CN109649030A - Caloric transfer printing technology and ink - Google Patents
Caloric transfer printing technology and ink Download PDFInfo
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- CN109649030A CN109649030A CN201811581675.4A CN201811581675A CN109649030A CN 109649030 A CN109649030 A CN 109649030A CN 201811581675 A CN201811581675 A CN 201811581675A CN 109649030 A CN109649030 A CN 109649030A
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- ink
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- photoinitiator
- transfer printing
- printing technology
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- 238000005516 engineering process Methods 0.000 title claims abstract description 31
- 238000010023 transfer printing Methods 0.000 title claims abstract description 30
- 238000007639 printing Methods 0.000 claims abstract description 86
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 36
- 239000010959 steel Substances 0.000 claims abstract description 36
- 239000004925 Acrylic resin Substances 0.000 claims description 32
- 239000002270 dispersing agent Substances 0.000 claims description 26
- 229920000178 Acrylic resin Polymers 0.000 claims description 22
- 229920000728 polyester Polymers 0.000 claims description 22
- 239000004593 Epoxy Substances 0.000 claims description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 20
- 229920000058 polyacrylate Polymers 0.000 claims description 16
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 15
- 239000002318 adhesion promoter Substances 0.000 claims description 15
- 229920000570 polyether Polymers 0.000 claims description 15
- 239000000178 monomer Substances 0.000 claims description 14
- 239000002344 surface layer Substances 0.000 claims description 12
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 11
- 125000005375 organosiloxane group Chemical group 0.000 claims description 11
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 10
- 229920005573 silicon-containing polymer Polymers 0.000 claims description 10
- 238000007711 solidification Methods 0.000 claims description 8
- 230000008023 solidification Effects 0.000 claims description 8
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical group C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 claims description 7
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 claims description 7
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical compound [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 claims description 6
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 5
- 238000013007 heat curing Methods 0.000 claims description 5
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 4
- 238000000016 photochemical curing Methods 0.000 claims description 4
- 239000003999 initiator Substances 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 229910000077 silane Inorganic materials 0.000 claims 1
- 239000003086 colorant Substances 0.000 abstract description 23
- 238000000034 method Methods 0.000 abstract description 11
- 230000008569 process Effects 0.000 abstract description 9
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 238000012546 transfer Methods 0.000 abstract description 3
- 239000000049 pigment Substances 0.000 description 57
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- -1 methylsiloxane Chemical class 0.000 description 8
- 239000000853 adhesive Substances 0.000 description 7
- 230000001070 adhesive effect Effects 0.000 description 7
- 229940106691 bisphenol a Drugs 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 4
- OLPZCIDHOZATMA-UHFFFAOYSA-N 2,2-dioxooxathiiran-3-one Chemical compound O=C1OS1(=O)=O OLPZCIDHOZATMA-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- ZMDDERVSCYEKPQ-UHFFFAOYSA-N Ethyl (mesitylcarbonyl)phenylphosphinate Chemical class C=1C=CC=CC=1P(=O)(OCC)C(=O)C1=C(C)C=C(C)C=C1C ZMDDERVSCYEKPQ-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- ONTQJDKFANPPKK-UHFFFAOYSA-L chembl3185981 Chemical compound [Na+].[Na+].CC1=CC(C)=C(S([O-])(=O)=O)C=C1N=NC1=CC(S([O-])(=O)=O)=C(C=CC=C2)C2=C1O ONTQJDKFANPPKK-UHFFFAOYSA-L 0.000 description 3
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 3
- 238000001723 curing Methods 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 125000005520 diaryliodonium group Chemical group 0.000 description 3
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 3
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 235000019239 indanthrene blue RS Nutrition 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 235000010215 titanium dioxide Nutrition 0.000 description 2
- PLXMOAALOJOTIY-FPTXNFDTSA-N Aesculin Natural products OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)[C@H]1Oc2cc3C=CC(=O)Oc3cc2O PLXMOAALOJOTIY-FPTXNFDTSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000003854 Surface Print Methods 0.000 description 1
- 206010000496 acne Diseases 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001768 cations Chemical group 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000012955 diaryliodonium Substances 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical group CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- HOCOIDRZLNGZMV-UHFFFAOYSA-N ethoxy(oxido)phosphanium Chemical compound CCO[PH2]=O HOCOIDRZLNGZMV-UHFFFAOYSA-N 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000007649 pad printing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- HPAFOABSQZMTHE-UHFFFAOYSA-N phenyl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)C1=CC=CC=C1 HPAFOABSQZMTHE-UHFFFAOYSA-N 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 229940099800 pigment red 48 Drugs 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 150000003254 radicals Chemical group 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0023—Digital printing methods characterised by the inks used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
