CN108986985A - 一种水性导电浆料的制作方法 - Google Patents
一种水性导电浆料的制作方法 Download PDFInfo
- Publication number
- CN108986985A CN108986985A CN201810610764.0A CN201810610764A CN108986985A CN 108986985 A CN108986985 A CN 108986985A CN 201810610764 A CN201810610764 A CN 201810610764A CN 108986985 A CN108986985 A CN 108986985A
- Authority
- CN
- China
- Prior art keywords
- conductive
- production method
- slurry
- content
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002002 slurry Substances 0.000 title claims abstract description 37
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 30
- 239000011248 coating agent Substances 0.000 claims abstract description 29
- 238000000576 coating method Methods 0.000 claims abstract description 29
- 239000008367 deionised water Substances 0.000 claims abstract description 23
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 12
- 238000007605 air drying Methods 0.000 claims abstract description 8
- 239000002270 dispersing agent Substances 0.000 claims abstract description 8
- 239000006185 dispersion Substances 0.000 claims abstract description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000005977 Ethylene Substances 0.000 claims abstract description 7
- 239000011231 conductive filler Substances 0.000 claims abstract description 7
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 5
- 239000002994 raw material Substances 0.000 claims abstract description 4
- NJSSICCENMLTKO-HRCBOCMUSA-N [(1r,2s,4r,5r)-3-hydroxy-4-(4-methylphenyl)sulfonyloxy-6,8-dioxabicyclo[3.2.1]octan-2-yl] 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)O[C@H]1C(O)[C@@H](OS(=O)(=O)C=2C=CC(C)=CC=2)[C@@H]2OC[C@H]1O2 NJSSICCENMLTKO-HRCBOCMUSA-N 0.000 claims abstract description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- -1 Acyl acetone Chemical compound 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 6
- GKWLILHTTGWKLQ-UHFFFAOYSA-N 2,3-dihydrothieno[3,4-b][1,4]dioxine Chemical compound O1CCOC2=CSC=C21 GKWLILHTTGWKLQ-UHFFFAOYSA-N 0.000 claims description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 4
- 229960001484 edetic acid Drugs 0.000 claims description 4
- 229910021389 graphene Inorganic materials 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- ZUDCKLVMBAXBIF-UHFFFAOYSA-N 3,4-dimethoxythiophene Chemical compound COC1=CSC=C1OC ZUDCKLVMBAXBIF-UHFFFAOYSA-N 0.000 claims description 3
- RFSKGCVUDQRZSD-UHFFFAOYSA-N 3-methoxythiophene Chemical compound COC=1C=CSC=1 RFSKGCVUDQRZSD-UHFFFAOYSA-N 0.000 claims description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- 239000002041 carbon nanotube Substances 0.000 claims description 3
