CN109651817A - A kind of erosion-resisting silicone rubber compound and its preparation method and application - Google Patents
A kind of erosion-resisting silicone rubber compound and its preparation method and application Download PDFInfo
- Publication number
- CN109651817A CN109651817A CN201811622945.1A CN201811622945A CN109651817A CN 109651817 A CN109651817 A CN 109651817A CN 201811622945 A CN201811622945 A CN 201811622945A CN 109651817 A CN109651817 A CN 109651817A
- Authority
- CN
- China
- Prior art keywords
- parts
- erosion
- silicone rubber
- rubber compound
- antioxidant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920002379 silicone rubber Polymers 0.000 title claims abstract description 36
- 150000001875 compounds Chemical class 0.000 title claims abstract description 26
- 239000004945 silicone rubber Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 20
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 18
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 18
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 15
- 239000000956 alloy Substances 0.000 claims abstract description 15
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical class COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910017318 Mo—Ni Inorganic materials 0.000 claims abstract description 13
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 13
- 239000003822 epoxy resin Substances 0.000 claims abstract description 13
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 13
- 229920002050 silicone resin Polymers 0.000 claims abstract description 13
- LAQFLZHBVPULPL-UHFFFAOYSA-N methyl(phenyl)silicon Chemical compound C[Si]C1=CC=CC=C1 LAQFLZHBVPULPL-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000012856 packing Methods 0.000 claims abstract description 8
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims description 15
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 12
- 238000005453 pelletization Methods 0.000 claims description 12
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 6
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 5
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical group CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 4
- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 claims description 4
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
- -1 polysiloxane Polymers 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 claims description 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims 2
- JNRLEMMIVRBKJE-UHFFFAOYSA-N 4,4'-Methylenebis(N,N-dimethylaniline) Chemical group C1=CC(N(C)C)=CC=C1CC1=CC=C(N(C)C)C=C1 JNRLEMMIVRBKJE-UHFFFAOYSA-N 0.000 claims 1
- 239000007822 coupling agent Substances 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 claims 1
- 125000003944 tolyl group Chemical group 0.000 claims 1
- 238000005260 corrosion Methods 0.000 abstract description 16
- 230000007797 corrosion Effects 0.000 abstract description 15
- 239000000463 material Substances 0.000 abstract description 10
- 150000003839 salts Chemical class 0.000 abstract description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052802 copper Inorganic materials 0.000 abstract description 3
- 239000010949 copper Substances 0.000 abstract description 3
- 239000007921 spray Substances 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 description 6
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 4
- SPJXZYLLLWOSLQ-UHFFFAOYSA-N 1-[(1-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical compound C1CCCCC1(N)CC1(N)CCCCC1 SPJXZYLLLWOSLQ-UHFFFAOYSA-N 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 229920000260 silastic Polymers 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 241000784732 Lycaena phlaeas Species 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical group [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- YCIVSJFIXXVSRH-UHFFFAOYSA-N amino-methyl-phenylsilicon Chemical compound C[Si](N)C1=CC=CC=C1 YCIVSJFIXXVSRH-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 238000012946 outsourcing Methods 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 125000000725 trifluoropropyl group Chemical group [H]C([H])(*)C([H])([H])C(F)(F)F 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0862—Nickel
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of erosion-resisting silicone rubber compounds and its preparation method and application, and the silicone rubber compound is made of by weight following component: 35~51 parts of methyl phenyl silicone resins, 22~30 parts of poly epoxy resins, 15~19 parts of methyl methacrylates, 3~5 parts of Mo-Ni alloys, 12~15 parts of silane coupling agents, 2~4 parts of curing agent, 1~4 part of antioxidant.The silicone rubber compound has excellent corrosion resistance, material is used for copper electrode outer packing and carries out salt spray corrosion test, it is tested by long-time, apparent corrosion phenomenon is not found, it can be widely applied to the preparation of electrode outer packing, preparation method is simple, and material is easy to get, and is suitable for popularization and application.
