CN109810519A - Tire powder modified asphalt and preparation method thereof - Google Patents
Tire powder modified asphalt and preparation method thereof Download PDFInfo
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- CN109810519A CN109810519A CN201711156621.9A CN201711156621A CN109810519A CN 109810519 A CN109810519 A CN 109810519A CN 201711156621 A CN201711156621 A CN 201711156621A CN 109810519 A CN109810519 A CN 109810519A
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- parts
- powder
- tyre
- pitch
- catalyst
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- 239000000843 powder Substances 0.000 title claims abstract description 29
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000010426 asphalt Substances 0.000 title abstract description 12
- 150000001412 amines Chemical class 0.000 claims abstract description 20
- 239000003054 catalyst Substances 0.000 claims abstract description 20
- 239000011159 matrix material Substances 0.000 claims abstract description 19
- 239000005060 rubber Substances 0.000 claims abstract description 17
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 14
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 14
- 239000003381 stabilizer Substances 0.000 claims abstract description 9
- 239000000454 talc Substances 0.000 claims description 12
- 229910052623 talc Inorganic materials 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 239000012190 activator Substances 0.000 claims description 6
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical group C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 claims description 5
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical group C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 claims description 5
- 229910021626 Tin(II) chloride Inorganic materials 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 230000008929 regeneration Effects 0.000 claims description 5
- 238000011069 regeneration method Methods 0.000 claims description 5
- 230000006641 stabilisation Effects 0.000 claims description 5
- 238000011105 stabilization Methods 0.000 claims description 5
- 239000001119 stannous chloride Substances 0.000 claims description 5
- 235000011150 stannous chloride Nutrition 0.000 claims description 5
- 238000000034 method Methods 0.000 abstract description 9
- 230000008901 benefit Effects 0.000 abstract description 6
- 238000005265 energy consumption Methods 0.000 abstract description 4
- 238000004134 energy conservation Methods 0.000 abstract 1
- 239000011295 pitch Substances 0.000 description 41
- 239000010920 waste tyre Substances 0.000 description 15
- 238000004519 manufacturing process Methods 0.000 description 9
- 239000002699 waste material Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 206010007269 Carcinogenicity Diseases 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 231100000260 carcinogenicity Toxicity 0.000 description 1
- 230000007670 carcinogenicity Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000004630 mental health Effects 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses tire powder modified asphalt and a preparation method thereof, and the tire powder modified asphalt comprises, by weight, 50-70 parts of matrix asphalt, 20-30 parts of tire powder, 0.2-0.4 part of organic amine, 0.2-0.4 part of catalyst, 15-35 parts of rubber powder, 3-5 parts of thermoplastic resin, 10-14 parts of emulsifier and 3-5 parts of stabilizer. The invention has the advantages of simple process, low cost, low energy consumption, energy conservation and emission reduction.
Description
Technical field
The present invention relates to a kind of modified pitch, and in particular to a kind of tyre powder-modified pitch and preparation method thereof.
Background technique
Waste tire powder-modified asphalt is the dispersing agent using pitch as waste tire powder, by the waste tire powder of high dose
With matrix pitch it is miscible under the high temperature conditions made of a kind of modified pitch.The incorporation of waste tire powder improves the height of pitch
Warm nature energy, elastic property and anti-aging property improve the pavement performance index of pitch: for example can be improved road wearability and
Cold resistance, prolonging service life of pavement, and shorten brake distance.On the other hand, waste tire powder is largely used to highway work
Cheng Zhong can effectively solve the problems, such as extensive waste tire bring noxious waste pollution, can also reduce noise, and waste and old
Tyre powder-modified pitch is low in cost with respect to other modified pitch, can reduce cost of building the road, and has significant environmental benefit and society
It can economic benefit.
Complex process, the higher cost of existing waste tire powder-modified asphalt, energy consumption is very big, and production cost is expensive.
It is first to be dissolved waste tire powder with solvent, then doped matrix pitch is through height that waste tire powder-modified asphalt, which produces another technique,
Waste tire powder-modified asphalt is made in speed stirring shearing, this technique is a large amount of organic because using during preparing modified pitch
Solvent, and these dissolutions are mostly carcinogenicity toxic and volatile aromatic hydrocarbon substance, can largely be escaped in production, use, and work is damaged
People's physical and mental health pollution of ecological environment.
Therefore, there are complex process, higher cost, energy for the production method of waste tire powder-modified asphalt in the prior art
Consume very big, production cost is expensive, there are the evolution of pernicious gas, pollute air, result in waste of resources the shortcomings that.
Summary of the invention
The object of the present invention is to provide a kind of tyre powder-modified pitches and preparation method thereof.The invention has technique letter
Single, at low cost, the advantages of energy consumption is small, energy-saving and emission-reduction.
