CN109206921A - 一种抗氧化树脂塑料 - Google Patents
一种抗氧化树脂塑料 Download PDFInfo
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- CN109206921A CN109206921A CN201710536151.2A CN201710536151A CN109206921A CN 109206921 A CN109206921 A CN 109206921A CN 201710536151 A CN201710536151 A CN 201710536151A CN 109206921 A CN109206921 A CN 109206921A
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- 239000004033 plastic Substances 0.000 title claims abstract description 27
- 229920003023 plastic Polymers 0.000 title claims abstract description 27
- 239000011347 resin Substances 0.000 title claims abstract description 19
- 229920005989 resin Polymers 0.000 title claims abstract description 19
- 230000003064 anti-oxidating effect Effects 0.000 title claims abstract description 13
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 8
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 8
- 239000000945 filler Substances 0.000 claims abstract description 3
- 239000003999 initiator Substances 0.000 claims abstract description 3
- 239000004611 light stabiliser Substances 0.000 claims abstract description 3
- 239000000314 lubricant Substances 0.000 claims abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 2
- 239000004342 Benzoyl peroxide Substances 0.000 claims 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical group C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims 1
- 125000002252 acyl group Chemical group 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 235000019400 benzoyl peroxide Nutrition 0.000 claims 1
- 235000013312 flour Nutrition 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 239000004408 titanium dioxide Substances 0.000 claims 1
- FEXBEKLLSUWSIM-UHFFFAOYSA-N 2-Butyl-4-methylphenol Chemical compound CCCCC1=CC(C)=CC=C1O FEXBEKLLSUWSIM-UHFFFAOYSA-N 0.000 abstract description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 abstract description 2
- 108010010803 Gelatin Proteins 0.000 abstract description 2
- 238000005299 abrasion Methods 0.000 abstract description 2
- 239000002253 acid Substances 0.000 abstract description 2
- -1 alcohol ester Chemical class 0.000 abstract description 2
- 230000003712 anti-aging effect Effects 0.000 abstract description 2
- 239000006229 carbon black Substances 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 239000008273 gelatin Substances 0.000 abstract description 2
- 229920000159 gelatin Polymers 0.000 abstract description 2
- 235000019322 gelatine Nutrition 0.000 abstract description 2
- 235000011852 gelatine desserts Nutrition 0.000 abstract description 2
- FIBARIGPBPUBHC-UHFFFAOYSA-N octyl 8-(3-octyloxiran-2-yl)octanoate Chemical compound CCCCCCCCOC(=O)CCCCCCCC1OC1CCCCCCCC FIBARIGPBPUBHC-UHFFFAOYSA-N 0.000 abstract 1
- 235000006708 antioxidants Nutrition 0.000 description 5
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
本发明涉及一种抗氧化树脂塑料，由以下重量份数的组分组成：对苯二甲酸丁二醇酯，100份；环氧硬脂酸辛酯，100份；光稳定剂，8‑15份；填充剂，8‑15份；润滑剂，10‑20份；引发剂，5‑10份；明胶，5‑15份；防老剂ODA，8‑10份；高耐磨碳黑，5‑10份；抗氧剂，6‑10份。本发明塑料加入了2，6‑三级丁基‑4‑甲基苯酚作为抗氧剂，提高了塑料的抗氧化性。
Description
技术领域
本发明涉及一种塑料，具体涉及一种抗氧化树脂塑料。
背景技术
树脂塑料是用树脂塑料通过挤出机高温挤出，经过相应的模具口挤出得到不同厚度的板材，是一种高熔点、高结晶性的热塑性工程塑料，因树脂塑料板所具有的良好特性，非常适合在自动车床上机加工，特别适合用来制造精密零件。
然而由于树脂塑料本身存在耐热、耐老化、耐大气老化性较差，使得用其制得的树脂塑料板的使用寿命非常短，从而降低了其使用范围。
有鉴于上述的缺陷，本设计人，积极加以研究创新，以期创设一种新型结构的树脂塑料，使其更具有产业上的利用价值。
发明内容
为解决上述技术问题，本发明的目的是提供一种抗氧化树脂塑料。
本发明的技术方案如下：
一种抗氧化树脂塑料，其特征在于，由以下重量份数的组分组成：