- B41M5/0256—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet the transferable ink pattern being obtained by means of a computer driven printer, e.g. an ink jet or laser printer, or by electrographic means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/0081—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using electromagnetic radiation or waves, e.g. ultraviolet radiation, electron beams
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/009—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using thermal means, e.g. infrared radiation, heat
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Electromagnetism (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to a kind of caloric transfer printing technology and its ink, caloric transfer printing technology is printed ink to bat printing steel plate by predetermined pattern by digital printing the following steps are included: ink is loaded into the print cartridge of digital printing device；Ink on ultraviolet light precuring bat printing steel plate；The viscous ink taken on bat printing steel plate of shift printing rubber head, is then transferred on stock.Digital printing and caloric transfer printing technology are combined together, matched colors by computer according to predetermined pattern, and according to the color demand of predetermined pattern, will be since ink print to be on bat printing steel plate, complete pattern is disposably prepared in realization；Being solidified by ultraviolet light, which improves the viscosity of ink, is suitble to transfer, is then transferred on stock by transferring rubber head；By digital printing formed patterns, monochromatic or multicolor patterns can be formed, it is once-forming, do not have to repeatedly trapping printing, it is therefore prevented that the problem of covering color shift, and process is simplified, reduce production cost.
Description
Technical field
The present invention relates to printing technology and printing material technical fields, more particularly to caloric transfer printing technology and ink.
Background technique
Bat printing, can in irregular special-shaped subject surface printing word, figure and image, just becoming now a kind of important
Specialty printing.Traditional tampon-printing process is printing ink in surface of steel plate, and pattern is presented on surface of steel plate, then again by steel plate
On ink adhesion in shift printing rubber head, by shift printing rubber head by ink adhesion on workpiece.This traditional pad printing method needs
Following process: upper photoresists, printing down, development and etching steel plate, a process can be only done printing and the bat printing of a kind of color, when
When pattern is multiple color, printing and bat printing repeatedly is needed, set color shift is easy to produce, leads to the mistake of intersection color
Very, and process is many and diverse, high production cost.
Summary of the invention
Based on this, the present invention provides a kind of caloric transfer printing technology, by digital printing formed patterns, can form monochromatic or polychrome
Pattern, it is once-forming, do not have to chromatography, it is therefore prevented that the problem of covering color shift simplifies process, reduce production cost.
A kind of caloric transfer printing technology, comprising the following steps:
Ink is loaded into the print cartridge of digital printing device, is printed ink to shifting by predetermined pattern by digital printing
It prints on steel plate；
Ink on ultraviolet light precuring bat printing steel plate；
The viscous ink taken on bat printing steel plate of shift printing rubber head, is then transferred on stock.
Above-mentioned caloric transfer printing technology, digital printing and caloric transfer printing technology are combined together, by computer according to predetermined pattern
Color matching, and according to the color demand of predetermined pattern, it will realize because ink print is on bat printing steel plate and disposably prepare complete graph
Case；Being solidified by ultraviolet light, which improves the viscosity of ink, is suitble to transfer, is then transferred on stock by transferring rubber head；Pass through
Digital printing formed patterns can form monochromatic or multicolor patterns, once-forming, not have to repeatedly trapping printing, it is therefore prevented that set
The problem of color shift, and process is simplified, reduce production cost.
The temperature of print cartridge is kept for 50 DEG C~65 DEG C in one of the embodiments,.
Ultraviolet light wavelength is 250nm~420nm in one of the embodiments, and luminous intensity is 95~130mw/
cm2, irradiation time is 5~30 seconds.
After ink is transferred to stock in one of the embodiments, heat cure or photocuring are also carried out.
Ink includes the component of following mass percentage in one of the embodiments:
Acrylic polymer is polyester acrylate resin and/or epoxy acrylic resin in one of the embodiments,；It is single
Body is 1,6 hexanediol diacrylate or trimethylolpropane trimethacrylate；Photoinitiator be surface layer solidify photoinitiator and
Deep cure photoinitiator；Adhesion promoter is silane coupling agent；Dispersing agent is type siloxane dispersing agent；Levelling agent is poly- two
At least one of methylsiloxane, polyether polyester azo polyether polyeste and alkyl-modified organosiloxane.
