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CN108256607A - A kind of temperature induced color changing bar-code label and its reading method - Google Patents

A kind of temperature induced color changing bar-code label and its reading method Download PDF

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Publication number
CN108256607A
CN108256607A CN201611236018.7A CN201611236018A CN108256607A CN 108256607 A CN108256607 A CN 108256607A CN 201611236018 A CN201611236018 A CN 201611236018A CN 108256607 A CN108256607 A CN 108256607A
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CN
China
Prior art keywords
color changing
temperature induced
induced color
bar
code label
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611236018.7A
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Chinese (zh)
Inventor
张义锦
郭栋
张享久
沈锦兴
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujian New Continent Automatic Recognition Technology Coltd
Fujian Newland Auto ID Technology Co Ltd
Original Assignee
Fujian New Continent Automatic Recognition Technology Coltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fujian New Continent Automatic Recognition Technology Coltd filed Critical Fujian New Continent Automatic Recognition Technology Coltd
Priority to CN201611236018.7A priority Critical patent/CN108256607A/en
Publication of CN108256607A publication Critical patent/CN108256607A/en
Pending legal-status Critical Current

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Classifications

    • GPHYSICS
    • G06COMPUTING OR CALCULATING; COUNTING
    • G06KGRAPHICAL DATA READING; PRESENTATION OF DATA; RECORD CARRIERS; HANDLING RECORD CARRIERS
    • G06K19/00Record carriers for use with machines and with at least a part designed to carry digital markings
    • G06K19/06Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code
    • G06K19/06009Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code with optically detectable marking
    • G06K19/06037Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code with optically detectable marking multi-dimensional coding
    • GPHYSICS
    • G06COMPUTING OR CALCULATING; COUNTING
    • G06KGRAPHICAL DATA READING; PRESENTATION OF DATA; RECORD CARRIERS; HANDLING RECORD CARRIERS
    • G06K19/00Record carriers for use with machines and with at least a part designed to carry digital markings
    • G06K19/06Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code
    • G06K19/06009Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code with optically detectable marking
    • G06K19/06046Constructional details
    • G06K19/06056Constructional details the marking comprising a further embedded marking, e.g. a 1D bar code with the black bars containing a smaller sized coding
    • GPHYSICS
    • G06COMPUTING OR CALCULATING; COUNTING
    • G06KGRAPHICAL DATA READING; PRESENTATION OF DATA; RECORD CARRIERS; HANDLING RECORD CARRIERS
    • G06K7/00Methods or arrangements for sensing record carriers, e.g. for reading patterns
    • G06K7/0008General problems related to the reading of electronic memory record carriers, independent of its reading method, e.g. power transfer

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Theoretical Computer Science (AREA)
  • Artificial Intelligence (AREA)
  • Computer Vision & Pattern Recognition (AREA)
  • Measuring Temperature Or Quantity Of Heat (AREA)

Abstract

A kind of temperature induced color changing bar-code label and its reading method, it is a kind of label for indicating vaccine product information and preserving state that the temperature, which becomes bar-code label, it includes the region of temperature induced color changing and the region comprising product information, and the region of the temperature induced color changing is made of VVM thermal labels.Temperature induced color changing bar-code label is read by using recognizing apparatus, a step is realized to read production information and preserve status information, accelerate the data input process of vaccine cold chain transportation and cold chain, the problem of improving typing accuracy, avoiding artificial fatiguability inefficiency under mass read mode.

