CN1095118A - Far infrared ceramic chemical fiber - Google Patents
Far infrared ceramic chemical fiber Download PDFInfo
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- CN1095118A CN1095118A CN 93104713 CN93104713A CN1095118A CN 1095118 A CN1095118 A CN 1095118A CN 93104713 CN93104713 CN 93104713 CN 93104713 A CN93104713 A CN 93104713A CN 1095118 A CN1095118 A CN 1095118A
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Abstract
本发明属于纺织领域，采用远红外陶瓷粉末作原 料进行化学纤维的纺织。将ZrO2，Fe2O3，MnO2和 相增强剂的超细粉末与高分子聚合物制成母粒(或切 片)及熔融纺丝制成远红外陶瓷化学纤维。该纤维经 过适当处理后具有良好的弹性和柔软性。可制成各 种具有保健功能的衣物。The invention belongs to the textile field and uses far-infrared ceramic powder as a raw material to weave chemical fibers. The superfine powder of ZrO 2 , Fe 2 O 3 , MnO 2 and phase reinforcing agent are made into masterbatch (or chip) with high molecular polymer, and melt spinning is made into far-infrared ceramic chemical fiber. The fiber has good elasticity and softness after proper treatment. It can be made into various clothes with health care functions.
Description
本发明属纺织领域，尤其涉及的是远红外陶瓷纤维的制作及制品。The invention belongs to the field of textiles, and in particular relates to the production and products of far-infrared ceramic fibers.
具有远红外辐射效应的纤维在国外专利上已多次提出，日本昭63-105107提出以15～20wt%的粒土、硅石等天然陶瓷原料和化学纤维原料溶解，然后按常规纺丝方法制作化学纤维。日本平1-162824中介绍的远红外化学纤维采用粒土中加入氧化锆、氧化硅等产生全辐射率（500℃）0.4以上，粒度5μm的远红外陶瓷与某些分散媒介混合后，作为辅助添加物与化纤原料溶融纺织。从以上专利中看它们所采用的陶瓷粉末只是一些混合成份的天然陶瓷原料，其远红外频谱是陶瓷原料本身所固有的，不能和人体生物频谱紧密吻合。再则，天然陶瓷原料的颗粒度太大，在纤维中粉末分布不均。大颗粒陶瓷粉末对纺织机械的磨损较大，也不适合于制作超细纤度的化学纤维。在日本昭63-126971中采用铝、镁、锆系列的陶瓷粉，所得纤维为一种芯鞘结构的化纤产品，其中的陶瓷粉末在30℃环境温度的辐射率为0.65，波长4.5～30μm，此种芯部含有陶瓷粉，或纤维表面含有陶瓷粉，它的多层结构势必影响纤维细旦化，而且多层包覆方式对纤维的伸长、回弹、柔性等都有很大影响。Fibers with far-infrared radiation effects have been proposed many times in foreign patents. Japanese Zhao 63-105107 proposed to dissolve 15-20 wt% of natural ceramic raw materials such as granular soil and silica and chemical fiber raw materials, and then make chemical fibers according to conventional spinning methods. fiber. The far-infrared chemical fiber introduced in Japanese Hei 1-162824 uses zirconia, silicon oxide, etc. to add zirconia, silicon oxide, etc. to the granular soil to produce a total radiation rate (500°C) of more than 0.4, and far-infrared ceramics with a particle size of 5 μm are mixed with some dispersion media as an auxiliary Additives and chemical fiber raw materials are melted and spun. Seen from the above patents, the ceramic powders they adopt are just some natural ceramic raw materials with mixed components, and their far-infrared spectrum is inherent in the ceramic raw materials themselves, which cannot closely match the biological spectrum of the human body. Furthermore, the particle size of the natural ceramic raw material is too large, and the powder distribution in the fiber is uneven. Large-grained ceramic powders have greater wear and tear on textile machinery, and are not suitable for making ultra-fine chemical fibers. In Japan Zhao 63-126971, aluminum, magnesium, and zirconium series ceramic powders are used, and the obtained fiber is a chemical fiber product with a core-sheath structure. The ceramic powder has an emissivity of 0.65 at an ambient temperature of 30 °C and a wavelength of 4.5 to 30 μm. This kind of core contains ceramic powder, or the surface of the fiber contains ceramic powder. Its multi-layer structure will inevitably affect the denier of the fiber, and the multi-layer coating method has a great impact on the elongation, rebound, and flexibility of the fiber.