In one of the embodiments, surface layer solidify 3~5:1 of mass ratio of photoinitiator and deep cure photoinitiator~
2。
Ink is 300CPS~500CPS in the viscosity of 50 DEG C of temperature in one of the embodiments,.
The present invention also provides a kind of ink to obtain good printing effect suitable for above-mentioned caloric transfer printing technology, and turns
Pattern shows full cleaning after print, and adhesive force is good.The ink includes the component of following mass percentage:
Acrylic polymer is polyester acrylate resin and/or epoxy acrylic resin in one of the embodiments,；It is single
Body is 1,6 hexanediol diacrylate or trimethylolpropane trimethacrylate；Photoinitiator be surface layer solidify photoinitiator and
Deep cure photoinitiator, surface layer solidify mass ratio 3~5:1~2 of photoinitiator and deep cure photoinitiator；Attachment is made every effort to promote
It is silane coupling agent into agent；Dispersing agent is type siloxane dispersing agent；Levelling agent is dimethyl silicone polymer, polyether polyester modification has
At least one of organic siloxane and alkyl-modified organosiloxane.
Specific embodiment
It to facilitate the understanding of the present invention, below will be to invention is more fully described.But the present invention can be to be permitted
Mostly different form is realized, however it is not limited to embodiment described herein.On the contrary, purpose of providing these embodiments is makes
It is more thorough and comprehensive to the understanding of the disclosure.
Unless otherwise defined, all technical and scientific terms used herein and belong to technical field of the invention
The normally understood meaning of technical staff is identical.Term as used herein in the specification of the present invention is intended merely to description tool
The purpose of the embodiment of body, it is not intended that in the limitation present invention.
The present invention provides a kind of caloric transfer printing technology, and digital printing and caloric transfer printing technology are combined together, and passes through computer root
It matches colors according to predetermined pattern, and according to the color demand of predetermined pattern, it will be disposable in realizing on bat printing steel plate due to ink print
Prepare complete pattern.The caloric transfer printing technology the following steps are included:
S110: ink being loaded into the print cartridge of digital printing device, is matched colors according to the pattern of computer, the oil of each color
Ink, will be on ink print to bat printing steel plate by predetermined pattern by corresponding type channel.
In one embodiment, the temperature of print cartridge is kept for 50 DEG C~65 DEG C, and the viscosity of ink is reduced by heating, has ink
The problem of having good mobility, be suitable for digital printing, reducing spray head blocking, but temperature is unsuitable excessively high, when being such as higher than 65 DEG C,
Constituent part in ink can generate reaction and lose subsequent reactivity, influence the adhesive force of printing effect and ink.
S210: the ink on ultraviolet light precuring bat printing steel plate.
In one embodiment, ultraviolet light wavelength is 250nm~420nm, and luminous intensity is 95~130mw/cm2, this light
The problem of intensity can make ink rapid curing, and it is uneven to generate solidification, form particle pimple, irradiation time is 5~
30 seconds.
S310: the viscous ink taken on bat printing steel plate of shift printing rubber head is then transferred on stock.
In one embodiment, after ink is transferred to stock, heat cure or photocuring is also carried out, keeps the component of ink abundant
Reaction, increases the adhesive force of ink.Thermosetting, which turns to, to be heating and curing, and heating temperature is 80 DEG C~105 DEG C.Photocuring is infrared light photograph
Penetrate solidification.
In one embodiment, ink includes the component of following mass percentage: acrylic polymer 35%~50%, list
Body 10%~25%, photoinitiator 5%~12%, adhesion promoter 5%~10%, dispersing agent 0.3%~3%, levelling agent
1%~7% and pigment 1%~10%.After ultraviolet light, photoinitiator absorbs ultraviolet light-initiated each component and generates crosslinking instead
It answers, forms cross-linked structure, and then improve viscosity, form the more stable pattern of shape；Dispersing agent is mainly used for increasing each component
Dispersion degree makes to be uniformly mixed, and reduces the formation of defoaming, makes the better effect of digital printing；Levelling agent can make to print on bat printing
The ink of steel plate has preferable surface tension, paves by predetermined pattern, avoids the poly- drop of ink, influences forming effect；Adhesive force
Promotor can promote each component and further react, and be attached to ink more securely on stock.
