分体积的30~70%;1) Preparation of volume stable components: select organic fibers with a length of 3 to 8 mm and organic fibers with a length of 10 to 19 mm, and mix them to obtain a volume stable component; wherein, the diameter of the organic fibers is 15 to 30 μm, and the length is 3 to 19 mm. 8mm organic fibers account for 30-70% of the volume of the volume stabilization component;
2)按各组分所占质量份数为:高温成孔矿物外加剂∶体积稳定组分为1∶0.001~0.01,高温成孔矿物外加剂∶抗爆增韧组分为1∶0.5~1.5,选取体积稳定组分、抗爆增韧组分和高温成孔矿物外加剂;2) According to the mass fraction of each component: high-temperature pore-forming mineral admixture: volume-stabilizing component is 1:0.001-0.01, high-temperature pore-forming mineral admixture: anti-knock toughening component is 1:0.5-1.5 , selecting volume stabilizing components, anti-explosion toughening components and high temperature pore-forming mineral admixtures;
所述的抗爆增韧组分为金属纤维,金属纤维长度为15~30mm,长径比为15~50;The anti-explosion toughening component is a metal fiber, the length of the metal fiber is 15-30 mm, and the aspect ratio is 15-50;
所述的高温成孔矿物外加剂为具有达到1200℃以上的热历史、玻璃体含量达到50%以上、比表面积达到4000~4500cm2/g、性能应符合GB/T 18736-2002标准规定的物质;The high-temperature pore-forming mineral admixture is a substance that has a thermal history above 1200°C, a vitreous body content of more than 50%, a specific surface area of 4000-4500 cm 2 /g, and its performance should meet the requirements of the GB/T 18736-2002 standard;
先将体积稳定组分与高温成孔矿物外加剂搅拌均匀后再加入抗爆增韧组分搅拌均匀,得高温抗爆常温抗裂矿物掺合料产品。Stir the volume stabilizing component and the high-temperature pore-forming mineral admixture evenly, and then add the anti-explosion and toughening component and stir evenly to obtain a high-temperature, anti-explosion, normal-temperature, and anti-cracking mineral admixture product.
本发明的高温抗爆常温抗裂矿物掺合料采用内掺法等量代替水泥重量的20~30%。The high-temperature anti-explosion and normal-temperature anti-crack mineral admixture of the present invention adopts an internal mixing method to replace 20-30% of the weight of cement in equal amounts.
本发明的有益效果是:在常温下,所提供的高温抗爆常温抗裂矿物掺合料不仅可以缓解混凝土因为温度应力、收缩应力和结构应力等造成的开裂问题;而且同时具有良好的韧性和抵抗外部环境有害离子(如,Cl-、SO4 2-、Mg2+、H2O等)侵蚀特点;在常温具有较好体积稳定性、物理力学性与耐久性。在高温时,该高温抗爆常温抗裂矿物掺合料将增强混凝土抵抗瞬时高温的作用,使混凝土保持较好的完整性和稳定性,避免了混凝土爆裂所导致的人身伤害与建筑物结构损伤,即高温时具有抗爆裂能力。其产生效果的机理为:The beneficial effects of the present invention are: at normal temperature, the provided high-temperature anti-explosion and normal-temperature anti-crack mineral admixture can not only relieve the cracking problem of concrete caused by temperature stress, shrinkage stress and structural stress, but also have good toughness and It is resistant to the erosion of harmful ions in the external environment (such as Cl - , SO 4 2- , Mg 2+ , H 2 O, etc.); it has good volume stability, physical mechanics and durability at room temperature. At high temperature, the high temperature anti-explosion and normal temperature anti-cracking mineral admixture will enhance the concrete's resistance to instantaneous high temperature, so that the concrete maintains better integrity and stability, and avoids personal injury and building structure damage caused by concrete bursting , that is, it has anti-burst ability at high temperature. The mechanism of its effect is:
1.纤维增强机理:1. Fiber reinforcement mechanism:
混凝土作为一种包含固液气三相的非均质材料,其内部存在缺陷,欲提高混凝土的性能,必须尽可能地减少缺陷的程度,提高韧性,降低内部裂缝端部的应力集中系数。As a heterogeneous material containing three phases of solid, liquid and gas, concrete has internal defects. To improve the performance of concrete, it is necessary to reduce the degree of defects as much as possible, improve toughness, and reduce the stress concentration factor at the end of internal cracks.
