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CN108310812A - A kind of antifoaming agent for powder liquid system artificial nails' system - Google Patents

A kind of antifoaming agent for powder liquid system artificial nails' system Download PDF

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Publication number
CN108310812A
CN108310812A CN201810135731.5A CN201810135731A CN108310812A CN 108310812 A CN108310812 A CN 108310812A CN 201810135731 A CN201810135731 A CN 201810135731A CN 108310812 A CN108310812 A CN 108310812A
Authority
CN
China
Prior art keywords
anhydride
powder liquid
fatty acids
liquid system
antifoaming agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201810135731.5A
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Chinese (zh)
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CN108310812B (en
Inventor
张元丰
胡红光
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Luoyang Kedi Yisi Cosmetics Co.,Ltd.
Original Assignee
Luoyang Codi Art Resin Co Ltd
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Priority to CN201810135731.5A priority Critical patent/CN108310812B/en
Publication of CN108310812A publication Critical patent/CN108310812A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D19/00Degasification of liquids
    • B01D19/02Foam dispersion or prevention
    • B01D19/04Foam dispersion or prevention by addition of chemical substances
    • B01D19/0404Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D19/00Degasification of liquids
    • B01D19/02Foam dispersion or prevention
    • B01D19/04Foam dispersion or prevention by addition of chemical substances
    • B01D19/0404Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
    • B01D19/0431Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance containing aromatic rings

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Cosmetics (AREA)

Abstract

The present invention relates to a kind of antifoaming agent for powder liquid system artificial nails' system, which is the mixture of long chain fatty acids and organic acid anhydride, and the mass ratio of long chain fatty acids and organic acid anhydride is 20 ~ 30:70 ~ 80, the mass fraction for the long chain fatty acids added in the powder liquid system is 0.5% ~ 5%, the long chain fatty acids are palmitic acid, heptadecanoic acid or stearic acid, and the organic acid anhydride is phthalic anhydride, tetrahydrophthalic anhydride, methyl tetrahydro phthalic anhydride, hexahydrophthalic anhydride, methyl hexahydrophthalic anhydride or maleic anhydride;The present invention is added using the mixture of long chain fatty acids and organic acid anhydride in powder liquid system artificial nails' oil, there is extraordinary defoaming effect;And individually long chain fatty acids or organic acid anhydride are in this system, without defoaming effect.After the mixture of long chain fatty acids and organic acid anhydride is added in powder liquid system, when manufacturing artificial nail, many small steep oneself-meeting are condensed into bulla rapidly, and brokenly bubble speed greatly improves.

