Summary of the invention
Goal of the invention: it is an object of the present invention to provide a kind of ship tail gas processing unit and its birotor supergravity reactor,
Solve the problems, such as that conventional reactor or single rotor reactor are halfway to tail gas detoxication.
Technical solution: a kind of birotor supergravity reactor of the present invention, including motor, the first reaction chamber and the second reaction
Room, rotor is provided in first reaction chamber and the second reaction chamber, and the motor shaft of the motor passes through hollow shaft band turn
Son rotation, the part that the hollow shaft is contacted with rotor is provided with through-hole;The outside of first reaction chamber and the second reaction chamber
It is provided with the first cavity and the second cavity, the part that the hollow shaft is located in the first cavity and the second cavity is provided with through-hole.
Further, the hollow shaft is welded by the equal stainless steel jointless hollow steel pipe of two cross-sectional areas, institute
State one end that the pad between stainless steel jointless hollow steel pipe is located at interior and close second reaction chamber of the first cavity;It is described stainless
Steel is seamless, and hollow steel pipe both ends are provided with the polytetrafluoroethylene (PTFE) end socket for sealing, form two independent space difference in this way
For loading NaOH solution and H2O2Solution.
Further, it is connected between first reaction chamber and the second reaction chamber by U-tube, for being connected to tail gas into one
Step processing.
Further, flange-face coupling is provided between the hollow shaft and motor shaft;The hollow shaft is reacted with first
Room and the second reaction chamber contact position are provided with V-seal device;The hollow shaft is connect by fixing element with rotor.
Further, the V-seal device includes L-type support, and the L-type support is set close to one side two sides of hollow shaft
It is equipped with V-shaped seal ring and O-ring, and V-shaped seal ring is in contact with hollow shaft;First reaction chamber and the second reaction chamber with it is right
The one side of the L-type support answered far from hollow shaft is fixedly connected by fastening screw;The L-type support is close to one side of hollow shaft
Inside is provided with rolling bearing.
A kind of ship tail gas processing unit being provided with the birotor supergravity reactor as described in any of the above-described, including text
Washer and hydrocyclone in mound, the exhaust outlet and leakage fluid dram of the Venturi scrubber bottom respectively with birotor hypergravity
First reaction chamber of reactor is connected with hydrocyclone liquid-inlet, the air inlet at the top of Venturi scrubber by blower with
Exhaust gas inlet connection;Second reaction chamber of the birotor supergravity reactor is connect by demister with waste gas outlet.
Further, the leakage fluid dram of the hydrocyclone is connected by the inlet of water pump and Venturi scrubber, water
The sand sinking port of power cyclone is connect with waste residue slot;The water pump is also connect with sink;In Venturi scrubber, fresh water pair is utilized
Tail gas is washed, and the waste liquid after washing is pumped to Venturi scrubber reuse by water after hydrocyclone separates particle.
Further, the first reaction chamber of the birotor supergravity reactor and the bottom of the second reaction chamber are provided with
Solution recycles holding vessel, and the first cavity and the second cavity of birotor supergravity reactor pass through anticorrosion diaphragm pump and solution
Tank connection;NaOH solution and H2O2Solution is pumped to the first cavity of birotor supergravity reactor by anticorrosion diaphragm pump respectively
It is flowed out in the second cavity, then from the through-hole of rotor-position.
Further, the exhaust gas inlet is connect by blower with waste gas outlet;The blower and Venturi scrubber top
Valve is provided between demister and waste gas outlet between the air inlet in portion, between blower and waste gas outlet;By switch valve,
Ship tail gas processing unit can be overhauled.
The utility model has the advantages that the present invention is based on birotor supergravity reactor, by the tail after solid particle washs
Gas obtains higher rotation speed in birotor supergravity reactor, and higher rotation speed can generate biggish shearing force,
Thus by NaOH solution and H2O2Solution is decomposed into more tiny drop, expands the effective contact area of gas-liquid;Further, since
Tail gas and NaOH solution and H2O2Collision between solution increases, and higher rotation speed also results in liquid phase renewal speed and adds
Fastly, so that SO in tail gas2With NaOH solution, NOXWith H2O2The reaction of solution is more abundant, improves vent gas treatment effect
Rate can save money for the pollutant catabolic gene of ship;The tail gas of final purification is discharged into atmosphere, and generates raw material of industry sodium sulphate
With nitric acid, " waste utilization " is realized, there is excellent economy and environmental benefit.
Specific embodiment
The present invention is described further with reference to the accompanying drawings and examples:
As shown in Figure 1, the birotor supergravity reactor in ship tail gas processing unit of the present invention, including motor 1, first
It is provided with rotor 4 in reaction chamber 2 and the second reaction chamber 3, the first reaction chamber 2 and the second reaction chamber 3, loads filler in rotor 4,
The motor shaft 11 of motor 1 by hollow shaft 5 drive rotor 4 rotate, i.e., drive rotor 4 filler rotation, by rotation generate from
Heart acceleration is up to 20-500 times of acceleration of gravity, and 1-2 quantity can be improved in mass transfer rate under the action of this centrifugal force field
Grade;Higher rotation speed can generate biggish shearing force, to breaing up liquid for more tiny drop, expanding gas-liquid has
Imitate contact area.Tail gas and NaOH solution or H simultaneously2O2Collision between solution increases, and higher rotation speed also results in gas
Liquid phase renewal speed is accelerated, so that the SO in tail gas2With NaOH solution, NOXWith H2O2The reaction of solution is more abundant, by
This improves vent gas treatment efficiency.