纤维的乱向分布大大削弱了混凝土的收缩应力。收缩能量被分散到纤维上,纤维吸收了部分能量,极大地提高其柔韧性,抑制了微细裂缝的产生和发展,达到纤维抗裂,增强混凝土体积稳定性的目的。同时纤维的引入,可以缓解混凝土内部应力的作用,阻止微裂缝的扩展,避免了大尺度裂纹的产生,从而提高了混凝土的耐久性。此外,高弹性模量与高抗拉强度纤维的适量掺入,也有利于提高混凝土基体的韧性及其他的物理力学性能。The random distribution of fibers greatly weakens the shrinkage stress of concrete. The shrinkage energy is dispersed to the fiber, and the fiber absorbs part of the energy, greatly improving its flexibility, inhibiting the generation and development of micro cracks, achieving the purpose of fiber crack resistance and enhancing the volume stability of concrete. At the same time, the introduction of fibers can relieve the internal stress of concrete, prevent the expansion of micro-cracks, and avoid the generation of large-scale cracks, thereby improving the durability of concrete. In addition, the appropriate addition of high elastic modulus and high tensile strength fibers is also conducive to improving the toughness and other physical and mechanical properties of the concrete matrix.
2.高温抗爆机理2. High temperature anti-knock mechanism
(1)低熔点纤维的作用机理(1) Mechanism of action of low melting point fiber
根据混凝土爆裂的蒸汽压机理,利用低熔点纤维(熔点低于200~400℃的有机纤维)在高温作用下软化,熔融与燃烧的特性,在混凝土内部形成连通至混凝土表面的通道,从而有利于混凝土内部所产生的气体得以顺利排除,避免气体体积膨胀产生的张应力达到试件的极限抗拉强度而产生爆裂。According to the steam pressure mechanism of concrete bursting, the low-melting fiber (organic fiber with a melting point lower than 200-400°C) is used to soften, melt and burn at high temperature to form a channel connected to the concrete surface inside the concrete, so that there is It is conducive to the smooth removal of the gas generated inside the concrete, and prevents the tensile stress generated by the gas volume expansion from reaching the ultimate tensile strength of the specimen and causing bursting.
利用低长径比纤维(长度为3~8mm的有机纤维)的高分散性,使聚丙烯纤维均匀分布于试件中,从而有效避免高温作用时试件局部区域蒸汽压过高所导致的爆裂。其次,高长径比纤维(长度为10~19mm的有机纤维)在纤维直径与掺量一定的条件下,可在水泥石内部形成长距离连通通道,这将有利于在较大区域内排除高温所产生的气体,减小或避免混凝土径向严重爆裂,导致混凝土内部钢筋暴露于高温环境。Utilizing the high dispersion of low aspect ratio fibers (organic fibers with a length of 3-8 mm), the polypropylene fibers are evenly distributed in the specimen, thereby effectively avoiding bursting caused by excessive vapor pressure in the local area of the specimen under high temperature . Secondly, high aspect ratio fibers (organic fibers with a length of 10-19mm) can form long-distance communication channels inside the cement stone under the condition of certain fiber diameter and content, which will help to eliminate high temperature in a large area. The generated gas reduces or avoids severe radial bursting of the concrete, which causes the steel bars inside the concrete to be exposed to high temperature environments.
(2)高熔点纤维的作用机理(2) Mechanism of high melting point fiber
利用金属纤维的高熔点特性及其高弹性模量与抗拉强度的特性,有效抵抗混凝土高温作用时产生的瞬时拉应力与剪应力,避免在极短时间所产生的破坏应力达到或超过混凝土自身的极限强度导致爆裂。其次,在混凝土爆裂时,金属纤维可对混凝土的爆裂区域产生约束作用,减小爆裂面积,保持混凝土的完整性。Utilizing the high melting point characteristics of metal fibers and their high elastic modulus and tensile strength characteristics, it can effectively resist the instantaneous tensile stress and shear stress generated by concrete under high temperature, and avoid the failure stress generated in a very short time to reach or exceed the concrete itself. The ultimate strength results in bursting. Secondly, when the concrete bursts, the metal fiber can restrain the bursting area of the concrete, reduce the bursting area, and maintain the integrity of the concrete.
