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CN1083474C - Improved Zeotropic Working Medium Used in Thermodynamic Cycles - Google Patents

Improved Zeotropic Working Medium Used in Thermodynamic Cycles Download PDF

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CN1083474C
CN1083474C CN95117074A CN95117074A CN1083474C CN 1083474 C CN1083474 C CN 1083474C CN 95117074 A CN95117074 A CN 95117074A CN 95117074 A CN95117074 A CN 95117074A CN 1083474 C CN1083474 C CN 1083474C
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azeotropic working
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顾雏军
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Abstract

The present invention provides a series of non-azeotropic working media containing two or more than two components for thermodynamic circulation system, and is characterized by that it can have large-scale energy-saving effect, at the same time it is applicable to four working temp. regions of refrigeration, air-conditioner, heat pump and thermal fluid power generation, and in the actual application it only has need of making small change or no change on refrigeration, air-conditioner, heat pump and thermal fluid power generation equipment. The refrigerant can save energy by 15 to 25 percent in an air conditioning device, 15 to 30 percent in a refrigerating device, 15 to 30 percent in a heat pump device and more than 20 percent of energy utilization rate in a hot fluid power generation device.

Description

在热力循环中使用的改进的非共沸工作介质Improved Zeotropic Working Medium Used in Thermodynamic Cycles

这项发明涉及到热力循环系统有关的工作介质，特别是，它涉及到一类非共沸的、有用的混合物，例如，在逆循环装置中，有更高的性能系数COP[COP定义为从周围环境中净排出能量率(就制冷而言)或净输出能量率(就加热而言)与总输入能量之比，表示为一个恒定的单位和比率条件]，在正循环装置中，有更高的做功效率。This invention relates to working media related to thermodynamic cycle systems, and in particular, it relates to a class of non-azeotropic, useful mixtures, for example, in reverse cycle devices, having a higher coefficient of performance COP [COP is defined as from The ratio of the net output energy rate (for cooling) or net output energy rate (for heating) to the total input energy in the surrounding environment, expressed as a constant unit and ratio condition], in a positive cycle device, there is more High working efficiency.

目前在商业和工业上，用于热力循环系统中的工作介质通常是一些纯组份，或者是共沸的和非共沸的工作介质。At present, in commerce and industry, the working medium used in the thermal cycle system is usually some pure components, or azeotropic and non-azeotropic working medium.

许多这样的混合物已经公布于世，例如，下列参考文献：Many such mixtures have been published, for example, the following references:

1.美国专利2,641,580，题为“1，1-四氟乙烷和一氯五氟乙烷共沸制冷剂的组成”，发明人：Lewis，专利批准日：1953年6月9日。1. US Patent No. 2,641,580, titled "Composition of 1,1-tetrafluoroethane and chloropentafluoroethane azeotropic refrigerant", inventor: Lewis, date of patent approval: June 9, 1953.

2.美国专利3,203,194，题为“制冷压缩过程”，发明人：Fuderer，专利批准日：1965年8月31日。2. US Patent 3,203,194, titled "Refrigeration Compression Process", inventor: Fuderer, date of patent approval: August 31, 1965.

3.美国专利4,303,536，题为“包含一氯四氟甲烷非共沸制冷剂组成及使用方法”，发明人：Orfeo等，专利批准日：1981年12月1日。3. US Patent No. 4,303,536, titled "Composition and Application of Zeotropic Refrigerants Containing Chlorotetrafluoromethane", inventor: Orfeo et al., date of patent approval: December 1, 1981.

4.美国专利4,603,002，题为“用于冷冻及储存产品上的方法及制冷介质”，发明人：Nikolsky等，专利批准日：1986年7月29日。4. US Patent 4,603,002, titled "Method and Refrigeration Medium for Freezing and Storing Products", inventor: Nikolsky et al., patent approval date: July 29, 1986.

5.日本专利52-70466，题为“低沸点制冷剂的组成”，发明人：Kokai，1977年发表于DaKogyo KK。5. Japanese Patent 52-70466, titled "Composition of Low Boiling Point Refrigerants", inventor: Kokai, published in DaKogyo KK in 1977.

6.“制冷和空调”，作者：B.C.Langly，1982年第二版。6. "Refrigeration and Air Conditioning," by B.C. Langly, second edition, 1982.

7.法国专利2,130,556(VEB Monsator Haushait grossgeratekombinat)。7. French patent 2,130,556 (VEB Monsator Haushait grossgeratekombinat).

8.法国专利2,177,785(VEB Monsator Haushait grossgeratekombinat)。8. French patent 2,177,785 (VEB Monsator Haushait grossgeratekombinat).

9.法国专利2,607,144(Institute Francaise du Petrole)。9. French patent 2,607,144 (Institute Francaise du Petrole).

10.“氟氯碳及其替代物”，作者：M.F.Bouzianis(ArthurD.Little，1988年)。10. "Clorofluorocarbons and their alternatives", by M.F. Bouzianis (Arthur D. Little, 1988).

11.“以后市场汽车空调用的制冷剂混合物”，作者：D.J.Bateman等，SAE系列技术论文900216(SAE国际会议及展览会一底特律，密执安，1990年2月26日-3月2日)。11. "Refrigerant Mixtures for Automotive Air Conditioning in Future Markets", Author: D.J.Bateman et al., SAE Series Technical Paper 900216 (SAE International Conference and Exhibition - Detroit, Michigan, February 26-March 2, 1990 ).

12.“ASHRAE供热、通风、空调及制冷术语汇编”，第二版(美国供热、制冷及空调工程师协会，1991年)。12. "ASHRAE Glossary of Heating, Ventilating, Air-Conditioning, and Refrigeration Terms," Second Edition (American Society of Heating, Refrigerating, and Air-Conditioning Engineers, 1991).

在基本相同循环外部条件下，与一纯的工作介质或者一共沸的工作介质相比较，非共沸混合物(如果是优秀的)是这样一种有优点的工作介质，其优点是：在等压蒸发过程中吸更多的热，在等压冷凝过程中放更多的热，在膨胀过程中做更多的功或者在压缩过程中做更少的功，也就是说，在逆循环装置中，有更高的性能系数COP，在正循环装置中，有更高的做功效率Under basically the same external conditions of the cycle, compared with a pure working medium or an azeotropic working medium, the non-azeotropic mixture (if it is excellent) is such an advantageous working medium, and its advantages are: absorbs more heat during evaporation, releases more heat during isobaric condensation, and does more work during expansion or less work during compression, that is, in a reverse cycle device , has a higher coefficient of performance COP, and in a positive cycle device, has a higher work efficiency

但是每一种制冷剂都有一定的局限性，对于不同的蒸发温度区域和冷凝温度区域，不可能有一种混合制冷剂会同时适用，因此必须寻找更多种制冷剂。另外，在这些在先专利中所介绍的制冷剂用在制冷和空调设备中，节能效果都不很大，一般为5％-10％。另外，这些在先的制冷剂往往要求对原制冷和空调设备作较多的改造，这将给实际应用和推广带来困难。However, each refrigerant has certain limitations. For different evaporation temperature regions and condensation temperature regions, it is impossible to have a mixed refrigerant that is suitable at the same time, so more refrigerants must be found. In addition, when the refrigerants introduced in these prior patents are used in refrigeration and air-conditioning equipment, the energy saving effect is not very great, generally 5%-10%. In addition, these prior refrigerants often require more modifications to the original refrigeration and air-conditioning equipment, which will bring difficulties to practical application and promotion.

本发明提供了一系列含有两种或两种以上组份的热力循环系统的非共沸工作介质，它的特征是：能有较大比例的节能效果，同时适用于制冷、空调、热泵、热流体发电四种工作温度区域，而且在实际应用中只需对制冷、空调、热泵、热流体发电装置进行较小的改动或不做改动的非共沸混合制冷剂。这种制冷剂在空调装置中可节能15％-25％，在制冷装置中可节能15％-30％，在热泵装置中可节能15％-30％，在热流体发电装置中可提高能量利用率20％以上。The invention provides a series of non-azeotropic working mediums of thermodynamic cycle systems containing two or more components, which are characterized in that they can have a large proportion of energy-saving effects, and are also suitable for refrigeration, air conditioning, heat pumps, heat Fluid power generation has four operating temperature regions, and in practical applications, it only needs to make minor changes to refrigeration, air conditioning, heat pumps, thermal fluid power generation devices or non-azeotropic mixed refrigerants without modification. This refrigerant can save energy by 15%-25% in air-conditioning devices, 15%-30% in refrigeration devices, 15%-30% in heat pump devices, and improve energy utilization in thermal fluid power generation devices The rate is more than 20%.

图1表示了一种使用本发明的非共沸工作介质的制冷单元。Figure 1 shows a refrigeration unit using the zeotropic working medium of the present invention.