The part that hollow shaft 5 is contacted with rotor 4 is provided with through-hole 51;The outside of first reaction chamber 2 and the second reaction chamber 3 is set
It is equipped with the first cavity 6 and the second cavity 7, the part that hollow shaft 5 is located in the first cavity 6 and the second cavity 7 is also equipped with through-hole
51;Its hollow mandrel 5 is welded by the equal stainless steel jointless hollow steel pipe 52 of two cross-sectional areas, and stainless steel jointless is hollow
Pad between steel pipe 52 is located in the first cavity 6 and close to one end of the second reaction chamber 3;Stainless steel jointless hollow steel pipe 52
Both ends are provided with the polytetrafluoroethylene (PTFE) end socket 53 for sealing, therefore are capable of forming two independent spaces and are respectively used to load
NaOH solution and H2O2Solution;NaOH solution enters in the first cavity 6, enters hollow shaft 5 by the through-hole 51 in the first cavity 6
In, then pass through the outflow of through-hole 51 for the part that hollow shaft 5 is contacted with rotor 4, into rotor filler, make itself and the SO in tail gas2
It sufficiently reacts, similarly H2O2Solution enters in the second cavity 7, is entered in hollow shaft 5 by the through-hole 51 in the second cavity 7, then lead to
The through-hole 51 for crossing the part that hollow shaft 5 is contacted with rotor 4 flows out, and into rotor filler, keeps it sufficiently anti-with the NOx in tail gas
It answers.
As shown in Fig. 2, the tail gas after desulfurization enters in the second reaction chamber 3 by U-tube 8 in the first reaction chamber 2, after
It is continuous that tail gas is further processed.
As shown in figure 3, being provided with flange-face coupling 9 between hollow shaft 5 and motor shaft 11, flange-face coupling 9 passes through locking
Hollow shaft 5 is connect by screw 91 with motor shaft 11, and there are also washers 92 for preventing sky for the junction of hollow shaft 5 and motor shaft 11
Mandrel 5 and motor shaft 11 collide.
As shown in figure 5, since hollow shaft 5 passes through the first reaction chamber 2 and the second reaction chamber 3, in hollow shaft 5 and first
V-seal device 10 is provided at the 5 of reaction chamber 2 and the contact of the second reaction chamber 3, and V-seal device 10 includes L-type support
105, the both sides of L-type support 105 are in close contact with the wall of corresponding first reaction chamber 2 and the second reaction chamber 3, while L-type
Bracket 105 is provided with V-shaped seal ring 101 and O-ring 104 close to one side two sides of hollow shaft 5, and V-shaped seal ring 101 with it is hollow
Axis 5 is in contact, and V-shaped seal ring 101 and O-ring 104 are all built-in between reaction chamber and hollow shaft 5, L-type support 105, V-type
Sealing ring 101 and O-ring 104 increase sealing effect, further prevent NaOH solution or H2O2Solution flows out from hollow shaft 5;
First reaction chamber 2 and the second reaction chamber 3 pass through fastening screw 103 with the corresponding one side of L-type support 105 far from hollow shaft 5
It is fixedly connected;L-type support 105 is provided with rolling bearing 102 on the inside of one side of hollow shaft 5.
As shown in figure 4, then connecting by fixing element 12 between hollow shaft 5 and rotor 4, specifically pass through fixing element 12
On fastening bolt 121 hollow shaft 5 is fixedly connected with rotor 4.
As shown in fig. 6, ship tail gas processing unit of the invention has birotor supergravity reactor, it further include venturi
Washer 13 and hydrocyclone 14, the exhaust outlet and leakage fluid dram of 13 bottom of Venturi scrubber are anti-with birotor hypergravity respectively
The first reaction chamber 2 of device is answered to connect with 14 liquid-inlet of hydrocyclone, the air inlet at 13 top of Venturi scrubber passes through wind
Machine 15 is connect with exhaust gas inlet 16;Second reaction chamber 3 of birotor supergravity reactor passes through demister 17 and waste gas outlet 18
Connection;
The leakage fluid dram of hydrocyclone 14 is connect by water pump 19 with the inlet of Venturi scrubber 13, hydrocyclone
14 sand sinking port is connect with waste residue slot 20;In Venturi scrubber 13, tail gas is washed using fresh water, it is useless after washing
Liquid is sent to 13 reuse of Venturi scrubber after hydrocyclone 14 separates particle by water pump 19, and water pump 19 also with sink 25
Connection.