3.高温成孔矿物外加剂作用机理3. Mechanism of high temperature pore-forming mineral admixture
在常温下,高温成孔矿物外加剂能与水泥水化产生Ca(OH)2发生反应形成C-S-H凝胶,从而使水泥石和界面区的孔结构细化,孔隙率降低,混凝土的耐蚀性提高。此外,掺入高温成孔矿物外加剂的混凝土,水化热大幅度下降,这对混凝土的耐久性有利。在高温作用下,由于高温成孔矿物外加剂有效减少了水泥水化产生的Ca(OH)2,将减弱混凝土受热时所产生的蒸汽压。而且,高温成孔矿物外加剂在高温下发生物理化学变化,导致原有硬化水泥石结构体系产生三维连续通道,从而有利于硬化水泥石中水分由内至外及时迁移,避免了局部蒸汽压过高而达到或超过水泥基复合材料的极限抗拉或抗剪强度而爆裂破坏。At room temperature, the high-temperature pore-forming mineral admixture can react with the Ca(OH) 2 produced by cement hydration to form CSH gel, so that the pore structure of the cement stone and the interface area is refined, the porosity is reduced, and the corrosion resistance of concrete is improved. . In addition, the heat of hydration of concrete mixed with high-temperature pore-forming mineral admixtures is greatly reduced, which is beneficial to the durability of concrete. Under the effect of high temperature, because the high temperature pore-forming mineral admixture effectively reduces the Ca(OH) 2 produced by cement hydration, it will weaken the vapor pressure generated when the concrete is heated. Moreover, the high-temperature pore-forming mineral admixture undergoes physical and chemical changes at high temperatures, resulting in the formation of three-dimensional continuous channels in the original hardened cement stone structure system, which facilitates the timely migration of water in the hardened cement stone from the inside to the outside, and avoids local vapor pressure. High enough to reach or exceed the ultimate tensile or shear strength of cement-based composites and burst failure.
附图说明 Description of drawings
图1是本发明的工艺流程图。Fig. 1 is a process flow diagram of the present invention.
图2是本发明试件在600℃时的外观照片。Fig. 2 is a photograph of the appearance of the test piece of the present invention at 600°C.
图3是本发明试件在800℃时的外观照片。Fig. 3 is a photograph of the appearance of the test piece of the present invention at 800°C.
图4是未掺入本发明掺合料试件在800℃时的外观照片。Fig. 4 is a photograph of the appearance of a test piece not mixed with the admixture of the present invention at 800°C.
图5(a)是实施例1的试样编号1混凝土试件爆裂照片。Fig. 5(a) is a photograph of the bursting of the sample number 1 concrete specimen of embodiment 1.
图5(b)是实施例1的试样编号2混凝土试件爆裂照片。Fig. 5(b) is a photograph of the bursting of the sample number 2 concrete specimen of Example 1.
具体实施方式 Detailed ways
为了更好地理解本发明,下面结合实施例进一步阐明本发明的内容,但本发明的内容不仅仅局限于下面的实施例。In order to better understand the present invention, the content of the present invention is further illustrated below in conjunction with the examples, but the content of the present invention is not limited to the following examples.
实施例1:Example 1:
一种高温抗爆常温抗裂矿物掺合料的制备方法,它包括如下步骤:A preparation method of a high temperature anti-explosion normal temperature anti-cracking mineral admixture, which comprises the following steps:
1)体积稳定组分的制备:选取长度为3mm的有机纤维和长度为12mm的有机纤维,混合,得体积稳定组分;其中,长度为3mm的有机纤维占体积稳定组分体积的30%;有机纤维为聚丙烯纤维,直径为20μm,熔点为150~190℃;1) Preparation of volume-stabilizing components: select organic fibers with a length of 3 mm and organic fibers with a length of 12 mm, and mix them to obtain a volume-stabilizing component; wherein, the organic fibers with a length of 3 mm account for 30% of the volume of the volume-stabilizing component; The organic fiber is polypropylene fiber with a diameter of 20 μm and a melting point of 150-190°C;
2)按各组分所占质量份数为:高温成孔矿物外加剂∶体积稳定组分为1∶0.003,高温成孔矿物外加剂∶抗爆增韧组分为1∶0.5,选取体积稳定组分、抗爆增韧组分和高温成孔矿物外加剂;2) According to the mass fraction of each component: high-temperature pore-forming mineral admixture: volume-stabilizing component is 1:0.003, high-temperature pore-forming mineral admixture: anti-knock toughening component is 1:0.5, and volume-stable components, anti-knock toughening components and high-temperature pore-forming mineral admixtures;
所述的抗爆增韧组分为金属纤维,金属纤维长度为20mm,长径比为30;The anti-explosion toughening component is a metal fiber, the length of the metal fiber is 20mm, and the aspect ratio is 30;
所述的高温成孔矿物外加剂为具有达到1200℃以上的热历史、玻璃体含量达到50%以上、比表面积达到4000~4500cm2/g、性能应符合GB/T 18736-2002标准规定的物质;所述的高温成孔矿物外加剂为炉渣,高温成孔矿物外加剂烘干、粉磨,备用;The high-temperature pore-forming mineral admixture is a substance that has a thermal history above 1200°C, a vitreous body content of more than 50%, a specific surface area of 4000-4500 cm 2 /g, and its performance should meet the requirements of the GB/T 18736-2002 standard; The high-temperature pore-forming mineral admixture is slag, and the high-temperature pore-forming mineral admixture is dried and ground for use;
如图1所示,先将体积稳定组分与高温成孔矿物外加剂搅拌均匀后再加入抗爆增韧组分搅拌均匀,得高温抗爆常温抗裂矿物掺合料产品。As shown in Figure 1, the volume stabilizing component and the high-temperature pore-forming mineral admixture are firstly stirred evenly, and then the anti-knock toughening component is added and stirred evenly to obtain a high-temperature anti-knock, normal temperature and anti-crack mineral admixture product.