图2表示了一种使用图1的那种制冷单元所制造的空调装置最主要组件的装置的描述。FIG. 2 presents a plant depiction of the most essential components of an air-conditioning unit manufactured using a refrigeration unit of the type shown in FIG. 1 .

参看图1所显示的制冷单元，本发明中的工作介质在如下的一个循环系统中循环，循环方向如图中15处的箭头所指的方向，流体由压缩机20按15处的指向流向冷凝器30，然后是节流阀40，然后是蒸发器50，然后流回压缩机20，冷凝器30和一个换热器相连，并通过这个换热器把热量传递给另外一个装置，比如冷却塔60。蒸发器50向一个指定的控制空间供冷，以除去此空间的热量或者它通过一个热交换器向一个低温流体70供应冷量。Referring to the refrigerating unit shown in Fig. 1, the working medium in the present invention circulates in the following circulation system, the circulation direction is the direction indicated by the arrow at 15 among the figures, and the fluid is directed to the condensation by the compressor 20 according to the direction at 15 The condenser 30, then the throttle valve 40, then the evaporator 50, and then flows back to the compressor 20, the condenser 30 is connected to a heat exchanger, and the heat is transferred to another device through this heat exchanger, such as a cooling tower 60. The evaporator 50 supplies cooling to a designated controlled space to remove heat from the space or it supplies cooling to a cryogenic fluid 70 through a heat exchanger.

参见图2，根据现在的发明所制造的一个空调系统，包括一个制冷单元140(显示在图1中的)和一个流体流线100，这个流线代表提供新鲜空气，包括一个再循环的控制回路105，由105回路提供的空气和110线提供的空气在混合器120中进行混合，经过130中的一个风扇和过滤器，然后到类似于图1所示的一个制冷装置140，然后再到加湿器150，然后通向一个分流装置170、180。170、180分流系统都分别供应各自的冷空气用户190。Referring to FIG. 2, an air conditioning system made according to the present invention includes a refrigeration unit 140 (shown in FIG. 1) and a fluid flow line 100 representing a control loop for supplying fresh air, including a recirculation 105, the air provided by the circuit 105 and the air provided by the line 110 are mixed in the mixer 120, pass through a fan and filter in 130, and then go to a refrigeration device 140 similar to that shown in Figure 1, and then to humidification 150, and then leads to a splitter 170, 180. The splitters 170, 180 each supply their respective cold air users 190.

本发明的工作介质可以用在热力工程上的压缩、冷凝、膨胀及蒸发循环系统中，如热泵装置、制冷装置、空调装置和热流体的发电装置，而不需要对这些系统作昂贵的修改。The working medium of the present invention can be used in compression, condensation, expansion and evaporation cycle systems in thermal engineering, such as heat pump devices, refrigeration devices, air conditioning devices and thermal fluid power generation devices, without requiring expensive modifications to these systems.

在本发明中所提到的杂质是指除指定组份物质以外的任何物质及其混合物。The impurity mentioned in the present invention refers to any substance and its mixture except the specified component substances.

可用于本发明的含有两种或两种以上组份的、用于热力系统的非共沸工作介质的具体构成如下：1.一种非共沸的工作介质，它的组份和重量浓度如下：Can be used for the specific composition of the non-azeotropic working medium that contains two or more components of the present invention and is used for thermodynamic system as follows: 1. a kind of non-azeotropic working medium, its composition and weight concentration are as follows :

组份                重量浓度Component Weight Concentration

CHClF2(R22)        0.40-0.999CHClF 2 (R22) 0.40-0.999

CH2＝CH-CH3(R1270)           0.001-0.60并允许含有最大浓度不超过20％的杂质。CH 2 =CH-CH 3 (R1270) 0.001-0.60 and allowed to contain impurities with a maximum concentration of no more than 20%.

2.一种非共沸的工作介质，它的组份和重量浓度如下：2. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                            重量浓度Component Weight Concentration

CHClF2(R22)                   0.04-0.99CHClF 2 (R22) 0.04-0.99

CH2＝CH-CH3(R1270)           0.001-0.30CH 2 =CH-CH 3 (R1270) 0.001-0.30

CH2F2(R32)                   0.001-0.95并允许含有最大浓度不超过20％的杂质。CH 2 F 2 (R32) 0.001-0.95 and allowed to contain impurities with a maximum concentration of no more than 20%.

3.一种非共沸的工作介质，它的组份和重量浓度如下：3. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                            重量浓度Component Weight Concentration

CHClF2(R22)                   0.04-0.99CHClF 2 (R22) 0.04-0.99

CH2＝CH-CH3(R1270)           0.001-0.3CH 2 =CH-CH 3 (R1270) 0.001-0.3

C2HF5(R125)                  0.001-0.95并允许含有最大浓度不超过20％的杂质。C 2 HF 5 (R125) 0.001-0.95 and allows the maximum concentration of impurities not exceeding 20%.

4.一种非共沸的工作介质，它的组份和重量浓度如下：4. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                            重量浓度Component Weight Concentration

CHClF2(R22)                   0.04-0.99CHClF 2 (R22) 0.04-0.99

CH2＝CH-CH3(R1270)           0.001-0.3CH 2 =CH-CH 3 (R1270) 0.001-0.3

CH3CF3(R143a)                0.001-0.95并允许含有最大浓度不超过20％的杂质。CH 3 CF 3 (R143a) 0.001-0.95 and allowed to contain impurities with a maximum concentration of no more than 20%.

5.一种非共沸的工作介质，它的组份和重量浓度如下：5. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                            重量浓度Component Weight Concentration

CHClF2(R22)                   0.04-0.99CHClF 2 (R22) 0.04-0.99

CH2＝CH-CH3(R1270)           0.001-0.3CH 2 =CH-CH 3 (R1270) 0.001-0.3

C2HF5(R125)                  0.001-0.95C 2 HF 5 (R125) 0.001-0.95

CH2F2(R32)                   0.001-0.95并允许含有最大浓度不超过20％的杂质。CH 2 F 2 (R32) 0.001-0.95 and allowed to contain impurities with a maximum concentration of no more than 20%.

6.一种非共沸的工作介质，它的组份和重量浓度如下：6. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                     重量浓度Component Weight Concentration

CHClF2(R22)            0.04-0.99CHClF 2 (R22) 0.04-0.99

CH2＝CH-CH3(R1270)    0.001-0.3CH 2 =CH-CH 3 (R1270) 0.001-0.3

CH3CF3(R143a)         0.001-0.95CH 3 CF 3 (R143a) 0.001-0.95

CH2F2(R32)            0.001-0.95并允许含有最大浓度不超过20％的杂质。CH 2 F 2 (R32) 0.001-0.95 and allowed to contain impurities with a maximum concentration of no more than 20%.

7.一种非共沸的工作介质，它的组份和重量浓度如下：7. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                     重量浓度Component Weight Concentration

CHClF2(R22)             0.04-0.99CHClF 2 (R22) 0.04-0.99

CH2＝CH-CH3(R1270)     0.001-0.3CH 2 =CH-CH 3 (R1270) 0.001-0.3

CH3CF3(R143a)          0.001-0.95CH 3 CF 3 (R143a) 0.001-0.95

C2HF5(R125)            0.001-0.95并允许含有最大浓度不超过20％的杂质。C 2 HF 5 (R125) 0.001-0.95 and allows the maximum concentration of impurities not exceeding 20%.

8.一种非共沸的工作介质，它的组份和重量浓度如下：8. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                      重量浓度Component Weight Concentration

CHClF2(R22)             0.04-0.99CHClF 2 (R22) 0.04-0.99

CH3CFCl2(R141b)        0.001-0.95CH 3 CFCl 2 (R141b) 0.001-0.95

CH2＝CH-CH3(R1270)     0.001-0.3并允许含有最大浓度不超过20％的杂质。CH 2 =CH-CH 3 (R1270) 0.001-0.3 and allowed to contain impurities with a maximum concentration of no more than 20%.

9.一种非共沸的工作介质，它的组份和重量浓度如下：9. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                      重量浓度Component Weight Concentration

CHClF2(R22)             0.04-0.99CHClF 2 (R22) 0.04-0.99

CH2＝CH-CH3(R1270)     0.001-0.3CH 2 =CH-CH 3 (R1270) 0.001-0.3

CHF2Br(R22B1)           0.001-0.95并允许含有最大浓度不超过20％的杂质。CHF 2 Br(R22B1) 0.001-0.95 and allows the maximum concentration of impurities not exceeding 20%.

