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CN109516816A - A kind of shell active carbon removes ceramic material of scale and preparation method thereof - Google Patents

A kind of shell active carbon removes ceramic material of scale and preparation method thereof Download PDF

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Publication number
CN109516816A
CN109516816A CN201811566195.0A CN201811566195A CN109516816A CN 109516816 A CN109516816 A CN 109516816A CN 201811566195 A CN201811566195 A CN 201811566195A CN 109516816 A CN109516816 A CN 109516816A
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Prior art keywords
parts
active carbon
conch meal
shell
ceramic material
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Pending
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CN201811566195.0A
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Chinese (zh)
Inventor
陈旭亚
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Hangzhou Yushanjin Environmental Protection Technology Co Ltd
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Hangzhou Yushanjin Environmental Protection Technology Co Ltd
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Priority to CN201811566195.0A priority Critical patent/CN109516816A/en
Publication of CN109516816A publication Critical patent/CN109516816A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605Treating the starting powders individually or as mixtures
    • C04B35/62645Thermal treatment of powders or mixtures thereof other than sintering
    • C04B35/62675Thermal treatment of powders or mixtures thereof other than sintering characterised by the treatment temperature
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/04Clay; Kaolin
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/131Inorganic additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54Particle size related information
    • C04B2235/5418Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5427Particle size related information expressed by the size of the particles or aggregates thereof millimeter or submillimeter sized, i.e. larger than 0,1 mm
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54Particle size related information
    • C04B2235/5418Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5436Particle size related information expressed by the size of the particles or aggregates thereof micrometer sized, i.e. from 1 to 100 micron
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Environmental & Geological Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Medicines Containing Material From Animals Or Micro-Organisms (AREA)
  • Water Treatment By Sorption (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

The invention discloses the ceramic materials that a kind of shell active carbon removes scale, its raw material poidometer by weight is as follows: 10-15 parts of conch meal, 7-12 parts of rock phosphate in powder, 10-15 parts of zeolite, 20-25 parts of clay, 8-12 parts of silicon ore, 6-15 parts of stone needle, 10-15 parts of active carbon, 9-12 parts of selenium mine soil, 8-15 parts of diatomite.Conch meal and active carbon is added in the present invention, ceramic liner is added as raw material using the conch meal and active carbon of crushing, so that the conch meal in conch meal be enable to play the role of absorption; and there is no saturability; service life using for a long time, can adsorb hazardous substance for a long time, protect family health;The rock phosphate in powder and silicon ore of addition, it can stablize various carbonate in water, and calcium carbonate not soluble in water can be made to be converted into the calcium monohydrogen phosphate for being dissolved in water, it is made to keep stablizing in a heated state, therefore achieve the purpose that control fouling.The liner of such ceramic material has health care, sterilizes, and absorption purifies water, the effect of scale-deposit-preventing.

