CN108316055A - 一种阻燃的纸质家具用瓦楞纸及其制备方法 - Google Patents
一种阻燃的纸质家具用瓦楞纸及其制备方法 Download PDFInfo
- Publication number
- CN108316055A CN108316055A CN201810261938.7A CN201810261938A CN108316055A CN 108316055 A CN108316055 A CN 108316055A CN 201810261938 A CN201810261938 A CN 201810261938A CN 108316055 A CN108316055 A CN 108316055A
- Authority
- CN
- China
- Prior art keywords
- parts
- paper
- fire
- retardant
- corrugated paper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 48
- 238000002360 preparation method Methods 0.000 title claims description 24
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 36
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 24
- 238000004513 sizing Methods 0.000 claims abstract description 22
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 10
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910021389 graphene Inorganic materials 0.000 claims abstract description 10
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 9
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052982 molybdenum disulfide Inorganic materials 0.000 claims abstract description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 9
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 9
- 235000019362 perlite Nutrition 0.000 claims abstract description 7
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 7
- 150000007973 cyanuric acids Chemical class 0.000 claims abstract description 6
- 239000002002 slurry Substances 0.000 claims description 13
- 238000010438 heat treatment Methods 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 229920001131 Pulp (paper) Polymers 0.000 claims description 9
- 239000003822 epoxy resin Substances 0.000 claims description 8
- 239000000017 hydrogel Substances 0.000 claims description 8
- 229920000647 polyepoxide Polymers 0.000 claims description 8
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 7
- 229920000459 Nitrile rubber Polymers 0.000 claims description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 7
- 239000004202 carbamide Substances 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 6
