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CN1097559C - Vaporizing and concentration drying apparatus and method - Google Patents

Vaporizing and concentration drying apparatus and method Download PDF

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Publication number
CN1097559C
CN1097559C CN94194698A CN94194698A CN1097559C CN 1097559 C CN1097559 C CN 1097559C CN 94194698 A CN94194698 A CN 94194698A CN 94194698 A CN94194698 A CN 94194698A CN 1097559 C CN1097559 C CN 1097559C
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steam
evaporator
vapor
heat
wet material
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CN1142810A (en
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辛根
李大成
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Pu Longyi
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Pu Longyi
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/28Evaporating with vapour compression
    • B01D1/284Special features relating to the compressed vapour
    • B01D1/2846The compressed vapour is not directed to the same apparatus from which the vapour was taken off
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/0011Heating features
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D3/00Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/02Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in boilers or stills
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D5/00Condensation of vapours; Recovering volatile solvents by condensation
    • B01D5/0057Condensation of vapours; Recovering volatile solvents by condensation in combination with other processes
    • B01D5/006Condensation of vapours; Recovering volatile solvents by condensation in combination with other processes with evaporation or distillation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D5/00Condensation of vapours; Recovering volatile solvents by condensation
    • B01D5/0057Condensation of vapours; Recovering volatile solvents by condensation in combination with other processes
    • B01D5/0075Condensation of vapours; Recovering volatile solvents by condensation in combination with other processes with heat exchanging
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D5/00Condensation of vapours; Recovering volatile solvents by condensation
    • B01D5/0078Condensation of vapours; Recovering volatile solvents by condensation characterised by auxiliary systems or arrangements
    • B01D5/009Collecting, removing and/or treatment of the condensate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D5/00Condensation of vapours; Recovering volatile solvents by condensation
    • B01D5/0078Condensation of vapours; Recovering volatile solvents by condensation characterised by auxiliary systems or arrangements
    • B01D5/0096Cleaning
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/048Purification of waste water by evaporation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/40Valorisation of by-products of wastewater, sewage or sludge processing

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)
  • Drying Of Solid Materials (AREA)
  • Treatment Of Sludge (AREA)

Abstract

Vaporizing and concentration drying apparatus and method are disclosed. The apparatus and method prepare good quality of condensed water and save evaporation energy and are wide used in making contamined waste water become distilled water and in purification of the waste water and in concentration and drying of varieties of environmental polluting sludge. The apparatus and method recover and reuse the heating energy, which energy was applied to the vapor so as to heat the vapor to a high temperature and to remove the environmental polluting impurities, such as odor, B.O.D. and C.O.D. laden in the vapor, so that the apparatus and method remarkably save the cost for the heating energy. The apparatus saves the energy by 2 to 10 times in comparison with the conventional apparatus.

Description

蒸发和浓缩干燥设备与方法Evaporation and concentration drying equipment and method

技术领域technical field

本发明一般地涉及蒸发和浓缩干燥设备与方法,特别是一项这种设备与方法方面的改进,用于通过在某一高温下液化来回收和重新利用汽化热量,亦即出现在增压或减压蒸发过程中的潜热,以致节省加热能量,并且用于在某一高温下氧化或碳化蒸发的各种杂质,诸如充满在蒸发中的气味、B.O.D.和C.O.D.,以便除掉蒸发的各种杂质并提供良好品质的冷凝水。This invention relates generally to evaporation and concentration drying apparatus and methods, and in particular to an improvement in such apparatus and methods for recovering and reusing the heat of vaporization by liquefaction at an elevated temperature, i.e. Latent heat in the decompression evaporation process, so as to save heating energy, and is used to oxidize or carbonize various impurities evaporated at a certain high temperature, such as odors, B.O.D. and C.O.D. filled in evaporation, so as to remove various impurities evaporated And provide good quality condensate.

背景技术Background technique

在传统的蒸发设备中,用于汽凝蒸气的冷却水必须与蒸发所需的热量,亦即沸腾热量(100Kcal)和汽化热量(蒸发潜热,539Kcal/1)一起加于设备。在使用上述蒸发设备通过蒸发和浓缩诸如湿泥浆或废水等湿料制备蒸馏水的情况下,一部分环境污染杂质,诸如充满在湿料中的气味、B.O.D.和C.O.D.,与蒸气一起蒸发,从而充斥在蒸气中。充斥在蒸气中的各种杂质本身又在冷凝蒸气时与蒸气一起被液化。蒸馏水因而不能达到允许的标准水质,以致蒸馏水需要进行再处理,以便达到允许的标准质量。In traditional evaporation equipment, the cooling water used for condensing steam must be added to the equipment together with the heat required for evaporation, that is, the heat of boiling (100Kcal) and the heat of vaporization (latent heat of evaporation, 539Kcal/1). In the case of producing distilled water by evaporating and concentrating wet materials such as wet mud or waste water using the above-mentioned evaporation equipment, a part of environmental pollution impurities such as odors, B.O.D. middle. Various impurities in the steam are liquefied together with the steam when the steam is condensed. The distilled water thus does not meet the permissible standard water quality, so that the distilled water needs to be reprocessed in order to achieve the permissible standard quality.

一般的蒸发设备以及一般的蒸发方法不能回收和重新利用蒸气的蒸发潜热(539Kcal/l),而是通过一用于冷却和冷凝充斥各种杂质的蒸气的汽凝系统中把潜热废弃了。其次,潜热的这种废弃必定是与大量成本相伴的。General evaporation equipment and general evaporation methods cannot recover and reuse the latent heat of evaporation (539Kcal/l) of steam, but waste the latent heat through a condensation system for cooling and condensing steam full of various impurities. Secondly, this waste of latent heat is necessarily accompanied by substantial costs.

此外,一般的蒸发设备或一般的蒸发方法不能除掉各种杂质,诸如气味、B.O.D.和C.O.D.,这些杂质与蒸气一起蒸发和液化而降低了蒸馏水的质量。就此而论,蒸馏水必须经过一另外的水净化过程予以处理以便改进蒸馏水的质量。用于改进蒸馏水质量的另外的水净化过程是很复杂的并提高了制备蒸馏水的成本。In addition, general evaporation equipment or general evaporation methods cannot remove various impurities such as odor, B.O.D. and C.O.D., which are evaporated and liquefied together with steam to reduce the quality of distilled water. As such, distilled water must be treated through an additional water purification process in order to improve the quality of the distilled water. Additional water purification processes to improve distilled water quality are complex and increase the cost of producing distilled water.

在使用一降压蒸发方法使水蒸发成为蒸汽时,汽化热量可以通过对应于某一真空度的降低压力的大小而得以节省。不过,这种降压蒸发方法仍存在一个难题,即冷凝水充满气味、B.O.D.和C.O.D.,从而冷凝水需要通过另外的脱臭和净水过程而予以处理。When using a reduced-pressure evaporation method to evaporate water into steam, the heat of vaporization can be saved by reducing the pressure corresponding to a certain degree of vacuum. However, this reduced pressure evaporation method still has a problem that the condensed water is full of odor, B.O.D. and C.O.D., so that the condensed water needs to be treated through additional deodorization and water purification processes.

