CN109535816A - Coating organic silicon defoamer and preparation method thereof - Google Patents
Coating organic silicon defoamer and preparation method thereof Download PDFInfo
- Publication number
- CN109535816A CN109535816A CN201811518022.1A CN201811518022A CN109535816A CN 109535816 A CN109535816 A CN 109535816A CN 201811518022 A CN201811518022 A CN 201811518022A CN 109535816 A CN109535816 A CN 109535816A
- Authority
- CN
- China
- Prior art keywords
- parts
- organic silicon
- coating
- silicon defoamer
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000576 coating method Methods 0.000 title claims abstract description 29
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 239000011248 coating agent Substances 0.000 title claims abstract description 27
- 229910052710 silicon Inorganic materials 0.000 title claims abstract description 27
- 239000010703 silicon Substances 0.000 title claims abstract description 27
- 239000013530 defoamer Substances 0.000 title claims abstract description 24
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims abstract description 33
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 22
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 17
- 239000000463 material Substances 0.000 claims abstract description 14
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229940008099 dimethicone Drugs 0.000 claims abstract description 11
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims abstract description 11
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 11
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims abstract description 11
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 11
- 239000011780 sodium chloride Substances 0.000 claims abstract description 11
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 10
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 10
- 239000008116 calcium stearate Substances 0.000 claims abstract description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 8
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 8
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 238000010792 warming Methods 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- 239000002202 Polyethylene glycol Substances 0.000 claims 1
- 235000021355 Stearic acid Nutrition 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims 1
- 229920001223 polyethylene glycol Polymers 0.000 claims 1
- 239000008117 stearic acid Substances 0.000 claims 1
- 239000006260 foam Substances 0.000 abstract description 7
- 230000005764 inhibitory process Effects 0.000 abstract description 5
- 239000003960 organic solvent Substances 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 3
- POAXRNROGRXJKW-UHFFFAOYSA-N C(CCC)OC(=O)CCCC.C1=CC=CC=C1 Chemical group C(CCC)OC(=O)CCCC.C1=CC=CC=C1 POAXRNROGRXJKW-UHFFFAOYSA-N 0.000 description 2
- 230000003254 anti-foaming effect Effects 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- -1 polyoxypropylene ethylene oxide glycerin Polymers 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- HSRJKNPTNIJEKV-UHFFFAOYSA-N Guaifenesin Chemical compound COC1=CC=CC=C1OCC(O)CO HSRJKNPTNIJEKV-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of coating organic silicon defoamers and preparation method thereof, by weight, constitutive material are as follows: 30-35 parts of organic siliconresin, 18-25 parts of polyvinyl resin, 5-7 parts of ethoxylated dodecyl alcohol, 2-4 parts of sodium cellulose glycolate, 10-15 parts of calcium stearate, 6-8 parts of sodium chloride, 2-4 parts of triethylamine, 4-6 parts of dibutyl phthalate, 2-4 parts of tetradecyl alchohol, 6-10 parts of dimethicone；Organic silicon defoamer raw material of the invention passes through science collocation, it is not added with organic solvent, preparation method is simple, required foam time is short, have the advantages that dosage is few, defoaming is fast, the foam inhibition time is long, graphene improves the hydrophobicity of coating, to improve the antifoam performance of defoaming agent, present invention improves coating qualities simultaneously, delay the service life of coating.
Description
Technical field
The present invention relates to defoaming agent technical fields, and in particular to a kind of coating organic silicon defoamer and preparation method thereof.
Background technique
Currently, common defoaming agent is generally divided into three classes in industry: polyether-type defoaming agent, organic defoaming agent and organosilicon disappear
Infusion.Organic silicon defoamer is compared with other two kinds of defoaming agents, with dosage is few, defoaming capacity is strong, chemical property is stable, nothing
Poison, bioaffinity is good, Small side effects advantage, therefore it is a kind of defoaming agent ideal, that application range is most wide.
Organic silicon defoaming agent generally comprises dimethyl silicone polymer etc..Organic silicon defoaming agent dissolubility is poor, normal
Temperature is lower have antifoaming speed quickly, foam inhibition it is preferable, but layering, antifoaming speed occur at high temperature compared with the features such as slow, foam inhibition is poor；
Polyethers defoaming agent includes polyoxypropylene ethylene oxide glycerin ether etc..Polyethers defoaming agent is with the foam inhibition time is long, effect is good, disappears
Steep the features such as speed is fast, thermal stability is good.
It needs to use defoaming agent when coating material production, but current defoaming agent is there are the deficiency of using effect difference,
It cannot satisfy the use demand.
