CN108269802B - Carbon nano tube beam field effect transistor array and manufacturing method thereof - Google Patents
Carbon nano tube beam field effect transistor array and manufacturing method thereof Download PDFInfo
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Abstract
本发明提供一种碳纳米管束场效应晶体管阵列及其制造方法,所述碳纳米管束场效应晶体管阵列包括:源极材料层、漏极材料层以及连接于所述源极材料层与漏极材料层之间的碳纳米管束阵列;所述碳纳米管束阵列包括若干分立设置的碳纳米管束单元,其中,所述碳纳米管束单元的轴向第一端与所述源极材料层连接,所述碳纳米管束单元的轴向第二端与所述漏极材料层连接;所述碳纳米管束单元被栅极结构所包围。本发明的碳纳米管束场效应晶体管阵列能够耐受更高的操作电压及操作电流,能够应用于大功率器件。并且本发明采用环栅结构,可以提高栅极对沟道的操控能力。本发明的碳纳米管束场效应晶体管阵列的制造方法具有工艺步骤简单的特点,有利于降低生产成本。
The present invention provides a carbon nanotube bundle field effect transistor array and a manufacturing method thereof. The carbon nanotube bundle field effect transistor array comprises: a source material layer, a drain material layer, and a material connected to the source material layer and the drain material. A carbon nanotube bundle array between layers; the carbon nanotube bundle array includes several discretely arranged carbon nanotube bundle units, wherein the axial first end of the carbon nanotube bundle unit is connected to the source material layer, and the The second axial end of the carbon nanotube bundle unit is connected with the drain material layer; the carbon nanotube bundle unit is surrounded by the grid structure. The carbon nanotube bundle field effect transistor array of the present invention can withstand higher operating voltage and operating current, and can be applied to high-power devices. Moreover, the present invention adopts the gate-all-around structure, which can improve the control ability of the gate to the channel. The manufacturing method of the carbon nanotube bundle field effect transistor array of the present invention has the characteristics of simple process steps, which is beneficial to reduce the production cost.
Description
技术领域technical field
本发明属于集成电路技术领域,涉及一种碳纳米管束场效应晶体管阵列及其制造方法。The invention belongs to the technical field of integrated circuits, and relates to a carbon nanotube bundle field effect transistor array and a manufacturing method thereof.
背景技术Background technique
对于载流子运输介质,真空本质上优于固体,因为它允许弹道运输,而在半导体中,载流子会遭受光学和声学声子散射。真空中的电子速度理论上是3×1010cm/s,但在半导体中,电子速度仅约为5×107cm/s。一些科学家认为,在真空晶体管中,似乎只有电子可以在电极之间流动,而空穴不能。除非我们学会处理正电子,否则将不可能做任何互补型电路,例如CMOS。而没有互补型电路,功率将过高,最有可能限制真空晶体管进入细分市场。很难想象,任何大型数字电路都会用到真空晶体管。For carrier transport media, vacuum is inherently superior to solids because it allows ballistic transport, whereas in semiconductors, carriers suffer from optical and acoustic phonon scattering. The electron velocity in a vacuum is theoretically 3×10 10 cm/s, but in a semiconductor, the electron velocity is only about 5×10 7 cm/s. Some scientists believe that in vacuum transistors, it seems that only electrons can flow between electrodes, not holes. Unless we learn to deal with positrons, it will be impossible to do any complementary circuits, such as CMOS. Without complementary circuits, the power would be too high, most likely limiting the entry of vacuum transistors into the market segment. It is hard to imagine that any large digital circuit would use vacuum transistors.
目前真空晶体管主要有四种类型(Jin-Woo Han,Jae Sub Oh and M.Meyyappan,Vacuum Nanoelectronics:Back to the Future?-Gate insulated nanoscale vacuumchannel transistor,APL,100,213505(2012)):(a)垂直场发射型、(b)平面横向场发射型、(c)MOSFET型、(d)绝缘栅空气沟道晶体管。There are currently four main types of vacuum transistors (Jin-Woo Han, Jae Sub Oh and M. Meyyappan, Vacuum Nanoelectronics: Back to the Future?-Gate insulated nanoscale vacuumchannel transistor, APL, 100, 213505 (2012)): (a) Vertical field emission type, (b) planar lateral field emission type, (c) MOSFET type, (d) insulated gate air channel transistor.
