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CN1090060C - Circular disc shape honeycomb, esp. catalyst carrier - Google Patents

Circular disc shape honeycomb, esp. catalyst carrier Download PDF

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Publication number
CN1090060C
CN1090060C CN95195280A CN95195280A CN1090060C CN 1090060 C CN1090060 C CN 1090060C CN 95195280 A CN95195280 A CN 95195280A CN 95195280 A CN95195280 A CN 95195280A CN 1090060 C CN1090060 C CN 1090060C
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China
Prior art keywords
honeycomb ceramics
press
macrostructure
disk
microstructure
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Expired - Fee Related
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CN95195280A
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Chinese (zh)
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CN1158576A (en
Inventor
沃尔夫冈·毛斯
罗尔夫·布鲁克
翰斯·博德
尤多·马丁
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Vitesco Technologies Lohmar Verwaltungs GmbH
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Emitec Gesellschaft fuer Emissionstechnologie mbH
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Priority to CN95195280A priority Critical patent/CN1090060C/en
Publication of CN1158576A publication Critical patent/CN1158576A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2803Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
    • F01N3/2807Metal other than sintered metal
    • F01N3/281Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates
    • F01N3/2821Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates the support being provided with means to enhance the mixing process inside the converter, e.g. sheets, plates or foils with protrusions or projections to create turbulence
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/28Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer comprising a deformed thin sheet, i.e. the layer having its entire thickness deformed out of the plane, e.g. corrugated, crumpled
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion
    • F01N3/2006Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating
    • F01N3/2013Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating using electric or magnetic heating means
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion
    • F01N3/2006Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating
    • F01N3/2013Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating using electric or magnetic heating means
    • F01N3/2026Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating using electric or magnetic heating means directly electrifying the catalyst substrate, i.e. heating the electrically conductive catalyst substrate by joule effect
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2803Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2803Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
    • F01N3/2807Metal other than sintered metal
    • F01N3/281Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2892Exhaust flow directors or the like, e.g. upstream of catalytic device
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2330/00Structure of catalyst support or particle filter
    • F01N2330/30Honeycomb supports characterised by their structural details
    • F01N2330/32Honeycomb supports characterised by their structural details characterised by the shape, form or number of corrugations of plates, sheets or foils
    • F01N2330/323Corrugations of saw-tooth or triangular form
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2330/00Structure of catalyst support or particle filter
    • F01N2330/30Honeycomb supports characterised by their structural details
    • F01N2330/38Honeycomb supports characterised by their structural details flow channels with means to enhance flow mixing,(e.g. protrusions or projections)
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
    • F01N2330/00Structure of catalyst support or particle filter
    • F01N2330/30Honeycomb supports characterised by their structural details
    • F01N2330/44Honeycomb supports characterised by their structural details made of stacks of sheets, plates or foils that are folded in S-form
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/12Improving ICE efficiencies

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Exhaust Gas After Treatment (AREA)

Abstract

The invention concerns a honeycomb element, in particular a catalyst support (3) for the catalytic conversion of exhaust gases in an exhaust system, in particular for an exhaust system in an internal combustion engine, preferably a spark ignition engine. The element in question has a plurality of channels (4) each of which discharges at one end into a central channel (5). The channels (4) curve outwards from the central channel (5) and are bounded by disks (15) which lie contiguously. At least some of the disks (15) have a macrostructure which forms the lateral boundary of the channels (4). A microstructure (19) provided additionally in some or all of the disks (15) can enhance the efficiency of a catalytic conversion process.