Description

A kind of shell active carbon removes ceramic material of scale and preparation method thereof
Technical field
The present invention relates to technical field of ceramic material more particularly to a kind of shell active carbon go scale ceramic material and its Preparation method.
Background technique
Common ceramic material has clay, aluminium oxide, kaolin etc..The general hardness of ceramic material is higher, but plasticity compared with Difference.Ceramic material is used in feeder, on decoration more.
It is poor to the adsorptivity of impurity in water using liner made of existing ceramic material, it cannot be adsorbed with for a long time Evil substance, and liner is easy to fouling in a heated state, long-time service is not conducive to good health.
Summary of the invention
The purpose of the present invention is to solve disadvantages existing in the prior art, and a kind of shell active carbon proposed removes water The ceramic material and preparation method thereof of dirt.
To achieve the goals above, present invention employs following technical solutions:
A kind of shell active carbon removes the ceramic material of scale, and raw material poidometer by weight is as follows: 10-15 parts of conch meal, phosphorus 7-12 parts of ore, 10-15 parts of zeolite, 20-25 parts of clay, 8-12 parts of silicon ore, 6-15 parts of stone needle, 10-15 parts of active carbon, selenium mine It is 9-12 parts native, 8-15 parts of diatomite.
Preferably, the conch meal impregnates in the hydrochloric acid solution of 0.1-0.3% the preparation method is as follows: cleaning shell 30-40min is calcined 1-2 hours at 900-1000 DEG C after taking-up drains, is washed with deionized water, dries, using planetary ball Grinding machine is ground, and be finally sieved to obtain conch meal.
Preferably, the conch meal is any one in pearl shell, abalone shells or oyster shell, the conch meal.
Preferably, the sieve mesh number used is sieved as 120-200.
A kind of shell active carbon goes the preparation method of the ceramic material of scale, includes the following steps:
S1: respectively by rock phosphate in powder, zeolite, silicon ore, stone needle crushed, is sieved, is then placed in ball mill, is milled to partial size It is 50-100 μm, obtains mixture A;
S2: to clay, selenium mine soil and diatomite are dried, and are crushed, and obtain mixture B after being then sieved;
It after S3: mixture A and mixture B mixing, then puts into conch meal and active carbon after mixing, is baked, bake temperature Degree is 450-520 DEG C, and baking time is 4-5 hours, finally screens, obtains ceramic material.
Compared with prior art, the beneficial effects of the present invention are: a kind of shell active carbon provided by the invention removes scale Ceramic material and preparation method thereof is added conch meal and active carbon, adds using the conch meal and active carbon of crushing as raw material Enter ceramic liner, so that the conch meal in conch meal be enable to play the role of absorption, and there is no saturability, it is permanent that the service life uses, can Absorption hazardous substance for a long time protects family health;
The rock phosphate in powder and silicon ore of addition, it can stablize various carbonate in water, and calcium carbonate not soluble in water can be made to be converted into It is dissolved in the calcium monohydrogen phosphate of water, it is made to keep stablizing in a heated state, therefore achievees the purpose that control fouling, using shell activity The liner water that charcoal ceramic liner purifies has good health value;
Selenium mine soil is added, supplements the selenium element of needed by human body, may participate in human metabolism, improve the immunity of the human body;
Be added stone needle, supplement human body necessary to calcium, magnesium, zinc, chromium, strontium, etc. more than 20 kinds of anti-aging elements;
The liner of such ceramic material has health care, sterilizes, and absorption purifies water, the effect of scale-deposit-preventing, and service life Long, persistently protection is healthy.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, below in conjunction with specific embodiment, to this Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not For limiting the present invention.
Embodiment 1
A kind of shell active carbon removes the ceramic material of scale, and raw material poidometer by weight is as follows: 10 parts of conch meal, rock phosphate in powder 7 parts, 10 parts of zeolite, 20 parts of clay, 8 parts of silicon ore, 6 parts of stone needle, 10 parts of active carbon, 9 parts, 8 parts of diatomite of soil of selenium mine.
Specifically, the conch meal impregnates in 0.1% hydrochloric acid solution the preparation method is as follows: cleaning shell 40min is calcined 1 hour at 1000 DEG C after taking-up drains, is washed with deionized water, dries, ground using planetary ball mill It is milled broken, be finally sieved to obtain conch meal.
Specifically, the conch meal is any one in pearl shell, abalone shells or oyster shell, the conch meal.
Specifically, the sieve mesh number that uses of sieving is 200.
A kind of shell active carbon goes the preparation method of the ceramic material of scale, includes the following steps:
S1: respectively by rock phosphate in powder, zeolite, silicon ore, stone needle crushed, is sieved, is then placed in ball mill, is milled to partial size It is 50 μm, obtains mixture A;
S2: to clay, selenium mine soil and diatomite are dried, and are crushed, and obtain mixture B after being then sieved;
It after S3: mixture A and mixture B mixing, then puts into conch meal and active carbon after mixing, is baked, bake temperature Degree is 450 DEG C, and baking time is 5 hours, finally screens, obtains ceramic material.
Embodiment 2
A kind of shell active carbon removes the ceramic material of scale, and raw material poidometer by weight is as follows: 15 parts of conch meal, rock phosphate in powder 12 parts, 15 parts of zeolite, 25 parts of clay, 12 parts of silicon ore, 15 parts of stone needle, 15 parts of active carbon, 12 parts, 15 parts of diatomite of soil of selenium mine.
Specifically, the conch meal impregnates in 0.3% hydrochloric acid solution the preparation method is as follows: cleaning shell 30min is calcined 2 hours at 1000 DEG C after taking-up drains, is washed with deionized water, dries, ground using planetary ball mill It is milled broken, be finally sieved to obtain conch meal.
Specifically, the conch meal is any one in pearl shell, abalone shells or oyster shell, the conch meal.
Specifically, the sieve mesh number that uses of sieving is 180.
A kind of shell active carbon goes the preparation method of the ceramic material of scale, includes the following steps:
S1: respectively by rock phosphate in powder, zeolite, silicon ore, stone needle crushed, is sieved, is then placed in ball mill, is milled to partial size It is 100 μm, obtains mixture A;
S2: to clay, selenium mine soil and diatomite are dried, and are crushed, and obtain mixture B after being then sieved;
It after S3: mixture A and mixture B mixing, then puts into conch meal and active carbon after mixing, is baked, bake temperature Degree is 520 DEG C, and baking time is 4 hours, finally screens, obtains ceramic material.
A kind of shell active carbon provided by the invention removes ceramic material of scale and preparation method thereof, and conch meal and work is added Property charcoal, using crushing conch meal and active carbon as raw material be added ceramic liner, to enable the conch meal in conch meal There is absorption, and there is no saturability, the service life using for a long time, can adsorb hazardous substance for a long time, protect family health;
The rock phosphate in powder and silicon ore of addition, it can stablize various carbonate in water, and calcium carbonate not soluble in water can be made to be converted into It is dissolved in the calcium monohydrogen phosphate of water, it is made to keep stablizing in a heated state, therefore achievees the purpose that control fouling, using shell activity The liner water that charcoal ceramic liner purifies has good health value;
Selenium mine soil is added, supplements the selenium element of needed by human body, may participate in human metabolism, improve the immunity of the human body;
Be added stone needle, supplement human body necessary to calcium, magnesium, zinc, chromium, strontium, etc. more than 20 kinds of anti-aging elements;
The liner of such ceramic material has health care, sterilizes, and absorption purifies water, the effect of scale-deposit-preventing, and service life Long, persistently protection is healthy.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (5)

