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CN109786593A - It rechargeable battery and its manufacturing method - Google Patents

It rechargeable battery and its manufacturing method Download PDF

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Publication number
CN109786593A
CN109786593A CN201711113239.XA CN201711113239A CN109786593A CN 109786593 A CN109786593 A CN 109786593A CN 201711113239 A CN201711113239 A CN 201711113239A CN 109786593 A CN109786593 A CN 109786593A
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Prior art keywords
battery
sealing ring
negative
rechargeable battery
collecting body
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CN201711113239.XA
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CN109786593B (en
Inventor
叶敏华
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Chung Pak Guangdong Battery Industrial Co ltd
CHUNG PAK INVESTMENT Ltd
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Chung Pak Guangdong Battery Industrial Co ltd
CHUNG PAK INVESTMENT Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Connection Of Batteries Or Terminals (AREA)
  • Sealing Battery Cases Or Jackets (AREA)
  • Secondary Cells (AREA)

Abstract

The present invention provides one kind rechargeable battery comprising: negative can has three-level hierarchic structure, first order ladder, second level ladder and the third level ladder successively to successively decrease from end including internal diameter in side wall;Plus plate current-collecting body, the plus plate current-collecting body are nested in the negative can;And sealing ring, the sealing ring, which is arranged between the side wall of the negative can and the side wall of the plus plate current-collecting body and is isolated the negative can and the plus plate current-collecting body, makes it not contact and short circuit occurs;Wherein the second level ladder of the sealing ring and the negative can fits closely, and forms the sealing of battery;The ends curved inwards of the first order ladder and be bonded with the sealing ring, formed sealing position;And the lower part of the sealing ring is resisted against on the interconnecting piece between the second level ladder and third level ladder, to be supported.The present invention also provides a kind of methods that manufactures and rechargeable battery.

Description

可充电的电池及其制造方法Rechargeable battery and method of making the same

技术领域technical field

本发明涉及小型电池领域,更具体地,涉及一种可充电的电池及其制造方法。The present invention relates to the field of small batteries, and more particularly, to a rechargeable battery and a manufacturing method thereof.

背景技术Background technique

目前的小型可充电电池有很多类型。以常用的锂离子电池为例,其外壳通常采用柱状罐体。罐体材料是铁镀镍或不锈钢。There are many types of small rechargeable batteries available today. Taking a common lithium-ion battery as an example, its outer casing is usually a cylindrical tank. Tank material is iron nickel plated or stainless steel.

图1是根据现有技术制造的小型可充电的锂离子电池的截面图。可充电锂离子电池一般通过以下方式制造:1 is a cross-sectional view of a small rechargeable lithium-ion battery fabricated according to the prior art. Rechargeable lithium-ion batteries are generally manufactured by:

将正、负极片按要求裁切后,端部分别点焊上正极极耳106和负极极耳103。在正负极片中间加放隔膜,通过卷绕将加放有隔膜的正负极片卷成电芯卷包102。在罐体底部(即,负极端子1023)放入下绝缘片104,并将电芯卷包102装入罐体中。通过点焊将负极极耳103连接至罐体的侧壁。在罐体口部下方约1~3mm(例如,3mm)处滚压一圈,以形成约宽0.8~2.5mm(例如,2mm)、深0.5~1.5mm(例如,1mm)的沿径向方向向内突出的槽,并将上绝缘片105置于槽下方、电芯卷包102上方。然后,将包括外接触片(用作顶帽的正极端子1020)、内接触片(正极铝帽1022)以及密封圈108在内的正极集流体放入罐体内。正极集流体由槽的突出部支撑住。外接触片材料为镀镍铁片,内接触片为铝片,密封圈材料为PP(聚丙烯)或其他塑料材料。之后,将包裹有正极胶纸1021的正极极耳106穿过上绝缘片105,并与正极集流体点焊连接。After cutting the positive and negative electrodes as required, the ends are spot welded with the positive tabs 106 and the negative tabs 103 respectively. A separator is placed between the positive and negative electrode sheets, and the positive and negative electrode sheets with the separator added and placed are rolled into a battery pack 102 by winding. The lower insulating sheet 104 is placed at the bottom of the can body (ie, the negative terminal 1023 ), and the cell wrap 102 is loaded into the can body. The negative tab 103 is attached to the side wall of the can body by spot welding. Roll a circle at about 1-3mm (eg, 3mm) below the mouth of the can to form a radial direction with a width of about 0.8-2.5mm (eg, 2mm) and a depth of 0.5-1.5mm (eg, 1mm). The inwardly protruding groove is placed, and the upper insulating sheet 105 is placed under the groove and above the cell wrap 102 . Then, the positive current collector including the outer contact piece (positive terminal 1020 serving as the top cap), the inner contact piece (positive aluminum cap 1022 ), and the sealing ring 108 is put into the can. The positive current collector is supported by the protrusions of the groove. The outer contact sheet material is nickel-plated iron sheet, the inner contact sheet is aluminum sheet, and the sealing ring material is PP (polypropylene) or other plastic materials. After that, the positive electrode tab 106 wrapped with the positive electrode tape 1021 is passed through the upper insulating sheet 105 and connected to the positive electrode current collector by spot welding.

点焊正极集流体后,将整个电池置于85℃的烘箱内烘烤24~36小时。冷却后在相对湿度1%以下的环境中加入电解液。然后,将正极集流体从罐体口部插入,与罐体组合。用封口机模具将罐体口部折弯,完成电池的封口。After spot welding the positive current collector, the entire battery was placed in an oven at 85°C for 24 to 36 hours. After cooling, add electrolyte in an environment with a relative humidity of 1% or less. Then, the positive electrode current collector was inserted through the mouth of the can body and combined with the can body. Bend the mouth of the can body with a sealing machine mold to complete the sealing of the battery.

上述锂离子电池的优势在于装配技术比较成熟,比较容易操作。但是,由图1的结构可见,正极集流体所占空间较大,因而电池整体空间较小,造成电池容量也偏小。The advantage of the above-mentioned lithium-ion battery is that the assembly technology is relatively mature and it is relatively easy to operate. However, as can be seen from the structure of FIG. 1 , the space occupied by the positive electrode current collector is large, so the overall space of the battery is small, resulting in a small battery capacity.