近年来,已经有报道公开了在理想的围栅几何形态下,碳纳米管场效应晶体管(CNTFET)的自对准栅极尺寸可缩小到20纳米(IBM创造了第一个9nm碳纳米管晶体管,通过Gareth Halfacree于2012年1月30日发表)。栅极包围碳纳米管沟道的均匀性已经被证实,并且这个过程不会损坏碳纳米管。此外,利用合适的栅极介质层,可以实现N型晶体管或P型晶体管,其中,利用HfO2作为栅介质层可以实现N型晶体管,利用Al2O3作为栅介质层可以实现P型晶体管(Aaron D.Franklin,Carbon Nanotube Complementary Wrap-GateTransistors,Nano Lett.,2013,13(6),pp 2490–2495)。这些发现不仅为围栅碳纳米管器件的进一步研究提供了一个有前途的平台,并表明采用碳纳米管的大规模数字开关拥有现实的技术潜力。In recent years, reports have disclosed that the self-aligned gate size of carbon nanotube field effect transistors (CNTFETs) can be scaled down to 20 nanometers with ideal gate-around geometry (IBM created the first 9nm carbon nanotube transistors) , by Gareth Halfacree on January 30, 2012). The uniformity of the gate surrounding the carbon nanotube channel has been demonstrated, and the process does not damage the carbon nanotubes. In addition, using a suitable gate dielectric layer, an N-type transistor or a P-type transistor can be realized, wherein, an N-type transistor can be realized by using HfO 2 as the gate dielectric layer, and a P-type transistor can be realized by using Al 2 O 3 as the gate dielectric layer ( Aaron D. Franklin, Carbon Nanotube Complementary Wrap-Gate Transistors, Nano Lett., 2013, 13(6), pp 2490–2495). These findings not only provide a promising platform for further research on gated carbon nanotube devices, but also demonstrate the realistic technological potential of large-scale digital switches employing carbon nanotubes.
然而,仍有必要开发CNTFET的潜力和可能性,使其能够用于制造拥有高操作电压和高驱动电流的大功率器件。However, there is still a need to exploit the potential and possibilities of CNTFETs for the fabrication of high-power devices with high operating voltages and high drive currents.
发明内容SUMMARY OF THE INVENTION
鉴于以上所述现有技术的缺点,本发明的目的在于提供一种碳纳米管束场效应晶体管阵列及其制造方法,用于解决现有技术中碳纳米管场效应晶体管不能应用于大功率器件的问题。In view of the above-mentioned shortcomings of the prior art, the purpose of the present invention is to provide a carbon nanotube bundle field effect transistor array and a manufacturing method thereof, which are used to solve the problem that carbon nanotube field effect transistors in the prior art cannot be applied to high-power devices. question.
为实现上述目的及其他相关目的,本发明提供一种碳纳米管束场效应晶体管阵列,包括:To achieve the above purpose and other related purposes, the present invention provides a carbon nanotube bundle field effect transistor array, comprising:
源极材料层;source material layer;
漏极材料层,形成于所述源极材料层上方;a drain material layer formed above the source material layer;
碳纳米管束阵列,连接于所述源极材料层与所述漏极材料层之间;所述碳纳米管束阵列包括若干分立设置的碳纳米管束单元,其中,所述碳纳米管束单元的轴向第一端与所述源极材料层连接,所述碳纳米管束单元的轴向第二端与所述漏极材料层连接;A carbon nanotube bundle array, connected between the source material layer and the drain material layer; the carbon nanotube bundle array includes a number of discretely arranged carbon nanotube bundle units, wherein the axial direction of the carbon nanotube bundle unit The first end is connected to the source material layer, and the axial second end of the carbon nanotube bundle unit is connected to the drain material layer;
栅极结构,形成于所述碳纳米管束阵列中各个碳纳米管束单元之间,且所述栅极结构与所述源极材料层之间通过第一绝缘层隔离,所述栅极结构与所述漏极材料层之间通过第二绝缘层隔离;其中,所述栅极结构包括栅极介质层及栅极材料层,所述栅极介质层包围所述碳纳米管束单元的外侧面,所述栅极材料层包围所述栅极材料层外侧面。A gate structure is formed between each carbon nanotube bundle unit in the carbon nanotube bundle array, and the gate structure is isolated from the source material layer by a first insulating layer, and the gate structure is connected to the source material layer. The drain material layers are separated by a second insulating layer; wherein, the gate structure includes a gate dielectric layer and a gate material layer, and the gate dielectric layer surrounds the outer side surface of the carbon nanotube bundle unit, so The gate material layer surrounds the outer side surface of the gate material layer.
可选地,所述碳纳米管束场效应晶体管阵列还包括基底及形成于所述基底上的第三绝缘层,所述源极材料层形成于所述第三绝缘层上。Optionally, the carbon nanotube bundle field effect transistor array further includes a substrate and a third insulating layer formed on the substrate, and the source material layer is formed on the third insulating layer.
