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CN108250848A - A kind of pipeline impregnation - Google Patents

A kind of pipeline impregnation Download PDF

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Publication number
CN108250848A
CN108250848A CN201711433227.5A CN201711433227A CN108250848A CN 108250848 A CN108250848 A CN 108250848A CN 201711433227 A CN201711433227 A CN 201711433227A CN 108250848 A CN108250848 A CN 108250848A
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CN
China
Prior art keywords
pipeline
parts
gas piping
corrosion
impregnation
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711433227.5A
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Chinese (zh)
Inventor
何超
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chongqing Ante Pipe Industry Co Ltd
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Chongqing Ante Pipe Industry Co Ltd
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Priority to CN201711433227.5A priority Critical patent/CN108250848A/en
Publication of CN108250848A publication Critical patent/CN108250848A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/10Homopolymers or copolymers of propene
    • C09D123/12Polypropene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0218Pretreatment, e.g. heating the substrate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0254After-treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/10Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by other chemical means
    • B05D3/102Pretreatment of metallic substrates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • B05D7/146Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies to metallic pipes or tubes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/08Iron or steel
    • C23G1/083Iron or steel solutions containing H3PO4
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2507/00Polyolefins
    • B05D2507/01Polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2507/00Polyolefins
    • B05D2507/02Polypropylene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)
  • Rigid Pipes And Flexible Pipes (AREA)

Abstract

In order to solve the problem of that the bad production maintenance of the antiseptic property of current gas piping is of high cost, the present invention provides a kind of antiseptic finish methods of gas piping, include the following steps:Derusting;After processing of rust removing smearing asphalt primer is carried out in 1 hour;Pipeline is heated, gas piping temperature controls 190 DEG C~210 DEG C after heating, then spraying corrosion resistant coating;Finishing coat is smeared, finishing coat uses polyurethane anti-corrosion paint.The antiseptic finish method of gas piping of the present invention is used and is first primed, clinkering type ring oxygen powder bed is further added by, finally smears the mode of finishing coat, main function is being capable of anti-corrosion, extraneous more complicated soil environment and climatic environment are resisted, the ability with extremely strong weatherability and resistant to mechanical damage.

Description

一种管道浸塑工艺A pipe impregnation process

技术领域technical field

本发明涉及管道加工技术领域,尤其涉及一种管道的防锈加工领域。The invention relates to the technical field of pipeline processing, in particular to the field of antirust processing of pipelines.

背景技术Background technique

在现有技术中,常用的管道防腐采用镀锌管,镀锌钢管质地坚硬,刚度大、韧性高、坚固可靠,应用广泛;镀锌钢管与现有各种塑料管道相比较,其主要缺陷表现在管道内壁经长期水流浸泡,会产生锈蚀,管道内壁逐渐变成疏松、凹凸不平,增大水阻,而更为严重的是内壁锈蚀导致水含铁锈;于是出现了很多工程塑料管,塑料管道与传统钢管相比,具有自重轻,耐腐蚀、使用寿命长,水流阻力小、节约能源等优点,但塑料管道的耐压、耐撞击性能、耐高低温反复变化性能都比传统钢管差很多,因此,如何做到又能耐压又能防锈是本领域技术人员所遇到的问题。In the prior art, galvanized pipes are commonly used for anti-corrosion of pipelines. Galvanized steel pipes are hard in texture, high in rigidity, high in toughness, solid and reliable, and widely used. Compared with various existing plastic pipes, galvanized steel pipes have major defects After long-term water immersion on the inner wall of the pipeline, corrosion will occur, and the inner wall of the pipeline will gradually become loose and uneven, increasing water resistance, and what is more serious is that the corrosion of the inner wall will cause water to contain rust; so many engineering plastic pipes and plastic pipes have appeared. Compared with traditional steel pipes, it has the advantages of light weight, corrosion resistance, long service life, small water flow resistance, and energy saving. However, the pressure resistance, impact resistance, and high and low temperature resistance of plastic pipes are much worse than traditional steel pipes. Therefore, how to achieve both pressure resistance and rust prevention is a problem encountered by those skilled in the art.

发明内容Contents of the invention

为了解决目前管道又能耐压又能防锈的需求,本发明提供了一种管道浸塑工艺,其目的在于提供一种耐腐蚀、不生锈、管壁光滑,且刚直不易变形、耐热、耐压的管道。In order to solve the current demand for pipelines to be pressure-resistant and rust-proof, the present invention provides a plastic dipping process for pipelines. , Pressure-resistant pipelines.

