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CN100363276C - A kind of sludge ultrasonic dehydration method - Google Patents

A kind of sludge ultrasonic dehydration method Download PDF

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CN100363276C
CN100363276C CNB2006100114135A CN200610011413A CN100363276C CN 100363276 C CN100363276 C CN 100363276C CN B2006100114135 A CNB2006100114135 A CN B2006100114135A CN 200610011413 A CN200610011413 A CN 200610011413A CN 100363276 C CN100363276 C CN 100363276C
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sludge
ultrasonic
dewatering
dehydration
sewage treatment
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CN1821130A (en
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蒋建国
张群芳
郭权
杜雪娟
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Tsinghua University
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Abstract

The present invention relates to a supersonic wave dewatering method for sludge, which belongs to the technical field of solid waste treatment. In the method, sludge 1 dewatered in a sewage treatment plant is first pressed into cakes by a stirring appliance 2 and a tabletting appliance 3; the sludge is loaded into supersonic wave treating devices 5 arranged at the upper end and the lower end of a conveying belt 4 by the conveying belt 4; the sludge is treated by supersonic waves of certain frequency and power, which are generated by the supersonic wave treating devices 5; the sludge treated by the supersonic waves are further dewatered by a dewatering appliance 6, and water 7 obtained through dewatering is drained into a sewage treatment plant 8; and the dewatered sludge is changed into resources 9 at a later stage. In the dewatering method, the water content is dropped from the original range of 80 to 85% to the range of 60 to 70% after the sludge is treated by the supersonic waves, which lays a good foundation for changing the sludge into resources at a later stage. In addition, a used supersonic wave generator and other supporting facilities are mechanical appliances with low power and little consumed energy; compared with other dewatering technologies, both the cost and the energy consumption of the method are greatly reduced. Consequently, the method has a preferable market prospect.

Description

一种污泥超声波脱水方法 A kind of sludge ultrasonic dehydration method

技术领域technical field

本发明涉及一种利用超声波原理对污水处理厂污泥进行改性脱水的方法,属于固体废弃物处理技术领域。The invention relates to a method for modifying and dehydrating the sludge of a sewage treatment plant by using the ultrasonic principle, and belongs to the technical field of solid waste treatment.

背景技术Background technique

随着对环境保护问题的日益严峻,越来越多的城市建设了城市污水处理厂来处理居民生活污水,因此产生了副产物-污泥。污泥是由有机残片、细菌菌体、胶体、各种微生物和有机、无机颗粒组成的,含水分90%~99%,而固含物占1%~10%。目前我国的城市污泥排放量达到千万吨,而且每年还以10%的速度在增长,给环境带来了巨大的压力。国外的污泥产量也很大,例如英国污水处理所产生污泥的年产量为110.7万t干固体,人均每天产生污泥干固体为62g。由于污泥中含有大量容易腐烂的物质,而且还含有氮、磷等营养元素和镉、铜、汞等重金属物质,必须进行妥当处理处置,否则会给环境带来严重的污染。With the increasingly severe environmental protection problems, more and more cities have built urban sewage treatment plants to treat domestic sewage, thus producing a by-product - sludge. Sludge is composed of organic debris, bacterial cells, colloids, various microorganisms, and organic and inorganic particles. It contains 90% to 99% of water and 1% to 10% of solid content. At present, the discharge of urban sludge in my country has reached tens of millions of tons, and it is increasing at a rate of 10% every year, which has brought enormous pressure to the environment. The sludge production in foreign countries is also very large. For example, the annual output of sludge produced by sewage treatment in the UK is 1.107 million tons of dry solids, and the per capita dry solids of sludge produced per day is 62g. Since the sludge contains a large amount of perishable substances, and also contains nutrients such as nitrogen and phosphorus and heavy metals such as cadmium, copper and mercury, it must be properly disposed of, otherwise it will bring serious pollution to the environment.