Description

A kind of antifoaming agent for powder liquid system artificial nails' system
Technical field
The present invention relates to artificial nails' preparing technical fields, specifically a kind of to be used for powder liquid system artificial nails' system Antifoaming agent.
Background technology
The artificial engraving nail system being made of first powder, two packet system of solution A, have it is easy to use, can especially carve Go out life-like, well-rounded space pattern.It is still occupied an important position in manicure field at present.
First powder in two backpack body system of powder liquid, the generally homopolymer or methyl methacrylate and first of ethyl methacrylate The copolymer of base ethyl acrylate, the copolymer etc. of methyl methacrylate and butyl methacrylate.It is typically contained in first powder Solid radical polymerization initiator, generally benzoyl peroxide can also contain pigment, pearl powder etc..Solution A is generally by several (Methyl)Acrylate monomer forms, general in solution A also to contain aromatic amine type accelerator, such as N, N- dihydroxypropyl pair Methylaniline, N, N- dihydroxy ethyl open-chain crown ethers etc. can also contain antioxidant or stabilizer, such as 2, and 6- di-t-butyls are to methyl Phenol (BHT) or p methoxy phenol(MEHQ)Deng.Solution A copes with first powder, and there is enough solvabilities, the requirement to solution A to be Low taste or tasteless, small to the irritation of skin, small toxicity or nontoxic.Pigment, dyestuff etc. can also be contained in solution A.
When preparing nail-care products, is first frustrated with nail and nail surface is frustrated flat, except degreasing etc., be ready work.Then, Solution A is poured in suitable container, brush, which is immersed in solution A, to be made to form small liquid pearl at its tip, will then carry small liquid pearl Brush be immersed in another container for filling first powder, soft agglomerate substance is formed at the tip of brush.Using carrying The tip of the brush of soft agglomerate substance prepares artificial nails in the meticulous sculpture of nail surface.Peroxide contained in first powder It is catalyzed the polymerization of the composition in solution A together with amine type accelerator contained in solution A, then polishing is manually referred on demand First.
When preparing nail-care products with first powder and solution A, because there are what gap, first powder and solution A were formed to mix between first powder particles Close object in there are a large amount of bubbles, larger bubble can be gradually increasing and rupture, but many minute bubbles be difficult to be condensed into it is larger Bubble and brokenly bubble.The method for reducing foam in first powder and solution A blend, first, making first powder that there is preferable size distribution to make It can be compared with dense packing, second is that the adding liquid antifoaming agent in solution A.Although make first powder have preferable size distribution, first powder and Foam in solution A blend can be slightly a little less, but this problem still has;It is difficult to find that addition but effective liquid in solution A Body antifoaming agent.Deaeration problem is a technical barrier during preparing the artificial nails of engraving with powder liquid system.
Invention content
Technical barrier existing for deaeration problem during the artificial nails carved for the preparation of above-mentioned existing powder liquid system, The present invention provides a kind of antifoaming agent for powder liquid system artificial nails' system.
In order to solve the above technical problems, the technical solution adopted by the present invention is:
A kind of antifoaming agent for powder liquid system artificial nails' system, the antifoaming agent are the mixing of long chain fatty acids and organic acid anhydride The mass ratio of object, long chain fatty acids and organic acid anhydride is 20 ~ 30:70 ~ 80, the long chain fatty acids added in the powder liquid system Mass fraction is 0.5% ~ 5%, and the long chain fatty acids are palmitic acid, heptadecanoic acid or stearic acid, and the organic acid anhydride is benzene Acid anhydride, tetrahydrophthalic anhydride, methyl tetrahydro phthalic anhydride, hexahydrophthalic anhydride, methyl hexahydrophthalic anhydride or maleic anhydride.
The mass ratio of the long chain fatty acids and organic acid anhydride is 25:75.
The mass fraction for the long chain fatty acids added in the powder liquid system is 2 ~ 3%.
The organic acid anhydride is phthalic anhydride.
First powder in the powder liquid system is the homopolymer or methyl methacrylate and methyl-prop of ethyl methacrylate The copolymer of olefin(e) acid ethyl ester, the copolymer of methyl methacrylate and butyl methacrylate contain benzoyl peroxide first in first powder Acyl initiator.
Solution A in the powder liquid system is by several(Methyl)Acrylate monomer forms, and contains N, N- dihydroxies in solution A Propyl open-chain crown ether or N, the aromatic amine type accelerator of N- dihydroxy ethyl open-chain crown ethers.
