CN1094382A - Slag alkali cement and manufacture method thereof - Google Patents
Slag alkali cement and manufacture method thereof Download PDFInfo
- Publication number
- CN1094382A CN1094382A CN93110678A CN93110678A CN1094382A CN 1094382 A CN1094382 A CN 1094382A CN 93110678 A CN93110678 A CN 93110678A CN 93110678 A CN93110678 A CN 93110678A CN 1094382 A CN1094382 A CN 1094382A
- Authority
- CN
- China
- Prior art keywords
- slag
- cement
- alkali
- manufacture method
- activator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002893 slag Substances 0.000 title claims abstract description 48
- 239000004568 cement Substances 0.000 title claims abstract description 36
- 239000003513 alkali Substances 0.000 title claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 238000000034 method Methods 0.000 title claims abstract description 10
- 239000012190 activator Substances 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 8
- 239000007787 solid Substances 0.000 claims abstract description 7
- 238000001035 drying Methods 0.000 claims abstract description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- 238000000227 grinding Methods 0.000 claims description 7
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 6
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 claims description 6
- 229910052748 manganese Inorganic materials 0.000 claims description 6
- 239000011572 manganese Substances 0.000 claims description 6
- 239000000292 calcium oxide Substances 0.000 claims description 5
- 235000012255 calcium oxide Nutrition 0.000 claims description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 4
- 239000010881 fly ash Substances 0.000 claims description 3
- 235000017550 sodium carbonate Nutrition 0.000 claims description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- GYZGFUUDAQXRBT-UHFFFAOYSA-J calcium;disodium;disulfate Chemical compound [Na+].[Na+].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GYZGFUUDAQXRBT-UHFFFAOYSA-J 0.000 claims description 2
- 229910052602 gypsum Inorganic materials 0.000 claims description 2
- 239000010440 gypsum Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 239000011574 phosphorus Substances 0.000 claims description 2
- 229910052698 phosphorus Inorganic materials 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- OBSZRRSYVTXPNB-UHFFFAOYSA-N tetraphosphorus Chemical compound P12P3P1P32 OBSZRRSYVTXPNB-UHFFFAOYSA-N 0.000 claims description 2
- 235000005979 Citrus limon Nutrition 0.000 claims 1
- 244000248349 Citrus limon Species 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 239000002699 waste material Substances 0.000 abstract description 11
- 238000005516 engineering process Methods 0.000 abstract description 5
- 239000003469 silicate cement Substances 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000011398 Portland cement Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 159000000000 sodium salts Chemical class 0.000 description 5
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229930013930 alkaloid Natural products 0.000 description 1
- 150000003797 alkaloid derivatives Chemical class 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/14—Cements containing slag
- C04B7/147—Metallurgical slag
- C04B7/153—Mixtures thereof with other inorganic cementitious materials or other activators
- C04B7/1535—Mixtures thereof with other inorganic cementitious materials or other activators with alkali metal containing activators, e.g. sodium hydroxide or waterglass
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/20—Retarders
- C04B2103/22—Set retarders
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
What the present invention relates to is slag alkali cement and manufacture method thereof, it is characterized in that adopting slag, the high alkali-activator of solid and retardant to make raw material, the common levigate cement that makes after the drying both can be as the convenient use of silicate cement, and its physical and mechanical property is better than other cement with label again, technology investment is few simultaneously, production unit is simple, has made full use of waste residue, turns waste into wealth, improve environment, society and remarkable in economical benefits.
Description
The invention belongs to cement and make the field.
Traditional cement manufacturing method is to adopt two mills, one firing technique, is about to the levigate roasting of starting material and generates grog, and is again that grog and spike is levigate.This technology investment is big, the energy consumption height, and the high offscum in alkali number of metallurgical slag, flyash, chemical industry of the annual discharging in the whole nation can't effectively utilize serious pollution of ecological environment mostly with hundred million tons.Initial stage in the sixties, but Soviet Union scientist begin the lateral reactivity of alkali activated slag is studied, utilize highly basic activated slag lateral reactivity, make it setting and harden, obtain cured body, promptly alleged alkali slag cement and concrete as cement stone.It is actually uses the slag powders with certain fineness, this powder can not as silicate cement alone with water effect setting and harden, when using, the highly basic exciting agent need be mixed with liquid, or with liquid as exciting agent, again with slag powders, gathering materials is mixed into concrete, use, all very inconvenience of transportation.And if solid alkali exciting agent and slag are worn into cement altogether because solid alkali is expensive, so cost height not only, and strength of cement is lower again, so be difficult to apply.
