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CN109957701A - A kind of production method of equipment furnace shell NR400ZL steel plate - Google Patents

A kind of production method of equipment furnace shell NR400ZL steel plate Download PDF

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Publication number
CN109957701A
CN109957701A CN201910249103.4A CN201910249103A CN109957701A CN 109957701 A CN109957701 A CN 109957701A CN 201910249103 A CN201910249103 A CN 201910249103A CN 109957701 A CN109957701 A CN 109957701A
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steel plate
steel
temperature
nr400zl
furnace shell
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Inventor
李�杰
赵国昌
王甜甜
龙杰
庞辉勇
李劲峰
瞿征
尹卫江
丁文科
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Wuyang Iron and Steel Co Ltd
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Wuyang Iron and Steel Co Ltd
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Priority to CN201910249103.4A priority Critical patent/CN109957701A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/10Supplying or treating molten metal
    • B22D11/11Treating the molten metal
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • C21D1/28Normalising
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/005Heat treatment of ferrous alloys containing Mn
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/008Heat treatment of ferrous alloys containing Si
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/0081Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for slabs; for billets
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Abstract

The invention discloses a kind of production method of equipment furnace shell NR400ZL steel plate, the production method includes steel-making, continuous casting, heating, rolling and heat treatment procedure.The present invention passes through to C, Si element component content is limited, by to convertor steelmaking process baking temperature of steel ladle and C content control, LF refining process white slag retention time and the control of vacuum soft blow time, using molding casting, control steel plate rolling technique and red temperature, gained steel plate has good compactness, higher intensity and good welds performance, steel plate thickness is 60~160mm, steel plate yield strength >=320MPa, tensile strength >=420MPa, elongation percentage >=24%, 0 DEG C of impact >=60J, 350 DEG C of high temperature tensile strength >=230MPa, fully meet standard and safety requirements, it is suitable for equipment shell steel demand.

Description

A kind of production method of equipment furnace shell NR400ZL steel plate
Technical field
The invention belongs to metallurgical technology fields, and in particular to a kind of production method of equipment furnace shell NR400ZL steel plate.
Background technique
NR400ZL steel plate is novel converter furnace shell plate, elevated temperature strength with higher and creep-resistant property, by increasingly More extensive uses, demand of the market to such steel plate are increasing.
With the enlargement of converter installation and the increase of smelting requirements, when design, is obvious compared with standard to the intensity rank of steel plate It improves, and the thickness of steel plate is also in increase trend.With the increase of steel plate thickness, it is bound to cause the increase of production difficulty, is adopted With traditional production method, it has been difficult to meet the market demand.
To sum up, further the production method of exploitation high-performance NR400ZL steel plate has the development of domestic converter shell steel It is of great importance.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of production methods of equipment furnace shell NR400ZL steel plate.This hair It is good to ensure that steel plate has for the bright control by master operation technical parameter in steel plate chemical component and production technology Performance meets market to the requirement of equipment furnace shell NR400ZL steel plate.
In order to solve the above technical problems, the technical solution used in the present invention is: a kind of equipment furnace shell NR400ZL steel plate Production method, the production method include steel-making, continuous casting, heating, rolling and heat treatment procedure;The continuous casting working procedure, continuous casting 15~25 DEG C of the degree of superheat, molding casting, stopper rod of tundish Argon and argon blowing sealing are used when continuous casting, argon pressure control exists 0.2~0.4MPa, argon flow control guarantee that continuous casting is made in liquid slag layer thickness after 10~15mm, continuous casting in 15~20L/min Base;The rolling process, using II type controlled rolling, the red temperature of steel plate is 650~750 DEG C.
Steel making working procedure of the present invention, in convertor steelmaking process, baking temperature of steel ladle >=1000 DEG C, molten steel C when tapping >= 0.06%, 1560~1600 DEG C of tapping temperature, pre-deoxidation is carried out in big packet after tapping;It is good that Ar is blown in LF refining guarantee, and white slag is protected Holding the time is 25~35min, sample aluminium content >=0.015% of skimming;VD refining terminates 5~10min of soft blow after vacuum.
Heating process of the present invention, steel billet is in continuous stove heating, and 1260 DEG C of maximum heating temperature, soaking temperature 1240~ 1250℃。
Rolling process of the present invention, I 1050~1150 DEG C of stage start rolling temperature, dry in the air steel thickness >=2H, and the H is finished product Steel plate thickness.
Rolling process of the present invention, II stage start rolling temperature≤930 DEG C, 830~860 DEG C of finishing temperature.