按照表1配比制备C50混凝土试件,将混凝土试件置于目标温度场达到800℃的高温炉中,进行瞬时高温加热,当加热至混凝土爆裂声停止后15min,取出试件。Prepare C50 concrete specimens according to the ratio in Table 1. Place the concrete specimens in a high-temperature furnace whose target temperature field reaches 800°C, and conduct instantaneous high-temperature heating. After heating until 15 minutes after the cracking sound of the concrete stops, take out the specimens.
本发明试件在600℃时的外观照片如图2所示,本发明试件在800℃时的外观照片如图3所示。未掺入本发明掺合料试件在800℃时的外观照片如图4所示。图2与图3说明本发明掺合料抑制了混凝土在经历高温(≥600℃)作用时的爆裂,有效保证了混凝土试件的完整性。图4则表明未参加本发明掺合料的混凝土在高温作用下发生了粉碎性爆裂。上述结果表明:高温抗爆常温抗裂矿物掺合料有助于改善混凝土在高温作用下的性能。The photo of the appearance of the test piece of the present invention at 600°C is shown in Figure 2, and the photo of the appearance of the test piece of the present invention at 800°C is shown in Figure 3. The photo of the appearance of the test piece without the admixture of the present invention at 800°C is shown in Figure 4. Figure 2 and Figure 3 illustrate that the admixture of the present invention inhibits the concrete from bursting when subjected to high temperature (≥600°C), effectively ensuring the integrity of the concrete specimen. Fig. 4 then shows that the concrete that does not join the admixture of the present invention has taken place comminution bursting under high temperature. The above results show that the high temperature anti-explosion and normal temperature anti-crack mineral admixture is helpful to improve the performance of concrete under high temperature.
表1 C50混凝土配合比(Kg/m3)Table 1 C50 concrete mix ratio (Kg/m 3 )
为了能够较全面地说明混凝土试件的爆裂程度,以混凝土高温前后质量损失率,爆裂试件数、爆裂形式,平均最大爆裂面积与最大爆裂深度进行表征。其中,混凝土试件的爆裂形式分为三类:表面局部剥落;边角和棱部出现剥落;断裂。平均最大爆裂面积定义为一组混凝土试件中各试件最大爆裂面积的平均值,爆裂面积采用DT2000图像分析软件(V2.0)对爆裂试件数码照片进行分析计算。In order to describe the bursting degree of concrete specimens more comprehensively, the mass loss rate of concrete before and after high temperature, the number of bursting specimens, the bursting form, the average maximum bursting area and the maximum bursting depth were used to characterize. Among them, the bursting forms of concrete specimens are divided into three categories: partial peeling of the surface; peeling of corners and edges; fracture. The average maximum burst area is defined as the average value of the maximum burst area of each specimen in a group of concrete specimens, and the burst area is analyzed and calculated by using DT2000 image analysis software (V2.0) to analyze and calculate the digital photos of burst specimens.
