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CN1092122A - Function textiles and manufacture method thereof - Google Patents

Function textiles and manufacture method thereof Download PDF

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CN1092122A
CN1092122A CN 94102823 CN94102823A CN1092122A CN 1092122 A CN1092122 A CN 1092122A CN 94102823 CN94102823 CN 94102823 CN 94102823 A CN94102823 A CN 94102823A CN 1092122 A CN1092122 A CN 1092122A
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functional
yarn
viscose
ceramic powder
textiles
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CN1030536C (en
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李雨葆
韩逊滨
杨伏明
关明华
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Advanced Technology and Materials Co Ltd
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China Iron and Steel Research Institute Group
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Abstract

本发明属于功能性纺织物。该纺织物由功能粘 胶纤维和棉纱、涤纶纱或尼纶纱等编织而成;功能粘 胶纤维由功能陶瓷粉末与粘胶组成;功能陶瓷粉的成 分由SiO2、Al2O3、B2O3、FeO、MgO、Na2O、TiO2、 CaO和MnO组成。其制造方法是首先按成分范围 制备功能陶瓷粉末;随后将功能陶瓷粉末与粘胶在一 定条件下制成粘胶棉,进一步制成功能粘胶纤维;该 功能粘胶纤维与棉纱涤纶纱等在编织机上织成纺织 物。The invention belongs to functional textiles. The textile is woven from functional viscose fiber and cotton yarn, polyester yarn or nylon yarn; the functional viscose fiber is composed of functional ceramic powder and viscose; the composition of functional ceramic powder is SiO 2 , Al 2 O 3 , B 2 O 3 , FeO, MgO, Na 2 O, TiO 2 , CaO and MnO. The manufacturing method is to first prepare functional ceramic powder according to the composition range; then make viscose cotton from functional ceramic powder and viscose under certain conditions, and further make functional viscose fiber; the functional viscose fiber and cotton yarn polyester yarn etc. Woven into textiles on a weaving machine.

Description

本发明属于功能性纺织物。适用于编织人体用的内衣、内裤、护膝、袜子和护腰等各种织物。The invention belongs to functional textiles. It is suitable for knitting various fabrics such as underwear, panties, knee pads, socks and waist pads for human body.

在现有技术中,针对人们的保健意识和治病一些常见慢性病的需要,已开发了一些具有增强人体血液循环,提高微循环血流量等生物功能,并能增强体质和消除疾病的仪器或人体附着物等。In the prior art, in response to people's awareness of health care and the need to treat some common chronic diseases, some instruments or human bodies have been developed that have biological functions such as enhancing human blood circulation, improving microcirculation blood flow, and can enhance physical fitness and eliminate diseases. attachments, etc.

日本专利JP03137213提供了一种功能,它是在一种特殊纤维中含有细小的陶瓷粉末。这种材料反射远红外线,具备远红外线辐照、防腐、导热防护、除臭等功能。陶瓷粉末的粒度小于100微米。但是远红外线要在热源的情况下才能发挥作用,使用途受到限制;另外,陶瓷粉末粒度大,其纤维强度低,制成的成品也受到了限制。Japanese patent JP03137213 provides a kind of function, and it is to contain fine ceramic powder in a kind of special fiber. This material reflects far-infrared rays and has functions such as far-infrared radiation, anti-corrosion, heat conduction protection, and deodorization. The particle size of the ceramic powder is less than 100 microns. However, far-infrared rays can only play a role under the condition of a heat source, and the use is limited; in addition, the ceramic powder has a large particle size, and its fiber strength is low, and the finished product is also limited.

EP-331160专利也提供了一种功能材料,该材料由Ti、Zr、V、Nb、Ta、Cr、Ce、Co、Mn等元素的碳化物、氧化物、氮化物、氧-氢化物中一种或多种组成。呈纤维状或粒子状,该材料具有压电性、电子发射性、生物学特性以及磁特性等。可用于电容器、压电体、催化剂、多层电路板、人造骨等。但这种材料难于制成纺织物,用途受到了限制。The EP-331160 patent also provides a functional material, which is composed of carbides, oxides, nitrides, and oxygen-hydrides of elements such as Ti, Zr, V, Nb, Ta, Cr, Ce, Co, and Mn. one or more components. In the form of fibers or particles, the material has piezoelectricity, electron emission, biological properties and magnetic properties. It can be used in capacitors, piezoelectric bodies, catalysts, multilayer circuit boards, artificial bones, etc. However, this material is difficult to make into textiles, and its use is limited.

