CN108703893A - A kind of detergent composition and its application - Google Patents
A kind of detergent composition and its application Download PDFInfo
- Publication number
- CN108703893A CN108703893A CN201810634510.2A CN201810634510A CN108703893A CN 108703893 A CN108703893 A CN 108703893A CN 201810634510 A CN201810634510 A CN 201810634510A CN 108703893 A CN108703893 A CN 108703893A
- Authority
- CN
- China
- Prior art keywords
- detergent composition
- salt
- component
- glycine
- acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000203 mixture Substances 0.000 title claims abstract description 43
- 239000003599 detergent Substances 0.000 title claims abstract description 37
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims abstract description 30
- -1 fatty acyl group N-methyltaurines Chemical class 0.000 claims abstract description 26
- 150000003839 salts Chemical class 0.000 claims abstract description 25
- 239000004471 Glycine Substances 0.000 claims abstract description 17
- 238000004140 cleaning Methods 0.000 claims abstract description 14
- 125000001924 fatty-acyl group Chemical group 0.000 claims abstract description 14
- 239000002537 cosmetic Substances 0.000 claims abstract description 13
- 238000005406 washing Methods 0.000 claims abstract description 8
- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 claims description 10
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 claims description 6
- 229960003080 taurine Drugs 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 125000002252 acyl group Chemical group 0.000 claims description 3
- JAJWGJBVLPIOOH-IZYKLYLVSA-M sodium taurocholate Chemical compound [Na+].C([C@H]1C[C@H]2O)[C@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@@H](CCC(=O)NCCS([O-])(=O)=O)C)[C@@]2(C)[C@@H](O)C1 JAJWGJBVLPIOOH-IZYKLYLVSA-M 0.000 claims description 3
- PWWJJDVDTKXWOF-UHFFFAOYSA-M sodium;2-[hexadecanoyl(methyl)amino]ethanesulfonate Chemical compound [Na+].CCCCCCCCCCCCCCCC(=O)N(C)CCS([O-])(=O)=O PWWJJDVDTKXWOF-UHFFFAOYSA-M 0.000 claims description 2
- XHDJZIZDKIUZGM-UHFFFAOYSA-N CCCCCCCCCCCCC(=O)[Na] Chemical compound CCCCCCCCCCCCC(=O)[Na] XHDJZIZDKIUZGM-UHFFFAOYSA-N 0.000 claims 1
- VKEQBMCRQDSRET-UHFFFAOYSA-N Methylone Chemical compound CNC(C)C(=O)C1=CC=C2OCOC2=C1 VKEQBMCRQDSRET-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 abstract description 10
- 230000001835 salubrious effect Effects 0.000 abstract description 8
- 230000007935 neutral effect Effects 0.000 abstract description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 9
- 229930195729 fatty acid Natural products 0.000 description 9
- 239000000194 fatty acid Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 235000001014 amino acid Nutrition 0.000 description 7
- 150000004665 fatty acids Chemical class 0.000 description 6
- 239000003921 oil Substances 0.000 description 6
- 235000019198 oils Nutrition 0.000 description 6
- 238000010998 test method Methods 0.000 description 6
- 150000001413 amino acids Chemical class 0.000 description 5
- 235000015424 sodium Nutrition 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- 206010018612 Gonorrhoea Diseases 0.000 description 3
- 235000013350 formula milk Nutrition 0.000 description 3
- 230000007794 irritation Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- 239000004475 Arginine Substances 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 238000003436 Schotten-Baumann reaction Methods 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- KEMQGTRYUADPNZ-UHFFFAOYSA-N heptadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)=O KEMQGTRYUADPNZ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- ISYWECDDZWTKFF-UHFFFAOYSA-N nonadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCCC(O)=O ISYWECDDZWTKFF-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 239000008257 shaving cream Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 229940065859 sodium cocoyl glycinate Drugs 0.000 description 2
- IKGKWKGYFJBGQJ-UHFFFAOYSA-M sodium;2-(dodecanoylamino)acetate Chemical compound [Na+].CCCCCCCCCCCC(=O)NCC([O-])=O IKGKWKGYFJBGQJ-UHFFFAOYSA-M 0.000 description 2