表2混凝土试件经受高温作用的爆裂程度Table 2 The degree of bursting of concrete specimens subjected to high temperature
从表2可知,掺入高温抗爆常温抗裂矿物掺合料的混凝土(试样编号2)在质量损失率,爆裂试件数、爆裂形式,平均最大爆裂面积与最大爆裂深度的测试结果上均优于未掺入本发明掺合料的混凝土(试样编号1),表现出较好的抵抗高温作用能力。图5(b)中的试样编号2的爆裂照片与图5(a)中的试样编号1相比较,具有完整的外观,爆裂损伤区域小,说明在制备混凝土时,高温抗爆常温抗裂矿物掺合料掺入到混凝土中有利于改善混凝土的抗爆裂高温性能。It can be seen from Table 2 that the concrete (sample number 2) mixed with high-temperature anti-explosion and normal temperature anti-cracking mineral admixtures has the same test results in terms of mass loss rate, bursting specimen number, bursting form, average maximum bursting area and maximum bursting depth. It is better than the concrete (sample number 1) that is not mixed with the admixture of the present invention, and shows better ability to resist high temperature. Compared with the sample No. 1 in Fig. 5(a), the burst photo of sample No. 2 in Fig. 5(b) has a complete appearance, and the burst damage area is small, which shows that when preparing concrete, high temperature anti-explosion and normal temperature anti-explosion The addition of cracking mineral admixtures to concrete is beneficial to improve the anti-cracking high temperature performance of concrete.
实施例2:Example 2:
一种高温抗爆常温抗裂矿物掺合料的制备方法,它包括如下步骤:A preparation method of a high temperature anti-explosion normal temperature anti-cracking mineral admixture, which comprises the following steps:
1)体积稳定组分的制备:选取长度为5mm的有机纤维和长度为19mm的有机纤维,混合,得体积稳定组分;其中,长度为5mm的有机纤维占体积稳定组分体积的30%;有机纤维直径为20μm,所述的有机纤维为聚酰胺(PA)纤维;1) Preparation of volume-stabilizing components: select organic fibers with a length of 5 mm and organic fibers with a length of 19 mm, and mix them to obtain a volume-stabilizing component; wherein, the organic fibers with a length of 5 mm account for 30% of the volume of the volume-stabilizing component; The diameter of the organic fiber is 20 μm, and the organic fiber is a polyamide (PA) fiber;
2)按各组分所占质量份数为:高温成孔矿物外加剂∶体积稳定组分为1∶0.001,高温成孔矿物外加剂∶抗爆增韧组分为1∶0.8,选取体积稳定组分、抗爆增韧组分和高温成孔矿物外加剂;2) According to the mass fraction of each component: high-temperature pore-forming mineral admixture: volume-stabilizing component is 1:0.001, high-temperature pore-forming mineral admixture: anti-knock toughening component is 1:0.8, and volume-stable components, anti-knock toughening components and high-temperature pore-forming mineral admixtures;
所述的抗爆增韧组分为金属纤维,金属纤维长度为15mm,长径比为15;The anti-explosion toughening component is a metal fiber, the length of the metal fiber is 15mm, and the aspect ratio is 15;
所述的高温成孔矿物外加剂为具有达到1200℃以上的热历史、玻璃体含量达到50%以上、比表面积达到4000~4500cm2/g、性能应符合GB/T 18736-2002标准规定的物质;所述的高温成孔矿物外加剂为矿粉;高温成孔矿物外加剂烘干、粉磨,备用;The high-temperature pore-forming mineral admixture is a substance that has a thermal history above 1200°C, a vitreous body content of more than 50%, a specific surface area of 4000-4500 cm 2 /g, and its performance should meet the requirements of the GB/T 18736-2002 standard; The high-temperature pore-forming mineral admixture is mineral powder; the high-temperature pore-forming mineral admixture is dried, ground, and set aside;
先将体积稳定组分与高温成孔矿物外加剂搅拌均匀后再加入抗爆增韧组分搅拌均匀,得高温抗爆常温抗裂矿物掺合料产品。Stir the volume stabilizing component and the high-temperature pore-forming mineral admixture evenly, and then add the anti-explosion and toughening component and stir evenly to obtain a high-temperature, anti-explosion, normal-temperature, and anti-cracking mineral admixture product.