借由上述方案，本发明至少具有以下优点：
本发明塑料加入了2，6-三级丁基-4-甲基苯酚作为抗氧剂，提高了塑料的抗氧化性。
上述说明仅是本发明技术方案的概述，为了能够更清楚了解本发明的技术手段，并可依照说明书的内容予以实施，以下以本发明的较佳实施例。
具体实施方式
下面结合实施例，对本发明的具体实施方式作进一步详细描述。以下实施例用于说明本发明，但不用来限制本发明的范围。
一种抗氧化树脂塑料的制备方法，包括以下原料对苯二甲酸丁二醇酯、环氧硬脂酸辛酯、光稳定剂、填充剂、润滑剂、引发剂、明胶、防老剂ODA、高耐磨碳黑、抗氧剂。将上述原料混合后，加入到挤塑机中，在120℃下混合均匀，再采用螺杆机挤出，得到树脂塑料。
制备的具体组分如下。
实施例1
实施例2
实施例3
本发明塑料加入了2，6-三级丁基-4-甲基苯酚作为抗氧剂，提高了塑料的抗氧化性。
以上所述仅是本发明的优选实施方式，并不用于限制本发明，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明技术原理的前提下，还可以做出若干改进和变型，这些改进和变型也应视为本发明的保护范围。
Claims (6)
1.一种抗氧化树脂塑料，其特征在于，由以下重量份数的组分组成：
2.根据权利要求1所述的一种抗氧化树脂塑料，其特征在于：所述光稳定剂为钛白粉。
3.根据权利要求1所述的一种抗氧化树脂塑料，其特征在于：所述填充剂为石英粉。
4.根据权利要求1所述的一种抗氧化树脂塑料，其特征在于：所述润滑剂为氧化聚乙烯。
5.根据权利要求1所述的一种抗氧化树脂塑料，其特征在于：所述引发剂为过氧化苯甲酰。
6.根据权利要求1所述的一种抗氧化树脂塑料，其特征在于：所述抗氧剂为2，6-三级丁基-4-甲基苯酚。
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710536151.2A CN109206921A (zh) | 2017-07-04 | 2017-07-04 | 一种抗氧化树脂塑料 |
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| CN201710536151.2A CN109206921A (zh) | 2017-07-04 | 2017-07-04 | 一种抗氧化树脂塑料 |
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| CN109206921A true CN109206921A (zh) | 2019-01-15 |
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Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080090961A1 (en) * | 2006-10-13 | 2008-04-17 | Bayer Materialscience Llc | Impact resistant, flame retardant thermoplastic molding composition |
| US20090143513A1 (en) * | 2007-11-30 | 2009-06-04 | Bayer Materialscience Llc | Impact resistant, flame retardant thermoplastic molding composition |
| CN102181133A (zh) * | 2011-01-27 | 2011-09-14 | 上海锦湖日丽塑料有限公司 | 金属纤维增强pbt树脂及其制备方法 |
| CN102464868A (zh) * | 2010-11-05 | 2012-05-23 | 合肥杰事杰新材料股份有限公司 | 一种耐刮擦聚对苯二甲酸丁二醇酯组合物及其制备方法 |
| CN102464870A (zh) * | 2010-11-15 | 2012-05-23 | 上海锦湖日丽塑料有限公司 | 一种微晶pbt树脂及其制备方法 |
| CN103384658A (zh) * | 2011-02-22 | 2013-11-06 | 沙伯基础创新塑料知识产权有限公司 | 抗冲改性的聚(对苯二甲酸丁二醇酯)组合物及其制备方法和制品 |
| CN103391915A (zh) * | 2011-02-22 | 2013-11-13 | 沙伯基础创新塑料知识产权有限公司 | 阻燃聚(对苯二甲酸丁二醇酯)组合物、其制备方法、及其制品 |
| CN103709659A (zh) * | 2012-09-30 | 2014-04-09 | 青岛欣展塑胶有限公司 | 玻纤增强pbt/pet合金材料 |
| CN103849124A (zh) * | 2012-11-30 | 2014-06-11 | 杜邦公司 | 增韧的含聚酯热塑性组合物 |
| CN104845198A (zh) * | 2014-12-15 | 2015-08-19 | 王妮娜 | 一种阻燃性聚对苯二甲酸丁二醇酯复合材料及其制备方法 |
-
2017
- 2017-07-04 CN CN201710536151.2A patent/CN109206921A/zh active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080090961A1 (en) * | 2006-10-13 | 2008-04-17 | Bayer Materialscience Llc | Impact resistant, flame retardant thermoplastic molding composition |
| US20090143513A1 (en) * | 2007-11-30 | 2009-06-04 | Bayer Materialscience Llc | Impact resistant, flame retardant thermoplastic molding composition |
| CN102464868A (zh) * | 2010-11-05 | 2012-05-23 | 合肥杰事杰新材料股份有限公司 | 一种耐刮擦聚对苯二甲酸丁二醇酯组合物及其制备方法 |
| CN102464870A (zh) * | 2010-11-15 | 2012-05-23 | 上海锦湖日丽塑料有限公司 | 一种微晶pbt树脂及其制备方法 |
| CN102181133A (zh) * | 2011-01-27 | 2011-09-14 | 上海锦湖日丽塑料有限公司 | 金属纤维增强pbt树脂及其制备方法 |
| CN103384658A (zh) * | 2011-02-22 | 2013-11-06 | 沙伯基础创新塑料知识产权有限公司 | 抗冲改性的聚(对苯二甲酸丁二醇酯)组合物及其制备方法和制品 |
| CN103391915A (zh) * | 2011-02-22 | 2013-11-13 | 沙伯基础创新塑料知识产权有限公司 | 阻燃聚(对苯二甲酸丁二醇酯)组合物、其制备方法、及其制品 |
| CN103709659A (zh) * | 2012-09-30 | 2014-04-09 | 青岛欣展塑胶有限公司 | 玻纤增强pbt/pet合金材料 |
| CN103849124A (zh) * | 2012-11-30 | 2014-06-11 | 杜邦公司 | 增韧的含聚酯热塑性组合物 |
| CN104845198A (zh) * | 2014-12-15 | 2015-08-19 | 王妮娜 | 一种阻燃性聚对苯二甲酸丁二醇酯复合材料及其制备方法 |
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