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 claims description 3
- 125000001255 4-fluorophenyl group Chemical group [H]C1=C([H])C(*)=C([H])C([H])=C1F 0.000 claims description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Divinylene sulfide Natural products C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000000908 ammonium hydroxide Substances 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 238000003786 synthesis reaction Methods 0.000 claims description 2
- 229930192474 thiophene Natural products 0.000 claims description 2
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 claims description 2
- SXMUSCUQMMSSKP-UHFFFAOYSA-N [O].C=1C=CSC=1 Chemical compound [O].C=1C=CSC=1 SXMUSCUQMMSSKP-UHFFFAOYSA-N 0.000 claims 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Substances CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- 229920000123 polythiophene Polymers 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 238000004528 spin coating Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 3
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 12
- 229920002521 macromolecule Polymers 0.000 description 3
- WNOOCRQGKGWSJE-UHFFFAOYSA-N 3,4-dihydro-2h-thieno[3,4-b][1,4]dioxepine Chemical compound O1CCCOC2=CSC=C21 WNOOCRQGKGWSJE-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 241001479434 Agfa Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920001609 Poly(3,4-ethylenedioxythiophene) Polymers 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000002042 Silver nanowire Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 229920000547 conjugated polymer Polymers 0.000 description 1
- 230000021615 conjugation Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002070 nanowire Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/22—Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/24—Conductive material dispersed in non-conductive organic material the conductive material comprising carbon-silicon compounds, carbon or silicon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
- H01B13/0026—Apparatus for manufacturing conducting or semi-conducting layers, e.g. deposition of metal
Landscapes
- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Conductive Materials (AREA)
Abstract
一种水性导电浆料的制作方法,其特征在于,配方由以下质量比含量的成分组成:去离子水:100份;聚噻吩衍生物:1~5份;聚乙烯胺:1~6份;四(二甲基胺)乙烯:0~3份;N型无机导电填料:0~5份;分散剂:0~3份;消泡剂:0~0.1份;其中聚二烯丙基二甲基氯化铵含量不低于加入的聚噻吩衍生物含量,分散剂含量不低于无机导电填料含量的1/2,制作方法为将功能成分加入去离子水中,室温~50℃超声波环境下搅拌8~12小时得到稳定导电分散液浆料,将浆料旋涂或刮涂在材料表面,室温~70℃下风干可得到导电涂层。本发明所有原料均为常见廉价化学品,易于规模化量产。涂层为N型导电特性,可用于柔性热电器件、柔性光电器件等领域。
Description
技术领域