Heat treatment procedure of the present invention, using normalizing heat treatment technique, normalizing furnace carries out normalizing, and normalizing temperature 900~ 930 DEG C, soaking time: 2.0~2.3min/mm, come out of the stove it is air-cooled after obtain equipment furnace shell NR400ZL steel plate.
Steel plate thickness of the present invention is 60~160mm.
Steel plate yield strength >=320MPa of the present invention, tensile strength >=420MPa, elongation percentage >=24%, 0 DEG C impact >= 60J, 350 DEG C of high temperature tensile strength >=230MPa.
Steel plate chemical component composition and its mass percentage of the present invention are as follows: C:0.11~0.15%, Si:0.15~ 0.40%, Mn:0.90~1.30%, P≤0.020%, S≤0.010%, Nb≤0.045%, V≤0.045%, Ti≤0.020%, Mo: 0.20~0.40%, Alt:0.020~0.050%, surplus are Fe and inevitable impurity.
Process design mechanism of the present invention:
Pouring technology control aspect in steelmaking process of the present invention, the purpose of molding casting are to occur two after liquid steel refining in order to prevent Secondary oxidative phenomena guarantees the smelting of clean steel, improves slab quality, guarantees that plate property is stablized;Two ranks are used in rolling process Section rolling, in conjunction with the red temperature of steel grade control steel plate, hence it is evident that improve the stability of steel plate.
Two-phase control rolling principle, first stage rolling is the controlled rolling in austenite recrystallization area, mainly makes austenite crystal The significant refinement of grain;Second stage makes equi-axed crystal become flat crystal grain in the rolling of non-recrystallization zone, and austenite crystal interfacial area is into one Step expands, while introducing a large amount of dislocations and Zona transformans transgranular, becomes the cenotype nucleation site with Grain-Boundary Phase competition;It limits simultaneously The red temperature of steel plate further makes even tissue tiny, hence it is evident that improves plate property stability.
The beneficial effects of adopting the technical scheme are that 1, the present invention by C, Si element component content into Row limitation, it is ensured that armor plate strength meets design needs.2, the present invention is by convertor steelmaking process baking temperature of steel ladle and C content Control, LF refining process white slag retention time and the control of vacuum soft blow time, ensure that steel inner clamps sundries sufficiently floats, reach Composition Control precision and internal soundness are excellent.3, the present invention prevents generation secondary oxidation after liquid steel refining existing using molding casting As guaranteeing the good surface quality of steel billet and internal stresses release, guaranteeing the smelting of clean steel, improve slab quality, it is ensured that steel billet The defects of not cracking.4, this hair passes through to I, II rank start rolling temperature, finishing temperature control in rolling process, it is ensured that steel plate Good tissue deposit, being heat-treated subsequently through normalizing further improves tissue topography, reaches steel plate requirement.5, of the invention Steel plate have good compactness, higher intensity and good welds performance, steel plate yield strength >=320MPa, tensile strength >= 420MPa, elongation percentage >=24%, 0 DEG C impact >=60J, 350 DEG C of high temperature tensile strength >=230MPa fully meet standard and safety It is required that being suitable for equipment shell steel demand.
Specific embodiment
The present invention will be further described in detail below with reference to specific embodiments.
Embodiment 1
The present embodiment equipment furnace shell is 60mm with NR400ZL steel plate thickness, and chemical component composition and mass percentage are shown in Table 1。
The production method of the present embodiment equipment furnace shell NR400ZL steel plate includes at steel-making, continuous casting, heating, rolling and heat Science and engineering sequence, specific process step are as described below:
(1) steel making working procedure: in convertor steelmaking process, 1000 DEG C of baking temperature of steel ladle, molten steel C:0.06% when tapping, tapping temperature 1560 DEG C, pre-deoxidation is carried out in big packet after tapping;It is good that Ar is blown in LF refining guarantee, and the white slag retention time is 25min, takes off slag specimen Aluminium content 0.020%;VD refining terminates soft blow 10min after vacuum;
(2) continuous casting working procedure: 25 DEG C of the continuous casting degree of superheat, molding casting is used when continuous casting, stopper rod of tundish Argon and argon blowing are close Envelope, in 0.2MPa, argon flow control guarantees that liquid slag layer thickness is made after 10mm, continuous casting in 15L/min for argon pressure control Continuous casting billet;
(3) heating process: steel billet is in continuous stove heating, and 1260 DEG C of maximum heating temperature, 1250 DEG C of soaking temperature;
(4) rolling process: II type controlled rolling is used, I 1050 DEG C of stage start rolling temperature, dry in the air steel thickness 150mm;The open rolling of II stage 930 DEG C of temperature, 860 DEG C of finishing temperature;The red temperature of steel plate is 650 DEG C.;
(5) heat treatment procedure: use normalizing heat treatment technique, normalizing furnace carry out normalizing, 910 DEG C of normalizing temperature, soaking time: 2.1min/mm, come out of the stove it is air-cooled after obtain equipment furnace shell NR400ZL steel plate.
