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CN109232005A - Kilneye castable after a kind of cement rotary kiln - Google Patents

Kilneye castable after a kind of cement rotary kiln Download PDF

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Publication number
CN109232005A
CN109232005A CN201811277013.8A CN201811277013A CN109232005A CN 109232005 A CN109232005 A CN 109232005A CN 201811277013 A CN201811277013 A CN 201811277013A CN 109232005 A CN109232005 A CN 109232005A
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CN
China
Prior art keywords
parts
rotary kiln
calcium aluminate
kilneye
cement rotary
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811277013.8A
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Chinese (zh)
Inventor
朱国平
王立旺
李新明
朱其良
王琪
彭晶晶
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Jincheng New Material Ltd By Share Ltd
Original Assignee
Zhejiang Jincheng New Material Ltd By Share Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Jincheng New Material Ltd By Share Ltd filed Critical Zhejiang Jincheng New Material Ltd By Share Ltd
Priority to CN201811277013.8A priority Critical patent/CN109232005A/en
Publication of CN109232005A publication Critical patent/CN109232005A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/66Monolithic refractories or refractory mortars, including those whether or not containing clay

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Products (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)

Abstract

The present invention relates to kilneye castables after a kind of cement rotary kiln, including following each component and parts by weight: 18~25 parts of 8~5mm mullite, 15~20 parts of 5~3mm mullite, 5~10 parts of 3~1mm titanium calcium aluminate, 20~25 parts of 1~0mm titanium calcium aluminate, no more than 200 12~18 parts of mesh titanium calcium aluminate powders, 6~10 parts of alumina powder, 4~8 parts of aluminous cement, 2~4 parts of silicon powder, 0.01~0.03 part of explosion-proof fiber, 0.01~0.03 part of water-reducing agent.The present invention is using mullite and aluminium titanates calcium as composite aggregate, microdilatancy effect is generated using the mullitization reaction in matrix and the object phase change in titanium calcium aluminate, the thermal shock resistance of castable is improved, while also avoiding the oxidative phenomena that carbofrax material is introduced and generated.