此外,锂离子电池在过度充放电时,电池内部可能会产生大量气体。当气体达到一定的气压时,气体会冲破正极封口或负极罐体,产生爆炸现象。一般体积较大的锂离子电池会在正极集流体设置防爆装置,但小型的锂离子电池,由于正极集流体太小,不能设置防爆装置。因此,小型锂离子电池在充放电过程中很有可能会产生爆炸,因而安全方面存有隐患。In addition, when the lithium-ion battery is overcharged and discharged, a large amount of gas may be generated inside the battery. When the gas reaches a certain pressure, the gas will break through the positive seal or the negative tank, resulting in an explosion. Generally, an explosion-proof device is installed on the positive electrode current collector for a larger lithium-ion battery, but for a small lithium-ion battery, an explosion-proof device cannot be installed because the positive electrode current collector is too small. Therefore, small lithium-ion batteries are likely to explode during charging and discharging, so there are hidden dangers in terms of safety.

因此,本领域需要一种能有效利用空间、最大化发挥电池容量并避免充放电过程中爆炸的可充电电池以及制造方法。Therefore, there is a need in the art for a rechargeable battery and a manufacturing method that can effectively utilize space, maximize battery capacity, and avoid explosion during charging and discharging.

发明内容SUMMARY OF THE INVENTION

本发明的目的之一在于提供一种能够有效利用空间、最大化发挥电池容量的小型可充电电池及其制造方法。额外地,本发明的进一步的目的在于提供一种能够有效利用空间、最大化发挥电池容量并避免充放电过程中爆炸的小型可充电电池及其制造方法。One of the objects of the present invention is to provide a small rechargeable battery capable of effectively utilizing space and maximizing battery capacity, and a manufacturing method thereof. Additionally, a further object of the present invention is to provide a small rechargeable battery and a manufacturing method thereof that can effectively utilize space, maximize battery capacity, and avoid explosion during charging and discharging.

根据本发明的一个方面,提供了一种可充电的电池,其包括:负极罐体,其在口部具有三级阶梯结构,从末端起包括内径依次递减的第一级阶梯、第二级阶梯和第三级阶梯;正极集流体,所述正极集流体嵌套在所述负极罐体内;和密封圈,所述密封圈设置在所述负极罐体的口部和所述正极集流体的口部之间并隔离所述负极罐体和所述正极集流体使其不接触而发生短路;其中所述密封圈与所述负极罐体的第二级阶梯紧密贴合,形成电池的密封部;所述第一级阶梯的端部向内弯曲而与所述密封圈贴合,形成封口位;并且所述密封圈的下部抵靠在所述第二级阶梯和第三级阶梯之间的连接部上,从而获得支撑。According to one aspect of the present invention, there is provided a rechargeable battery, which includes: a negative electrode can body, which has a three-level stepped structure at the mouth, and includes a first-level ladder and a second-level ladder with decreasing inner diameters from the end. and the third step; a positive electrode current collector, the positive electrode current collector is nested in the negative electrode tank; and a sealing ring, the sealing ring is provided at the mouth of the negative electrode tank body and the mouth of the positive electrode current collector between the parts and isolate the negative electrode can body and the positive electrode current collector so that they do not contact and cause a short circuit; wherein the sealing ring is closely attached to the second step of the negative electrode can body to form a sealing part of the battery; The end of the first step is bent inward to fit with the sealing ring to form a sealing position; and the lower part of the sealing ring abuts against the connection between the second step and the third step on the top for support.

优选地,所述负极罐体在所述第一级阶梯的侧壁上具有至少一个孔。Preferably, the negative electrode can body has at least one hole on the side wall of the first step.

优选地,所述密封圈具有U形凹槽,所述正极集流体的口部容纳在该U形凹槽内。优选地,所述密封圈的材料为绝缘可压缩材料。Preferably, the sealing ring has a U-shaped groove, and the mouth of the positive electrode current collector is accommodated in the U-shaped groove. Preferably, the material of the sealing ring is an insulating compressible material.

优选地,所述正极集流体具有倒扣的杯状结构,所述杯状结构的口部的直径等于或大于所述杯状结构的底部的直径。Preferably, the positive electrode current collector has an inverted cup-shaped structure, and the diameter of the mouth of the cup-shaped structure is equal to or greater than the diameter of the bottom of the cup-shaped structure.

优选地,所述电池还包括由正极片、负极片以及正极片和负极片之间的分隔机构卷绕而成的电芯卷包。Preferably, the battery further includes a battery core wrap formed by a positive electrode sheet, a negative electrode sheet, and a separation mechanism between the positive electrode sheet and the negative electrode sheet.

优选地,从正极片末端延伸出正极极耳,其与所述正极集流体连接;并且从所述负极片末端延伸出负极极耳,其与所述负极罐体连接。Preferably, a positive electrode tab is extended from the end of the positive electrode sheet, which is connected with the positive electrode current collector; and a negative electrode tab is extended from the end of the negative electrode sheet, which is connected with the negative electrode can body.

优选地,所述电池还包括置于所述电芯卷包上方的上绝缘片和所述电芯卷包下方的下绝缘片。Preferably, the battery further includes an upper insulating sheet placed above the cell wrap and a lower insulating sheet below the cell wrap.

优选地,当所述正极集流体向上移动时,与所述正极集流体连接的正极极耳断裂。Preferably, when the positive electrode current collector moves upward, the positive electrode tab connected to the positive electrode current collector is broken.

优选地,所述电池为柱状电池,例如圆柱状。Preferably, the battery is a cylindrical battery, such as cylindrical.

优选地,所述电池为锂离子电池,更优选柱状锂离子电池。Preferably, the battery is a lithium ion battery, more preferably a cylindrical lithium ion battery.

根据本发明的另一个方面,提供了一种制造本发明所述的可充电的电池的方法。According to another aspect of the present invention, there is provided a method of manufacturing the rechargeable battery of the present invention.