- RRLOOYQHUHGIRJ-UHFFFAOYSA-M sodium;ethyl sulfate Chemical compound [Na+].CCOS([O-])(=O)=O RRLOOYQHUHGIRJ-UHFFFAOYSA-M 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- ZDSCFBCGDDCJFZ-UHFFFAOYSA-N 2-(methylamino)ethanesulfonic acid;sodium Chemical compound [Na].CNCCS(O)(=O)=O ZDSCFBCGDDCJFZ-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- YNDCACVZPKJRGE-UHFFFAOYSA-N CCCCCCCCCCCCCCC(=O)[Na] Chemical compound CCCCCCCCCCCCCCC(=O)[Na] YNDCACVZPKJRGE-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000020616 amino acid formula Nutrition 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 210000000481 breast Anatomy 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229940043237 diethanolamine Drugs 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- SFNALCNOMXIBKG-UHFFFAOYSA-N ethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCO SFNALCNOMXIBKG-UHFFFAOYSA-N 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 150000002333 glycines Chemical class 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- YAQXGBBDJYBXKL-UHFFFAOYSA-N iron(2+);1,10-phenanthroline;dicyanide Chemical compound [Fe+2].N#[C-].N#[C-].C1=CN=C2C3=NC=CC=C3C=CC2=C1.C1=CN=C2C3=NC=CC=C3C=CC2=C1 YAQXGBBDJYBXKL-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- CKDDRHZIAZRDBW-UHFFFAOYSA-N n-heneicosanoic acid Natural products CCCCCCCCCCCCCCCCCCCCC(O)=O CKDDRHZIAZRDBW-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229940079781 sodium cocoyl glutamate Drugs 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 229940048109 sodium methyl cocoyl taurate Drugs 0.000 description 1
- JXKPEJDQGNYQSM-UHFFFAOYSA-M sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 230000016776 visual perception Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q9/00—Preparations for removing hair or for aiding hair removal
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of detergent composition and its applications, including following component：（A）N- long-chain fatty acyl group glycine and/or its salt；（B）N- long-chain fatty acyl group N-methyltaurines and/or its salt；Wherein, component（A）And component（B）Weight ratio be 80：20-20：80, preferably 60：40-40：60.The detergent composition of the present invention in N- long-chain fatty acyl group glycine and/or its salt by adding N- long-chain fatty acyl group N-methyltaurines and/or its salt; and the proportioning by optimizing the two; detergent composition is prepared, and not only use feeling is not salubrious, glutinous and do not dry, but also can ensure that the composition in pH is acid or neutral（pH≤7）Under conditions of can reach transparent appearance, to extend its application range, can be widely used in the cosmetics such as cleaning products or hair washing product.
Description
Technical field
The present invention relates to biotechnology, more particularly to a kind of detergent composition and its application.
Background technology
People in hair washing, shower, face cleaning and are typically the dosage that cleaning product is weighed with foam when washing one's hands, when foam compared with
When less or rapidly disappearing, people will be further added by the dosage of cleaning product, and the increase of cleaning product dosage will improve detergency.Cause
This, the cleaning product of height bubble can be to avoid the excessive degreasing of washing process.
The conventional anions tables such as laureth sodium sulfovinate, laruyl alcohol sodium sulfovinate and C14-16 alkene sulfonic acid sodiums are lived
With good lather quickness and ability, but its irritation is higher.Simultaneously because its residual on human body is higher, frequent occurrence
Continue wiping after crossing water and the case where foam occur, to further provide residue for stimulation.
It applies pH higher to fatty acid soaps, and usually 10 or so, there is very strong cleaning effect.Due to excessively cleaning, skin
The natural cover for defense " sebum film " on surface can be deteriorated, and skin loses excessive grease.Skin can be secreted for the protection of itself
More greases prevent moisture of skin to be excessively lost in, and if subsequent water and milk is not in place, skin will be kept more and more oily.Together
When since it is intolerant to hard water, there is the astringent sense rinsed well when in use.
