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CN1096631A - " hydro-peening (spilling) goes out "---space spraying and the good long-acting sterilized solution of washing performance - Google Patents

" hydro-peening (spilling) goes out "---space spraying and the good long-acting sterilized solution of washing performance Download PDF

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Publication number
CN1096631A
CN1096631A CN 94105320 CN94105320A CN1096631A CN 1096631 A CN1096631 A CN 1096631A CN 94105320 CN94105320 CN 94105320 CN 94105320 A CN94105320 A CN 94105320A CN 1096631 A CN1096631 A CN 1096631A
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content
acid
agent
mixture
peening
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李潜德
赵曼云
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Abstract

This " hydro-peening (spilling) goes out "---space spraying and the good long-acting sterilized solution of washing performance, be a kind ofly have no side effect, powerful, long-acting food, health special use sterilizing spray decontaminant.It contains a, at least a main bactericide, and its content is 10-90%, elemental iodine, and glutaraldehyde, 3-35% hydrogen peroxide, Dalmatian chrysanthemum or its content of pyrethroid mixture are 0-16%.B, its content of atomizing reinforcing agent are 0-30%.C. water quality and its content of soda acid inorganic agent are 0-20%.D, increased activity or colloid bleeding agent, nonionic surface active agent or its complex, its content are 0-30%.E, deodorizing, synergist, ethylene glycol, propane diols, its content of glycerine are 0-15%.F and mixture, water surplus.A+b+c+d+e+f=100% (weight).

