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CN108576004A - A kind of mixed herbicide and its application containing dichloro quinolinic acid, propanil and dimethyl tetrachloride - Google Patents

A kind of mixed herbicide and its application containing dichloro quinolinic acid, propanil and dimethyl tetrachloride Download PDF

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Publication number
CN108576004A
CN108576004A CN201810572370.0A CN201810572370A CN108576004A CN 108576004 A CN108576004 A CN 108576004A CN 201810572370 A CN201810572370 A CN 201810572370A CN 108576004 A CN108576004 A CN 108576004A
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CN
China
Prior art keywords
propanil
quinolinic acid
dichloro quinolinic
dimethyl tetrachloride
mixed herbicide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810572370.0A
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Chinese (zh)
Inventor
郭晓刚
许平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hefei Hetian Biological Science And Technology Co Ltd
Original Assignee
Hefei Hetian Biological Science And Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hefei Hetian Biological Science And Technology Co Ltd filed Critical Hefei Hetian Biological Science And Technology Co Ltd
Priority to CN201810572370.0A priority Critical patent/CN108576004A/en
Publication of CN108576004A publication Critical patent/CN108576004A/en
Withdrawn legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N39/00Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02Aryloxy-carboxylic acids; Derivatives thereof
    • A01N39/04Aryloxy-acetic acids; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A01N43/42Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings condensed with carbocyclic rings

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention provides a kind of mixed herbicide containing dichloro quinolinic acid, propanil and dimethyl tetrachloride and its application;Active constituent is made of dichloro quinolinic acid, propanil and dimethyl tetrachloride, and the weight ratio of the dichloro quinolinic acid, propanil and dimethyl tetrachloride is 1 30:1‑30:1‑10;It can be used for the prevention of rice terrace grass family and broad leaved weed.