可选地,所述碳纳米管束单元的轴向与所述源极材料层所在平面之间的角度为80°~100°。Optionally, the angle between the axial direction of the carbon nanotube bundle unit and the plane where the source material layer is located is 80°˜100°.
可选地,所述碳纳米管束单元的高度大于100μm。Optionally, the height of the carbon nanotube bundle unit is greater than 100 μm.
可选地,所述栅极介质层采用高K介质,所述栅极材料层包括金属材料。Optionally, the gate dielectric layer adopts a high-K dielectric, and the gate material layer includes a metal material.
可选地,所述源极材料层与漏极材料层均包括金属材料。Optionally, both the source material layer and the drain material layer include metal materials.
本发明还提供一种碳纳米管束场效应晶体管阵列的制造方法,包括如下步骤:The present invention also provides a method for manufacturing a carbon nanotube bundle field effect transistor array, comprising the following steps:
S1:提供一基底,在所述基底上依次形成第三绝缘层、源极材料层及第一绝缘层;S1: providing a substrate, and sequentially forming a third insulating layer, a source material layer and a first insulating layer on the substrate;
S2:在所述第一绝缘层中形成通孔阵列;所述通孔阵列包括若干分立设置的通孔,所述通孔暴露出所述源极材料层上表面;S2: forming a through hole array in the first insulating layer; the through hole array includes a plurality of discrete through holes, and the through holes expose the upper surface of the source material layer;
S3:基于所述通孔阵列形成碳纳米管束阵列;所述碳纳米管束阵列包括若干与所述通孔位置相对应的碳纳米管束单元,其中,所述碳纳米管束单元的轴向第一端与所述源极材料层连接;S3: forming a carbon nanotube bundle array based on the through hole array; the carbon nanotube bundle array includes a plurality of carbon nanotube bundle units corresponding to the positions of the through holes, wherein the axial first end of the carbon nanotube bundle unit connected with the source material layer;
S4:形成覆盖所述碳纳米管束单元外侧面的栅极介质层;S4: forming a gate dielectric layer covering the outer side surface of the carbon nanotube bundle unit;
S5:形成覆盖所述栅极介质层外侧面的栅极材料层;S5: forming a gate material layer covering the outer side surface of the gate dielectric layer;
S6:依次形成第二绝缘层及漏极材料层,其中,所述碳纳米管束单元的轴向第二端与所述漏极材料层连接,所述栅极介质层及栅极材料层与所述漏极材料层之间通过第二绝缘层隔离。S6: forming a second insulating layer and a drain material layer in sequence, wherein the axial second end of the carbon nanotube bundle unit is connected to the drain material layer, and the gate dielectric layer and the gate material layer are connected to the drain material layer. The drain material layers are isolated by a second insulating layer.
可选地,于所述步骤S3中,在保护性气氛下,利用催化剂及碳源,通过化学气相沉积法形成所述碳纳米管束阵列。Optionally, in the step S3, in a protective atmosphere, the carbon nanotube bundle array is formed by a chemical vapor deposition method using a catalyst and a carbon source.
可选地,所述保护性气氛包括N2、H2、Ar中的一种或多种,所述催化剂包括Fe、Ni、Co中的一种或多种,所述碳纳米管束阵列的生长温度范围是500~740℃。Optionally, the protective atmosphere includes one or more of N 2 , H 2 , and Ar, the catalyst includes one or more of Fe, Ni, and Co, and the growth of the carbon nanotube bundle array The temperature range is 500 to 740°C.
可选地,首先基于所述通孔阵列在所述源极材料层上表面形成所述催化剂,然后基于所述催化剂生长所述碳纳米管束阵列。Optionally, firstly, the catalyst is formed on the upper surface of the source material layer based on the through hole array, and then the carbon nanotube bundle array is grown based on the catalyst.
可选地,将包含催化剂离子的溶液施加于所述源极材料层表面,并进行退火,以增加催化剂离子与所述源极材料层的结合强度。Optionally, a solution containing catalyst ions is applied to the surface of the source material layer and annealed to increase the bonding strength of the catalyst ions and the source material layer.
可选地,所述退火的温度范围是700~900℃,退火时间为30~90min。Optionally, the temperature range of the annealing is 700˜900° C., and the annealing time is 30˜90 min.
可选地,还包括去除所述第二绝缘层表面多余的催化剂离子的步骤。Optionally, it also includes the step of removing excess catalyst ions on the surface of the second insulating layer.
