CN109569220A - Purify air, water-soluble material of deodorization and preparation method thereof - Google Patents
Purify air, water-soluble material of deodorization and preparation method thereof Download PDFInfo
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- CN109569220A CN109569220A CN201811433020.2A CN201811433020A CN109569220A CN 109569220 A CN109569220 A CN 109569220A CN 201811433020 A CN201811433020 A CN 201811433020A CN 109569220 A CN109569220 A CN 109569220A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/76—Gas phase processes, e.g. by using aerosols
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/38—Removing components of undefined structure
- B01D53/44—Organic components
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/10—Oxidants
- B01D2251/108—Halogens or halogen compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/708—Volatile organic compounds V.O.C.'s
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- Environmental & Geological Engineering (AREA)
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- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The present invention relates to water-soluble consumptive material fields, disclose purification air, water-soluble material of deodorization and preparation method thereof, material is composed of following component: citric acid solid, sodium chlorite, sodium alginate, copper sulphate, sodium sulphate, gelatin, potassium dihydrogen phosphate.The present invention obtains being solid material, soluble easily in water, is dissolved in contained citric acid solid after water, sodium chlorite can quickly react to each other in water, generates chlorine dioxide, can pernicious gas molecule in oxygenolysis air, and there is preferable sterilizing deodoring performance.This product contains ingredient and is dissolved in after water not only with air-cleaning function, and contained ingredient also can be as aquatic plant fertilizer.It can be used as the vegetable fertilizer with air-cleaning function.Water-soluble material of the invention, safety and environmental protection, using easy, action time persistently, removal chemical contamination, especially voc, formaldehyde it is high-efficient, preparation process is simple, and cost is small.
Description
Technical field
The present invention relates to water-soluble consumptive material fields, more particularly to purification air, the water-soluble material of deodorization and its preparation side
Method.
Background technique
Lavatory peculiar smell is removed at present and relies primarily on the conventional methods such as champignon, camphor ball, santal, or is added using ventilating system
Fastly；Its principle of the methods of champignon, camphor ball is fragrance covering method, and there is no really removal lavatory smell pollutions, is not also had
Real sterilizing effect.And ventilating system or fresh air system are used, equipment installation cost is higher, so being difficult to large area
It promotes the use of.Therefore, how at lower cost, smell pollution in lavatory is really eliminated, air quality in lavatory is promoted, it has also become
Indoor environment field project urgently to be resolved.
Application number CN201010537761.2 be patent of invention disclose Unitary solid chlorine dioxide sustained-release generating agent and its
Preparation method, the propellant are free of solid acid, by stable acidic of the potassium hydrogen persulfate composite salts in solution system and sub- chlorine
Hydrochlorate and synergist concerted reaction generate chlorine dioxide, and material is by chlorite, potassium hydrogen persulfate composite salts, synergist, steady
Determine agent, forming agent, desiccant, adhesive, effervescent agent composition, preparation process uses chlorite and potassium hydrogen peroxymonosulfate is compound
Salt is separately dried, and is uniformly mixed according to a certain percentage with unclassified stores, and is pressed under certain ambient humidity and pressure
The tablet of different size.Unitary solid chlorine dioxide sustained-release generating agent the preparation method comprises the following steps: (1) press chlorite 20-30 parts, mistake
One 20-35 parts of potassium acid sulfate complex salt, 1-5 parts of stabilizer, 20-35 parts of forming agent, 5-15 parts of desiccant, is glued 1-5 parts of synergist
0.2-3 parts and effervescent agent 0.5-5 parts of mixture weigh, and are dried and dehydrated under conditions of relative humidity is less than 40%, dry temperature
Degree guarantees that the water content of each component is respectively less than 0.5% between 60~80 DEG C；(2) it is added into mixing machine and passes through step (1)
Each component of drying and dehydrating is uniformly mixed；(3) by uniformly mixed sample to be pressed into two under the pressure of 3.5~6T/cm2
Tablet occurs for chlorine monoxid.It can be sustained releasing chlorine dioxide after the complex tablet is soluble in water, there is long-acting, sustained release, ring
The features such as protecting, be safe, but add since all raw materials prepare chlorine dioxide generation tablet by the way of disposable drying and moulding
Entering in water directly to react, and tablet can be made to fail under more moist environment, therefore stores and to be completely dried
Confined space, storage condition is higher, and higher concentration solution cannot be continuously maintained in after tablet dissolved, and bactericidal effect falls short of
Effect, the also not no function of fresh air, it is therefore desirable to a kind of slow release effect preferably, purification, fresh air water-soluble material.