实施例3:Example 3:
一种高温抗爆常温抗裂矿物掺合料的制备方法,它包括如下步骤:A preparation method of a high temperature anti-explosion normal temperature anti-cracking mineral admixture, which comprises the following steps:
1)体积稳定组分的制备:选取长度为3mm的有机纤维和长度为19mm的有机纤维,混合,得体积稳定组分;其中,长度为3mm的有机纤维占体积稳定组分体积的40%;有机纤维直径为20μm,所述的3mm有机纤维为聚丙烯纤维,19mm的有机纤维为聚酰胺纤维;1) Preparation of volume-stabilizing components: select organic fibers with a length of 3 mm and organic fibers with a length of 19 mm, and mix them to obtain a volume-stabilizing component; wherein, the organic fibers with a length of 3 mm account for 40% of the volume of the volume-stabilizing component; The diameter of the organic fiber is 20 μm, the 3mm organic fiber is a polypropylene fiber, and the 19mm organic fiber is a polyamide fiber;
2)按各组分所占质量份数为:高温成孔矿物外加剂∶体积稳定组分为1∶0.002,高温成孔矿物外加剂∶抗爆增韧组分为1∶1,选取体积稳定组分、抗爆增韧组分和高温成孔矿物外加剂;2) According to the mass fraction of each component: high-temperature pore-forming mineral admixture: volume-stable component is 1:0.002, high-temperature pore-forming mineral admixture: anti-knock toughening component is 1:1, and volume-stable components, anti-knock toughening components and high-temperature pore-forming mineral admixtures;
所述的抗爆增韧组分为金属纤维,金属纤维长度为30mm,长径比为50;The anti-explosion toughening component is a metal fiber, the length of the metal fiber is 30 mm, and the aspect ratio is 50;
所述的高温成孔矿物外加剂为具有达到1200℃以上的热历史、玻璃体含量达到50%以上、比表面积达到4000~4500cm2/g、性能应符合GB/T 18736-2002标准规定的物质;所述的高温成孔矿物外加剂为粉煤灰;高温成孔矿物外加剂烘干、粉磨,备用;The high-temperature pore-forming mineral admixture is a substance that has a thermal history above 1200°C, a vitreous body content of more than 50%, a specific surface area of 4000-4500 cm 2 /g, and its performance should meet the requirements of the GB/T 18736-2002 standard; The high-temperature pore-forming mineral admixture is fly ash; the high-temperature pore-forming mineral admixture is dried, ground, and set aside;
先将体积稳定组分与高温成孔矿物外加剂搅拌均匀后再加入抗爆增韧组分搅拌均匀,得高温抗爆常温抗裂矿物掺合料产品。Stir the volume stabilizing component and the high-temperature pore-forming mineral admixture evenly, and then add the anti-explosion and toughening component and stir evenly to obtain a high-temperature, anti-explosion, normal-temperature, and anti-cracking mineral admixture product.
实施例4:Example 4:
一种高温抗爆常温抗裂矿物掺合料的制备方法,它包括如下步骤:A preparation method of a high temperature anti-explosion normal temperature anti-cracking mineral admixture, which comprises the following steps:
1)体积稳定组分的制备:选取长度为8mm的有机纤维和长度为10mm的有机纤维,混合,得体积稳定组分;其中,有机纤维直径为30μm,长度为8mm的有机纤维占体积稳定组分体积的30%;所述的有机纤维为聚乙烯醇缩甲醛(PVA)纤维;1) Preparation of volume-stabilizing components: select organic fibers with a length of 8 mm and organic fibers with a length of 10 mm, and mix them to obtain volume-stabilizing components; wherein, the diameter of the organic fibers is 30 μm, and the organic fibers with a length of 8 mm account for the volume-stabilizing group 30% of sub-volume; Described organic fiber is polyvinyl formal (PVA) fiber;
2)按各组分所占质量份数为:高温成孔矿物外加剂∶体积稳定组分为1∶0.01,高温成孔矿物外加剂∶抗爆增韧组分为1∶1.5,选取体积稳定组分、抗爆增韧组分和高温成孔矿物外加剂;2) According to the mass fraction of each component: high-temperature pore-forming mineral admixture: volume-stabilizing component is 1:0.01, high-temperature pore-forming mineral admixture: anti-explosion toughening component is 1:1.5, and volume-stable components, anti-knock toughening components and high-temperature pore-forming mineral admixtures;
所述的抗爆增韧组分为金属纤维,金属纤维长度为30mm,长径比为50;The anti-explosion toughening component is a metal fiber, the length of the metal fiber is 30 mm, and the aspect ratio is 50;
所述的高温成孔矿物外加剂为具有达到1200℃以上的热历史、玻璃体含量达到50%以上、比表面积达到4000~4500cm2/g、性能应符合GB/T 18736-2002标准规定的物质;所述的高温成孔矿物外加剂为钢渣,高温成孔矿物外加剂烘干、粉磨,备用;The high-temperature pore-forming mineral admixture is a substance that has a thermal history above 1200°C, a vitreous body content of more than 50%, a specific surface area of 4000-4500 cm 2 /g, and its performance should meet the requirements of the GB/T 18736-2002 standard; The high-temperature pore-forming mineral admixture is steel slag, and the high-temperature pore-forming mineral admixture is dried and ground for use;
先将体积稳定组分与高温成孔矿物外加剂搅拌均匀后再加入抗爆增韧组分搅拌均匀,得高温抗爆常温抗裂矿物掺合料产品。Stir the volume stabilizing component and the high-temperature pore-forming mineral admixture evenly, and then add the anti-explosion and toughening component and stir evenly to obtain a high-temperature, anti-explosion, normal-temperature, and anti-cracking mineral admixture product.