城市污泥含有有机质,氮、磷、钾等营养元素以及Ni、Pb、Cr、Cu、Zn等重金属元素。有机物未经稳定化处理容易腐烂,而营养元素与重金属物质也会造成环境的二次污染。面对艰巨的污泥处理处置问题,中国政府非常重视,相继制定了《农用污泥中污染物控制标准》(GB4284-84)、《城镇污水处理厂污染物排放标准》(GB18918-2002)、《城市污水处理厂污水污泥排放标准》(CJ3025-93)以及《城市污水处理及污染防治技术政策》,对污泥的处理处置提出了严格的要求。Municipal sludge contains organic matter, nutrients such as nitrogen, phosphorus, and potassium, and heavy metals such as Ni, Pb, Cr, Cu, and Zn. Organic matter is easy to rot without stabilization treatment, and nutrients and heavy metals will also cause secondary pollution to the environment. Facing the difficult problem of sludge treatment and disposal, the Chinese government attaches great importance to it, and successively formulated the "Standards for the Control of Pollutants in Agricultural Sludge" (GB4284-84), the "Standards for Discharge of Pollutants from Urban Sewage Treatment Plants" (GB18918-2002), "Urban Sewage Treatment Plant Sewage Sludge Discharge Standard" (CJ3025-93) and "Urban Sewage Treatment and Pollution Prevention Technical Policy" put forward strict requirements for sludge treatment and disposal.

目前常用的处理方法主要包括重力沉降、调节和机械脱水。重力沉降可使污泥中固含物重量比从2%提高到5%,通常采用厌氧、好氧、加石灰、加热和冷溶等方法调节,工艺复杂,费用较高,部分污水处理厂未采用。机械脱水是污水处理厂的必备,常用方法有普通过滤、压滤、真空过滤和离心等,机械脱水受到污泥本身结构的限制,脱水效果十分有限。另外,上海市石洞口城市污水处理厂采用污泥干化焚烧工程,采用热工方法对污泥进行烘干脱水,需要大量热量,因此成本十分昂贵。Currently commonly used treatment methods mainly include gravity settling, conditioning and mechanical dehydration. Gravity settling can increase the weight ratio of solid content in sludge from 2% to 5%. It is usually adjusted by anaerobic, aerobic, lime, heating and cold solution methods. The process is complicated and the cost is high. Some sewage treatment plants Not adopted. Mechanical dehydration is a must for sewage treatment plants. Common methods include ordinary filtration, pressure filtration, vacuum filtration, and centrifugation. Mechanical dehydration is limited by the structure of the sludge itself, and the dehydration effect is very limited. In addition, Shanghai Shidongkou Urban Wastewater Treatment Plant adopts sludge drying and incineration project, and adopts thermal method to dry and dehydrate sludge, which requires a lot of heat, so the cost is very expensive.

发明内容Contents of the invention

本发明所要解决的问题是针对上述现有污泥脱水技术存在的不足而提出一种利用超声波本身所具有的机械和空化作用来破坏污泥中菌胶团结构,脱除其包含的水分,达到良好的污泥脱水效果。The problem to be solved by the present invention is to propose a method that utilizes the mechanical and cavitation effects of the ultrasonic wave itself to destroy the structure of bacterial micelles in the sludge and remove the moisture contained in it, aiming at the shortcomings of the above-mentioned existing sludge dewatering technology. Achieve good sludge dewatering effect.

本发明提出的一种污泥超声波脱水方法,其特征在于:所述方法是将污水处理厂经过脱水处理后的污泥(1)先经过搅拌设备(2)和压片设备(3)压成饼状,通过传送带(4)送入位于该传送带上下两端的超声波处理装置(5),超声波处理装置(5)产生一定频率和功率的超声波对污泥进行处理,超声波处理后的污泥经过脱水设备(6)进一步脱水,脱出的水分(7)回排入污水处理厂(8),脱水后的污泥进入后期资源化(9)。A kind of sludge ultrasonic dehydration method proposed by the present invention is characterized in that: the method is that the sludge (1) after the dehydration treatment in the sewage treatment plant is first pressed into The cake is sent to the ultrasonic treatment device (5) located at the upper and lower ends of the conveyor belt through the conveyor belt (4). The ultrasonic treatment device (5) generates ultrasonic waves of a certain frequency and power to treat the sludge. The sludge after ultrasonic treatment is dehydrated. The equipment (6) is further dehydrated, and the dehydrated water (7) is discharged back into the sewage treatment plant (8), and the dehydrated sludge enters the later stage of resource utilization (9).

在上述污泥超声波脱水方法中,所述超声波处理装置(5)的超声频率为20、33、40、50KHz,超声声能密度控制在0.1-2.0w/g。In the above sludge ultrasonic dehydration method, the ultrasonic frequency of the ultrasonic treatment device (5) is 20, 33, 40, 50KHz, and the ultrasonic sound energy density is controlled at 0.1-2.0w/g.