10.一种非共沸的工作介质，它的组份和重量浓度如下：10. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                     重量浓度Component Weight Concentration

CHClF2(R22)            0.04-0.99CHClF 2 (R22) 0.04-0.99

CH2＝CH-CH3(R1270)    0.001-0.3CH 2 =CH-CH 3 (R1270) 0.001-0.3

C3F6(R1216)           0.001-0.95并允许含有最大浓度不超过20％的杂质。C 3 F 6 (R1216) 0.001-0.95 and allowed to contain impurities with a maximum concentration of no more than 20%.

11.一种非共沸的工作介质，它的组份和重量浓度如下：11. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                     重量浓度Component Weight Concentration

CHClF2(R22)            0.04-0.99CHClF 2 (R22) 0.04-0.99

CH2＝CH-CH3(R1270)    0.001-0.3CH 2 =CH-CH 3 (R1270) 0.001-0.3

C3HF5(R1225)          0.001-0.95并允许含有最大浓度不超过20％的杂质。C 3 HF 5 (R1225) 0.001-0.95 and allows the maximum concentration of impurities not exceeding 20%.

12.一种非共沸的工作介质，它的组份和重量浓度如下：12. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                    重量浓度Component Weight Concentration

CHClF2(R22)            0.04-0.99CHClF 2 (R22) 0.04-0.99

CH2＝CH-CH3(R1270)    0.001-0.3CH 2 =CH-CH 3 (R1270) 0.001-0.3

C3H3F3(R1243)        0.001-0.95并允许含有最大浓度不超过20％的杂质。C 3 H 3 F 3 (R1243) 0.001-0.95 and allows the maximum concentration of impurities not exceeding 20%.

13.一种非共沸的工作介质，它的组份和重量浓度如下：13. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                     重量浓度Component Weight Concentration

CHClF2(R22)            0.04-0.99CHClF 2 (R22) 0.04-0.99

CH2＝CH-CH3(R1270)    0.001-0.3CH 2 =CH-CH 3 (R1270) 0.001-0.3

CHF2CHF2(R134)         0.001-0.95并允许含有最大浓度不超过20％的杂质。CHF 2 CHF 2 (R134) 0.001-0.95 and allows the maximum concentration of impurities not exceeding 20%.

14.一种非共沸的工作介质，它的组份和重量浓度如下：14. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                      重量浓度Component Weight Concentration

CHClF2(R22)             0.40-0.99CHClF 2 (R22) 0.40-0.99

CH2＝CH-CH3(R1270)     0.001-0.3CH 2 =CH-CH 3 (R1270) 0.001-0.3

CF3CFH2(R134a)         0.001-0.95并允许含有最大浓度不超过20％的杂质。CF 3 CFH 2 (R134a) 0.001-0.95 and allows the maximum concentration of impurities not exceeding 20%.

15.一种非共沸的工作介质，它的组份和重量浓度如下：15. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                      重量浓度Component Weight Concentration

CHClF2(R22)             0.04-0.99CHClF 2 (R22) 0.04-0.99

CH2＝CH-CH3(R1270)     0.001-0.3CH 2 =CH-CH 3 (R1270) 0.001-0.3

C2H3F(R1141)           0.001-0.95并允许含有最大浓度不超过20％的杂质。C 2 H 3 F (R1141) 0.001-0.95 and allows the maximum concentration of impurities not exceeding 20%.

16.一种非共沸的工作介质，它的组份和重量浓度如下：16. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                     重量浓度Component Weight Concentration

CHClF2(R22)            0.04-0.99CHClF 2 (R22) 0.04-0.99

CH2＝CH-CH3(R1270)    0.001-0.3CH 2 =CH-CH 3 (R1270) 0.001-0.3

C2H2F2(R1132a)       0.001-0.95并允许含有最大浓度不超过20％的杂质。C 2 H 2 F 2 (R1132a) 0.001-0.95 and allows the maximum concentration of impurities not exceeding 20%.

17.一种非共沸的工作介质，它的组份和重量浓度如下：17. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                     重量浓度Component Weight Concentration

CHClF2(R22)            0.15-0.99CHClF 2 (R22) 0.15-0.99

CH3CHF2(R152a)        0.001-0.50CH 3 CHF 2 (R152a) 0.001-0.50

C2F4ClH(R124a)      0.001-0.70C 2 F 4 ClH(R124a) 0.001-0.70

CH3CClF2(R142b)     0.001-0.80并允许含有最大浓度不超过20％的杂质。CH 3 CClF 2 (R142b) 0.001-0.80 and allowed to contain impurities with a maximum concentration of no more than 20%.

18.一种非共沸的工作介质，它的组份和重量浓度如下：18. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                   重量浓度Component Weight Concentration

CHClF2(R22)          0.3-0.99CHClF 2 (R22) 0.3-0.99

CH3CHF2(R152a)      0.001-0.5CH 3 CHF 2 (R152a) 0.001-0.5

CF3CFH2(R134a)      0.001-0.5CF 3 CFH 2 (R134a) 0.001-0.5

C2F4C1H(R124a)      0.001-0.6并允许含有最大浓度不超过20％的杂质。C 2 F 4 C1H (R124a) 0.001-0.6 and allowed to contain impurities with a maximum concentration of no more than 20%.

19.一种非共沸的工作介质，它的组份和重量浓度如下：19. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                    重量浓度Component Weight Concentration

CHClF2(R22)            0.15-0.99CHClF 2 (R22) 0.15-0.99

CH3CHF2(R152a)       0.001-0.5CH 3 CHF 2 (R152a) 0.001-0.5

CH3CClF2(R142b)      0.001-0.7CH 3 CClF 2 (R142b) 0.001-0.7

C2H3FCl2(R141b)     0.001-0.8并允许含有最大浓度不超过20％的杂质。C 2 H 3 FCl 2 (R141b) 0.001-0.8 and allows the maximum concentration of impurities not exceeding 20%.

20.一种非共沸的工作介质，它的组份和重量浓度如下：20. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

CHClF2(R22)         0.2-0.99CHClF 2 (R22) 0.2-0.99

CH3CHF2(R152a)     0.001-0.6CH 3 CHF 2 (R152a) 0.001-0.6

C3F5H(R1225)       0.001-0.7并允许含有最大浓度不超过20％的杂质。C 3 F 5 H (R1225) 0.001-0.7 and allows the maximum concentration of impurities not exceeding 20%.

21.一种非共沸的工作介质，它的组份和重量浓度如下：21. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

CHClF2(R22)           0.15-0.99CHClF 2 (R22) 0.15-0.99

CH3CHF2(R152a)       0.001-0.6CH 3 CHF 2 (R152a) 0.001-0.6

C3F5H(R1225)         0.001-0.7C 3 F 5 H(R1225) 0.001-0.7

C2F4ClH(R124a)       0.001-0.8并允许含有最大浓度不超过20％的杂质。C 2 F 4 ClH (R124a) 0.001-0.8 and allowed to contain impurities with a maximum concentration of no more than 20%.

22.一种非共沸的工作介质，它的组份和重量浓度如下：22. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                    重量浓度Component Weight Concentration

CHClF2(R22)           0.19-0.99CHClF 2 (R22) 0.19-0.99

CH3CHF2(R152a)       0.001-0.6CH 3 CHF 2 (R152a) 0.001-0.6

C3H3F3(R1243)       0.001-0.8并允许含有最大浓度不超过20％的杂质。C 3 H 3 F 3 (R1243) 0.001-0.8 and allowed to contain impurities with a maximum concentration of no more than 20%.

23.一种非共沸的工作介质，它的组份和重量浓度如下：23. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                    重量浓度Component Weight Concentration

CHClF2(R22)            0.27-0.99CHClF 2 (R22) 0.27-0.99

CH3CHF2(R152a)       0.001-0.6CH 3 CHF 2 (R152a) 0.001-0.6

C3H3F3(R1243)       0.001-0.7C 3 H 3 F 3 (R1243) 0.001-0.7

C2F4ClH(R124a)       0.001-0.7并允许含有最大浓度不超过20％的杂质。C 2 F 4 ClH (R124a) 0.001-0.7 and allowed to contain impurities with a maximum concentration of no more than 20%.

24.一种非共沸的工作介质，它的组份和重量浓度如下：24. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

CHClF2(R22)         0.17-0.99CHClF 2 (R22) 0.17-0.99

CH3CHF2(R152a)     0.001-0.7CH 3 CHF 2 (R152a) 0.001-0.7

CF2BrH(R22B1)       0.001-0.7CF 2 BrH(R22B1) 0.001-0.7

CH3CClF2(R142b)    0.001-0.8并允许含有最大浓度不超过20％的杂质。CH 3 CClF 2 (R142b) 0.001-0.8 and allowed to contain impurities with a maximum concentration of no more than 20%.