本发明的目的在于提供一种能促进、调节和改善人体皮肤浅表层血液微循环,提高皮肤相对血流量的功能纺织物及其制造方法。The purpose of the present invention is to provide a functional textile that can promote, regulate and improve the superficial blood microcirculation of human skin and improve the relative blood flow of the skin and its manufacturing method.

为了达到上述目的,本发明所采用的主要技术方案是在纺织物的组成中,含有一种复杂氧化物陶瓷材料。该陶瓷经粉碎后,每个微粒都具有永电性、压电性和热电性。将这种带有特殊性能的陶瓷粉末与粘胶(Rayon)混合制成粘胶棉,进一步制成功能粘胶纤维;该功能粘胶纤维与棉纱、涤纶纱、尼纶纱、胺纶纱中任一种或两种以上织成纺织物。用这种纺织物再制成人体的内衣、内裤等,供人们使用。In order to achieve the above object, the main technical solution adopted by the present invention is to contain a complex oxide ceramic material in the composition of the textile. After the ceramic is pulverized, each particle has permanent electricity, piezoelectricity and pyroelectricity. Mix this kind of ceramic powder with special properties with viscose (Rayon) to make viscose cotton, and further make functional viscose fiber; the functional viscose fiber is mixed with cotton yarn, polyester yarn, nylon yarn and polyurethane yarn Any one or two or more are woven into textiles. This kind of textile is used to make underwear, underwear, etc. of the human body for people to use.

即本发明所述的功能纺织物由功能粘胶纤维和棉纱、涤纶纱、尼纶纱、受纶纱中任一种或两种以上组成,其具体的组成成分(重量%)如下:That is to say, the functional textile of the present invention is composed of functional viscose fiber and any one or more of cotton yarn, polyester yarn, nylon yarn and spun yarn, and its specific composition (weight %) is as follows:

功能粘胶纤维为40~60%;棉纱、涤纶纱、尼纶纱、胺纶纱中任一种或两种以上之和为60~40%。The functional viscose fiber is 40-60%; the sum of any one or two or more of cotton yarn, polyester yarn, nylon yarn, and polyurethane yarn is 60-40%.

在功能粘胶纤维中,其组成成分(重量%)为:In functional viscose fiber, its composition (weight %) is:

功能陶瓷粉末1~10%,粘胶90~99%;Functional ceramic powder 1-10%, viscose 90-99%;

其中功能陶瓷粉末的粒度<0.5μm。The particle size of the functional ceramic powder is <0.5 μm.

该功能陶瓷粉末的组成成分(重量%)为:The composition (weight %) of this functional ceramic powder is:

SiO235~37%,Al2O329~34%,B2O39~11%,FeO 5~15,MgO 5~8%,Na2O 1.5~3%,TiO20.5~1.5%,CaO 0.5~1.5%,K2O 0.001~0.05%,MnO 0.001~0.05%。SiO 2 35~37%, Al 2 O 3 29~34%, B 2 O 3 9~11%, FeO 5~15, MgO 5~8%, Na 2 O 1.5~3%, TiO 2 0.5~1.5% , CaO 0.5-1.5%, K 2 O 0.001-0.05%, MnO 0.001-0.05%.

由上可知,本发明纺织物原料中的功能陶瓷粉末为复杂的氧化物,具有永电性、热电性和压电性,因而,纺织物也具有同样的性能,它能使水电解,使硫酸铜溶液改变颜色;经卫生检验表明,该纺织物无毒、无味、无污染。As can be seen from the above, the functional ceramic powder in the textile raw material of the present invention is a complex oxide, which has permanent electricity, pyroelectricity and piezoelectricity. Therefore, the textile also has the same performance. It can electrolyze water and make sulfuric acid The copper solution changes color; the sanitary inspection shows that the textile is non-toxic, odorless and non-polluting.