The present embodiment equipment furnace shell is shown in Table 2 with the mechanical property of NR400ZL steel plate.
Embodiment 2
The present embodiment equipment furnace shell is 80mm with NR400ZL steel plate thickness, and chemical component composition and mass percentage are shown in Table 1。
The production method of the present embodiment equipment furnace shell NR400ZL steel plate includes at steel-making, continuous casting, heating, rolling and heat Science and engineering sequence, specific process step are as described below:
(1) steel making working procedure: in convertor steelmaking process, 1020 DEG C of baking temperature of steel ladle, molten steel C:0.07% when tapping, tapping temperature 1600 DEG C, pre-deoxidation is carried out in big packet after tapping;It is good that Ar is blown in LF refining guarantee, and the white slag retention time is 35min, takes off slag specimen Aluminium content 0.015%;VD refining terminates soft blow 5min after vacuum;
(2) continuous casting working procedure: 15 DEG C of the continuous casting degree of superheat, molding casting is used when continuous casting, stopper rod of tundish Argon and argon blowing are close Envelope, in 0.4MPa, argon flow control guarantees that liquid slag layer thickness is made after 15mm, continuous casting in 20L/min for argon pressure control Continuous casting billet;
(3) heating process: steel billet is in continuous stove heating, and 1260 DEG C of maximum heating temperature, 1240 DEG C of soaking temperature;
(4) rolling process: II type controlled rolling is used, I 1150 DEG C of stage start rolling temperature, dry in the air steel thickness 165mm;The open rolling of II stage 920 DEG C of temperature, 830 DEG C of finishing temperature;The red temperature of steel plate is 750 DEG C.;
(5) heat treatment procedure: use normalizing heat treatment technique, normalizing furnace carry out normalizing, 900 DEG C of normalizing temperature, soaking time: 2.2min/mm, come out of the stove it is air-cooled after obtain equipment furnace shell NR400ZL steel plate.
The present embodiment equipment furnace shell is shown in Table 2 with the mechanical property of NR400ZL steel plate.
Embodiment 3
The present embodiment equipment furnace shell is 120mm with NR400ZL steel plate thickness, and chemical component composition and mass percentage are shown in Table 1。
The production method of the present embodiment equipment furnace shell NR400ZL steel plate includes at steel-making, continuous casting, heating, rolling and heat Science and engineering sequence, specific process step are as described below:
(1) steel making working procedure: in convertor steelmaking process, 1050 DEG C of baking temperature of steel ladle, molten steel C:0.08% when tapping, tapping temperature 1570 DEG C, pre-deoxidation is carried out in big packet after tapping;It is good that Ar is blown in LF refining guarantee, and the white slag retention time is 30min, takes off slag specimen Aluminium content 0.017%;VD refining terminates soft blow 7min after vacuum;
(2) continuous casting working procedure: 20 DEG C of the continuous casting degree of superheat, molding casting is used when continuous casting, stopper rod of tundish Argon and argon blowing are close Envelope, in 0.3MPa, argon flow control guarantees that liquid slag layer thickness is made after 12mm, continuous casting in 17L/min for argon pressure control Continuous casting billet;
(3) heating process: steel billet is in continuous stove heating, and 1260 DEG C of maximum heating temperature, 1245 DEG C of soaking temperature;
(4) rolling process: II type controlled rolling is used, I 1100 DEG C of stage start rolling temperature, dry in the air steel thickness 260mm;The open rolling of II stage 910 DEG C of temperature, 840 DEG C of finishing temperature;The red temperature of steel plate is 660 DEG C;
(5) heat treatment procedure: use normalizing heat treatment technique, normalizing furnace carry out normalizing, 915 DEG C of normalizing temperature, soaking time: 2.0min/mm, come out of the stove it is air-cooled after obtain equipment furnace shell NR400ZL steel plate.
The present embodiment equipment furnace shell is shown in Table 2 with the mechanical property of NR400ZL steel plate.