在一般的加热蒸发设备中,在大气压下蒸发一升零度(0℃)的水所需的总热量是639Kcal。亦即,使水在100℃沸腾的沸腾热量是100Kcal,而用于蒸发沸腾水的汽化热量是539Kcal,从而用于蒸发一升水的总热量是639Kcal,亦即,100Kcal+539Kcal=639Kcal。在使用降压蒸发器蒸发1升零度(0℃)的水时,在真空度是大约10Torr(750mmHg)的条件下水在35℃时沸腾,以致用于蒸发1升水的总热量是605Kcal,即35Kcal+570Kcal=605Kcal(在蒸发压力是0.1Kg/cm2。A时,潜热可以是大约570Kcal)。In general heating evaporation equipment, the total heat required to evaporate one liter of zero-degree (0°C) water at atmospheric pressure is 639Kcal. That is, the boiling heat for boiling water at 100°C is 100Kcal, and the vaporization heat for evaporating boiling water is 539Kcal, so the total heat for evaporating one liter of water is 639Kcal, that is, 100Kcal+539Kcal=639Kcal. When using a decompression evaporator to evaporate 1 liter of zero-degree (0°C) water, the water boils at 35°C under a vacuum of about 10 Torr (750mmHg), so that the total heat used to evaporate 1 liter of water is 605Kcal, which is 35Kcal +570Kcal=605Kcal (when the evaporation pressure is 0.1Kg/cm 2 .A, the latent heat can be about 570Kcal).

不过,一般的蒸发设备必须使用一部汽凝器以冷凝和液化蒸气,以致大量用于汽凝的冷却水必须加于设备。其次,蒸气的潜热(539Kcal)不能回收和重新使用,而是废弃掉了。However, general evaporation equipment must use a condenser to condense and liquefy the vapor, so that a large amount of cooling water for condensation must be added to the equipment. Secondly, the latent heat of steam (539Kcal) cannot be recovered and reused, but discarded.

已经简略说明过,在使用或者是一般的降压蒸发方法或者是一般的加热蒸发方法在大气压下蒸发一升零度(0℃)的水时,有待施用于水的总热量是574Kcal或639Kcal。其次,用于向冷凝器提供冷却水的额外能量必须加于设备。在冷凝蒸气的过程中,蒸发潜热(539Kcal)不能回收而废弃掉了。此外,一般的蒸发设备本身不能从冷凝水中除掉各种环境污染杂质,诸如气味、B.O.D.和C.O.D.,以致冷凝水需要通过另外的脱臭和净水过程予以处理。It has been briefly stated that the total heat to be applied to water is 574Kcal or 639Kcal when evaporating one liter of zero degree (0°C) water at atmospheric pressure using either the general reduced pressure evaporation method or the general heating evaporation method. Second, additional energy for supplying cooling water to the condenser must be added to the equipment. In the process of condensing steam, the latent heat of evaporation (539Kcal) cannot be recovered and is discarded. In addition, general evaporation equipment itself cannot remove various environmental pollutants such as odor, B.O.D., and C.O.D. from condensed water, so that condensed water needs to be treated through additional deodorization and water purification processes.

发明内容Contents of the invention

因而,本发明的目的是提供一种蒸发和浓缩干燥设备与方法,其中,以上各种问题得以克服并可提供优质冷凝水和节省汽化能量,以便通过重新利用在增压或减压蒸发过程中所出现的潜能而节省加热能量,并可广泛地用于使污染废水成为蒸馏水、净化废水和浓缩干燥各种各样的环境污染泥浆。Therefore, the object of the present invention is to provide a kind of evaporation and concentration drying equipment and method, wherein, the above various problems are overcome and can provide high-quality condensed water and save vaporization energy, so that by reusing The emerging potential saves heating energy, and can be widely used to make polluted wastewater into distilled water, purify wastewater, and concentrate and dry various environmental pollution muds.

本发明的设备和方法可回收和重新利用加热能量,这种能量被施用于蒸气以便把蒸气加热到某一高温进行氧化或碳化,并除掉充满在蒸气中的各种环境污染杂质,诸如气味、B.O.D.和C.O.D.等,从而本设备和方法可显著地节约用于加热能量的成本。The apparatus and method of the present invention can recover and reuse heating energy, which is applied to the steam so as to heat the steam to a certain high temperature for oxidation or carbonization, and remove various environmental pollutants filled in the steam, such as odor , B.O.D. and C.O.D., etc., so that the device and method can significantly save the cost of heating energy.

本发明与传统的设备相比,可降低蒸发设备的生产成本和设备的操作成本,从而为用户提供了经济效益。与传统的设备相比本发明设备还可节省能量2至10倍。在本发明的设备中,充斥在蒸气中的气味和各种杂质在蒸气加热至某一高温时可被氧化和碳化并从蒸气中完全除掉,以致本设备可提供优质蒸馏水而勿需使用另外的水净化装置。Compared with the traditional equipment, the invention can reduce the production cost of the evaporation equipment and the operation cost of the equipment, thereby providing economic benefits for users. Compared with traditional equipment, the equipment of the present invention can also save energy by 2 to 10 times. In the equipment of the present invention, the odor and various impurities in the steam can be oxidized and carbonized and completely removed from the steam when the steam is heated to a high temperature, so that the equipment can provide high-quality distilled water without using another water purification device.

附图说明Description of drawings

本发明以上和其他各项目的、特点和其他各项优点通过以下结合各附图所作的详细说明将会得到更为清晰的了解,其中The above and other objects, features and other advantages of the present invention will be more clearly understood through the following detailed descriptions made in conjunction with the accompanying drawings, wherein

图1是本发明一优选实施例的蒸发和浓缩干燥设备的局部剖视图;Fig. 1 is a partial sectional view of evaporation and concentration drying equipment of a preferred embodiment of the present invention;

图2是图1设备的一热量回收装置的透视图,表明此装置的内部结构;Fig. 2 is the perspective view of a heat recovery device of Fig. 1 equipment, shows the internal structure of this device;

图3是图2热量回收装置的局部剖前视图,表明此装置中逆流高温蒸气与正流低温蒸气之间的热交换状态:Fig. 3 is a partial cut-away front view of the heat recovery device in Fig. 2, showing the heat exchange state between the counter-current high-temperature steam and the forward-flow low-temperature steam in this device:

图4是搅动叶片和板式蒸汽室的局部透视图,这些叶片和腔室装设在图1设备的一蒸发器之中;以及Figure 4 is a partial perspective view of the stirring blades and plate steam chambers installed in an evaporator of the apparatus of Figure 1; and

图5是表示图4各板式蒸汽室的局部放大视图。Fig. 5 is a partially enlarged view showing each plate-type steam chamber in Fig. 4 .