本发明功能纺织物具有促进、改善和调节人体血液循环,提高微血管相对血流量,达到保健和治疗效果。其作用原理如下:The functional textile of the invention can promote, improve and regulate human blood circulation, increase the relative blood flow of microvessels, and achieve health care and treatment effects. Its working principle is as follows:

本发明功能纺织物由于具有永电性、压电性和热电性,当由它所织成的内衣内裤等织物包复在人体皮肤表面时,纺织物的微电极作用于皮肤表面,形成微弱电场,产生微弱电流,对人体皮肤和某些穴位产生刺激,刺激人体表皮下的毛细血管、网目状神经或皮肤的感觉细胞,使之受到电荷的作用。这种作用能够增强皮肤血液的循环,并将这种作用传达到中枢神经,产生反射,进一步使微血管扩张,增加微循环的血流量,同时,本发明所形成的微弱电场作用于人体各部位的穴位,而穴位的一端通过神经与中枢神经相连,通入大脑。即穴位所感受到的微电场,转换为“电信号”,使神经细胞膜内、外电位发生变化,也就是形成神经兴奋或刺激,并传递到大脑,使植物神经介入,达到调节人体机能的作用。Because the functional textile of the present invention has permanent electricity, piezoelectricity and pyroelectricity, when fabrics such as underwear and panties woven from it are wrapped on the surface of human skin, the microelectrodes of the textile act on the surface of the skin to form a weak electric field. , produce a weak current, stimulate the human skin and certain acupoints, stimulate the capillaries, reticular nerves or sensory cells of the skin under the human epidermis, so that they are charged. This effect can enhance the blood circulation of the skin, and transmit this effect to the central nervous system to generate reflections, further dilate the microvessels, and increase the blood flow of the microcirculation. Acupoints, and one end of the acupoints is connected to the central nervous system through nerves and leads to the brain. That is, the micro-electric field felt by the acupuncture points is converted into an "electrical signal", which changes the inner and outer potentials of the nerve cell membrane, that is, the formation of nerve excitement or stimulation, and transmits it to the brain, so that the autonomic nerves intervene to achieve the function of regulating human body functions.

另一方面,皮肤表面形成的微电流在流经皮肤表面时,由于皮肤表面存在着电阻,导致产生焦耳热,使皮肤表面的温度升高,人体感到温暖。当皮肤表面温度升高到一定程度时,由于微血循环充分改善,人体表面蒸发速度加快,使之具有凉爽感觉。On the other hand, when the micro-current formed on the skin surface flows through the skin surface, Joule heat is generated due to the resistance on the skin surface, which increases the temperature of the skin surface and the human body feels warm. When the temperature of the skin surface rises to a certain level, due to the sufficient improvement of the micro-blood circulation, the evaporation speed of the human body surface is accelerated, so that it has a cool feeling.

本发明功能纺织物的制造方法如下:The manufacture method of functional textile of the present invention is as follows:

其制造方法的具体工序为:①功能陶瓷粉末制备;②由功能陶瓷粉末与粘胶制成粘胶棉和功能粘胶纤维;③由功能粘胶纤维和棉纱等制成功能纺织物。现分述如下:The specific steps of the manufacturing method are as follows: (1) preparation of functional ceramic powder; (2) production of viscose cotton and functional viscose fiber from functional ceramic powder and viscose; (3) production of functional textiles from functional viscose fiber and cotton yarn. Now it is described as follows:

〈1〉功能陶瓷粉末制备<1> Preparation of functional ceramic powder

首先按照陶瓷粉末的组成成分范围进行配料,并且进行粗破碎,破碎的粒度为50~70μm,然后进一步精磨,最终要求粒度<0.5μm。Firstly, batching is carried out according to the composition range of the ceramic powder, and the coarse crushing is carried out, and the crushed particle size is 50-70 μm, and then further refined grinding, and the final particle size is required to be <0.5 μm.

〈2〉功能粘胶纤维的制备<2> Preparation of functional viscose fiber

将按成分范围配制的粒度<0.5μm的功能陶瓷微细粉与粘胶根据其比例进行配料混合,并在60~80℃温度下喷制成粘胶棉,并进一步制成功能粘胶纤维。Mix functional ceramic fine powder with a particle size of <0.5 μm and viscose according to the proportions prepared according to the composition range, spray at 60-80°C to make viscose cotton, and further make functional viscose fiber.