Description
Technical field
The invention belongs to polymeric material fields, and in particular to a kind of erosion-resisting silicone rubber compound and preparation method thereof
And application.
Background technique
Silicon rubber refers to that main chain is alternately made of silicon and oxygen atom, and the rubber there are two organic group is usually connected on silicon atom
Glue.Common silicon rubber is mainly made of the silicon oxygen chain link containing methyl and a small amount of vinyl.Silicon rubber can be improved in the introducing of phenyl
High- and low-temperature resistance performance, the heatproof and oil resistance of silicon rubber then can be improved in the introducing of trifluoro propyl and cyano.Silicon rubber is resistance to low
Temperature is functional, generally remains to work at -55 DEG C.After introducing phenyl, reachable -73 DEG C.The heat resistance of silicon rubber is also very prominent
Out, at 180 DEG C can long-term work, a little higher than 200 DEG C can also bear several weeks or longer time it is still flexible, be instantaneously resistant to 300
DEG C or more high temperature.Although traditional silastic material has high temperature resistance, its corrosion resistance is not protruded, is especially needed
To be applied in electrode preparation, electrode generally understands one layer of silicone resin of outsourcing, and the electrode for preventing it internal is destroyed, therefore
Need anti-corrosion capability silastic material outstanding.
CN 108440885A discloses a kind of resin combination, uses acrylic resin, acrylic rubber, poly- ammonia
Ester rubber, silicon rubber are raw material, though resin combination obtained has excellent mechanical property and heat resistance, corrosion resistance
It can be general.
Summary of the invention
In view of the deficiencies of the prior art, the present invention provides a kind of erosion-resisting silicone rubber compound and preparation method thereof and
Using the silicone rubber compound has excellent corrosion resistance, and material is used for copper electrode outer packing and carries out salt air corrosion examination
It tests, is tested by long-time, do not find apparent corrosion phenomenon, can be widely applied to the preparation of electrode outer packing,
Preparation method is simple, and material is easy to get, and is suitable for popularization and application.
What the present invention made to be achieved through the following technical solutions:
A kind of erosion-resisting silicone rubber compound is made of by weight following component: 35~51 parts of aminomethyl phenyl silicon trees
Rouge, 22~30 parts of poly epoxy resins, 15~19 parts of methyl methacrylates, 3~5 parts of Mo-Ni alloys, 12~15 parts it is silane coupled
Agent, 2~4 parts of curing agent, 1~4 part of antioxidant.
Preferably, the silane coupling agent is vinyltrimethoxysilane or vinyltriethoxysilane.
Preferably, the curing agent is di-2-ethylhexylphosphine oxide hexamethylene alkanamine or diethylenetriamine.
Preferably, the antioxidant is antioxidant TPP or antioxidant 264.
A kind of preparation method of erosion-resisting silicone rubber compound, comprising the following steps:
Step 1) weigh by weight methyl phenyl silicone resin, poly epoxy resin, methyl methacrylate, Mo-Ni alloy,
Silane coupling agent is put into high-speed mixer, and 1000~1200r/min stirs 1~3h at 50~80 DEG C, and mixing masterbatch is made；
Step 1) mixing masterbatch obtained is mixed evenly step 2) with curing agent, antioxidant, puts into double roller mill
In machine, after 210~240 DEG C of melt blendings, extruding pelletization is cooled to room temperature, pelletizing, dry, obtains the erosion-resisting silicon
Rubber composition.
Application of the erosion-resisting silicone rubber compound in terms of electrode outer packing.
Beneficial effects of the present invention are as follows:
Mo-Ni alloy is the alloy that metallic element nickel is added by matrix element of metal molybdenum and forms, and is mainly situated between in reproducibility
It is used under conditions of matter corrosion, is a kind of best alloy of hydrochloric acid corrosion resistant.Erosion-resisting silicone rubber compound of the invention
There is excellent corrosion resistance in conjunction with silicone resin and auxiliary agent appropriate as raw material using Mo-Ni alloy.Material is used for copper
Electrode outer packing carries out salt spray corrosion test, tests by long-time, does not find apparent corrosion phenomenon, can widely answer
For the preparation of electrode outer packing, preparation method is simple, and material is easy to get, and is suitable for popularization and application.