Description

" hydro-peening (spilling) goes out "---space spraying and the good long-acting sterilized solution of washing performance
The patented invention of the long-acting sterilized solution that this " hydro-peening (spilling) goes out "-space spraying and washing performance are good is about the sterilization decontamination solution.Say exactly, announce a kind of moisturely, can be used for space (gas phase), can be used for again that the three dimensions of liquid, solid phase (as food, organism, material, utensil etc.) aspect uses, powerful, long-acting sterilizing spray, decontamination solution.Sterilized solution of the present invention also is a kind of humans and animals not to be constituted any injury, and the disinfection system that can store for a long time.
As everyone knows, have, be applicable to that the chemical disinfection material in space is less though be called as efficient sterilization disinfectant.Its toxicity such as traditional chemical material such as formaldehyde, oxirane, ozone are bigger, to such an extent as to during sterilizing ten surplus hour in, humans and animals can not enter the scene; In addition, though some can be used for the space simultaneously, can be used for water and disinfection sanitizer soft, crust again, as Peracetic acid etc., its excitant and corrosivity are very big.Having, as disinfection sanitizers such as chloride series, glutaraldehyde, surface-active substances, is not Disinfection Effect relatively poor (hold time short, sterilizing power low) again, is exactly to lose efficacy easily, can not store for a long time etc.And there is peculiar smell in various degree in above-mentioned these disinfection sanitizer great majority, and the sense organ that stimulates the people is harmful to health, and has limited their application.Therefore we can say a kind of space disinfectant safely and effectively, also be in the development phase,, have a extensive future its research in China.
The present invention utilizes compounded technology, and in the traditional disinfectant overall merit of performance, the toxicity that overcomes its existence is big, use inconvenience, weak points such as storage property difference, it is better to have studied a combination property, can be applicable to the sterilization decontamination system of space and other any relevant occasions fully.
The present invention is a primary solvent with water, contains bactericide, the comprehensive disinfection system that atomizing, reinforcing agent, water quality and soda acid inorganic agent, increased activity or colloid bleeding agent, deodorizing synergist etc. are combined into and a kind ofly are perfectly safe, sterilizing power is strong.
The present invention achieves the goal by following technique measures.
1, " hydro-peening (spilling) liquid " of the present invention, its technical characterictic is (weight %):
A, at least a main bactericide: they are, C12-C18 chain cationic surfactant, and C12-C16 chain zwitterionic surfactant, its content are 10-90%; Elemental iodine, glutaraldehyde, the 3-35% hydrogen peroxide, 5% pyrethroid or 15% pyrethroid mixture, its content is 0-16%.
B, atomizing, reinforcing agent: isopropyl alcohol, ethanol, its content are 0-30%.
C, water quality and soda acid inorganic agent: EDTA or its sodium salt, citric acid, lactic acid, tartaric acid, fumaric acid, malic acid, phosphorous acid, monoethanolamine etc., its content is 0-20%.
D, increased activity or colloid bleeding agent: nonionic surface active agent or its complex, its content are 0-30%.
E, deodorizing, synergist: ethylene glycol, propane diols, glycerine, its content are 0-15%.
F and mixture: water, surplus.
A+b+c+d+e+f=100%(weight).
The present invention also can be reached by following technical measures more specifically.
2, " hydro-peening (spilling) goes out " of the present invention, its technical characterictic is (weight %):
A, at least a main bactericide: they are cation quaternary ammonium salt type surfactants, as: the ammonium chloride of the alkyl dimethyl (or dimethyl benzyl) of C12 or C14 or two C18 carbochains, and the ammonium bromide of C16 alkyl trimethyl.Amphoteric surfactant, as C12 alkyl (or C16 alkyl) dimethyl betaine, its content is 20-80%, elemental iodine, glutaraldehyde, 3-35% hydrogen peroxide, 5% pyrethroid or 15% pyrethroid mixture, its content 0-12%.
B, atomizing, reinforcing agent: isopropyl alcohol, ethanol, its content are 3-25%.
C, water quality, soda acid inorganic agent: EDTA or its sodium salt, citric acid, lactic acid, tartaric acid, fumaric acid, malic acid, phosphorous acid, monoethanolamine etc., its content is 0.1-18%.
D, increased activity or colloid bleeding agent: nonionic surface active agent or its complex, its content are 0-25%.
E, deodorizing, synergist: ethylene glycol, propane diols, glycerine, its content are 0-10%.
F, a+b+c+d+e+f=100%(weight).
The present invention also has better technical measures.
3, " hydro-peening (spilling) goes out " of the present invention technical characterictic is:
A, at least a main bactericide: its best proportioning:
Dodecyl benzyl dimethyl ammonium chloride is 0-44%;
The myristyl dimethyl benzyl ammonium chloride is 0-28%;
Dioctadecyl dimethyl ammonium chloride is 0-32%;
Two decyl trimethylammonium bromides are 0-20%;
Softex kw (pulvis) is 0-10%;
Dodecyl (or cetyl) dimethyl betaine is 0-80%;
Elemental iodine is 0-8%;
7.5% or 15% hydrogen peroxide (being adjusted to 30% hydrogen peroxide raw material) is 0-12%.
5% chlorine cyanogen (or bromine oxygen) chrysanthemum ester or its mixture of 15% are 0-1.5%.Only limit to desinsection, sterilized sanitary accessories.
Its mixture of 15% is that the shelled sesame oil that adds 2 times of chrysanthemum ester contents in chlorine cyanogen (or bromine cyanogen) the chrysanthemum ester 5% is formed.
B, atomizing, reinforcing agent, best proportioning is:
Isopropyl alcohol, ethanol, 3-15%.
C, water quality, acid-base modifier, its best proportioning is:
EDTA disodium 0-1%;
Citric acid 0-10%;
Lactic acid 0-18;
Phosphorous acid 0-15%;
Monoethanolamine 0-10%.
D, increased activity or colloid bleeding agent, its best proportioning is:
Alkylphenol polyoxyethylene OP-10,1-12%.
E, deodorizing, synergist: its best proportioning is:
Propane diols 0-10%;
Glycerine 0-10%.
F, water are surplus.
A+b+c+d+e+f=100%(weight).
Sterilization series technique of the present invention, except that the sterilization that contains insecticide (Dalmatian chrysanthemum of low toxicity or pyrethroid) that is made into, insecticide when using the nontoxic level in true border by the proportioning dilution, all the other stostes are nontoxic, no burn into pollution-free, non-stimulated when dilution use (particularly).Humans and animals is perfectly safe, can under any circumstance uses.
Sterilization series technique of the present invention, raw material is easy to get, and to the grade of raw material, content does not have particular requirement, if off-gauge should be amounted to use, corresponding adjustment prescription.During fabrication, its composite accent need only be converted.Generally speaking, can add water earlier, and formula ratio is less than 3% component, then should consider how to make its disperse more even getting final product.Can pack after filtering by 400 orders then.To being used for food and health care goods, and answer sedimentation after 5 days, get the supernatant liquor packing.
Sterilization series technique of the present invention, its stability is high, can be under-5-40 ℃ winter and summer environment, not obvious reduction bactericidal activity more than a year.
Sterilization series technique of the present invention, content height, usage amount are few.Owing to adopt compounded technology, material that can be inexpensive constitutes enhancing, synergy, activity increase agent and the high bactericide of replacement valency, thereby can reduce the content of sterilization, insecticide, when reducing side effect, can reduce cost, makes that it is more economical, have more practicality.
Sterilization series technique of the present invention, owing to adopt biomechanism and compounded technology, its good combination property, sterilization ability is more excellent.
Brute force of the present invention, long-acting, food, the sterilizing spray of health special use, decontamination solution, through the strictness detection confirmation of food, health and animal quarantine department, nontoxic, non-stimulated, the no burn into of its reality has no side effect, sterilization and clean result excellence, its LD 50(stoste, per os) reaches more than the 15700mg/kg for>10800mg/kg(fiducial limit), LC 50>16600mg/kg, content of beary metal Pb<1ppm, AS<0.5ppm(only is the 1/10-1/6 of GB washing agent), because the bacillus anthracoideses that drag is the strongest in the energy killing microorganisms etc. are so can think that all microorganisms are all had special efficacy and can be described as powerful sterilized dose (by the up-to-date regulation classification of the Ministry of Public Health about the disinfectant standard).Detect proof, this sterilization hydro-peening liquid can be quick in 10 minutes, 100% kill quasi-anthrax bud cell and withered grass brood cell bacterium; Can be in 5 minutes fast, complete inactivation titre higher H BsAg hepatitis B surface antigen; Can be in 1 minute rapidly, 100% kill tubercle bacillus, staphylococcus aureus, Escherichia coli, salmonella, gonococcus, pseudomonas aeruginosa, and skin wire-like bacteria, aspergillus flavus, newcastle disease virus NDX, pig parvoviral PPN and spermatozoon etc., and can by 15000-5000 doubly and 2000-200 times dilution factor be used for mariculture, the sterilization of livestock and poultry, insect environment and drinking-water, sterilizing rate can reach more than 95.0%, be used for antibacterial, its extension rate can reach 100000-500000 doubly more than.Stoste does not have corrosion to fabric, to carbon steel mild corrosion (continuous dipping 72 hours), aluminium is had corrosion inhibition.
Sterilization series technique of the present invention also shows good sterilization, fungistatic effect in actual applications.On probation through the large tracts of land of large-scale plant, when bigger at the space bacteria containing amount, the dynamic environment of clump count more than 150-300, by 0.6% dilution factor, with " two agricultural 40 type high pressure washing machines " spraying, its droplet is about in the of 20, amount of space 80-120ml/m 3Dilution, the dynamic bactericidal effect in its 24 hours can reach the 90.8%(clump count and reduce to 16.7 by 181.5) and can clump count be remained in 37, dynamically sterilization, fungi-proofing respond well.
Sterilization series technique of the present invention except that the sterilization performance, deodorizing, kills sanitary insect pest (fly, mosquito, cockroach, ant etc.) and cleaning performance all can reach about 90%, and also has certain pure and fresh and fresh-keeping effect.
Sterilization series technique of the present invention when reality is used, can dilute more than 16-2000 times with water by the difference requirement, and (being used for antibacterial extension rate also may be up to more than tens thousand of times) under this concentration, its acidity-basicity ph value is 5-7 or 7-9.And to most practical application proportionings, its dilution factor is in the time of 50-500 times, and acidity-basicity ph value is 5.5-8.0.
Sterilization series technique of the present invention, in actual use through 700,000 time young chickens, the chicken that grows up on a large scale with the disinfection of drinking water tests of chicken air sterillization test and 0.4 ten thousand young chickens, comprising during spraying is used when participating in the cintest of operator, have no effect.It is efficient that use on true border, spraying, the decontaminant of the sterilization that has no side effect that is perfectly safe.