〈3〉功能纺织物的制备<3> Preparation of functional textiles

将40~60%的功能粘胶纤维与60~40%的棉纱、涤纶纱、尼纶纱、胺纶纱中的任一种或两种以上,在编织机上织制成纺织物,诸如人体所需的内衣、内裤、袜子、毛巾、围巾等。Weave 40-60% functional viscose fiber and 60-40% cotton yarn, polyester yarn, nylon yarn, or any one or two or more of them on a weaving machine to make textiles, such as those used by the human body. Necessary underwear, panties, socks, towels, scarves, etc.

通过激光多普勒血流量图象测定仪测量,本发明功能纺织物具有升高皮肤相对血流量的显著作用。Measured by a laser Doppler blood flow image measuring instrument, the functional textile of the present invention has a significant effect of increasing the relative blood flow of the skin.

具体地说,本发明具有如下效果:Specifically, the present invention has the following effects:

①促进人体机能组织,特别是皮肤表层的血液循环,产生活血作用,减少因血流不顺而引起的有关病痛;①Promote the blood circulation of the functional tissues of the human body, especially the surface layer of the skin, produce blood circulation, and reduce related diseases caused by unsmooth blood flow;

②可以抑制和调节人体皮肤表层的温度,干燥皮肤,防止因皮肤潮湿而引起的细菌繁殖,达到皮肤具有抗菌、杀菌作用,同时,使人体具有冬暖夏凉的感觉。② It can inhibit and adjust the temperature of the surface layer of the human skin, dry the skin, prevent bacteria from multiplying due to skin moisture, achieve antibacterial and bactericidal effects on the skin, and at the same time make the human body feel warm in winter and cool in summer.

③改善人体新陈代谢,调节人体潜在的机能和活力,具有积极的保健、保健作用。③Improve the metabolism of the human body, regulate the potential function and vitality of the human body, and have positive health care and health effects.

实施例Example

根据本发明所述的功能纺织物的组成成分及制造方法配制了三批功能纺织物,并选取该功能纺织物对人体做了皮肤表层血流量的测试。Three batches of functional textiles were prepared according to the composition and manufacturing method of the functional textiles described in the present invention, and the functional textiles were selected to test the blood flow of the skin surface on the human body.

首先按照本发明所述的功能陶瓷粉末组成成分范围配制了三批功能陶瓷粉末,其具体成分如表1所示。Firstly, three batches of functional ceramic powders were prepared according to the composition range of the functional ceramic powders described in the present invention, the specific components of which are shown in Table 1.

三批功能陶瓷粉末与相应的粘胶相匹配,混合后在一定温度下制成粘胶棉,进一步制成功能粘胶纤维。功能粘胶纤维的组成成分和制备条件如表2所示。Three batches of functional ceramic powder are matched with the corresponding viscose, and after mixing, they are made into viscose cotton at a certain temperature, and further made into functional viscose fiber. The composition and preparation conditions of the functional viscose fiber are shown in Table 2.

将三批制备好的功能粘胶纤维分别与棉纱、涤纶纱、尼纶纱、胺纶纱或其混合物相匹配,织成四批功能纺织物。表3为功能粘胶纤维与棉纱、涤纶纱、尼纶纱、胺纶纱或其混合物相匹配的组成成分。Three batches of prepared functional viscose fibers were matched with cotton yarn, polyester yarn, nylon yarn, polyurethane yarn or their mixtures respectively to weave four batches of functional textiles. Table 3 shows the composition of functional viscose fiber matched with cotton yarn, polyester yarn, nylon yarn, polyurethane yarn or their mixtures.

取批号1功能纺织物对人体皮肤表层做血流量测量,相对血流量以电压(V)表示,测量在激光多普勒血流量图象测定仪上进行,即在某一人体的左前臂裹普通纺织物30分钟,之后在同一位置裹本发明功能纺织物30分钟,在上述两种情况下,在左前臂屈侧的5×5cm处,测量血流量电压,其结果列入表4。Take batch number 1 functional textile to measure the blood flow on the surface of human skin, and the relative blood flow is represented by voltage (V). The measurement is carried out on a laser Doppler blood flow image measuring instrument, that is, a normal Fabric for 30 minutes, then wrap the functional fabric of the present invention at the same position for 30 minutes. In the above two cases, measure the blood flow voltage at the 5×5 cm of the flexor side of the left forearm. The results are listed in Table 4.