Contain 2,6-di-tert-butyl p-methylphenol or p methoxy phenol antioxidant in the solution A.
Contain pigments or dyes in the solution A.
Beneficial effects of the present invention:
Provided by the present invention for the antifoaming agent of powder liquid system artificial nails' system, using the mixed of long chain fatty acids and organic acid anhydride It closes object to be added in powder liquid system artificial nails' oil, there is extraordinary defoaming effect;And individually long chain fatty acids or organic acid anhydride exist In this system, without defoaming effect.After the mixture of long chain fatty acids and organic acid anhydride is added in powder liquid system, manufacturing artificial When nail, many small steep oneself-meeting are condensed into bulla rapidly, and brokenly bubble speed greatly improves;Long chain fatty acids and organic acid anhydride it is mixed Close object has excellent defoaming effect in powder liquid system;The antifoaming agent adds in the first powder or solution A that powder liquid is united, powder liquid The mass fraction for the long chain fatty acids added in system is 0.5% ~ 5%, preferably 2 ~ 3%;The additive amount of long chain fatty acids is less than 0.5% When, defoaming effect is not notable;When the additive amount of long chain fatty acids is higher than 5%, defoaming effect no longer improves.
Specific implementation mode
The present invention is further elaborated With reference to embodiment.
First powder formula and the solution A formula used in the following examples and comparative example is as follows:
First powder formula
Methyl methacrylate-ethyl methacrylate copolymers(Molar ratio 70:30) 98.88%(Mass fraction, similarly hereinafter)
Benzoyl peroxide 1.12%
Solution A formula
Ethyl methacrylate 82.20%
Hydroxyethyl methacrylate 11%
Ethylene glycol dimethacrylate 6%
N, N- dimethyl open-chain crown ether 0.8%
Palmitic acid, heptadecanoic acid, stearic acid are weighed respectively, then it is 25 to be made into quality with phthalic anhydride respectively:75 tri- kinds of defoamings of A, B, C Agent.
Embodiment 1
2g antifoaming agent A is weighed to be added in the first powder of the above-mentioned formulas of 98g.Coordinated with this first powder and above-mentioned solution A, prepares artificial nails (Crystal first).It was found that in artificial nails' preparation process, foam is agglomerated rapidly, is ruptured.Nothing in crystal first made of detecting by an unaided eye Bubble or stomata.
Embodiment 2
3g antifoaming agent A is weighed to be added in the first powder of the above-mentioned formulas of 97g.Coordinated with this first powder and above-mentioned solution A, prepares artificial nails (Crystal first).It was found that in artificial nails' preparation process, foam is agglomerated rapidly, is ruptured.Nothing in crystal first made of detecting by an unaided eye Bubble or stomata.
Embodiment 3
In addition to using antifoaming agent B, remaining is same as Example 1.It was found that in artificial nails' preparation process, foam is agglomerated rapidly, is ruptured. Bubble-free or stomata in crystal first made of detecting by an unaided eye.
Embodiment 4
In addition to using antifoaming agent B, remaining is same as Example 2.It was found that in artificial nails' preparation process, foam is agglomerated rapidly, is ruptured. Bubble-free or stomata in crystal first made of detecting by an unaided eye.
Embodiment 5
In addition to using antifoaming agent C, remaining is same as Example 1.It was found that in artificial nails' preparation process, foam is agglomerated rapidly, is ruptured. Bubble-free or stomata in crystal first made of detecting by an unaided eye.
Embodiment 6
In addition to using antifoaming agent C, remaining is same as Example 2.It was found that in artificial nails' preparation process, foam is agglomerated rapidly, is ruptured. Bubble-free or stomata in crystal first made of detecting by an unaided eye.
Comparative example 1
Except the antifoaming agent for not adding the present invention in first powder, BYK088 in solution A respectively containing solution A gross mass 0.7%, 0.7% BYK066N liquid antifoam agents, 1.2% liquid antifoam agent BYK-535 outside, remaining is same as Example 1.During preparing artificial nails, It was found that in the case of using above-mentioned three kinds of antifoaming agent respectively, there are a large amount of minute bubbles to be difficult to deaeration, detect by an unaided eye and be made Crystal first in have many minute bubbles or stomata.
Comparative example 2
Except the antifoaming agent for not adding the present invention in first powder, palmitic acid, heptadecanoic acid in solution A respectively containing solution A gross mass 3%, Outside stearic acid, remaining is same as Example 1.During preparing artificial nails, find in the case of using above-mentioned three kinds of antifoaming agent respectively, There are a large amount of minute bubbles to be difficult to deaeration, has many minute bubbles or stomata in the manufactured crystal first that detects by an unaided eye.