Technical solution of the present invention: a kind of tyre powder-modified pitch, according to poidometer, by 50~70 parts of matrix pitch, wheel
20~30 parts of tire powder, 0.2~0.4 part of organic amine, 0.2~0.4 part of catalyst, 15~35 parts of rubber powder, thermoplastic resin 3~5
Part, 10~14 parts of emulsifier, 3~5 parts of stabilizer compositions.
Tyre powder-modified pitch above-mentioned, according to poidometer, by 60 parts of matrix pitch, 25 parts of tyre talc, organic amine 0.3
Part, 0.3 part of catalyst, 20 parts of rubber powder, 4 parts of thermoplastic resin, 12 parts of emulsifier, 4 parts of stabilizer compositions.
Tyre powder-modified pitch above-mentioned and preparation method thereof, includes following steps:
A, tyre talc is added after mixing organic amine and catalyst according to the ratio of 1:1, stirred in blender 20~30min,
A product are made；
B, A product obtained are added in hybrid heater, the matrix pitch, thermoplastic resin and stabilization of above-mentioned poidometer is added
Agent continuously stirs 40~30min of heating, and the rubber powder and emulsifier for adding above-mentioned poidometer are mixed, it is heated to 160~
180 DEG C to get.
Tyre powder-modified pitch above-mentioned, the organic amine are diphenylguanidine.
Tyre powder-modified pitch above-mentioned, the catalyst are stannous chloride.
Tyre powder-modified pitch above-mentioned, the activator are regeneration softening oil.
Beneficial effects of the present invention: compared with prior art, the invention has the following advantages that
After the present invention is modified waste tire powder using organic amine, catalyst, activator, rubber powder can be increased and be uniformly dispersed
Property and interface binding power, the modified composite asphalt of waste tire powder obtained be substantially reduced relative to matrix pitch needle penetration, it is soft
Change point to improve, modified pitch has better stability and low-temperature cracking-resistance than matrix pitch, and storage stability significantly improves；By
It is low in production temperature, in production or work progress, it not will cause the evolution of toxic gas, it is environmentally protective；Waste tire powder
The production technology of modified pitch is substituted by simple pure stirring production technology, makes rubber powder under certain conditions by additive
It is directly thrown into the matrix pitch of thawing after surface-modified pretreatment, can sufficiently dissolve expansion merely through simple stirring
And rubber crumb modified asphalt is made, the process is realized without the strong external force factor such as high speed shear and colloid mill, thus
Greatly reduce the production cost of waste tire powder-modified asphalt.Therefore, the invention have simple process, at low cost, energy consumption is small,
The advantages of energy-saving and emission-reduction.
Specific embodiment
The embodiment of the present invention 1.
A kind of tyre powder-modified pitch, according to poidometer, by 50~70 parts of matrix pitch, 20~30 parts of tyre talc, organic
0.2~0.4 part of amine, 0.2~0.4 part of catalyst, 15~35 parts of rubber powder, 3~5 parts of thermoplastic resin, 10~14 parts of emulsifier,
3~5 parts of stabilizer compositions.
The tyre powder-modified pitch, according to poidometer, by 60 parts of matrix pitch, 25 parts of tyre talc, organic amine 0.3
Part, 0.3 part of catalyst, 20 parts of rubber powder, 4 parts of thermoplastic resin, 12 parts of emulsifier, 4 parts of stabilizer compositions.
Described tyre powder-modified pitch and preparation method thereof, includes following steps:
A, tyre talc is added after mixing organic amine and catalyst according to the ratio of 1:1, stirred in blender 20~30min,
A product are made；
B, A product obtained are added in hybrid heater, the matrix pitch, thermoplastic resin and stabilization of above-mentioned poidometer is added
Agent continuously stirs 40~30min of heating, and the rubber powder and emulsifier for adding above-mentioned poidometer are mixed, it is heated to 160~
180 DEG C to get.
The organic amine is diphenylguanidine.
The catalyst is stannous chloride.
The activator is regeneration softening oil.
The embodiment of the present invention 2.
A kind of tyre powder-modified pitch, according to poidometer, by 50 parts of matrix pitch, 20 parts of tyre talc, 0.2 part of organic amine,
0.2 part of catalyst, 15 parts of rubber powder, 3 parts of thermoplastic resin, 10 parts of emulsifier, 3 parts of stabilizer compositions.
Described tyre powder-modified pitch and preparation method thereof, includes following steps:
A, tyre talc is added after mixing organic amine and catalyst according to the ratio of 1:1, stirred in blender 20~30min,
A product are made；
B, A product obtained are added in hybrid heater, the matrix pitch, thermoplastic resin and stabilization of above-mentioned poidometer is added
Agent continuously stirs 40~30min of heating, and the rubber powder and emulsifier for adding above-mentioned poidometer are mixed, it is heated to 160~
180 DEG C to get.
The organic amine is diphenylguanidine.