另外,采用批号2本发明功能纺织物,利用激光多普勒血流量图象测定仪,对30例18~30岁健康者(其中女性12例,男性18例,平均年龄22.7岁)进行皮肤浅表组织血流量测定。在他们的左前臂分别裹普通纺织物和裹本发明功能纺织物各30分钟,然后分别测定该区皮肤5×5cm范围内浅表组织相对血流量,测量结果为:In addition, using the functional textiles of the present invention with batch No. 2, using a laser Doppler blood flow image measuring instrument, 30 cases of healthy people aged 18 to 30 (including 12 females and 18 males, with an average age of 22.7 years) were subjected to skin lightening. Table tissue blood flow measurement. Wrap the common fabric and the functional fabric of the present invention on their left forearm respectively for 30 minutes, then measure the relative blood flow of the superficial tissue in the area skin 5 * 5cm, and the measurement results are:

①裹普通纺织物与不裹任何纺织物相比,血流量上升的平均值为0.01367,标准误差为0.00689,经显著性检验,t值为1.9872.P>0.05,说明无显著性差异。①Compared with non-wrapped fabrics, the mean increase in blood flow was 0.01367, and the standard error was 0.00689. After the significance test, the t value was 1.9872. P>0.05, indicating that there was no significant difference.

②裹本发明功能纺织物与不裹任何纺织物相比,血流量上升的平均值为0.02233,标准误差为0.01025,经显著性检验,t值为2.176732,P>0.05,有显著性差异。②Wrapping the functional textile of the present invention compared with not wrapping any textile, the average value of blood flow increase is 0.02233, the standard error is 0.01025, after the significance test, the t value is 2.176732, P>0.05, there is a significant difference.

测试结果表明:本发明功能纺织物具有升高皮肤相对血流量的作用。The test results show that: the functional textile of the present invention has the effect of increasing the relative blood flow of the skin.

表1 实施例功能陶瓷粉末组成成分(重量%)Table 1 Example functional ceramic powder components (weight %) 序号 serial number SiO SiO AlO AlO B O B O FeO FeO MgO MgO NaO NaO TiO TiO CaO CaO K O K O MnO MnO 1 1 36 36 29 29 11 11 11 11 8 8 2.1 2.1 1.4 1.4 1.2 1.2 0.03 0.03 0.009 0.009 2 2 36.5 36.5 31 31 8.9 8.9 6.5 6.5 7 7 1.6 1.6 1.0 1.0 1.4 1.4 0.05 0.05 0.02 0.02 3 3 37 37 33 33 10 10 14 14 6 6 2.8 2.8 0.7 0.7 0.6 0.6 0.003 0.003 0.04 0.04

表2 实施例功能粘胶纤维组成成分(重量%)及制备条件Table 2 Example functional viscose fiber composition (weight %) and preparation conditions 批号 batch number 组成成分(重量%) Composition (weight%) 制备条件 Preparation conditions 陶瓷粉末 ceramic powder 粘胶 Viscose 陶瓷粉末粒度μm Ceramic powder particle size μm 喷制温度℃ Spray temperature ℃ 批号配比 Batch ratio 配比 Proportion 1 1 1  3 1 3 97 97 0.45 0.45 72 72 2 2 2  1 twenty one 99 99 0.26 0.26 61 61 3 3 3  6 3 6 94 94 0.38 0.38 80 80

表3 实施例功能纺织物中粘胶纤维与棉纱等成分(重量%)配比Table 3 Proportion of viscose fiber and cotton yarn and other components (weight %) in the functional textiles of the examples 批号 batch number 粘胶纤维 Viscose fiber 棉纱 cotton yarn 尼纶纱 nylon yarn 涤纶纱 polyester yarn 胺纶纱 Spandex yarn 批号 batch number 配比 Proportion 1 1 1 1 45 45 30 30 25 25 2 2 2 2 60 60 40 40 3 3 3 3 50 50 10 10 20 20 20 20 4 4 4 4 42 42 25 25 3 3 15 15 15 15