The purpose of this invention is to provide a kind of slag alkali cement and manufacturing process thereof, the slag alkali cement of being produced can equally with ordinary Portland cement use, this technology can reduce investment, cut down the consumption of energy, and the cement early strength height of being produced, later strength increases by a fairly big margin, and has better physical and mechanical property.
Solution of the present invention is, uses slag, the high alkali-activator of solid and retardant to make raw material, and drying to residual water-content is not more than 1%, common grinding to required fineness cement, wherein high-alkali sharp side sends out that alkalinity is in the agent: with equivalent Na
2O weight counts 8～55%, and the proportioning of slag and high alkali-activator is 100: (3～60).
In technique scheme, the proportioning of slag and high alkali-activator is according to following principle the preparation, (SiO in the slag
2) and (Al
2O
3) total amount and the (K in the high alkali-activator
2O) and (Na
2O) ratio of total amount: ((SiO
2)+(Al
2O
3))/((Na
2O)+(K
2=60/1～20/1, and (CaO) in the cement and (SiO O))
2) and (Al
2O
3) ratio of total amount need satisfy ((CaO))/((SiO
2)+(Al
2O
3))=1/2～1/0.5, the content of determining alkali in the high alkali-activator is to guarantee reliable activated slag lateral reactivity.Raw material stoving to residual water-content is not more than 1%, is convenient to grinding on the one hand, the cement that makes on the other hand can not harden before use.With the common grinding of raw material of oven dry, make the raw material can thorough mixing, by test,, make the cement that makes behind the raw material thorough mixing through common grinding, its physical and mechanical property is greatly improved.
Detailed content of the present invention further describes as follows:
Described slag comprises one or more in the non-ferrous metal slags such as blast furnace slag, phosphorus slag, slag, flyash and manganese slag, has made full use of the waste residue of metallurgy industry discharging, turns waste into wealth, and has improved environment again.Described high alkali-activator comprises one or more in saltcake, glauberite, chemical industry alkaline residue, soda ash, sodium sulfate, grog, the unslaked lime etc., like this, adopt on the one hand solid alkali can with the common together grinding of slag, thorough mixing, improve the physical and mechanical property of cement, the cement that makes on the other hand can equally with Portland cement use, and is very convenient, uses the disadvantage of being brought thereby avoided needing that the highly basic exciting agent is made into liquid.Owing to adopt solid alkali to make exciting agent, use highly basic scope to enlarge relatively simultaneously, except the expensive solid-state soda ash of price, alkaloid substance that some other is cheap and alkaline residue all can use, not only reduced cost, but also can turn waste into wealth, comprehensive utilization.Described retardant comprises one or more in gypsum, phosphogypsum, yellow phosphorus slag, sugar, the citric acid etc.
The made cement fineness of the present invention is 4900 holes/cm
2Tail over and be not more than 15%, satisfy requirement of engineering to guarantee the cement that makes.
Slag cement provided by the invention and manufacture method thereof are because the characteristics of its raw material and technology, make the cement that makes in use as ordinary Portland cement, and this cement has the early strength height, and later strength increases big, and physical and mechanical property is better than the characteristics with other cement of label.By the slag alkali cement of this prescription with production method, technology investment is few, and production unit is simple, has saved the energy, and has made full use of waste residue, changes evil for benefit, improves environment, society and remarkable in economical benefits.
Specific examples scheme of the present invention is provided by following examples, and further specifies effect of the present invention.
Embodiment 1:
Metallurgical manganese slag, chemical industry sodium salt waste residue, phosphogypsum are dried in stoving oven, make residual water-content be not more than 1%, by following proportioning jointly in pulverizer levigate to 4900 holes/cm
2, tail over and be not more than 15%.
Proportioning: manganese slag: chemical industry sodium salt waste residue: grog: phosphogypsum=68: 15: 10: 7
According to the cement quality examination criteria, get following detected result:
It is early strong that the cement that this proportioning is made into reaches ordinary Portland cement 525() the type standard.
The chemical ingredients of manganese slag, chemical industry sodium salt waste residue, grog is as follows:
| SiO 2 | Al 2O 3 | CaO | MnO | Na 2O | K 2O | Fe 2O 3 | SO 2 | |
| Manganese slag sodium slag grog | 27.93 20.68 22.35 | 12.30 10.65 5.77 | 38.42 2.49 65.59 | 7.98 | 29.12 1.62 | 1.41 | 0.45 5.03 4.07 | 0.93 3.30 |
Example 2:
With blast furnace slag, lime, chemical industry sodium salt waste residue, phosphogypsum oven dry, be 4900 holes/cm by the common mix grinding of following proportioning to fineness
2Tail over and be not more than 15%.