25.一种非共沸的工作介质，它的组份和重量浓度如下：25. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份             重量浓度Component Weight Concentration

CHClF2(R22)       0.15-0.99CHClF 2 (R22) 0.15-0.99

CH3CHF2(R152a)   0.001-0.7CH 3 CHF 2 (R152a) 0.001-0.7

CF2BrH(R22B1)     0.001-0.7CF 2 BrH(R22B1) 0.001-0.7

C4F4ClH(R124a)   0.001-0.8并允许含有最大浓度不超过20％的杂质。C 4 F 4 ClH (R124a) 0.001-0.8 and allowed to contain impurities with a maximum concentration of no more than 20%.

26.一种非共沸的工作介质，它的组份和重量浓度如下：26. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份             重量浓度Component Weight Concentration

CHClF2(R22)         0.09-0.99CHClF 2 (R22) 0.09-0.99

CH3CHF2(R152a)     0.001-0.7CH 3 CHF 2 (R152a) 0.001-0.7

CH3CClF2(R142b)    0.001-0.2CH 3 CClF 2 (R142b) 0.001-0.2

C2F3ClH2(R133a)   0.001-0.9并允许含有最大浓度不超过20％的杂质。C 2 F 3 ClH 2 (R133a) 0.001-0.9 and allows the maximum concentration of impurities not exceeding 20%.

27.一种非共沸的工作介质，它的组份和重量浓度如下：27. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份             重量浓度Component Weight Concentration

CF2H2(R32)       0.01-0.9CF 2 H 2 (R32) 0.01-0.9

C2F5H(R125)      0.01-0.7C 2 F 5 H(R125) 0.01-0.7

CF3CH3(R143a)    0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 3 CH 3 (R143a) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

28.一种非共沸的工作介质，它的组份和重量浓度如下：28. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份             重量浓度Component Weight Concentration

CF2H2(R32)       0.01-0.9CF 2 H 2 (R32) 0.01-0.9

CF3CH3(R143a)    0.01-0.9CF 3 CH 3 (R143a) 0.01-0.9

CHClF2(R22)       0.01-0.95并允许含有最大浓度不超过20％的杂质。CHClF 2 (R22) 0.01-0.95 and allowed to contain impurities with a maximum concentration of no more than 20%.

29.一种非共沸的工作介质，它的组份和重量浓度如下：29. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                   重量浓度Component Weight Concentration

CF2H2(R32)          0.01-0.9CF 2 H 2 (R32) 0.01-0.9

C2F5H(R125)         0.001-0.9C 2 F 5 H(R125) 0.001-0.9

CH2＝CH-CH3(R1270)  0.01-0.7并允许含有最大浓度不超过20％的杂质。CH 2 =CH-CH 3 (R1270) 0.01-0.7 and allowed to contain impurities with a maximum concentration of no more than 20%.

30.一种非共沸的工作介质，它的组份和重量浓度如下：30. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                   重量浓度Component Weight Concentration

CF2H2(R32)          0.01-0.9CF 2 H 2 (R32) 0.01-0.9

C2F5H(R125)         0.01-0.9C 2 F 5 H(R125) 0.01-0.9

CF3CH3(R143a)       0.01-0.9CF 3 CH 3 (R143a) 0.01-0.9

CH2＝CH-CH3(R1270)  0.01-0.6并允许含有最大浓度不超过20％的杂质。CH 2 =CH-CH 3 (R1270) 0.01-0.6 and allowed to contain impurities with a maximum concentration of no more than 20%.

31.一种非共沸的工作介质，它的组份和重量浓度如下：31. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                   重量浓度Component Weight Concentration

CF2H2(R32)          0.01-0.9CF 2 H 2 (R32) 0.01-0.9

CF3CH3(R143a)       0.01-0.9CF 3 CH 3 (R143a) 0.01-0.9

CH2＝CH-CH3(R1270)  0.01-0.7并允许含有最大浓度不超过20％的杂质。CH 2 =CH-CH 3 (R1270) 0.01-0.7 and allowed to contain impurities with a maximum concentration of no more than 20%.

32.一种非共沸的工作介质，它的组份和重量浓度如下：32. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                   重量浓度Component Weight Concentration

CF2H2(R32)          0.01-0.9CF 2 H 2 (R32) 0.01-0.9

CF3CH3(R143a)       0.01-0.9CF 3 CH 3 (R143a) 0.01-0.9

CH2＝CH-CH3(R1270)  0.01-0.7CH 2 =CH-CH 3 (R1270) 0.01-0.7

CF3CFH2(R134a)      0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 3 CFH 2 (R134a) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

33.一种非共沸的工作介质，它的组份和重量浓度如下：33. A non-azeotropic working medium whose composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

CF2H2(R32)         0.01-0.9CF 2 H 2 (R32) 0.01-0.9

C2F5H(R125)        0.01-0.9C 2 F 5 H(R125) 0.01-0.9

CH2＝CH-CH3(R1270) 0.01-0.6CH 2 =CH-CH 3 (R1270) 0.01-0.6

CF3CFH2(R134a)     0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 3 CFH 2 (R134a) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

34.一种非共沸的工作介质，它的组份和重量浓度如下：34. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

C2F5H(R125)        0.01-0.9C 2 F 5 H(R125) 0.01-0.9

CF3CH3(R143a)      0.01-0.9CF 3 CH 3 (R143a) 0.01-0.9

CH2＝CH-CH3(R1270) 0.01-0.6CH 2 =CH-CH 3 (R1270) 0.01-0.6

CF3CFH2(R134a)     0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 3 CFH 2 (R134a) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

35.一种非共沸的工作介质，它的组份和重量浓度如下：35. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

CF2H2(R32)         0.01-0.9CF 2 H 2 (R32) 0.01-0.9

CF3CH3(R143a)      0.01-0.9CF 3 CH 3 (R143a) 0.01-0.9

CH2＝CH-CH3(R1270) 0.01-0.6CH 2 =CH-CH 3 (R1270) 0.01-0.6

CF2HCF2H(R134)     0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 2 HCF 2 H(R134) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

36.一种非共沸的工作介质，它的组份和重量浓度如下：36. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

CF2H2(R32)         0.01-0.9CF 2 H 2 (R32) 0.01-0.9

C2F5H(R125)        0.01-0.9C 2 F 5 H(R125) 0.01-0.9

CH2＝CH-CH3(R1270) 0.01-0.6CH 2 =CH-CH 3 (R1270) 0.01-0.6

CF2HCF2H(R134)     0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 2 HCF 2 H(R134) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

37.一种非共沸的工作介质，它的组份和重量浓度如下：37. A non-azeotropic working medium whose composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

C2F5H(R125)        0.01-0.9C 2 F 5 H(R125) 0.01-0.9

CF3CH3(R143a)      0.01-0.9CF 3 CH 3 (R143a) 0.01-0.9

CH2＝CH-CH3(R1270) 0.01-0.6CH 2 =CH-CH 3 (R1270) 0.01-0.6

CF2HCF2H(R134)     0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 2 HCF 2 H(R134) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

38.一种非共沸的工作介质，它的组份和重量浓度如下：38. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

C2F5H(R125)        0.01-0.9C 2 F 5 H(R125) 0.01-0.9

CH2＝CH-CH3(R1270) 0.01-0.7CH 2 =CH-CH 3 (R1270) 0.01-0.7

CF3CFH2(R134a)     0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 3 CFH 2 (R134a) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

39.一种非共沸的工作介质，它的组份和重量浓度如下：39. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

C2F5H(R125)        0.01-0.9C 2 F 5 H(R125) 0.01-0.9

CH2＝CH-CH3(R1270) 0.01-0.7CH 2 =CH-CH 3 (R1270) 0.01-0.7

CF2HCF2H(R134)     0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 2 HCF 2 H(R134) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

40.一种非共沸的工作介质，它的组份和重量浓度如下：40. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

CF3CH3(R143a)      0.01-0.9CF 3 CH 3 (R143a) 0.01-0.9

CH2＝CH-CH3(R1270) 0.01-0.7CH 2 =CH-CH 3 (R1270) 0.01-0.7

CF3CFH2(R134a)     0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 3 CFH 2 (R134a) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

41.一种非共沸的工作介质，它的组份和重量浓度如下：41. A non-azeotropic working medium whose composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

CF3CH3(R143a)      0.01-0.9CF 3 CH 3 (R143a) 0.01-0.9

CH2＝CH-CH3(R1270) 0.01-0.7CH 2 =CH-CH 3 (R1270) 0.01-0.7

CF2HCF2H(R134)     0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 2 HCF 2 H(R134) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

42.一种非共沸的工作介质，它的组份和重量浓度如下：42. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

C2F5H(R125)        0.01-0.9C 2 F 5 H(R125) 0.01-0.9

CH2＝CH-CH3(R1270) 0.01-0.6CH 2 =CH-CH 3 (R1270) 0.01-0.6

CF2BrH(R22B1)       0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 2 BrH (R22B1) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