可选地,通过湿法腐蚀去除所述第二绝缘层表面多余的催化剂离子。Optionally, excess catalyst ions on the surface of the second insulating layer are removed by wet etching.
可选地,所述碳纳米管束单元的轴向与所述源极材料层所在平面之间的角度为80°~100°。Optionally, the angle between the axial direction of the carbon nanotube bundle unit and the plane where the source material layer is located is 80°˜100°.
可选地,所述碳纳米管束单元的高度大于100μm。Optionally, the height of the carbon nanotube bundle unit is greater than 100 μm.
如上所述,本发明的碳纳米管束场效应晶体管阵列及其制造方法,具有以下有益效果:本发明的碳纳米管束场效应晶体管阵列采用碳纳米管束作为沟道材料,其中碳纳米管束单元只有外部的碳纳米管被栅极介质层所包围,而内部的碳纳米管并没有被栅极介质层所包围,但由于碳纳米管束中各碳纳米管之间的相互作用,处于碳纳米管束单元内部的碳纳米管仍然能够发挥有效作用。本发明的碳纳米管束场效应晶体管阵列能够耐受更高的操作电压及操作电流,能够应用于大功率器件。并且本发明采用环栅结构,可以提高栅极对沟道的操控能力。本发明的碳纳米管束场效应晶体管阵列的制造方法具有工艺步骤简单的特点,有利于降低生产成本。As mentioned above, the carbon nanotube bundle field effect transistor array of the present invention and the manufacturing method thereof have the following beneficial effects: the carbon nanotube bundle field effect transistor array of the present invention adopts carbon nanotube bundles as channel materials, wherein the carbon nanotube bundle unit has only external The carbon nanotubes are surrounded by the gate dielectric layer, and the inner carbon nanotubes are not surrounded by the gate dielectric layer, but due to the interaction between the carbon nanotubes in the carbon nanotube bundle, they are inside the carbon nanotube bundle unit. The carbon nanotubes can still play an effective role. The carbon nanotube bundle field effect transistor array of the present invention can withstand higher operating voltage and operating current, and can be applied to high-power devices. Moreover, the present invention adopts the gate-all-around structure, which can improve the control ability of the gate to the channel. The manufacturing method of the carbon nanotube bundle field effect transistor array of the present invention has the characteristics of simple process steps, which is beneficial to reduce the production cost.
附图说明Description of drawings
图1显示为本发明的碳纳米管束场效应晶体管阵列的结构示意图。FIG. 1 is a schematic diagram showing the structure of the carbon nanotube bundle field effect transistor array of the present invention.
图2显示为本发明的碳纳米管束场效应晶体管阵列的制造方法在所述基底上依次形成第三绝缘层、源极材料层及第一绝缘层的示意图。FIG. 2 is a schematic diagram of sequentially forming a third insulating layer, a source material layer and a first insulating layer on the substrate according to the method for manufacturing a carbon nanotube bundle field effect transistor array of the present invention.
图3显示为本发明的碳纳米管束场效应晶体管阵列的制造方法在所述第一绝缘层中形成通孔阵列的示意图。FIG. 3 is a schematic diagram illustrating the formation of a through hole array in the first insulating layer according to the manufacturing method of the carbon nanotube bundle field effect transistor array of the present invention.
图4显示为本发明的碳纳米管束场效应晶体管阵列的制造方法基于所述通孔阵列在所述源极材料层上表面形成所述催化剂的示意图。FIG. 4 is a schematic diagram showing the formation of the catalyst on the upper surface of the source material layer based on the through hole array in the manufacturing method of the carbon nanotube bundle field effect transistor array of the present invention.
图5显示为本发明的碳纳米管束场效应晶体管阵列的制造方法基于所述催化剂生长所述碳纳米管束阵列的示意图。FIG. 5 shows a schematic diagram of growing the carbon nanotube bundle array based on the catalyst in the manufacturing method of the carbon nanotube bundle field effect transistor array of the present invention.
图6显示为本发明的碳纳米管束场效应晶体管阵列的制造方法形成覆盖所述碳纳米管束单元外侧面的栅极介质层的示意图。FIG. 6 is a schematic diagram of forming a gate dielectric layer covering the outer side surface of the carbon nanotube bundle unit according to the manufacturing method of the carbon nanotube bundle field effect transistor array of the present invention.
图7显示为本发明的碳纳米管束场效应晶体管阵列的制造方法形成覆盖所述栅极介质层外侧面的栅极材料层的示意图。FIG. 7 is a schematic diagram of forming a gate material layer covering the outer side surface of the gate dielectric layer by the method for manufacturing a carbon nanotube bundle field effect transistor array of the present invention.