本发明涉及的一种管道浸塑工艺,包括以下步骤:A kind of pipeline dipping process that the present invention relates to comprises the following steps:

S1:除锈,将管路浸泡在酸洗液中进行除锈;S1: Rust removal, soak the pipeline in pickling solution for rust removal;

S2:清洗,并干燥,清洗液采用浓度为15~20%的皂化液;S2: cleaning and drying, the cleaning solution is a saponification solution with a concentration of 15-20%;

S3:浸塑,对管道进行加热至100℃~150℃,进行滚塑处理,所述滚塑材料为聚烯烃改性材料;S3: dipping, heating the pipe to 100°C-150°C, and performing rotomolding treatment, the rotomoulding material is a polyolefin modified material;

S4:保温,对浸塑后的管道进行在80℃~120℃范围内保温5min~10min;S4: heat preservation, heat preservation of the pipe after dipping in the range of 80 ℃ to 120 ℃ for 5 minutes to 10 minutes;

S5:冷却检测,将保温后的浸塑管道自然冷却至常温,然后检测是否合格。S5: Cooling test, cool the plastic-impregnated pipe after heat preservation to normal temperature naturally, and then test whether it is qualified.

进一步地,所述酸洗液体积配比为盐酸40%,磷酸30%,三乙醇胺7%,硫酸11%,十二烷基硫酸钠8%,其余用蒸馏水补充到100%。Further, the volume ratio of the pickling liquid is 40% of hydrochloric acid, 30% of phosphoric acid, 7% of triethanolamine, 11% of sulfuric acid, 8% of sodium lauryl sulfate, and the rest is replenished to 100% with distilled water.

进一步地,第二步骤中皂化温度控制在100℃~120℃,时间3~5min。Further, in the second step, the saponification temperature is controlled at 100° C. to 120° C. for 3 to 5 minutes.

进一步地,所述聚烯烃改性材料成分重量配比包括:聚丙烯15份、聚乙烯12份、碳酸钙17份、有机硅化合物3份。Further, the weight proportion of the polyolefin modified material includes: 15 parts of polypropylene, 12 parts of polyethylene, 17 parts of calcium carbonate, and 3 parts of organosilicon compound.

本发明采用浸塑的方法在管道内外表面形成塑料防腐层,具有机械强度高,承压能力强,电器绝缘能力优秀,外表面硬度高且光滑,摩擦系数小,吸水率低、使用温度范围大等钢塑复合管道固有的特性。The invention adopts the method of dipping to form a plastic anti-corrosion layer on the inner and outer surfaces of the pipeline, which has high mechanical strength, strong pressure bearing capacity, excellent electrical insulation ability, high hardness and smooth outer surface, small friction coefficient, low water absorption rate, and wide service temperature range. and other inherent characteristics of steel-plastic composite pipes.

具体实施方式Detailed ways

本发明一种管道浸塑工艺在实际使用中,采用普通碳钢管作为基础管道,在本实施例中具体加工方式如下:In the actual use of a pipeline dipping process of the present invention, ordinary carbon steel pipes are used as the basic pipeline, and the specific processing methods in this embodiment are as follows:

S1:除锈,将管路浸泡在酸洗液中进行除锈;在本实施例中,酸洗液体积配比为盐酸40%, 磷酸30%,三乙醇胺7%,硫酸11%,十二烷基硫酸钠8%,其余用蒸馏水补充到100%;酸洗缓蚀剂的加入既不影响金属表面锈斑的祛除,又能保证制件基体尽可能少的被酸性溶液腐蚀。S1: Rust removal, soak the pipeline in pickling solution for rust removal; in this embodiment, the volume ratio of the pickling solution is 40% hydrochloric acid, 30% phosphoric acid, 7% triethanolamine, 11% sulfuric acid, dodecyl Sodium alkyl sulfate is 8%, and the rest is added to 100% with distilled water; the addition of pickling corrosion inhibitor will not affect the removal of rust spots on the metal surface, and can ensure that the substrate of the workpiece is corroded by the acid solution as little as possible.

S2:清洗,并干燥;将除锈后的管道放入浓度为15~20%的皂化液里进行皂化处理,皂化温度控制在100℃~120℃,时间3~5min,清洗酸洗后的残余液体,同时防止管路生锈。S2: Clean and dry; put the rust-removed pipeline into saponification solution with a concentration of 15-20% for saponification treatment, control the saponification temperature at 100°C-120°C for 3-5 minutes, and clean the residue after pickling Liquid, while preventing the pipeline from rusting.

S3:浸塑,对管道进行加热至100℃~150℃,进行滚塑处理,为了提高防腐性能,滚塑材料为聚烯烃改性材料,为提高涂层与基材的附着力,本实施例中聚烯烃改性材料成分重量配比包括:聚丙烯15份、聚乙烯12份、碳酸钙17份、有机硅化合物3份。S3: dipping, heating the pipe to 100°C-150°C, and performing rotomolding treatment. In order to improve anti-corrosion performance, the rotomolding material is a polyolefin modified material. In order to improve the adhesion between the coating and the substrate, this embodiment The weight proportion of the polyolefin modified material includes: 15 parts of polypropylene, 12 parts of polyethylene, 17 parts of calcium carbonate, and 3 parts of organosilicon compound.