43.一种非共沸的工作介质，它的组份和重量浓度如下：43. A non-azeotropic working medium whose composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

C2F5H(R125)         0.01-0.9C 2 F 5 H(R125) 0.01-0.9

CH2＝CH-CH3(R1270)  0.01-0.6CH 2 =CH-CH 3 (R1270) 0.01-0.6

C3H3F3(R1243)      0.01-0.9并允许含有最大浓度不超过20％的杂质。C 3 H 3 F 3 (R1243) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

44.一种非共沸的工作介质，它的组份和重量浓度如下：44. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

C2F5H(R125)        0.01-0.9C 2 F 5 H(R125) 0.01-0.9

CH2＝CH-CH3(R1270) 0.01-0.6CH 2 =CH-CH 3 (R1270) 0.01-0.6

C3F5H(R1225)       0.01-0.9并允许含有最大浓度不超过20％的杂质。C 3 F 5 H (R1225) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

45.一种非共沸的工作介质，它的组份和重量浓度如下：45. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

CF3CH3(R143a)      0.01-0.9CF 3 CH 3 (R143a) 0.01-0.9

CH2＝CH-CH3(R1270) 0.01-0.6CH 2 =CH-CH 3 (R1270) 0.01-0.6

CF2BrH(R22B1)       0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 2 BrH (R22B1) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

46.一种非共沸的工作介质，它的组份和重量浓度如下：46. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

CF3CH3(R143a)      0.01-0.9CF 3 CH 3 (R143a) 0.01-0.9

CH2＝CH-CH3(R1270) 0.01-0.6CH 2 =CH-CH 3 (R1270) 0.01-0.6

C3F5H(R1225)       0.01-0.9并允许含有最大浓度不超过20％的杂质。C 3 F 5 H (R1225) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

47.一种非共沸的工作介质，它的组份和重量浓度如下：47. A non-azeotropic working medium whose composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

CF3CH3(R143a)       0.01-0.9CF 3 CH 3 (R143a) 0.01-0.9

CH2＝CH-CH3(R1270)  0.01-0.6CH 2 =CH-CH 3 (R1270) 0.01-0.6

C3H3F3(R1243)      0.01-0.9并允许含有最大浓度不超过20％的杂质。C 3 H 3 F 3 (R1243) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

48.一种非共沸的工作介质，它的组份和重量浓度如下：48. A non-azeotropic working medium whose composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

CF3CH3(R143a)      0.01-0.9CF 3 CH 3 (R143a) 0.01-0.9

C3H8(R290)         0.01-0.6C 3 H 8 (R290) 0.01-0.6

CF2BrH(R22B1)       0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 2 BrH (R22B1) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

49.一种非共沸的工作介质，它的组份和重量浓度如下：49. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份              重量浓度Component Weight Concentration

CF3CH3(R143a)  0.01-0.9CF 3 CH 3 (R143a) 0.01-0.9

C3H8(R290)     0.01-0.6C 3 H 8 (R290) 0.01-0.6

C3F5H(R1225)   0.01-0.9并允许含有最大浓度不超过20％的杂质。C 3 F 5 H (R1225) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

50.一种非共沸的工作介质，它的组份和重量浓度如下：50. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份              重量浓度Component Weight Concentration

CF3CH3(R143a)   0.01-0.9CF 3 CH 3 (R143a) 0.01-0.9

C3H8(R290)      0.01-0.6C 3 H 8 (R290) 0.01-0.6

C3H3F3(R1243)  0.01-0.9并允许含有最大浓度不超过20％的杂质。C 3 H 3 F 3 (R1243) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

51.一种非共沸的工作介质，它的组份和重量浓度如下：51. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份              重量浓度Component Weight Concentration

C2F5H(R125)    0.01-0.9C 2 F 5 H(R125) 0.01-0.9

C3H8(R290)     0.01-0.6C 3 H 8 (R290) 0.01-0.6

C3F5H(R1225)   0.01-0.9并允许含有最大浓度不超过20％的杂质。C 3 F 5 H (R1225) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

52.一种非共沸的工作介质，它的组份和重量浓度如下：52. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份              重量浓度Component Weight Concentration

C2F5H(R125)    0.01-0.9C 2 F 5 H(R125) 0.01-0.9

C3H8(R290)     0.01-0.6C 3 H 8 (R290) 0.01-0.6

CF2BrH(R22B1)   0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 2 BrH (R22B1) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

53.一种非共沸的工作介质，它的组份和重量浓度如下：53. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份             重量浓度Component Weight Concentration

C2F5H(R125)    0.01-0.9C 2 F 5 H(R125) 0.01-0.9

C3H8(R290)     0.01-0.6C 3 H 8 (R290) 0.01-0.6

C3F3H3(R1243) 0.01-0.9并允许含有最大浓度不超过20％的杂质。C 3 F 3 H 3 (R1243) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

54.一种非共沸的工作介质，它的组份和重量浓度如下：54. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份             重量浓度Component Weight Concentration

CHClF2(R22)    0.01-0.9CHClF 2 (R22) 0.01-0.9

C3H8(R290)    0.01-0.6C 3 H 8 (R290) 0.01-0.6

CF2BrH(R22B1)  0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 2 BrH (R22B1) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

55.一种非共沸的工作介质，它的组份和重量浓度如下：55. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份             重量浓度Component Weight Concentration

CHClF2(R22)    0.01-0.90CHClF 2 (R22) 0.01-0.90

C3H8(R290)    0.01-0.6C 3 H 8 (R290) 0.01-0.6

C3F5H(R1225)  0.01-0.90并允许含有最大浓度不超过20％的杂质。C 3 F 5 H (R1225) 0.01-0.90 and allows the maximum concentration of impurities not exceeding 20%.

56.一种非共沸的工作介质，它的组份和重量浓度如下：56. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份              重量浓度Component Weight Concentration

CHClF2(R22)     0.01-0.9CHClF 2 (R22) 0.01-0.9

C3H8(R290)     0.01-0.6C 3 H 8 (R290) 0.01-0.6

C3H3F3(R1243) 0.01-0.9并允许含有最大浓度不超过20％的杂质。C 3 H 3 F 3 (R1243) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

57.一种非共沸的工作介质，它的组份和重量浓度如下：57. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                     重量浓度Component Weight Concentration

CHClF2(R22)             0.27-0.99CHClF 2 (R22) 0.27-0.99

CH3CHF2(R152a)         0.001-0.5CH 3 CHF 2 (R152a) 0.001-0.5

CH3CClF2(R142b)        0.001-0.6CH 3 CClF 2 (R142b) 0.001-0.6

Figure C9511707400221
              0.001-0.7并允许含有最大浓度不超过20％的杂质。
Figure C9511707400221
0.001-0.7 and allowed to contain impurities with a maximum concentration of no more than 20%.

58.一种非共沸的工作介质，它的组份和重量浓度如下：58. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                     重量浓度Component Weight Concentration

CHClF2(R22)             0.3-0.95CHClF 2 (R22) 0.3-0.95

CH3CHF2(R152a)         0.01-0.5CH 3 CHF 2 (R152a) 0.01-0.5

CH(CH3)3(R600a)        0.01-0.5CH(CH 3 ) 3 (R600a) 0.01-0.5

Figure C9511707400222
              0.01-0.6并允许含有最大浓度不超过20％的杂质。
Figure C9511707400222
0.01-0.6 and allowed to contain impurities with a maximum concentration of no more than 20%.

59.一种非共沸的工作介质，它的组份和重量浓度如下：59. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                     重量浓度Component Weight Concentration

CHClF2(R22)             0.3-0.9CHClF 2 (R22) 0.3-0.9

CH3CHF2(R152a)         0.01-0.5CH 3 CHF 2 (R152a) 0.01-0.5

CH3(CH2)2CH3(R600)  0.01-0.5CH 3 (CH 2 ) 2 CH 3 (R600) 0.01-0.5

Figure C9511707400223
               0.01-0.6并允许含有最大浓度不超过20％的杂质。
Figure C9511707400223
0.01-0.6 and allowed to contain impurities with a maximum concentration of no more than 20%.

60.一种非共沸的工作介质，它的组份和重量浓度如下：60. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                     重量浓度Component Weight Concentration

CHClF2(R22)             0.3-0.95CHClF 2 (R22) 0.3-0.95

CH(CH3)3(R600a)        0.01-0.5CH(CH 3 ) 3 (R600a) 0.01-0.5

CH3CClF2(R142b)        0.01-0.5CH 3 CClF 2 (R142b) 0.01-0.5

               0.01-0.6并允许含有最大浓度不超过20％的杂质。 0.01-0.6 and allowed to contain impurities with a maximum concentration of no more than 20%.