In one embodiment, acrylic polymer is polyester acrylate resin and/or epoxy acrylic resin, polyester
The number-average molecular weight of acid resin is 1000~6000, and epoxy acrylic resin is the epoxy acrylic resin without bisphenol-A ingredient,
Its number-average molecular weight is 700~2000.
In one embodiment, monomer 1,6- hexanediyl ester or trimethylolpropane trimethacrylate.
In one embodiment, photoinitiator is that surface layer solidifies photoinitiator and deep cure photoinitiator, and surface layer solidifies light
Initiator and deep cure photoinitiator are used cooperatively, make ink pellet surface and inside can deep reaction, and solidification speed can be accelerated
Degree.It is cation light initiator that surface layer, which solidifies photoinitiator, such as can be, but be not limited to diaryl iodonium salt, triaryl sulphur
Salt, alkyl sulfosalt, sulfonyloxy ketone or triaryl silicon oxygen ether etc.；Deep cure photoinitiator is free radical photo-initiation,
Such as can be, but be not limited to 24,6- trimethylbenzoy-dipheny phosphine oxides or 2,4,6- trimethylbenzoyl benzene
Base phosphinic acid ethyl ester etc..
In one embodiment, surface layer solidifies mass ratio 3~5:1~2 of photoinitiator and deep cure photoinitiator, forming
Effect is best.
In one embodiment, adhesion promoter is silane coupling agent, such as can be vinyltriethoxysilane, second
Alkenyl trimethoxy silane or isobutyl ethyl triethoxy silicane etc., using in silane coupling agent containing electron rich functional group and propylene
The reaction such as sour prepolymer, monomer, promotes crosslinking.
In one embodiment, dispersing agent is type siloxane dispersing agent.
In one embodiment, levelling agent is dimethyl silicone polymer, polyether polyester azo polyether polyeste and alkyl-modified
At least one of organosiloxane, such as can change for dimethyl silicone polymer, polyether polyester azo polyether polyeste, alkyl
Property organosiloxane, the mixing of dimethyl silicone polymer and polyether polyester azo polyether polyeste, polyether polyester modified organic silicon
The mixing of oxygen alkane and alkyl-modified organosiloxane, the mixing of dimethyl silicone polymer and alkyl-modified organosiloxane or poly-
The mixing of dimethyl siloxane, polyether polyester azo polyether polyeste and alkyl-modified organosiloxane.
The problem of in one embodiment, ink is 300CPS~500CPS in the viscosity of 50 DEG C of temperature, reduces spray head blocking,
And while taking into account printing effect, curing time is reduced.So more preferably, digital printing uses high viscosity spray head.
In one embodiment, pigment is selected from pigment yellow 1, pigment yellow 3, pigment Yellow 12, pigment yellow 13, pigment Yellow 14, pigment
Huang 17, pigment yellow 42, pigment yellow 74, yellow -81, pigment yellow 83, pigment yellow 87, pigment yellow 93, pigment yellow 95, pigment yellow 109, face
Expect yellow 120, pigment Yellow 12 8, pigment yellow 13 8, pigment yellow 13 9, pigment yellow 150, pigment yellow 151, pigment yellow 166, pigment yellow
180, pigment yellow 185, pigment orange 16, pigment orange 36, pigment orange 38, paratonere 5, paratonere 22, pigment red 38, pigment red 48:
1, pigment red 4 8:2, pigment red 4 8:4, pigment red 4 9:1, paratonere 53:1, paratonere 57:1, paratonere 63:1, paratonere
101, pigment red 122, paratonere 144, pigment red 146, paratonere 177, paratonere 185, pigment violet 19, pigment Violet 23, pigment
Blue 15:1, pigment blue 15: 3, pigment blue 15: 4, pigment blue 18, pigment blue 27, pigment blue 19, pigment blue 60, pigment Green 7, pigment
Green 36, one of Pigment white 6, Pigment white 18, Pigment white 21 and pigment black 7.
Above-mentioned caloric transfer printing technology, digital printing and caloric transfer printing technology are combined together, by computer according to predetermined pattern
Color matching, and according to the color demand of predetermined pattern, will be since ink print be on bat printing steel plate, realizing disposable formulating colorful figure
Case；Being solidified by ultraviolet light, which improves the viscosity of ink, is suitble to transfer, is then transferred on stock by transferring rubber head；Pass through
Digital printing formed patterns can form monochromatic or multicolor patterns, once-forming, not have to repeatedly trapping printing, it is therefore prevented that set
The problem of color shift, and process is simplified, reduce production cost.