S4:保温,为了对浸塑层固化,对浸塑后的管道进行在80℃~120℃范围内保温5min~10min。S4: Heat preservation. In order to cure the impregnated layer, heat the impregnated pipe at 80°C to 120°C for 5min to 10min.

S5:冷却检测,将保温后的浸塑管道自然冷却至常温,然后检测是否合格,在本实施例中主要检测浸塑管道表面是否浸塑均匀,以及浸塑厚度是否均匀。S5: Cooling inspection, cooling the heat-preserved plastic-impregnated pipe to normal temperature naturally, and then checking whether it is qualified. In this embodiment, it mainly detects whether the surface of the plastic-impregnated pipe is evenly impregnated with plastic, and whether the thickness of the impregnated plastic is uniform.

本发明采用浸塑的方法在管道内外表面形成塑料防腐层,具有机械强度高,承压能力强,电器绝缘能力优秀,外表面硬度高且光滑,摩擦系数小,吸水率低、使用温度范围大等钢塑复合管道固有的特性;并且本发明中采用聚烯烃改性材料涂层,适用于热水管道,使用该涂层的涂塑复合钢管,能适应较大的温差交替变化场合。The invention adopts the method of dipping to form a plastic anti-corrosion layer on the inner and outer surfaces of the pipeline, which has high mechanical strength, strong pressure bearing capacity, excellent electrical insulation ability, high hardness and smooth outer surface, small friction coefficient, low water absorption rate, and wide service temperature range. Such as the inherent characteristics of steel-plastic composite pipes; and the polyolefin modified material coating is used in the present invention, which is suitable for hot water pipes, and the plastic-coated composite steel pipes using this coating can adapt to the occasions where large temperature differences alternately change.

尽管上文对本发明的具体实施方式给予了详细描述和说明,但是应该指明的是,我们可以依据本发明的构想对上述实施方式进行各种等效改变和修改,其所产生的功能作用仍未超出说明书所涵盖的精神时,均应在本发明的保护范围之内。Although the specific embodiments of the present invention have been described and illustrated in detail above, it should be pointed out that we can make various equivalent changes and modifications to the above-mentioned embodiments according to the concept of the present invention, and the functional effects produced by it are still the same. Anything beyond the spirit covered by the description shall be within the protection scope of the present invention.

Claims (4)

1. a kind of pipeline impregnation, which is characterized in that include the following steps:
S1:Derusting, pipeline is immersed in pickle and is derusted;
S2:Cleaning, and it is dry, and cleaning solution uses a concentration of 15~20% saponification liquor;
S3:Leaching modeling carries out pipeline to be heated to 100 DEG C~150 DEG C, carries out rotational moulding processing, the rotational moulding material changes for polyolefin Property material;
S4:Heat preservation, the pipeline after being moulded to leaching are carried out in 80 DEG C~120 DEG C range inside holding 5min~10min;
S5:Leaching modeling pipeline after heat preservation is naturally cooled to room temperature, then detects whether qualification by cooling detection.
2. pipeline impregnation according to claim 1, which is characterized in that the pickle volume proportion is hydrochloric acid 40%, Phosphoric acid 30%, triethanolamine 7%, sulfuric acid 11%, lauryl sodium sulfate 8%, remaining adds to 100% with distilled water.
3. pipeline impregnation according to claim 1 or 2, which is characterized in that saponification temperature control exists in second step 100 DEG C~120 DEG C, 3~5min of time.
4. pipeline impregnation according to claim 4, which is characterized in that the polyolefine modified material Ingredients Weight is matched Than including:15 parts of polypropylene, 12 parts of polyethylene, 17 parts of calcium carbonate, 3 parts of organo-silicon compound.
CN201711433227.5A 2017-12-26 2017-12-26 A kind of pipeline impregnation Pending CN108250848A (en)

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Publication number Priority date Publication date Assignee Title
CN111019277A (en) * 2019-12-23 2020-04-17 苏州茂顺成通信技术有限公司 Composite reinforced chlorinated polyvinyl chloride cable sheath tube and manufacturing process thereof
CN115077736A (en) * 2022-05-24 2022-09-20 国网河北省电力有限公司磁县供电分公司 Thermochromic sheath and manufacturing process thereof

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Cited By (2)

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Publication number Priority date Publication date Assignee Title
CN111019277A (en) * 2019-12-23 2020-04-17 苏州茂顺成通信技术有限公司 Composite reinforced chlorinated polyvinyl chloride cable sheath tube and manufacturing process thereof
CN115077736A (en) * 2022-05-24 2022-09-20 国网河北省电力有限公司磁县供电分公司 Thermochromic sheath and manufacturing process thereof

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Application publication date: 20180706