First reaction chamber 2 of birotor supergravity reactor and the bottom of the second reaction chamber 3 are provided with solution recycling storage
Tank 21 is deposited, wherein the solution recycling holding vessel 21 that the bottom of the first reaction chamber 2 is arranged is Na2SO4Solution recycling holding vessel, second
The solution recycling holding vessel 21 of the bottom setting of reaction chamber 3 is HNO3Solution recycles holding vessel;Birotor supergravity reactor
First cavity 6 and the second cavity 7 are connect by anticorrosion diaphragm pump 22 with NaOH solution tank NaOH 23, wherein connect with the first cavity 6
NaOH solution tank NaOH 23 is NaOH solution tank, and the NaOH solution tank NaOH 23 connecting with the second cavity 7 is H2O2NaOH solution tank NaOH, thus NaOH solution and
H2O2Solution is pumped in the first cavity 6 and the second cavity 7 of birotor supergravity reactor by anticorrosion diaphragm pump 22 respectively,
It is flowed out again from the through-hole 51 of 4 position of rotor.
Exhaust gas inlet 16 is connect by blower 15 with waste gas outlet 18;The air inlet at 13 top of blower 15 and Venturi scrubber
It is provided with valve 24 between demister 17 and waste gas outlet 18 between mouthful, between blower 15 and waste gas outlet 18, passes through switch
Valve 24 can overhaul ship tail gas processing unit.
Working principle: it is first turned between blower 15 and the air inlet at the top of Venturi scrubber 13, demister 17 and useless
Valve 24 between gas outlet 18, closes the valve 24 between blower 15 and waste gas outlet 18;Then tail gas by exhaust gas inlet 16 into
Enter the ship tail gas processing unit, first pass through blower 15 and pressurize to it, then passes through the air inlet at 13 top of Venturi scrubber
Mouth enters in Venturi scrubber 13, since the temperature of tail gas is 250-350 DEG C, SO2Concentration is 600ppm, and NOx concentration is
1500ppm, particle concentration 120mg/Nm3, O2Concentration is 13%, thus by water pump 19 by the water in sink 25 from Wen Qiu
In the inlet introducing of washer 13 washed and cooled down, in order to avoid particle in tail gas blocks rotor filler, tail gas after washing
Particle concentration is down to 20mg/Nm3Hereinafter, temperature is down to 50 DEG C or so, while absorbable part SO2;It is super that tail gas enters birotor
First reaction chamber 2 of gravity reactor;And the leakage fluid dram of 13 bottom of Venturi scrubber is by the waste water of washing and granular material discharged
Into hydrocyclone 14, hydrocyclone 14 drains into particulate matter in waste residue slot 20 by its sand sinking port, and waste liquid passes through water
Pump 19 is sent to 13 reuse of Venturi scrubber.
In the first reaction chamber 2, since the NaOH solution tank NaOH 23 of the first cavity 6 connection is NaOH solution tank, NaOH solution
It is pumped in the first cavity 6 of birotor supergravity reactor by anticorrosion diaphragm pump 22, then is flowed from the through-hole 51 of 4 position of rotor
Out, the SO in tail gas2It is reacted with NaOH solution and generates Na2SO4, SO2Content reaches the emission limit of IMO;Tail gas warp after desulfurization
It crosses U-tube 8 to enter in the second reaction chamber 3, since the NaOH solution tank NaOH 23 of the second cavity 7 connection is H2O2NaOH solution tank NaOH, therefore H2O2Solution
It is pumped in the second cavity 7 of birotor supergravity reactor by anticorrosion diaphragm pump 22, then is flowed from the through-hole 51 of 4 position of rotor
Out, the NOx and H in tail gas2O2Solution carries out reaction and generates HNO3, NOx content meet as defined in emission limit requirement, most pass through afterwards
Atmosphere is discharged by waste gas outlet 18 after 17 demisting of demister.
Reaction equation in birotor supergravity reactor is as follows,
(1)SO2With the reaction equation of NaOH:
SO2+1/2O2+2NaOH→Na2SO4+H2O
(2)SO2With water reaction equation:
SO2+H2O=H2SO3
1/2H2SO3+O2=H2SO 4(a small amount of)
(3)NOXWith H2O2Reaction equation:
2NO2+H2O2→2HNO3
2NO+3H2O2→2HNO 3+2H2O
Wherein NOXWith H2O2Reaction it is more complicated, be divided into: NO2With H2O2Reaction and NO and H2O2Reaction, NO2With
H2O2Directly reaction generates HNO3, and NO both can be with H2O2Directly reaction generates HNO3Nitrous acid HNO can be generated again2, nitrous
Sour HNO2Generation nitric acid can be oxidized.
For the Na generated in the first reaction chamber 22SO4Solution, the Na being arranged by the bottom of the first reaction chamber 22SO4
Solution recycling holding vessel is recycled;The HNO generated in second reaction chamber 33Solution is arranged by the bottom of the second reaction chamber 3
HNO3Solution recycling holding vessel is recycled, and collection gained sodium sulphate can be used as the raw material of industry with nitric acid and be utilized.When
When needing to safeguard the present apparatus, close between blower 15 and the air inlet at the top of Venturi scrubber 13, demister 17 with
Valve 24 between waste gas outlet 18 is opened the valve 24 between blower 15 and waste gas outlet 18, can be carried out to exhaust gas processing device
Maintenance.