附图说明Description of drawings

下面将结合附图及实施例对本发明作进一步说明,附图中:The present invention will be further described below in conjunction with the accompanying drawings and embodiments, in which:

图1是根据现有技术制造的小型可充电锂离子电池的截面图;以及1 is a cross-sectional view of a small rechargeable lithium-ion battery fabricated in accordance with the prior art; and

图2是根据本发明的一个实施例的可充电锂离子电池的截面图。2 is a cross-sectional view of a rechargeable lithium-ion battery according to one embodiment of the present invention.

具体实施方式Detailed ways

以下说明是本发明的典型实施方式,其并不旨在以任何方式限制本发明的范围或适用范围。相反,下列说明旨在提供用于实施本发明的各种实施方式的示例。The following description is of typical embodiments of the invention and is not intended to limit the scope or applicability of the invention in any way. Rather, the following description is intended to provide examples of various embodiments for implementing the invention.

在下文中,以小型柱状可充电锂离子电池为例来具体说明本发明的构思及概念。但如本领域技术人员所意识,本发明的可充电电池并不限于小型锂离子电池,也不限于柱状结构,其他本领域中常用的电池结构(例如,纽扣状结构)和材料均可适用。Hereinafter, the idea and concept of the present invention will be described in detail by taking a small cylindrical rechargeable lithium-ion battery as an example. However, as appreciated by those skilled in the art, the rechargeable battery of the present invention is not limited to small lithium-ion batteries, nor is it limited to columnar structures, and other battery structures (eg, button-like structures) and materials commonly used in the art are applicable.

本发明的小型锂离子电池包括负极罐体,其内部被配置来容纳正负极片卷包(即电芯卷包)。正负极片卷包包括正极片和负极片,两者中间用隔膜隔离。用隔膜隔离的正负极片被卷绕成柱状卷包,然后可用胶纸包扎。从正极极片末端延伸出正极极耳,其与正极集流体连接。从负极极片末端延伸出负极极耳,其与罐身连接。正负极片卷包还可以设置有上绝缘片和下绝缘片。The small lithium-ion battery of the present invention includes a negative electrode can body, the interior of which is configured to accommodate positive and negative electrode sheet wraps (ie, cell wraps). The positive and negative electrode sheet roll package includes a positive electrode sheet and a negative electrode sheet, and the two are separated by a separator. The positive and negative electrode sheets separated by the separator are wound into a cylindrical roll, which can then be wrapped with adhesive tape. A positive tab extends from the end of the positive pole piece, which is connected with the positive current collector. A negative electrode lug extends from the end of the negative electrode pole piece, which is connected with the can body. The positive and negative electrode sheet rolls can also be provided with an upper insulating sheet and a lower insulating sheet.

如图2所示,在一个优选的实施方式中,本发明的负极罐体1在其口部具有三级阶梯,从末端起包括内径依次递减的第一级阶梯9、第二级阶梯10和第三级阶梯11。例如,第二级阶梯10的内径可以比第一级阶梯9小约0.05~0.20mm,而比第三级阶梯11大约0.05~0.20mm。优选地,第二级阶梯10的内径可以为约3~18mm,取决于电池的尺寸。第二级阶梯10和第三级阶梯11之间连接部可在安装电池时用来支撑密封圈8的底部。As shown in FIG. 2, in a preferred embodiment, the negative electrode can body 1 of the present invention has three steps at its mouth, including a first step 9, a second step 10 and The third step is 11. For example, the inner diameter of the second step 10 may be smaller than that of the first step 9 by about 0.05-0.20 mm, and smaller than that of the third step 11 by about 0.05-0.20 mm. Preferably, the inner diameter of the second step 10 may be about 3˜18 mm, depending on the size of the battery. The connecting portion between the second step 10 and the third step 11 can be used to support the bottom of the sealing ring 8 when the battery is installed.

由于第二级阶梯10向内压紧密封圈8,已保证了负极罐体1与正极流体7之间的良好密封,因此,第一级阶梯9与密封圈之间可以有间隙并且该间隙中可以无需填充胶水。当然,为了进一步加强密封,也可以在该间隙中填充密封胶水。Since the second step 10 presses the sealing ring 8 inward, a good seal between the negative electrode tank 1 and the positive electrode fluid 7 has been ensured. Therefore, there may be a gap between the first step 9 and the sealing ring, and there may be a gap in the gap. Can be filled without glue. Of course, in order to further strengthen the sealing, sealing glue can also be filled in the gap.

在一个进一步优选的实施方式中,在第一级阶梯9可具有至少一个孔,该孔穿过负极罐体1。在一个方面,可在第一级阶梯9设置2~6个孔,优选4个。优选地,多个孔是周向对称的。在一个方面,孔直径可以为0.10~0.8mm。孔可以呈圆形、长方形、正方形、棱形或不规则形状,优选不规则形状。In a further preferred embodiment, the first step 9 may have at least one hole, the hole passing through the negative electrode can body 1 . In one aspect, 2 to 6 holes, preferably 4 holes, may be provided in the first step 9 . Preferably, the plurality of holes are circumferentially symmetrical. In one aspect, the hole diameter may be 0.10-0.8 mm. The holes may be circular, rectangular, square, prismatic or irregular in shape, preferably irregular.

负极罐体1的厚度可以为约0.10~0.30mm,材料可以是铁镀镍或不锈钢。The thickness of the negative electrode can body 1 can be about 0.10-0.30 mm, and the material can be iron plated with nickel or stainless steel.

在一个实施方式中,正极集流体7可以为倒扣杯状,其杯口部直径可等于或大于杯底部直径,优选大于杯底部直径,例如大出来约0.05~0.30mm,优选约0.10~0.15mm。正极集流体的材料可以为铁镀镍或不锈钢,而厚度可以为约0.1~0.35mm。In one embodiment, the positive electrode current collector 7 can be in the shape of an inverted cup, and the diameter of the mouth of the cup can be equal to or larger than the diameter of the bottom of the cup, preferably larger than the diameter of the bottom of the cup, for example, about 0.05-0.30 mm larger, preferably about 0.10-0.15 mm. mm. The material of the positive electrode current collector may be iron nickel-plated or stainless steel, and the thickness may be about 0.1-0.35 mm.