Specific embodiment
The present invention will be further described combined with specific embodiments below.
Embodiment 1
A kind of erosion-resisting silicone rubber compound is made of by weight following component: 35 parts of methyl phenyl silicone resins, 22
Part poly epoxy resin, 15 parts of methyl methacrylates, 3 parts of Mo-Ni alloys, 12 parts of silane coupling agents, 2 parts of curing agent, 1 part of antioxygen
Agent.
In the present embodiment, the silane coupling agent uses vinyltrimethoxysilane, and the curing agent uses methylene
Bis cyclohexane amine, the antioxidant use antioxidant TPP.
Preparation method includes the following steps:
(1) 35 parts of methyl phenyl silicone resins, 22 parts of poly epoxy resins, 15 parts of methyl methacrylates, 3 are weighed by weight
Part Mo-Ni alloy, 12 parts of vinyltrimethoxysilanes, put into high-speed mixer, and 1000r/min stirs 1h at 50 DEG C, are made
Mix masterbatch.
(2) mixing masterbatch obtained and 2 parts of di-2-ethylhexylphosphine oxide hexamethylene alkanamines, 1 part of antioxidant TPP are mixed evenly, are thrown
Entering in two-roll mill, after 210 DEG C of melt blendings, extruding pelletization is cooled to room temperature, pelletizing, and it is dry, it obtains described anticorrosive
Silicone rubber compound.
Embodiment 2
A kind of erosion-resisting silicone rubber compound is made of by weight following component: 51 parts of methyl phenyl silicone resins, 30
Part poly epoxy resin, 19 parts of methyl methacrylates, 5 parts of Mo-Ni alloys, 15 parts of silane coupling agents, 4 parts of curing agent, 4 parts of antioxygens
Agent.
In the present embodiment, the silane coupling agent uses vinyltriethoxysilane, and the curing agent uses divinyl
Triamine, the antioxidant use antioxidant 264.
Preparation method includes the following steps:
(1) 51 parts of methyl phenyl silicone resins, 30 parts of poly epoxy resins, 19 parts of methyl methacrylates, 5 are weighed by weight
Part Mo-Ni alloy, 15 parts of vinyltriethoxysilane, put into high-speed mixer, and 1200r/min stirs 3h at 80 DEG C, are made
Mix masterbatch.
(2) mixing masterbatch obtained and 4 parts of diethylenetriamines, 4 parts of antioxidant 264s are mixed evenly, put into double roller
In open mill, after 240 DEG C of melt blendings, extruding pelletization is cooled to room temperature, pelletizing, dry, obtains the erosion-resisting silicon rubber
Glue composition.
Embodiment 3
A kind of erosion-resisting silicone rubber compound is made of by weight following component: 43 parts of methyl phenyl silicone resins, 25
Part poly epoxy resin, 16 parts of methyl methacrylates, 4 parts of Mo-Ni alloys, 14 parts of silane coupling agents, 3 parts of curing agent, 3 parts of antioxygens
Agent.
In the present embodiment, the silane coupling agent uses vinyltriethoxysilane, and the curing agent uses methylene
Bis cyclohexane amine, the antioxidant use antioxidant 264.
Preparation method includes the following steps:
(1) 43 parts of methyl phenyl silicone resins, 25 parts of poly epoxy resins, 16 parts of methyl methacrylates, 4 are weighed by weight
Part Mo-Ni alloy, 14 parts of vinyltriethoxysilane, put into high-speed mixer, and 1100r/min stirs 2h at 60 DEG C, are made
Mix masterbatch.