Description

A kind of mixed herbicide and its application containing dichloro quinolinic acid, propanil and dimethyl tetrachloride
Technical field
The invention belongs to pesticide fields, and in particular to a kind of Herbicidal mixture containing dichloro quinolinic acid, propanil and dimethyl tetrachloride Agent and its application.
Background technology
Dichloro quinolinic acid is a kind of quinoline carboxylic acid hormone-type selective herbicide, is the paddy field of BASF Corp. of Germany's exploitation Herbicide starts the large-scale popularization use in paddy field weeding the nineties in last century in China.By the work for interfering enzyme in plant Property, the biosynthesis of ethylene can be promoted, lead to the accumulation of a large amount of abscisic acids, plant growth is made to slow down, seriously then cause plant dead It dies.It can promote plant growth in low concentration, when high concentration destroys plant hormone balance, keeps plant metabolism disorderly, influences light Cooperation is used, respiration.Dichloro quinolinic acid is mainly used for preventing the monocotyledon weeds such as barnyard grass.
Propanil is a kind of contact killing type herbicide of tool high selectivity.There is very strong work of tagging to barnyard grass to rice seedling safety With.The effect of propanil is to destroy the photosynthesis of plant, inhibits respiration and oxidative phosphorylation, interfering nucleic acid and albumen Matter synthesis etc., makes the physiological function of aggrieved plant be affected, and dehydration, blade is accelerated gradually to dry up, last dead.Propanil is main Barnyard grass, needle spikesedge herb are prevented and kill off for rice seedling bed, live streaming field and Honda.Can also be used for dry land prevent and kill off lady's-grass, green bristlegrass, Monochoria vaginalis, The weeds seedling such as amaranth, amur foxtail.But it is substantially invalid to four leaf duckweed, bog pondweed, wild water chestnut etc., herbicidal spectrum is single, to weeds Control has limitation
Dimethyl tetrachloride is phenoxy acetic acid class selectivity Uptake and translocation hormone like herbicide, can destroy the defeated of dicotyledon Tissue is led, weed growth development is made to be interfered, cauline leaf distortion, basal part of stem expands thicker or cracking, weeds to be occurred after by medicine Hormone-type poisoning symptom.
Herbicide for paddy field is limited by crop safety at present, and herbicide controlling spectrum is also limited, and a kind of herbicide single dose is used alone Cannot completely effectively control the generation of paddy field weed, furthermore some herbicides due to the water-soluble big or field lasting period too It grows, dosage is excessive or the uneven residual hazard all be easy to causeing to this season crop or succession crop of dispenser.Between herbicide Compounding can solve the problems, such as that pesticide single dose toxicity is big, effect is poor and the R&D cycle is short, and between different pesticides Be used interchangeably the generation for capableing of retarding action object drug resistance, there is ideal using effect, therefore different role mechanism Between the compounding of pesticide be current research focus in the field of pesticide.Not dichloro quinolinic acid, propanil and diformazan four in the prior art The relevant report of chlorine compounding.
Invention content
The purpose of the present invention is to provide a kind of component is reasonable, drug cost is low, is not likely to produce the herbicide group of drug resistance Object is closed, it is miscellaneous to rice terrace grass family that there is preferable control effect, to slow down Weed Resistance, reduce drug dosage etc. With positive effect.
The present invention provides following technical scheme
A kind of mixed herbicide containing dichloro quinolinic acid, propanil and dimethyl tetrachloride, active constituent is by dichloro quinolinic acid, propanil It is formed with dimethyl tetrachloride, the weight ratio of the dichloro quinolinic acid, propanil and dimethyl tetrachloride is 1-30:1-30:1-10.Described two First tetrachloro can be the form of its sodium salt, ammonium salt, diformazan ammonium salt.
The weight ratio of mixed herbicide of the present invention, the dichloro quinolinic acid, propanil and dimethyl tetrachloride is 1-10: 5-20:2-10.The weight ratio of the preferred dichloro quinolinic acid, propanil and dimethyl tetrachloride is 1-5:5-9:2-4.Preferred institute The weight ratio for stating dichloro quinolinic acid, propanil and dimethyl tetrachloride is 3:7:3.
The gross weight of dichloro quinolinic acid, propanil and dimethyl tetrachloride in the composition described in mixed herbicide of the present invention Amount percentage composition is 5-85%.The preferred total weight percentage of the dichloro quinolinic acid, propanil and dimethyl tetrachloride in the composition Content is 25-75%.
The present composition can be prepared into adaptation dosage form, preferred dosage form wettable powder with agriculturally acceptable auxiliary combination Agent, missible oil, suspending agent, oil-suspending agent, microemulsion, aqueous emulsion, suspended emulsion, water dispersible granules etc..Auxiliary agent of the present invention Including emulsifier, dispersant, wetting agent, binder, disintegrant, thickener, stabilizer, antifreezing agent, antifoaming agent filler etc..Select From the common auxiliary material in this field.
Mixed herbicide of the present invention is used to prevent and kill off the purposes of paddy field weed.It is preferred for grass family and broad-leaved is miscellaneous Grass.The weeds include barnyard grass, moleplant seed, Monochoria vaginalis, Chinese celery, lady's-grass, green bristlegrass etc..
The present invention obtains following advantageous effects:
Composition of the present invention uses the active ingredient combinations of three kinds of different role mechanism, can effectively reduce weeds The generation of drug resistance expands herbicide controlling spectrum;Prevention when available for grassy weed and broad leaved weed.Weeding of the present invention Composition has significant synergies, higher with the field efficacy of single dose, binary composition, can effectively reduce active constituent Administration dosage, reduce environmental pollution, while doing crop safety.
Specific implementation mode
The specific implementation mode of the present invention is described in detail with reference to embodiment, it is to be understood that the guarantor of the present invention Shield range is not restricted by specific implementation.
Biological test one:Dichloro quinolinic acid, propanil and dimethyl tetrachloride are to Monochoria vaginalis Toxicity Determination.
Test method:Experiment carries out under greenhouse experiment, and seed is seeded in flowerpot by 20-35 DEG C of indoor temperature, ensures Per 20 seeds of basin, the thick mixed husky fine earths of covering 1cm or so make soil conservation moisten, water content from flowerpot bottom Jia Shui on seed In 25-35%.The consistent Monochoria vaginalis of growth selection is colonized, and does cauline leaf process, and water drenching carries out cauline leaf after blade drying Spraying treatment.After processing 30 days, fresh weight is measured, calculates preventive effect.
Herbicide associated form is evaluated according to Colby methods.Evaluation criterion:As E ﹣ E0 > 10%, it is expressed as synergistic effect; As ﹣ 10%≤E ﹣ E0≤10%, summation action is shown as;As E ﹣ E0 < ﹣ 10%, antagonism is shown as.
1 dichloro quinolinic acid of table, propanil and dimethyl tetrachloride compounding are to Monochoria vaginalis Toxicity Determination
As seen from the above table, dichloro quinolinic acid, propanil and dimethyl tetrachloride compounding to Monochoria vaginalis have apparent synergistic effect, three Kind substance, which is applied in combination, can effectively reduce Pesticide use dosage.
Further, the effect for evaluation ternary composition compared to binary composition:Dichloro quinolinic acid and propanil are pressed According to proportioning 3:7 are combined as component A, by dichloro quinolinic acid and dimethyl tetrachloride according to proportioning 3:3 are combined as component B;By propanil and two First tetrachloro is according to proportioning 7:3 are combined as component C;Evaluate the combined effect of ternary composition.
2 complex composition of table is to Monochoria vaginalis Toxicity Determination
As seen from the above table, compared with binary combination, ternary composition is more apparent to Monochoria vaginalis synergistic effect.
Biological test two:Dichloro quinolinic acid, propanil and dimethyl tetrachloride compounding are to paddy field weed field efficacy.
Subjects:Rice terrace grassy weed and broad leaved weed:Barnyard grass, moleplant seed, Monochoria vaginalis, lady's-grass, etc..
Test medicine:Medicament 1:(dichloro quinolinic acid, propanil and dimethyl tetrachloride proportioning are 3 to 39% suspending agent:7:3);Medicament 2:(dichloro quinolinic acid, propanil and dimethyl tetrachloride proportioning are 3 to 56% wettable powder:9:2);Medicament 3:26% water dispersible granules (dichloro quinolinic acid, propanil and dimethyl tetrachloride proportioning are 5:5:And comparison medicament 3).
Test method:According to experimental plot area, weighed medicament, and be watered and be diluted, using backpack sprayer into Row cauline leaf is sprayed 1 time, fresh weight preventive effect after investigation 30 days, and the activity of weeding of more various medicaments, and observe medicament whether rice Crop generates key.Preventive effect (%)=[(clear water control group weeds fresh weight-processing group weeds fresh weight)/clear water group weeds fresh weight] * 100%.
2 dichloro quinolinic acid of table, propanil and dimethyl tetrachloride compounding are to paddy field weed field efficacy
As seen from the above table, compared with single dose, dichloro quinolinic acid, propanil and dimethyl tetrachloride compounding application can significantly improve it It to the control effect of grass family and broad leaved weed, has significant synergies, can effectively lower the administration dosage of pesticide, reduce Environmental pollution, to crop safety.
The above is only a preferred embodiment of the present invention, to those skilled in the art, this hair is not being departed from It under the premise of bright raw material, can be suitably modified, these are improved also within protection scope of the present invention.