Claims (3)

1, spray and wash good long-acting bactericidal agent in this " hydro-peening (spilling) goes out "-space, be a kind ofly have no side effect, the special-purpose sterilizing spray decontaminant of food, health that foam is abundant, powerful, long-acting, bactericidal agent of the present invention also is a kind of disinfection system that humans and animals is not constituted any injury and can store for a long time.Its technical characterictic is (weight %): a, at least a main bactericide, and they are cationic surfactants of C12-C18 chain, and the amphoteric surfactant of C12-C16 chain, its content are 10-90%; Elemental iodine, glutaraldehyde, 3-35% hydrogen peroxide, Dalmatian chrysanthemum or pyrethroid mixture (food, feeder tool forbidding), its content is 0-16%.B, atomizing, reinforcing agent: isopropyl alcohol, ethanol, its content are 0-30%.C, water quality and soda acid inorganic agent: EDTA or its sodium salt, citric acid, lactic acid, tartaric acid, fumaric acid, malic acid, phosphorous acid, monoethanolamine etc., its content is 0-20%.D, increased activity or colloid bleeding agent, nonionic surface active agent or its complex, its content are 0-30%.E, deodorizing, synergist, ethylene glycol, propane diols, glycerine, its content are 0-15%.F and mixture, water surplus.A+b+c+d+e+f=100% (weight).
2, spraying, the decontamination solution of this " hydro-peening (spilling) goes out "-food, the special-purpose sterilization of health also can be made of (weight %): a, at least a main bactericide following technical characterictic, they are cation quaternary ammonium salt type surfactants, as the ammonium chloride of the alkyl dimethyl (or dimethyl benzyl) of C12 or C14 or two C18 chains, and the C16 alkyl trimethyl ammonium bromide; Amphoteric surfactant, as C12 alkyl dimethyl betain, its content is 20-80%; Elemental iodine, glutaraldehyde, 3-35% hydrogen peroxide, 5% pyrethroid or 15% pyrethroid mixture (food, feeder tool forbidding), its content is 0-12%.B, atomizing, reinforcing agent: isopropyl alcohol, ethanol, 3-25%.C, water quality, soda acid inorganic agent: EDTA or its sodium salt, citric acid, lactic acid, tartaric acid, fumaric acid, malic acid, phosphorous acid, monoethanolamine, its content 0.1-18%.D, increased activity or colloid bleeding agent: nonionic surface active agent or its complex, its content are 0-25%.E, deodorizing, synergist: its content such as ethylene glycol, propane diols, glycerine are 0-10%.F and mixture: water is surplus.A+b+c+d+e+f=100%(weight).
3, this " hydro-peening (spilling) goes out " can be made of (below be weight percentage) following technical characterictic.
A, at least a main bactericide: wherein best proportioning is:
Dodecyl benzyl dimethyl ammonium chloride is 0-44%;
The myristyl dimethyl benzyl ammonium chloride is 0-28%;
Dioctadecyl dimethyl ammonium chloride is 0-32%;
Two decyl trimethylammonium bromides are 0-20%;
Softex kw is 0-10%;
Dodecyl (or cetyl) dimethyl betaine is 0-80%;
Elemental iodine is 0-8%.
7.5% or 15% hydrogen peroxide (being adjusted to 30-35% hydrogen peroxide raw material) is 0-12%;
5% chlorine cyanogen (or bromine cyanogen) chrysanthemum ester or its mixture of 15% are 0-15%, only limit to desinsection, non-food stuff, feeder tool sterilized sanitary accessories.
Its mixture of 15% is that the shelled sesame oil that adds 2 times of chrysanthemum ester contents in chlorine cyanogen (or bromine cyanogen) the chrysanthemum ester 5% is formed.
B, atomizing, the best proportioning of reinforcing agent are:
Isopropyl alcohol, ethanol, 3-15%.
C, water quality, acid-base modifier, its best proportioning is:
The EDTA disodium, 0-1%;
Citric acid, 0-10%;
Lactic acid, 0-18%;
Phosphorous acid, 0-15%;
Monoethanolamine, 0-10%.
D, increased activity or colloid bleeding agent, its best proportioning is:
Alkylphenol polyoxyethylene OP-10,0-12%;
E, deodorizing, synergist.Its best proportioning is:
Propane diols, 0-10%;
Glycerine, 0-10%.
F, water are surplus.
A+b+c+d+e+f=100%(weight).
CN 94105320 1994-05-20 1994-05-20 " hydro-peening (spilling) goes out "---space spraying and the good long-acting sterilized solution of washing performance Pending CN1096631A (en)