表4、本发明功能纺织物与普通纺织物对人体皮肤表层血流量的影响Table 4, the influence of functional textiles of the present invention and ordinary textiles on the blood flow of human skin surface layer 裹缠物 Wrap 测量条件 Measurement conditions 皮肤表层电压(V) Skin surface voltage (V) 位置 Location 面积cm2 Area cm 2 时间分钟 time minute 最小 the smallest 最大 maximum 平均 average 普通纺织物 Ordinary Textiles 左前臂 left forearm 5×5 5×5 30 30 0.15 0.15 1.72 1.72 0.32 0.32 本发明功能纺织物 Functional textiles of the present invention 左前臂 left forearm 5×5 5×5 30 30 0.16 0.16 3.29 3.29 0.51 0.51

Claims (2)

1、一种功能纺织物,其特征在于:1. A functional textile, characterized in that: A、功能纺织物的组成成分(重量%)为:A, the composition (weight %) of functional textile is: 功能粘胶纤维为40~60%;Functional viscose fiber is 40-60%; 棉纱、绦纶纱、尼纶纱、胺纶纱中任一种或两种以上之和为60~40%;The sum of any one or two or more of cotton yarn, polyester yarn, nylon yarn, and polyurethane yarn is 60-40%; B、功能粘胶纤维的组成成分(重量%)为:B, the composition (weight %) of functional viscose fiber is: 功能陶瓷粉末  1~10%;Functional ceramic powder 1~10%; 粘胶          90~99%;Viscose 90~99%; C、功能陶瓷粉末的组成成分(重量%)为:C, the composition (weight %) of functional ceramic powder is: SiO235~37%,Al2O329~34%,B2O39~11%,FeO 5~15%,MgO 5~8%,Na2O 1.5~3%,TiO20.5~1.5%,CaO 0.5~1.5%,K2O 0.001~0.05%,MnO 0.001~0.05%。SiO 2 35-37%, Al 2 O 3 29-34%, B 2 O 3 9-11%, FeO 5-15%, MgO 5-8%, Na 2 O 1.5-3%, TiO 2 0.5-1.5 %, CaO 0.5-1.5%, K 2 O 0.001-0.05%, MnO 0.001-0.05%. 2、一种权利要求1所述的功能纺织物的制造方法,其特征在于:2. A method for manufacturing functional textiles according to claim 1, characterized in that: A、功能陶瓷粉末制备,原料按成分范围配备后进行破碎和精磨,要求最终粒度<0.5μm;A. Preparation of functional ceramic powder, the raw materials are prepared according to the composition range and then crushed and finely ground. The final particle size is required to be less than 0.5 μm; B、功能陶瓷粉末与粘胶按成分范围配备后,在60~80℃温度下喷制成粘胶棉,并进一步制成功能粘胶纤维;B. After the functional ceramic powder and viscose are prepared according to the composition range, they are sprayed at a temperature of 60-80°C to make viscose cotton, and further made into functional viscose fiber; C、依据成分范围,将功能粘胶纤维与棉纱、绦纶纱、尼纶纱、胺纶纱中任一种或两种以上,在纺织机上织制成功能纺织物。C. According to the composition range, functional viscose fiber and any one or more of cotton yarn, polyester yarn, nylon yarn, and polyurethane yarn are woven on a textile machine to make functional textiles.
CN 94102823 1994-03-23 1994-03-23 Functional fabric and weaving method thereof Expired - Lifetime CN1030536C (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2756742A1 (en) * 1996-12-10 1998-06-12 Wonder & Bioenergy Hi Tech Int Non-woven fabric containing a powder of mixed inorganic oxides
CN102152518A (en) * 2010-12-06 2011-08-17 吴江飞翔经编纺织有限公司 Sun-screening composite fabric
CN102926095A (en) * 2012-11-22 2013-02-13 吴江市虹凯纺织有限公司 Ultraviolet-proof leisure fabric

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2756742A1 (en) * 1996-12-10 1998-06-12 Wonder & Bioenergy Hi Tech Int Non-woven fabric containing a powder of mixed inorganic oxides
CN102152518A (en) * 2010-12-06 2011-08-17 吴江飞翔经编纺织有限公司 Sun-screening composite fabric
CN102926095A (en) * 2012-11-22 2013-02-13 吴江市虹凯纺织有限公司 Ultraviolet-proof leisure fabric

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