Summary of the invention
The present invention provides purification air, deodorization for the disadvantage that slow release effect is not good enough, storage condition is high in the prior art
Water-soluble material and preparation method thereof.
In order to solve the above-mentioned technical problem, the present invention is addressed by following technical proposals:
Water-soluble material with purification air and deodorization functions, by volume fraction, raw material is grouped as by below group:
Citric acid solid 10%~20%
Sodium chlorite 10%~20%
Sodium alginate 5%~10%
Copper sulphate 10%~20%
Sodium sulphate 10%~20%
Gelatin 30%~40%
Potassium dihydrogen phosphate 5%~10%.
Including potassium dihydrogen phosphate not only has the function of stablizing ph value, chemical fertilizer can be more used as, so that this product not only has
There is purification air deodorization function, when in the water body for being added into planting aquatic plants, can be used for as vegetable fertilizer.
Copper sulphate primarily serves the effect for absorbing hydrone, keeps completely dried state, drying regime during storing it
Lower sodium chlorite can not react with citric acid；Copper sulphate plays a warning role simultaneously, if material makes moist, copper sulphate can be inhaled
Moisture is received, blue is presented.If obvious blue is presented in material, illustrating may damp failure.
Sodium sulphate is used as interleaving agent, and the main sodium chlorite kept in gelatin is isolated with external citric acid, is not sent out
Raw reaction.And also function to the effect for adjusting effective component concentration.
Purify air, deodorization water-soluble material preparation method, comprising the following steps:
Step A: by volume fraction proportion prepare raw material, raw material include 10%~20% citric acid solid,
10%~20% sodium chlorite, 5%~10% alginic acid, 10%~20% copper sulphate sodium sulphate, 30%
~40% gelatin, 5%~10% potassium dihydrogen phosphate；
Step B: at room temperature, ready sodium chlorite, sodium alginate, gelatin, sodium sulphate are added into container, mixing is stirred
Add water after mixing uniformly, is stirred for uniformly obtaining complex colloid；
Step C: being fabricated to graininess for the obtained complex colloid of step B, obtains solid gelatinous particle after drying drying；System
At material internal contain gelatin particle, sodium chlorite is present in gelatin, and gelatin is solid state.And citric acid is also solid
Body is present in the ingredient of gelatin solids external, does not have lemon sour component in gelatin particle, thus maintains sodium chlorite and lemon
Lemon acid is in isolation, and the two will not react.
Step D: the solid gelatinous particle and citric acid solid, copper sulphate, sodium sulphate, potassium dihydrogen phosphate that step C is obtained
Mixing, and dry pressurization, are compressed into tablet form or bulk obtain water-soluble material.All the components are water solubility, therefore work as material
When soluble in water, sodium chlorite and citric acid will all be in solution state, and sodium chlorite will be in citric acid reactions, will be sufficiently anti-
Chlorine dioxide should be generated.Sodium chlorite is present in gelatin simultaneously, and gelatin is that solution rate is relatively slow, therefore sodium chlorite
The speed incorporated in water is also relatively slow, it is achieved that the effect of slow reaction.
Sodium chlorite is present in gelatin simultaneously, and gelatin is that solution rate is relatively slow, therefore sodium chlorite incorporates water
In speed it is also relatively slow, it is achieved that the effect of slow reaction.
In addition reaction generate chlorine dioxide after, under the barriering effect of gelatin, can slow release chlorine dioxide,
Continue to sterilize in water, in air.
Preferably, the diameter of solid gelatinous particle is 0.7~1.5mm in step C.