Embodiment 4
The present embodiment equipment furnace shell is 100mm with NR400ZL steel plate thickness, and chemical component composition and mass percentage are shown in Table 1。
The production method of the present embodiment equipment furnace shell NR400ZL steel plate includes at steel-making, continuous casting, heating, rolling and heat Science and engineering sequence, specific process step are as described below:
(1) steel making working procedure: in convertor steelmaking process, 1060 DEG C of baking temperature of steel ladle, molten steel C:0.07% when tapping, tapping temperature 1580 DEG C, pre-deoxidation is carried out in big packet after tapping;It is good that Ar is blown in LF refining guarantee, and the white slag retention time is 32min, takes off slag specimen Aluminium content 0.017%;VD refining terminates soft blow 8min after vacuum;
(2) continuous casting working procedure: 21 DEG C of the continuous casting degree of superheat, molding casting is used when continuous casting, stopper rod of tundish Argon and argon blowing are close Envelope, in 0.35MPa, argon flow control guarantees that liquid slag layer thickness is made after 13mm, continuous casting in 16L/min for argon pressure control At continuous casting billet;
(3) heating process: steel billet is in continuous stove heating, and 1260 DEG C of maximum heating temperature, 1247 DEG C of soaking temperature;
(4) rolling process: II type controlled rolling is used, I 1070 DEG C of stage start rolling temperature, dry in the air steel thickness 220mm;The open rolling of II stage 915 DEG C of temperature, 845 DEG C of finishing temperature;The red temperature of steel plate is 670 DEG C;
(5) heat treatment procedure: use normalizing heat treatment technique, normalizing furnace carry out normalizing, 920 DEG C of normalizing temperature, soaking time: 2.3min/mm, come out of the stove it is air-cooled after obtain equipment furnace shell NR400ZL steel plate.
The present embodiment equipment furnace shell is shown in Table 2 with the mechanical property of NR400ZL steel plate.
Embodiment 5
The present embodiment equipment furnace shell is 160mm with NR400ZL steel plate thickness, and chemical component composition and mass percentage are shown in Table 1。
The production method of the present embodiment equipment furnace shell NR400ZL steel plate includes at steel-making, continuous casting, heating, rolling and heat Science and engineering sequence, specific process step are as described below:
(1) steel making working procedure: in convertor steelmaking process, 1035 DEG C of baking temperature of steel ladle, molten steel C:0.08% when tapping, tapping temperature 1580 DEG C, pre-deoxidation is carried out in big packet after tapping;It is good that Ar is blown in LF refining guarantee, and the white slag retention time is 30min, takes off slag specimen Aluminium content 0.018%;VD refining terminates soft blow 7min after vacuum;
(2) continuous casting working procedure: 20 DEG C of the continuous casting degree of superheat, molding casting is used when continuous casting, stopper rod of tundish Argon and argon blowing are close Envelope, in 0.35MPa, argon flow control guarantees that liquid slag layer thickness is made after 14mm, continuous casting in 18L/min for argon pressure control At continuous casting billet;
(3) heating process: steel billet is in continuous stove heating, and 1260 DEG C of maximum heating temperature, 1242 DEG C of soaking temperature;
(4) rolling process: II type controlled rolling is used, I 1120 DEG C of stage start rolling temperature, dry in the air steel thickness 320mm;The open rolling of II stage 925 DEG C of temperature, 855 DEG C of finishing temperature;The red temperature of steel plate is 695 DEG C;
(5) heat treatment procedure: use normalizing heat treatment technique, normalizing furnace carry out normalizing, 930 DEG C of normalizing temperature, soaking time: 2.2min/mm, come out of the stove it is air-cooled after obtain equipment furnace shell NR400ZL steel plate.
The present embodiment equipment furnace shell is shown in Table 2 with the mechanical property of NR400ZL steel plate.
