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CN1083767A - Be used for the Electric radiant Heating Film of Plastic Welding and manufacturing thereof and with the method for its welding plastic - Google Patents

Be used for the Electric radiant Heating Film of Plastic Welding and manufacturing thereof and with the method for its welding plastic Download PDF

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CN1083767A
CN1083767A CN 93106765 CN93106765A CN1083767A CN 1083767 A CN1083767 A CN 1083767A CN 93106765 CN93106765 CN 93106765 CN 93106765 A CN93106765 A CN 93106765A CN 1083767 A CN1083767 A CN 1083767A
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welding
plastic
electric heating
heating film
welded
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益小苏
吴国章
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Zhejiang University ZJU
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Abstract

焊接塑料的电热膜,是塑料基体和导电填料混合 物,填料取炭黑或金属粉末;或取碳纤维或金属纤维; 或是上述填料互混物。制造电热膜,先将基体与填料 混合,然后挤出、注塑或压延成与焊接面匹配的电热 膜;或直接挤出、注塑在待焊面上形成电热膜。使用 上述电热膜对塑料件焊接,是对电热膜通电并施加一 定压力,电热膜发热达到塑料焊接温度,使电热膜与 塑料件焊接面充分融合,切断电源冷却后,便完成焊 接过程。

The electrothermal film for welding plastics is a mixture of plastic matrix and conductive filler. The filler is carbon black or metal powder; or carbon fiber or metal fiber; or a mixture of the above fillers. To manufacture the electric heating film, first mix the matrix with the filler, and then extrude, inject or calender it into an electric heating film that matches the welding surface; or directly extrude and injection mold it on the surface to be welded to form an electric heating film. Using the above-mentioned electric heating film to weld plastic parts is to energize the electric heating film and apply a certain pressure. The electric heating film heats up to the plastic welding temperature, so that the electric heating film and the welding surface of the plastic part are fully fused. After the power is cut off and cooled, the welding process is completed.

Description

本发明属于用作塑料焊接,具体涉及塑料焊接的构件及其制造和应用方法。The invention belongs to plastic welding, and in particular relates to a component for plastic welding and its manufacturing and application method.

塑料制品以其价廉物美,加工方法简单,而在日常生活、建筑、航空航天等各方面得到越来越广泛的应用。如何连接材料使之满足制品使用性能的要求,并且操作简单,费用低廉一直是关键性问题。实践表明,除了机械紧固和粘接等连接手段外,焊接是一种高质量、高效率的塑料连接技术。目前,塑料的焊接方法很多,一般可划分为热焊接、摩擦焊接和电磁焊接三大类。其中属电磁焊接的电热丝焊接又称电熔焊,工业上应用始于八十年代初,由于施工操作简单,现场设备轻便,焊接速度快(一般<20秒),可焊接大而复杂的制品,这种焊接方法很快得到发展和推广。其基本原理是:将高电阻金属丝预先嵌入塑料的待焊平面或特制的塑料套筒内壁,通电后,电热丝发热使周围的塑料升温熔化并彼此融合。这种焊接技术已被许多国家用于小口径送气管道、下水管的焊接和修复,效果较好。但是电熔焊存在不少缺点:1)主要是成本昂贵,电热丝嵌入塑料内的注塑工艺和模具相当复杂,必然导至待焊件制作费用高昂;2)当塑料熔化并发生少量流动时,紧密排列的电热丝彼此搭接引起短路也常常使焊接失败;3)焊接完成后,电热丝残留在焊缝,一方面影响性能,另一方面造成不必要的合金材料浪费。Plastic products are used more and more widely in daily life, construction, aerospace and other aspects because of their low price, high quality and simple processing methods. How to connect materials to meet the performance requirements of the product, and the operation is simple and the cost is low has always been a key issue. Practice has shown that, in addition to mechanical fastening and bonding and other connection methods, welding is a high-quality, high-efficiency plastic connection technology. At present, there are many welding methods for plastics, which can generally be divided into three categories: thermal welding, friction welding and electromagnetic welding. Among them, electric heating wire welding, which belongs to electromagnetic welding, is also called electric fusion welding. Its industrial application began in the early 1980s. Due to the simple construction operation, light field equipment, and fast welding speed (generally <20 seconds), large and complex products can be welded. , this welding method was quickly developed and promoted. The basic principle is: pre-embed the high-resistance metal wire into the plastic surface to be welded or the inner wall of a special plastic sleeve. After the power is turned on, the electric heating wire heats up and melts the surrounding plastic and fuses with each other. This welding technology has been used in many countries for the welding and repair of small-diameter air supply pipes and sewer pipes, and the effect is good. However, there are many disadvantages in electrofusion welding: 1) the main reason is that the cost is high, and the injection molding process and mold of the heating wire embedded in the plastic are quite complicated, which will inevitably lead to high production costs of the parts to be welded; 2) when the plastic melts and a small amount of flow occurs, Closely arranged heating wires overlap each other to cause short circuit and often cause welding failure; 3) After welding, the heating wire remains in the weld seam, which affects performance on the one hand, and causes unnecessary waste of alloy materials on the other hand.