- 229920001568 phenolic resin Polymers 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 239000010893 paper waste Substances 0.000 claims description 4
- 229920002472 Starch Polymers 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 230000018044 dehydration Effects 0.000 claims description 3
- 238000006297 dehydration reaction Methods 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 3
- -1 isocyanuric acid ester Chemical class 0.000 claims description 3
- 238000005360 mashing Methods 0.000 claims description 3
- 238000012545 processing Methods 0.000 claims description 3
- 239000011265 semifinished product Substances 0.000 claims description 3
- 235000019698 starch Nutrition 0.000 claims description 3
- 239000002826 coolant Substances 0.000 claims description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Natural products OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 2
- 238000011160 research Methods 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000004480 active ingredient Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 235000004258 Cordia alliodora Nutrition 0.000 description 1
- 244000085692 Cordia alliodora Species 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/07—Nitrogen-containing compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/64—Alkaline compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/66—Salts, e.g. alums
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/12—Coatings without pigments applied as a solution using water as the only solvent, e.g. in the presence of acid or alkaline compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/34—Ignifugeants
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Paper (AREA)
Abstract
本发明公开了一种阻燃的纸质家具用瓦楞纸，按照重量份包括在100份原浆中含有1‑5份改性剂和1‑3份阻燃剂，其中所述改性剂按重量份包括50‑60份二氧化钛、10‑15份珍珠岩、10‑15份二硫化钼和1‑5份稀土元素；所述阻燃剂按重量份包括40‑50份的红磷、20‑30份异氰脲酸酯、10‑15份的次磷酸铝、1‑5份的氢氧化钠、1‑5份的马来酰亚胺和1‑5份的石墨烯。通过本发明所得到的瓦楞纸，通过在造纸原料中添加改性剂和阻燃剂，大大增强了瓦楞纸的耐破指数和阻燃性能，使得本瓦楞纸具备较高的强度和阻燃性，提高了瓦楞纸箱的使用寿命。另外采用自主研发的施胶剂，进一步提高瓦楞纸的强度。
Description
技术领域
本发明涉及造纸技术，特别是一种阻燃的纸质家具用瓦楞纸及其制备方法。