在上述污泥超声波脱水方法中,其特征在于:所述超声波处理装置(5)的处理时间为4-10分钟内。In the above method for ultrasonic dewatering of sludge, it is characterized in that: the processing time of the ultrasonic treatment device (5) is within 4-10 minutes.

在上述污泥超声波脱水方法中,其特征在于:所述泥饼厚度控制在20cm内。In the above sludge ultrasonic dehydration method, it is characterized in that: the thickness of the mud cake is controlled within 20cm.

本发明的特点是超声波对于污水厂污泥脱水处理效果良好,且价格低廉,能耗低。首先超声波技术在我国的船舶、冶金和机械等部门得到了广泛的应用,有着良好的工业基础,国内很多厂家都具备生产能力并可达到国际先进水平,这为降低成本和应用提供了良好的条件。其次,本发明同现存的污泥脱水技术相比,能耗很低,是热处理耗能1/5甚至1/8,更加符合节能环保的特点,从经济角度来看也更加划算。The invention is characterized in that the ultrasonic wave has good dehydration treatment effect on sewage plant sludge, and has low price and low energy consumption. First of all, ultrasonic technology has been widely used in my country's shipbuilding, metallurgy and machinery departments, and has a good industrial foundation. Many domestic manufacturers have production capacity and can reach the international advanced level, which provides good conditions for cost reduction and application. . Secondly, compared with the existing sludge dewatering technology, the present invention has very low energy consumption, which is 1/5 or even 1/8 of the heat treatment energy consumption, which is more in line with the characteristics of energy saving and environmental protection, and is more cost-effective from an economic point of view.

附图说明Description of drawings

图1为本发明超声波污泥脱水技术的工艺流程示意图。Fig. 1 is a schematic process flow diagram of the ultrasonic sludge dewatering technology of the present invention.

具体实施方式Detailed ways

下面结合附图对本发明的技术方案做进一步说明:Below in conjunction with accompanying drawing, technical scheme of the present invention is described further:

1-污泥,2-搅拌设备,3-压片设备,4-传送带,5-超声波处理装置,6-脱水设备,7-脱除下的水分,8-污水处理厂,9-后期资源化,10-超声波。1-sludge, 2-mixing equipment, 3-tabletting equipment, 4-conveyor belt, 5-ultrasonic treatment device, 6-dehydration equipment, 7-remove water, 8-sewage treatment plant, 9-post-recycling , 10 - Ultrasonic.

本发明具体的流程为:将污水处理厂经过脱水处理后的污泥1先经过搅拌设备2和压片设备3,污泥被压成有一定厚度的饼状,通过传送带4送入位于该传送带上下两端的超声波处理装置5,超声波处理装置5产生一定频率和功率的超声波对污泥进行处理,超声波处理后的污泥经过脱水设备6进一步脱水,脱出的水分7将回排入污水处理厂8,脱水后的污泥进入后期资源化9。脱水后的污泥含水率可以达到60-70%,为后期的资源化打下了良好的基础,例如堆肥、燃料棒和制砖行业。The specific process of the present invention is: the sludge 1 after the dehydration treatment of the sewage treatment plant first passes through the stirring equipment 2 and the tableting equipment 3, and the sludge is pressed into a cake shape with a certain thickness, and is sent to the conveyor belt 4 through the conveyor belt. The ultrasonic treatment device 5 at the upper and lower ends, the ultrasonic treatment device 5 generates ultrasonic waves of a certain frequency and power to treat the sludge, the sludge after ultrasonic treatment is further dehydrated by the dehydration equipment 6, and the dehydrated water 7 will be discharged back into the sewage treatment plant 8 , the dehydrated sludge enters the later stage of resource utilization9. The moisture content of dehydrated sludge can reach 60-70%, which lays a good foundation for later resource utilization, such as composting, fuel rods and brick making industries.