实施例5:Example 5:
一种高温抗爆常温抗裂矿物掺合料的制备方法,它包括如下步骤:A preparation method of a high temperature anti-explosion normal temperature anti-cracking mineral admixture, which comprises the following steps:
1)体积稳定组分的制备:选取长度为3mm的有机纤维和长度为10mm的有机纤维,混合,得体积稳定组分;其中,有机纤维直径为15μm,长度为3mm的有机纤维占体积稳定组分体积的30%;长度为3mm的有机纤维为聚乙烯醇缩甲醛(PVA)纤维和高强高模量聚乙烯(PE)纤维,二者各占长度为3mm的有机纤维体积的1/2;长度为10mm的有机纤维为聚丙烯(PP)纤维、聚酰胺(PA)纤维,二者各占长度为10mm的有机纤维体积的1/2;1) Preparation of volume-stabilizing components: select organic fibers with a length of 3 mm and organic fibers with a length of 10 mm, and mix them to obtain volume-stabilizing components; wherein, the diameter of the organic fibers is 15 μm, and the organic fibers with a length of 3 mm account for the volume-stabilizing group 30% of the sub-volume; the organic fibers with a length of 3mm are polyvinyl formal (PVA) fibers and high-strength and high-modulus polyethylene (PE) fibers, each accounting for 1/2 of the volume of the organic fibers with a length of 3mm; The organic fibers with a length of 10 mm are polypropylene (PP) fibers and polyamide (PA) fibers, each accounting for 1/2 of the volume of the organic fibers with a length of 10 mm;
2)按各组分所占质量份数为:高温成孔矿物外加剂∶体积稳定组分为1∶0.001,高温成孔矿物外加剂∶抗爆增韧组分为1∶0.5,选取体积稳定组分、抗爆增韧组分和高温成孔矿物外加剂;2) According to the mass fraction of each component: high-temperature pore-forming mineral admixture: volume-stabilizing component is 1:0.001, high-temperature pore-forming mineral admixture: anti-knock toughening component is 1:0.5, and volume-stable components, anti-knock toughening components and high-temperature pore-forming mineral admixtures;
所述的抗爆增韧组分为金属纤维,金属纤维长度为15mm,长径比为15;The anti-explosion toughening component is a metal fiber, the length of the metal fiber is 15mm, and the aspect ratio is 15;
所述的高温成孔矿物外加剂为具有达到1200℃以上的热历史、玻璃体含量达到50%以上、比表面积达到4000~4500cm2/g、性能应符合GB/T 18736-2002标准规定的物质;所述的高温成孔矿物外加剂为矿粉和粉煤灰,二者各占高温成孔矿物外加剂质量的1/2;The high-temperature pore-forming mineral admixture is a substance that has a thermal history above 1200°C, a vitreous body content of more than 50%, a specific surface area of 4000-4500 cm 2 /g, and its performance should meet the requirements of the GB/T 18736-2002 standard; The high-temperature pore-forming mineral admixture is mineral powder and fly ash, both of which account for 1/2 of the mass of the high-temperature pore-forming mineral admixture;
先将体积稳定组分与高温成孔矿物外加剂搅拌均匀后再加入抗爆增韧组分搅拌均匀,得高温抗爆常温抗裂矿物掺合料产品。Stir the volume stabilizing component and the high-temperature pore-forming mineral admixture evenly, and then add the anti-explosion and toughening component and stir evenly to obtain a high-temperature, anti-explosion, normal-temperature, and anti-cracking mineral admixture product.