The present invention is due to using above technical scheme, and have significant technical effect: this product of the present invention is solid material,
Soluble easily in water, being dissolved in contained citric acid solid and sodium chlorite after water can smoothly react to each other in water, generate chlorine dioxide
Body, can pernicious gas molecule in oxygenolysis air, and there is preferable sterilizing deodoring performance.This product contains ingredient and is dissolved in water
Not only there is air-cleaning function afterwards, contained ingredient also can be as aquatic plant fertilizer.It can be used as with air cleaning function
The vegetable fertilizer of energy.Water-soluble material of the invention, safety and environmental protection, using easy, action time persistently, removal chemical contamination,
Especially voc, formaldehyde it is high-efficient, preparation process is simple, and cost is small.It is particularly suitable for removing the chemistry such as lavatory peculiar smell, voc
Water-soluble consumptive material of pollutant and preparation method thereof.
Specific embodiment
Below with reference to embodiment, present invention is further described in detail.
Embodiment 1
Water-soluble material with purification air and deodorization functions, by volume fraction, raw material is grouped as by below group:
Citric acid solid 10%~20%
Sodium chlorite 10%~20%
Sodium alginate 5%~10%
Copper sulphate 10%~20%
Sodium sulphate 10%~20%
Gelatin 30%~40%
Potassium dihydrogen phosphate 5%~10%.
In the present embodiment, raw material is grouped as by below group: citric acid solid 10%, sodium chlorite 10%, sodium alginate
5%, copper sulphate 10%, sodium sulphate 20%, gelatin 40%, potassium dihydrogen phosphate 5%.
Purify air, deodorization water-soluble material preparation method, comprising the following steps:
Step A: by volume fraction proportion prepare raw material, raw material include 10%~20% citric acid solid,
10%~20% sodium chlorite, 5%~10% alginic acid, 10%~20% copper sulphate sodium sulphate, 30%
~40% gelatin, 5%~10% potassium dihydrogen phosphate；In the present embodiment, raw material is grouped as by below group: citric acid solid
10%, sodium chlorite 10%, sodium alginate 5%, copper sulphate 10%, sodium sulphate 20%, gelatin 40%, potassium dihydrogen phosphate 5%.
Step B: at room temperature, ready sodium chlorite, sodium alginate, gelatin, sodium sulphate are added into container, mixing is stirred
Add water after mixing uniformly, is stirred for uniformly obtaining complex colloid；
Step C: being fabricated to graininess for the obtained complex colloid of step B, obtains solid gelatinous particle after drying drying；
Step D: the solid gelatinous particle and citric acid solid, copper sulphate, sodium sulphate, potassium dihydrogen phosphate that step C is obtained
Mixing, and dry pressurization, are compressed into tablet form or bulk obtain water-soluble material.
The diameter of solid gelatinous particle is 0.7~1.5mm in step C.In the present embodiment, the diameter of solid gelatinous particle is
0.7mm。
Embodiment 2
Water-soluble material with purification air and deodorization functions, by volume fraction, raw material is grouped as by below group:
Citric acid solid 10%~20%
Sodium chlorite 10%~20%
Sodium alginate 5%~10%
Copper sulphate 10%~20%
Sodium sulphate 10%~20%
Gelatin 30%~40%
Potassium dihydrogen phosphate 5%~10%.
In the present embodiment, raw material is grouped as by below group: citric acid solid 15%, sodium chlorite 15%, sodium alginate
10%, copper sulphate 10%, sodium sulphate 10%, gelatin 30%, potassium dihydrogen phosphate 5%.
Purify air, deodorization water-soluble material preparation method, comprising the following steps:
Step A: by volume fraction proportion prepare raw material, raw material include 10%~20% citric acid solid,
10%~20% sodium chlorite, 5%~10% alginic acid, 10%~20% copper sulphate sodium sulphate, 30%
~40% gelatin, 5%~10% potassium dihydrogen phosphate；In the present embodiment, raw material includes citric acid solid 15%, sodium chlorite
15%, sodium alginate 10%, copper sulphate 10%, sodium sulphate 10%, gelatin 30%, potassium dihydrogen phosphate 5%.