本发明属于材料化学技术领域,涉及一种水性导电浆料的制作方法。
背景技术
随着智能化电子技术的发展,柔性化成为电子器件的一大发展趋势。柔性导电电极材料研究在全球范围内方兴未艾。柔性导电涂层和电极主要包括无机导电填料填充的聚合物以及共轭导电高分子两类。无机导电填料填充的聚合物涂层的聚合物主要起到粘结剂作用,主要通过渗流实现导电,电导稳定性受到影响;而共轭导电高分子涂层为本征导电涂层。德国Clevios生产的PH200~PH1000系列共轭高分子全有机透明导电浆料和比利时Agfa公司的OrgaCon系列的PEDOT导电油墨都是成功的商品化导电浆料。在此基础上,加入炭黑、石墨烯、银纳米线、铜纳米线等材料共混以提高导电性,如加入炭黑的Orgacon EL-P4020产品,但是现有产品昂贵的价格给柔性电子制造业带来较重的成本压力。有机光电领域中,柔性N型电极多为蒸镀的小分子化合物,之对应N型高分子导电浆料基本处于空白。高分子导电浆料的丝印工艺在制造成本和稳定性上较之气相蒸镀均有显著优势,因此,开发共轭导电高分子为基础的N型导电涂料对柔性电子产业有较大意义。
发明内容
针对现有技术不足,本发明的目的在于提供一种水性导电浆料的制作方法,其特征在于,配方由以下质量比含量的成分组成:
去离子水:100份;
聚噻吩衍生物:1~5份;
聚乙烯胺:1~6份;
四(二甲基胺)乙烯:0~3份;
N型无机导电填料:0~5份;
分散剂:0~3份;
消泡剂:0~0.1份;
去离子水为溶剂,其余为功能成分,其中聚二烯丙基二甲基氯化铵含量不低于加入的聚噻吩衍生物含量,分散剂含量不低于无机导电填料含量的1/2,制作方法为将功能成分加入去离子水中,室温~50℃超声波环境下搅拌8~12小时得到稳定导电分散液浆料,将浆料旋涂或刮涂在材料表面,室温~70℃下风干可得到导电涂层。
所述原料聚噻吩衍生物包括中的聚3,4-乙撑二氧噻吩、聚3,4-二甲氧基噻吩、聚3-甲氧基噻吩、聚3,4-丙烯二氧噻吩、聚4-氟苯基-3-噻吩中的一种或其组合,采用化学氧化合成,经氨水去掺杂后烘干。
所述无机导电填料为N型导电特性,包括聚乙烯胺处理的碳纳米管、聚乙烯胺处理的石墨烯、纳米镍、纳米钴、纳米碳化钨、纳米碳化钛中的一种或其组合。
所述分散剂包括乙酰丙酮、乙二胺四乙酸或其组合。
所述消泡剂包括矿物油、聚硅氧烷、聚醚化合物、改性有机硅中的一种或其组合。
本发明所有原料均为常见廉价化学品,易于规模化量产。合成的浆料具有电导率高、分散均匀、稳定性好的优点。涂层为N型导电特性,可用于柔性热电器件、柔性光电器件等领域。
本发明的内容和特点已揭示如上,然而前面叙述的本发明仅仅简要地或只涉及本发明的特定部分,本发明的特征可能比在此公开的内容涉及的更多。因此,本发明的保护范围应不限于实施例所揭示的内容,而应该包括在不同部分中所体现的所有内容的组合,以及各种不背离本发明的替换和修饰,并为本发明的权利要求书所涵盖。
具体实施方式
实施例1
一种水性导电浆料的制作方法,配方由以下质量比含量的成分组成:
去离子水:100份;
聚3,4-乙撑二氧噻吩:1份;
聚乙烯胺:1份;
四(二甲基胺)乙烯:2份;
去离子水为溶剂,其余为功能成分,制作方法为将功能成分加入去离子水中,室温~50℃超声波环境下搅拌8~12小时得到稳定导电分散液浆料,将浆料旋涂或刮涂在材料表面,室温~70℃下风干可得到导电涂层,电导率0.4Scm-1,Seebeck系数-26μV/K。
实施例2
一种水性导电浆料的制作方法,配方由以下质量比含量的成分组成:
去离子水:100份;
聚3,4-二甲氧基噻吩:4份;
聚乙烯胺:4份;
聚乙烯胺处理的碳纳米管:3份;
乙酰丙酮:2份;
矿物油:0.1份;
去离子水为溶剂,其余为功能成分,制作方法为将功能成分加入去离子水中,室温~50℃超声波环境下搅拌8~12小时得到稳定导电分散液浆料,将浆料旋涂或刮涂在材料表面,室温~70℃下风干可得到导电涂层,电导率35Scm-1,Seebeck系数-8μV/K。
实施例3
一种水性导电浆料的制作方法,配方由以下质量比含量的成分组成:
去离子水:100份;
聚3-甲氧基噻吩:5份;
聚乙烯胺:5份;
四(二甲基胺)乙烯:3份;
聚乙烯胺处理的石墨烯:2份;
乙酰丙酮:2份;
聚醚化合物:0.1份;
去离子水为溶剂,其余为功能成分,制作方法为将功能成分加入去离子水中,室温~50℃超声波环境下搅拌8~12小时得到稳定导电分散液浆料,将浆料旋涂或刮涂在材料表面,室温~70℃下风干可得到导电涂层,电导率47Scm-1,Seebeck系数-6μV/K。
实施例4
一种水性导电浆料的制作方法,配方由以下质量比含量的成分组成:
去离子水:100份;
聚3,4-丙烯二氧噻吩:4份;
聚乙烯胺:4份;
四(二甲基胺)乙烯:2份;
纳米镍:2份;
乙二胺四乙酸:2份;
聚硅氧烷:0.1份;
去离子水为溶剂,其余为功能成分,制作方法为将功能成分加入去离子水中,室温~50℃超声波环境下搅拌8~12小时得到稳定导电分散液浆料,将浆料旋涂或刮涂在材料表面,室温~70℃下风干可得到导电涂层,电导率77Scm-1,Seebeck系数-5μV/K。
实施例5
一种水性导电浆料的制作方法,配方由以下质量比含量的成分组成:
去离子水:100份;
聚3,4-乙撑二氧噻吩:5份;
聚乙烯胺:6份;
四(二甲基胺)乙烯:1份;
纳米碳化钨:5份;
乙二胺四乙酸:3份;
聚硅氧烷:0.1份;
去离子水为溶剂,其余为功能成分,制作方法为将功能成分加入去离子水中,室温~50℃超声波环境下搅拌8~12小时得到稳定导电分散液浆料,将浆料旋涂或刮涂在材料表面,室温~70℃下风干可得到导电涂层,电导率61Scm-1,Seebeck系数-7μV/K。
Claims (6)
1.一种水性导电浆料的制作方法,其特征在于,配方由以下质量比含量的成分组成:
去离子水:100份;
聚噻吩衍生物:1~5份;
聚乙烯胺:1~6份;
四(二甲基胺)乙烯:0~3份;
N型无机导电填料:0~5份;
分散剂:0~3份;
消泡剂:0~0.1份;