Embodiment 6
The present embodiment equipment furnace shell is 140mm with NR400ZL steel plate thickness, and chemical component composition and mass percentage are shown in Table 1。
The production method of the present embodiment equipment furnace shell NR400ZL steel plate includes at steel-making, continuous casting, heating, rolling and heat Science and engineering sequence, specific process step are as described below:
(1) steel making working procedure: in convertor steelmaking process, 1030 DEG C of baking temperature of steel ladle, molten steel C:0.06% when tapping, tapping temperature 1590 DEG C, pre-deoxidation is carried out in big packet after tapping;It is good that Ar is blown in LF refining guarantee, and the white slag retention time is 28min, takes off slag specimen Aluminium content 0.016%;VD refining terminates soft blow 9min after vacuum;
(2) continuous casting working procedure: 23 DEG C of the continuous casting degree of superheat, molding casting is used when continuous casting, stopper rod of tundish Argon and argon blowing are close Envelope, in 0.25MPa, argon flow control guarantees that liquid slag layer thickness is made after 11mm, continuous casting in 19L/min for argon pressure control At continuous casting billet;
(3) heating process: steel billet is in continuous stove heating, and 1260 DEG C of maximum heating temperature, 1248 DEG C of soaking temperature;
(4) rolling process: II type controlled rolling is used, I 1130 DEG C of stage start rolling temperature, dry in the air steel thickness 300mm;The open rolling of II stage 905 DEG C of temperature, 850 DEG C of finishing temperature;The red temperature of steel plate is 720 DEG C;
(5) heat treatment procedure: use normalizing heat treatment technique, normalizing furnace carry out normalizing, 905 DEG C of normalizing temperature, soaking time: 2.1min/mm, come out of the stove it is air-cooled after obtain equipment furnace shell NR400ZL steel plate.
The present embodiment equipment furnace shell is shown in Table 2 with the mechanical property of NR400ZL steel plate.
Embodiment 7
The present embodiment equipment furnace shell is 90mm with NR400ZL steel plate thickness, and chemical component composition and mass percentage are shown in Table 1。
The production method of the present embodiment equipment furnace shell NR400ZL steel plate includes at steel-making, continuous casting, heating, rolling and heat Science and engineering sequence, specific process step are as described below:
(1) steel making working procedure: in convertor steelmaking process, 1040 DEG C of baking temperature of steel ladle, molten steel C:0.08% when tapping, tapping temperature 1575 DEG C, pre-deoxidation is carried out in big packet after tapping;It is good that Ar is blown in LF refining guarantee, and the white slag retention time is 27min, takes off slag specimen Aluminium content 0.019%;VD refining terminates soft blow 6min after vacuum;
(2) continuous casting working procedure: 18 DEG C of the continuous casting degree of superheat, molding casting is used when continuous casting, stopper rod of tundish Argon and argon blowing are close Envelope, in 0.28MPa, argon flow control guarantees that liquid slag layer thickness is made after 15mm, continuous casting in 17L/min for argon pressure control At continuous casting billet;
(3) heating process: steel billet is in continuous stove heating, and 1260 DEG C of maximum heating temperature, 1243 DEG C of soaking temperature;
(4) rolling process: II type controlled rolling is used, I 1090 DEG C of stage start rolling temperature, dry in the air steel thickness 180mm;The open rolling of II stage 922 DEG C of temperature, 835 DEG C of finishing temperature;The red temperature of steel plate is 725 DEG C;
(5) heat treatment procedure: use normalizing heat treatment technique, normalizing furnace carry out normalizing, 925 DEG C of normalizing temperature, soaking time: 2.3min/mm, come out of the stove it is air-cooled after obtain equipment furnace shell NR400ZL steel plate.
The present embodiment equipment furnace shell is shown in Table 2 with the mechanical property of NR400ZL steel plate.
Embodiment 8
The present embodiment equipment furnace shell is 130mm with NR400ZL steel plate thickness, and chemical component composition and mass percentage are shown in Table 1。
The production method of the present embodiment equipment furnace shell NR400ZL steel plate includes at steel-making, continuous casting, heating, rolling and heat Science and engineering sequence, specific process step are as described below:
(1) steel making working procedure: in convertor steelmaking process, 1010 DEG C of baking temperature of steel ladle, molten steel C:0.06% when tapping, tapping temperature 1595 DEG C, pre-deoxidation is carried out in big packet after tapping;It is good that Ar is blown in LF refining guarantee, and the white slag retention time is 33min, takes off slag specimen Aluminium content 0.018%;VD refining terminates soft blow 8min after vacuum;
(2) continuous casting working procedure: 17 DEG C of the continuous casting degree of superheat, molding casting is used when continuous casting, stopper rod of tundish Argon and argon blowing are close Envelope, in 0.32MPa, argon flow control guarantees that liquid slag layer thickness is made after 12mm, continuous casting in 19L/min for argon pressure control At continuous casting billet;
(3) heating process: steel billet is in continuous stove heating, and 1260 DEG C of maximum heating temperature, 1246 DEG C of soaking temperature;
(4) rolling process: II type controlled rolling is used, I 1080 DEG C of stage start rolling temperature, dry in the air steel thickness 280mm;The open rolling of II stage 918 DEG C of temperature, 847 DEG C of finishing temperature;The red temperature of steel plate is 740 DEG C;
(5) heat treatment procedure: use normalizing heat treatment technique, normalizing furnace carry out normalizing, 916 DEG C of normalizing temperature, soaking time: 2.0min/mm, come out of the stove it is air-cooled after obtain equipment furnace shell NR400ZL steel plate.