(2) mixing masterbatch obtained and 3 parts of di-2-ethylhexylphosphine oxide hexamethylene alkanamines, 3 parts of antioxidant 264s are mixed evenly, are thrown
Entering in two-roll mill, after 225 DEG C of melt blendings, extruding pelletization is cooled to room temperature, pelletizing, and it is dry, it obtains described anticorrosive
Silicone rubber compound.
Comparative example 1
A kind of erosion-resisting silicone rubber compound is made of by weight following component: 47 parts of methyl phenyl silicone resins, 24
Part poly epoxy resin, 18 parts of methyl methacrylates, 14 parts of silane coupling agents, 3 parts of curing agent, 2 parts of antioxidant.
In the present embodiment, the silane coupling agent uses vinyltriethoxysilane, and the curing agent uses methylene
Bis cyclohexane amine, the antioxidant use antioxidant 264.
Preparation method includes the following steps:
(1) weigh by weight 47 parts of methyl phenyl silicone resins, 24 parts of poly epoxy resins, 18 parts of methyl methacrylates,
14 parts of vinyltriethoxysilane are put into high-speed mixer, and 1100r/min stirs 2h at 60 DEG C, and mixing masterbatch is made.
(2) mixing masterbatch obtained and 3 parts of di-2-ethylhexylphosphine oxide hexamethylene alkanamines, 2 parts of antioxidant 264s are mixed evenly, are thrown
Entering in two-roll mill, after 225 DEG C of melt blendings, extruding pelletization is cooled to room temperature, pelletizing, and it is dry, obtain rubber composition
Object.
Test case 1
Silicone rubber compound made from erosion-resisting silicone rubber compound made from Examples 1 to 3 and comparative example 1 is distinguished
It is wrapped in except common copper electrode, carries out the test of salt air corrosion performance, as a result such as the following table 1.
1 test result of table
According to the test result of table 1, it can be deduced that the silastic material can be resisted effectively as the outer packaging layer of electrode
Corrosion phenomenon under acid or alkali environment reduces costs indirectly to improve the service life of electrode.
Claims (6)
1. a kind of erosion-resisting silicone rubber compound, which is characterized in that be made of by weight following component: 35~51 parts of methyl
Phenyl polysiloxane, 22~30 parts of poly epoxy resins, 15~19 parts of methyl methacrylates, 3~5 parts of Mo-Ni alloys, 12~15 parts
Silane coupling agent, 2~4 parts of curing agent, 1~4 part of antioxidant.
2. a kind of erosion-resisting silicone rubber compound according to claim 1, which is characterized in that the silane coupling agent is
Vinyltrimethoxysilane or vinyltriethoxysilane.
3. a kind of erosion-resisting silicone rubber compound according to claim 1, which is characterized in that the curing agent is methylene
Base bis cyclohexane amine or diethylenetriamine.
4. a kind of erosion-resisting silicone rubber compound according to claim 1, which is characterized in that the antioxidant is antioxygen
Agent TPP or antioxidant 264.
5. a kind of preparation method of erosion-resisting silicone rubber compound described in claim 1, which is characterized in that including following step
It is rapid:
Step 1) weighs methyl phenyl silicone resin, poly epoxy resin, methyl methacrylate, Mo-Ni alloy, silane by weight
Coupling agent is put into high-speed mixer, and 1000~1200r/min stirs 1~3h at 50~80 DEG C, and mixing masterbatch is made；
Step 1) mixing masterbatch obtained is mixed evenly step 2) with curing agent, antioxidant, puts into two-roll mill,
After 210~240 DEG C of melt blendings, extruding pelletization is cooled to room temperature, pelletizing, dry, obtains the erosion-resisting silicon rubber group
Close object.