去离子水为溶剂,其余为功能成分,其中聚二烯丙基二甲基氯化铵含量不低于加入的聚噻吩衍生物含量,分散剂含量不低于无机导电填料含量的1/2,制作方法为将功能成分加入去离子水中,室温~50℃超声波环境下搅拌8~12小时得到稳定导电分散液浆料,将浆料旋涂或刮涂在材料表面,室温~70℃下风干可得到导电涂层。
2.根据权利要求1所述一种水性导电浆料的制作方法,其特征在于:所述原料聚噻吩衍生物包括中的聚3,4-乙撑二氧噻吩、聚3,4-二甲氧基噻吩、聚3-甲氧基噻吩、聚3,4-丙烯二氧噻吩、聚4-氟苯基-3-噻吩中的一种或其组合,采用化学氧化合成,经氨水去掺杂后烘干。
3.根据权利要求1所述一种水性导电浆料的制作方法,其特征在于:所述无机导电填料为N型导电特性,包括聚乙烯胺处理的碳纳米管、聚乙烯胺处理的石墨烯、纳米镍、纳米钴、纳米碳化钨、纳米碳化钛中的一种或其组合。
4.根据权利要求1所述一种水性导电浆料的制作方法,其特征在于:所述分散剂包括乙酰丙酮、乙二胺四乙酸或其组合。
5.根据权利要求1所述一种水性导电浆料的制作方法,其特征在于:所述消泡剂包括矿物油、聚硅氧烷、聚醚化合物、改性有机硅中的一种或其组合。
6.一种如权利要求1~5任意一项所述的水性导电浆料的制作方法所制作的水性导电浆料。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810610764.0A CN108986985A (zh) | 2018-06-07 | 2018-06-07 | 一种水性导电浆料的制作方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810610764.0A CN108986985A (zh) | 2018-06-07 | 2018-06-07 | 一种水性导电浆料的制作方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108986985A true CN108986985A (zh) | 2018-12-11 |
Family
ID=64540373
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810610764.0A Pending CN108986985A (zh) | 2018-06-07 | 2018-06-07 | 一种水性导电浆料的制作方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108986985A (zh) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107863174A (zh) * | 2017-11-02 | 2018-03-30 | 电子科技大学 | 一种柔性复合电极材料及其制备方法 |
| CN110108394A (zh) * | 2019-05-20 | 2019-08-09 | 中国科学院重庆绿色智能技术研究院 | 大面阵分离式压力传感器及其制备方法、水性导电浆料及其制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101529531A (zh) * | 2006-10-25 | 2009-09-09 | 拜尔材料科学股份公司 | 含银含水配方及其用于生产导电或反射涂层的用途 |
| US20120001130A1 (en) * | 2010-06-30 | 2012-01-05 | Chung Shan Institute Of Science And Technology, Armaments Bureau, M.N.D. | Method for manufacturing conductive adhesive containing one-dimensional conductive nanomaterial |
| CN104464880A (zh) * | 2014-11-17 | 2015-03-25 | 苏州斯迪克新材料科技股份有限公司 | 一种耐热柔性透明导电薄膜及其制备方法 |
| CN104538086A (zh) * | 2014-12-05 | 2015-04-22 | 北京航空航天大学 | 水性导电高分子-石墨烯分散液及其制备方法 |
| CN106128556A (zh) * | 2016-06-30 | 2016-11-16 | 嘉兴市高正高分子材料有限公司 | 一种高分散型油系碳纳米管导电浆料的制备方法 |
-
2018
- 2018-06-07 CN CN201810610764.0A patent/CN108986985A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101529531A (zh) * | 2006-10-25 | 2009-09-09 | 拜尔材料科学股份公司 | 含银含水配方及其用于生产导电或反射涂层的用途 |
| US20120001130A1 (en) * | 2010-06-30 | 2012-01-05 | Chung Shan Institute Of Science And Technology, Armaments Bureau, M.N.D. | Method for manufacturing conductive adhesive containing one-dimensional conductive nanomaterial |
| CN104464880A (zh) * | 2014-11-17 | 2015-03-25 | 苏州斯迪克新材料科技股份有限公司 | 一种耐热柔性透明导电薄膜及其制备方法 |
| CN104538086A (zh) * | 2014-12-05 | 2015-04-22 | 北京航空航天大学 | 水性导电高分子-石墨烯分散液及其制备方法 |
| CN106128556A (zh) * | 2016-06-30 | 2016-11-16 | 嘉兴市高正高分子材料有限公司 | 一种高分散型油系碳纳米管导电浆料的制备方法 |
Non-Patent Citations (1)
