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CN108987011A - Compound bonded permanent magnet - Google Patents

Compound bonded permanent magnet Download PDF

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Publication number
CN108987011A
CN108987011A CN201710403060.1A CN201710403060A CN108987011A CN 108987011 A CN108987011 A CN 108987011A CN 201710403060 A CN201710403060 A CN 201710403060A CN 108987011 A CN108987011 A CN 108987011A
Authority
CN
China
Prior art keywords
permanent magnet
magnet
rare earth
powder
rare
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710403060.1A
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Chinese (zh)
Inventor
胡健
曾华
黄道平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
YIBIN JINYUAN COMPOSITE MATERIALS Co Ltd
Original Assignee
YIBIN JINYUAN COMPOSITE MATERIALS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by YIBIN JINYUAN COMPOSITE MATERIALS Co Ltd filed Critical YIBIN JINYUAN COMPOSITE MATERIALS Co Ltd
Priority to CN201710403060.1A priority Critical patent/CN108987011A/en
Publication of CN108987011A publication Critical patent/CN108987011A/en
Pending legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F7/00Magnets
    • H01F7/02Permanent magnets [PM]
    • H01F7/0205Magnetic circuits with PM in general
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/032Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials
    • H01F1/04Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys
    • H01F1/047Alloys characterised by their composition
    • H01F1/053Alloys characterised by their composition containing rare earth metals
    • H01F1/0533Alloys characterised by their composition containing rare earth metals in a bonding agent
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/032Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials
    • H01F1/04Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys
    • H01F1/047Alloys characterised by their composition
    • H01F1/053Alloys characterised by their composition containing rare earth metals
    • H01F1/055Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5
    • H01F1/057Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IIIa elements, e.g. Nd2Fe14B
    • H01F1/0571Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IIIa elements, e.g. Nd2Fe14B in the form of particles, e.g. rapid quenched powders or ribbon flakes
    • H01F1/0575Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IIIa elements, e.g. Nd2Fe14B in the form of particles, e.g. rapid quenched powders or ribbon flakes pressed, sintered or bonded together
    • H01F1/0578Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IIIa elements, e.g. Nd2Fe14B in the form of particles, e.g. rapid quenched powders or ribbon flakes pressed, sintered or bonded together bonded together
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F7/00Magnets
    • H01F7/02Permanent magnets [PM]
    • H01F7/0205Magnetic circuits with PM in general
    • H01F7/021Construction of PM

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  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Hard Magnetic Materials (AREA)

Abstract

The invention proposes a kind of compound bonded permanent magnets, including rare-earth bond magnet layer and neodymium iron boron binding magnet layer, two layers of compoiste adhering forms, the rare-earth bond magnet is that rare earth permanent magnet powder and binder are bonded according to the ratio of mass fraction 9:1, the rare earth permanent magnet powder is made of rare earth element Sm, Fe, M, Si and N element, and wherein M is at least one of Be, Cr, Al, Mo;The neodymium iron boron binding magnet NdFeB magnetic powder, yttrium iron alloy, aluminium oxide, manganese oxide, zinc oxide, thermosetting adhesive.Working condition requirement of the invention is low, and cost of material to can help to flexible and efficient development magnet generation preparation work, and helps to reduce the production cost of magnet also compared with conventional magnet relative moderate.