Description

圆盘形蜂窝体特别是催化剂载体Disc-shaped honeycomb bodies, especially catalyst supports

本发明涉及蜂窝体特别是催化剂载体,用以在排气系统内,特别是在内燃机、最好是四冲程内燃机的排气系统内催化转化废气,蜂窝体具有若干通道,各通道以其一端通向一中心通道。这种带有催化涂层的蜂窝体也称作径向催化转化器。这种装置可见之于德国工程师协会新闻期刊1993年9月24日第38期第11页的“催化转化器走向高技术”。The invention relates to a honeycomb body, in particular a catalyst carrier, for the catalytic conversion of exhaust gas in an exhaust system, in particular of an internal combustion engine, preferably a four-stroke internal combustion engine, the honeycomb body having a plurality of channels, each channel being connected at one end to a central channel. Such catalytically coated honeycomb bodies are also referred to as radial catalytic converters. Such a device can be seen in "Catalytic Converters Going High-Tech", Newsletter of the German Association of Engineers, Issue 38, September 24, 1993, page 11.

本发明的目的是在此现有装置的基础上进一步发展蜂窝体,使其举例来说在用作催化剂载体时改进对废气的催化转化。此外还使其制造简单。The object of the present invention is to further develop the honeycomb body on the basis of this known device in such a way that it improves the catalytic conversion of exhaust gases, for example when used as a catalyst carrier. In addition, the production is simplified.

这一目的可通过权利要求1的特征所述特别用以催化转化废气的蜂窝体得以实现。其他的特点载于各从属权利要求中。This object is achieved by a honeycomb body in particular for the catalytic conversion of exhaust gases according to the features of claim 1 . Further features are contained in the respective dependent claims.

本发明蜂窝体的特点是各通道从中心通道向外作弧形延伸。采用这一实施例使通道在不必改变载体的外部尺寸下就得以增长。The honeycomb body of the present invention is characterized in that each channel extends outward in an arc from the central channel. Using this embodiment allows the channel to be increased without having to change the outer dimensions of the carrier.

载体就其作外部尺寸来说可在取得相同的催化表面面积下作灵活的设计。通道从彼此接触的圆盘为界,至少某些圆盘具有构成通道侧面边界的宏观结构,其高度举例来说约为0.5-5mm。The support can be designed flexibly with regard to its external dimensions while achieving the same catalytic surface area. The channels are bounded by discs in contact with each other, at least some of the discs have macrostructures constituting the lateral boundaries of the channels, the height of which is for example about 0.5-5 mm.

这种蜂窝体结构的优点是制造简单,因为这种宏观结构举例来说可通过在圆盘上压纹得出。这种结构的另一优点是改变圆盘式通道的数量就可较为简单地使催化表面面积与催化剂载体的用途相适应。The advantage of such a honeycomb structure is the simple production, since such a macrostructure can be obtained, for example, by embossing a disc. Another advantage of this structure is that it is relatively simple to adapt the catalytic surface area to the use of the catalyst support by varying the number of disk-like passages.

各圆盘的一些宏观结构可彼此作不同的弯曲。载体的通道可具有相同的曲率但不同的横截面。对催化剂载体可采用曲率相同和(或)不同的宏观结构来满足各种要求。在交替采用带或不带宏观结构的圆盘或宏观结构曲率不同的圆盘时就可作出组合式的载体结构而取得圆盘间所规定的间距。Some of the macrostructures of the disks may be curved differently from each other. The channels of the carrier may have the same curvature but different cross-sections. Macrostructures with the same and/or different curvatures can be used for catalyst supports to meet various requirements. By alternately using disks with or without macrostructures or disks with different curvatures of the macrostructures, a combined carrier structure can be produced in order to achieve a defined distance between the disks.

最好使各通道从中央通道向外作大体上的渐开式延伸。这样,各渐开体在任何部位都具有相同的间距,因而通道在流动方向上的自由流动截面大致保持恒定不变。Preferably the channels extend generally inwardly from the central channel. In this way, the involute bodies have the same spacing everywhere, so that the free flow cross-section of the channel in the direction of flow remains approximately constant.