图8显示为本发明的碳纳米管束场效应晶体管阵列的制造方法去除部分栅极介质层及栅极材料层,以暴露碳纳米管束阵列上部的示意图。FIG. 8 is a schematic diagram of removing part of the gate dielectric layer and the gate material layer to expose the upper part of the carbon nanotube bundle array according to the manufacturing method of the carbon nanotube bundle field effect transistor array of the present invention.
图9显示为本发明的碳纳米管束场效应晶体管阵列的制造方法形成第二绝缘层及漏极材料层的示意图。FIG. 9 is a schematic diagram illustrating the formation of the second insulating layer and the drain material layer in the method for manufacturing the carbon nanotube bundle field effect transistor array of the present invention.
元件标号说明Component label description
101 基底101 Substrate
102 第三绝缘层102 The third insulating layer
103 源极材料层103 Source material layer
104 第一绝缘层104 first insulating layer
105 碳纳米管束单元105 carbon nanotube bundle units
106 栅极介质层106 gate dielectric layer
107 栅极材料层107 Gate Material Layer
108 第二绝缘层108 Second insulating layer
109 漏极材料层109 Drain material layer
110 通孔110 through hole
111 催化剂111 Catalyst
具体实施方式Detailed ways
以下通过特定的具体实例说明本发明的实施方式,本领域技术人员可由本说明书所揭露的内容轻易地了解本发明的其他优点与功效。本发明还可以通过另外不同的具体实施方式加以实施或应用,本说明书中的各项细节也可以基于不同观点与应用,在没有背离本发明的精神下进行各种修饰或改变。The embodiments of the present invention are described below through specific specific examples, and those skilled in the art can easily understand other advantages and effects of the present invention from the contents disclosed in this specification. The present invention can also be implemented or applied through other different specific embodiments, and various details in this specification can also be modified or changed based on different viewpoints and applications without departing from the spirit of the present invention.
请参阅图1至图9。需要说明的是,本实施例中所提供的图示仅以示意方式说明本发明的基本构想,遂图式中仅显示与本发明中有关的组件而非按照实际实施时的组件数目、形状及尺寸绘制,其实际实施时各组件的型态、数量及比例可为一种随意的改变,且其组件布局型态也可能更为复杂。See Figures 1 to 9. It should be noted that the drawings provided in this embodiment are only to illustrate the basic concept of the present invention in a schematic way, so the drawings only show the components related to the present invention rather than the number, shape and the number of components in actual implementation. For dimension drawing, the type, quantity and proportion of each component can be changed at will in actual implementation, and the component layout may also be more complicated.
实施例一Example 1
本发明提供一种碳纳米管束场效应晶体管阵列,请参阅图1,显示为该碳纳米管束场效应晶体管阵列的结构示意图,包括:The present invention provides a carbon nanotube bundle field effect transistor array. Please refer to FIG. 1 , which is a schematic structural diagram of the carbon nanotube bundle field effect transistor array, including:
源极材料层103;
漏极材料层109,形成于所述源极材料层103上方;The
碳纳米管束阵列,连接于所述源极材料层103与所述漏极材料层109之间;所述碳纳米管束阵列包括若干分立设置的碳纳米管束单元105,其中,所述碳纳米管束单元105的轴向第一端与所述源极材料层103连接,所述碳纳米管束单元105的轴向第二端与所述漏极材料层109连接;A carbon nanotube bundle array, connected between the
栅极结构,形成于所述碳纳米管束阵列中各个碳纳米管束单元105之间,且所述栅极结构与所述源极材料层103之间通过第一绝缘层104隔离,所述栅极结构与所述漏极材料层109之间通过第二绝缘层108隔离;其中,所述栅极结构包括栅极介质层106及栅极材料层107,所述栅极介质层106包围所述碳纳米管束单元105的外侧面,所述栅极材料层107包围所述栅极材料层107的外侧面。The gate structure is formed between each carbon
本实施例中,所述碳纳米管束场效应晶体管阵列还包括基底101及形成于所述基底101上的第三绝缘层102,所述源极材料层103形成于所述第三绝缘层102上。In this embodiment, the carbon nanotube bundle field effect transistor array further includes a
具体的,所述基底101包括但不限于Si、Ge等常规半导体衬底材料。所述第三绝缘层102可采用氧化硅或其它绝缘材料,用于将所述源极材料层103与所述基底101隔离。Specifically, the