在正极集流体7的侧壁与负极罐体1的口部之间可设有密封圈8,以起到密封电池的作用并且防止负极罐体1与正极顶盖7接触而导致的短路。优选地,密封圈8为带有U型凹槽的环状结构。优选地,密封圈8的材料是可压缩的。A sealing ring 8 may be provided between the side wall of the positive electrode current collector 7 and the mouth of the negative electrode can body 1 to seal the battery and prevent short circuit caused by the contact between the negative electrode can body 1 and the positive electrode top cover 7 . Preferably, the sealing ring 8 is an annular structure with a U-shaped groove. Preferably, the material of the sealing ring 8 is compressible.

更加具体地,在一个实施方式中,密封圈8可具有U型凹槽,厚度可以为约0.05~0.30mm,优选为约0.08~0.20mm。杯口部可被套入密封圈8的U型凹槽中。密封圈8的内表面可紧贴正极集流体7的杯口部外表面。密封圈8的外径最好与负极罐体1的第二级阶梯10的内径基本相同,例如,密封圈8的外径与负极罐体1的第二级阶梯10相同或小0.01~0.03mm,最大不超过0.10mm,否则将影响电池的密封性能。密封圈材料可以是聚丙烯(PP)或聚醚醚酮(PEEK),也可以是其它可以使用的弹性绝缘材料。More specifically, in one embodiment, the sealing ring 8 may have a U-shaped groove, and the thickness may be about 0.05-0.30 mm, preferably about 0.08-0.20 mm. The mouth of the cup can be inserted into the U-shaped groove of the sealing ring 8 . The inner surface of the sealing ring 8 can be in close contact with the outer surface of the cup mouth of the positive electrode current collector 7 . The outer diameter of the sealing ring 8 is preferably substantially the same as the inner diameter of the second step 10 of the negative electrode can body 1. For example, the outer diameter of the sealing ring 8 is the same as or 0.01-0.03 mm smaller than the second step 10 of the negative electrode can body 1 , the maximum does not exceed 0.10mm, otherwise it will affect the sealing performance of the battery. The sealing ring material can be polypropylene (PP) or polyetheretherketone (PEEK), or other elastic insulating materials that can be used.

密封圈8在与正极集流体7组合前,可以在其凹槽处涂环氧树脂或其他胶水,使两者紧密结合。Before the sealing ring 8 is combined with the positive electrode current collector 7, epoxy resin or other glue can be applied to the groove of the sealing ring 8, so that the two are tightly combined.

电池在添加电解质后进行组装时,正极集流体7从负极罐体1的口部插入,并例如通过从上部加压,使得与正极集流体7组合的密封圈8与负极罐体1第二级阶梯紧密贴合,形成电池的主要密封部。密封圈8下部抵靠在第二级阶梯10和第三级阶梯11之间的连接部上,从而获得支撑。When the battery is assembled after adding the electrolyte, the positive electrode current collector 7 is inserted from the mouth of the negative electrode can body 1, and, for example, by pressurizing from above, the sealing ring 8 combined with the positive electrode current collector 7 is connected to the second stage of the negative electrode can body 1. The steps fit snugly and form the primary seal of the battery. The lower part of the sealing ring 8 abuts on the connecting part between the second step 10 and the third step 11 to obtain support.

然后用封口机模具将第一级阶梯9收窄,使其第一级阶梯9的末端向内弯曲,与密封圈8贴合,形成封口位。此时,负极罐体1的第二级阶梯10同样会受到来自径向的力向内拉伸,压缩密封圈8,从而使密封圈8与罐壁更加紧贴,密封性更好。如此组装后,密封圈8被压缩,其压缩后的厚度为原始厚度的10%~90%之间,尤其在30%~70%之间,特别优选为约50%,从而起到良好的密封效果。Then, the first step 9 is narrowed with a sealing machine mold, so that the end of the first step 9 is bent inward, and is fitted with the sealing ring 8 to form a sealing position. At this time, the second step 10 of the negative electrode can body 1 will also be stretched inward by the force from the radial direction, compressing the sealing ring 8, so that the sealing ring 8 and the can wall are more closely attached, and the sealing performance is better. After being assembled in this way, the sealing ring 8 is compressed, and its compressed thickness is between 10% and 90% of the original thickness, especially between 30% and 70%, particularly preferably about 50%, so as to provide a good seal Effect.

用上述结构制成的锂离子电池与相同体积的传统结构锂离子电池相比,内体积至少可增加大约10~12%或甚至更高,因此,在不增加电池尺寸的情况下容量得到大幅度提高。Compared with the conventional structure lithium ion battery of the same volume, the lithium ion battery made with the above structure can increase the inner volume by at least about 10-12% or even higher, so the capacity can be greatly improved without increasing the battery size improve.

此外,用上述结构制成的锂离子电池还在提高电池容量的同时使得电池更加安全可靠。当在过度充放电时电池内部所产生的气体将正极集流体往上推,正极集流体会脱离负极罐体的第二级阶梯,当到达第一级阶梯时,杯口部会被第一级阶梯所形成的封口位卡住,并且气体会从第一级阶梯的气孔泻出,从而消除电池因气压过大而爆炸的危险。此外,由于第一级阶梯与密封圈8之间的缝隙的存在并且通常不添加胶水,将孔设置于第一级阶梯可防止胶水堵塞孔,并且所存在的缝隙也使得内部气压首先得到初步释放。In addition, the lithium ion battery made with the above structure can improve the battery capacity and make the battery more safe and reliable. When the gas generated inside the battery pushes up the positive electrode current collector during overcharge and discharge, the positive electrode current collector will be separated from the second step of the negative electrode tank. When the first step is reached, the mouth of the cup will be blocked by the first step. The resulting seal gets stuck, and gas escapes from the air holes of the first step, eliminating the risk of the battery exploding due to excess air pressure. In addition, due to the existence of the gap between the first step and the sealing ring 8 and usually no glue is added, arranging the hole on the first step can prevent the glue from blocking the hole, and the existing gap also allows the internal air pressure to be initially released first .

