CN100366817C - Mould proof odour eliminating moisture guiding antistatic chitin adjuvant and process and application - Google Patents
Mould proof odour eliminating moisture guiding antistatic chitin adjuvant and process and application Download PDFInfo
- Publication number
- CN100366817C CN100366817C CNB031416608A CN03141660A CN100366817C CN 100366817 C CN100366817 C CN 100366817C CN B031416608 A CNB031416608 A CN B031416608A CN 03141660 A CN03141660 A CN 03141660A CN 100366817 C CN100366817 C CN 100366817C
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- CN
- China
- Prior art keywords
- chitin
- antistatic
- auxiliary agent
- mildew
- wet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920002101 Chitin Polymers 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims description 4
- 239000002671 adjuvant Substances 0.000 title abstract 3
- 238000005516 engineering process Methods 0.000 claims abstract description 12
- 239000012752 auxiliary agent Substances 0.000 claims description 15
- 230000001877 deodorizing effect Effects 0.000 claims description 15
- 150000001414 amino alcohols Chemical class 0.000 claims description 11
- 239000003093 cationic surfactant Substances 0.000 claims description 8
- 230000007062 hydrolysis Effects 0.000 claims description 5
- 238000006460 hydrolysis reaction Methods 0.000 claims description 5
- 229920001661 Chitosan Polymers 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 229920002994 synthetic fiber Polymers 0.000 claims description 4
- 239000012209 synthetic fiber Substances 0.000 claims description 2
- 238000009988 textile finishing Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 125000002091 cationic group Chemical group 0.000 abstract description 3
- 239000004094 surface-active agent Substances 0.000 abstract description 3
- 230000008030 elimination Effects 0.000 abstract 2
- 238000003379 elimination reaction Methods 0.000 abstract 2
- 230000002265 prevention Effects 0.000 abstract 2
- LKAPTZKZHMOIRE-KVTDHHQDSA-N (2s,3s,4s,5r)-3,4-dihydroxy-5-(hydroxymethyl)oxolane-2-carbaldehyde Chemical compound OC[C@H]1O[C@H](C=O)[C@@H](O)[C@@H]1O LKAPTZKZHMOIRE-KVTDHHQDSA-N 0.000 abstract 1
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 abstract 1
- 238000003889 chemical engineering Methods 0.000 abstract 1
- LKAPTZKZHMOIRE-UHFFFAOYSA-N chitose Natural products OCC1OC(C=O)C(O)C1O LKAPTZKZHMOIRE-UHFFFAOYSA-N 0.000 abstract 1
- 230000006196 deacetylation Effects 0.000 abstract 1
- 238000003381 deacetylation reaction Methods 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 238000009987 spinning Methods 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000004913 activation Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to the technical field of chemical engineering, more specifically, a chitin adjuvant for mould prevention, odour elimination, moisture guide and franklinism resistance, a technology thereof and an application thereof. The present invention is characterized in that the adjuvant is composed of deacetylation poly chitose solution to which aminoalcohol ramifications and cationic surface active agents are added, is prepared from the components to which the processing technology is carried out and can be applied to the field of spinning, etc. Compared with the prior art, the present invention has the functions of bacteriostasis, mould prevention, odour elimination, moisture guide, franklinism resistance, etc., has favorable compatibility with human skin, has obvious effect, can be applied in great numbers and popularized, has the advantages of simple use, low cost and less investment, does not need to change original production equipment and production technologies and is worth spreading and applying.
Description
[technical field]
The present invention relates to chemical technology field, wet antistatic chitin auxiliary agent and technology and application are led in specifically a kind of mildew-resistant deodorizing.
[technical background]
The chitin biomembrane is a chitosan, in order to textile fabric and textiles are filmed.Before filming, often to carry out pre-treatment, improve the film forming on fiber top layer fiber and fabric.When filming
Must strictly control coating thickness, then, through baking of long period.Functions such as that though the chitin biomembrane has is antibiotic, deodorizing, washability is poor, and operating procedure is complicated, factors such as the film forming on controlling fiber surface and coating thickness, and quality is wayward.And it is antistatic and lead function such as moist and be difficult to abundant demonstration.The composition that Chinese patent discloses relevant aminoalcohol derivative on July nineteen ninety-five 19, publication number be CN1105354. Chemical Industry Press in December, 1979 the chemical industry dictionary " cationic surface active agent " disclosed, aminoalcohol derivative and cationic surfactant are clearly to this professional people.