具体的,每个碳纳米管束单元105均作为一个场效应晶体管的沟道材料,其轴向两端分别与所述源极材料层103及所述漏极材料层109连接。所述源极材料层103作为碳纳米管束场效应晶体管的N+型源极,所述漏极材料层109作为碳纳米管束场效应晶体管的N+型漏极。Specifically, each carbon
本实施例中,所述碳纳米管束单元105的高度大于100μm。所述碳纳米管束单元105的轴向与所述源极材料层103所在平面之间的角度为80°~100°,优选为90°。换句话说,所述碳纳米管束单元105的轴向与所述源极材料层103所在平面垂直,或基本垂直。In this embodiment, the height of the carbon
具体的,所述碳纳米管束单元105由多根碳纳米管组成,其中,只有位于碳纳米管束外围的碳纳米管被所述栅极介质层106部分包围或全部包围,而位于碳纳米管束内部的碳纳米管并没有被栅极介质层106所包围,但由于碳纳米管束中各碳纳米管之间的相互作用,处于所述碳纳米管束单元105内部的碳纳米管仍然能够发挥有效作用。相对于单根碳纳米管作为沟道,本发明采用包含多根碳纳米管的碳纳米管束作为沟道材料,可以使得碳纳米管束场效应晶体管阵列耐受更高的操作电压及操作电流,从而能够应用于大功率器件。Specifically, the carbon
本发明中,由于所述栅极介质层106包围所述碳纳米管束单元105的外侧面,所述栅极材料层107包围所述栅极材料层107的外侧面,使得所述栅极结构构成环栅结构,可以提高栅极对碳纳米管束沟道的操控能力。In the present invention, since the
作为示例,所述栅极结构中,所述栅极介质层106采用高K介质(高于二氧化硅的介电常数3.9),例如铪基氧化物,HfO2、HfSiO、HfSiON、HfTaO、HfTiO等,或者其他介电材料。所述栅极材料层107采用金属栅,其包括金属材料,例如包括Ti、Ta、Hf、Ni、Ru、Ir、Au、Pt、Al、Co、W、Mo中的任意一种或其合金中的任意一种。As an example, in the gate structure, the
作为示例,所述源极材料层103与漏极材料层109也均包括金属材料,例如包括Ti、Ta、Hf、Ni、Ru、Ir、Au、Pt、Al、Co、W、Mo中的任意一种或其合金中的任意一种。As an example, both the
本发明的碳纳米管束场效应晶体管阵列采用碳纳米管束作为沟道材料,并采用环栅结构,不仅能够应用于大功率器件,并且具有较强的沟道控制能力。The carbon nanotube bundle field effect transistor array of the present invention adopts carbon nanotube bundles as channel materials and adopts a gate-all-around structure, which can not only be applied to high-power devices, but also has strong channel control capability.
实施例二Embodiment 2
本发明还提供一种碳纳米管束场效应晶体管阵列的制造方法,包括如下步骤:The present invention also provides a method for manufacturing a carbon nanotube bundle field effect transistor array, comprising the following steps:
首先请参阅图2,执行步骤S1:提供一基底101,在所述基底101上依次形成第三绝缘层102、源极材料层103及第一绝缘层104。Referring first to FIG. 2 , step S1 is performed: a
具体的,所述基底101包括但不限于Si、Ge等常规半导体衬底材料。所述第三绝缘层102采用氧化硅或其它绝缘材料,用于将所述源极材料层103与所述基底101隔离。所述源极材料层103包括金属材料,例如包括Ti、Ta、Hf、Ni、Ru、Ir、Au、Pt、Al、Co、W、Mo中的任意一种或其合金中的任意一种。所述第一绝缘层104采用氧化硅或其它绝缘材料。Specifically, the
所述第三绝缘层102、源极材料层103、第一绝缘层104可采用物理气相沉积法或化学气相沉积法形成。The third
然后请参阅图3,执行步骤S2:在所述第一绝缘层104中形成通孔阵列;所述通孔阵列包括若干分立设置的通孔110,所述通孔110暴露出所述源极材料层103上表面。Then referring to FIG. 3 , step S2 is performed: forming a via array in the first insulating
具体的,通过光刻、刻蚀等工艺步骤形成所述通孔阵列。所述通孔110的形状包括但不限于多边形、圆形、椭圆形等。Specifically, the through hole array is formed by photolithography, etching and other process steps. The shape of the through
接着请参阅图4-图5,执行步骤S3:基于所述通孔阵列形成碳纳米管束阵列;所述碳纳米管束阵列包括若干与所述通孔110位置相对应的碳纳米管束单元105,其中,所述碳纳米管束单元105的轴向第一端与所述源极材料层103连接。Next, referring to FIGS. 4-5 , step S3 is performed: forming a carbon nanotube bundle array based on the through hole array; the carbon nanotube bundle array includes a plurality of carbon
具体的,每个通孔110对应于一个碳纳米管束单元105,每个碳纳米管束单元105均作为一个场效应晶体管的沟道材料。Specifically, each through
本实施例中,在保护性气氛下,利用催化剂及碳源,通过化学气相沉积法形成所述碳纳米管束阵列。所述保护性气氛包括N2、H2、Ar中的一种或多种,所述碳源包括但不限于甲烷、乙炔等含碳气体,所述催化剂包括Fe、Ni、Co中的一种或多种,所述碳纳米管束阵列的生长温度范围是500~740℃。In this embodiment, in a protective atmosphere, the carbon nanotube bundle array is formed by chemical vapor deposition using a catalyst and a carbon source. The protective atmosphere includes one or more of N 2 , H 2 , and Ar, the carbon source includes but is not limited to carbon-containing gases such as methane and acetylene, and the catalyst includes one of Fe, Ni, and Co. Or more, the growth temperature range of the carbon nanotube bundle array is 500-740°C.