另外,为了避免电池的过度充放电,也可以在正极集流体向上移动时,使与正极集流体连接的正极极耳或与负极罐体连接的负极极耳断裂。举例来说,可以在正极集流体和正极极耳之间设置撕裂部(例如,撕裂线结构),其当正极集流体向外移动预定距离时断裂,从而切断正极极耳与正极集流体的连接,避免产生更多气体而导致电池爆炸。In addition, in order to avoid overcharging and discharging of the battery, when the positive electrode current collector moves upward, the positive electrode tab connected to the positive electrode current collector or the negative electrode tab connected to the negative electrode can is broken. For example, a tear portion (eg, a tear line structure) can be provided between the positive electrode current collector and the positive electrode tab, which breaks when the positive electrode current collector moves outward a predetermined distance, thereby cutting the positive electrode tab and the positive electrode current collector. connection to avoid generating more gas and causing the battery to explode.

下文进一步结合图2更详细地描述本发明。图2是根据本发明的一个示例性实施例的可充电锂离子电池的截面图。如图2中所示,可充电的锂离子电池包括负极外壳、正极顶盖和绝缘密封圈。The present invention is described in more detail further below in conjunction with FIG. 2 . 2 is a cross-sectional view of a rechargeable lithium-ion battery according to an exemplary embodiment of the present invention. As shown in FIG. 2, a rechargeable lithium-ion battery includes a negative electrode casing, a positive electrode cap, and an insulating seal.

实施例1Example 1

负极外壳为一柱状罐体,即,负极罐体1。负极罐体1的材质为不锈钢,其厚度为0.15mm,高度为24mm。可以通过例如冲床制成如图2所示的负极罐体1。在负极罐体1的口部具有一个三级阶梯结构,包括内径依次递减的第一级阶梯9、第二级阶梯10和第三集阶梯11。第二级阶梯10的内径比第一级阶梯9小0.15mm,而比第三阶梯11大0.20mm。第二级阶梯10的内径为10mm,并且内壁涂有封口胶水。负极罐体1的口部的侧壁上还具有至少一个气孔16。在该实施例中,气孔16的数量为四个并且对称设置。气孔16的直径为0.5mm。The negative electrode shell is a cylindrical can body, that is, the negative electrode can body 1 . The negative electrode can body 1 is made of stainless steel with a thickness of 0.15 mm and a height of 24 mm. The negative electrode can body 1 as shown in FIG. 2 can be formed by, for example, a punching machine. The mouth of the negative electrode can body 1 has a three-stage ladder structure, including a first-stage ladder 9 , a second-stage ladder 10 and a third-stage ladder 11 whose inner diameters decrease in sequence. The inner diameter of the second step 10 is smaller than that of the first step 9 by 0.15 mm, and is larger than that of the third step 11 by 0.20 mm. The inner diameter of the second step 10 is 10mm, and the inner wall is coated with sealing glue. The side wall of the mouth of the negative electrode can body 1 also has at least one air hole 16 . In this embodiment, the air holes 16 are four in number and symmetrically arranged. The diameter of the air hole 16 is 0.5 mm.

将正极片13、负极片14按要求裁切,分别点焊至正极极耳6和负极极耳3。正极片和负极片中间加放隔膜15。将正负极片卷绕成柱状卷包2,并用胶纸包扎。卷包2的高度为电池总高减去正负极集流体7和两个绝缘片的厚度,并留出约0.5~1mm的空间。The positive electrode sheet 13 and the negative electrode sheet 14 are cut as required, and spot welded to the positive electrode tab 6 and the negative electrode tab 3 respectively. A separator 15 is placed between the positive electrode sheet and the negative electrode sheet. Wind the positive and negative electrode sheets into a cylindrical wrap 2 and wrap them with adhesive tape. The height of the roll package 2 is the total height of the battery minus the thickness of the positive and negative electrode current collectors 7 and the two insulating sheets, and a space of about 0.5-1 mm is left.

先在负极罐体1的内底部放入下绝缘片4,然后放入卷包2。将负极极耳3与罐身焊接。在卷包2上部放置上绝缘片5,而正极极耳6穿过上绝缘片5,与正极集流体7焊接。First put the lower insulating sheet 4 on the inner bottom of the negative electrode can body 1 , and then put the roll pack 2 . Weld the negative electrode tab 3 to the can body. An upper insulating sheet 5 is placed on the upper part of the roll package 2 , and the positive electrode tabs 6 pass through the upper insulating sheet 5 and are welded with the positive electrode current collector 7 .

正极集流体7具有倒杯状结构,其杯口部外径比杯底部外径大0.15mm,并且其材料为不锈钢,厚度为0.15m。The positive electrode current collector 7 has an inverted cup-shaped structure, the outer diameter of the mouth of the cup is 0.15 mm larger than the outer diameter of the bottom of the cup, and the material is stainless steel with a thickness of 0.15 m.

将正极集流体7杯口部套入密封圈8。密封圈8为一个带有U型凹槽的环状,材料为PP。在与正极集流体7组合前,在其凹槽处涂密封胶水12,使两者紧密结合。密封圈8的厚度为0.15mm,并且其外径与负极罐体1的第二级阶梯10的内径相同或者小0.02mm。Put the mouth of the positive electrode current collector 7 into the sealing ring 8 . The sealing ring 8 is an annular shape with a U-shaped groove, and the material is PP. Before being combined with the positive electrode current collector 7, a sealing glue 12 is applied to the groove to make the two tightly combined. The thickness of the sealing ring 8 is 0.15 mm, and its outer diameter is the same as or 0.02 mm smaller than the inner diameter of the second step 10 of the negative electrode can body 1 .