The following are embodiments to illustrate.
Embodiment 1
The present embodiment caloric transfer printing technology the following steps are included:
S100: ink is prepared, ink includes the component of following mass percentage: acrylic polymer 35%, monomer
26%, photoinitiator 10.6%, adhesion promoter 10%, dispersing agent 0.4%, levelling agent 7% and pigment 11%.
Acrylic polymer is polyester acrylate resin and/or epoxy acrylic resin, and the number of polyester acrylate resin is equal
Molecular weight is 2000, and epoxy acrylic resin is the epoxy acrylic resin without bisphenol-A ingredient, and number-average molecular weight is
2000。
Monomer is 1,6 hexanediol diacrylate.
Photoinitiator is triaryl silicon oxygen ether and 2,4,6- trimethylbenzoy-dipheny phosphine oxides, triaryl silicon oxygen
The mass ratio 3:1 of ether and 2,4,6- trimethylbenzoy-dipheny phosphine oxide.
Adhesion promoter is vinyltriethoxysilane.
Dispersing agent is type siloxane dispersing agent.
Levelling agent is dimethyl silicone polymer.
Ink is 500CPS in the viscosity of 50 DEG C of temperature.
The present embodiment uses the ink of two kinds of colors, and the pigment of the ink of two kinds of colors is respectively pigment yellow 95 and Pigment white
21
S110: the ink of two kinds of colors being loaded into respectively in the print cartridge of digital printing device, and the temperature of print cartridge keeps 55
It ± 1 DEG C, is matched colors according to the pattern of computer, the ink of each color is played ink by predetermined pattern by corresponding type channel
On print to bat printing steel plate.
S210: the ink on ultraviolet light precuring bat printing steel plate, ultraviolet light wavelength are 250nm~420nm, light
Intensity is 100mw/cm2, irradiation time is 10 seconds.
S310: the viscous ink taken on bat printing steel plate of shift printing rubber head is then transferred on stock.
S410: Infrared irradiation solidification is carried out to the ink on stock.
Embodiment 2
The present embodiment caloric transfer printing technology the following steps are included:
S100: ink is prepared, ink includes the component of following mass percentage: acrylic polymer 41%, monomer
25%, photoinitiator 5%, adhesion promoter 9%, dispersing agent 3%, levelling agent 7% and pigment 10%.
Acrylic polymer is polyester acrylate resin and/or epoxy acrylic resin, and the number of polyester acrylate resin is equal
Molecular weight is 4000, and epoxy acrylic resin is the epoxy acrylic resin without bisphenol-A ingredient, and number-average molecular weight is
1500。
Monomer is 1,6 hexanediol diacrylate.
Photoinitiator is diaryl iodonium salt and 2,4,6- trimethylbenzoy-dipheny phosphine oxides, Diaryl iodonium
The mass ratio 4:2 of salt and 2,4,6- trimethylbenzoy-dipheny phosphine oxide.
Adhesion promoter is vinyltrimethoxysilane.
Dispersing agent is type siloxane dispersing agent.
Levelling agent is alkyl-modified organosiloxane.
Ink is 450CPS in the viscosity of 50 DEG C of temperature.
The present embodiment uses the ink of four kinds of colors, and the pigment of the ink of four kinds of colors is respectively pigment orange 36, paratonere
48:2, pigment violet 19 and pigment black 7.
S110: the ink of four kinds of colors being loaded into respectively in the print cartridge of digital printing device, and the temperature of print cartridge keeps 51
It ± 1 DEG C, is matched colors according to the pattern of computer, the ink of each color is played ink by predetermined pattern by corresponding type channel
On print to bat printing steel plate.
S210: the ink on ultraviolet light precuring bat printing steel plate, ultraviolet light wavelength are 250nm~420nm, light
Intensity is 95mw/cm2, irradiation time is 30 seconds.
S310: the viscous ink taken on bat printing steel plate of shift printing rubber head is then transferred on stock.
S410: Infrared irradiation solidification is carried out to the ink on stock.
Embodiment 3
The present embodiment caloric transfer printing technology the following steps are included:
S100: ink is prepared, ink includes the component of following mass percentage: acrylic polymer 44%, monomer
24%, photoinitiator 12%, adhesion promoter 6%, dispersing agent 2.5%, levelling agent 1.5% and pigment 10%.