The catalyst is stannous chloride.
The activator is regeneration softening oil.
The embodiment of the present invention 3.
A kind of tyre powder-modified pitch, according to poidometer, by 70 parts of matrix pitch, 30 parts of tyre talc, 0.4 part of organic amine,
0.4 part of catalyst, 35 parts of rubber powder, 5 parts of thermoplastic resin, 14 parts of emulsifier, 5 parts of stabilizer compositions.
Described tyre powder-modified pitch and preparation method thereof, includes following steps:
A, tyre talc is added after mixing organic amine and catalyst according to the ratio of 1:1, stirred in blender 20~30min,
A product are made；
B, A product obtained are added in hybrid heater, the matrix pitch, thermoplastic resin and stabilization of above-mentioned poidometer is added
Agent continuously stirs 40~30min of heating, and the rubber powder and emulsifier for adding above-mentioned poidometer are mixed, it is heated to 160~
180 DEG C to get.
The organic amine is diphenylguanidine.
The catalyst is stannous chloride.
The activator is regeneration softening oil.
Claims (6)
1. a kind of tyre powder-modified pitch, it is characterised in that: according to poidometer, by 50~70 parts of matrix pitch, tyre talc 20~
30 parts, 0.2~0.4 part of organic amine, 0.2~0.4 part of catalyst, 15~35 parts of rubber powder, 3~5 parts of thermoplastic resin, emulsifier
10~14 parts, 3~5 parts of stabilizer compositions.
2. tyre powder-modified pitch according to claim 1, it is characterised in that: according to poidometer, by 60 parts of matrix pitch,
25 parts of tyre talc, 0.3 part of organic amine, 0.3 part of catalyst, 20 parts of rubber powder, 4 parts of thermoplastic resin, 12 parts of emulsifier, stabilizer
4 parts of compositions.
3. a kind of tyre powder-modified pitch as claimed in claim 1 or 2 and preparation method thereof, it is characterised in that: include with
Lower step:
A, tyre talc is added after mixing organic amine and catalyst according to the ratio of 1:1, stirred in blender 20~30min,
A product are made；
B, A product obtained are added in hybrid heater, the matrix pitch, thermoplastic resin and stabilization of above-mentioned poidometer is added
Agent continuously stirs 40~30min of heating, and the rubber powder and emulsifier for adding above-mentioned poidometer are mixed, it is heated to 160~
180 DEG C to get.
4. tyre powder-modified pitch according to claim 1 or 2, it is characterised in that: the organic amine is diphenylguanidine.
5. tyre powder-modified pitch according to claim 1 or 2, it is characterised in that: the catalyst is stannous chloride.
6. tyre powder-modified pitch according to claim 1 or 2, it is characterised in that: the activator is regeneration softening oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711156621.9A CN109810519A (en) | 2017-11-20 | 2017-11-20 | Tire powder modified asphalt and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711156621.9A CN109810519A (en) | 2017-11-20 | 2017-11-20 | Tire powder modified asphalt and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109810519A true CN109810519A (en) | 2019-05-28 |
Family
ID=66598509
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711156621.9A Pending CN109810519A (en) | 2017-11-20 | 2017-11-20 | Tire powder modified asphalt and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109810519A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102448907A (en) * | 2009-09-07 | 2012-05-09 | 许政道 | Temperature-adjusted and modified recycled ascon composition for reusing 100% of waste ascon for road pavement, and method for manufacturing same |
| CN105295398A (en) * | 2015-10-10 | 2016-02-03 | 广东石油化工学院 | Low-viscosity rubber asphalt |
| CN105419359A (en) * | 2015-12-22 | 2016-03-23 | 福建省泉州市公路局 | Waste tyre powder modified asphalt and preparation method therefor |
-
2017
- 2017-11-20 CN CN201711156621.9A patent/CN109810519A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102448907A (en) * | 2009-09-07 | 2012-05-09 | 许政道 | Temperature-adjusted and modified recycled ascon composition for reusing 100% of waste ascon for road pavement, and method for manufacturing same |
| CN105295398A (en) * | 2015-10-10 | 2016-02-03 | 广东石油化工学院 | Low-viscosity rubber asphalt |
| CN105419359A (en) * | 2015-12-22 | 2016-03-23 | 福建省泉州市公路局 | Waste tyre powder modified asphalt and preparation method therefor |
Non-Patent Citations (2)
| Title |
|---|
| 刘尚乐: "《乳化沥青及其在道路、建筑工程中的应用》", 31 July 2008, 中国建材工业出版社 * |
| 姚佳良 等: "《公路工程复合材料及其应用》", 31 July 2015, 湖南大学出版社 * |
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190528 |
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