Description

Compound bonded permanent magnet
Technical field
The present invention relates to field of compound material, particularly relate to a kind of compound bonded permanent magnet.
Background technique
Today of rapid development of information technology, electronic product bring huge convenience to the mankind.Meanwhile electromagnetic radiation is made At pollution also at the another overall situation problem of facing mankind, electromagnetic pollution has become worldwide public hazards.World health group Knit the fourth-largest pollution being classified as after water pollution, atmosphere pollution, noise pollution.United Nations Conference on the Human Environment is also It is classified as one of environmental protection project.
Scientific circles are own to be confirmed, is driven or is generated such as the article or substance of energy using energy, can discharge on its periphery Electromagnetic wave out is seen everywhere electric equipment products among daily life, such as: TV, computer, mobile phone, electric light, hair drier And micro-wave oven etc., as long as can all issue certain electromagnetic wave after electric equipment products are powered.According to medical report, it is chronically exposed to and is higher than Electromagnetic wave standard value person is easy to feel tired physical fatigue, eyes, shoulder pain, headache etc., also will cause under immunity function what is more How the diseases such as drop, leukaemia, tumour ... therefore obstruct, dissipation electromagnetic wave, reduce injury of the electromagnetic wave to human body, have been existing For important topic in people's life.
Countries in the world all attach great importance to the electromagnetic environment to become increasingly complex and its caused by influence.Electromagnetic environment is protected The new disciplines field rapidly developed as one, electromagnetic radiation are not seen, be can not touch, and are referred to as stealthy killer, therefore not Cause the extensive attention of people, in order to protect environment, protection human health, ensure information safety, it is necessary to be subject to electromagnetic radiation Protection, the protection of electromagnetic radiation pollution have been very urgent.
With the high speed development of modern electronics industry and information industry, electromagenetic wave radiation that electronic product generates and its mutually Interference, it has also become a kind of serious environmental pollution, some developed countries and international organization have promulgated control electromagenetic wave radiation And the electromagnetic compatibility standard of Electromagnetic Interference was carried out inhibiting from 1998 by the regulation of interference, China, and from January 1 in 2000 It rises day and enforces.The mobile phone communication tool mobile as the modern times, while offering convenience to the mankind, also inevitably by In its transmitting concentration and strong electromagnetic wave causes to damage to human body, how to prevent and shield electromagnetic wave to cause people universal Ground concern.
Bonded permanent magnet refers to that the magnetic powder by certain permanent magnetism performance is mixed with a certain proportion of binder, by certain molding work A kind of magnet made of skill.If applying alignment magnetic field in forming process, make the direction of easy axis of magnetic powder in magnet all along same One direction, otherwise it to be exactly isotropic magnet that here it is anisotropic bonded magnets.The manufacturing process of bonded permanent magnet is a variety of more Sample, including compression molding, injection moulding, extrusion molding and calendering formation etc..
Bonded permanent magnet is big by its freedom shape, and dimensional accuracy is high, without advantages such as secondary operation, it has also become modern high The indispensable Important Components of New Product.
Summary of the invention
The present invention proposes a kind of compound bonded permanent magnet, can improve the excessive problem of the viscosity encountered in preparation process.
The technical scheme of the present invention is realized as follows: a kind of compound bonded permanent magnet, including rare-earth bond magnet layer With neodymium iron boron binding magnet layer, two layers of compoiste adhering is formed, and the rare-earth bond magnet is that rare earth permanent magnet powder and binder are pressed It being bonded according to the ratio of mass fraction 9:1, the rare earth permanent magnet powder is made of rare earth element Sm, F e, M, Si and N element, Middle M is at least one of Be, Cr, Al, Mo;Sm constituent content is interior in 5-8at% range-in the rare earth permanent magnet powder, and Si is in 3- Within the scope of 5at%, M is in range 2-5at%, and for N within the scope of 6-8at%, surplus is iron;
The neodymium iron boron binding magnet includes the following component by mass fraction: NdFeB magnetic powder 80-90%, yttrium iron alloy 1-2%, aluminium oxide 2%-3%, manganese oxide 3%-6%, zinc oxide 1%-3%, thermosetting adhesive 5-12%.
Preferably, the yttrium iron alloy, aluminium oxide, manganese oxide, zinc oxide are nutty structure, and the largest particles is straight Diameter is greater than 3mm, and degree of purity is not less than 92%.
Preferably, the rare earth permanent magnet powder at least 85vol% is TbCu7 phase.
Preferably, the average thickness for stating rare earth permanent magnet powder is 15-50 μm;By the nanometer of average-size 20-70nm Brilliant and amorphous structure is constituted.