具体实施方式Detailed ways

参见图1,其中以局部剖视图表明本发明一优选实施例的蒸发和浓缩干燥设备的结构。此图中,附图标记1表示一用于盛放有待通过蒸发予以处理的湿料(wet material)的容器。其中配备有一盘管R的容器1在其顶部设有一第一入口15a,用于填装有待处理的湿料,比如水或湿泥浆。容器1的外壳是双重结构壁板,这种双重结构壁板用于从将在容器1中循环的冷凝水中回收废热。容器1用于蒸发和浓缩干燥湿料的蒸发器10相连接,该蒸发器10是一搅动型蒸发器并在其中盛装诸如废水或湿泥浆等湿料。此蒸发器10在其顶部设有一第二入口15b,用于选择性地填装有待予以蒸发的湿料。此蒸发器10的底部做成圆形并在圆形底部侧壁的下部有一凹槽11。一用于把泥浆排至蒸发器10外面的螺旋11s安放在凹槽11之中。为了搅动蒸发器10中的湿料,许多板式半圆形蒸汽室13铅直地设置在蒸发器10之中,以致这些腔室13沿水平方向排列并彼此等距地间隔开来。如图4和5所示。许多搅动叶片12设置在各腔室13之间。每一叶片12都可在由各腔室13界定的空间中沿相反的两个方向转动,从而搅动有待蒸发的湿料。如图5所示,各板式蒸汽室13的相对侧壁的内端部分平滑地渐缩至一单一脊部,从而使位于各板式蒸汽室13之间的各搅动叶片12作平滑转动。各搅动叶片12套装在一叶片轴S上,此轴S在长度方向上沿着蒸发器10的中心延伸。各板式蒸汽室13与形成在蒸发器10的双重结构壁板中的一蒸汽室14相连通。蒸发器10的顶部经由一连接管16连接于一溢流防止室17,此溢流防止室17本身又经由一U形弯管18连接于蒸发器10的内部。弯管18从腔室17的底部伸向蒸发器10的内部。Referring to Fig. 1, wherein shows the structure of the evaporation and concentration drying equipment of a preferred embodiment of the present invention with partial sectional view. In this figure, reference numeral 1 denotes a container for holding wet material to be treated by evaporation. The container 1 equipped with a coil R in it is provided at its top with a first inlet 15a for filling with wet material to be treated, such as water or wet slurry. The outer shell of the vessel 1 is a double structural wall for the recovery of waste heat from the condensed water to be circulated in the vessel 1 . The container 1 is connected to an evaporator 10 for evaporating and concentrating the dried wet material, which is an agitation type evaporator and holds therein a wet material such as waste water or wet mud. The evaporator 10 is provided at its top with a second inlet 15b for selectively filling the wet material to be evaporated. The bottom of the evaporator 10 is circular and has a groove 11 at the bottom of the side wall of the circular bottom. A screw 11s for discharging the slurry to the outside of the evaporator 10 is placed in the groove 11 . In order to stir the wet material in the evaporator 10, a plurality of plate-type semicircular steam chambers 13 are arranged vertically in the evaporator 10, so that the chambers 13 are arranged in the horizontal direction and spaced equidistantly from each other. As shown in Figures 4 and 5. A number of stirring blades 12 are provided between the chambers 13 . Each blade 12 is rotatable in two opposite directions in the space delimited by each chamber 13, thereby agitating the wet material to be evaporated. As shown in FIG. 5, the inner end portions of the opposite side walls of the plate steam chambers 13 are smoothly tapered to a single ridge, so that the stirring blades 12 located between the plate steam chambers 13 are smoothly rotated. Each stirring blade 12 is sleeved on a blade shaft S, and the shaft S extends along the center of the evaporator 10 in the length direction. Each plate-type steam chamber 13 communicates with a steam chamber 14 formed in the double-structured wall panels of the evaporator 10 . The top of the evaporator 10 is connected via a connecting pipe 16 to an overflow prevention chamber 17 which itself is connected to the interior of the evaporator 10 via a U-shaped bend 18 . An elbow 18 extends from the bottom of the chamber 17 to the interior of the evaporator 10 .

一第一导管R1从溢流防止室17的顶部伸向一蒸气压缩透平(vaporcompressing turbine)20。导管R1设有一控制阀21,用于向在导管R1之中流动的蒸气供应预热空气。蒸气压缩透平20的后端本身又经由一第二导管R2连接于一蒸气压缩泵30。一第三导管R3从蒸气压缩泵30伸向一热量回收装置60。如图1至3所示,适于从高温蒸气回收热量并将回收的热量再用于预热低温蒸气的该热量回收装置60配备有一束第九导管或蒸汽导管R9,这些导管R9在装置60之中沿水平方向延伸并等距地间隔开来。热量回收装置60的对置两端本身又分别经由第四和第六导管R4和R6连接于一具有自己的加热装置的辅助锅炉40和蒸发器10。在辅助锅炉40中,第四导管R4连接于一燃烧器41喷嘴前面的一蒸气加热盘管42。燃烧器41装在锅炉40的前壁并生成将导引至锅炉40内部的火焰。环绕锅炉40中的一蒸气加热室43的盘管42本身又经由一第五导管R5连接于热量回收装置60。这样,蒸气的潜热可由装置60回收并重新用于预热在蒸汽导管R9之中流动的低温蒸气。A first conduit R1 extends from the top of the flood prevention chamber 17 to a vapor compressing turbine 20 . The conduit R1 is provided with a control valve 21 for supplying preheated air to the steam flowing in the conduit R1 . The rear end of the vapor compression turbine 20 itself is connected to a vapor compression pump 30 via a second conduit R2 . A third conduit R3 extends from the vapor compression pump 30 to a heat recovery device 60 . As shown in Figures 1 to 3, the heat recovery unit 60 adapted to recover heat from high-temperature steam and reuse the recovered heat for preheating low-temperature steam is equipped with a bundle of ninth or steam conduits R9 , which are located at The devices 60 extend horizontally and are equally spaced apart. The opposite ends of the heat recovery device 60 are themselves connected via fourth and sixth conduits R4 and R6 , respectively, to an auxiliary boiler 40 and evaporator 10 with their own heating means. In the auxiliary boiler 40 , the fourth conduit R 4 is connected to a steam heating coil 42 in front of the nozzle of a burner 41 . The burner 41 is mounted on the front wall of the boiler 40 and generates a flame to be guided to the inside of the boiler 40 . The coil 42 surrounding a steam heating chamber 43 in the boiler 40 is itself connected to the heat recovery unit 60 via a fifth conduit R5 . In this way, the latent heat of the steam can be recovered by the device 60 and reused for preheating the low temperature steam flowing in the steam conduit R9 .

具有一压力调节器51以及一泄放阀52的第七导管R7在蒸发器10的圆形底部处从蒸发器10的蒸汽室14延伸出并连接于容器1。在容器1中,冷凝水在通过盘管R时失去热量。此后,冷凝水被送入一冷凝水池50,从而被收集在池50之中。A seventh conduit R 7 with a pressure regulator 51 and a relief valve 52 extends from the vapor chamber 14 of the evaporator 10 at the circular bottom of the evaporator 10 and is connected to the vessel 1 . In vessel 1, the condensate loses heat as it passes through coil R. Thereafter, the condensed water is sent to a condensed water tank 50 to be collected in the tank 50 .

在上述设备的操作中,有待蒸发的湿料,比如废水,通过容器1的第一入口15a装进容器1,此容器1可从冷凝水中回收废热。废水本身又经由一第八导管R8被送进蒸发器10,从而在蒸发器10中被蒸发或浓缩干燥而成为蒸气。蒸气本身又经由连接管16流向溢流防止室17,并且随后经由第一导管R1被送进透平20。在蒸气被送往透平20之前,第一导管R1的控制阀21向蒸气添加适当数量的预热空气。在此,根据充斥在蒸气中的各种被蒸发的杂质的特性而添加于蒸气的预热空气是为了促进这些杂质的氧化。不过,应当理解,在不根据蒸发主体的特性添加预热空气的情况下,充满各种杂质的蒸气在高温下可能会碳化。此时,蒸发室10由于蒸气压缩透平20和蒸气压缩泵30的作用被抽成真空,以致蒸发器10具有大约60℃的内部温度以及范围从大约300mmHg(毫米汞柱)到大约400mmHg的真空度。蒸气此后由蒸气压缩泵30再予以压缩,以致蒸气压力增大。In the operation of the above-mentioned plant, wet material to be evaporated, such as waste water, is introduced into the container 1 through the first inlet 15a of the container 1, which recovers waste heat from the condensed water. The waste water itself is sent to the evaporator 10 via an eighth conduit R8 , where it is evaporated or concentrated to dryness into vapor. The steam itself flows in turn via the connecting pipe 16 to the flood prevention chamber 17 and is then sent into the turbine 20 via the first conduit R 1 . The control valve 21 of the first conduit R1 adds an appropriate amount of preheated air to the steam before it is sent to the turbine 20 . Here, the preheated air added to the steam according to the characteristics of various evaporated impurities filled in the steam is to promote the oxidation of these impurities. However, it should be understood that the steam full of various impurities may be carbonized at high temperature without adding preheated air according to the characteristics of the evaporation body. At this time, the evaporation chamber 10 is evacuated due to the action of the vapor compression turbine 20 and the vapor compression pump 30, so that the evaporator 10 has an internal temperature of about 60° C. and a vacuum ranging from about 300 mmHg to about 400 mmHg Spend. The vapor is thereafter recompressed by the vapor compression pump 30 so that the vapor pressure increases.