Amino acid table, which is lived, has irritation low, safe to use, nontoxic, the preferable feature of biological degradability.But its valence
Lattice are higher, and lather quickness and ability are unsatisfactory.These factors limit the large-scale application of amino acid formula.
Seemingly with fatty acid salt, skin sense is salubrious for the structure of N- long-chain fatty acyl group glycine and/or its salt, has good bubble
Foam use feeling.But the pH of gonorrhoea is relatively high under its low temperature, and sodium cocoyl glycinate is about 8.2, and it is in the condition of pH acidity
Under can be changed into molecular conformation from ionic forms, to generate knot cream.Therefore N- long-chain fatty acyl group glycine and/or its salt are in pH
It is acid or neutral（pH≤7）Under conditions of easy to produce gonorrhoea or knot cream, formula stability it is poor, answered to limit it
Use range.
Therefore, there is an urgent need for a kind of detergent compositions by people, smaller to skin and hair irritation, are the same of clear formula
When with salubrious, glutinous and not dry use feeling.
Invention content
In order to solve the above technical problems, the primary purpose of the present invention is that provide a kind of detergent composition, the detergent
Not only use feeling is not salubrious, glutinous and do not dry for composition, but also can ensure that the composition in pH is acid or neutral（pH≤7）
Under conditions of can reach transparent appearance.
Detergent composition of the present invention, including following component：
（A）N- long-chain fatty acyl group glycine and/or its salt；
（B）N- long-chain fatty acyl group N-methyltaurines and/or its salt；
Wherein, component（A）And component（B）Weight ratio be 80：20-20：80, preferably 60：40-40：60.
Only adjust component（A）And component（B）Weight ratio be 80：20-20：80, the detergent composition being prepared
Use feeling is salubrious, does not stick and does not dry, while having and can reach transparent appearance under conditions of pH≤7.And work as component
（A）And component（B）Weight ratio be more than 80：20, the appearance of gonorrhoea will occur in the detergent composition being prepared, production
Product can not ensure its transparent visual perception and good stability.And work as component（A）And component（B）Weight ratio be less than 20：
80, the detergent composition being prepared, can not live with glycine series of tables when product use use salubrious, not glutinous and
Not dry advantage.
Wherein, pH≤7 of the detergent composition, the i.e. pH of composition are acid or neutral.
Component in the present invention（A）The N- long-chain fatty acyl group glycine used and/or its salt can be obtained by known method
It arrives.For example, the Schotten-Baumann reactions between glycine and fatty acid halide are well-known method.
Component in the present invention（B）The N- long-chain fatty acyl group N-methyltaurines used and/or its salt can be by known sides
Method obtains.For example, the Schotten-Baumann between N-methyltaurine and fatty acid halide reacts the side of being well-known
Method.
Composition（A）,（B）Fatty acyl group group, can use 8-22 carbon saturation and unsaturated fatty acid derived from branch
Chain fatty acyl group group, aliphatic acid example include octanoic acid, capric acid, lauric acid, myristic acid, stearic acid, isostearic acid, palm
The fatty acid of acid, oleic acid, linoleic acid, behenic acid, coco-nut oil fatty acid, PALM FATTY ACID, hydrogenated animal, nine acid, undecanoic acid, 13
Acid, pentadecanoic acid, heptadecanoic acid, nonadecanoic acid, heneicosoic acid etc..They can be used alone or two kinds and two or more aforementioned substances
It is used in mixed way.In view of excellent foaming capacity and quality, froth, particularly preferred coco-nut oil fatty acid, palm kernel fatty acid,
Lauric acid and myristic acid.
Component（A）,（B）Salt be not particularly limited, example includes inorganic salts, such as alkali metal such as sodium and potassium, alkali
Earth metal calcium and magnesium, aluminum and zinc, organic salt, such as ammonia, organic amine such as monoethanolamine, diethanol amine and triethanolamine, and
The salt of basic amino acid such as arginine and lysine.They can be used alone or two kinds and two or more aforementioned substances are mixed
It closes and uses.In view of easily acquirement property and operability, preferred as alkali salt, organic amine salt and basic amino acid salt, and it is outstanding
The salt of its preferred sodium, potassium, triethanolamine, arginine and N-methyltaurine sodium.