Summary of the invention
In order to alleviate shortcomings and deficiencies of the prior art, the purpose of the present invention is to provide a kind of coating to be defoamed with organosilicon
Agent and preparation method thereof.
To achieve the goals above, the present invention adopts the following technical scheme:
Coating organic silicon defoamer, by weight, constitutive material are as follows: 30-35 parts of organic siliconresin, polyethylene tree
18-25 parts of rouge, 5-7 parts of ethoxylated dodecyl alcohol, 2-4 parts of sodium cellulose glycolate, 10-15 parts of calcium stearate, sodium chloride 6-8
Part, 2-4 parts of triethylamine, 4-6 parts of dibutyl phthalate, 2-4 parts of tetradecyl alchohol, 6-10 parts of dimethicone.
Coating organic silicon defoamer, by weight, constitutive material are as follows: 32 parts of organic siliconresin, polyvinyl resin
20 parts, 6 parts of ethoxylated dodecyl alcohol, 3 parts of sodium cellulose glycolate, 12 parts of calcium stearate, 7 parts of sodium chloride, 3 parts of triethylamine,
5 parts of dibutyl phthalate, 3 parts of tetradecyl alchohol, 8 parts of dimethicone.
The preparation method of coating organic silicon defoamer, specifically includes the following contents: weighing by the parts by weight of constitutive material
First reaction is added in organic siliconresin, polyvinyl resin, ethoxylated dodecyl alcohol, calcium stearate, dimethicone by each raw material
In kettle, 35 DEG C -45 DEG C are warming up to, stirs and evenly mixs half an hour, mixing speed 500-600rpm is controlled, is then warming up to 85 again
DEG C -100 DEG C, sodium cellulose glycolate, sodium chloride, triethylamine, dibutyl phthalate, tetradecyl alchohol are sequentially added, is mixed
Stirring 2-3 hours, mixing speed 800-1000rpm is cooled to room temperature, obtains organic silicon defoamer.
The heating rate is 3 DEG C -5 DEG C/min.
The organic silicon defoamer is applied on exterior coating, pipe coatings.
Graphene is added in the constitutive material, the graphene additive amount is total mass of raw material 1.5%-
2.0%.
Beneficial effects of the present invention:
Compared with prior art, organic silicon defoamer raw material of the invention is not added with organic solvent by science collocation, makes
Preparation Method is simple, and required foam time is short, has the advantages that dosage is few, defoaming is fast, the foam inhibition time is long, graphene improves coating
Hydrophobicity, to improve the antifoam performance of defoaming agent, while present invention improves coating qualities, delay the use of coating
Service life.
Specific embodiment
Embodiment 1: coating organic silicon defoamer, by weight (jin) meter, constitutive material are as follows: organic siliconresin 32 gathers
Vinyl 20, ethoxylated dodecyl alcohol 6, sodium cellulose glycolate 3, calcium stearate 12, sodium chloride 7, triethylamine 3, adjacent benzene
Dibutyl carboxylic acid 5, tetradecyl alchohol 3, dimethicone 8.
The preparation method of coating organic silicon defoamer, specifically includes the following contents: weighing by the parts by weight of constitutive material
First reaction is added in organic siliconresin, polyvinyl resin, ethoxylated dodecyl alcohol, calcium stearate, dimethicone by each raw material
In kettle, 40 DEG C are warming up to, stirs and evenly mixs half an hour, mixing speed 550rpm is controlled, is then warming up to 95 DEG C again, then is successively added
Enter sodium cellulose glycolate, sodium chloride, triethylamine, dibutyl phthalate, tetradecyl alchohol, is mixed 2.5 hours, stirring speed
Degree is 1000rpm, is cooled to room temperature, obtains organic silicon defoamer.
Embodiment 2: coating organic silicon defoamer, by weight (jin) meter, constitutive material are as follows: organic siliconresin 32 gathers
Vinyl 20, ethoxylated dodecyl alcohol 6, sodium cellulose glycolate 3, calcium stearate 12, sodium chloride 7, triethylamine 3, adjacent benzene
Dibutyl carboxylic acid 5, tetradecyl alchohol 3, dimethicone 8 and graphene 1.8.
The preparation method of coating organic silicon defoamer, specifically includes the following contents: weighing by the parts by weight of constitutive material
Each raw material, first by organic siliconresin, polyvinyl resin, ethoxylated dodecyl alcohol, calcium stearate, graphene, dimethicone
It is added in reaction kettle, is warming up to 40 DEG C, stir and evenly mix half an hour, control mixing speed 550rpm, be then warming up to 95 DEG C again,
Sodium cellulose glycolate, sodium chloride, triethylamine, dibutyl phthalate, tetradecyl alchohol are sequentially added, it is small to be mixed 2.5
When, mixing speed 1000rpm is cooled to room temperature, obtains organic silicon defoamer.