点焊正极集流体7后,将整个电池置于85℃的烘箱内烘烤24~36小时。冷却后在相对湿度1%以下的环境中加入电解液。然后将正极集流体7从负极罐体1的口部插入,与负极罐体1组合,然后从上部加压,使密封圈8与负极罐体1的第二级阶梯10紧密贴合,并抵靠在负极罐体1的第二级阶梯和第三级阶梯11之间的连接托位。然后用封口机模具将第一级阶梯9向内收窄,使罐体第一级阶梯9的口部向内弯曲至与密封圈8贴合,并进一步挤压密封圈8。After spot welding the positive electrode current collector 7, the entire battery is placed in an oven at 85°C for 24-36 hours. After cooling, add electrolyte in an environment with a relative humidity of 1% or less. Then, the positive electrode current collector 7 is inserted from the mouth of the negative electrode can body 1, combined with the negative electrode can body 1, and then pressurized from the upper part, so that the sealing ring 8 is closely attached to the second step 10 of the negative electrode can body 1, and is pressed against the negative electrode can body 1. Rely on the connection between the second step and the third step 11 of the negative electrode can body 1 . Then, the first step 9 is narrowed inward by a sealing machine mold, so that the mouth of the first step 9 of the can body is bent inward to fit the sealing ring 8, and the sealing ring 8 is further squeezed.

实施例2Example 2

负极外壳为一柱状罐体,即,负极罐体1。负极罐体1的材质为不锈钢,其厚度为0.15mm,高度为24mm。可以通过例如冲床制成如图2所示的负极罐体1。在负极罐体1的口部具有一个三级阶梯结构,包括内径依次递减的第一级阶梯9、第二级阶梯10和第三集阶梯11。第二级阶梯10的内径比第一级阶梯9小0.15mm,而比第三阶梯11大0.20mm。第二级阶梯10的内径为10mm,并且内壁涂有封口胶水。负极罐体1的口部的侧壁上还具有至少一个气孔16。在该实施例中,气孔16的数量为四个并且对称设置。气孔16的直径为0.5mm。The negative electrode shell is a cylindrical can body, that is, the negative electrode can body 1 . The negative electrode can body 1 is made of stainless steel with a thickness of 0.15 mm and a height of 24 mm. The negative electrode can body 1 as shown in FIG. 2 can be formed by, for example, a punching machine. The mouth of the negative electrode can body 1 has a three-stage ladder structure, including a first-stage ladder 9 , a second-stage ladder 10 and a third-stage ladder 11 whose inner diameters decrease in sequence. The inner diameter of the second step 10 is smaller than that of the first step 9 by 0.15 mm, and is larger than that of the third step 11 by 0.20 mm. The inner diameter of the second step 10 is 10mm, and the inner wall is coated with sealing glue. The side wall of the mouth of the negative electrode can body 1 also has at least one air hole 16 . In this embodiment, the air holes 16 are four in number and symmetrically arranged. The diameter of the air hole 16 is 0.5 mm.

将正极片13、负极片14按要求裁切,分别点焊至正极极耳6和负极极耳3。正极片和负极片中间加放隔膜15。将正负极片卷绕成柱状卷包2,并用胶纸包扎。卷包2的高度为电池总高减去正负极集流体7和两个绝缘片的厚度,并留出约0.5~1mm的空间。The positive electrode sheet 13 and the negative electrode sheet 14 are cut as required, and spot welded to the positive electrode tab 6 and the negative electrode tab 3 respectively. A separator 15 is placed between the positive electrode sheet and the negative electrode sheet. Wind the positive and negative electrode sheets into a cylindrical wrap 2 and wrap them with adhesive tape. The height of the roll package 2 is the total height of the battery minus the thickness of the positive and negative electrode current collectors 7 and the two insulating sheets, and a space of about 0.5-1 mm is left.

先在负极罐体1的内底部放入下绝缘片4,然后放入卷包2。将负极极耳3与罐身焊接。在卷包2上部放置上绝缘片5,而正极极耳6穿过上绝缘片5,与正极集流体7焊接。First put the lower insulating sheet 4 on the inner bottom of the negative electrode can body 1 , and then put the roll pack 2 . Weld the negative electrode tab 3 to the can body. An upper insulating sheet 5 is placed on the upper part of the roll package 2 , and the positive electrode tabs 6 pass through the upper insulating sheet 5 and are welded with the positive electrode current collector 7 .

正极集流体7具有倒杯状结构,其杯口部外径比杯底部外径大0.15mm,并且其材料为不锈钢,厚度为0.15m。The positive electrode current collector 7 has an inverted cup-shaped structure, the outer diameter of the mouth of the cup is 0.15 mm larger than the outer diameter of the bottom of the cup, and the material is stainless steel with a thickness of 0.15 m.

将正极集流体7杯口部套入密封圈8。密封圈8为一个带有U型凹槽的环状,材料为聚醚醚酮PEEK。由于在密封圈与正极集流体7组合前为管状,先将其套在正极集流体7的口部,然后用热风使其向内弯曲收缩,形成U型凹槽,并与正极集流体7紧密结合。密封圈8的厚度为0.08mm,并且其外径与负极罐体1的第二级阶梯10的内径相同或小0.02mm。Put the mouth of the positive electrode current collector 7 into the sealing ring 8 . The sealing ring 8 is a ring with a U-shaped groove, and the material is polyetheretherketone PEEK. Since the sealing ring is tubular before it is combined with the positive electrode current collector 7 , it is first sleeved on the mouth of the positive electrode current collector 7 , and then bent and contracted inward with hot air to form a U-shaped groove, which is tightly connected with the positive electrode current collector 7 combine. The thickness of the sealing ring 8 is 0.08 mm, and its outer diameter is the same as or 0.02 mm smaller than the inner diameter of the second step 10 of the negative electrode can body 1 .