Claims (8)

1. a kind of mixed herbicide containing dichloro quinolinic acid, propanil and dimethyl tetrachloride, it is characterised in that:Active constituent is by two chloroquines The weight ratio of quinoline acid, propanil and dimethyl tetrachloride composition, the dichloro quinolinic acid, propanil and dimethyl tetrachloride is 1-30:1-30:1- 10。
2. mixed herbicide according to claim 1, it is characterised in that:The dichloro quinolinic acid, propanil and dimethyl tetrachloride Weight ratio be 1-5:5-9:2-4.
3. according to the mixed herbicide described in claim 1-2, it is characterised in that:The dimethyl tetrachloride can be its sodium salt, ammonium salt, The form of diformazan ammonium salt.
4. according to the mixed herbicide described in claim 1-3, it is characterised in that:The dichloro quinolinic acid, propanil and diformazan four The total weight percentage composition of chlorine in the composition is 5-85%.
5. mixed herbicide according to claim 4, it is characterised in that:The dichloro quinolinic acid, propanil and dimethyl tetrachloride Total weight percentage composition in the composition is 25-75%.
6. according to the mixed herbicide described in claim 1-5, it is characterised in that:Combination dosage form can be wettable powder, breast One kind in oil, suspending agent, oil-suspending agent, microemulsion, aqueous emulsion, suspended emulsion, water dispersible granules etc..
7. the mixed herbicide according to claim 1-6 is used to prevent and kill off the purposes of paddy field weed.
8. purposes according to claim 7, it is characterised in that:The weeds are preferably grass family and broad leaved weed.
CN201810572370.0A 2018-06-06 2018-06-06 A kind of mixed herbicide and its application containing dichloro quinolinic acid, propanil and dimethyl tetrachloride Withdrawn CN108576004A (en)

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CN201810572370.0A CN108576004A (en) 2018-06-06 2018-06-06 A kind of mixed herbicide and its application containing dichloro quinolinic acid, propanil and dimethyl tetrachloride

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109452285A (en) * 2018-11-01 2019-03-12 安徽远景作物保护有限公司 A kind of Herbicidal combinations and its application containing propanil

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109452285A (en) * 2018-11-01 2019-03-12 安徽远景作物保护有限公司 A kind of Herbicidal combinations and its application containing propanil

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Application publication date: 20180928