背景技术
纸质家具是材料以纸质为主的家具都可以统称纸家具。如瓦楞纸家具。纸家具常用的材质是瓦楞纸，与包装物流领域的纸箱在工艺上区别不大，表面就是牛皮纸，只不过选用了最好的材料，本身的承重力更强，而且通过结构设计可以实现更大承重。这些家具大多用的都是进口纸张，防水性很好，能够防水5分钟以上，因此很容易清洁，只需要用湿布擦洗就行。相比传统家具，纸家具的造价并不低，但是相对于有品牌、有设计的传统家具，一些普通纸家具的成本还是较低的，售价也低得多。但传统意义上的纸质家具还是存在一定的问题，如阻燃性不高。
发明内容
本发明的主要目的在于提供一种整体结构强度较高、更为环保的阻燃的纸质家具用瓦楞纸及其制备方法。
为达到以上目的，本发明采用的技术方案为：一种阻燃的纸质家具用瓦楞纸，所述瓦楞纸按照重量份包括在100份原浆中含有1-5份改性剂和1-3份阻燃剂，其中所述改性剂按重量份包括50-60份二氧化钛、10-15份珍珠岩、10-15份二硫化钼和1-5份稀土元素；所述阻燃剂按重量份包括40-50份的红磷、20-30份异氰脲酸酯、10-15份的次磷酸铝、1-5份的氢氧化钠、1-5份的马来酰亚胺和1-5份的石墨烯。
所述瓦楞纸的表面涂覆有施胶剂，其中施胶剂按重量份包括20-30份纳米丁腈橡胶、10-15份环氧树脂、5-10份的改性酚醛树脂、5-10份水凝胶、20-30份尿素和40-50份水。
一种阻燃的纸质家具用瓦楞纸的制备方法，包括以下步骤：
步骤一、选取造纸原料，加水进行泡浆，投入碎浆机中粉碎，使造纸原料离解为纸浆；
步骤二、所述纸浆依次经过压力筛和除渣器除去杂质；
步骤三、经除杂后的纸浆输入至磨盘进行打浆处理，制得原浆；
步骤四、往以重量计的100份原浆中加入1-5份改性剂和1-3份阻燃剂，充分搅拌，而后去除水分，得到含水率为10-20%的抄纸浆，
步骤五、将抄纸浆送至网部成型脱水至干度为15-25%；
步骤六、成型后的浆料输送至压榨部，压榨部将所述浆料压榨脱水至干度为40-50%，然后采用施胶机将施胶剂均匀涂抹在纸张表面；
步骤七、将表面施过胶的瓦楞纸半成品放入烘缸内，调至温度到105-110℃，水份在2-4%，放在室内静置24小时以后，再取出放在通风干燥处放置24小时，即可得到阻燃的纸质家具用瓦楞纸。
所述造纸原料按重量份包括木屑70-80份和废纸20-30份。
所述改性剂的制备方法是将50-60份二氧化钛、10-15份珍珠岩、10-15份二硫化钼和1-5份稀土元素混合均匀，然后边搅拌边加热，加热温度是200-250℃，待冷却后研磨成粉末即得改性剂。
所述阻燃剂的制备方法是先将40-50份的红磷、20-30份异氰脲酸酯、10-15份的次磷酸铝和1-5份的石墨烯混合均匀，然后放入反应釜中，加热温度为600-700℃，加热时间30min，待冷却至200℃后再加1-5份的氢氧化钠、1-5份的马来酰亚胺，加热时间15min，冷却后研磨成粉末即得阻燃剂。
所述施胶剂的制备方法是将20-30份纳米丁腈橡胶、10-15份环氧树脂、5-10份的改性酚醛树脂、5-10份水凝胶、20-30份尿素和40-50份水，搅拌均匀后加热至50-60℃使各成分全部溶解，待温度自然降低至室温即可。
所述改性剂中的二氧化钛作为粘结剂，可以提高各个原料之间的粘结强度，珍珠岩可做保温材料，提高耐热性，二硫化钼作为润滑剂，稀土元素促进上述有效成分的功效发挥，最终提高瓦楞纸的强度。
10-15份的次磷酸铝、1-5份的氢氧化钠、1-5份的马来酰亚胺和1-5份的石墨烯
所述阻燃剂中的红磷和异氰脲酸酯，均有高效的阻燃剂，可以提高阻燃能力。次磷酸铝和马来酰亚胺具有良好的热稳定性和阻燃性。石墨烯则用于促进阻燃有效成分的功效发挥，最终提高其阻燃能力。采用本发明的生产方法制得的瓦楞纸的各项性能和物质指标完全符合瓦楞纸的各项要求。
所述施胶剂中的纳米丁腈橡胶、环氧树脂、改性酚醛树脂，能大幅度提高表面施胶的效果，增强瓦楞纸环压强度。另外将水凝胶加入瓦楞纸表面施胶剂基料中，能够改善施胶剂施胶后纸张的疏水性，同时还可以改善各种构成相之间的表面张力，使之形成均匀稳定的分散体系。
所述造纸原料包括木屑和废纸，有效的利用各行业所产生的废弃物，适应全社会倡导的节能环保以及循环经济精神。
本发明得到的一种阻燃的纸质家具用瓦楞纸及其制备方法，其技术效果通过在造纸原料中添加改性剂和阻燃剂，大大增强了瓦楞纸的耐破指数和阻燃性能，使得本瓦楞纸具备较高的强度和阻燃性，提高了瓦楞纸箱的使用寿命。另外采用自主研发的施胶剂，进一步提高瓦楞纸的强度。
具体实施方式
以下描述用于揭露本发明以使本领域技术人员能够实现本发明。以下描述中的优选实施例只作为举例，本领域技术人员可以想到其他显而易见的变型。
实施例1：