Description

Kilneye castable after a kind of cement rotary kiln
Technical field
The invention belongs to technical field of refractory materials, and in particular to kilneye castable after a kind of cement rotary kiln.
Background technique
New type nonaqueous cement rotary kiln has the characteristics that kiln temperature is higher, kiln is fast faster, alkali corrodes exacerbation, structure is more complicated, Traditional cement kiln refractory is no longer satisfied the use of new dry process rotary kiln, it is necessary to corresponding exploitation has excellent performance, Adapt to the novel refractory of new dry process rotary kiln.The operating temperature of kilneye is usually between 1100~1200 DEG C afterwards, relatively Although decreasing in preceding kilneye temperature, as liner, then being difficult to produce using preceding kilneye castable under the conditions of this temperature Raw sufficiently sintering, and by even more serious abrasion and washed away than preceding kilneye, in addition each start-stop kiln can make kilneye position Change dramatically occurs for temperature, and alkaline volatile matter in kiln etc. is enriched at this position, these severe working conditions cause the position Refractory lining used often damages, and damage is mainly manifested in peeling chip off-falling, and since alkali erosion seriously causes structure to be destroyed Local shedding caused by and.
Kilneye castable experienced one from single selection corundum Low Cement Castable, the low cement of High-Alumina after cement kiln Castable is extended to the process including more materials such as mullite, mullite silicon carbide.Corundum pouring material is at high cost, high Aluminum castable thermal shock resistance is poor, and the castable inoxidizability of silicon carbide-containing matter is poor, is all difficult to reach in terms of service life To synchronous with cement kiln liner tile.Titanium calcium aluminate was widely applied in recent years as a kind of novel material, in titanium calcium aluminate Principal crystalline phase is calcium hexaluminate and titanium calcium aluminate, and secondary crystal phase is by the high temperature phase composition such as a small amount of Calcium dialuminate, aluminium titanates, calcium titanate, tool Have that thermal stability is good, not aquation, the features such as thermal expansion coefficient is low, and thermal shock resistance is good, and wear-resisting property is excellent.Patent CN107311677A, CN107285786A, CN105036774B etc. are disclosed using titanium calcium aluminate as raw material preparation fire resisting Material, but usage mode, application field, in terms of be not able to satisfy cement rotary kiln after kilneye to refractory material Application requirement.
Summary of the invention
Technical problem to be solved by the present invention lies in kilneye castable after a kind of cement rotary kiln is provided, use does not come Stone and aluminium titanates calcium are generated micro- as composite aggregate using the mullitization reaction in matrix and the object phase change in titanium calcium aluminate Bulking effect, improves the thermal shock resistance of castable, while also avoiding the oxidative phenomena that carbofrax material is introduced and generated.
In order to solve the above technical problems, kilneye castable after a kind of cement rotary kiln provided by the invention, including it is following Each component and parts by weight:
Preferably, the mullite includes 8~5mm, 5~3mm, two kinds of specifications, and the parts by weight of various specifications are as follows:
18~25 parts of 8~5mm mullite
15~20 parts of 5~3mm mullite.
Preferably, Al in the mullite2O3Mass percentage be not less than 68%.
Preferably, the titanium calcium aluminate includes 3~1mm, 1~0mm, is not more than 200 mesh, three kinds of specifications, the weight of various specifications It is as follows to measure part:
5~10 parts of 3~1mm titanium calcium aluminate
20~25 parts of 1~0mm titanium calcium aluminate
No more than 200 12~18 parts of mesh titanium calcium aluminate powders.
Preferably, Al in the titanium calcium aluminate2O3Mass percentage not less than 70%, the mass percentage of CaO not Less than 10%, TiO2Mass percentage be not less than 10%.
Preferably, Al in the aluminous cement2O3Mass percentage be not less than 50%.
Preferably, the water-reducing agent is Quadrafos.