在另一优选实施例中,在装置中交替地设置带宏观结构的圆盘和带微观结构的圆盘而使宏观结构与微观结构成一角度相交。这种改进的优点是微观结构干扰通道内的流动而引起流动中的涡流。流动中的涡流可使流层和催化剂表面上的扩散层相互干扰而改进废气和催化剂之间的质量传递。In another preferred embodiment, the macrostructured disks and the microstructured disks are arranged alternately in the device such that the macrostructures intersect the microstructures at an angle. The advantage of this modification is that the microstructure interferes with the flow in the channel causing eddies in the flow. Eddy currents in the flow can cause the flow layer and the diffusion layer on the surface of the catalyst to interfere with each other to improve mass transfer between the exhaust gas and the catalyst.

微观结构举例来说可以作成与中央通道同心的凸纹。微观结构一词在这里可理解为高度仅为宏观结构约5-30%的结构。The microstructure can for example be formed as a relief concentric to the central channel. The term microstructure is understood here to mean structures whose height is only about 5-30% of the macrostructure.

按权利要求7所述的另一特点,微观结构形成与宏观结构成一角度相交的凸纹。According to a further feature of claim 7, the microstructures form reliefs intersecting the macrostructures at an angle.

带有宏观结构的圆盘也可另外带有与宏观结构成一角度延伸的微观结构以便加强催化剂作用。The discs with macrostructures may also additionally have microstructures extending at an angle to the macrostructures in order to enhance the catalytic action.

废气流程最好是从内向外流经载体。因此使中央通道与废气入口连通。这种流程的优点是载体中部的操作温度可相对较快地达到催化转化所要求的温度。因此,装置具有相对较快的反应速度。The flow of exhaust gas is preferably from the inside to the outside through the carrier. The central channel is thus communicated with the exhaust gas inlet. The advantage of this procedure is that the operating temperature in the middle of the carrier can reach the temperature required for catalytic conversion relatively quickly. Therefore, the device has a relatively fast reaction speed.

为进一步减少冷态起动期的污染性排放体,应对载体作电加热或电磁加热。电加热的载体举例来说可见之于国际专利WO92/18245。In order to further reduce polluting emissions during the cold start period, the carrier should be heated by electric heating or electromagnetic heating. Electrically heated supports are described, for example, in International Patent WO 92/18245.

现对本发明非限制性的实施例、优点和可能的应用结合附图说明如下,图中:Now non-limiting embodiments, advantages and possible applications of the present invention are described below in conjunction with the accompanying drawings, in the figure:

图1为本发明装置第一实施例的纵剖面图;Fig. 1 is the longitudinal sectional view of the first embodiment of device of the present invention;

图2为本发明装置第二实施例的纵剖面图;Fig. 2 is the longitudinal sectional view of the second embodiment of the device of the present invention;

图3为圆盘的平面视图;Fig. 3 is the plane view of disc;

图4为带微观结构的圆盘平面视图;Fig. 4 is the disc plane view of band microstructure;

图5为图4中沿线V-V的剖面图;Fig. 5 is a sectional view along the line V-V in Fig. 4;

图1示出用以在排气系统中催化转化废气的装置1。装置具有内装催化剂载体3的外壳2。催化剂载体3具有若干通道4。各通道通向中央通道5。中央通道5与壳体2的废气入口6连通。废气入口6或壳体2与作为排气系统一部分的排气管7连通。FIG. 1 shows a device 1 for the catalytic conversion of exhaust gases in an exhaust system. The device has a housing 2 in which a catalyst carrier 3 is housed. The catalyst carrier 3 has several channels 4 . Each channel leads to the central channel 5 . The central channel 5 communicates with the exhaust gas inlet 6 of the housing 2 . The exhaust gas inlet 6 or housing 2 communicates with an exhaust pipe 7 which is part of the exhaust system.

壳体2具有与另一排气管9连通的废气出口8。与废气入口相对的一端10是封闭的。The housing 2 has an exhaust gas outlet 8 communicating with another exhaust pipe 9 . The end 10 opposite the exhaust gas inlet is closed.