本实施例提供的一种阻燃的纸质家具用瓦楞纸，所述瓦楞纸按照重量份包括在100份原浆中含有3份改性剂和3份阻燃剂，其中所述改性剂按重量份包括50份二氧化钛、10份珍珠岩、10份二硫化钼和1份稀土元素；所述阻燃剂按重量份包括40份的红磷、20份异氰脲酸酯、10份的次磷酸铝、1份的氢氧化钠、1份的马来酰亚胺和1份的石墨烯。
所述瓦楞纸的表面涂覆有施胶剂，其中施胶剂按重量份包括20份纳米丁腈橡胶、10份环氧树脂、5份的改性酚醛树脂、5份水凝胶、20份尿素和40份水。
一种阻燃的纸质家具用瓦楞纸的制备方法，包括以下步骤：
步骤一、选取造纸原料，加水进行泡浆，投入碎浆机中粉碎，使造纸原料离解为纸浆；
步骤二、所述纸浆依次经过压力筛和除渣器除去杂质；
步骤三、经除杂后的纸浆输入至磨盘进行打浆处理，制得原浆；
步骤四、往以重量计的100份原浆中加入3份改性剂和3份阻燃剂，充分搅拌，而后去除水分，得到含水率为10-20%的抄纸浆，
步骤五、将抄纸浆送至网部成型脱水至干度为15-25%；
步骤六、成型后的浆料输送至压榨部，压榨部将所述浆料压榨脱水至干度为40-50%，然后采用施胶机将施胶剂均匀涂抹在纸张表面；
步骤七、将表面施过胶的瓦楞纸半成品放入烘缸内，调至温度到105-110℃，水份在2-4%，放在室内静置24小时以后，再取出放在通风干燥处放置24小时，即可得到阻燃的纸质家具用瓦楞纸。
所述造纸原料按重量份包括木屑70份和废纸30份。
所述改性剂的制备方法是将50份二氧化钛、10份珍珠岩、10份二硫化钼和1份稀土元素混合均匀，然后边搅拌边加热，加热温度是200-250℃，待冷却后研磨成粉末即得改性剂。
所述阻燃剂的制备方法是先将40份的红磷、20份异氰脲酸酯、10份的次磷酸铝和1份的石墨烯混合均匀，然后放入反应釜中，加热温度为600-700℃，加热时间30min，待冷却至200℃后再加1份的氢氧化钠、1份的马来酰亚胺，加热时间15min，冷却后研磨成粉末即得阻燃剂。
所述施胶剂的制备方法是将20份纳米丁腈橡胶、10份环氧树脂、5份的改性酚醛树脂、5份水凝胶、20份尿素和40份水，搅拌均匀后加热至50-60℃使各成分全部溶解，待温度自然降低至室温即可。
本实施例制得的瓦楞纸的耐破强度为730Kpa，环压指数为8.1 N·m /g。同时该瓦楞纸的阻燃性能优良，其平均引燃时间为50s。
实施例2：
本实施例提供的一种阻燃的纸质家具用瓦楞纸及其制备方法大致与实施例1相同，其不同点在于所述改性剂按重量份包括60份二氧化钛、15份珍珠岩、15份二硫化钼和5份稀土元素。
本实施例制得的瓦楞纸的耐破强度为700KPa，环压指数为7.9 N·m /g。同时该瓦楞纸的阻燃性能优良，其平均引燃时间为50s。
实施例3：
本实施例提供的一种阻燃的纸质家具用瓦楞纸及其制备方法大致与实施例1相同，其不同点在于所述阻燃剂按重量份包括50份的红磷、30份异氰脲酸酯、15份的次磷酸铝、5份的氢氧化钠、5份的马来酰亚胺和5份的石墨烯。
本实施例制得的瓦楞纸的耐破强度为710KPa，环压指数为8.0 N·m /g。同时该瓦楞纸的阻燃性能优良，其平均引燃时间为50s。
实施例4：
本实施例提供的一种阻燃的纸质家具用瓦楞纸及其制备方法大致与实施例1相同，其不同点在于所述施胶剂按重量份包括30份纳米丁腈橡胶、15份环氧树脂、10份的改性酚醛树脂、10份水凝胶、30份尿素和50份水。
本实施例制得的瓦楞纸的耐破强度为750KPa，环压指数为8.3 N·m /g。同时该瓦楞纸的阻燃性能优良，其平均引燃时间为50s。
以上显示和描述了本发明的基本原理、主要特征和本发明的优点。本行业的技术人员应该了解，本发明不受上述实施例的限制，上述实施例和说明书中描述的只是本发明的原理，在不脱离本发明精神和范围的前提下本发明还会有各种变化和改进，这些变化和改进都落入要求保护的本发明的范围内。本发明要求的保护范围由所附的权利要求书及其等同物界定。
Claims (7)
1.一种阻燃的纸质家具用瓦楞纸，其特征在于，所述瓦楞纸按照重量份包括在100份原浆中含有1-5份改性剂和1-3份阻燃剂，其中所述改性剂按重量份包括50-60份二氧化钛、10-15份珍珠岩、10-15份二硫化钼和1-5份稀土元素；所述阻燃剂按重量份包括40-50份的红磷、20-30份异氰脲酸酯、10-15份的次磷酸铝、1-5份的氢氧化钠、1-5份的马来酰亚胺和1-5份的石墨烯。
2.根据权利要求1所述的一种阻燃的纸质家具用瓦楞纸，其特征在于，所述瓦楞纸的表面涂覆有施胶剂，其中施胶剂按重量份包括20-30份纳米丁腈橡胶、10-15份环氧树脂、5-10份的改性酚醛树脂、5-10份水凝胶、20-30份尿素和40-50份水。
3.一种如权利要求1或2所述的阻燃的纸质家具用瓦楞纸的制备方法，其特征在于，包括以下步骤：
步骤一、选取造纸原料，加水进行泡浆，投入碎浆机中粉碎，使造纸原料离解为纸浆；
步骤二、所述纸浆依次经过压力筛和除渣器除去杂质；
步骤三、经除杂后的纸浆输入至磨盘进行打浆处理，制得原浆；