实施例6:Embodiment 6:
一种高温抗爆常温抗裂矿物掺合料的制备方法,它包括如下步骤:A preparation method of a high temperature anti-explosion normal temperature anti-cracking mineral admixture, which comprises the following steps:
1)体积稳定组分的制备:选取长度为8mm的有机纤维和长度为19mm的有机纤维,混合,得体积稳定组分;其中,有机纤维为聚丙烯(PP)纤维,直径为15μm,长度为8mm的有机纤维占体积稳定组分体积的70%;1) Preparation of volume-stabilizing components: select organic fibers with a length of 8 mm and organic fibers with a length of 19 mm, and mix them to obtain volume-stabilizing components; wherein, the organic fibers are polypropylene (PP) fibers with a diameter of 15 μm and a length of 8mm organic fibers account for 70% of the volume of the volume stabilization component;
2)按各组分所占质量份数为:高温成孔矿物外加剂∶体积稳定组分为1∶0.01,高温成孔矿物外加剂∶抗爆增韧组分为1∶1.5,选取体积稳定组分、抗爆增韧组分和高温成孔矿物外加剂;2) According to the mass fraction of each component: high-temperature pore-forming mineral admixture: volume-stabilizing component is 1:0.01, high-temperature pore-forming mineral admixture: anti-explosion toughening component is 1:1.5, and volume-stable components, anti-knock toughening components and high-temperature pore-forming mineral admixtures;
所述的抗爆增韧组分为金属纤维,金属纤维长度为30mm,长径比为15;The anti-explosion toughening component is a metal fiber, the length of the metal fiber is 30mm, and the aspect ratio is 15;
所述的高温成孔矿物外加剂为具有达到1200℃以上的热历史、玻璃体含量达到50%以上、比表面积达到4000~4500cm2/g、性能应符合GB/T 18736-2002标准规定的物质;所述的高温成孔矿物外加剂为钢渣,高温成孔矿物外加剂烘干、粉磨,备用;The high-temperature pore-forming mineral admixture is a substance that has a thermal history above 1200°C, a vitreous body content of more than 50%, a specific surface area of 4000-4500 cm 2 /g, and its performance should meet the requirements of the GB/T 18736-2002 standard; The high-temperature pore-forming mineral admixture is steel slag, and the high-temperature pore-forming mineral admixture is dried and ground for use;
先将体积稳定组分与高温成孔矿物外加剂搅拌均匀后再加入抗爆增韧组分搅拌均匀,得高温抗爆常温抗裂矿物掺合料产品。Stir the volume stabilizing component and the high-temperature pore-forming mineral admixture evenly, and then add the anti-explosion and toughening component and stir evenly to obtain a high-temperature, anti-explosion, normal-temperature, and anti-cracking mineral admixture product.
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| CNA2008100471076A Pending CN101244903A (en) | 2008-03-20 | 2008-03-20 | A high-temperature anti-explosion and normal-temperature anti-crack mineral admixture and its preparation method |
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| CN (1) | CN101244903A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105400120A (en) * | 2015-12-30 | 2016-03-16 | 福建江夏学院 | Composite material for toughening concrete |
| CN106630733A (en) * | 2016-12-20 | 2017-05-10 | 天津雨茅科技有限公司 | Composite mixing material for building decoration engineering and preparation method thereof |
| CN107907571A (en) * | 2017-11-13 | 2018-04-13 | 山西大学 | One kind is used to characterize concrete explosive spalling degree test stove and test method |
| CN108002784A (en) * | 2017-12-28 | 2018-05-08 | 安徽宏实光机电高科有限公司 | A kind of high-strength concrete of modified polypropylene fiber-steel fibre doping and preparation method thereof |
| CN109476540A (en) * | 2017-04-28 | 2019-03-15 | 住友大阪水泥股份有限公司 | Cement composition, method for producing the same, and method for producing fly ash for cement composition |
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2008
- 2008-03-20 CN CNA2008100471076A patent/CN101244903A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105400120A (en) * | 2015-12-30 | 2016-03-16 | 福建江夏学院 | Composite material for toughening concrete |
| CN105400120B (en) * | 2015-12-30 | 2017-10-17 | 福建江夏学院 | A kind of composite for concrete toughness reinforcing |
| CN106630733A (en) * | 2016-12-20 | 2017-05-10 | 天津雨茅科技有限公司 | Composite mixing material for building decoration engineering and preparation method thereof |
| CN106630733B (en) * | 2016-12-20 | 2019-01-18 | 深圳市信雅装饰设计工程有限公司 | A kind of building decoration engineering composite blend and preparation method thereof |
| CN109476540A (en) * | 2017-04-28 | 2019-03-15 | 住友大阪水泥股份有限公司 | Cement composition, method for producing the same, and method for producing fly ash for cement composition |
| CN109476540B (en) * | 2017-04-28 | 2021-02-12 | 住友大阪水泥股份有限公司 | Cement composition, method for producing same, and method for producing fly ash for cement composition |
| CN107907571A (en) * | 2017-11-13 | 2018-04-13 | 山西大学 | One kind is used to characterize concrete explosive spalling degree test stove and test method |
| CN108002784A (en) * | 2017-12-28 | 2018-05-08 | 安徽宏实光机电高科有限公司 | A kind of high-strength concrete of modified polypropylene fiber-steel fibre doping and preparation method thereof |
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Application publication date: 20080820 |