本发明基于的技术原理为:将污水处理厂经过脱水处理后的污泥经过搅拌和压饼,送入超声波处理装置,位于上下两端的超声波发生器产生一定频率和功率的超声波,对污泥中的菌胶团进行破坏,经过一定的处理时间达到最佳的脱水效率后,脱水后的污泥将自动转运到超声波处理装置外的压滤设备上,脱除经过超声波处理后产生的水分。这一过程产生的水分将排入污水处理厂,剩余的污泥组分由于达到了良好的脱水效果,可以用于后期的资源化,例如堆肥、燃料棒和制砖行业。The technical principle of the present invention is as follows: the dehydrated sludge of the sewage treatment plant is stirred and cake-pressed, and then sent to the ultrasonic treatment device, and the ultrasonic generators located at the upper and lower ends generate ultrasonic waves of a certain frequency and power, which are used in the sludge. After a certain treatment time to achieve the best dehydration efficiency, the dehydrated sludge will be automatically transferred to the filter press equipment outside the ultrasonic treatment device to remove the water generated after ultrasonic treatment. The moisture produced in this process will be discharged into the sewage treatment plant, and the remaining sludge components can be used for later resource utilization due to the good dehydration effect, such as composting, fuel rods and brick making industries.

在本发明中,需要有几个关键的参数选定,分别为:处理时间、泥饼厚度、超声波频率、超声波功率。超声波的频率和功率控制是本技术的关键之处,过弱的超声波对于污泥不起作用,而过强的超声波将破坏污泥内部细菌的结构,不利于后期污泥资源化。本发明现选定的超声波频率为20、33、40、50KHz,超声波声能密度控制在0.1-2.0w/g,超声波处理时间为4-10分钟内,泥饼厚度控制在20cm内。本发明可以将含水率80%的污泥脱水至60-70%,这样对后续的资源化奠定了良好的基础。由于各地污水成分不同和污水厂采取的工艺有差别,这几个参数也会相应的随之变化,因此在不违背本发明的实质和所附权利要求范围的前提下,在具体实施过程中,可以对本发明中关键参数的选择做出一些适当的改变。In the present invention, several key parameters need to be selected, namely: processing time, mud cake thickness, ultrasonic frequency, ultrasonic power. The frequency and power control of ultrasonic waves is the key point of this technology. Too weak ultrasonic waves have no effect on sludge, while too strong ultrasonic waves will destroy the structure of bacteria inside the sludge, which is not conducive to the recycling of sludge in the later stage. In the present invention, the selected ultrasonic frequency is 20, 33, 40, 50KHz, the ultrasonic sound energy density is controlled at 0.1-2.0w/g, the ultrasonic treatment time is within 4-10 minutes, and the mud cake thickness is controlled within 20cm. The invention can dehydrate the sludge with a water content of 80% to 60-70%, thus laying a good foundation for subsequent resource utilization. Due to the different components of sewage in different places and the differences in the processes adopted by sewage plants, these parameters will also change accordingly. Therefore, under the premise of not violating the essence of the present invention and the scope of the appended claims, in the specific implementation process, Some appropriate changes can be made to the selection of key parameters in the present invention.

试验结果表明,超声波对于污泥脱水效果良好。本发明的前述和其它目的、特点和积极效果结合附图对优选实施例的详细说明会变得更加明显。The test results show that ultrasonic has a good effect on sludge dewatering. The aforementioned and other objects, features and positive effects of the present invention will become more apparent from the detailed description of the preferred embodiments in conjunction with the accompanying drawings.

实施例1Example 1

秦皇岛某城市污水处理厂,采用活性污泥法处理,其脱水污泥的性质如表2所示:An urban sewage treatment plant in Qinhuangdao adopts the activated sludge method for treatment, and the properties of the dewatered sludge are shown in Table 2:

表2处理前污泥性质及组分表Table 2 Sludge properties and components before treatment

    含水率(%)  Moisture content (%)   挥发分含量(%)Volatile content (%)     灰分含量(%)  Ash content (%)     固定碳(%)Fixed carbon (%)     低位热值(kcal/g)  Lower calorific value (kcal/g)     84.2084.20   40.9540.95     56.6656.66     2.392.39     457457

处理后的污泥含水率如表3所示:The moisture content of the treated sludge is shown in Table 3:

表3超声波处理后污泥含水率表Table 3 Water content of sludge after ultrasonic treatment

  编号 serial number   时间(min)time (min)   超声频率(KHz)Ultrasonic frequency (KHz)     声能密度(w/g)  Sound energy density (w/g)   反应后温度(℃)Temperature after reaction (°C)   污泥厚度(cm)Sludge thickness (cm)   含水率(%)Moisture content (%)     1 1     00     00     00     2020     1010     84.284.2     2 2     44     4040     0.80.8     22 twenty two     1010     63.363.3     33     66     4040     0.80.8     3030     1010     64.864.8     44     8 8     4040     0.80.8     3333     1010     64.464.4