6. application of the erosion-resisting silicone rubber compound in terms of electrode outer packing as described in claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811622945.1A CN109651817A (en) | 2018-12-28 | 2018-12-28 | A kind of erosion-resisting silicone rubber compound and its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811622945.1A CN109651817A (en) | 2018-12-28 | 2018-12-28 | A kind of erosion-resisting silicone rubber compound and its preparation method and application |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109651817A true CN109651817A (en) | 2019-04-19 |
Family
ID=66117296
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811622945.1A Pending CN109651817A (en) | 2018-12-28 | 2018-12-28 | A kind of erosion-resisting silicone rubber compound and its preparation method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109651817A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105754298A (en) * | 2016-05-09 | 2016-07-13 | 李红玉 | Corrosion-resistant buried communication pipe and preparation method thereof |
| CN106317897A (en) * | 2015-06-30 | 2017-01-11 | 信越化学工业株式会社 | Sealing material for solid polymer fuel cell separator, separator seal and separator |
| CN107698978A (en) * | 2017-08-22 | 2018-02-16 | 浙江久运汽车零部件有限公司 | A kind of modified flame-retardant silicone rubber compounds |
-
2018
- 2018-12-28 CN CN201811622945.1A patent/CN109651817A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106317897A (en) * | 2015-06-30 | 2017-01-11 | 信越化学工业株式会社 | Sealing material for solid polymer fuel cell separator, separator seal and separator |
| CN105754298A (en) * | 2016-05-09 | 2016-07-13 | 李红玉 | Corrosion-resistant buried communication pipe and preparation method thereof |
| CN107698978A (en) * | 2017-08-22 | 2018-02-16 | 浙江久运汽车零部件有限公司 | A kind of modified flame-retardant silicone rubber compounds |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110041869A (en) | A kind of modified epoxy injecting type anchoring adhesive and preparation method thereof | |
| CN111777994A (en) | Heat-conducting gel and preparation method thereof | |
| CN102382552A (en) | Low temperature cured solvent-free epoxy anticorrosion paint and its preparation method | |
| JP6013906B2 (en) | Liquid epoxy resin composition | |
| WO2017028008A1 (en) | High-refractive-index, high-toughness and vulcanization-resistant led packaging silicone | |
| EP3354674A1 (en) | Liquid epoxy resin composition | |
| CN110845852A (en) | High-thermal-conductivity liquid silicone rubber and preparation method and application thereof | |
| CN104292755A (en) | High-molecule LED (Light-Emitting Diode) packaging material and preparation method thereof | |
| CN111978726A (en) | A kind of thermosetting resin composition and its preparation method and use | |
| CN115838535A (en) | Bi-component heat-conducting gel and preparation method thereof | |
| CN109913081A (en) | A kind of solvent-free and high temperature-resistant anticorrosive paint for crude oil storage tank | |
| JP6497652B2 (en) | Epoxy resin molding material for sealing and electronic parts | |
| CN102382555B (en) | Solvent-free low-temperature solidified phenolic epoxy anticorrosive paint and preparation method thereof | |
| CN109651817A (en) | A kind of erosion-resisting silicone rubber compound and its preparation method and application | |
| CN104332309A (en) | Potting material of metallic film capacitor | |
| CN101503608B (en) | A kind of novolac epoxy resin system conductive adhesive and preparation method thereof | |
| TWI621685B (en) | Conductive adhesive and semiconductor device | |
| JP5053930B2 (en) | Epoxy resin composition for semiconductor encapsulation and semiconductor device using the same | |
| CN108795137A (en) | Modified warming agent and reversible thermocoating and preparation method thereof and product | |
| WO2026007360A1 (en) | Epoxy resin molding material for c-mold process and preparation method therefor and use thereof | |
| JP4525079B2 (en) | Thermosetting liquid encapsulating resin composition and semiconductor device using the same | |
| CN106433405A (en) | Polyaniline graphene anti-corrosion coating and preparation method thereof | |
| CN117986810B (en) | A zero-VOC water-based thermally conductive insulating resin composition and preparation method thereof | |
| JP6115758B2 (en) | Liquid epoxy resin composition and semiconductor device using the same | |
| CN109735299A (en) | High-adhesion yellowing-resistant joint filling adhesive and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190419 |
|
| RJ01 | Rejection of invention patent application after publication |