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001002525A1 (en) * 1999-07-06 2001-01-11 Helen Dolisznyj An insecticidal cleaner
CN101108256B (en) * 2007-05-18 2010-05-19 张勤福 A kind of preparation method of biological antibacterial deodorant
CN102417282A (en) * 2011-08-24 2012-04-18 同济大学 Deodorant for treating biological sludge, preparation method and application of deodorant
CN101492632B (en) * 2009-03-02 2012-10-31 上海九誉生物科技有限公司 Composite disinfection detergent
CN103168776A (en) * 2012-12-19 2013-06-26 新疆德蓝股份有限公司 High-efficiency broad-spectrum bactericide
GB2500381A (en) * 2012-03-19 2013-09-25 Marine Harvest Scotland Ltd The combination of pyrethroid and hydrogen peroxide for control of ectoparasite infestation in fish
CN105943413A (en) * 2016-06-23 2016-09-21 李建 Antibacterial hand sanitizer
CN105943412A (en) * 2016-06-23 2016-09-21 李建 High-efficiency antibacterial hand sanitizer
CN105997574A (en) * 2016-06-23 2016-10-12 李建 Hand sanitizer with disinfection function
CN105997575A (en) * 2016-06-23 2016-10-12 李建 Compound liquid soap
CN106038358A (en) * 2016-06-23 2016-10-26 李建 Efficient hand sanitizer
CN106857659A (en) * 2017-04-01 2017-06-20 江西凝盛生物科技有限公司 A kind of thing table thimerosal of asepsis environment-protecting and preparation method thereof
CN107079925A (en) * 2017-05-08 2017-08-22 李潜德 Deodorization and sterilization hydro-peening liquid clean may just as well excellent and available for gas-solid liquid environment
CN108477209A (en) * 2018-05-30 2018-09-04 军事科学院系统工程研究院卫勤保障技术研究所 A kind of thimerosal and preparation method thereof

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001002525A1 (en) * 1999-07-06 2001-01-11 Helen Dolisznyj An insecticidal cleaner
CN101108256B (en) * 2007-05-18 2010-05-19 张勤福 A kind of preparation method of biological antibacterial deodorant
CN101492632B (en) * 2009-03-02 2012-10-31 上海九誉生物科技有限公司 Composite disinfection detergent
CN102417282A (en) * 2011-08-24 2012-04-18 同济大学 Deodorant for treating biological sludge, preparation method and application of deodorant
GB2500381A (en) * 2012-03-19 2013-09-25 Marine Harvest Scotland Ltd The combination of pyrethroid and hydrogen peroxide for control of ectoparasite infestation in fish
CN103168776A (en) * 2012-12-19 2013-06-26 新疆德蓝股份有限公司 High-efficiency broad-spectrum bactericide
CN105943413A (en) * 2016-06-23 2016-09-21 李建 Antibacterial hand sanitizer
CN105943412A (en) * 2016-06-23 2016-09-21 李建 High-efficiency antibacterial hand sanitizer
CN105997574A (en) * 2016-06-23 2016-10-12 李建 Hand sanitizer with disinfection function
CN105997575A (en) * 2016-06-23 2016-10-12 李建 Compound liquid soap
CN106038358A (en) * 2016-06-23 2016-10-26 李建 Efficient hand sanitizer
CN106857659A (en) * 2017-04-01 2017-06-20 江西凝盛生物科技有限公司 A kind of thing table thimerosal of asepsis environment-protecting and preparation method thereof
CN107079925A (en) * 2017-05-08 2017-08-22 李潜德 Deodorization and sterilization hydro-peening liquid clean may just as well excellent and available for gas-solid liquid environment
CN108477209A (en) * 2018-05-30 2018-09-04 军事科学院系统工程研究院卫勤保障技术研究所 A kind of thimerosal and preparation method thereof
CN108477209B (en) * 2018-05-30 2021-01-15 军事科学院系统工程研究院卫勤保障技术研究所 Disinfectant and preparation method thereof

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