高压蒸气本身又经由第三导管R3送进热量回收装置60的蒸汽导管R9并从装置60经由第四导管R4排放到辅助锅炉40。在辅助锅炉40中,蒸气在通过蒸气加热管42和蒸气加热室43时由蒸气加热装置予以加热,从而成为高温蒸气,此蒸气的温度范围从大约600℃到800℃。由于蒸气在锅炉40中被加热,充斥在蒸气中的各种杂质,诸如气味、B.O.D.和C.O.D.,通过氧化和碳化而予以清除。蒸气在由锅炉40加热之后经由第五导管R5返回热量回收装置60。在装置60中,600℃至800℃的蒸气与新蒸气交换热量,此新蒸气新送进装置60的导管R9并具有范围从60℃至100℃的低温。在热量回收装置60中,已被锅炉40的蒸气加热装置加热的蒸气由装置60的各导引隔板导向蒸汽导管R9周围,低温蒸气从导管R9通过。亦即,装置60中的高温蒸气在一曲折的通路中从装置60的后部流向前部并与从前部向后部通过导管R9的低温蒸气交换热量。The high-pressure steam is itself sent via the third conduit R3 to the steam conduit R9 of the heat recovery unit 60 and discharged from the unit 60 to the auxiliary boiler 40 via the fourth conduit R4 . In the auxiliary boiler 40, the steam is heated by the steam heating means while passing through the steam heating pipe 42 and the steam heating chamber 43, thereby becoming high-temperature steam, and the temperature of the steam ranges from about 600°C to 800°C. As the steam is heated in the boiler 40, various impurities contained in the steam, such as odor, BOD and COD, are removed by oxidation and carbonization. The steam returns to the heat recovery device 60 via the fifth conduit R 5 after being heated by the boiler 40 . In unit 60, the steam at 600°C to 800°C exchanges heat with live steam which is freshly fed into conduit R9 of unit 60 and has a low temperature ranging from 60°C to 100°C. In the heat recovery device 60, the steam heated by the steam heating device of the boiler 40 is guided around the steam conduit R9 by each guide partition of the device 60, and the low-temperature steam passes through the conduit R9 . That is, the high-temperature steam in the device 60 flows from the rear to the front of the device 60 in a tortuous path and exchanges heat with the low-temperature steam passing through the conduit R9 from the front to the rear.

如图2所示,各导引隔板可以铅直地安放在热量回收装置60之中,以致各隔板以相等间距间隔开来。各隔板会延长装置60中蒸气的热交换时间,从而提高装置60的热交换效果。不过,在设备操作的第一阶段,锅炉40中的水由锅炉40的加热装置加热,从而成为高温蒸汽。经过碳化或氧化的锅炉40的高温蒸汽再经由一第十导管R10、带有调节器41的第三导管R3、热量回收装置60、第四导管R4、锅炉40、第五导管R5、装置60和第六导管R6提供给蒸发器10的各板式蒸汽室13和蒸汽室14。在蒸发器10中,从锅炉40供给的高温蒸汽与废水交换热量,从而使废水成为大约60℃至100℃的低温蒸气。约60℃至100℃的蒸气经过上述过程被送进热量回收装置60并吸收经由第五导管R5从锅炉40供给的高温蒸气的热量。由于热交换,低温蒸气的温度从60℃至100℃增至450℃至600℃。450℃至600℃的预热蒸气本身又经由第四导管R4从装置60排放到锅炉40。同时,由于在热量回收装置60中进行热交换而温度降至150℃至200℃的蒸气经由第六导管R6排放到蒸发器10。As shown in FIG. 2, the guide partitions may be placed vertically in the heat recovery unit 60 so that the partitions are spaced at equal intervals. Each partition will prolong the heat exchange time of the vapor in the device 60 , thereby improving the heat exchange effect of the device 60 . However, in the first stage of plant operation, the water in the boiler 40 is heated by the heating means of the boiler 40 so as to become high-temperature steam. The high-temperature steam from the carbonized or oxidized boiler 40 passes through a tenth conduit R 10 , a third conduit R 3 with a regulator 41, a heat recovery device 60, a fourth conduit R 4 , a boiler 40, and a fifth conduit R 5 , the device 60 and the sixth conduit R 6 are provided to each plate vapor chamber 13 and vapor chamber 14 of the evaporator 10 . In the evaporator 10, the high-temperature steam supplied from the boiler 40 exchanges heat with the waste water so that the waste water becomes a low-temperature steam of about 60°C to 100°C. The steam of about 60°C to 100°C is sent into the heat recovery device 60 through the above process and absorbs heat of the high temperature steam supplied from the boiler 40 through the fifth conduit R5 . Due to heat exchange, the temperature of the low-temperature steam increases from 60°C to 100°C to 450°C to 600°C. The preheated steam at 450°C to 600°C is itself discharged from the device 60 to the boiler 40 via the fourth conduit R4 . Meanwhile, the vapor whose temperature is lowered to 150° C. to 200° C. due to heat exchange in the heat recovery device 60 is discharged to the evaporator 10 through the sixth conduit R 6 .

经由第四导管R4从装置60排放到锅炉40的450℃至600℃的预热蒸气在锅炉40中由锅炉40的蒸气热装置加热并被送进蒸气加热盘管42和蒸气加热室43,从而被氧化或碳化并成为600℃至800℃的高温蒸气。锅炉40的经过氧化或碳化的蒸气经由第五导管R5被送进装置60,并沿曲折通路从装置60的后部流向前部,与从前部向后部通过导管R9的60℃至100℃低温蒸气交换热量。在此,在锅炉40中由蒸气加热装置作用于蒸气而加热蒸气并将蒸气温度提高到600℃至800℃的加热能量在热量回收装置60中予以回收。亦即,充满在600℃至800℃高温蒸气中的加热能量被回收并重新用于预热流经装置60的蒸汽导管R9的蒸气,如图3所示。由于预热,从蒸发器10送来的蒸气的温度从60℃至80℃提高到450℃至600℃。由于将被送进锅炉40的蒸气的温度通过在装置60中进行热交换而从60℃到80℃提高到450℃至600℃,锅炉40加热装置的加热能量可以大为节省。The preheated steam at 450°C to 600°C discharged from the device 60 to the boiler 40 via the fourth conduit R4 is heated in the boiler 40 by the steam heating device of the boiler 40 and sent into the steam heating coil 42 and the steam heating chamber 43, Thereby it is oxidized or carbonized and becomes a high-temperature steam of 600°C to 800°C. The oxidized or carbonized steam of the boiler 40 is sent into the device 60 through the fifth conduit R5 , and flows from the rear of the device 60 to the front along a tortuous path, and the temperature from 60°C to 100°C is passed through the conduit R9 from the front to the rear. ℃ low temperature steam exchange heat. Here, heating energy that heats the steam and raises the temperature of the steam to 600° C. to 800° C. by acting on the steam by the steam heating means in the boiler 40 is recovered in the heat recovery means 60 . That is, the heating energy filled in the high-temperature steam of 600°C to 800°C is recovered and reused for preheating the steam flowing through the steam conduit R9 of the device 60, as shown in FIG. 3 . Due to the preheating, the temperature of the vapor sent from the evaporator 10 increases from 60°C to 80°C to 450°C to 600°C. Since the temperature of the steam to be fed into the boiler 40 is increased from 60°C to 80°C to 450°C to 600°C by heat exchange in the device 60, the heating energy of the heating device of the boiler 40 can be greatly saved.