步骤四、往以重量计的100份原浆中加入1-5份改性剂和1-3份阻燃剂，充分搅拌，而后去除水分，得到含水率为10-20%的抄纸浆；
步骤五、将抄纸浆送至网部成型脱水至干度为15-25%；
步骤六、成型后的浆料输送至压榨部，压榨部将所述浆料压榨脱水至干度为40-50%，然后采用施胶机将施胶剂均匀涂抹在纸张表面；
步骤七、将表面施过胶的瓦楞纸半成品放入烘缸内，调至温度到105-110℃，水份在2-4%，放在室内静置24小时以后，再取出放在通风干燥处放置24小时，即可得到阻燃的纸质家具用瓦楞纸。
4.根据权利要求4所述的一种阻燃的纸质家具用瓦楞纸的制备方法，其特征在于：所述造纸原料按重量份包括木屑70-80份和废纸20-30份。
5.根据权利要求4所述的一种阻燃的纸质家具用瓦楞纸的制备方法，其特征在于：所述改性剂的制备方法是将50-60份二氧化钛、10-15份珍珠岩、10-15份二硫化钼和1-5份稀土元素混合均匀，然后边搅拌边加热，加热温度是200-250℃，待冷却后研磨成粉末即得改性剂。
6.根据权利要求4所述的一种阻燃的纸质家具用瓦楞纸的制备方法，其特征在于：所述阻燃剂的制备方法是先将40-50份的红磷、20-30份异氰脲酸酯、10-15份的次磷酸铝和1-5份的石墨烯混合均匀，然后放入反应釜中，加热温度为600-700℃，加热时间30min，待冷却至200℃后再加1-5份的氢氧化钠、1-5份的马来酰亚胺，加热时间15min，冷却后研磨成粉末即得阻燃剂。
7.根据权利要求4所述的一种阻燃的纸质家具用瓦楞纸的制备方法，其特征在于：所述施胶剂的制备方法是将20-30份纳米丁腈橡胶、10-15份环氧树脂、5-10份的改性酚醛树脂、5-10份水凝胶、20-30份尿素和40-50份水，搅拌均匀后加热至50-60℃使各成分全部溶解，待温度自然降低至室温即可。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810261938.7A CN108316055A (zh) | 2018-03-28 | 2018-03-28 | 一种阻燃的纸质家具用瓦楞纸及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810261938.7A CN108316055A (zh) | 2018-03-28 | 2018-03-28 | 一种阻燃的纸质家具用瓦楞纸及其制备方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108316055A true CN108316055A (zh) | 2018-07-24 |
Family
ID=62899309
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810261938.7A Pending CN108316055A (zh) | 2018-03-28 | 2018-03-28 | 一种阻燃的纸质家具用瓦楞纸及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108316055A (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110080030A (zh) * | 2019-04-18 | 2019-08-02 | 襄阳金飞环彩色包装有限公司 | 一种阻燃防伪纸张的制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104480772A (zh) * | 2014-11-18 | 2015-04-01 | 柳江县联华纸制品厂 | 高强度瓦楞纸的制备方法 |
| WO2015189034A1 (de) * | 2014-06-12 | 2015-12-17 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verwendung von hydroxybenzotriazol-derivaten und/oder hydroxy-indazol-derivaten als flammschutzmittel für kunststoffe sowie flammgeschützte kunststoffformmasse |
| CN105369669A (zh) * | 2015-10-28 | 2016-03-02 | 福建纸匠文化科技股份有限公司 | 一种高强度瓦楞纸的制备方法 |
| CN105670168A (zh) * | 2016-02-03 | 2016-06-15 | 滁州卷烟材料厂 | 一种高抗压耐冲击瓦楞纸箱 |
| CN107075202A (zh) * | 2014-09-18 | 2017-08-18 | 弗劳恩霍弗应用研究促进协会 | 有机氧基酰亚胺盐作为阻燃剂的用途，阻燃塑料组合物，其制备方法以及模塑部件、油漆或涂料 |