61.一种非共沸的工作介质，它的组份和重量浓度如下：61. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                     重量浓度Component Weight Concentration

CHClF2(R22)             0.3-0.95CHClF 2 (R22) 0.3-0.95

CH3(CH2)2CH3(R600)  0.01-0.5CH 3 (CH 2 ) 2 CH 3 (R600) 0.01-0.5

CH3CClF2(R142b)        0.01-0.5CH 3 CClF 2 (R142b) 0.01-0.5

               0.01-0.6并允许含有最大浓度不超过20％的杂质。 0.01-0.6 and allowed to contain impurities with a maximum concentration of no more than 20%.

62.一种非共沸的工作介质，它的组份和重量浓度如下：62. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                     重量浓度Component Weight Concentration

C2F5H(R125)            0.01-0.9C 2 F 5 H(R125) 0.01-0.9

CH2＝CH-CH3(R1270)     0.01-0.6CH 2 =CH-CH 3 (R1270) 0.01-0.6

     0.01-0.8并允许含有最大浓度不超过20％的杂质。 0.01-0.8 and allowed to contain impurities with a maximum concentration of no more than 20%.

63.一种非共沸的工作介质，它的组份和重量浓度如下：63. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                 重量浓度Component Weight Concentration

C2F5H(R125)        0.01-0.9C 2 F 5 H(R125) 0.01-0.9

CH3CHF2(R152a)     0.01-0.6CH 3 CHF 2 (R152a) 0.01-0.6

            0.01-0.8并允许含有最大浓度不超过20％的杂质。 0.01-0.8 and allowed to contain impurities with a maximum concentration of no more than 20%.

64.一种非共沸的工作介质，它的组份和重量浓度如下：64. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                       重量浓度Component Weight Concentration

C2F5H(R125)              0.01-0.9C 2 F 5 H(R125) 0.01-0.9

CH3(CH2)2CH3(R600)    0.01-0.6CH 3 (CH 2 ) 2 CH 3 (R600) 0.01-0.6

                0.01-0.8并允许含有最大浓度不超过20％的杂质。 0.01-0.8 and allowed to contain impurities with a maximum concentration of no more than 20%.

65.一种非共沸的工作介质，它的组份和重量浓度如下：65. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                     重量浓度Component Weight Concentration

C2F5H(R125)            0.01-0.9C 2 F 5 H(R125) 0.01-0.9

CH(CH3)3(R600a)        0.01-0.5CH(CH 3 ) 3 (R600a) 0.01-0.5

               0.01-0.8并允许含有最大浓度不超过20％的杂质。 0.01-0.8 and allowed to contain impurities with a maximum concentration of no more than 20%.

66.一种非共沸的工作介质，它的组份和重量浓度如下：66. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                    重量浓度Component Weight Concentration

CF3CFH2(R134a)        0.01-0.9CF 3 CFH 2 (R134a) 0.01-0.9

CH3(CH2)2CH3(R600) 0.01-0.6CH 3 (CH 2 ) 2 CH 3 (R600) 0.01-0.6

Figure C9511707400244
              0.01-0.8并允许含有最大浓度不超过20％的杂质。
Figure C9511707400244
0.01-0.8 and allowed to contain impurities with a maximum concentration of no more than 20%.

67.一种非共沸的工作介质，它的组份和重量浓度如下：67. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

CF3CFH2(R134a)      0.01-0.9CF 3 CFH 2 (R134a) 0.01-0.9

CH(CH3)3(R600a)     0.01-0.6                0.01-0.8并允许含有最大浓度不超过20％的杂质。CH(CH 3 ) 3 (R600a) 0.01-0.6 0.01-0.8 and allowed to contain impurities with a maximum concentration of no more than 20%.

68.一种非共沸的工作介质，它的组份和重量浓度如下：68. A non-azeotropic working medium whose composition and weight concentration are as follows:

组份                       重量浓度Component Weight Concentration

CF2HCF2H(R134)           0.01-0.9CF 2 HCF 2 H(R134) 0.01-0.9

CH3(CH2)2CH3(R600)    0.01-0.6CH 3 (CH 2 ) 2 CH 3 (R600) 0.01-0.6

Figure C9511707400252
                0.01-0.8并允许含有最大浓度不超过20％的杂质。
Figure C9511707400252
0.01-0.8 and allowed to contain impurities with a maximum concentration of no more than 20%.

69.一种非共沸的工作介质，它的组份和重量浓度如下：69. A non-azeotropic working medium whose composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

CF2HCF2H(R134)      0.01-0.9CF 2 HCF 2 H(R134) 0.01-0.9

CH(CH3)3(R600a)     0.01-0.6CH(CH 3 ) 3 (R600a) 0.01-0.6

Figure C9511707400253
            0.01-0.8并允许含有最大浓度不超过20％的杂质。
Figure C9511707400253
0.01-0.8 and allowed to contain impurities with a maximum concentration of no more than 20%.

70.一种非共沸的工作介质，它的组份和重量浓度如下：70. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

CF3CFH2(R134a)      0.01-0.9CF 3 CFH 2 (R134a) 0.01-0.9

C2F4ClH(R124a)             0.01-0.6C 2 F 4 ClH(R124a) 0.01-0.6

Figure C9511707400261
                  0.01-0.8并允许含有最大浓度不超过20％的杂质。
Figure C9511707400261
0.01-0.8 and allowed to contain impurities with a maximum concentration of no more than 20%.

71.一种非共沸的工作介质，它的组份和重量浓度如下：71. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

CF2HCF2H(R134)      0.01-0.9CF 2 HCF 2 H(R134) 0.01-0.9

C2F4ClH(R124a)      0.01-0.6C 2 F 4 ClH(R124a) 0.01-0.6

           0.01-0.8并允许含有最大浓度不超过20％的杂质。 0.01-0.8 and allowed to contain impurities with a maximum concentration of no more than 20%.

72.一种非共沸的工作介质，它的组份和重量浓度如下：72. A non-azeotropic working medium whose composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

C2F5H(R125)         0.01-0.9C 2 F 5 H(R125) 0.01-0.9

CH2＝CH-CH3(R1270)  0.01-0.6CH 2 =CH-CH 3 (R1270) 0.01-0.6

CH3CHF2(R152a)      0.01-0.7CH 3 CHF 2 (R152a) 0.01-0.7

Figure C9511707400263
            0.01-0.9并允许含有最大浓度不超过20％的杂质。
Figure C9511707400263
0.01-0.9 and allowed to contain impurities with a maximum concentration of no more than 20%.

73.一种非共沸的工作介质，它的组份和重量浓度如下：73. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

C2F5H(R125)         0.01-0.9C 2 F 5 H(R125) 0.01-0.9

CF3CH3(R143a)       0.01-0.6CF 3 CH 3 (R143a) 0.01-0.6

CH3CHF2(R152a)      0.01-0.7CH 3 CHF 2 (R152a) 0.01-0.7

            0.01-0.9并允许含有最大浓度不超过20％的杂质。 0.01-0.9 and allowed to contain impurities with a maximum concentration of no more than 20%.

74.一种非共沸的工作介质，它的组份和重量浓度如下：74. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

C2F5H(R125)         0.01-0.9C 2 F 5 H(R125) 0.01-0.9

CF3CH3(R143a)       0.01-0.6CF 3 CH 3 (R143a) 0.01-0.6

CH3(CH3)3(R600a)   0.01-0.7CH 3 (CH 3 ) 3 (R600a) 0.01-0.7

Figure C9511707400271
            0.01-0.9并允许含有最大浓度不超过20％的杂质。
Figure C9511707400271
0.01-0.9 and allowed to contain impurities with a maximum concentration of no more than 20%.

75.一种非共沸的工作介质，它的组份和重量浓度如下：75. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                    重量浓度Component Weight Concentration

C2F5H(R125)           0.01-0.9C 2 F 5 H(R125) 0.01-0.9

CF3CH3(R143a)         0.01-0.6CF 3 CH 3 (R143a) 0.01-0.6

CH3(CH2)2CH3(R600) 0.01-0.7CH 3 (CH 2 ) 2 CH 3 (R600) 0.01-0.7

Figure C9511707400272
           0.01-0.9并允许含有最大浓度不超过20％的杂质。
Figure C9511707400272
0.01-0.9 and allowed to contain impurities with a maximum concentration of no more than 20%.

76.一种非共沸的工作介质，它的组份和重量浓度如下：76. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                 重量浓度Component Weight Concentration

CF3CH3(R143a)      0.01-0.9CF 3 CH 3 (R143a) 0.01-0.9

CH3CHF2(R152a)     0.01-0.6CH 3 CHF 2 (R152a) 0.01-0.6

CF3CFH2(R134a)     0.01-0.7CF 3 CFH 2 (R134a) 0.01-0.7

          0.01-0.9并允许含有最大浓度不超过20％的杂质。 0.01-0.9 and allowed to contain impurities with a maximum concentration of no more than 20%.

