CN109810803A - A kind of antifreeze glass water and preparation method thereof - Google Patents
A kind of antifreeze glass water and preparation method thereof Download PDFInfo
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- CN109810803A CN109810803A CN201910249579.8A CN201910249579A CN109810803A CN 109810803 A CN109810803 A CN 109810803A CN 201910249579 A CN201910249579 A CN 201910249579A CN 109810803 A CN109810803 A CN 109810803A
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- Prior art keywords
- sodium
- acid
- polysorbate
- deionized water
- ethylene glycol
- Prior art date
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- 239000011521 glass Substances 0.000 title claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 230000002528 anti-freeze Effects 0.000 title claims abstract 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 46
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000008367 deionised water Substances 0.000 claims abstract description 19
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 19
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000001509 sodium citrate Substances 0.000 claims abstract description 16
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims abstract description 16
- -1 polyoxyethylene tridecyl ether sodium sulfate Polymers 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 229920001213 Polysorbate 20 Polymers 0.000 claims abstract description 13
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 claims abstract description 13
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 claims abstract description 13
- 229940068977 polysorbate 20 Drugs 0.000 claims abstract description 13
- 229930182478 glucoside Natural products 0.000 claims abstract description 10
- 229940073507 cocamidopropyl betaine Drugs 0.000 claims abstract 6
- 235000011187 glycerol Nutrition 0.000 claims abstract 6
- 229920001529 polyepoxysuccinic acid Polymers 0.000 claims abstract 6
- 229940057950 sodium laureth sulfate Drugs 0.000 claims abstract 5
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 claims abstract 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 48
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 10
- 239000011259 mixed solution Substances 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 4
- 229920000136 polysorbate Polymers 0.000 claims 4
- 229950008882 polysorbate Drugs 0.000 claims 4
- 229910052708 sodium Inorganic materials 0.000 claims 4
- 239000011734 sodium Substances 0.000 claims 4
- 238000005303 weighing Methods 0.000 claims 2
- OQUFOZNPBIIJTN-UHFFFAOYSA-N 2-hydroxypropane-1,2,3-tricarboxylic acid;sodium Chemical compound [Na].OC(=O)CC(O)(C(O)=O)CC(O)=O OQUFOZNPBIIJTN-UHFFFAOYSA-N 0.000 claims 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims 1
- 229910052938 sodium sulfate Inorganic materials 0.000 claims 1
- 235000011152 sodium sulphate Nutrition 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N EtOH Substances CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 3
- 229920001800 Shellac Polymers 0.000 abstract description 2
- 239000000428 dust Substances 0.000 abstract description 2
- 239000004208 shellac Substances 0.000 abstract description 2
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 abstract description 2
- 229940113147 shellac Drugs 0.000 abstract description 2
- 235000013874 shellac Nutrition 0.000 abstract description 2
- 238000005202 decontamination Methods 0.000 abstract 1
- 230000003588 decontaminative effect Effects 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 11
- DCEMCPAKSGRHCN-UHFFFAOYSA-N oxirane-2,3-dicarboxylic acid Chemical compound OC(=O)C1OC1C(O)=O DCEMCPAKSGRHCN-UHFFFAOYSA-N 0.000 description 11
- RRLOOYQHUHGIRJ-UHFFFAOYSA-M sodium;ethyl sulfate Chemical compound [Na+].CCOS([O-])(=O)=O RRLOOYQHUHGIRJ-UHFFFAOYSA-M 0.000 description 11
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 5
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 4
- 241000219095 Vitis Species 0.000 description 4
- 235000009754 Vitis X bourquina Nutrition 0.000 description 4
- 235000012333 Vitis X labruscana Nutrition 0.000 description 4
- 235000014787 Vitis vinifera Nutrition 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 150000008131 glucosides Chemical class 0.000 description 4
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 4