Preferably, the component（A）For sodium cocoyl glycinate, cocounut oil acyl glycine potassium, cocounut oil acyl glycine, palmityl
The mixing of one or more of glycine and decoyl glycine
Preferably, the component（B）For sodium methyl cocoyl taurate, methyl cocoyl taurine potassium, methyl lauroyl
Base sodium taurocholate, sodium methyl palmitoyl taurate, methyl myristoyl sodium taurocholate, cocounut oil acyl methyl taurine taurine
The mixing of one or more of sodium and methyl cocoyl taurine.
The detergent composition of the present invention, can under the premise of not reducing effect of the present invention in addition to above-mentioned main component
With a variety of suitable components suitably used containing ordinary cosmetics, special cosmetics etc..More specifically, it may include N-
Long-chain fatty acyl group amino acid and/or its salt and/or N- long-chain fatty acyl group modified amino acids and/or its salt（Cocoamido propionic acid
Sodium, sodium lauroyl sarcosine, myristoyl-N-methylaminoacetic acid sodium, cocoyl glutamic acid TEA salt, sodium cocoyl glutamate, cocounut oil
Acyl disodium glutamate, lauroyl methylaminopropionic acid TEA salt and lauroyl NaAsp）, finish, surfactant, increasing
Thick dose, preservative, essence, ultra-violet absorber, wetting agent, physiologically active ingredient, antioxidant, anti-inflammatory agent, antiseptic, hidroschesis
Medicine, chelating agent, neutralizer, pH adjusting agent etc., and said components can be contained according to specific purposes and form.
The detergent composition of the present invention is produced by common method, and the forms such as liquid, gel may be used.
It is suitable as the cosmetics of skin, hair etc..
The application that the present invention also provides said detergent compositions in cosmetics.The detergent composition of the present invention
Purposes is not particularly limited, but can provide a variety of cosmetics.Its example includes：Cleaning supplies such as perfumed soap, cleanser（Including
Face cosmetic, liquid gel, wetting agent etc.）, shampoo, makeup removing agent and detergent, substrate product such as hair treating agent（Including breast
Oil product, spray product, oil product, gel products, the product of other forms and bifurcated hair coverture）And shaving cream（It shaves
Frost, shaving cream etc. behind palpus）, etc..In view of the use scope that amino-acid modified amino acid table is lived, it is preferred for cleaning products
And hair washing product.
Compared with prior art, the present invention having the advantages that：
The detergent composition of the present invention in N- long-chain fatty acyl group glycine and/or its salt by adding N- long-chain acyl ylmethyls
Taurine and/or its salt, and the proportioning by both optimizing, detergent composition be prepared not only have it is salubrious, not glutinous and
Not dry use feeling, and can ensure that the composition in pH is acid or neutral（pH≤7）Under conditions of can reach it is transparent
Appearance can be widely used in the cosmetics such as cleaning products or hair washing product to extend its application range.
Specific implementation mode
It is further illustrated the present invention below by specific implementation mode, but embodiments of the present invention are not by following realities
Apply the limitation of example.
Raw material used in the embodiment of the present invention and comparative example derives from purchased in market.
Test method：
The test method of the pH of detergent composition：By sample constant temperature to 25 ± 1 DEG C, by method specified in GB/T13531.1
It measures（It is straight to survey method）.
The test method of the transparency at room temperature of detergent composition：Sample is placed in 100ml Clear glass bottles and jars, in room
Mild non-direct sunlight visual observations.
The test method of transparency at 4 DEG C of detergent composition：Sample is placed in 100ml Clear glass bottles and jars, at 4 DEG C
It places 24 hours, in non-direct sunlight visual observations after restoring immediately to room temperature within 24 hours with placement after taking-up.
Use feeling is evaluated：
Tested number：13 people；
Position on probation：Face；
Application method：Face cleaning is carried out using detergent composition.