载体3与壳体2内作间隔分开安装而使载体3和壳体2之间留出一间隙11。The carrier 3 is installed separately from the inside of the housing 2 so that a gap 11 is reserved between the carrier 3 and the housing 2 .

来自内燃机(未示出)的废气A经排气管7和废气入口6流进中央通道5。废气从中央通道5经由载体2的通道4流出载体。Exhaust gas A from an internal combustion engine (not shown) flows into the central passage 5 via an exhaust pipe 7 and an exhaust gas inlet 6 . The exhaust gas flows out of the carrier from the central channel 5 via the channels 4 of the carrier 2 .

废气经间隙11和壳体2的废气出口8流进排气管9。The exhaust gas flows into the exhaust pipe 9 through the gap 11 and the exhaust gas outlet 8 of the housing 2 .

图2示出另一实施例。第二实施例与图1第一实施例的差别在于废气的流程不同。在第一实施例中,废气从内向外流经载体,而在第二实施例中废气从外向内流经载体3。Figure 2 shows another embodiment. The difference between the second embodiment and the first embodiment in FIG. 1 lies in the flow of exhaust gas. In the first embodiment, the exhaust gas flows through the carrier from the inside to the outside, whereas in the second embodiment the exhaust gas flows through the carrier 3 from the outside to the inside.

在废气入口区12内设有导流器13,用以使废气流转向间隙11这种导流器在流体学上用以减少压力损失。A deflector 13 is provided in the exhaust gas inlet region 12 to deflect the exhaust gas flow into the gap 11 . This deflector serves fluidly to reduce the pressure loss.

在图2实施例中,载体3也是可电加热的。为此,使电压源14经中央通道5接到载体3的内部。使载体3的外表面也与电压源14连接。载体3由若干彼此接触的圆盘构成。图3示出带有宏观结构16的圆盘15。宏观结构16构成通道4的侧面边界。通道4从中央区17向外大体上作渐开状延伸。圆盘可另外带有与宏观结构成一角度延伸的微观结构20。In the embodiment of FIG. 2, the carrier 3 is also electrically heatable. For this purpose, the voltage source 14 is connected via the central channel 5 to the interior of the carrier 3 . The outer surface of the carrier 3 is also connected to a voltage source 14 . The carrier 3 consists of several discs in contact with each other. FIG. 3 shows a disk 15 with macrostructures 16 . The macrostructures 16 form the lateral boundaries of the channel 4 . The channel 4 extends generally involutely from the central region 17 outwards. The disk may additionally be provided with microstructures 20 extending at an angle to the macrostructures.

图4、5示出带微观结构的圆盘。微观结构19具有与中央区17同心的凸纹。中央区17用作在组装载体时成为中央通道5的开口。微观结构19可只在圆盘18的一侧但最好在其两侧设置。最好使其彼此相隔一相当于0.5-10倍于宏观结构16高度的间距。Figures 4, 5 show discs with microstructures. The microstructure 19 has a relief concentric to the central zone 17 . The central area 17 serves as an opening which becomes the central channel 5 when the carrier is assembled. The microstructures 19 may be provided on only one side of the disk 18 but preferably on both sides. Preferably, they are separated from each other by a distance corresponding to 0.5-10 times the height of the macrostructures 16 .

本发明蜂窝体由于其具有灵活的结构可用于即使可利用空间很有限的场合。Due to its flexible structure, the honeycomb body according to the invention can be used even where the available space is very limited.