1. the ceramic material that a kind of shell active carbon removes scale, it is characterised in that: its raw material poidometer by weight is as follows: shell 10-15 parts of powder, 7-12 parts of rock phosphate in powder, 10-15 parts of zeolite, 20-25 parts of clay, 8-12 parts of silicon ore, 6-15 parts of stone needle, active carbon 10-15 parts, 9-12 parts of selenium mine soil, 8-15 parts of diatomite.
2. the ceramic material that a kind of shell active carbon according to claim 1 removes scale, it is characterised in that: the conch meal 30-40min is impregnated in the hydrochloric acid solution of 0.1-0.3% the preparation method is as follows: cleaning shell, taking-up drain after, 900- It is calcined 1-2 hours at 1000 DEG C, is washed with deionized water, dries, ground using planetary ball mill, is finally sieved Obtain conch meal.
3. the ceramic material that a kind of shell active carbon according to claim 1 removes scale, it is characterised in that: the conch meal For any one in pearl shell, abalone shells or oyster shell, the conch meal.
4. the ceramic material that a kind of shell active carbon according to claim 2 removes scale, it is characterised in that: use of being sieved Sieve mesh number is 120-200.
5. the preparation method that a kind of shell active carbon described in claim 1 removes the ceramic material of scale, it is characterised in that: including Following steps:
S1: respectively by rock phosphate in powder, zeolite, silicon ore, stone needle crushed, is sieved, is then placed in ball mill, is milled to partial size It is 50-100 μm, obtains mixture A;
S2: to clay, selenium mine soil and diatomite are dried, and are crushed, and obtain mixture B after being then sieved;
It after S3: mixture A and mixture B mixing, then puts into conch meal and active carbon after mixing, is baked, bake temperature Degree is 450-520 DEG C, and baking time is 4-5 hours, finally screens, obtains ceramic material.
CN201811566195.0A 2018-12-21 2018-12-21 A kind of shell active carbon removes ceramic material of scale and preparation method thereof Pending CN109516816A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112209702A (en) * 2020-10-14 2021-01-12 武汉轻工大学 Selenium-rich ceramic pot and preparation method thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB299074A (en) * 1927-05-17 1928-10-17 James Gordon Process for conditioning or treating water in boilers and the like to prevent incrustation and corrosion
US20060124301A1 (en) * 2004-12-15 2006-06-15 Bj Services Company Slow release scale inhibitor composites and methods of using the same
CN201785280U (en) * 2010-09-15 2011-04-06 肖玉芳 Household multi-medium and ultraviolet nanofiltration membrane water producer
CN107175071A (en) * 2017-05-05 2017-09-19 浙江艾波特环保科技股份有限公司 A kind of sintering activity charcoal forming filter core
CN107243322A (en) * 2017-06-07 2017-10-13 包鑫 A kind of diatom ore deposit crystalline substance purification particle containing oyster shell whiting and preparation method thereof
CN107416987A (en) * 2017-06-30 2017-12-01 科比环保科技(天津自贸试验区)有限公司 Water softening agent and its preparation method and application
CN107555950A (en) * 2017-07-21 2018-01-09 宜兴市紫云商贸有限公司 A kind of selenium-rich coconut husk inner bag and preparation method thereof
CN108715556A (en) * 2018-08-17 2018-10-30 浙江小水滴环保科技有限公司 Multifunctional ceramic material and its preparation method and application

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB299074A (en) * 1927-05-17 1928-10-17 James Gordon Process for conditioning or treating water in boilers and the like to prevent incrustation and corrosion
US20060124301A1 (en) * 2004-12-15 2006-06-15 Bj Services Company Slow release scale inhibitor composites and methods of using the same
CN201785280U (en) * 2010-09-15 2011-04-06 肖玉芳 Household multi-medium and ultraviolet nanofiltration membrane water producer
CN107175071A (en) * 2017-05-05 2017-09-19 浙江艾波特环保科技股份有限公司 A kind of sintering activity charcoal forming filter core
CN107243322A (en) * 2017-06-07 2017-10-13 包鑫 A kind of diatom ore deposit crystalline substance purification particle containing oyster shell whiting and preparation method thereof
CN107416987A (en) * 2017-06-30 2017-12-01 科比环保科技(天津自贸试验区)有限公司 Water softening agent and its preparation method and application
CN107555950A (en) * 2017-07-21 2018-01-09 宜兴市紫云商贸有限公司 A kind of selenium-rich coconut husk inner bag and preparation method thereof
CN108715556A (en) * 2018-08-17 2018-10-30 浙江小水滴环保科技有限公司 Multifunctional ceramic material and its preparation method and application

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112209702A (en) * 2020-10-14 2021-01-12 武汉轻工大学 Selenium-rich ceramic pot and preparation method thereof

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