[summary of the invention]
The present invention adopts the biological-chemical means, in chitosan solution, add aminoalcohol derivative and cationic surfactant, increase the degree of hydrolysis of shitosan and to the molecular link relay of fiber, and improve the antistatic behaviour of shitosan and lead moistly, the function of shitosan is better brought into play.Purpose is utilize that chitin has antibacterial, mildew-resistant, deodorizing, leads functions such as biologically active such as wet, antistatic, can be included in the application of aspects such as field of textiles, thereby makes product reach natural, environmental protection, effect without any side effects.
For achieving the above object, design and a kind ofly have antibacterial mildew-resistant deodorizing and lead wet anlistatig chitin auxiliary agent, it is characterized in that, add aminoalcohol derivative and cationic surfactant and form by in the chitosan solution.The percentage by weight of aminoalcohol derivative is 5-7%.The percentage by weight of cationic surfactant is 3-5%.The processing step of the technology of wet antistatic chitin auxiliary agent is led in the mildew-resistant deodorizing: at first shitosan is immersed in the acetum and dissolve, then put into the incubator slaking, adding aminoalcohol derivative and cationic surfactant then stirs, is in harmonious proportion, then activate, hydrolysis, filter, promptly get the chitin auxiliary agent.The described maturing process time is 24 hours, and temperature is 20 ℃-25 ℃.Described soak time is 24 hours, and temperature is 20 ℃-25 ℃.Described mildew-resistant deodorizing is led wet antistatic chitin auxiliary agent and be can be applicable to yarn, lining, the ready-made clothes textile finishing technical field that natural fabric, artificial fibre, synthetic fiber are made.
The present invention compares with prior art, have antibacterial, mildew-resistant, deodorizing, lead functions such as wet, antistatic, human body skin there is excellent compatibility, effect is remarkable, can use in a large number and popularize, and uses simple, need not change original production equipment and production technology, cost is low, and small investment is worthy of promotion and application.
[description of drawings]
Fig. 1 is a process chart of the present invention.
Referring to Fig. 1: 1 be the shitosan raw material, 2 for the acetum dissolving, 3 for the incubator slaking, 4 for add aminoalcohol derivative and cationic active agent stir and be in harmonious proportion, 5 for activation, 6 for hydrolysis, 7 for filtering, 8 being product.
[embodiment]
Be described further below in conjunction with accompanying drawing, the manufacturing of this technology concerning this professional people still clearly.
Referring to Fig. 1, at first the shitosan raw material is immersed in the acetum, put into 24 hours temperature of incubator slaking subsequently and be set at 20 ℃-25 ℃, add aminoalcohol derivative, surfactant stirring mediation afterwards, then activate 24 hours temperature and also be set at 20 ℃-25 ℃, hydrolysis is then filtered, and obtains the chitin auxiliary agent at last.
Claims (7)
1. wet antistatic chitin auxiliary agent is led in a mildew-resistant deodorizing, it is characterized in that by in the chitosan solution, adds aminoalcohol derivative and cationic surfactant and forms.
2. wet antistatic chitin auxiliary agent is led in mildew-resistant deodorizing as claimed in claim 1, and the percentage by weight that it is characterized in that aminoalcohol derivative is 5-7%.
3. wet antistatic chitin auxiliary agent is led in 1 described mildew-resistant deodorizing as claims, and the percentage by weight that it is characterized in that cationic surfactant is 3-5%.
4. the technology of wet antistatic chitin auxiliary agent is led in a mildew-resistant deodorizing, it is characterized in that comprising following processing step: at first shitosan is immersed in the acetum and dissolve, then put into the incubator slaking, adding aminoalcohol derivative and cationic surfactant then stirs, is in harmonious proportion, then activate, hydrolysis is filtered, and promptly gets the chitin auxiliary agent.