经由第六导管R6从装置60排出并具有150℃至200℃温度、且其各种杂质被氧化或碳化的蒸气被供给蒸发器10的各板式蒸汽室13和蒸汽室14。在蒸发器10中,从装置60供给的蒸气与废水交换热量,从而失去其汽化热而被液化并成为相对高温的冷凝水,以致蒸发器10的水或湿料借助于在高温下液化而从蒸气中回收539Kcal(在蒸发压力是1.013Kg/cm2。A时)的潜热。大约80℃至120℃的这种冷凝水本身又经由兼有压力调节器51和泄放阀52二者的第七导管R7被送进容器1的盘管R。盘管R再次从冷凝水中回收废热。冷凝水被收集于冷凝水池50之中。当在池50中过滤冷凝水后,经过氧化或碳化的各种杂质从冷凝水中被去除,从而使冷凝水成为良好的蒸馏水。The vapor discharged from the device 60 through the sixth conduit R6 and having a temperature of 150° C. to 200° C. and whose various impurities are oxidized or carbonized is supplied to each plate type vapor chamber 13 and vapor chamber 14 of the evaporator 10 . In the evaporator 10, the steam supplied from the device 60 exchanges heat with the waste water, thereby losing its heat of vaporization and being liquefied and becoming relatively high-temperature condensed water, so that the water or wet material of the evaporator 10 is liquefied at a high temperature from The latent heat of 539Kcal (when the evaporation pressure is 1.013Kg/cm 2 .A) is recovered in the steam. This condensed water at about 80° C. to 120° C. is itself sent to the coil R of the vessel 1 via a seventh conduit R 7 having both a pressure regulator 51 and a relief valve 52 . Coil R again recovers waste heat from the condensate. The condensed water is collected in the condensed water tank 50 . When the condensed water is filtered in the tank 50, various impurities that have been oxidized or carbonized are removed from the condensed water, so that the condensed water becomes good distilled water.

在上述实施例中,废水通过降压蒸发方法被蒸发。不过,应当理解,废水可以在不低于大气压的某一高压下予以蒸发。亦即,本发明的设备可以在加压状况下蒸发废水。In the above examples, waste water was evaporated by the reduced-pressure evaporation method. However, it should be understood that waste water may be evaporated at a certain high pressure not lower than atmospheric pressure. That is, the apparatus of the present invention can evaporate waste water under pressurized conditions.

本发明的操作效果将在以下予以说明。The operational effects of the present invention will be described below.

容器1中有待蒸发的湿料或废水从流经盘管R的高温冷凝水吸收废热。此后,由于蒸气压缩透平20的降压作用以及蒸气压缩泵30的降压作用,经过预热的废水经由第八导管R8自然而然地被引进蒸发器10。在蒸发器10中,各搅动叶片12搅匀废水,以致废水将如下述被蒸发。在搅混预热废水之后,废水的浆渣收集在蒸发器10的凹槽11之中。凹槽11中的浆渣本身又通过浆渣排放螺旋11s被排放到蒸发器10的外面。同时,留下的不带浆渣的废水从流动在蒸发器10的各板式蒸汽室13之中和流动在蒸汽室14之中的150℃至200℃的高温蒸气吸收汽化热量,从而被蒸发而成为低温蒸气。处于蒸气状态的废水本身又经由连接管16从蒸发器10被送进溢流防止室17,此溢流防止室17具有U形弯管18,从腔室17的底部延伸向蒸发器10的内部并适于在蒸发器10中蒸发期间防止废水可能溢出蒸发器10。废水的蒸气此后经由从腔室17的顶部伸向蒸气压缩透平20的第一导管R1被送进蒸气压缩透平20。在蒸气送进透平20之前,在控制阀21的控制之下蒸气可以选择性地添加预定数量的预热空气,此阀21安放在透平20的蒸气入口的前面。The wet material or waste water to be evaporated in container 1 absorbs waste heat from the high temperature condensed water flowing through the coil R. Thereafter, the preheated waste water is naturally introduced into the evaporator 10 through the eighth conduit R8 due to the depressurizing action of the vapor compression turbine 20 and the depressurizing action of the vapor compression pump 30 . In the evaporator 10, the respective agitating blades 12 agitate the waste water so that the waste water will be evaporated as described below. After mixing the preheated wastewater, the sludge of the wastewater is collected in the groove 11 of the evaporator 10 . The rejects themselves in the groove 11 are discharged to the outside of the evaporator 10 through the reject discharge screw 11s. At the same time, the remaining waste water without slurry absorbs the heat of vaporization from the high-temperature steam of 150° C. to 200° C. flowing in each plate steam chamber 13 and in the steam chamber 14 of the evaporator 10, thereby being evaporated and Become a low-temperature vapor. The waste water itself in the vapor state is sent from the evaporator 10 via the connecting pipe 16 into the overflow prevention chamber 17, which has a U-shaped bend 18 extending from the bottom of the chamber 17 to the inside of the evaporator 10 And adapted to prevent waste water from possibly overflowing the evaporator 10 during evaporation in the evaporator 10 . The vapor of the waste water is thereafter fed into the vapor compression turbine 20 via a first conduit R 1 extending from the top of the chamber 17 to the vapor compression turbine 20 . Before the steam is fed into the turbine 20, the steam may optionally be added with a predetermined amount of preheated air under the control of a control valve 21, which is placed in front of the steam inlet of the turbine 20.

蒸气压缩透平20的蒸气本身又被送进蒸气压缩泵30,其中蒸气受到压缩以增大其压力。此时,蒸发器10中的废水由于蒸发器10中的降压状况而在大约60℃的温度下蒸发。此外,由于蒸气压缩透平20的降压作用以及由于蒸气压缩泵30的降压作用,蒸发器10达到范围从大约300mmHg至大约400mmHg的真空度。正如以下关于理想气体的基本方程(E-1)所表明的那样,蒸气压力既可由透平20也可由泵30予以提高,以致蒸气在某一高压和某一高温下得以液化。当然,本发明的设备可以使用一种真空增压泵(vacuumbooster)、一种真空分子泵或一种蒸气压缩装置,代替上述主要实施例的蒸气压缩透平20。The vapor from the vapor compression turbine 20 is itself fed to a vapor compression pump 30 where the vapor is compressed to increase its pressure. At this time, the waste water in the evaporator 10 evaporates at a temperature of about 60° C. due to the depressurization condition in the evaporator 10 . In addition, the evaporator 10 achieves a vacuum ranging from about 300 mmHg to about 400 mmHg due to the depressurizing action of the vapor compression turbine 20 and due to the depressurizing action of the vapor compression pump 30 . As indicated by the following basic equation (E-1) for ideal gases, the vapor pressure can be increased by either the turbine 20 or the pump 30 so that the vapor is liquefied at a certain high pressure and a certain high temperature. Of course, the apparatus of the present invention may use a vacuum booster, a vacuum molecular pump or a vapor compression device instead of the vapor compression turbine 20 of the above-mentioned main embodiment.

     PV=ntRT……………………………………………(E-1)其中PV=n t RT…………………………………(E-1) where

P-蒸气压力;P - vapor pressure;

V-蒸气体积;V - vapor volume;

T-蒸气的绝对温度;T - the absolute temperature of the vapor;

R-气体常数;以及R - gas constant; and

nt-包含在体积V的蒸气中的各种气体的总摩尔数。n t - the total number of moles of each gas contained in the volume V of vapor.