本发明的任务是提供一种用于塑料焊接的电热膜及其制作和焊接使用方法,用其焊接待焊塑料制品,可简化待焊件的制作工艺,降低 成本,同时避免电热丝短路等不良现象。The task of the present invention is to provide a kind of electrothermal film for plastic welding and its production and welding use method, welding plastic products to be welded with it, can simplify the manufacturing process of the parts to be welded, reduce Cost, while avoiding the short circuit of the heating wire and other bad phenomena.

本发明的电热膜是一种复合型材料,是由塑料基体和导电填料两种成分组成的混合物。塑料基体取与待焊塑料制品相同的塑料或是与待焊件具有良好焊接性能的另一种塑料,导电填料取粒径小于0.3μm的碳黑、或金属及其合金粉末;或取长径比大于21~30的碳纤维或石墨纤维或金属及其合金纤维或是上述导体填料的互混物。The electrothermal film of the present invention is a composite material, which is a mixture composed of a plastic matrix and a conductive filler. The plastic matrix is made of the same plastic as the plastic product to be welded or another plastic with good welding performance with the piece to be welded. The conductive filler is made of carbon black with a particle size of less than 0.3 μm, or metal and its alloy powder; or the long diameter Carbon fiber or graphite fiber or metal and its alloy fiber with a ratio greater than 21-30 or a mixture of the above-mentioned conductor fillers.

上述复合型电热膜具有下列性能:The above composite electric heating film has the following properties:

1.与待焊件有良好的焊接效果,由此选定基体种类;1. It has a good welding effect with the parts to be welded, so the type of substrate is selected;

2.具有良好的导电性能;2. Has good electrical conductivity;

3.具有良好的机械性能,因电热膜留在焊缝中,其机械性能常决定焊接强度;3. Has good mechanical properties, because the electrothermal film remains in the weld, its mechanical properties often determine the welding strength;

4.电阻率在室温到熔融温度区内不能有过强的正温度系数效应(即PTC效应)。4. The resistivity cannot have too strong positive temperature coefficient effect (ie PTC effect) in the range from room temperature to melting temperature.

由后三条可选定导电填料的种类和含量。导电填料在复合型电热膜中的重量含量一般在10~60%之间。若含量<10%,则导电性能太差,电热膜输入功率过低,焊接速度过慢;而若含量>60%,则电热膜机械性能太低,影响焊接强度,故电热膜配方需统筹兼顾。在电热膜两端分别设置一个电极,以接通电源。The type and content of conductive filler can be selected from the last three items. The weight content of the conductive filler in the composite electrothermal film is generally between 10% and 60%. If the content is less than 10%, the electrical conductivity is too poor, the input power of the electric heating film is too low, and the welding speed is too slow; and if the content is more than 60%, the mechanical properties of the electric heating film are too low, which affects the welding strength, so the electric heating film formula needs to be overall considered . An electrode is respectively arranged at both ends of the electrothermal film to connect the power supply.

上述复合型电热膜的制造方法:The manufacture method of above-mentioned composite electrothermal film:

首先将塑料基体与导电填料均匀混合,然后将混合物通过挤出、注塑或压延成与待焊塑料制品的焊接面相匹配的电热膜;或将混合料直接挤出或注塑在待焊面上形成电热膜。在塑料基体与导电填料混合前可以先将导电填料进行硅烷或酞酸酯等偶联剂处理。First, the plastic matrix and conductive filler are uniformly mixed, and then the mixture is extruded, injected or calendered to form an electric heating film that matches the welding surface of the plastic product to be welded; or the mixture is directly extruded or injected on the surface to be welded to form an electric heating film membrane. Before the plastic matrix is mixed with the conductive filler, the conductive filler can be treated with a coupling agent such as silane or phthalate.