Claims (6)
1. coating organic silicon defoamer, which is characterized in that by weight, constitutive material are as follows: organic siliconresin 30-35
Part, 18-25 parts of polyvinyl resin, 5-7 parts of ethoxylated dodecyl alcohol, 2-4 parts of sodium cellulose glycolate, calcium stearate 10-15
Part, 6-8 parts of sodium chloride, 2-4 parts of triethylamine, 4-6 parts of dibutyl phthalate, 2-4 parts of tetradecyl alchohol, dimethicone 6-10
Part.
2. coating organic silicon defoamer according to claim 1, which is characterized in that by weight, constitutive material
Are as follows: 32 parts of organic siliconresin, 20 parts of polyvinyl resin, 6 parts of ethoxylated dodecyl alcohol, 3 parts of sodium cellulose glycolate, stearic acid
12 parts of calcium, 7 parts of sodium chloride, 3 parts of triethylamine, 5 parts of dibutyl phthalate, 3 parts of tetradecyl alchohol, 8 parts of dimethicone.
3. a kind of preparation method of coating organic silicon defoamer as described in claim 1, which is characterized in that specifically include with
Lower content: weighing each raw material by the parts by weight of constitutive material, first by organic siliconresin, polyvinyl resin, lauryl alcohol polyethylene glycol oxide
Ether, calcium stearate, dimethicone are added in reaction kettle, are warming up to 35 DEG C -45 DEG C, stir and evenly mix half an hour, control stirring
Then speed 500-600rpm is warming up to 85 DEG C -100 DEG C again, sequentially add sodium cellulose glycolate, sodium chloride, triethylamine,
Dibutyl phthalate, tetradecyl alchohol are mixed 2-3 hours, and mixing speed 800-1000rpm is cooled to room temperature, obtains
Organic silicon defoamer.
4. the preparation method of coating organic silicon defoamer according to claim 3, which is characterized in that the heating speed
Rate is 3 DEG C -5 DEG C/min.
5. the preparation method of coating organic silicon defoamer according to claim 3, which is characterized in that the organosilicon
Defoaming agent is applied on exterior coating, pipe coatings.
6. coating organic silicon defoamer according to claim 1, which is characterized in that be added in the constitutive material
Graphene, the graphene additive amount are total mass of raw material 1.5%-2.0%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811518022.1A CN109535816A (en) | 2018-12-12 | 2018-12-12 | Coating organic silicon defoamer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811518022.1A CN109535816A (en) | 2018-12-12 | 2018-12-12 | Coating organic silicon defoamer and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109535816A true CN109535816A (en) | 2019-03-29 |
Family
ID=65854776
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811518022.1A Pending CN109535816A (en) | 2018-12-12 | 2018-12-12 | Coating organic silicon defoamer and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109535816A (en) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030186003A1 (en) * | 2002-04-01 | 2003-10-02 | Fuji Photo Film Co., Ltd. | Fine particle dispersion, coating solution for accepting layer for coloring agent for ink-jet recording sheet, ink-jet recording sheet using the dispersion, and method for producing fine particle dispersion |
| CN1919936A (en) * | 2006-08-31 | 2007-02-28 | 南京四新科技应用研究所有限公司 | Organosilicon defoaming agent for water-based system and preparation method thereof |
| CN101360543A (en) * | 2005-11-15 | 2009-02-04 | 莫门蒂夫性能材料股份有限公司 | Silicone defoamer composition |
| CN102302869A (en) * | 2011-07-27 | 2012-01-04 | 南京四新科技应用研究所有限公司 | Solid particle foam inhibitor and method for preparing same |
| CN103572653A (en) * | 2013-10-31 | 2014-02-12 | 江苏赛欧信越消泡剂有限公司 | Emulsion type silicon resin defoaming agent for pulping in papermaking |
| CN103641195A (en) * | 2013-12-13 | 2014-03-19 | 深圳市安品有机硅材料有限公司 | Organic silicon defoamer and preparation method thereof |
| CN105498302A (en) * | 2015-11-24 | 2016-04-20 | 宜兴市丰烨化学有限公司 | Polyether silicone oil triglyceride antifoaming agent and preparation method thereof |
| CN106807118A (en) * | 2016-12-28 | 2017-06-09 | 广东中联邦精细化工有限公司 | A kind of non-organic silicon high-performance defoamer and preparation method thereof |
| CN107469412A (en) * | 2017-09-30 | 2017-12-15 | 徐州中泰能源科技有限公司 | A kind of graphene modified organic silicon liquid antifoam agent |
-
2018