蒸气本身又在蒸气压力由透平20和泵30增加的条件下通过热量回收装置60的蒸汽导管R9。在通过蒸气导管R9时,蒸气从在装置60中围绕导管R9逆流的高温蒸气吸收热量。充斥各种杂质的蒸气,在导管R9中经过预热后,被送进锅炉40的蒸气加热室43并被锅炉40的蒸气加热装置加热到600℃至800℃的温度,从而被氧化或碳化。被氧化或碳化的高温蒸气返回到热量回收装置60并在装置60中沿着曲折的通路围绕蒸汽导管R9逆向流动。此时,被新送进装置60并具有60℃℃至100℃较低温度的新的蒸气在装置60的蒸气导管R9之中流动。在装置60中,曾由锅炉40的蒸气加热装置予以加热的蒸气由装置60的沿铅直方向安放的各导引隔板导引而围绕蒸汽导管R9,从而与新蒸气交换热量,如图2和3所示。The steam itself passes through the steam conduit R 9 of the heat recovery unit 60 under the condition that the steam pressure is increased by the turbine 20 and the pump 30 . While passing through vapor conduit R 9 , the vapor absorbs heat from the high temperature vapor flowing countercurrently around conduit R 9 in device 60 . The steam full of various impurities is sent to the steam heating chamber 43 of the boiler 40 after being preheated in the conduit R9 , and is heated to a temperature of 600°C to 800°C by the steam heating device of the boiler 40, thereby being oxidized or carbonized . The oxidized or carbonized high-temperature steam returns to the heat recovery device 60 and flows reversely in the device 60 around the steam conduit R9 along a tortuous path. At this time, new vapor that is newly fed into the device 60 and has a lower temperature of 60° C. to 100° C. flows in the vapor conduit R 9 of the device 60 . In the device 60, the steam once heated by the steam heating device of the boiler 40 is guided by the guide partitions placed in the vertical direction of the device 60 and surrounds the steam conduit R9 , thereby exchanging heat with the new steam, as shown in the figure 2 and 3 are shown.

被预热至450℃至600℃温度的蒸气经由第四导管R4被送进蒸气加热管42和蒸气加热室43,从而成为被氧化或碳化的600℃至800℃的高温蒸气。同时,失去热能且温度已被降低到150℃至200的蒸气经由导管R6被送进蒸发器10的各板式蒸汽室13和蒸汽室14。在通过蒸发器10的各板式蒸汽室13和蒸汽室14时,150℃至200℃的蒸气与废水交换热量,从而被液化并成为大约80℃至120℃的冷凝水。这是因为,如上述方程E-1所表明的那样,由于蒸气在某一正比于蒸气压力的温度下液化,高压蒸气在某一正比于其蒸气压力的高温下液化。The steam preheated to a temperature of 450°C to 600°C is sent to the steam heating pipe 42 and the steam heating chamber 43 through the fourth conduit R4 , thereby becoming oxidized or carbonized high temperature steam of 600°C to 800°C. Simultaneously, the steam which has lost heat energy and whose temperature has been lowered to 150° C. to 200° C. is sent into the respective plate steam chambers 13 and 14 of the evaporator 10 via the conduit R 6 . While passing through the plate-type steam chambers 13 and 14 of the evaporator 10, steam at 150°C to 200°C exchanges heat with waste water to be liquefied and becomes condensed water at about 80°C to 120°C. This is because, as indicated by Equation E-1 above, since the vapor liquefies at a certain temperature proportional to its vapor pressure, high pressure vapor liquefies at a certain high temperature proportional to its vapor pressure.

大约80℃至120℃的冷凝水本身又经由具有压力调节器51和泄放阀52的第七导管R7被送进容器1的盘管R。盘管R再次从冷凝水回收废热并把废热给予容器1的废水。冷凝水在失去废热之后被收集于冷凝水池50。另一方面,利用由蒸发器10回收的潜热通过蒸发废水所制备的温度为60℃至100的蒸气经由溢流防止室17被送进热量回收装置60。The condensed water at about 80° C. to 120° C. is itself fed into the coil R of the vessel 1 via a seventh conduit R 7 with a pressure regulator 51 and a relief valve 52 . Coil R again recovers waste heat from the condensate and imparts waste heat to the waste water in vessel 1 . The condensed water is collected in the condensed water sump 50 after losing waste heat. On the other hand, steam at a temperature of 60° C. to 100° C. prepared by evaporating waste water using latent heat recovered by the evaporator 10 is sent to the heat recovery unit 60 via the overflow prevention chamber 17 .

蒸气中的各种杂质,诸如气味、B.O.D.和C.O.D.,它们与蒸气一同蒸发并充斥在蒸气之中,与由控制阀21供给的预定数量的预热空气相掺混,此阀21安放在透平20的蒸气入口的前面。由于与预热空气相掺混,蒸气的各种杂质成为可氧化的杂质。可氧化的杂质被送进锅炉40的蒸气加热装置,亦即蒸气加热管42和蒸气加热室43。因而,各种杂质在锅炉40中在600℃至800℃的高温氛围下被氧化和燃烧,从而从蒸气中除掉。另外,在不根据蒸气特性添加预热空气的情况下,充斥各种杂质的蒸气可在600℃至800℃的高温氛围下被碳化从而从蒸气中除掉诸如气味、B.O.D.和C.O.D.等各种杂质。曾由锅炉40的蒸气加热装置施用于蒸气以产生高温氛围的蒸气加热能量由装置60回收并重新用于预热装置60中的低温蒸气。就此而论,本发明的设备所节省的蒸气加热能量数量等于用于预热装置60中蒸气的回收能量。Various impurities in the steam, such as odor, B.O.D., and C.O.D., which evaporate together with the steam and fill the steam, are mixed with a predetermined amount of preheated air supplied by the control valve 21, which is installed in the turbine. 20 to the front of the steam inlet. Due to mixing with the preheated air, various impurities of the steam become oxidizable impurities. The oxidizable impurities are sent to the steam heating means of the boiler 40, that is, the steam heating tube 42 and the steam heating chamber 43. Thus, various impurities are oxidized and burned in the boiler 40 in a high-temperature atmosphere of 600°C to 800°C, thereby being removed from the steam. In addition, without adding preheated air according to the characteristics of the steam, the steam full of various impurities can be carbonized in a high-temperature atmosphere of 600°C to 800°C to remove various impurities such as odor, B.O.D., and C.O.D. from the steam . The steam heating energy once applied to the steam by the steam heating means of the boiler 40 to create a high temperature atmosphere is recovered by the means 60 and reused for preheating the low temperature steam in the means 60 . In this regard, the steam heating energy saved by the apparatus of the present invention is equal to the recovered energy used to preheat the steam in the device 60 .

应当理解,本发明的设备可以通过对容器1、蒸发器10、辅助锅炉40等作隔热处理而提高其能量效率。It should be understood that the energy efficiency of the plant of the present invention can be improved by insulating the vessel 1, evaporator 10, auxiliary boiler 40, etc.

为了度量本发明设备和方法的运用效果,曾经进行了以下的一项实例。亦即,作为有待蒸发的湿料的排泄物曾在620℃下被加热、氧化和燃烧或在620℃下被加热和碳化。结果示在下表(T-1)。如表(T-1)所示,使用本发明设备并按照本发明方法所处理的湿料可以最为有效地予以净化。In order to measure the effectiveness of the application of the apparatus and method of the present invention, the following example was carried out. That is, excrement as wet material to be evaporated was heated, oxidized and burned at 620°C or heated and carbonized at 620°C. The results are shown in Table (T-1) below. As shown in Table (T-1), the wet material treated by the device of the present invention and the method of the present invention can be most effectively purified.