实施例2Example 2

深圳南山区某城市污水处理厂,采用氧化沟工艺处理污水,脱水污泥的性质如表4所示:An urban sewage treatment plant in Nanshan District, Shenzhen, adopts the oxidation ditch process to treat sewage. The properties of dewatered sludge are shown in Table 4:

表4超声波处理前污泥含水率和组分表Table 4 Sludge moisture content and components before ultrasonic treatment

    含水率(%)  Moisture content (%)   挥发分含量(%)Volatile content (%)     灰分含量(%)  Ash content (%)   固定碳(%)Fixed carbon (%)     低位热值(kcal/g)  Lower calorific value (kcal/g)     82.7082.70   42.3242.32     55.6455.64   2.042.04     463463

处理后污泥含水率如表5所示:The moisture content of the treated sludge is shown in Table 5:

表5超声波处理后污泥含水率统计表Table 5 Statistical table of moisture content of sludge after ultrasonic treatment

  编号 serial number   时间(min)time (min)     超声频率(KHz) Ultrasonic Frequency(KHz)   声能密度(w/g)Sound energy density (w/g)   反应后温度(℃)Temperature after reaction (°C)   污泥厚度(cm)Sludge thickness (cm)     含水率(%)  Moisture content (%)     1 1     00     00     00     2020     2020     82.782.7     2 2     44     5050     1.61.6     2525     2020     60.160.1     33     66     5050     1.61.6     3434     2020     62.262.2     44     8 8     5050     1.61.6     4040     2020     63.063.0

以上实例可以得出,污泥经过超声波处理之后,含水率从原来的80-85%下降到60-70%,这对污泥后期的资源化奠定了一个较好的基础。本发明的能耗主要来源于超声波发生器和其他配套设施的耗能,均为功率低、耗能少的机械设备,与其它脱水技术相比,成本和能耗都将大幅降低,因此有较好的市场前景。From the above examples, it can be concluded that after the sludge is treated with ultrasonic waves, the water content drops from 80-85% to 60-70%, which lays a good foundation for the later recycling of sludge. The energy consumption of the present invention mainly comes from the energy consumption of the ultrasonic generator and other supporting facilities, all of which are mechanical equipment with low power and low energy consumption. Compared with other dehydration technologies, the cost and energy consumption will be greatly reduced, so there is a comparative advantage. Good market prospect.

Claims (1)

1.一种污泥超声波脱水方法,其特征在于:所述方法是将污水处理厂经过脱水处理后的污泥(1)先经过搅拌设备(2)和压片设备(3)压成饼状,通过传送带(4)送入位于该传送带上下两端的超声波处理装置(5),超声波处理装置(5)产生一定频率和功率的超声波对污泥进行处理,超声波处理后的污泥经过脱水设备(6)进一步脱水,脱出的水分(7)回排入污水处理厂(8),脱水后的污泥进入后期资源化(9);所述超声波处理装置(5)的超声频率为20、33、40、50KHz,超声声能密度控制在0.1-2.0w/g;所述超声波处理装置(5)的处理时间为4-10分钟内;所述泥饼厚度控制在20cm内。1. A sludge ultrasonic dehydration method, characterized in that: the method is to press the sludge (1) from a sewage treatment plant into a cake through a stirring device (2) and a tableting device (3) after dehydration treatment , sent through the conveyor belt (4) to the ultrasonic treatment device (5) located at the upper and lower ends of the conveyor belt, the ultrasonic treatment device (5) generates ultrasonic waves of a certain frequency and power to treat the sludge, and the sludge after ultrasonic treatment passes through the dehydration equipment ( 6) Further dehydration, the dehydrated water (7) is discharged back into the sewage treatment plant (8), and the dehydrated sludge enters the later stage of resource utilization (9); the ultrasonic frequency of the ultrasonic treatment device (5) is 20, 33, 40, 50KHz, the ultrasonic sound energy density is controlled at 0.1-2.0w/g; the processing time of the ultrasonic treatment device (5) is within 4-10 minutes; the thickness of the mud cake is controlled within 20cm.
CNB2006100114135A 2006-03-03 2006-03-03 A kind of sludge ultrasonic dehydration method Expired - Fee Related CN100363276C (en)

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