Step B: at room temperature, ready sodium chlorite, sodium alginate, gelatin, sodium sulphate are added into container, mixing is stirred
Add water after mixing uniformly, is stirred for uniformly obtaining complex colloid；
Step C: being fabricated to graininess for the obtained complex colloid of step B, obtains solid gelatinous particle after drying drying；
Step D: the solid gelatinous particle and citric acid solid, copper sulphate, sodium sulphate, potassium dihydrogen phosphate that step C is obtained
Mixing, and dry pressurization, are compressed into tablet form or bulk obtain water-soluble material.
The diameter of solid gelatinous particle is 0.7~1.5mm in step C.In the present embodiment, the diameter of solid gelatinous particle is
1.0mm。
Embodiment 3
Water-soluble material with purification air and deodorization functions, by volume fraction, raw material is grouped as by below group:
Citric acid solid 10%~20%
Sodium chlorite 10%~20%
Sodium alginate 5%~10%
Copper sulphate 10%~20%
Sodium sulphate 10%~20%
Gelatin 30%~40%
Potassium dihydrogen phosphate 5%~10%.
In the present embodiment, raw material is grouped as by below group: citric acid solid 20%, sodium chlorite 20%, sodium alginate
5%, copper sulphate 10%, sodium sulphate 10%, gelatin 30%, potassium dihydrogen phosphate 5%.
Purify air, deodorization water-soluble material preparation method, comprising the following steps:
Step A: by volume fraction proportion prepare raw material, raw material include 10%~20% citric acid solid,
10%~20% sodium chlorite, 5%~10% alginic acid, 10%~20% copper sulphate sodium sulphate, 30%
~40% gelatin, 5%~10% potassium dihydrogen phosphate；In the present embodiment, raw material includes citric acid solid 20%, sodium chlorite
20%, sodium alginate 5%, copper sulphate 10%, sodium sulphate 10%, gelatin 30%, potassium dihydrogen phosphate 5%.
Step B: at room temperature, ready sodium chlorite, sodium alginate, gelatin, sodium sulphate are added into container, mixing is stirred
Add water after mixing uniformly, is stirred for uniformly obtaining complex colloid；
Step C: being fabricated to graininess for the obtained complex colloid of step B, obtains solid gelatinous particle after drying drying；
Step D: the solid gelatinous particle and citric acid solid, copper sulphate, sodium sulphate, potassium dihydrogen phosphate that step C is obtained
Mixing, and dry pressurization, are compressed into tablet form or bulk obtain water-soluble material.
The diameter of solid gelatinous particle is 0.7~1.5mm in step C.In the present embodiment, the diameter of solid gelatinous particle is
1.5mm。
Embodiment 4
Measure embodiment 1-3 resulting materials the dissolution time and bactericidal effect that are dissolved in 100mL water, obtain with
Lower data:
14 days Acceleration study contents are fallen to according to national standard, and water-soluble material is carried out Acceleration study, are with 14 days
Standard measures changes of contents value.
Embodiment 5
Water-soluble material with purification air and deodorization functions, it is same as Example 1, the difference is that, raw material
In do not add gelatin, step B does not add gelatin, obtains water-soluble material, measures the time being dissolved in 100 milliliters of water and is
0.07h, 14 days Acceleration study contents decline 87.15% are added to the water after 10min that bactericidal effect is 100% in water, are added to the water
Bactericidal effect is 32% in water after 10h, and being added to the water after 10min bactericidal effect in air is 98%, is added to the water air after 10h
Middle bactericidal effect is 3%.
The hardness of water-soluble material is bigger, and dissolution time is longer, in the prior art, the very long reagent of dissolution time due to
Dissolve early period concentration is low or the content of chlorine dioxide is always held at lower value, bactericidal effect is bad, is maintained in concentration
When reduced levels, tablet is not to the bactericidal effect of air；And dissolve the concentration of faster reagent chlorine dioxide in a short time
It is higher, it sterilizes in water quickly, the stabilization time of solution is very short, without slow release effect, compares with embodiment 5, embodiment 1-3 adds
Gelatin coatings are added, slow release effect is obvious, and the high concentration state of ClO 2 solution is sustainable, illustrates the present invention in terms of sustained release
There is relatively good effect.