-
2018
- 2018-03-28 CN CN201810261938.7A patent/CN108316055A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015189034A1 (de) * | 2014-06-12 | 2015-12-17 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Verwendung von hydroxybenzotriazol-derivaten und/oder hydroxy-indazol-derivaten als flammschutzmittel für kunststoffe sowie flammgeschützte kunststoffformmasse |
| CN107075202A (zh) * | 2014-09-18 | 2017-08-18 | 弗劳恩霍弗应用研究促进协会 | 有机氧基酰亚胺盐作为阻燃剂的用途，阻燃塑料组合物，其制备方法以及模塑部件、油漆或涂料 |
| CN104480772A (zh) * | 2014-11-18 | 2015-04-01 | 柳江县联华纸制品厂 | 高强度瓦楞纸的制备方法 |
| CN105369669A (zh) * | 2015-10-28 | 2016-03-02 | 福建纸匠文化科技股份有限公司 | 一种高强度瓦楞纸的制备方法 |
| CN105670168A (zh) * | 2016-02-03 | 2016-06-15 | 滁州卷烟材料厂 | 一种高抗压耐冲击瓦楞纸箱 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110080030A (zh) * | 2019-04-18 | 2019-08-02 | 襄阳金飞环彩色包装有限公司 | 一种阻燃防伪纸张的制备方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110344279A (zh) | 一种耐磨高强瓦楞纸板及其制备方法 | |
| CN105862490A (zh) | 一种环保型阻燃纸及其制备方法 | |
| CN108505372A (zh) | 一种利用国产废纸生产低克重高强度电商专用牛卡纸的方法 | |
| CN107435274B (zh) | 防潮耐磨的瓦楞纸及其制备方法 | |
| CN102020720B (zh) | 造纸湿端用高支链阳离子淀粉及其制备方法 | |
| CN111979815A (zh) | 一种抗回潮防分层高强度环保牛皮挂面箱板纸的制备方法 | |
| CN102127170A (zh) | 一种用木浆制备纤维素醚的方法 | |
| CN102305255A (zh) | 纸基摩擦片及其制备方法 | |
| CN102031004A (zh) | 一种阻燃纤维模塑环保墙体装饰材料及其制备方法 | |
| CN109608907A (zh) | 石头纸用改性碳酸钙的改性方法 | |
| CN108385440A (zh) | 一种高强度的纸质家具用瓦楞纸及其制备方法 | |
| CN108316055A (zh) | 一种阻燃的纸质家具用瓦楞纸及其制备方法 | |
| CN104944846A (zh) | 一种抗压防火板材及其制备方法 | |
| CN113146792A (zh) | 一种环保型锡基阻燃刨花板的制备方法 | |
| CN108468254A (zh) | 一种防潮的纸质家具用瓦楞纸及其制备方法 | |
| CN106868916B (zh) | 一种环保型阻燃纸板及其制备方法 | |
| CN103073234B (zh) | 稻草秸秆垃圾再生板材的制造方法 | |
| CN102995493B (zh) | 一种升降机滤清器用滤纸及其制备方法 | |
| CN104911951A (zh) | 一种高性能无纺壁纸原纸及其制备方法与应用 | |
| CN101649575B (zh) | 陶瓷纤维配抄复合纸及其生产方法 | |
| CN106947190A (zh) | 一种生态木 | |
| CN102995499A (zh) | 一种含有改性蒙脱石粉的滤清器滤纸及其制备方法 | |
| CN111349409B (zh) | 一种瓦楞纸板淀粉胶黏剂的制备工艺 | |
| CN107200541A (zh) | 一种废弃秸秆复合板材及其制备方法 | |
| CN103397566A (zh) | 一种利用再生浆制造壁纸原纸的方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180724 |