77.一种非共沸的工作介质，它的组份和重量浓度如下：77. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

CF3CH3(R143a)       0.01-0.9CF 3 CH 3 (R143a) 0.01-0.9

CH3CHF2(R152a)      0.01-0.6CH 3 CHF 2 (R152a) 0.01-0.6

CF2HCF2H(R134)      0.01-0.7CF 2 HCF 2 H(R134) 0.01-0.7

Figure C9511707400281
            0.01-0.8并允许含有最大浓度不超过20％的杂质。
Figure C9511707400281
0.01-0.8 and allowed to contain impurities with a maximum concentration of no more than 20%.

78.一种非共沸的工作介质，它的组份和重量浓度如下：78. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                     重量浓度Component Weight Concentration

CHClF2(R22)             0.01-0.9CHClF 2 (R22) 0.01-0.9

CH3CHF2(R152a)         0.01-0.6CH 3 CHF 2 (R152a) 0.01-0.6

CH3CClF2(R142b)        0.01-0.7CH 3 CClF 2 (R142b) 0.01-0.7

CF3CF2CF2CF3(R3110) 0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 3 CF 2 CF 2 CF 3 (R3110) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

79.一种非共沸的工作介质，它的组份和重量浓度如下：79. A non-azeotropic working medium whose composition and weight concentration are as follows:

组份                     重量浓度Component Weight Concentration

CHClF2(R22)             0.01-0.9CHClF 2 (R22) 0.01-0.9

CH3CHF2(R152a)         0.01-0.6CH 3 CHF 2 (R152a) 0.01-0.6

CF3CF2CF2CF3(R3110) 0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 3 CF 2 CF 2 CF 3 (R3110) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

80.一种非共沸的工作介质，它的组份和重量浓度如下：80. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                  重量浓度Component Weight Concentration

CHClF2(R22)          0.01-0.9CHClF 2 (R22) 0.01-0.9

CH3CClF2(R142b)     0.01-0.6CH 3 CClF 2 (R142b) 0.01-0.6

CF3CF2CF2CF3(R3110)   0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 3 CF 2 CF 2 CF 3 (R3110) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

81.一种非共沸的工作介质，它的组份和重量浓度如下：81. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                       重量浓度Component Weight Concentration

CHClF2(R22)               0.01-0.9CHClF 2 (R22) 0.01-0.9

CF3CFH2(R134a)           0.01-0.9CF 3 CFH 2 (R134a) 0.01-0.9

CF3CF2CF2CF3(R3110)   0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 3 CF 2 CF 2 CF 3 (R3110) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

82.一种非共沸的工作介质，它的组份和重量浓度如下：82. A non-azeotropic working medium whose composition and weight concentration are as follows:

组份                       重量浓度Component Weight Concentration

CHClF2(R22)               0.01-0.9CHClF 2 (R22) 0.01-0.9

CF2HCF2H(R134)           0.01-0.9CF 2 HCF 2 H(R134) 0.01-0.9

CF3CF2CF2CF3(R3110)   0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 3 CF 2 CF 2 CF 3 (R3110) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

83.一种非共沸的工作介质，它的组份和重量浓度如下：83. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                      重量浓度Component Weight Concentration

C2F5H(R125)             0.01-0.9C 2 F 5 H(R125) 0.01-0.9

CH2＝CH-CH3(R1270)      0.01-0.6CH 2 =CH-CH 3 (R1270) 0.01-0.6

CF3CF2CF2CF3(R3110)  0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 3 CF 2 CF 2 CF 3 (R3110) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

84.一种非共沸的工作介质，它的组份和重量浓度如下：84. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                      重量浓度Component Weight Concentration

CF3CH3(R143a)           0.01-0.7CF 3 CH 3 (R143a) 0.01-0.7

CH2＝CH-CH3(R1270)      0.01-0.6CH 2 =CH-CH 3 (R1270) 0.01-0.6

CF3CF2CF2CF3(R3110)  0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 3 CF 2 CF 2 CF 3 (R3110) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

85.一种非共沸的工作介质，它的组份和重量浓度如下：85. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                       重量浓度Component Weight Concentration

C2F5H(R125)              0.01-0.9C 2 F 5 H(R125) 0.01-0.9

C3H8(R290)               0.01-0.6C 3 H 8 (R290) 0.01-0.6

CF3CF2CF2CF3(R3110)   0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 3 CF 2 CF 2 CF 3 (R3110) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

86.一种非共沸的工作介质，它的组份和重量浓度如下：86. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                       重量浓度Component Weight Concentration

C2F5H(R125)              0.01-0.9C 2 F 5 H(R125) 0.01-0.9

CH(CH3)3(R600a)          0.01-0.6CH(CH 3 ) 3 (R600a) 0.01-0.6

CF3CF2CF2CF3(R3110)   0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 3 CF 2 CF 2 CF 3 (R3110) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

87.一种非共沸的工作介质，它的组份和重量浓度如下：87. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                       重量浓度Component Weight Concentration

C2F5H(R125)              0.01-0.9C 2 F 5 H(R125) 0.01-0.9

CH3(CH2)2CH3(R600)    0.01-0.6CH 3 (CH 2 ) 2 CH 3 (R600) 0.01-0.6

CF3CF2CF2CF3(R3110)   0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 3 CF 2 CF 2 CF 3 (R3110) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

88.一种非共沸的工作介质，它的组份和重量浓度如下：88. A non-azeotropic working medium whose composition and weight concentration are as follows:

组份                       重量浓度Component Weight Concentration

CF3CH3(R143a)            0.01-0.9CF 3 CH 3 (R143a) 0.01-0.9

CH(CH3)3(R600a)          0.01-0.6CH(CH 3 ) 3 (R600a) 0.01-0.6

CF3CF2CF2CF3(R3110)   0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 3 CF 2 CF 2 CF 3 (R3110) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

89.一种非共沸的工作介质，它的组份和重量浓度如下：89. A non-azeotropic working medium whose composition and weight concentration are as follows:

组份                     重量浓度Component Weight Concentration

CF3CH3(R143a)          0.01-0.9CF 3 CH 3 (R143a) 0.01-0.9

CH3(CH2)2CH3(R600)  0.01-0.6CH 3 (CH 2 ) 2 CH 3 (R600) 0.01-0.6

CF3CF2CF2CF3(R3110) 0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 3 CF 2 CF 2 CF 3 (R3110) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

90.一种非共沸的工作介质，它的组份和重量浓度如下：90. A non-azeotropic working medium, its composition and weight concentration are as follows:

组份                     重量浓度Component Weight Concentration

CF3CH3(R143a)          0.01-0.9CF 3 CH 3 (R143a) 0.01-0.9

C3H8(R290)             0.01-0.6C 3 H 8 (R290) 0.01-0.6

CF3CF2CF2CF3(R3110) 0.01-0.9并允许含有最大浓度不超过20％的杂质。CF 3 CF 2 CF 2 CF 3 (R3110) 0.01-0.9 and allows the maximum concentration of impurities not exceeding 20%.

本发明的主题还包括：The subject of the invention also includes:

一种热力循环系统的热工装置，其特征是，该装置使用1，2，3，4，5，6，7，8，9，10，11，12，13，14，15，16，17，18，19，20，21，22，23，24，25，26，27，28，29，30，31，32，33，34，35，36，37，38，39，40，41，42，43，44，45，46，47，48，49，50，51，52，53，54，55，56，57，58，59，60，61，62，63，64，65，66，67，68，69，70，71，72，73，74，75，76，77，78，79，80，81，82，83，84，85，86，87，88，89，90所构成的非共沸工作介质。A thermal device of a thermal cycle system, characterized in that the device uses 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17 , 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42 , 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67 , 68, 69, 70, 71, 72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 86, 87, 88, 89, 90 Azeotropic working medium.

一种热力循环系统工作的空调系统，其特征是，该装置使用1，2，3，4，5，6，7，8，9，10，11，12，13，14，15，16，17，18，19，20，21，22，23，24，25，26，27，28，29，30，31，32，33，34，35，36，37，38，39，40，41，42，43，44，45，46，47，48，49，50，51，52，53，54，55，56，57，58，59，60，61，62，63，64，65，66，67，68，69，70，71，72，73，74，75，76，77，78，79，80，81，82，83，84，85，86，87，88，89，90所构成的非共沸工作介质。An air-conditioning system working in a thermodynamic cycle system, characterized in that the device uses , 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42 , 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67 , 68, 69, 70, 71, 72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 86, 87, 88, 89, 90 Azeotropic working medium.