The test method of detergent composition clearly spent：Questionnaire is filled in after on probation（It is 0-5 points, sticky-salubrious）, so
Statistical average score afterwards, the results are shown in Table 1.
The test method of the moist degree of detergent composition：Questionnaire is filled in after on probation（It is 0-5 points, dry-to moisten）, so
Statistical average score afterwards, the results are shown in Table 1.
Embodiment 1-6 and comparative example 1-4：
According to the proportioning of table 1 by water, component（A）N- long-chain fatty acyl group glycine and/or its salt, component（B）N- long-chain fatty acyl groups
N-methyltaurine and/or its salt are heated to proper temperature dissolving, stir evenly, and surplus material, moisturizing to formula are intervened after cooling
The 100% of amount is stirred evenly and is adjusted after pH to prescribed limit to get detergent composition, and the results are shown in Table 1 for test performance.
The composition and the performance test results of 1 embodiment and comparative example of table（Weight percent）
Continued 1
The detergent composition of the present invention passes through in the sweet ammonia of N- long-chain fatty acyl groups it can be seen from the embodiment and comparative example of table 1
Acid and/or its salt addition N- long-chain fatty acyl group N-methyltaurines and/or its salt, and the proportioning by optimizing the two, are prepared
Detergent composition not only has salubrious, glutinous and not dry use feeling, but also can ensure that the composition in pH is acidity
Or it is neutral（pH≤7）Under conditions of can reach transparent appearance, to extend its application range, can be widely used for cleaning
In the cosmetics such as product or hair washing product.
Claims (7)
1. a kind of detergent composition, which is characterized in that include following component：
（A）N- long-chain fatty acyl group glycine and/or its salt；
（B）N- long-chain fatty acyl group N-methyltaurines and/or its salt；
Wherein, component（A）And component（B）Weight ratio be 80：20-20：80, preferably 60：40-40：60.
2. detergent composition according to claim 1, which is characterized in that pH≤7 of the detergent composition.
3. detergent composition according to claim 1 or 2, which is characterized in that the component（A）For cocounut oil acyl glycine
The mixing of one or more of sodium, cocounut oil acyl glycine potassium, cocounut oil acyl glycine, palmityl glycine and decoyl glycine.
4. detergent composition according to claim 1 or 2, which is characterized in that the component（B）For methyl cocoyl
Sodium taurocholate, methyl cocoyl taurine potassium, methyl lauroyl sodium taurocholate, sodium methyl palmitoyl taurate, methyl
One or more of myristoyl sodium taurocholate, cocounut oil acyl methyl taurine sodium taurocholate and methyl cocoyl taurine
Mixing.
5. application of the claim 1-4 any one of them detergent compositions in cosmetics.
6. a kind of cosmetics, including claim 1-4 any one of them detergent compositions.
7. cosmetics according to claim 6, which is characterized in that the cosmetics are cleaning products or hair washing product.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103356408A (en) * | 2013-08-06 | 2013-10-23 | 珀莱雅化妆品股份有限公司 | Conditioning shampoo composition free of sulfates and dioxan |
| CN106619302A (en) * | 2016-12-29 | 2017-05-10 | 广州市中通生化制品有限公司 | Mild allergy-relieving cleansing milk and preparation method thereof |
| CN106955248A (en) * | 2017-03-31 | 2017-07-18 | 上海浦大工贸有限公司 | A kind of plant profit supports shampoo and its method for preparing extractive and preparation method thereof |
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2018
- 2018-06-20 CN CN201810634510.2A patent/CN108703893A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103356408A (en) * | 2013-08-06 | 2013-10-23 | 珀莱雅化妆品股份有限公司 | Conditioning shampoo composition free of sulfates and dioxan |
| CN106619302A (en) * | 2016-12-29 | 2017-05-10 | 广州市中通生化制品有限公司 | Mild allergy-relieving cleansing milk and preparation method thereof |
| CN106955248A (en) * | 2017-03-31 | 2017-07-18 | 上海浦大工贸有限公司 | A kind of plant profit supports shampoo and its method for preparing extractive and preparation method thereof |
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