- 239000002904 solvent Substances 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000003158 alcohol group Chemical group 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
本发明公开了一种抗冻玻璃水及其制备方法，该抗冻玻璃水由以下质量百分比的原料制备而成：聚氧乙烯十三烷基醚硫酸钠4.8％～6.2％；聚山梨酯20 2.0％～5.0％；月桂醇聚醚硫酸酯钠7.0％～9.0％；甘油1.0％～3.0％；烷基葡萄糖苷3.0％～8.0％；椰油酰胺丙基甜菜碱1.0％～5.0％；乙二醇17.0％～21.0％；异硬脂酸0.5％～3.0％；聚环氧琥珀酸1.0％～2.0％；柠檬酸钠0.1％～0.8％；余量为去离子水。本发明的玻璃水去污能力强，可以快速有效去除玻璃上的虫胶、树胶、油污、灰尘等污渍，腐蚀性低，且具有优良的防冻性能。The invention discloses an antifreeze glass water and a preparation method thereof. The antifreeze glass water is prepared from the following raw materials by mass percentage: polyoxyethylene tridecyl ether sodium sulfate 4.8%-6.2%; polysorbate 20 2.0%～5.0%; Sodium Laureth Sulfate 7.0%～9.0%; Glycerin 1.0%～3.0%; Alkyl Glucoside 3.0%～8.0%; Cocamidopropyl Betaine 1.0%～5.0%; Ethanol Diol 17.0%-21.0%; Isostearic acid 0.5%-3.0%; Polyepoxysuccinic acid 1.0%-2.0%; Sodium citrate 0.1%-0.8%; The balance is deionized water. The glass water of the invention has strong decontamination ability, can quickly and effectively remove stains such as shellac, gum, oil, dust, etc. on the glass, has low corrosiveness, and has excellent antifreeze performance.
Description
Technical field
The present invention relates to Automobile Products fields, and in particular to a kind of freeze proof bath of glass and preparation method thereof.
Background technique
Bath of glass is most commonly seen, frequency of use highest on automobile, a kind of liquid for being easiest to supplement.It cooperates rain brush
Device is responsible for the cleaning of windshield.Presently commercially available bath of glass main component be solvent, antifreezing agent, detergent and other
Additive.Solvent: deionized water, methanol (or another name for) etc..Deionized water degree of purity is higher than distilled water, for making bath of glass
More it is suitble to.Methanol is preferable solvent, colourless, there is alcohol smell, volatile, but belongs to less toxic toxicity.Other additives: light
Bright dose, corrosion inhibiter, essence, pigment.Brightener improves glassy lustre degree, makes glass more thorough；Corrosion inhibiter can effectively be kept away
Exempt from bath of glass to corrode rubber pipeline, vehicle paint, metal parts；Essence, for covering unpleasant alcohol smell；Pigment, it is main to make
With being to allow bath of glass that color is presented, facilitate the liquid level in observation glass water pot.
In cold winter, the resistance to frost of bath of glass is particularly important, and when temperature is lower, part can be precipitated in bath of glass
Substance is sticked on glass sprinkler head, blocks glass sprinkler head, and the normal use for influencing bath of glass once freezes, bath of glass
It cannot gush out from jet blower, influence the cleaning of windshield, or even influence traffic safety.
In addition, needing repeatedly to spray could be dry by dirt cleaning currently, most cleaning capacity of existing bath of glass is limited
Only, the chemical component and in bath of glass easily causes the damages such as the burn into hardening to rubber pipeline, car body component.
Summary of the invention
To solve the above problems, that the present invention provides a kind of dirt-removing powers is strong, cleaning effect is good and with excellent freeze proof
The freeze proof bath of glass and preparation method thereof of property.
To achieve the above object, the technical scheme adopted by the invention is as follows:
A kind of freeze proof bath of glass, is prepared by the raw material of following mass percent:
Trideceth sulfate 4.8%~6.2%；Polysorbate 20 2.0%~5.0%；Laruyl alcohol is poly-
Ether sodium sulfovinate 7.0%~9.0%；Glycerol 1.0%~3.0%；Alkyl-glucoside 3.0%~8.0%；Cocamidopropyl propyl amide
Glycine betaine 1.0%~5.0%；Ethylene glycol 17.0%~21.0%；Isostearic acid 0.5%~3.0%；Poly-epoxy succinic acid
1.0%~2.0%；Sodium citrate 0.1%~0.8%；Surplus is deionized water.
Preferably, it is prepared by the raw material of following mass percent:
Trideceth sulfate 4.8%；Polysorbate 20 2.0%；Laureth sodium sulfovinate
7.0%；Glycerol 1.0%；Alkyl-glucoside 3.0%；Cocoamidopropyl betaine 1.0%；Ethylene glycol 17.0%%；It is different hard
Resin acid 0.5%；Poly-epoxy succinic acid 1.0%；Sodium citrate 0.1%；Surplus is deionized water.