                    表(T-1)成分          标准                结果                                                         

                       (A)           (B)pH            5.8----8.6   9.0           9.8COD           150(mg/l)    6.4(mg/l)     6.6(mg/l)BOD           150(mg/l)    5.6(mg/l)     5.9(mg/l)SS            150(mg/l)    4.0(mg/l)     4.5(mg/l)正己烷        30(mg/l)     0.8(mg/l)     4.0(mg/l)T-N           60(mg/l)     16.1(mg/l)    16.5(mg/l)T-P           8(mg/l)      0.033(mg/l)   O.034(mg/l)NH3-N        -            5.358(mg/l)   4.632(mg/l)(A) (B)pH 5.8----8.6 9.0 9.8COD 150(mg/l) 6.4(mg/l) 6.6(mg/l)BOD 150(mg/l) 5.6(mg/l) 5.9(mg /l) SS 150 (mg/l) 4.0 (mg/l) 4.5 (mg/l) n-Hexane 30 (mg/l) 0.8 (mg/l) 4.0 (mg/l) TN 60 (mg/l) 16.1 (mg/l) 16.5(mg/l)TP 8(mg/l) 0.033(mg/l) O.034(mg/l)NH 3 -N - 5.358(mg/l) 4.632(mg/l)

如上所述,本发明与传统的蒸发设备相比可降低生产蒸发和浓缩干燥设备的成本和本设备的操作成本,从而为用户提供经济效益。本设备还可保持其经过改进的性能,以致本设备可以以低成本制备良好的蒸馏水并广泛用于有毒废水和环境污染废水的蒸发和浓缩干燥,以及废弃泥浆的蒸发、浓缩和干燥。其次,本发明设备的热量回收装置可回收蒸气加热能量,此能量曾由锅炉的加热装置施用于蒸气以便把蒸气加热到某一高温并除掉充斥在蒸气中的诸如气味、B.O.D.和C.O.D.等各种杂质。回收的能量重新用于预热新送进热量回收装置的蒸气。就此而论,本发明设备所节省的加热能量数量等于用于预热热量回收装置中蒸气的回收能量。As described above, the present invention can reduce the cost of producing evaporation and concentration drying equipment and the operating cost of the equipment compared with conventional evaporation equipment, thereby providing economic benefits to users. This equipment also maintains its improved performance, so that this equipment can prepare good distilled water at low cost and is widely used for evaporation and concentration drying of toxic waste water and environmental pollution waste water, and for evaporation, concentration and drying of waste mud. Secondly, the heat recovery device of the apparatus of the present invention can recover steam heating energy which was once applied to the steam by the heating device of the boiler in order to heat the steam to a certain high temperature and remove various substances such as odor, B.O.D. and C.O.D. kinds of impurities. The recovered energy is re-used to preheat the steam that is newly fed to the heat recovery unit. In this connection, the amount of heating energy saved by the plant according to the invention is equal to the recovered energy used to preheat the vapor in the heat recovery unit.

尽管本发明各项优选实施例已经为说明目的而予以披露,但是本技术领域的熟练人员应当理解,在不背离本发明的范畴和精神的条件下,各种各样的改变、附加和代换都是可能的。Although the preferred embodiments of the present invention have been disclosed for illustrative purposes, those skilled in the art will understand that various changes, additions and substitutions can be made without departing from the scope and spirit of the present invention. It's all possible.

Claims (3)