Water-granulated slag: chemical industry sodium salt waste residue: lime: phosphogypsum=75: 15: 3: 7
According to the cement quality examination criteria, get following detected result:
It is early strong that this example cement reaches ordinary Portland cement 425R() the type standard.
Claims (4)
1, a kind of slag alkali cement and manufacture method thereof, feature of the present invention is to use slag, the high alkali-activator of solid and retardant to make raw material, drying to residual water-content is not more than 1%, common grinding to required fineness cement, wherein the proportioning of slag and high alkali-activator is 100: (3～60).
2, slag alkali cement according to claim 1 and manufacture method thereof is characterized in that described slag comprises one or more in the non-ferrous metal slags such as blast furnace slag, phosphorus slag, slag, flyash and manganese slag.
3, slag alkali cement according to claim 1 and manufacture method thereof is characterized in that high alkali-activator comprises one or more in saltcake, glauberite, chemical industry alkaline residue, soda ash, sodium sulfate, grog, the unslaked lime etc.
4, slag alkali cement according to claim 1 and manufacture method thereof is characterized in that retardant comprises one or more in gypsum, phosphogypsum, yellow phosphorus slag, sugar, the stubborn lemon acid etc.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN93110678A CN1094382A (en) | 1993-04-24 | 1993-04-24 | Slag alkali cement and manufacture method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN93110678A CN1094382A (en) | 1993-04-24 | 1993-04-24 | Slag alkali cement and manufacture method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1094382A true CN1094382A (en) | 1994-11-02 |
Family
ID=4988515
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN93110678A Pending CN1094382A (en) | 1993-04-24 | 1993-04-24 | Slag alkali cement and manufacture method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1094382A (en) |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102167533A (en) * | 2010-12-30 | 2011-08-31 | 中南大学 | Slag cement admixture including compositely activated and modified manganese slag and preparation method thereof |
| CN103979867A (en) * | 2014-04-16 | 2014-08-13 | 安徽颐鑫节能材料有限公司 | Phosphorus slag/steel slag composite lightweight partition board and production method thereof |
| CN104016603A (en) * | 2014-06-27 | 2014-09-03 | 淮安市楚城水泥有限公司 | Preparation method of industrial waste residue mixed ore powder |
| CN105060758A (en) * | 2015-08-26 | 2015-11-18 | 西南科技大学 | Method for preparing alkali-slag cement retarder through jarosite slag |
| CN106220007A (en) * | 2016-07-29 | 2016-12-14 | 淮安市水泥厂有限公司 | A kind of method that activation fine coal produces wear-resisting impervious, cement |
| CN106587673A (en) * | 2016-12-12 | 2017-04-26 | 天津凡旋科技有限公司 | Green and environment-friendly type ecological cement |
| CN106746784A (en) * | 2016-12-12 | 2017-05-31 | 天津凡旋科技有限公司 | One kind building environment protecting cement |
| CN108059373A (en) * | 2017-11-30 | 2018-05-22 | 中冶建筑研究总院有限公司 | Application of the alkali-slag cement as treatment of soft foundation material |
| CN108249789A (en) * | 2018-01-15 | 2018-07-06 | 三峡大学 | A kind of phosphorus slag base compound cementitious matter of no first-hand datum and preparation method thereof |
| CN108275899A (en) * | 2018-03-09 | 2018-07-13 | 济南大学 | A kind of alkali-excited cement and preparation method thereof |
| CN110922148A (en) * | 2019-11-11 | 2020-03-27 | 中建西部建设湖南有限公司 | Light wallboard prepared from phosphate tailings and slag sulfate cement and preparation method thereof |
| CN112960920A (en) * | 2021-04-27 | 2021-06-15 | 天津金石建材科技有限公司 | Green ecological environment-friendly cement and preparation method thereof |
| CN114956614A (en) * | 2022-05-30 | 2022-08-30 | 中国地质大学（武汉） | Slag cement based on synergistic excitation of sodium citrate and caustic alkali and preparation method thereof |