Preferably, it is prepared by the raw material of following mass percent:
Trideceth sulfate 6.2%；Polysorbate 20 5.0%；Laureth sodium sulfovinate
9.0%；Glycerol 3.0%；Alkyl-glucoside 8.0%；Cocoamidopropyl betaine 5.0%；Ethylene glycol 21.0%；Different tristearin
Acid 3.0%；Poly-epoxy succinic acid 2.0%；Sodium citrate 0.8%；Surplus is deionized water.
Preferably, it is prepared by the raw material of following mass percent:
Trideceth sulfate 5.5%；Polysorbate 20 3.5%；Laureth sodium sulfovinate
8.0%；Glycerol 2%；Alkyl-glucoside 5.5%；Cocoamidopropyl betaine 3.0%；Ethylene glycol 19.0%；Isostearic acid
1.75%；Poly-epoxy succinic acid 1.5%；Sodium citrate 0.45%；Surplus is deionized water.
The present invention also provides a kind of above-mentioned preparation methods of freeze proof bath of glass, include the following steps:
S1, each raw material is weighed by above-mentioned formula；
S2, by weighed trideceth sulfate, laureth sodium sulfovinate, glycerol, alkyl grape
Glucosides, polysorbate 20, isostearic acid and ethylene glycol are placed in container after mixing, are heated to 45~50 DEG C, and stirring 15~
20min obtains closing solution A；
S3, weighed Cocoamidopropyl betaine is added in weighed deionized water, is heated to 60~70 DEG C, stirring
It is extremely transparent, poly-epoxy succinic acid, sodium citrate, mixed solution A are sequentially added, 50~60min is stirred, is uniformly mixed it, i.e.,
?.
Bath of glass dirt-removing power of the invention is strong, can quickly and effectively remove shellac, natural gum, greasy dirt, dust on glass
Etc. spots, corrosivity is low, and have excellent resistance to frost.
Specific embodiment
In order to which objects and advantages of the present invention are more clearly understood, the present invention is carried out with reference to embodiments further
It is described in detail.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to limit this hair
It is bright.
Embodiment 1
A kind of preparation method of freeze proof bath of glass, includes the following steps:
S1, each raw material is weighed by following mass percent:
Trideceth sulfate 4.8%；Polysorbate 20 2.0%；Laureth sodium sulfovinate
7.0%；Glycerol 1.0%；Alkyl-glucoside 3.0%；Cocoamidopropyl betaine 1.0%；Ethylene glycol 17.0%%；It is different hard
Resin acid 0.5%；Poly-epoxy succinic acid 1.0%；Sodium citrate 0.1%；Surplus is deionized water；
S2, by weighed trideceth sulfate, laureth sodium sulfovinate, glycerol, alkyl grape
Glucosides, polysorbate 20, isostearic acid and ethylene glycol are placed in container after mixing, are heated to 45~50 DEG C, and stirring 15~
20min obtains closing solution A；
S3, weighed Cocoamidopropyl betaine is added in weighed deionized water, is heated to 60~70 DEG C, stirring
It is extremely transparent, poly-epoxy succinic acid, sodium citrate, mixed solution A are sequentially added, 50~60min is stirred, is uniformly mixed it, i.e.,
?.
Embodiment 2
A kind of preparation method of freeze proof bath of glass, includes the following steps:
S1, each raw material is weighed by following mass percent:
Trideceth sulfate 6.2%；Polysorbate 20 5.0%；Laureth sodium sulfovinate
9.0%；Glycerol 3.0%；Alkyl-glucoside 8.0%；Cocoamidopropyl betaine 5.0%；Ethylene glycol 21.0%；Different tristearin
Acid 3.0%；Poly-epoxy succinic acid 2.0%；Sodium citrate 0.8%；Surplus is deionized water；
S2, by weighed trideceth sulfate, laureth sodium sulfovinate, glycerol, alkyl grape
Glucosides, polysorbate 20, isostearic acid and ethylene glycol are placed in container after mixing, are heated to 45~50 DEG C, and stirring 15~
20min obtains closing solution A；
S3, weighed Cocoamidopropyl betaine is added in weighed deionized water, is heated to 60~70 DEG C, stirring
It is extremely transparent, poly-epoxy succinic acid, sodium citrate, mixed solution A are sequentially added, 50~60min is stirred, is uniformly mixed it, i.e.,
?.