Compared with the prior art, the advantages of the present invention are as follows: working condition requirement is low, and cost of material is also compared with conventional magnet Relative moderate to can help to flexible and efficient development magnet generation preparation work, and helps to reduce being produced into for magnet This, at the same time, separately effectively raises magnet density and structural strength, magnet internal grain stability is good, reduces magnet Eddy-current loss, magnetic hystersis loss and magnetocrystalline anisotropy constant, also effectively to the magnetic mechanical performance of magnet, conductance temperature and frequency Improvement is optimized in rate characteristic, so as to effectively raise magnet total quality stability in use.Pass through in the present invention The addition of Si element, increases amorphous formation ability, and strap can be made to be formed under lower belt speed, improves into band efficiency, Tape thickness is stabilized into, microstructure and even grain size are made, is conducive to the magnetic property for improving magnetic powder.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field Art personnel every other embodiment obtained without creative efforts belongs to the model that the present invention protects It encloses.
Embodiment: a kind of compound bonded permanent magnet, including rare-earth bond magnet layer and neodymium iron boron binding magnet layer, two layers Compoiste adhering forms, and the rare-earth bond magnet is that rare earth permanent magnet powder and binder are bonded according to the ratio of mass fraction 9:1 It forms, the rare earth permanent magnet powder is made of rare earth element Sm, Fe, M, Si and N element, and wherein M is at least one in Be, Cr, Al, Mo Kind;Sm constituent content is interior in 5-8at% range-in the rare earth permanent magnet powder, and Si is within the scope of 3-5at%, and M is in range 2-5at% Interior, for N within the scope of 6-8at%, surplus is iron;
The neodymium iron boron binding magnet includes the following component by mass fraction: NdFeB magnetic powder 80-90%, yttrium iron alloy 1-2%, aluminium oxide 2%-3%, manganese oxide 3%-6%, zinc oxide 1%-3%, thermosetting adhesive 5-12%.
Preferably, the yttrium iron alloy, aluminium oxide, manganese oxide, zinc oxide are nutty structure, and the largest particles is straight Diameter is greater than 3mm, and degree of purity is not less than 92%.
Preferably, the rare earth permanent magnet powder at least 85vol% is TbCu7 phase.
Preferably, the average thickness for stating rare earth permanent magnet powder is 15-50 μm;By the nanometer of average-size 20-70nm Brilliant and amorphous structure is constituted.
Embodiment 1: a kind of compound bonded permanent magnet, including rare-earth bond magnet layer and neodymium iron boron binding magnet layer, two Layer compoiste adhering forms, and the rare-earth bond magnet is that rare earth permanent magnet powder and binder are viscous according to the ratio of mass fraction 9:1 It ties, the rare earth permanent magnet powder is made of rare earth element Sm, Fe, M, Si and N element, and wherein M is Al, Mo;The rare earth permanent magnet Sm constituent content is 5at%, Si 3at%, M 2at%, N 6at%, Fe 84at% in powder;The neodymium iron boron binding magnetic Body includes the following component by mass fraction: NdFeB magnetic powder 80%, yttrium iron alloy 2%, aluminium oxide 3%, manganese oxide 6%, oxygen Change zinc 2%, thermosetting adhesive 7%.The yttrium iron alloy, aluminium oxide, manganese oxide, zinc oxide are nutty structure, and most Bulky grain diameter is greater than 3mm, and degree of purity is lower than 95%.The average thickness for stating rare earth permanent magnet powder is 15-30 μm;By The nanocrystalline and amorphous structure of average-size 20-40nm is constituted.
Embodiment 2: a kind of compound bonded permanent magnet, including rare-earth bond magnet layer and neodymium iron boron binding magnet layer, two Layer compoiste adhering forms, and the rare-earth bond magnet is that rare earth permanent magnet powder and binder are viscous according to the ratio of mass fraction 9:1 It ties, the rare earth permanent magnet powder is made of rare earth element Sm, Fe, M, Si and N element, and wherein M is Be, Cr;The rare earth permanent magnet Sm constituent content is for 8at%, Si 5at%, M 5at%, N 8at%, Fe 74at% in powder;The neodymium iron boron binding Magnet includes the following component by mass fraction: NdFeB magnetic powder 88%, yttrium iron alloy 1%, aluminium oxide 2%, manganese oxide 3%, Zinc oxide 1%, thermosetting adhesive 5%.The yttrium iron alloy, aluminium oxide, manganese oxide, zinc oxide are nutty structure, and The largest particles diameter is 5mm, and degree of purity is not less than 92%.The rare earth permanent magnet powder at least 88vol% is TbCu7 phase.Institute The average thickness for stating rare earth permanent magnet powder is 30-50 μm;It is made of the nanocrystalline and amorphous structure of average-size 50-70nm.
Working condition of the invention requires low, and cost of material is also compared with conventional magnet relative moderate, to can help to spirit Efficient development magnet generation preparation work living, and help to reduce the production cost of magnet, it is at the same time, separately effective to improve Magnet density and structural strength, magnet internal grain stability is good, reduce eddy-current loss, magnetic hystersis loss and the magnetocrystalline of magnet Also improvement effectively is optimized to the magnetic mechanical performance of magnet, conductance temperature and frequency characteristic in anisotropy constant, thus Magnet total quality stability in use can be effectively raised.The addition for passing through Si element in the present invention, increases amorphous At ability, strap can be made to be formed under lower belt speed, improve into band efficiency, stabilize into tape thickness, make microstructure And even grain size, be conducive to the magnetic property for improving magnetic powder.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.