Claims (12)

  1. A honeycomb ceramics particularly a kind of in vent systems in order to the catalyst carrier (3) of catalyzed conversion waste gas, this honeycomb ceramics is made of adjacent disk (15,18), have some passages (4), each passage is the boundary with disk (15,18), each passage (4) leads to a centre gangway (5) with the one end
    It is characterized in that:
    At least some disk (15) has the macrostructure (16) on formation passage (4) border, side, and macrostructure is made the involute shape substantially and stretched out from centre gangway (5).
  2. 2. press the described honeycomb ceramics of claim 1,
    It is characterized in that:
    Each passage (4) has the curvature that differs from one another.
  3. 3. press the described honeycomb ceramics of claim 2,
    It is characterized in that:
    At least some disk (15) has the macrostructure (16) of different curvature bending.
  4. 4. press the described honeycomb ceramics of claim 4,
    It is characterized in that:
    Each passage (4) departs from desirable involute shape and tangentially extends from central area (17).
  5. 5. press the described honeycomb ceramics of claim 1,
    It is characterized in that:
    The free flow cross section of passage (4) is invariable substantially on flow direction.
  6. 6. press the described honeycomb ceramics of claim 1,
    It is characterized in that:
    The disk (18) that has the disk (15) of a macrostructure (16) and have a microstructure (19) is done installation alternately, and wherein, described macrostructure (16) intersects at angle with microstructure (19).
  7. 7. press the described honeycomb ceramics of claim 6,
    It is characterized in that:
    Described microstructure (19) has and the concentric burr of a central area (17).
  8. 8. press the described honeycomb ceramics of claim 6,
    It is characterized in that:
    Described microstructure is to be made of the burr that intersects at angle with macrostructure.
  9. 9. press one of claim 1-3 described honeycomb ceramics,
    It is characterized in that:
    The disk (15) that has macrostructure (16) also has the microstructure of extending at angle with macrostructure (16).
  10. 10. press the described honeycomb ceramics of claim 1,
    It is characterized in that:
    Described carrier (3) is heatable.
  11. 11. by the described honeycomb ceramics of claim 10,
    It is characterized in that:
    Described carrier (3) but electric heating.
  12. 12. by the described honeycomb ceramics of claim 10,
    It is characterized in that:
    Described carrier (3) but electromagnetism heating.
CN95195280A 1994-09-26 1995-09-22 Circular disc shape honeycomb, esp. catalyst carrier Expired - Fee Related CN1090060C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN95195280A CN1090060C (en) 1994-09-26 1995-09-22 Circular disc shape honeycomb, esp. catalyst carrier

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DEP4434363.9 1994-09-26
DEP4435913.6 1994-10-07
CN95195280A CN1090060C (en) 1994-09-26 1995-09-22 Circular disc shape honeycomb, esp. catalyst carrier

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CN1090060C true CN1090060C (en) 2002-09-04

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CN101190330A (en) 2006-11-30 2008-06-04 深圳市鼎兴生物医药技术开发有限公司 Application of cholinesterase in antagonizing tachykinin drugs

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4311513A1 (en) * 1992-04-15 1993-10-21 Jenbacher Energiesysteme Ag Je Catalytic converter with extended life
EP0567034A1 (en) * 1992-04-20 1993-10-27 Toyota Jidosha Kabushiki Kaisha Electrically heatable catalytic converter
DE9315010U1 (en) * 1993-10-04 1994-04-07 Heinrich Gillet Gmbh & Co Kg, 67480 Edenkoben Carrier body for exhaust gas catalysts
DE4339025A1 (en) * 1992-12-14 1994-06-16 Mannesmann Ag Catalytic purificn. of polluted air - using element with absorbent portion and catalytic combustion portion.

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4311513A1 (en) * 1992-04-15 1993-10-21 Jenbacher Energiesysteme Ag Je Catalytic converter with extended life
EP0567034A1 (en) * 1992-04-20 1993-10-27 Toyota Jidosha Kabushiki Kaisha Electrically heatable catalytic converter
DE4339025A1 (en) * 1992-12-14 1994-06-16 Mannesmann Ag Catalytic purificn. of polluted air - using element with absorbent portion and catalytic combustion portion.
DE9315010U1 (en) * 1993-10-04 1994-04-07 Heinrich Gillet Gmbh & Co Kg, 67480 Edenkoben Carrier body for exhaust gas catalysts

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