In short, the foregoing is merely presently preferred embodiments of the present invention, it is all according to equalization made by scope of the present invention patent
Variation and modification, shall all be covered by the patent of the invention.
Claims (3)
1. the water-soluble material with purification air and deodorization functions, which is characterized in that press volume fraction, raw material is by below
Group is grouped as:
Citric acid solid 10%~20%
Sodium chlorite 10%~20%
Sodium alginate 5%~10%
Copper sulphate 10%~20%
Sodium sulphate 10%~20%
Gelatin 30%~40%
Potassium dihydrogen phosphate 5%~10%.
2. the preparation method with the water-soluble material of purification air and deodorization functions, which comprises the following steps:
Step A: by volume fraction proportion prepare raw material, raw material include 10%~20% citric acid solid,
10%~20% sodium chlorite, 5%~10% alginic acid, 10%~20% copper sulphate sodium sulphate, 30%~
40% gelatin, 5%~10% potassium dihydrogen phosphate；
Step B: at room temperature, ready sodium chlorite, sodium alginate, gelatin, sodium sulphate being added into container, are mixed equal
Add water after even, is stirred for uniformly obtaining complex colloid；
Step C: being fabricated to graininess for the obtained complex colloid of step B, obtains solid gelatinous particle after drying drying；
Step D: the solid gelatinous particle that step C is obtained is mixed with citric acid solid, copper sulphate, sodium sulphate, potassium dihydrogen phosphate,
And dry pressurization, it is compressed into tablet form or bulk obtains water-soluble material.
3. the preparation method of the water-soluble material with purification air and deodorization functions according to claim 1, feature
Be: the diameter of solid gelatinous particle is 0.7~1.5mm in step C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811433020.2A CN109569220A (en) | 2018-11-28 | 2018-11-28 | Purify air, water-soluble material of deodorization and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811433020.2A CN109569220A (en) | 2018-11-28 | 2018-11-28 | Purify air, water-soluble material of deodorization and preparation method thereof |
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| CN109569220A true CN109569220A (en) | 2019-04-05 |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101228868A (en) * | 2008-02-27 | 2008-07-30 | 河北科技大学 | Monobasic solid chlorine dioxide effervescent tablet and preparation method thereof |
| JP2008284547A (en) * | 2007-04-19 | 2008-11-27 | Imex Co Ltd | Deodorization device |
| CN101530625A (en) * | 2009-04-26 | 2009-09-16 | 白东江 | Deodorizing antistaling agent |
| CN105145626A (en) * | 2015-07-30 | 2015-12-16 | 竹安（北京）生物科技发展有限公司 | Aroma type immobilized gel-like chlorine dioxide air cleanser |
| CN107519744A (en) * | 2017-09-15 | 2017-12-29 | 安徽中弘科技发展有限公司 | A kind of furniture eliminating smell agent and preparation method thereof |
| CN108094441A (en) * | 2017-12-24 | 2018-06-01 | 天津市纳斯特科技有限公司 | A kind of multipurpose disinfection tablet |
-
2018
- 2018-11-28 CN CN201811433020.2A patent/CN109569220A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008284547A (en) * | 2007-04-19 | 2008-11-27 | Imex Co Ltd | Deodorization device |
| CN101228868A (en) * | 2008-02-27 | 2008-07-30 | 河北科技大学 | Monobasic solid chlorine dioxide effervescent tablet and preparation method thereof |
| CN101530625A (en) * | 2009-04-26 | 2009-09-16 | 白东江 | Deodorizing antistaling agent |
| CN105145626A (en) * | 2015-07-30 | 2015-12-16 | 竹安（北京）生物科技发展有限公司 | Aroma type immobilized gel-like chlorine dioxide air cleanser |
| CN107519744A (en) * | 2017-09-15 | 2017-12-29 | 安徽中弘科技发展有限公司 | A kind of furniture eliminating smell agent and preparation method thereof |
| CN108094441A (en) * | 2017-12-24 | 2018-06-01 | 天津市纳斯特科技有限公司 | A kind of multipurpose disinfection tablet |
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Application publication date: 20190405 |