5. the technology of wet antistatic chitin auxiliary agent is led in mildew-resistant deodorizing as claimed in claim 4, and it is characterized in that: the described maturing process time is 24 hours, and temperature is 20 ℃-25 ℃.
6. the technology of wet antistatic chitin auxiliary agent is led in mildew-resistant deodorizing as claimed in claim 4, and it is characterized in that: described soak time is 24 hours, and temperature is 20 ℃-25 ℃.
7. the purposes of wet antistatic chitin auxiliary agent is led in mildew-resistant deodorizing as claimed in claim 1, it is characterized in that: be applied in yarn, lining, ready-made clothes textile finishing technical field that natural fabric, artificial fibre, synthetic fiber are made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031416608A CN100366817C (en) | 2003-07-17 | 2003-07-17 | Mould proof odour eliminating moisture guiding antistatic chitin adjuvant and process and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031416608A CN100366817C (en) | 2003-07-17 | 2003-07-17 | Mould proof odour eliminating moisture guiding antistatic chitin adjuvant and process and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1475623A CN1475623A (en) | 2004-02-18 |
| CN100366817C true CN100366817C (en) | 2008-02-06 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB031416608A Expired - Fee Related CN100366817C (en) | 2003-07-17 | 2003-07-17 | Mould proof odour eliminating moisture guiding antistatic chitin adjuvant and process and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100366817C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103147305A (en) * | 2013-03-26 | 2013-06-12 | 无锡嘉德纺织制品有限公司 | Chitin composite textile auxiliary and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5718954A (en) * | 1993-05-24 | 1998-02-17 | Idemitsu Petrochemical Co., Ltd. | Substance including natural organic substance fine powder |
| CN1233296A (en) * | 1996-09-17 | 1999-10-27 | 三菱丽阳株式会社 | Acrylonitrile fiber containing chitosan and its preparation method |
| CN1378007A (en) * | 2001-03-30 | 2002-11-06 | 林宇德 | Manufacturing method of sterilizing and deodorizing fiber product |
| CN1508353A (en) * | 2002-12-19 | 2004-06-30 | 全球生技股份有限公司 | Processing method for applying chitin to fiber antibiosis |
-
2003
- 2003-07-17 CN CNB031416608A patent/CN100366817C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5718954A (en) * | 1993-05-24 | 1998-02-17 | Idemitsu Petrochemical Co., Ltd. | Substance including natural organic substance fine powder |
| CN1233296A (en) * | 1996-09-17 | 1999-10-27 | 三菱丽阳株式会社 | Acrylonitrile fiber containing chitosan and its preparation method |
| CN1378007A (en) * | 2001-03-30 | 2002-11-06 | 林宇德 | Manufacturing method of sterilizing and deodorizing fiber product |
| CN1508353A (en) * | 2002-12-19 | 2004-06-30 | 全球生技股份有限公司 | Processing method for applying chitin to fiber antibiosis |
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| Publication number | Publication date |
|---|---|
| CN1475623A (en) | 2004-02-18 |
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Owner name: LONGTOU,SHANGHAI ( GROUP ) CO., LTD. Free format text: FORMER OWNER: SHANGHAI LONGTOU BIOTECHNOLOGY CO., LTD. Effective date: 20080321 |
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Effective date of registration: 20080321 Address after: Seat A, No. 584, manufacturing office, Shanghai Patentee after: Shanghai Longtou (Group) Co.,Ltd. Address before: Shanghai Textile Science and Technology Industrial Zone, No. 988, Pingliang Road, Shanghai Patentee before: Shanghai Longtou Biotechnology Co.,Ltd. |
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Effective date of registration: 20081226 Address after: Shanghai Helen Road, 88 Lane 22, room 2101 Patentee after: SHANGHAI XIDOU SCIENCE AND TRADE Co.,Ltd. Address before: Seat A, No. 584, manufacturing office, Shanghai Patentee before: Shanghai Longtou (Group) Co.,Ltd. |
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