Claims (8)

1. a kind of antifoaming agent for powder liquid system artificial nails' system, it is characterised in that:The antifoaming agent be long chain fatty acids and The mass ratio of the mixture of organic acid anhydride, long chain fatty acids and organic acid anhydride is 20 ~ 30:70 ~ 80, it adds in the powder liquid system Long chain fatty acids mass fraction be 0.5% ~ 5%, the long chain fatty acids be palmitic acid, heptadecanoic acid or stearic acid, it is described Organic acid anhydride be phthalic anhydride, tetrahydrophthalic anhydride, methyl tetrahydro phthalic anhydride, hexahydrophthalic anhydride, methyl hexahydrophthalic anhydride or maleic anhydride.
2. being used for the antifoaming agent of powder liquid system artificial nails' system as described in claim 1, it is characterised in that:The long-chain fat The mass ratio of fat acid and organic acid anhydride is 25:75.
3. being used for the antifoaming agent of powder liquid system artificial nails' system as described in claim 1, it is characterised in that:Powder liquid system The mass fraction for the long chain fatty acids added in system is 2 ~ 3%.
4. being used for the antifoaming agent of powder liquid system artificial nails' system as described in claim 1, it is characterised in that:Described is organic Acid anhydrides is phthalic anhydride.
5. being used for the antifoaming agent of powder liquid system artificial nails' system as described in claim 1, it is characterised in that:Powder liquid system First powder in system is the homopolymer or methyl methacrylate and the copolymer of ethyl methacrylate, first of ethyl methacrylate The copolymer of base methyl acrylate and butyl methacrylate contains benzoyl peroxide initiator in first powder.
6. being used for the antifoaming agent of powder liquid system artificial nails' system as described in claim 1, it is characterised in that:Powder liquid system Solution A in system is by several(Methyl)Acrylate monomer forms, and contains N, N- dihydroxypropyls open-chain crown ether or N in solution A, The aromatic amine type accelerator of N- dihydroxy ethyl open-chain crown ethers.
7. being used for the antifoaming agent of powder liquid system artificial nails' system as claimed in claim 6, it is characterised in that:In the solution A Contain 2,6-di-tert-butyl p-methylphenol or p methoxy phenol antioxidant.
8. being used for the antifoaming agent of powder liquid system artificial nails' oil as claimed in claim 6, it is characterised in that:Contain in the solution A There are pigments or dyes.
CN201810135731.5A 2018-02-09 2018-02-09 Defoaming agent for powder-liquid system artificial nail system Active CN108310812B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810135731.5A CN108310812B (en) 2018-02-09 2018-02-09 Defoaming agent for powder-liquid system artificial nail system

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Application Number Priority Date Filing Date Title
CN201810135731.5A CN108310812B (en) 2018-02-09 2018-02-09 Defoaming agent for powder-liquid system artificial nail system

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CN108310812A true CN108310812A (en) 2018-07-24
CN108310812B CN108310812B (en) 2020-09-29

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100041820A1 (en) * 2008-08-18 2010-02-18 Eslinger Delano R Resin and Paint Coating Compositions Comprising Highly Esterified Polyol Polyesters with Two or More Pairs of Conjugated Double Bonds
CN102027077A (en) * 2008-05-15 2011-04-20 巴斯夫欧洲公司 Silicone free defoamer for solvent based coatings

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102027077A (en) * 2008-05-15 2011-04-20 巴斯夫欧洲公司 Silicone free defoamer for solvent based coatings
US20100041820A1 (en) * 2008-08-18 2010-02-18 Eslinger Delano R Resin and Paint Coating Compositions Comprising Highly Esterified Polyol Polyesters with Two or More Pairs of Conjugated Double Bonds

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
张洪涛,黄锦霞: "《胶黏剂助剂手册》", 30 August 2014, 化学工业出版社 *
马宏远,范少强: "挥发酚测定中硬脂酸作为消泡剂的应用", 《甘肃环境研究与监控》 *

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Address after: 471000 Zhangling village, Hongshan Township, Xigong District, Luoyang City, Henan Province

Patentee after: Luoyang Kedi Yisi Cosmetics Co.,Ltd.

Address before: 471000 Zhangling village, Hongshan Township, Xigong District, Luoyang City, Henan Province

Patentee before: LUOYANG KEDI YISI RESIN Co.,Ltd.

CP01 Change in the name or title of a patent holder