Acrylic polymer is epoxy acrylic resin, and epoxy acrylic resin is the propylene oxide without bisphenol-A ingredient
Acid resin, number-average molecular weight 2000.
Monomer is trimethylolpropane trimethacrylate.
Photoinitiator is triaryl silicon oxygen ether and 2,4,6- trimethylbenzoyl phenyl phosphinic acid ethyl esters, triaryl silicon oxygen ether
With the mass ratio 5:2 of 2,4,6- trimethylbenzoyl phenyl phosphinic acid ethyl ester.
Adhesion promoter is vinyltriethoxysilane.
Dispersing agent is type siloxane dispersing agent.
Levelling agent is dimethyl silicone polymer.
Ink is 320CPS in the viscosity of 50 DEG C of temperature.
The present embodiment uses the ink of three kinds of colors, and the pigment of the ink of three kinds of colors is respectively pigment yellow 1, pigment blue 19
With Pigment white 18.
S110: the ink of three kinds of colors being loaded into the print cartridge of digital printing device, and the temperature of print cartridge keeps 60 ± 1
DEG C, matched colors according to the pattern of computer, the ink of each color by corresponding type channel, by predetermined pattern by ink print extremely
On bat printing steel plate.
S210: the ink on ultraviolet light precuring bat printing steel plate, ultraviolet light wavelength are 250nm~420nm, light
Intensity is 110mw/cm2, irradiation time is 18 seconds.
S310: the viscous ink taken on bat printing steel plate of shift printing rubber head is then transferred on stock.
S410: Infrared irradiation solidification is carried out to the ink on stock.
Embodiment 4
The present embodiment caloric transfer printing technology the following steps are included:
S100: ink is prepared, ink includes the component of following mass percentage: acrylic polymer 48%, monomer
18%, photoinitiator 12%, adhesion promoter 10%, dispersing agent 1.6%, levelling agent 6.4% and pigment 4%.
Acrylic polymer is epoxy acrylic resin, and epoxy acrylic resin is the propylene oxide without bisphenol-A ingredient
Acid resin, number-average molecular weight 1000.
Monomer is trimethylolpropane trimethacrylate.
Photoinitiator be alkyl sulfosalt and 2,4,6- trimethylbenzoy-dipheny phosphine oxides, alkyl sulfosalt and
The mass ratio 4:1 of 2,4,6- trimethylbenzoy-dipheny phosphine oxide.
Adhesion promoter is isobutyl ethyl triethoxy silicane.
Dispersing agent is type siloxane dispersing agent.
Levelling agent is alkyl-modified organosiloxane.
Ink is 401CPS in the viscosity of 50 DEG C of temperature.
The present embodiment uses the ink of three kinds of colors, and the pigment of the ink of three kinds of colors is respectively paratonere 101, pigment violet
19 and pigment black 7.
S110: the ink of three kinds of colors being loaded into the print cartridge of digital printing device, and the temperature of print cartridge keeps 55 ± 1
DEG C, matched colors according to the pattern of computer, the ink of each color by corresponding type channel, by predetermined pattern by ink print extremely
On bat printing steel plate.
S210: the ink on ultraviolet light precuring bat printing steel plate, ultraviolet light wavelength are 250nm~420nm, light
Intensity is 126mw/cm2, irradiation time is 10 seconds.
S310: the viscous ink taken on bat printing steel plate of shift printing rubber head is then transferred on stock.
S410: heat cure is carried out to the ink on stock, heating temperature is 85 DEG C.
Embodiment 5
The present embodiment caloric transfer printing technology the following steps are included:
S100: ink is prepared, ink includes the component of following mass percentage: acrylic polymer 50%, monomer
11%, photoinitiator 12%, adhesion promoter 9%, dispersing agent 2%, levelling agent 6% and pigment 10%.
Acrylic polymer is polyester acrylate resin and epoxy acrylic resin, the equal molecule of the number of polyester acrylate resin
Amount is 1200, and epoxy acrylic resin is the epoxy acrylic resin without bisphenol-A ingredient, number-average molecular weight 700, polyester
The mass ratio of acrylic resin and epoxy acrylic resin is 1:1.
Monomer is 1,6 hexanediol diacrylate.
Photoinitiator be sulfonyloxy ketone and 2,4,6- trimethylbenzoyl phenyl phosphinic acid ethyl esters, sulfonyloxy ketone and 2,
The mass ratio 3:1 of 4,6- trimethylbenzoyl phenyl phosphinic acid ethyl ester.