本发明的目的在于提供一种具有多种性能，同时能满足服用要求的远红外陶瓷化学纤维材料的制备及相应的制品。The object of the present invention is to provide a preparation of far-infrared ceramic chemical fiber material and corresponding products that have multiple properties and can meet the requirements of wearing.
本发明的主要技术特征是采用远红外陶瓷粉末作原料进行化学纤维的纺织，远红外陶瓷材料和相增强剂为平均粒度小于0.5μm的超细粉末，其辐射率为0.85-0.92，将粉末用干法或湿法制成化纤纺丝用陶瓷粒，将料与聚丙烯、聚氨脂、聚酰胺、聚脂等高分子聚合物切片融熔纺丝，陶瓷超细粉末为50-80wt%ZrO2、5-20wt%F2O3;10-30wt%MnO2与相增强剂为5-15wt%为原料。The main technical feature of the present invention is to use far-infrared ceramic powder as raw material to carry out the weaving of chemical fiber, the far-infrared ceramic material and the phase intensifier are superfine powders with an average particle size of less than 0.5 μm, and their emissivity is 0.85-0.92. Dry method or wet method to make ceramic particles for chemical fiber spinning, melt spinning the material with high molecular polymer chips such as polypropylene, polyurethane, polyamide, polyester, etc., ceramic ultrafine powder is 50-80wt%ZrO 2. 5-20wt% F 2 O 3 ; 10-30wt% MnO 2 and 5-15wt% phase enhancer as raw materials.
采用的纺丝工艺也可为陶瓷母粒与聚合物切片融熔同时加入色母粒纺出色丝。并通过改变喷丝板组件纺制出不同形态的异型丝如三角、三叶、中空等，纺出的丝或纱织成织物。The spinning process adopted can also be melting ceramic masterbatch and polymer chips while adding color masterbatch to spin colored silk. And by changing the spinneret assembly, different shapes of special-shaped filaments such as triangular, trilobal, hollow, etc. are spun, and the spun filaments or yarns are woven into fabrics.
本发明技术方案如下：Technical scheme of the present invention is as follows:
1.远红外陶瓷粉的配方1. Formula of far-infrared ceramic powder
本发明采用远红外陶瓷粉末的成份为ZrO2、Fe2O3、MnO2和相增剂，其中ZrO2为50～80wt%，Fe2O3为5-20wt%;MnO2为10-30wt%和相增强剂。其平均料径均为＜0.5μm，它在20～50℃能放射出2-25μm的远红外线，辐射系数0.85～0.92。The composition of the far-infrared ceramic powder used in the present invention is ZrO 2 , Fe 2 O 3 , MnO 2 and a phase enhancer, wherein ZrO 2 is 50-80wt%, Fe 2 O 3 is 5-20wt%; MnO 2 is 10-30wt% % and phase enhancer. Its average material diameter is <0.5μm, and it can emit 2-25μm far-infrared rays at 20-50°C, with an emissivity coefficient of 0.85-0.92.
2.远红外母粒的制作：2. Production of far infrared masterbatch:
将远红外陶瓷粉末与聚丙烯;聚氨脂;聚酰胺、聚酯等聚合物共混。制成切片或母粒，其中陶瓷粉含量为30～70wt%。Blend far-infrared ceramic powder with polypropylene; polyurethane; polyamide, polyester and other polymers. Made into slices or masterbatches, in which the content of ceramic powder is 30-70wt%.