Claims (4)

1. a kind of compound bonded permanent magnet, including rare-earth bond magnet layer and neodymium iron boron binding magnet layer, two layers of compoiste adhering It forms, it is characterised in that: the rare-earth bond magnet is that rare earth permanent magnet powder and binder are viscous according to the ratio of mass fraction 9:1 Tie, the rare earth permanent magnet powder is made of rare earth element Sm, Fe, M, Si and N element, wherein M be Be, Cr, Al, Mo at least It is a kind of;Sm constituent content is interior in 5-8at% range-in the rare earth permanent magnet powder, and Si is within the scope of 3-5at%, and M is in range 2- In 5at%, for N within the scope of 6-8at%, surplus is iron;
The neodymium iron boron binding magnet includes the following component by mass fraction: NdFeB magnetic powder 80-90%, yttrium iron alloy 1- 2%, aluminium oxide 2%-3%, manganese oxide 3%-6%, zinc oxide 1%-3%, thermosetting adhesive 5-12%.
2. compound bonded permanent magnet according to claim 1, it is characterised in that: the yttrium iron alloy, aluminium oxide, oxidation Manganese, zinc oxide are nutty structure, and the largest particles diameter is greater than 3mm, and degree of purity is not less than 92%.
3. compound bonded permanent magnet according to claim 1, it is characterised in that: the rare earth permanent magnet powder at least 85vol% For TbCu7 phase.
4. compound bonded permanent magnet according to claim 1, it is characterised in that: the average thickness for stating rare earth permanent magnet powder It is 15-50 μm;It is made of the nanocrystalline and amorphous structure of average-size 20-70nm.
CN201710403060.1A 2017-06-01 2017-06-01 Compound bonded permanent magnet Pending CN108987011A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201710403060.1A CN108987011A (en) 2017-06-01 2017-06-01 Compound bonded permanent magnet

Publications (1)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101145418A (en) * 2007-08-22 2008-03-19 上海爱普生磁性器件有限公司 Method for preparing powder for quasi-compression bonding rare earth permanent magnet
CN101552078A (en) * 2009-01-04 2009-10-07 康双双 Composite magnet
CN102208234A (en) * 2010-03-29 2011-10-05 有研稀土新材料股份有限公司 Rare earth permanent magnetic powder and bonded magnet
CN102456459A (en) * 2010-10-20 2012-05-16 北京中科三环高技术股份有限公司 Flexible magnet without magnetic powder falling and preparation method thereof
CN102610353A (en) * 2011-01-24 2012-07-25 北京中科三环高技术股份有限公司 Preparation method of anisotropic flexible magnet with high degree of orientation and high performance
CN103545076A (en) * 2013-10-30 2014-01-29 华南理工大学 Method for preparing neodymium-iron-boron-ferrite laminated composite bonded magnet by in-situ polymerization bonding agents
CN104945754A (en) * 2015-07-20 2015-09-30 广州新莱福磁电有限公司 Manufacturing method for improving attraction of rubber extrusion magnetic strip

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101145418A (en) * 2007-08-22 2008-03-19 上海爱普生磁性器件有限公司 Method for preparing powder for quasi-compression bonding rare earth permanent magnet
CN101552078A (en) * 2009-01-04 2009-10-07 康双双 Composite magnet
CN102208234A (en) * 2010-03-29 2011-10-05 有研稀土新材料股份有限公司 Rare earth permanent magnetic powder and bonded magnet
CN102456459A (en) * 2010-10-20 2012-05-16 北京中科三环高技术股份有限公司 Flexible magnet without magnetic powder falling and preparation method thereof
CN102610353A (en) * 2011-01-24 2012-07-25 北京中科三环高技术股份有限公司 Preparation method of anisotropic flexible magnet with high degree of orientation and high performance
CN103545076A (en) * 2013-10-30 2014-01-29 华南理工大学 Method for preparing neodymium-iron-boron-ferrite laminated composite bonded magnet by in-situ polymerization bonding agents
CN104945754A (en) * 2015-07-20 2015-09-30 广州新莱福磁电有限公司 Manufacturing method for improving attraction of rubber extrusion magnetic strip

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Application publication date: 20181211