点焊正极集流体7后,将整个电池置于85℃的烘箱内烘烤24~36小时。冷却后在相对湿度1%以下的环境中加入电解液。然后将正极集流体7从负极罐体1的口部插入,与负极罐体1组合,然后从上部加压,使密封圈8与负极罐体1的第二级阶梯10紧密贴合,并抵靠在负极罐体1的第二级阶梯和第三级阶梯11之间的连接托位。然后用封口机模具将第一级阶梯9向内收窄,使罐体第一级阶梯9的口部向内弯曲至与密封圈8贴合,并进一步挤压密封圈8。After spot welding the positive electrode current collector 7, the entire battery is placed in an oven at 85°C for 24-36 hours. After cooling, add electrolyte in an environment with a relative humidity of 1% or less. Then, the positive electrode current collector 7 is inserted from the mouth of the negative electrode can body 1, combined with the negative electrode can body 1, and then pressurized from the upper part, so that the sealing ring 8 is closely attached to the second step 10 of the negative electrode can body 1, and is pressed against the negative electrode can body 1. Rely on the connection between the second step and the third step 11 of the negative electrode can body 1 . Then, the first step 9 is narrowed inward by a sealing machine mold, so that the mouth of the first step 9 of the can body is bent inward to fit the sealing ring 8, and the sealing ring 8 is further squeezed.

比较实施例(现有结构)Comparative Example (Existing Structure)

图1为现用传统方法制造的一个小型锂离子电池的截面图。Figure 1 is a cross-sectional view of a small lithium-ion battery that is currently fabricated by conventional methods.

电池负极罐体是一个柱状罐体,罐体材料是0.15mm的不锈钢片,罐体直径为10mm,高度为24mm。The negative electrode tank of the battery is a cylindrical tank, the tank material is a 0.15mm stainless steel sheet, the tank diameter is 10mm, and the height is 24mm.

将正、负极片按要求裁切后,端部分别点焊上正极极耳106和负极极耳103。在正负极片中间加放隔膜,通过卷绕将加放有隔膜的正负极片卷成电芯卷包102。在罐体底部(即,负极端子1023)放入下绝缘片104,并将电芯卷包102装入罐体中。通过点焊将负极极耳103连接至罐体的侧壁。After cutting the positive and negative electrodes as required, the ends are spot welded with the positive tabs 106 and the negative tabs 103 respectively. A separator is placed between the positive and negative electrode sheets, and the positive and negative electrode sheets with the separator added and placed are rolled into a battery pack 102 by winding. The lower insulating sheet 104 is placed at the bottom of the can body (ie, the negative terminal 1023 ), and the cell wrap 102 is loaded into the can body. The negative tab 103 is attached to the side wall of the can body by spot welding.

在罐体口部下方约3mm处滚压一圈约宽2mm、深1mm的槽,然后将上绝缘片105下方、电芯卷包102上方。正极极耳穿过上绝缘片105与正极集流体7点焊连接。Roll a groove with a width of about 2mm and a depth of 1mm at about 3mm below the mouth of the can body, and then wrap the bottom of the upper insulating sheet 105 and the top of the cell 102 . The positive electrode tabs are connected to the positive electrode current collector 7 by spot welding through the upper insulating sheet 105 .

正极集流体7包括外接触片1020和内接触片1022,以及密封圈108。外接触片的材料为镀镍铁片,内接触片为铝片,密封圈材料为PP。将包括外接触片(用作顶帽的正极端子1020)、内接触片(正极铝帽1022)以及密封圈108在内的正极集流体放入罐体内。正极集流体由槽的突出部支撑住。外接触片材料为镀镍铁片,内接触片为铝片,密封圈材料为PP(聚丙烯)或其他塑料材料。之后,将包裹有正极胶纸1021的正极极耳106穿过上绝缘片105,并与正极集流体点焊连接。The positive electrode current collector 7 includes an outer contact piece 1020 and an inner contact piece 1022 , and a sealing ring 108 . The material of the outer contact sheet is nickel-plated iron sheet, the inner contact sheet is aluminum sheet, and the material of the sealing ring is PP. The positive current collector including the outer contact piece (positive terminal 1020 serving as the top cap), the inner contact piece (positive aluminum cap 1022), and the sealing ring 108 is placed into the can. The positive current collector is supported by the protrusions of the groove. The outer contact sheet material is nickel-plated iron sheet, the inner contact sheet is aluminum sheet, and the sealing ring material is PP (polypropylene) or other plastic materials. After that, the positive electrode tab 106 wrapped with the positive electrode tape 1021 is passed through the upper insulating sheet 105 and connected to the positive electrode current collector by spot welding.

点焊正极集流体后,将整个电池置于85℃的烘箱内烘烤24~36小时。冷却后在相对湿度1%以下的环境中加入电解液。然后,将正极集流体从罐体口部插入,与罐体组合。用封口机模具将罐体口部折弯,完成电池的封口。After spot welding the positive current collector, the entire battery was placed in an oven at 85°C for 24 to 36 hours. After cooling, add electrolyte in an environment with a relative humidity of 1% or less. Then, the positive electrode current collector was inserted through the mouth of the can body and combined with the can body. Bend the mouth of the can body with a sealing machine mold to complete the sealing of the battery.

结果比较Results comparison

从上述实施例1和实施例2制成的小型锂离子电池(图2)和比较实施例(现有结构)制成的小型锂离子电池(图1)的比较可以看出,两者的体积基本相同,但实施例1-2的电池内部空间相比于比较例明显更大,增加约10~12%。换言之,在相同的外部体积下,本发明的电池的电池内部空间要比传统结构的电池大约大10~12%。相应地,在材料和配方不变的情况下,电池容量可以提高10~12%。It can be seen from the comparison of the small lithium ion batteries ( FIG. 2 ) made in the above-mentioned examples 1 and 2 and the small lithium ion batteries ( FIG. 1 ) made in the comparative example (existing structure) that the volume of the two Basically the same, but the internal space of the battery of Example 1-2 is significantly larger than that of the comparative example, an increase of about 10-12%. In other words, under the same external volume, the internal space of the battery of the present invention is about 10-12% larger than that of the battery of the conventional structure. Correspondingly, the battery capacity can be increased by 10-12% under the condition of unchanged materials and formulations.