3.纺丝工艺3. Spinning process
将陶瓷母粒（或切片）与高分子聚合物切片共混，或同时加入色母粒共混。母粒占10～70wt%。在高温下融熔，喷丝，拉伸，卷绕，得初生纤维。经处理后，得到温度、模量、伸长率等各项指标均满足要求的远红外特性纤维。Blend ceramic masterbatches (or slices) with polymer slices, or add color masterbatches for blending at the same time. The masterbatch accounts for 10-70wt%. Melting at high temperature, spinning, stretching, winding to get primary fibers. After treatment, the far-infrared characteristic fiber whose temperature, modulus, elongation and other indicators all meet the requirements is obtained.
本发明可以通过改变喷丝板组件生产出中空、三角、三叶等异型丝。由于超细的陶瓷粉比表面大，在异型丝的纺丝过程中可适度增加纺丝速度。The invention can produce hollow, triangular, trilobal and other special-shaped filaments by changing the spinneret assembly. Due to the large specific surface area of ultra-fine ceramic powder, the spinning speed can be moderately increased during the spinning process of profiled yarn.
4.织物的制作4. Fabrication
将牵伸后的原丝或经处理后的纱绒按不同的规格，不同服用要求组造出各种不同用途的衣物。Combining the drawn raw silk or the treated velvet according to different specifications and different wearing requirements to produce a variety of clothes for different purposes.
如：胸衣、腹带、运动衣裤、袜子、床单，各种衣服、裤子，装饰织物等和各种卫生保健用衣物。Such as: bras, girdles, sportswear, socks, bed sheets, all kinds of clothes, pants, decorative fabrics, etc. and various health care clothes.
采用本发明的积极效果：由于用小于0.5μm的超细陶瓷粉末和母粒制作的方法，提高了陶瓷粉在纤维中的含量和均匀度。使纤维中的远红外辐射的比表面增大，辐射效果好。共混纺丝的远红外纤维其远红外辐射特性不受洗涤影响，辐射效果持久。同时，纺织的纤维其强度，伸缩性，柔软性等都很好，大大提高了纤维本身的性能指标。The positive effect of adopting the present invention is that the content and uniformity of the ceramic powder in the fiber are improved due to the method of making the ultrafine ceramic powder and master batch less than 0.5 μm. The specific surface of the far-infrared radiation in the fiber is increased, and the radiation effect is good. The far-infrared radiation characteristics of the blended and spun far-infrared fibers are not affected by washing, and the radiation effect is long-lasting. At the same time, the strength, flexibility and softness of the woven fiber are all very good, which greatly improves the performance index of the fiber itself.
实施例：Example:
陶瓷粉60wt%ZrO2，18%Fe2O3;12wt%MnO2和加入20wt%相增强剂，其平均粒度＜0.5μm;它们与30wt%聚丙烯共混制成母粒。再将母粒与聚丙烯按100∶70混合共熔于织纺机上纺成不同规格的纤维。纤维经过加弹等后处理，纺成衣服，袜子等。纤维的强度为5.2克/旦，断裂伸长为38.6%，沸水收缩为3.1%，是性能优异的纤维。织成物具有良好的保健功能。如用它制成的文胸。具有促进血液循环，起到消炎活血的作用。Ceramic powder 60wt% ZrO 2 , 18% Fe 2 O 3 ; 12wt% MnO 2 and adding 20wt% phase enhancer, the average particle size is <0.5μm; they are blended with 30wt% polypropylene to make masterbatch. Then the masterbatch and polypropylene are mixed and co-melted at a ratio of 100:70 and spun on a weaving machine to form fibers of different specifications. The fiber is spun into clothes, socks, etc. after post-processing such as texturing. The strength of the fiber is 5.2 g/denier, the elongation at break is 38.6%, and the boiling water shrinkage is 3.1%, which is a fiber with excellent performance. Fabrics have good health care functions. Such as bras made of it. It can promote blood circulation and play the role of anti-inflammatory and blood circulation.