Adhesion promoter is isobutyl ethyl triethoxy silicane.
Dispersing agent is type siloxane dispersing agent.
Levelling agent is dimethyl silicone polymer.
Ink is 497CPS in the viscosity of 50 DEG C of temperature.
The present embodiment uses the ink of two kinds of colors, and the pigment of the ink of two kinds of colors is respectively pigment blue 60 and Pigment white
6。
S110: the ink of two kinds of colors being loaded into the print cartridge of digital printing device, and the temperature of print cartridge keeps 63 ± 1
DEG C, matched colors according to the pattern of computer, the ink of each color by corresponding type channel, by predetermined pattern by ink print extremely
On bat printing steel plate.
S210: the ink on ultraviolet light precuring bat printing steel plate, ultraviolet light wavelength are 250nm~420nm, light
Intensity is 130mw/cm2, irradiation time is 6 seconds.
S310: the viscous ink taken on bat printing steel plate of shift printing rubber head is then transferred on stock.
S410: heat cure is carried out to the ink on stock, heating temperature is 85 DEG C.
Wherein, the stock of Examples 1 and 2 is all made of PET material and is made, and the stock of embodiment 3 and 4 is all made of ABS
Material is made, and the stock of embodiment 5 is made of PC material.The product of Example 1 to 5 observes ink layer, and pattern is complete,
Color is full, and then it detects adhesive force, wearability and resistance to ag(e)ing respectively.
The detection method of adhesive force are as follows: use on the ink layer of cross-cut tester after hardening vertical 100 side lengths for the small of 1mm
Grid covers printing zone with 3M610 adhesive tape, compresses, then vertically quickly draws 3 times.It is required that: printing type face or pattern
It does not fall off, is incomplete.
The detection method of wearability are as follows: RCA test, load 175g power, 300 circles.It is required that: printing type face or pattern do not take off
It falls, is incomplete.
The detection method of resistance to ag(e)ing are as follows: in artificial ageing instrument, power 30W, 24 hours.It is required that: printing type face or figure
Case is without discoloration, colour fading.
Testing result such as table 1.
Table 1
By printed using caloric transfer printing technology of the invention known to above-mentioned testing result pattern adhesive force, wearability and resistance to old
The property changed is good, and process is simple, it is easy to accomplish, it is suitble to commercial introduction.
Each technical characteristic of embodiment described above can be combined arbitrarily, for simplicity of description, not to above-mentioned reality
It applies all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, all should be considered as described in this specification.
The embodiments described above only express several embodiments of the present invention, and the description thereof is more specific and detailed, but simultaneously
It cannot therefore be construed as limiting the scope of the patent.It should be pointed out that coming for those of ordinary skill in the art
It says, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to protection of the invention
Range.Therefore, the scope of protection of the patent of the invention shall be subject to the appended claims.
Claims (10)
1. a kind of caloric transfer printing technology, which comprises the following steps:
Ink is loaded into the print cartridge of digital printing device, is printed ink to bat printing steel by predetermined pattern by digital printing
On plate；
Ink on ultraviolet light precuring bat printing steel plate；
The viscous ink taken on bat printing steel plate of shift printing rubber head, is then transferred on stock.
2. caloric transfer printing technology according to claim 1, which is characterized in that the temperature of the print cartridge is kept for 50 DEG C~65 DEG C.
3. caloric transfer printing technology according to claim 1, which is characterized in that the ultraviolet light wavelength be 250nm~
420nm, luminous intensity are 95~130mw/cm2, irradiation time is 5~30 seconds.
4. caloric transfer printing technology according to claim 1, which is characterized in that after the ink is transferred to stock, also carry out
Heat cure or photocuring.
5. caloric transfer printing technology according to claim 1, which is characterized in that the ink includes following mass percentage
Component:
6. caloric transfer printing technology according to claim 5, which is characterized in that the acrylic polymer is polyester acrylic tree
Rouge and/or epoxy acrylic resin；The monomer is 1,6 hexanediol diacrylate or trimethylolpropane trimethacrylate；
The photoinitiator is that surface layer solidifies photoinitiator and deep cure photoinitiator；The adhesion promoter is silane coupled
Agent；The dispersing agent is type siloxane dispersing agent；The levelling agent is dimethyl silicone polymer, polyether polyester modified organic silicon oxygen
At least one of alkane and alkyl-modified organosiloxane.