使用复合型电热膜焊接塑料制品的方法:The method of welding plastic products with composite electric heating film:

焊接时向电热膜两端电极接通电源,电热膜迅速发热,使被焊塑 料制品达到材料焊接温度,再加一定压力P,经加压通电一定时间后,电热膜两面与被焊塑料制品的焊接面充分融合,然后切断电源,焊接区冷却后,焊接过程便告完成。When welding, connect the power supply to the electrodes at both ends of the electric heating film, and the electric heating film will heat up rapidly, so that the plastic to be welded When the material product reaches the welding temperature of the material, add a certain pressure P. After a certain period of time, the two sides of the electric heating film and the welding surface of the plastic product to be welded are fully fused, and then the power supply is cut off. After the welding area cools down, the welding process is completed.

本发明与对比技术比较具有明显效果:Compared with the contrast technology, the present invention has obvious effect:

本发明不仅兼有电熔焊的各种长处,而且电热膜的制作远没有电热丝嵌入塑料中那么复杂,因而生产成本低廉;同时在焊接过程中不会出现电热丝短路等问题,焊接的安全可靠性得以提高;利用本发明焊接的塑料制品的机械强度较高,其拉伸强度一般约为母体塑料的0.8,甚至可达0.9以上,这也是电热丝焊接所不及。The invention not only has various advantages of electric fusion welding, but also the production of electric heating film is far less complicated than that of electric heating wire embedded in plastic, so the production cost is low; at the same time, problems such as short circuit of electric heating wire will not occur in the welding process, and the safety of welding The reliability is improved; the mechanical strength of the plastic products welded by the present invention is relatively high, and its tensile strength is generally about 0.8 of the parent plastic, even up to 0.9, which is also inferior to that of electric heating wire welding.

图面说明:Graphic description:

图1为应用本发明进行对接焊接的示意图;Fig. 1 is the schematic diagram that applies the present invention to carry out butt welding;

图2为应用本发明进行搭接焊接的示意图。Fig. 2 is a schematic diagram of applying the present invention for lap welding.

参照附图说明发明的实施例:Embodiments of the invention are described with reference to the accompanying drawings:

例1:如图1所示,待焊件1的对接面处设置本发明的电热膜2。Example 1: As shown in FIG. 1 , the electrothermal film 2 of the present invention is arranged on the butt joint surface of the workpiece 1 to be welded.

焊接条件:Welding conditions:

输入电热膜的电压V=150V;Input the electric heating film voltage V=150V;

对焊接面加压力P为1.5~3.0kg/cm2(用手轻压);The pressure P on the welding surface is 1.5~3.0kg/cm 2 (press lightly by hand);

通电加压时间30秒。The power-on pressurization time is 30 seconds.

焊接性能:Welding performance:

对接拉伸强度25.0MPa;Butt tensile strength 25.0MPa;

母材拉伸强度28.8MPa;Base metal tensile strength 28.8MPa;

焊接强度因子0.87。The welding strength factor is 0.87.

例2:如图2所示被焊塑料件1搭接,在搭接面处设置本发明的电热膜。Example 2: As shown in Figure 2, plastic parts 1 to be welded are overlapped, and the electrothermal film of the present invention is arranged at the overlapping surface.

焊接条件:Welding conditions:

输入电压150V;Input voltage 150V;

对搭接面施加压力P1.5~3.0kg/cm2;Apply pressure P1.5~3.0kg/cm 2 to the overlapping surface;

加压通电时间30秒。Pressurization and energization time is 30 seconds.

焊接后对搭接面进行剪切破坏试验,发现并非搭接处断裂,而是在其中一个试样条上断开。After welding, the shear failure test was carried out on the lap joints, and it was found that the lap joints were not fractured, but were broken on one of the sample strips.

从上述二实施例可知,采用本发成焊接塑料制品具有较高焊接强度,能满足复杂的工程技术要求。It can be seen from the above two embodiments that the welded plastic products produced by the present invention have higher welding strength and can meet complex engineering technical requirements.