| Title |
|---|
| 王中平等: "《表面物理化学》", 30 September 2015, 同济大学出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107863174A (zh) * | 2017-11-02 | 2018-03-30 | 电子科技大学 | 一种柔性复合电极材料及其制备方法 |
| CN107863174B (zh) * | 2017-11-02 | 2019-08-02 | 电子科技大学 | 一种柔性复合电极材料及其制备方法 |
| CN110108394A (zh) * | 2019-05-20 | 2019-08-09 | 中国科学院重庆绿色智能技术研究院 | 大面阵分离式压力传感器及其制备方法、水性导电浆料及其制备方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Eshkalak et al. | A review on inkjet printing of CNT composites for smart applications | |
| Yin et al. | Facile synthesis of oxidation‐resistant copper nanowires toward solution‐processable, flexible, foldable, and free‐standing electrodes | |
| Kell et al. | Versatile molecular silver ink platform for printed flexible electronics | |
| Li et al. | Printable copper sensor electronics for high temperature | |
| Cherrington et al. | Materials and deposition processes for multifunctionality | |
| Ali et al. | Transparent and conductive Ti3C2Tx (MXene) thin film fabrication by electrohydrodynamic atomization technique | |
| KR101307303B1 (ko) | 투명 도전성 박막과 그 제조 방법 | |
| CN104893428B (zh) | 一种纳米银导电油墨及其制备方法 | |
| Feng et al. | Copper nanomaterials and assemblies for soft electronics | |
| Duraisamy et al. | Deposition and characterization of silver nanowires embedded PEDOT: PSS thin films via electrohydrodynamic atomization | |
| Cao et al. | Highly conductive and highly dispersed polythiophene nanoparticles for fabricating high-performance conductive adhesives | |
| CN108986985A (zh) | 一种水性导电浆料的制作方法 | |
| KR20180005957A (ko) | 3차원 인쇄 가능한 유연전극용 복합소재 | |
| CN104449239A (zh) | 一种氮杂石墨烯复合的电磁屏蔽导电底漆及其制备方法 | |
| Zheng et al. | Smart Electronic Systems: Heterogeneous Integration of Silicon and Printed Electronics | |
| Chen et al. | Size effect enabling additive-free MXene ink with ultrahigh conductivity for screen printing of wireless electronics | |
| Ke et al. | Recent advances in conductive materials for printed electronics and printed technology | |
| Bu et al. | A highly conductive and transparent solution processed AZO/MWCNT nanocomposite | |
| Lukyanov et al. | Inkjet printing with (semi) conductive conjugated polymers: a review | |
| JP2015079725A (ja) | 導電性ペースト | |
| CN108986984A (zh) | 一种n型导电浆料的制备方法 | |
| CN108986951A (zh) | 一种水性导电浆料 | |
| CN108666001A (zh) | 一种n型导电浆料的制备方法 | |
| Chani et al. | Synthesis and pressure sensing properties of the pristine cobalt oxide nanopowder | |
| Chen et al. | Effect of Introducing Conductive Organic Carrier on Properties of Low-Temperature Conductive Silver Paste. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181211 |