7. caloric transfer printing technology according to claim 6, which is characterized in that the surface layer solidification photoinitiator and deep cure
Mass ratio 3~5:1~2 of photoinitiator.
8. caloric transfer printing technology according to claim 1 or 5, which is characterized in that the ink is in the viscosity of 50 DEG C of temperature
300CPS~500CPS.
9. a kind of ink, which is characterized in that the component including following mass percentage:
10. ink according to claim 9, which is characterized in that the acrylic polymer be polyester acrylate resin and/
Or epoxy acrylic resin；The monomer is 1,6 hexanediol diacrylate or trimethylolpropane trimethacrylate；It is described
Photoinitiator is that surface layer solidifies photoinitiator and deep cure photoinitiator, the surface layer solidification photoinitiator and deep cure light
Mass ratio 3~5:1~2 of initiator；The adhesion promoter is silane coupling agent；The dispersing agent is type siloxane dispersion
Agent；The levelling agent is in dimethyl silicone polymer, polyether polyester azo polyether polyeste and alkyl-modified organosiloxane
It is at least one.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110791143A (en) * | 2019-10-16 | 2020-02-14 | 苏州市贝特利高分子材料股份有限公司 | LED curing pad printing ink for plastic materials |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102666114A (en) * | 2009-11-26 | 2012-09-12 | 株式会社御牧工程 | Printing method and printing system |
| CN102673208A (en) * | 2012-06-20 | 2012-09-19 | 联志玩具礼品(东莞)有限公司 | Inkjet Pad Printing Process |
| CN102765269A (en) * | 2012-07-16 | 2012-11-07 | 联志玩具礼品(东莞)有限公司 | Inkjet plastic printing process |
| US8398224B2 (en) * | 1998-05-06 | 2013-03-19 | Sawgrass Technologies, Inc. | Heat activated printing process |
| CN103085519A (en) * | 2013-02-20 | 2013-05-08 | 珠海天威飞马打印耗材有限公司 | Ink-jet printing method and ink-jet printer |
| CN106758423A (en) * | 2016-11-17 | 2017-05-31 | 深圳市墨库图文技术有限公司 | Number weaving UV LED light solidification printing technology |
| CN107286740A (en) * | 2017-07-20 | 2017-10-24 | 洋紫荆油墨(中山)有限公司 | A kind of UV LED offset inks and preparation method thereof |
| CN108641470A (en) * | 2018-05-17 | 2018-10-12 | 清远慧谷新材料技术有限公司 | A kind of UV-LED solidification pad-transfer printing ink and preparation method thereof, application |
| CN108749297A (en) * | 2018-06-20 | 2018-11-06 | 东莞市基汇实业有限公司 | A kind of digital printing and steel plate bat printing composite integrated machine |
-
2018
- 2018-12-24 CN CN201811581675.4A patent/CN109649030A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8398224B2 (en) * | 1998-05-06 | 2013-03-19 | Sawgrass Technologies, Inc. | Heat activated printing process |
| CN102666114A (en) * | 2009-11-26 | 2012-09-12 | 株式会社御牧工程 | Printing method and printing system |
| CN102673208A (en) * | 2012-06-20 | 2012-09-19 | 联志玩具礼品(东莞)有限公司 | Inkjet Pad Printing Process |
| CN102765269A (en) * | 2012-07-16 | 2012-11-07 | 联志玩具礼品(东莞)有限公司 | Inkjet plastic printing process |
| CN103085519A (en) * | 2013-02-20 | 2013-05-08 | 珠海天威飞马打印耗材有限公司 | Ink-jet printing method and ink-jet printer |
| CN106758423A (en) * | 2016-11-17 | 2017-05-31 | 深圳市墨库图文技术有限公司 | Number weaving UV LED light solidification printing technology |
| CN107286740A (en) * | 2017-07-20 | 2017-10-24 | 洋紫荆油墨(中山)有限公司 | A kind of UV LED offset inks and preparation method thereof |
| CN108641470A (en) * | 2018-05-17 | 2018-10-12 | 清远慧谷新材料技术有限公司 | A kind of UV-LED solidification pad-transfer printing ink and preparation method thereof, application |
| CN108749297A (en) * | 2018-06-20 | 2018-11-06 | 东莞市基汇实业有限公司 | A kind of digital printing and steel plate bat printing composite integrated machine |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110791143A (en) * | 2019-10-16 | 2020-02-14 | 苏州市贝特利高分子材料股份有限公司 | LED curing pad printing ink for plastic materials |
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