Embodiment 3
A kind of preparation method of freeze proof bath of glass, includes the following steps:
S1, each raw material is weighed by following mass percent:
Trideceth sulfate 5.5%；Polysorbate 20 3.5%；Laureth sodium sulfovinate
8.0%；Glycerol 2%；Alkyl-glucoside 5.5%；Cocoamidopropyl betaine 3.0%；Ethylene glycol 19.0%；Isostearic acid
1.75%；Poly-epoxy succinic acid 1.5%；Sodium citrate 0.45%；Surplus is deionized water；
S2, by weighed trideceth sulfate, laureth sodium sulfovinate, glycerol, alkyl grape
Glucosides, polysorbate 20, isostearic acid and ethylene glycol are placed in container after mixing, are heated to 45~50 DEG C, and stirring 15~
20min obtains closing solution A；
S3, weighed Cocoamidopropyl betaine is added in weighed deionized water, is heated to 60~70 DEG C, stirring
It is extremely transparent, poly-epoxy succinic acid, sodium citrate, mixed solution A are sequentially added, 50~60min is stirred, is uniformly mixed it, i.e.,
?.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the principle of the present invention, it can also make several improvements and retouch, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910249579.8A CN109810803A (en) | 2019-03-29 | 2019-03-29 | A kind of antifreeze glass water and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910249579.8A CN109810803A (en) | 2019-03-29 | 2019-03-29 | A kind of antifreeze glass water and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN109810803A true CN109810803A (en) | 2019-05-28 |
Family
ID=66610899
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| Application Number | Title | Priority Date | Filing Date |
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| CN201910249579.8A Pending CN109810803A (en) | 2019-03-29 | 2019-03-29 | A kind of antifreeze glass water and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110819472A (en) * | 2019-10-21 | 2020-02-21 | 黑龙江大学 | A kind of preparation method of antifreeze and environmental friendly degradable glass cleaner |
| WO2025109215A1 (en) | 2023-11-23 | 2025-05-30 | Unilever Ip Holdings B.V. | Cleaning composition |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101041793A (en) * | 2007-04-23 | 2007-09-26 | 北京交通大学 | Automobile windscreen cleaning agent |
| CN105132222A (en) * | 2015-08-25 | 2015-12-09 | 河北深思新材料技术有限公司 | Cleaning agent with low surface tension for automobile glass |
| CN105647671A (en) * | 2016-02-28 | 2016-06-08 | 宋德安 | Environment-friendly automobile windscreen washer fluid |
| CN107083234A (en) * | 2017-05-23 | 2017-08-22 | 句容耀皮节能玻璃科技发展有限公司 | A kind of automobile glass anti-fog antifreezing agent and preparation method thereof |
| CN108165386A (en) * | 2017-12-24 | 2018-06-15 | 洛阳名力科技开发有限公司 | A kind of highly effective plaque-removing bath of glass |
-
2019
- 2019-03-29 CN CN201910249579.8A patent/CN109810803A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101041793A (en) * | 2007-04-23 | 2007-09-26 | 北京交通大学 | Automobile windscreen cleaning agent |
| CN105132222A (en) * | 2015-08-25 | 2015-12-09 | 河北深思新材料技术有限公司 | Cleaning agent with low surface tension for automobile glass |
| CN105647671A (en) * | 2016-02-28 | 2016-06-08 | 宋德安 | Environment-friendly automobile windscreen washer fluid |
| CN107083234A (en) * | 2017-05-23 | 2017-08-22 | 句容耀皮节能玻璃科技发展有限公司 | A kind of automobile glass anti-fog antifreezing agent and preparation method thereof |
| CN108165386A (en) * | 2017-12-24 | 2018-06-15 | 洛阳名力科技开发有限公司 | A kind of highly effective plaque-removing bath of glass |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110819472A (en) * | 2019-10-21 | 2020-02-21 | 黑龙江大学 | A kind of preparation method of antifreeze and environmental friendly degradable glass cleaner |
| WO2025109215A1 (en) | 2023-11-23 | 2025-05-30 | Unilever Ip Holdings B.V. | Cleaning composition |
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Application publication date: 20190528 |