- 2018-12-12 CN CN201811518022.1A patent/CN109535816A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030186003A1 (en) * | 2002-04-01 | 2003-10-02 | Fuji Photo Film Co., Ltd. | Fine particle dispersion, coating solution for accepting layer for coloring agent for ink-jet recording sheet, ink-jet recording sheet using the dispersion, and method for producing fine particle dispersion |
| CN101360543A (en) * | 2005-11-15 | 2009-02-04 | 莫门蒂夫性能材料股份有限公司 | Silicone defoamer composition |
| CN1919936A (en) * | 2006-08-31 | 2007-02-28 | 南京四新科技应用研究所有限公司 | Organosilicon defoaming agent for water-based system and preparation method thereof |
| CN102302869A (en) * | 2011-07-27 | 2012-01-04 | 南京四新科技应用研究所有限公司 | Solid particle foam inhibitor and method for preparing same |
| CN103572653A (en) * | 2013-10-31 | 2014-02-12 | 江苏赛欧信越消泡剂有限公司 | Emulsion type silicon resin defoaming agent for pulping in papermaking |
| CN103641195A (en) * | 2013-12-13 | 2014-03-19 | 深圳市安品有机硅材料有限公司 | Organic silicon defoamer and preparation method thereof |
| CN105498302A (en) * | 2015-11-24 | 2016-04-20 | 宜兴市丰烨化学有限公司 | Polyether silicone oil triglyceride antifoaming agent and preparation method thereof |
| CN106807118A (en) * | 2016-12-28 | 2017-06-09 | 广东中联邦精细化工有限公司 | A kind of non-organic silicon high-performance defoamer and preparation method thereof |
| CN107469412A (en) * | 2017-09-30 | 2017-12-15 | 徐州中泰能源科技有限公司 | A kind of graphene modified organic silicon liquid antifoam agent |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106519126B (en) | A kind of fluorinated silicone modified polyacrylate dispersion and the preparation method and application thereof | |
| CN105148571B (en) | For the preparation method of the defoamer of water-based system | |
| US9023781B2 (en) | Particle defoamer comprising a silicone emulsion and process for preparing same | |
| CN102745943B (en) | Manufacture and construction method of powdery outer wall natural stone paint | |
| CN106565897B (en) | A kind of external wall elastic lotion and preparation method thereof with lotus leaf effect | |
| EP2882697B1 (en) | Redispersible polymer powder mixtures for use in dry-mix formulations having improved properties | |
| CN106749965B (en) | A kind of preparation method of solid polycarboxylic acid water reducing agent | |
| CN103183795B (en) | Low air content polycarboxylic acid water reducer and preparation method thereof | |
| CN104311753A (en) | Silane modified polycarboxylate-type water reducing agent as well as preparation method and use method thereof | |
| CN107551610A (en) | A kind of composite organic liquid antifoam agent | |
| CN106188420B (en) | Anti- bleeding type water-reducing agent and preparation method thereof | |
| CN103539903B (en) | A kind of powder polycarboxylic acids water reducing agent preparation method with bleed, their defoaming function | |
| CN109535816A (en) | Coating organic silicon defoamer and preparation method thereof | |
| CN109970903A (en) | A kind of high bonding force and strong water resistance redispersable latex powder and preparation method thereof | |
| CN105601837A (en) | Polycarboxylate superplasticizer and preparation method thereof | |
| CN111826148A (en) | Salt-resistant foaming agent and preparation method and application thereof | |
| CN109796815B (en) | A kind of preparation method of graphene-modified styrene-acrylic emulsion | |
| CN104645675A (en) | Novel organic silicon defoaming agent with excellent stability and defoaming ability | |
| CN111548687A (en) | Mildew-proof heat-insulation heat-preservation coating with high bonding strength and preparation method thereof | |
| CN110684306A (en) | EVA type re-dispersible latex powder and preparation method thereof | |
| CN107880491A (en) | A kind of epoxy foams material | |
| CN109735208A (en) | One kind being based on polymer modification SiO2The aqueous insulation paint and its preparation process of aeroge | |
| CN109251618A (en) | A kind of quick-drying water-repellent paint | |
| CN103193923B (en) | Preparation method and application of pervaporation separation material based on polyacrylate resin | |
| CN107699086A (en) | A kind of flexible texture coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190329 |
|
| WD01 | Invention patent application deemed withdrawn after publication |