The present embodiment equipment furnace shell is shown in Table 2 with the mechanical property of NR400ZL steel plate.
The chemical component of 1 embodiment 1-8 equipment furnace shell NR400ZL steel plate of table forms
And its mass percentage (%)
Ingredient surplus is Fe and inevitable impurity in table 1.
The mechanical property of 2 equipment furnace shell NR400ZL steel plate of table
The above embodiments are only used to illustrate and not limit the technical solutions of the present invention, although referring to above-described embodiment to the present invention into Go detailed description, those skilled in the art should understand that: it can still modify to the present invention or equally replace It changes, without departing from the spirit or scope of the invention, or any substitutions, should all cover and be wanted in right of the invention It asks in range.

Claims (9)

1. a kind of production method of equipment furnace shell NR400ZL steel plate, which is characterized in that the production method includes steel-making, connects Casting, heating, rolling and heat treatment procedure;15~25 DEG C of the continuous casting degree of superheat, molding casting is used when continuous casting for the continuous casting working procedure, Stopper rod of tundish Argon and argon blowing sealing, argon pressure control are controlled in 0.2~0.4MPa, argon flow in 15~20L/ Min guarantees that continuous casting billet is made in liquid slag layer thickness after 10~15mm, continuous casting;The rolling process, using II type controlled rolling, The red temperature of steel plate is 650~750 DEG C.
2. a kind of production method of equipment furnace shell NR400ZL steel plate according to claim 1, which is characterized in that described Steel making working procedure, in convertor steelmaking process, baking temperature of steel ladle >=1000 DEG C, molten steel C >=0.06% when tapping, tapping temperature 1560 ~1600 DEG C, pre-deoxidation is carried out in big packet after tapping;It is good that Ar is blown in LF refining guarantee, and the white slag retention time is 25~35min, It skims sample aluminium content >=0.015%;VD refining terminates 5~10min of soft blow after vacuum.
3. a kind of production method of equipment furnace shell NR400ZL steel plate according to claim 1, which is characterized in that described Heating process, steel billet is in continuous stove heating, and 1260 DEG C of maximum heating temperature, 1240~1250 DEG C of soaking temperature.
4. a kind of production method of equipment furnace shell NR400ZL steel plate according to claim 1, which is characterized in that described Rolling process, I 1050~1150 DEG C of stage start rolling temperature, dry in the air steel thickness >=2H, and the H is finished steel plate thickness.
5. a kind of production method of equipment furnace shell NR400ZL steel plate according to claim 1, which is characterized in that described Rolling process, II stage start rolling temperature≤930 DEG C, 830~860 DEG C of finishing temperature.
6. a kind of production method of equipment furnace shell NR400ZL steel plate according to claim 1, which is characterized in that described Heat treatment procedure, using normalizing heat treatment technique, normalizing furnace carries out normalizing, and 900~930 DEG C of normalizing temperature, soaking time: 2.0 ~2.3min/mm, come out of the stove it is air-cooled after obtain equipment furnace shell NR400ZL steel plate.
7. production method of a kind of equipment furnace shell described in -6 any one with NR400ZL steel plate according to claim 1, feature It is, the steel plate thickness is 60~160mm.
8. production method of a kind of equipment furnace shell described in -6 any one with NR400ZL steel plate according to claim 1, feature It is, the steel plate yield strength >=320MPa, tensile strength >=420MPa, elongation percentage >=24%, 0 DEG C ballistic work >=60J, 350 DEG C high temperature tensile strength >=230MPa.
9. production method of a kind of equipment furnace shell described in -6 any one with NR400ZL steel plate according to claim 1, feature It is, the steel plate chemical component composition and its mass percentage are as follows: C:0.11~0.15%, Si:0.15~0.40%, Mn: 0.90~1.30%, P≤0.020%, S≤0.010%, Nb≤0.045%, V≤0.045%, Ti≤0.020%, Mo:0.20~ 0.40%, Alt:0.020~0.050%, surplus are Fe and inevitable impurity.
CN201910249103.4A 2019-03-29 2019-03-29 A kind of production method of equipment furnace shell NR400ZL steel plate Pending CN109957701A (en)

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