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93104713 CN1033597C (en) | 1993-05-07 | 1993-05-07 | Far-infrared ceramic chemical fibre |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93104713 CN1033597C (en) | 1993-05-07 | 1993-05-07 | Far-infrared ceramic chemical fibre |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1095118A true CN1095118A (en) | 1994-11-16 |
| CN1033597C CN1033597C (en) | 1996-12-18 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 93104713 Expired - Fee Related CN1033597C (en) | 1993-05-07 | 1993-05-07 | Far-infrared ceramic chemical fibre |
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| Country | Link |
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| CN (1) | CN1033597C (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997036027A1 (en) * | 1996-03-25 | 1997-10-02 | Baoling Zhang | A far-infrared fabric, the preparing method and the usage thereof |
| CN100344804C (en) * | 2003-12-25 | 2007-10-24 | 纳米科技国际集团有限公司 | Bioactive nanofibers and their products |
| SG138444A1 (en) * | 2002-12-04 | 2008-01-28 | Inventio Ag | Reinforced synthetic cable for lifts |
| WO2008098473A1 (en) * | 2007-02-15 | 2008-08-21 | Shenzhen Yuelang Techno-Industrial Co., Ltd. | A far-infrared anion compound sanitary napkin and pad |
| CN100575573C (en) * | 2004-11-08 | 2009-12-30 | 住友金属矿山株式会社 | Near-infrared-absorbing fiber and fiber product using the same |
| CN104480573A (en) * | 2014-12-23 | 2015-04-01 | 常熟市云燕化纤有限公司 | Fireproof and antibacterial fiber |
| CN106245127A (en) * | 2016-08-03 | 2016-12-21 | 三德亿顺商贸(深圳)有限公司 | A kind of natural nano-mineral stone powder functional fibre and a kind of functional heat energy cotton |
| CN107151843A (en) * | 2017-05-23 | 2017-09-12 | 浙江亚星纤维有限公司 | A kind of manufacture method of the bright and beautiful ammonia cladding wire of far-infrared negative-ion |
| CN109629035A (en) * | 2018-12-25 | 2019-04-16 | 南通东屹高新纤维科技有限公司 | A kind of manufacture craft of 56 fiber of biology base nylon with far-infrared functional |
| CN110629340A (en) * | 2019-08-26 | 2019-12-31 | 宁波大千纺织品有限公司 | Seaweed carbon fiber far infrared moisture absorption multifunctional fabric and preparation method thereof |
-
1993
- 1993-05-07 CN CN 93104713 patent/CN1033597C/en not_active Expired - Fee Related
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997036027A1 (en) * | 1996-03-25 | 1997-10-02 | Baoling Zhang | A far-infrared fabric, the preparing method and the usage thereof |
| SG138444A1 (en) * | 2002-12-04 | 2008-01-28 | Inventio Ag | Reinforced synthetic cable for lifts |
| CN100344804C (en) * | 2003-12-25 | 2007-10-24 | 纳米科技国际集团有限公司 | Bioactive nanofibers and their products |
| CN100575573C (en) * | 2004-11-08 | 2009-12-30 | 住友金属矿山株式会社 | Near-infrared-absorbing fiber and fiber product using the same |
| WO2008098473A1 (en) * | 2007-02-15 | 2008-08-21 | Shenzhen Yuelang Techno-Industrial Co., Ltd. | A far-infrared anion compound sanitary napkin and pad |
| CN104480573A (en) * | 2014-12-23 | 2015-04-01 | 常熟市云燕化纤有限公司 | Fireproof and antibacterial fiber |
| CN106245127A (en) * | 2016-08-03 | 2016-12-21 | 三德亿顺商贸(深圳)有限公司 | A kind of natural nano-mineral stone powder functional fibre and a kind of functional heat energy cotton |
| CN107151843A (en) * | 2017-05-23 | 2017-09-12 | 浙江亚星纤维有限公司 | A kind of manufacture method of the bright and beautiful ammonia cladding wire of far-infrared negative-ion |
| CN109629035A (en) * | 2018-12-25 | 2019-04-16 | 南通东屹高新纤维科技有限公司 | A kind of manufacture craft of 56 fiber of biology base nylon with far-infrared functional |
| CN110629340A (en) * | 2019-08-26 | 2019-12-31 | 宁波大千纺织品有限公司 | Seaweed carbon fiber far infrared moisture absorption multifunctional fabric and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1033597C (en) | 1996-12-18 |
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