此外,用上述结构制成的锂离子电池还在提高电池容量的同时使得电池更加安全可靠。当在过度充放电时电池内部所产生的气体将正极集流体往上推,正极集流体会脱离负极罐体的第二级阶梯,当到达第一级阶梯时,杯口部会被第一级阶梯所形成的封口位卡住,并且气体会从第一级阶梯的气孔泻出,从而消除电池因气压过大而爆炸的危险。In addition, the lithium ion battery made with the above structure can improve the battery capacity and make the battery more safe and reliable. When the gas generated inside the battery pushes up the positive electrode current collector during overcharge and discharge, the positive electrode current collector will be separated from the second step of the negative electrode tank. When the first step is reached, the mouth of the cup will be blocked by the first step. The resulting seal gets stuck, and gas escapes from the air holes of the first step, eliminating the risk of the battery exploding due to excess air pressure.

虽然本发明通过具体实施例进行说明,但是所属领域技术人员应当理解,在不脱离本发明范围的情况下,还可以对本发明进行各种变换及等同替代。另外,针对特定情形或应用需求,可以对本发明做各种修改或替换,而不脱离本发明的范围。因此,本发明并不局限于所公开的具体实施例,而应当包括落入本发明权利要求范围内的全部实施方式。Although the present invention is described through specific embodiments, those skilled in the art should understand that various changes and equivalent substitutions can be made to the present invention without departing from the scope of the present invention. In addition, various modifications or substitutions may be made to the present invention for specific situations or application requirements without departing from the scope of the present invention. Therefore, the inventions are not to be limited to the specific embodiments disclosed, but are to include all embodiments falling within the scope of the claims of this invention.

Claims (12)

1. one kind rechargeable battery, which is characterized in that described rechargeable battery include:
Negative can has three-level hierarchic structure, the first order rank successively successively decreased from oral area end including internal diameter in oral area Ladder, second level ladder and third level ladder;
Plus plate current-collecting body, the plus plate current-collecting body are nested in the negative can;With
Sealing ring, the sealing ring are arranged between the oral area of the negative can and the oral area of the plus plate current-collecting body and are isolated The negative can and the plus plate current-collecting body make it not contact and short circuit occurs;
Wherein the second level ladder of the sealing ring and the negative can fits closely, and forms the sealing of battery;
The ends curved inwards of the first order ladder and be bonded with the sealing ring, formed sealing position;
And the lower part of the sealing ring is resisted against on the interconnecting piece between the second level ladder and third level ladder, to obtain It must support.
2. according to claim 1 rechargeable battery, which is characterized in that the negative can is in the first order ladder Side wall on have at least one hole.
3. according to claim 1 or 2 rechargeable battery, which is characterized in that the sealing ring has U-shaped groove, institute The oral area for stating plus plate current-collecting body is contained in the U-shaped groove.
4. according to claim 1 or 2 rechargeable battery, which is characterized in that the material of the sealing ring is that insulation can Compression material.
5. according to claim 1 or 2 rechargeable battery, which is characterized in that the plus plate current-collecting body has back-off Cup-like structure, the diameter of the oral area of the cup-like structure are equal to or more than the diameter of the bottom of the cup-like structure.
6. according to claim 1 or 2 rechargeable battery, which is characterized in that the battery further includes by positive plate, bears Core coil packet made of partition winding between pole piece and positive plate and negative electrode tab.
7. according to claim 6 rechargeable battery, which is characterized in that extend positive pole ear from positive plate end, It connect with the plus plate current-collecting body;And extends negative lug from the negative electrode tab end, connect with the negative can It connects.
8. according to claim 7 rechargeable battery, which is characterized in that the battery further includes being placed in the core coil Lower insulating trip below the upper insulating trip for the side of wrapping and the core coil packet.
9. according to claim 7 rechargeable battery, which is characterized in that when the plus plate current-collecting body moves up, The positive pole ear fracture being connect with the plus plate current-collecting body.
10. according to claim 1 rechargeable battery, which is characterized in that the battery is column battery.
11. according to claim 1 rechargeable battery, which is characterized in that the battery is lithium ion battery.
12. a kind of manufacture the method that rechargeable battery described in any one of -11 according to claim 1.
CN201711113239.XA 2017-11-10 2017-11-10 Rechargeable battery and method of making the same Active CN109786593B (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE821559A (en) * 1973-10-29 1975-04-28 ELECTRICAL POWER SUPPLY INCLUDING A BOX AND A DRY BATTERY
CN1753233A (en) * 2004-09-24 2006-03-29 株式会社东芝 Non-aqueous electrolyte battery
JP2010218909A (en) * 2009-03-17 2010-09-30 Hitachi Maxell Ltd Gasket for flat battery, and flat battery using the same
JP2011204623A (en) * 2010-03-26 2011-10-13 Hitachi Maxell Energy Ltd Sealed battery
CN103262296A (en) * 2010-10-16 2013-08-21 瓦尔达微电池有限责任公司 Button cell having bursting protection
CN104919617A (en) * 2012-11-09 2015-09-16 瓦尔达微电池有限责任公司 Button battery with electrode coil
CN207353315U (en) * 2017-11-10 2018-05-11 松栢投资有限公司 rechargeable battery

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE821559A (en) * 1973-10-29 1975-04-28 ELECTRICAL POWER SUPPLY INCLUDING A BOX AND A DRY BATTERY
CN1753233A (en) * 2004-09-24 2006-03-29 株式会社东芝 Non-aqueous electrolyte battery
JP2010218909A (en) * 2009-03-17 2010-09-30 Hitachi Maxell Ltd Gasket for flat battery, and flat battery using the same
JP2011204623A (en) * 2010-03-26 2011-10-13 Hitachi Maxell Energy Ltd Sealed battery
CN103262296A (en) * 2010-10-16 2013-08-21 瓦尔达微电池有限责任公司 Button cell having bursting protection
CN104919617A (en) * 2012-11-09 2015-09-16 瓦尔达微电池有限责任公司 Button battery with electrode coil
CN207353315U (en) * 2017-11-10 2018-05-11 松栢投资有限公司 rechargeable battery

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