具体的,如图4所示,首先基于所述通孔阵列在所述源极材料层103上表面形成所述催化剂111。作为示例,将包含催化剂离子的溶液施加于所述源极材料层103表面,以形成所述催化剂111。本实施例中,还包括行退火的步骤,以增加催化剂离子与所述源极材料层103的结合强度。所述退火的温度范围是700~900℃,退火时间为30~90min。Specifically, as shown in FIG. 4 , the
进一步的,退火之后,还包括去除所述第二绝缘层104表面多余的催化剂离子的步骤。作为示例,通过湿法腐蚀去除所述第二绝缘层104表面多余的催化剂离子。Further, after the annealing, the step of removing excess catalyst ions on the surface of the second insulating
如图5所示,然后基于所述催化剂111生长所述碳纳米管束阵列。本实施例中,所述碳纳米管束单元105的轴向与所述源极材料层103所在平面之间的角度为80°~100°,优选为90°。换句话说,所述碳纳米管束单元105的轴向与所述源极材料层103所在平面垂直,或基本垂直。As shown in FIG. 5 , the carbon nanotube bundle array is then grown based on the
作为示例,将处理过的基底置于反应炉中,在保护气体环境下加热到500℃~740℃,然后通入碳源气体并反应约5~30分钟,生长得到碳纳米管束阵列,其高度大于100微米。该碳纳米管束阵列为多个彼此平行且垂直于基底生长的碳纳米管形成的纯碳纳米管束阵列。该碳纳米管束与所述通孔面积基本相同。通过上述控制生长条件,该超顺排碳纳米管束阵列中基本不含有无定型碳或残留的催化剂金属颗粒等杂质。As an example, the treated substrate is placed in a reaction furnace, heated to 500°C to 740°C in a protective gas environment, and then a carbon source gas is introduced and reacted for about 5 to 30 minutes to grow a carbon nanotube bundle array with a height of greater than 100 microns. The carbon nanotube bundle array is a pure carbon nanotube bundle array formed by a plurality of carbon nanotubes grown parallel to each other and perpendicular to the substrate. The carbon nanotube bundle has substantially the same area as the through hole. By controlling the growth conditions above, the super-aligned carbon nanotube bundle array basically does not contain impurities such as amorphous carbon or residual catalyst metal particles.