The technical scheme adopted by the invention is that be arranged specifically for kilneye working condition after cement rotary kiln, using not Come stone and aluminium titanates calcium as composite aggregate, is generated using the mullitization reaction in matrix and the object phase change in titanium calcium aluminate Microdilatancy effect, improves the thermal shock resistance of castable, while also avoiding the oxidative phenomena that carbofrax material is introduced and generated. Kilneye not only reduces cost of material with castable after prepared cement rotary kiln, and service life is also than single using burning It ties mullite and improves 30% or more, with wear-resisting property, excellent, chemerosiveness resistent is by force, refractoriness under load point is high, intensity is high, The feature that thermal shock resistance energy is excellent, anti-structural peeling energy is good, high-temerature creep value is small, hardness is big uses the longevity in rear kilneye Life was more than 1 year or more.It may be implemented to match with kiln liner tile on large-size cement kiln, cement rotary kiln can be greatly improved Running rate, reduce the maintenance frequency of kiln, be conducive to improve cement production enterprise production efficiency and productivity effect, can be substantially Degree reduces the total consumption of large-scale cement production line refractory material, plays apparent effect of energy.
Specific embodiment
Embodiment 1
Kilneye castable after a kind of cement rotary kiln, including following each component and parts by weight:
Wherein, Al in the mullite2O3Mass percentage be not less than 68%.Al in the titanium calcium aluminate2O3Matter It measures mass percentage of the percentage composition not less than 70%, CaO and is not less than 10%, TiO2Mass percentage be not less than 10%.Al in the aluminous cement2O3Mass percentage be not less than 50%.The water-reducing agent is Quadrafos.
Embodiment 2
Kilneye castable after a kind of cement rotary kiln, including following each component and parts by weight:
Wherein, Al in the mullite2O3Mass percentage be not less than 68%.Al in the titanium calcium aluminate2O3Matter It measures mass percentage of the percentage composition not less than 70%, CaO and is not less than 10%, TiO2Mass percentage be not less than 10%.Al in the aluminous cement2O3Mass percentage be not less than 50%.The water-reducing agent is Quadrafos.
Embodiment 3
Kilneye castable after a kind of cement rotary kiln, including following each component and parts by weight:
Wherein, Al in the mullite2O3Mass percentage be not less than 68%.Al in the titanium calcium aluminate2O3Matter It measures mass percentage of the percentage composition not less than 70%, CaO and is not less than 10%, TiO2Mass percentage be not less than 10%.Al in the aluminous cement2O3Mass percentage be not less than 50%.The water-reducing agent is Quadrafos.
Embodiment 4
Kilneye castable after a kind of cement rotary kiln, including following each component and parts by weight:
Wherein, Al in the mullite2O3Mass percentage be not less than 68%.Al in the titanium calcium aluminate2O3Matter It measures mass percentage of the percentage composition not less than 70%, CaO and is not less than 10%, TiO2Mass percentage be not less than 10%.Al in the aluminous cement2O3Mass percentage be not less than 50%.The water-reducing agent is Quadrafos.
Kilneye is as follows with castable performance after cement rotary kiln prepared by above-described embodiment 1-4:
1, chemical component (mass percentage): (Al2O3+SiO2) % >=68%;
2, bulk density (g/cm3): 110 DEG C × for 24 hours >=2.7;
3, strength at normal temperature (MPa): 110 DEG C × for 24 hours >=10,1100 DEG C × 3h >=11;
4, cold crushing strength (MPa): 110 DEG C × for 24 hours >=80,1100 DEG C × 3h >=85;
5, the permanent Linear change rate (%) of heating: 1100 DEG C × 3h ± 0.4.
To sum up, the present invention is reacted using mullite and aluminium titanates calcium as composite aggregate using the mullitization in matrix Microdilatancy effect is generated with the object phase change in titanium calcium aluminate, improves the thermal shock resistance of castable, while also avoiding being carbonized Silicon materials introduce and the oxidative phenomena that generates, are specific to what kilneye working condition after cement rotary kiln was arranged.
Kilneye not only reduces cost of material with castable after prepared cement rotary kiln, and service life is also than list One improves 30% or more using fused mullite, has that wear-resisting property is excellent, chemerosiveness resistent is strong, refractoriness under load point Feature high, intensity is high, thermal shock resistance energy is excellent, anti-structural peeling energy is good, high-temerature creep value is small, hardness is big, no repairing In the case of in the service life of rear kilneye be more than 1 year or more.It may be implemented to match with kiln liner tile on large-size cement kiln, The running rate that cement rotary kiln can be greatly improved reduces the maintenance frequency of kiln, is conducive to the production for improving cement production enterprise The total consumption of large-scale cement production line refractory material can be greatly lowered in efficiency and productivity effect, play apparent energy conservation Consumption reduction effect.
Above description is exemplary and not limiting.By above description skilled person realizes that originally Many kinds of change and modification of invention, will also fall within the spirit and scope of the invention.