一种热力循环系统工作的供热系统，其特征是，该装置使用1，2，3，4，5，6，7，8，9，10，11，12，13，14，15，16，17，18，19，20，21，22，23，24，25，26，27，28，29，30，31，32，33，34，35.36，37，38.39，40，41，42，43，44，45，46，47，48，49，50，51，52，53，54，55，56，57，58，59，60，61，62，63，64，65，66，67，68，69，70，71，72，73，74，75，76，77，78，79，80，81，82，83，84，85，86，87，88，89，90所构成的非共沸工作介质。A heat supply system working with a thermodynamic cycle system is characterized in that the device uses 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35.36, 37, 38.39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 86, 87, 88, 89, 90 composed of non-azeotropic work medium.

一种热力循环系统工作的热流体发电装置，其特征是，该装置使用1，2，3，4，5，6，7，8，9，10，11，12，13，14，15，16，17，18，19，20，21，22，23，24，25，26，27，28，29，30，31，32，33，34，35，36，37，38，39，40，41，42，43，44，45，46，47，48，49，50，51，52，53，54，55，56，57，58，59，60，61，62，63，64，65，66，67，68，69，70，71，72，73，74，75，76，77，78，79，80，81，82，83，84，85，86，87，88，89，90所构成的非共沸工作介质。A thermal fluid power generation device working in a thermodynamic cycle system, characterized in that the device uses 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16 , 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41 , 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66 , 67, 68, 69, 70, 71, 72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 86, 87, 88, 89, 90 non-azeotropic working medium.

Claims (17)

1.一种非共沸的工作介质，它的组份和重量浓度如下：1. A non-azeotropic working medium, its composition and weight concentration are as follows: 组份                    重量浓度Component Weight Concentration CHClF2                0.40-0.999CHClF 2 0.40-0.999 CH2＝CH-CH3          0.001-0.60CH 2 =CH-CH 3 0.001-0.60 2.一种非共沸的工作介质，它的组份和重量浓度如下：2. A non-azeotropic working medium, its composition and weight concentration are as follows: 组份                    重量浓度Component Weight Concentration CHClF2                0.04-0.99CHClF 2 0.04-0.99 CH2＝CH-CH3          0.001-0.30CH 2 =CH-CH 3 0.001-0.30 CH2F2                0.001-0.95CH 2 F 2 0.001-0.95 3.一种非共沸的工作介质，它的组份和重量浓度如下：3. A non-azeotropic working medium, its composition and weight concentration are as follows: 组份                    重量浓度Component Weight Concentration CHClF2                0.04-0.99CHClF 2 0.04-0.99 CH2＝CH-CH3          0.001-0.3CH 2 =CH-CH 3 0.001-0.3 C2HF5                0.001-0.95C 2 HF 5 0.001-0.95 4.一种非共沸的工作介质，它的组份和重量浓度如下：4. A non-azeotropic working medium, its composition and weight concentration are as follows: 组份                    重量浓度Component Weight Concentration CHClF2                0.04-0.99CHClF 2 0.04-0.99 CH2＝CH-CH3          0.001-0.3CH 2 =CH-CH 3 0.001-0.3 CH3CF3               0.001-0.95CH 3 CF 3 0.001-0.95 5.一种非共沸的工作介质，它的组份和重量浓度如下：5. A non-azeotropic working medium, its composition and weight concentration are as follows: 组份                    重量浓度Component Weight Concentration CHClF2                0.04-0.99CHClF 2 0.04-0.99 CH2＝CH-CH3          0.001-0.3CH 2 =CH-CH 3 0.001-0.3 C2HF5                0.001-0.95C 2 HF 5 0.001-0.95 CH2F2                0.001-0.95CH 2 F 2 0.001-0.95 6.一种非共沸的工作介质，它的组份和重量浓度如下：6. A non-azeotropic working medium, its composition and weight concentration are as follows: 组份              重量浓度Component Weight Concentration CHClF2          0.04-0.99CHClF 2 0.04-0.99 CH2＝CH-CH3    0.001-0.3CH 2 =CH-CH 3 0.001-0.3 CH3CF3         0.001-0.95CH 3 CF 3 0.001-0.95 CH2F2          0.001-0.95CH 2 F 2 0.001-0.95 7.一种非共沸的工作介质，它的组份和重量浓度如下：7. A non-azeotropic working medium, its composition and weight concentration are as follows: 组份              重量浓度Component Weight Concentration CHClF2          0.04-0.99CHClF 2 0.04-0.99 CH2＝CH-CH3    0.001-0.3CH 2 =CH-CH 3 0.001-0.3 CH3CF3         0.001-0.95CH 3 CF 3 0.001-0.95 C2F5H          0.001-0.95C 2 F 5 H 0.001-0.95 8.一种非共沸的工作介质，它的组份和重量浓度如下：8. A non-azeotropic working medium, its composition and weight concentration are as follows: 组份              重量浓度Component Weight Concentration CHClF2          0.04-0.99CHClF 2 0.04-0.99 CH3CFCl2       0.001-0.95 CH3CFCl2 0.001-0.95 CH2＝CH-CH3    0.001-0.3CH 2 =CH-CH 3 0.001-0.3 9.一种非共沸的工作介质，它的组份和重量浓度如下：9. A non-azeotropic working medium, its composition and weight concentration are as follows: 组份              重量浓度Component Weight Concentration CHClF2          0.04-0.99CHClF 2 0.04-0.99 CH2＝CH-CH3    0.001-0.3CH 2 =CH-CH 3 0.001-0.3 CHF2Br          0.001-0.95CHF 2 Br 0.001-0.95 10.一种非共沸的工作介质，它的组份和重量浓度如下：10. A non-azeotropic working medium, its composition and weight concentration are as follows: 组份              重量浓度Component Weight Concentration CHClF2          0.04-0.99CHClF 2 0.04-0.99 CH2＝CH-CH3    0.001-0.3CH 2 =CH-CH 3 0.001-0.3 C3F6           0.001-0.95C 3 F 6 0.001-0.95 11.一种非共沸的工作介质，它的组份和重量浓度如下：11. A non-azeotropic working medium, its composition and weight concentration are as follows: 组份               重量浓度Component Weight Concentration CHClF2           0.04-0.99CHClF 2 0.04-0.99 CH2＝CH-CH3     0.001-0.3CH 2 =CH-CH 3 0.001-0.3 C3HF5           0.001-0.95C 3 HF 5 0.001-0.95 12.一种非共沸的工作介质，它的组份和重量浓度如下：12. A non-azeotropic working medium, its composition and weight concentration are as follows: 组份               重量浓度Component Weight Concentration CHClF2           0.04-0.99CHClF 2 0.04-0.99 CH2＝CH-CH3     0.001-0.3CH 2 =CH-CH 3 0.001-0.3 C3H3F3        0.001-0.95C 3 H 3 F 3 0.001-0.95 13.一种非共沸的工作介质，它的组份和重量浓度如下：13. A non-azeotropic working medium, its composition and weight concentration are as follows: 组份               重量浓度Component Weight Concentration CHClF2           0.04-0.99CHClF 2 0.04-0.99 CH2＝CH-CH3     0.001-0.3CH 2 =CH-CH 3 0.001-0.3 CHF2CHF2        0.001-0.95CHF 2 CHF 2 0.001-0.95 14.一种非共沸的工作介质，它的组份和重量浓度如下：14. A non-azeotropic working medium, its composition and weight concentration are as follows: 组份               重量浓度Component Weight Concentration CHClF2           0.04-0.99CHClF 2 0.04-0.99 CH2＝CH-CH3     0.001-0.3CH 2 =CH-CH 3 0.001-0.3 CF3CFH2         0.001-0.95CF 3 CFH 2 0.001-0.95 15.一种非共沸的工作介质，它的组份和重量浓度如下：15. A non-azeotropic working medium, its composition and weight concentration are as follows: 组份               重量浓度Component Weight Concentration CHClF2           0.04-0.99CHClF 2 0.04-0.99 CH2＝CH-CH3     0.001-0.3CH 2 =CH-CH 3 0.001-0.3 C2H3F           0.001-0.95C 2 H 3 F 0.001-0.95 16.一种非共沸的工作介质，它的组份和重量浓度如下：16. A non-azeotropic working medium, its composition and weight concentration are as follows: 组份                重量浓度Component Weight Concentration CHClF2            0.04-0.99CHClF 2 0.04-0.99 CH2＝CH-CH3      0.001-0.3CH 2 =CH-CH 3 0.001-0.3 C2H2F2          0.001-0.95C 2 H 2 F 2 0.001-0.95 17.一种按权利要求1-16的非共沸的工作介质用于热力循环系统工作的热工装置、空调系统、制冷系统、供热系统及热流体发电装置。17. A non-azeotropic working medium according to claims 1-16 is used for thermal equipment, air conditioning systems, refrigeration systems, heating systems and thermal fluid power generation devices for thermal cycle systems.
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