再请参阅图6,执行步骤S4:形成覆盖所述碳纳米管束单元105外侧面的栅极介质层106。Referring to FIG. 6 again, step S4 is performed: forming a
具体的,采用物理气相趁机沉积法或化学气相沉积法形成所述栅极介质层106。作为示例,所述栅极介质层106采用高K介质(高于二氧化硅的介电常数3.9),例如铪基氧化物,HfO2、HfSiO、HfSiON、HfTaO、HfTiO等,或者其他介电材料。Specifically, the
再请参阅图7,执行步骤S5:形成覆盖所述栅极介质层106外侧面的栅极材料层107。Referring to FIG. 7 again, step S5 is performed: forming a
具体的,采用物理气相趁机沉积法或化学气相沉积法形成所述栅极材料层107。作为示例,所述栅极材料层107采用金属栅,其包括金属材料,例如包括Ti、Ta、Hf、Ni、Ru、Ir、Au、Pt、Al、Co、W、Mo中的任意一种或其合金中的任意一种。Specifically, the
进一步的,如图8所示,去除部分所述栅极材料层107及栅极介质层106,暴露出所述碳纳米管束阵列上部。去除方法可以是湿法腐蚀或等离子体刻蚀等适合的方法。Further, as shown in FIG. 8 , part of the
最后请参阅图9,执行步骤S6:依次形成第二绝缘层108及漏极材料层109,其中,所述碳纳米管束单元105的轴向第二端与所述漏极材料层109连接,所述栅极介质层106及栅极材料层107与所述漏极材料层109之间通过第二绝缘层108隔离。Finally, referring to FIG. 9 , step S6 is performed: forming a second insulating
具体的,所述第二绝缘层108采用氧化硅或其它绝缘材料,所述漏极材料层109包括金属材料,例如包括Ti、Ta、Hf、Ni、Ru、Ir、Au、Pt、Al、Co、W、Mo中的任意一种或其合金中的任意一种。Specifically, the second insulating
具体的,所述碳纳米管束单元105顶端嵌入所述漏极材料层109中,可增加所述碳纳米管束单元105与所述漏极材料层109之间连接的牢固度。Specifically, the top of the carbon
至此,制造完成了本发明的碳纳米管束场效应晶体管阵列。本发明的碳纳米管束场效应晶体管阵列的制造方法具有工艺步骤简单的特点,有利于降低生产成本。So far, the carbon nanotube bundle field effect transistor array of the present invention is completed. The manufacturing method of the carbon nanotube bundle field effect transistor array of the present invention has the characteristics of simple process steps, which is beneficial to reduce the production cost.
综上所述,本发明的碳纳米管束场效应晶体管阵列采用碳纳米管束作为沟道材料,其中碳纳米管束单元只有外部的碳纳米管被栅极介质层所包围,而内部的碳纳米管并没有被栅极介质层所包围,但由于碳纳米管束中各碳纳米管之间的相互作用,处于碳纳米管束单元内部的碳纳米管仍然能够发挥有效作用。本发明的碳纳米管束场效应晶体管阵列能够耐受更高的操作电压及操作电流,能够应用于大功率器件。并且本发明采用环栅结构,可以提高栅极对沟道的操控能力。本发明的碳纳米管束场效应晶体管阵列的制造方法具有工艺步骤简单的特点,有利于降低生产成本。所以,本发明有效克服了现有技术中的种种缺点而具高度产业利用价值。To sum up, the carbon nanotube bundle field effect transistor array of the present invention uses carbon nanotube bundles as channel materials, wherein only the outer carbon nanotubes of the carbon nanotube bundle unit are surrounded by the gate dielectric layer, and the inner carbon nanotubes are not It is not surrounded by the gate dielectric layer, but due to the interaction between the carbon nanotubes in the carbon nanotube bundle, the carbon nanotubes inside the carbon nanotube bundle unit can still play an effective role. The carbon nanotube bundle field effect transistor array of the present invention can withstand higher operating voltage and operating current, and can be applied to high-power devices. Moreover, the present invention adopts the gate-all-around structure, which can improve the control ability of the gate to the channel. The manufacturing method of the carbon nanotube bundle field effect transistor array of the present invention has the characteristics of simple process steps, which is beneficial to reduce the production cost. Therefore, the present invention effectively overcomes various shortcomings in the prior art and has high industrial application value.
上述实施例仅例示性说明本发明的原理及其功效,而非用于限制本发明。任何熟悉此技术的人士皆可在不违背本发明的精神及范畴下,对上述实施例进行修饰或改变。因此,举凡所属技术领域中具有通常知识者在未脱离本发明所揭示的精神与技术思想下所完成的一切等效修饰或改变,仍应由本发明的权利要求所涵盖。The above-mentioned embodiments merely illustrate the principles and effects of the present invention, but are not intended to limit the present invention. Anyone skilled in the art can modify or change the above embodiments without departing from the spirit and scope of the present invention. Therefore, all equivalent modifications or changes made by those with ordinary knowledge in the technical field without departing from the spirit and technical idea disclosed in the present invention should still be covered by the claims of the present invention.
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CN1638066A (en) * | 2004-01-07 | 2005-07-13 | 国际商业机器公司 | Vertical carbon nanotube field effect transistor |
CN101217128A (en) * | 2007-01-04 | 2008-07-09 | 奇梦达股份公司 | Method for making an integrated circuit having a via hole |
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CN1638066A (en) * | 2004-01-07 | 2005-07-13 | 国际商业机器公司 | Vertical carbon nanotube field effect transistor |
US8168495B1 (en) * | 2006-12-29 | 2012-05-01 | Etamota Corporation | Carbon nanotube high frequency transistor technology |
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