| CN115259757A (en) * | 2022-07-18 | 2022-11-01 | 东南大学 | Modified geopolymer foam light soil and preparation method thereof |
| CN116354641A (en) * | 2023-04-03 | 2023-06-30 | 徐州科建环保科技有限公司 | High-performance slag micropowder |
| CN117049805A (en) * | 2023-10-13 | 2023-11-14 | 河北省建筑科学研究院有限公司 | Preparation method of cementing material with ammonia alkali white mud-slag-fly ash as raw material |
| CN119822715A (en) * | 2025-02-19 | 2025-04-15 | 天津大学 | Slag-steel slag base polymer concrete and preparation method thereof |
-
1993
- 1993-04-24 CN CN93110678A patent/CN1094382A/en active Pending
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102167533A (en) * | 2010-12-30 | 2011-08-31 | 中南大学 | Slag cement admixture including compositely activated and modified manganese slag and preparation method thereof |
| CN103979867A (en) * | 2014-04-16 | 2014-08-13 | 安徽颐鑫节能材料有限公司 | Phosphorus slag/steel slag composite lightweight partition board and production method thereof |
| CN104016603A (en) * | 2014-06-27 | 2014-09-03 | 淮安市楚城水泥有限公司 | Preparation method of industrial waste residue mixed ore powder |
| CN104016603B (en) * | 2014-06-27 | 2016-04-06 | 淮安市楚城水泥有限公司 | The preparation method of industrial residue formula mixed mineral powder |
| CN105060758A (en) * | 2015-08-26 | 2015-11-18 | 西南科技大学 | Method for preparing alkali-slag cement retarder through jarosite slag |
| CN105060758B (en) * | 2015-08-26 | 2017-01-18 | 西南科技大学 | Method for preparing alkali-slag cement retarder through jarosite slag |
| CN106220007B (en) * | 2016-07-29 | 2019-04-02 | 淮安市水泥厂有限公司 | A method of wear-resisting impervious, cement is produced with activating fly ash |
| CN106220007A (en) * | 2016-07-29 | 2016-12-14 | 淮安市水泥厂有限公司 | A kind of method that activation fine coal produces wear-resisting impervious, cement |
| CN106587673A (en) * | 2016-12-12 | 2017-04-26 | 天津凡旋科技有限公司 | Green and environment-friendly type ecological cement |
| CN106746784A (en) * | 2016-12-12 | 2017-05-31 | 天津凡旋科技有限公司 | One kind building environment protecting cement |
| CN108059373A (en) * | 2017-11-30 | 2018-05-22 | 中冶建筑研究总院有限公司 | Application of the alkali-slag cement as treatment of soft foundation material |
| CN108249789A (en) * | 2018-01-15 | 2018-07-06 | 三峡大学 | A kind of phosphorus slag base compound cementitious matter of no first-hand datum and preparation method thereof |
| CN108275899A (en) * | 2018-03-09 | 2018-07-13 | 济南大学 | A kind of alkali-excited cement and preparation method thereof |
| CN110922148A (en) * | 2019-11-11 | 2020-03-27 | 中建西部建设湖南有限公司 | Light wallboard prepared from phosphate tailings and slag sulfate cement and preparation method thereof |
| CN112960920A (en) * | 2021-04-27 | 2021-06-15 | 天津金石建材科技有限公司 | Green ecological environment-friendly cement and preparation method thereof |
| CN114956614A (en) * | 2022-05-30 | 2022-08-30 | 中国地质大学（武汉） | Slag cement based on synergistic excitation of sodium citrate and caustic alkali and preparation method thereof |
| CN115259757A (en) * | 2022-07-18 | 2022-11-01 | 东南大学 | Modified geopolymer foam light soil and preparation method thereof |
| CN116354641A (en) * | 2023-04-03 | 2023-06-30 | 徐州科建环保科技有限公司 | High-performance slag micropowder |
| CN116354641B (en) * | 2023-04-03 | 2023-11-10 | 徐州科建环保科技有限公司 | High-performance slag micropowder |
| CN117049805A (en) * | 2023-10-13 | 2023-11-14 | 河北省建筑科学研究院有限公司 | Preparation method of cementing material with ammonia alkali white mud-slag-fly ash as raw material |
| CN117049805B (en) * | 2023-10-13 | 2024-01-16 | 河北省建筑科学研究院有限公司 | Preparation method of cementing material with ammonia alkali white mud-slag-fly ash as raw material |
| CN119822715A (en) * | 2025-02-19 | 2025-04-15 | 天津大学 | Slag-steel slag base polymer concrete and preparation method thereof |
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