Claims (3)

1、一种用于塑料焊接的电热膜,其特征是由塑料基体和导电填料两种成分组成的混合物,塑料基体取与待焊塑料制品相同的塑料或是与待焊件具有良好焊接性能的另一种塑料,导电填料取粒径小于0.3μm的碳黑,或金属及其合金粉末;或取长径比大于20~30的碳纤维或石墨纤维或金属及其合金纤维;或是上述导电填料的互混物,导电填料在总的混合物中的重量含量为10~60%,在电热膜两端分别设置电极。1. An electric heating film for plastic welding, which is characterized by a mixture of plastic matrix and conductive filler. The plastic matrix is made of the same plastic as the plastic product to be welded or has good welding performance with the piece to be welded. Another kind of plastic, the conductive filler is carbon black with a particle size of less than 0.3 μm, or metal and its alloy powder; or carbon fiber or graphite fiber or metal and its alloy fiber with an aspect ratio greater than 20-30; or the above-mentioned conductive filler The weight content of the conductive filler in the total mixture is 10-60%, and electrodes are respectively arranged at both ends of the electrothermal film. 2、一种用于塑料焊接的电热膜的制造方法:2. A method of manufacturing an electric heating film for plastic welding: (1)将塑料基体与导电填料均匀混合;(1) Evenly mix the plastic matrix with the conductive filler; (2)将均匀混合物通过挤出、注塑或压延形成与待焊塑料制品的焊接面相匹配的电热膜;或将混合料直接挤出或注塑在待焊面上形成电热膜。(2) Extrude, inject or calender the homogeneous mixture to form an electric heating film that matches the welding surface of the plastic product to be welded; or directly extrude or inject the mixture on the surface to be welded to form an electric heating film. 3、一种用电热膜焊接塑料的方法:在焊接塑料制品时,向电热膜两端电极接通电源,电热膜迅速发热,使被焊塑料件达到材料焊接温度,在加一定压力下,使电热膜两面分别与塑料制品焊接面充分融合,然后切断电源,焊接区冷却后,焊接过程完成。3. A method of welding plastics with electric heating film: when welding plastic products, connect the power supply to the electrodes at both ends of the electric heating film, and the electric heating film will heat up rapidly, so that the plastic parts to be welded reach the material welding temperature. The two sides of the electric heating film are fully fused with the welding surface of the plastic product, and then the power supply is cut off. After the welding area cools down, the welding process is completed.
CN 93106765 1993-06-03 1993-06-03 Be used for the Electric radiant Heating Film of Plastic Welding and manufacturing thereof and with the method for its welding plastic Pending CN1083767A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100398261C (en) * 2001-04-24 2008-07-02 应用材料有限公司 Conductive Polishing Parts for Electrochemical Mechanical Polishing
CN105383051A (en) * 2015-12-01 2016-03-09 芜湖成德龙过滤设备有限公司 Plastic welding method
CN105729791A (en) * 2016-03-10 2016-07-06 中国民航大学 Thermoplastic composite material joint connecting method
CN105965996A (en) * 2016-04-11 2016-09-28 山东利普索航空科技有限公司 Self-repairing multifunctional composite material structure
CN114919197A (en) * 2022-05-13 2022-08-19 北京航空航天大学 Resistance welding system and welding method for carbon fiber/polyaryletherketone composite material laminate

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100398261C (en) * 2001-04-24 2008-07-02 应用材料有限公司 Conductive Polishing Parts for Electrochemical Mechanical Polishing
CN105383051A (en) * 2015-12-01 2016-03-09 芜湖成德龙过滤设备有限公司 Plastic welding method
CN105729791A (en) * 2016-03-10 2016-07-06 中国民航大学 Thermoplastic composite material joint connecting method
CN105965996A (en) * 2016-04-11 2016-09-28 山东利普索航空科技有限公司 Self-repairing multifunctional composite material structure
CN105965996B (en) * 2016-04-11 2018-02-13 山东利普索航空科技有限公司 A kind of selfreparing multifunctional composite structure
CN114919197A (en) * 2022-05-13 2022-08-19 北京航空航天大学 Resistance welding system and welding method for carbon fiber/polyaryletherketone composite material laminate

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