Claims (7)

1. kilneye castable after a kind of cement rotary kiln, which is characterized in that including following each component and parts by weight:
2. kilneye castable after a kind of cement rotary kiln according to claim 1, which is characterized in that the mullite packet 8~5mm, 5~3mm, two kinds of specifications are included, the parts by weight of various specifications are as follows:
18~25 parts of 8~5mm mullite
15~20 parts of 5~3mm mullite.
3. kilneye castable after a kind of cement rotary kiln according to claim 1 or 2, which is characterized in that described not come Al in stone2O3Mass percentage be not less than 68%.
4. kilneye castable after a kind of cement rotary kiln according to claim 1, which is characterized in that the titanium calcium aluminate Including 3~1mm, 1~0mm, it is not more than 200 mesh, three kinds of specifications, the parts by weight of various specifications are as follows:
5~10 parts of 3~1mm titanium calcium aluminate
20~25 parts of 1~0mm titanium calcium aluminate
No more than 200 12~18 parts of mesh titanium calcium aluminate powders.
5. kilneye castable after a kind of cement rotary kiln according to claim 1 or 4, which is characterized in that the titanium aluminium Al in sour calcium2O3Mass percentage not less than 70%, the mass percentage of CaO be not less than 10%, TiO2Quality percentage Content is not less than 10%.
6. kilneye castable after a kind of cement rotary kiln according to claim 1, which is characterized in that the calcium aluminate water Al in mud2O3Mass percentage be not less than 50%.
7. kilneye castable after a kind of cement rotary kiln according to claim 1, which is characterized in that the water-reducing agent is Quadrafos.
CN201811277013.8A 2018-10-30 2018-10-30 Kilneye castable after a kind of cement rotary kiln Pending CN109232005A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811277013.8A CN109232005A (en) 2018-10-30 2018-10-30 Kilneye castable after a kind of cement rotary kiln

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811277013.8A CN109232005A (en) 2018-10-30 2018-10-30 Kilneye castable after a kind of cement rotary kiln

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020083408A1 (en) * 2018-10-26 2020-04-30 通达耐火技术股份有限公司 Preparation method for titanium composite anti-erosion wear-resistant refractory castable
CN113979757A (en) * 2021-10-25 2022-01-28 安徽瑞泰新材料科技有限公司 Castable special for cement kiln opening
CN117326879A (en) * 2023-10-25 2024-01-02 襄阳聚力新材料科技有限公司 Special refractory ramming material for calcium titanate aluminate aluminum melting furnace and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104829245A (en) * 2015-04-10 2015-08-12 浙江锦诚耐火材料有限公司 Kilneye prefabricated component for cement kiln
CN105924196A (en) * 2016-05-10 2016-09-07 武汉科技大学 Castable for copper outlet ditch of copper converter and preparing method thereof
CN106747363A (en) * 2016-11-16 2017-05-31 武汉科技大学 A kind of chromite calcination rotary kiln working lining castable and preparation method thereof
CN107311677A (en) * 2017-07-12 2017-11-03 武汉科技大学 A kind of titanium calcium aluminate mullite Multiphase refractory material and preparation method thereof
CN107986805A (en) * 2018-01-22 2018-05-04 武汉科技大学 A kind of light thermal-shield refractory material based on titanium calcium aluminate and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104829245A (en) * 2015-04-10 2015-08-12 浙江锦诚耐火材料有限公司 Kilneye prefabricated component for cement kiln
CN105924196A (en) * 2016-05-10 2016-09-07 武汉科技大学 Castable for copper outlet ditch of copper converter and preparing method thereof
CN106747363A (en) * 2016-11-16 2017-05-31 武汉科技大学 A kind of chromite calcination rotary kiln working lining castable and preparation method thereof
CN107311677A (en) * 2017-07-12 2017-11-03 武汉科技大学 A kind of titanium calcium aluminate mullite Multiphase refractory material and preparation method thereof
CN107986805A (en) * 2018-01-22 2018-05-04 武汉科技大学 A kind of light thermal-shield refractory material based on titanium calcium aluminate and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
徐平坤: "利用炉渣生产耐火材料", 《再生资源与循环经济》 *
李雪松等: "钛铁渣加入量对高铝矾土浇注料抗渣性能的影响", 《陶瓷学报》 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020083408A1 (en) * 2018-10-26 2020-04-30 通达耐火技术股份有限公司 Preparation method for titanium composite anti-erosion wear-resistant refractory castable
CN113979757A (en) * 2021-10-25 2022-01-28 安徽瑞泰新材料科技有限公司 Castable special for cement kiln opening
CN117326879A (en) * 2023-10-25 2024-01-02 襄阳聚力新材料科技有限公司 Special refractory ramming material for calcium titanate aluminate aluminum melting furnace and preparation method thereof

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Application publication date: 20190118

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