1.一种蒸发和浓缩干燥设备,其中改进之处包括:1. An evaporation and concentration drying equipment, wherein the improvements include: 一用于在其中盛放湿料的容器,所述容器具有一双重壁板结构并在其中配备有一盘管,其顶部设有一第一入口,用于把湿料填装于容器中,所述盘管连接于一冷凝水池:A container for holding wet material therein, said container has a double-walled structure and is equipped with a coiled pipe therein, and a first inlet is provided at the top thereof for filling wet material into the container, said The coil is connected to a condensate sump: 一用于回收蒸气潜热并利用回收的潜热蒸发湿料的搅动式蒸发器,所述蒸发器经由一用于从容器接收湿料的导管连接于所述容器的底部,所述蒸发器包括:an agitated evaporator for recovering latent heat of vapor and utilizing the recovered latent heat to evaporate wet material, said evaporator being connected to the bottom of said vessel via a conduit for receiving wet material from said vessel, said evaporator comprising: 一设在蒸发器顶部的第二入口;a second inlet at the top of the evaporator; 一圆形的底部;a round bottom; 一设在靠近圆形底部的一侧壁上并配备有一用于把浆渣排放到蒸发器外面的螺旋的凹槽;- a groove provided on one side wall near the circular bottom and equipped with a helical groove for discharging the rejects to the outside of the evaporator; 多个彼此连通的板式半圆形蒸汽室,每一所述板式蒸汽室铅直地装设在蒸发器的内部,从而各板式腔室沿水平方向排列并等间距地间隔开,所述各板式腔室经由一配设有一压力调节器和一泄放阀的导管连接于容器的所述盘管:A plurality of plate-type semicircular steam chambers communicated with each other, each of the plate-type steam chambers is vertically installed inside the evaporator, so that each plate-type chamber is arranged in the horizontal direction and spaced at equal intervals, and each of the plate-type steam chambers The chamber is connected to said coil of the vessel via a conduit equipped with a pressure regulator and a relief valve: 多个用于搅动蒸发器中湿料的搅动叶片,所述各叶片位于所述各板式腔室之间,而且每一叶片双向转动,以便均匀地搅动湿料;A plurality of agitating blades for agitating the wet material in the evaporator, each blade is located between the plate chambers, and each blade rotates bidirectionally so as to evenly agitate the wet material; 一在长度方向沿所述蒸发器的中心延伸并支承各搅动叶片的叶片轴;以及a blade shaft extending lengthwise along the center of the evaporator and supporting the stirring blades; and 一用于在蒸发期间防止液体溢出所述蒸发器的溢流防止室,所述溢流防止室经由一连接管与蒸发器的顶部连接并经由一从其底部伸入蒸发器内部的U形弯管连接于蒸发器的内部;an overflow prevention chamber for preventing liquid from overflowing said evaporator during evaporation, said overflow prevention chamber being connected to the top of the evaporator via a connecting pipe and via a U-shaped bend protruding from its bottom into the interior of the evaporator The tube is connected to the inside of the evaporator; 一用于回收蒸气的潜热并用于预热从蒸发器送进其中的低温蒸气的热量回收装置,所述装置经由各相关的导管连接于所述蒸发器、围绕一辅助锅炉的蒸气加热室的蒸气加热盘管的入口、所述蒸发器的各板式蒸汽室和蒸气加热盘管的出口,所述装置包括:A heat recovery device for recovering the latent heat of the vapor and for preheating the low-temperature vapor fed into it from the evaporator, said device being connected via respective conduits to said evaporator, the steam surrounding a steam heating chamber of an auxiliary boiler The inlet of the heating coil, the plate steam chambers of the evaporator and the outlet of the steam heating coil, the device comprising: 多条沿水平方向延伸的蒸汽导管,所述沿水平方向延伸的各条蒸汽导管使低温蒸气从中通过;以及a plurality of horizontally extending steam conduits through which low-temperature steam passes; and 多个铅直地装设在装置中并等距地间隔开来的隔板;a plurality of partitions mounted vertically in the unit and equally spaced; 所述辅助锅炉用于从热量回收装置接受预热蒸气并把预热蒸气加热到某一高温以便氧化或碳化蒸气,所述辅助锅炉连接于热量回收装置并具有一燃烧器、所述蒸气加热盘管和蒸气加热室;The auxiliary boiler is used to receive preheated steam from the heat recovery device and heat the preheated steam to a certain high temperature to oxidize or carbonize the steam. The auxiliary boiler is connected to the heat recovery device and has a burner, the steam heating plate tube and steam heating chamber; 一蒸气压缩透平和一蒸气压缩泵,用于压缩从蒸发器供给的蒸气以提高蒸气压力,透平与泵二者都设在从蒸发器的溢流防止室伸向热量回收装置的一条导管上;以及a vapor compression turbine and a vapor compression pump for compressing the vapor supplied from the evaporator to increase the vapor pressure, both the turbine and the pump being provided in a conduit extending from the overflow prevention chamber of the evaporator to the heat recovery unit ;as well as 一预热空气供应控制阀,设在所述蒸气压缩透平前面的导管上,所述阀适于控制供向从蒸发器经由导管流往热量回收装置的蒸气的预热空气。A preheat air supply control valve is provided on the conduit preceding the vapor compression turbine, said valve being adapted to control the supply of preheat air to the vapor flowing from the evaporator via the conduit to the heat recovery unit. 2.按照权利要求1所述的设备,其中,蒸发器各板式蒸汽室的对置侧壁的内端部分平滑地汇接至一单一脊部,从而使安放在各板式蒸汽室之间的所述各搅动叶片平滑转动。2. Apparatus according to claim 1, wherein the inner end portions of the opposed side walls of the plate vapor chambers of the evaporator merge smoothly into a single ridge so that all the plate vapor chambers disposed between Each agitating blade rotates smoothly. 3.一种蒸发和浓缩干燥方法,包括以下各步骤:3. A method of evaporation and concentration drying, comprising the following steps: 加热一辅助锅炉中的水以产生蒸汽,并通过碳化或氧化蒸汽从所述蒸汽中除掉各种杂质,把蒸汽供向一蒸发器的多个板式蒸汽室以使蒸汽与蒸发器中的湿料交换热量,以及在热交换之后经由配设有压力调节器和泄放阀的一条导管把蒸汽排至一湿料容器的盘管,从而从蒸汽回收废热;Heating water in an auxiliary boiler to generate steam, and removing various impurities from the steam by carbonizing or oxidizing steam, supplying steam to a plurality of plate steam chambers of an evaporator to make the steam and the moisture in the evaporator waste heat recovery from the steam by discharging the steam to a wet material container coil after the heat exchange through a conduit equipped with a pressure regulator and a relief valve; 通过操作蒸气压缩透平和蒸气压缩泵提高或降低蒸发器的内压,从而将湿料从容器送进蒸发器,并通过蒸发器多个搅动叶片的相反方向的转动均匀地搅混湿料,以使湿料与流动在各板式蒸汽室中的150℃至200℃的经过碳化的蒸气交换热量并蒸发湿料,以及把由湿料产生的60℃到100℃的蒸气经由一连接管从蒸发器排出,同时把湿料的浆渣收集于蒸发器的一凹槽中以便把浆渣排放到外边去;The internal pressure of the evaporator is increased or decreased by operating the vapor compression turbine and the vapor compression pump, so that the wet material is sent from the container to the evaporator, and the wet material is evenly stirred by the rotation of the evaporator's multiple agitating blades in the opposite direction, so that The wet material exchanges heat with the carbonized steam of 150°C to 200°C flowing in each plate steam chamber and evaporates the wet material, and the steam generated by the wet material of 60°C to 100°C is discharged from the evaporator through a connecting pipe At the same time, collect the slurry residue of the wet material in a groove of the evaporator so as to discharge the slurry residue to the outside; 使包含在60℃至100℃蒸气中的溢流液体经由一连接溢流防止室和蒸发器的一U形弯管返回到蒸发器,通过操作一预热空气供给控制阀选择性地把预热空气供向所述60℃至100℃的蒸气,以及把60℃到100℃的蒸气借助于蒸气压缩透平和蒸气压缩泵二者送进热量回收装置的多条蒸汽导管;The overflow liquid contained in the vapor of 60°C to 100°C returns to the evaporator through a U-shaped elbow connecting the overflow prevention chamber and the evaporator, and the preheating air is selectively turned on by operating a preheating air supply control valve. Air is supplied to said 60°C to 100°C vapor, and a plurality of steam conduits for sending the 60°C to 100°C vapor into the heat recovery unit by means of both a vapor compression turbine and a vapor compression pump; 使热量回收装置各蒸汽导管中的60℃至100℃的蒸气与600℃至800℃的高温蒸气交换热量,所述600℃至800℃的蒸气供自所述辅助锅炉并在装置的等距间隔开来的各隔板导引下在装置中沿曲折通路、围绕各蒸汽导管反向流动,把蒸气从60℃至100℃预热到450℃至600℃,以及把由于热交换其温度从600℃至800℃降低到150℃至200℃的蒸气从热量回收装置排放到蒸发器的各板式蒸汽室,同时把经过预热的450℃至600℃的蒸气送进所述辅助锅炉的蒸气加热盘管和蒸气加热室;Make the steam from 60°C to 100°C in each steam pipe of the heat recovery device exchange heat with the high-temperature steam from 600°C to 800°C, the steam from 600°C to 800°C is supplied from the auxiliary boiler and arranged at equidistant intervals of the device Under the guidance of the separated partitions, it flows in reverse along the tortuous path and around the steam pipes in the device, preheats the steam from 60°C to 100°C to 450°C to 600°C, and changes its temperature from 600°C to 600°C due to heat exchange. The steam from ℃ to 800 ℃ lowered to 150 ℃ to 200 ℃ is discharged from the heat recovery device to each plate steam room of the evaporator, and at the same time, the preheated 450 ℃ to 600 ℃ steam is sent to the steam heating plate of the auxiliary boiler tube and steam heating chamber; 使用燃烧器加热在所述辅助锅炉的蒸气加热盘管和蒸气加热室二者之中流动的450℃至600℃的预热蒸气,从而把蒸气的温度从450℃至600℃提高到600℃至800℃并氧化或碳化预热蒸气的各种杂质以便除掉异味以及各种杂质,以及使600℃至800的蒸气返回所述热量回收装置,以便使600℃至800℃的高温蒸气与在热量回收装置的各蒸汽导管中流动的60℃至100℃的低温蒸气作热量交换;以及Burners are used to heat the preheated steam at 450°C to 600°C flowing in both the steam heating coil and the steam heating chamber of the auxiliary boiler, thereby increasing the temperature of the steam from 450°C to 600°C to 600°C to 800°C and oxidize or carbonize various impurities in the preheated steam to remove odors and various impurities, and return the steam at 600°C to 800°C to the heat recovery device so that the high temperature steam at 600°C to 800°C can be combined with heat Low-temperature steam from 60°C to 100°C flowing in each steam pipe of the recovery unit for heat exchange; and 使蒸发器各板式蒸汽室中150℃至200℃的蒸气与蒸发器的水和湿料交换热量,借助于在某一高温下液化从蒸气中回收539 Kcal的潜热,从而使蒸气成为大约80℃至120℃的冷凝水,借助于所述配设有压力调节器和泄放阀的导管把大约80℃至120℃的冷凝水送进容器的所述盘管,从而使冷凝水再次与容器的湿料交换热量并从冷凝水中回收废热,以及把汽凝水收集在一冷凝水池之中。Make the steam at 150°C to 200°C in each plate steam chamber of the evaporator exchange heat with the water and wet material in the evaporator, and recover the latent heat of 539 Kcal from the steam by liquefaction at a certain high temperature, so that the steam becomes about 80°C To 120 ℃ condensed water, by means of the conduit equipped with a pressure regulator and a relief valve, the condensed water of about 80 ℃ to 120 ℃ is sent to the coil of the container, so that the condensed water is reconnected with the container The wet material exchanges heat and recovers waste heat from the condensate, and collects the condensate in a condensate pool.
CN94194698A 1993-11-23 1994-11-17 Vaporizing and concentration drying apparatus and method Expired - Fee Related CN1097559C (en)

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