Description

A kind of temperature induced color changing bar-code label and its reading method
Technical field
The present invention relates to bar code reading field more particularly to a kind of temperature induced color changing bar-code labels and its reading method.
Background technology
Vaccine is an important means of the mankind to anti-disease, but vaccine needs to preserve at low temperature, once vaccine surpasses Temperature gently then fails, heavy then do harm to huamn body.It is inoculated with the vaccine for storing cold chain transportations without 2 DEG C -8 DEG C or expired vaccine, note Primary risk after penetrating is to be immunized, such as this kind of fatal infectious disease complex of rabies in vain, originally can be immunized to keep away by vaccine inoculation Exempt from death, but be inoculated with problem vaccine cause it is immunologically effective, inoculator may infection morbidity it is dead.It is domestic before this once to occur to connect Kind rabies vaccine for immunization leads to the event of inoculator's death in vain.Secondary risk may cause to pollute for vaccine because storage is improper Or antigen denaturation, cause adverse reaction after injection.It is limited to monitoring technology in the past, can not judges high temperature exposure amount, it also just can not be true Determine whether overtemperature vaccine can also be continuing with.
In order to cope with it is this lead to the situation of vaccine failure because cold chain link careless mistake occurs, had one kind can be with The scheme of monitored over time vaccine temperature environment, that is, and vaccine bottle temperature monitoring (Vaccine Vial Monitor, hereinafter referred to as VVM thermal labels).The shape of VVM thermal labels is similar with China's ancient money, round outside but spuare inside, 10 millimeters of diameter.Intermediate is rectangular to live Property surface, include variable chemical composition, this chemical composition is combined with two big element of time and temperature, shows intermediate rectangular The variation of surface color, this variation are slow, progressive, accumulate, it is contemplated that and irreversible.
And the present service condition of VVM thermal labels is in vaccine inoculation, judges vaccine in heat by manual identified label Degree of exposure under environment, determines whether current vaccines can be injected, and when this method faces vaccine negligible amounts, workload is also It is not heavy, but when the transhipment of bulk vaccine is stored, outbound storage is made an inventory, pass through artificial judgment not only inefficiency and easily Generate erroneous judgement.Meanwhile in Input Process, the bar-code label with production information is in the different positions of vaccine bottle from VVM thermal labels It puts, the matching typing of production information and vaccine activity grade can not be just completed by single pass.
Invention content
The purpose of the present invention, can not because effective means of identification is lacked primarily directed to existing vaccine cold chain link The problem of whether identification vaccine fails because of temperature change, while existing VVM tag readable degrees method falls behind.
In order to solve the above-mentioned technical problem, the present invention uses following technical proposals:
A kind of temperature induced color changing bar-code label, including:Temperature induced color changing region, product information region;
It is characterized in that, the temperature induced color changing region is made of VVM thermal labels, reaction principle is the diacetylene being substituted (Diacetylene) color change occurs after the solid-state polymerization of monomer, the product information region is bar code, includes production Quotient, production time produce the product informations such as address, temperature induced color changing grade.
The temperature induced color changing bar-code label is two-dimensional bar code QR codes, and the temperature induced color changing region is located at the bar-code label Center.
The temperature induced color changing region is located at around the bar-code label.
The temperature induced color changing region includes color change interval and contrast district.
The temperature induced color changing grade of the bar-code label is divided into four grades, is VVM2, VVM7, VVM14 and VVM30 respectively. 2,7,14,30 refer to reach the terminal required time under conditions of being exposed to 37 degrees Celsius.
A kind of reading method of temperature induced color changing bar-code label, includes the following steps:
S1:Scanning device scans temperature induced color changing bar-code label;
S2:Determine the bar code information region;
S3:It decodes image and obtains production information and temperature induced color changing grade;
S5:Determine the temperature induced color changing region where VVM thermal labels region;
S6:Identify VVM thermal label colors;
S7:It according to temperature induced color changing grade, determines whether current vaccines fail, and transmits information to host computer.
The bar code information further includes VVM thermal labels region location information.
In the S6 steps, the VVM thermal labels can be assisted in identifying currently used state by human eye.
The above technical solution of the present invention has the following advantages over the prior art:
It is combined by by the combination of traditional bar code and VVM thermal labels, realizing production information and preserving status information, The data input process of vaccine cold chain transportation and cold chain is accelerated, typing accuracy is improved, by using bar code scan Equipment realizes the scanning of label the typing of product information and safe condition, when solving mass typing, manual identified Vaccine safety state inefficiency.
Description of the drawings
In order to make the content of the present invention more clearly understood, it below according to specific embodiments of the present invention and combines Attached drawing, the present invention is described in further detail, wherein
Fig. 1 is a kind of label schematic diagram of one embodiment of temperature induced color changing bar-code label of one embodiment of the invention.
Fig. 2 is existing VVM thermal labels schematic diagram.
Fig. 3 is a kind of work of one embodiment of the reading method of temperature induced color changing bar-code label of one embodiment of the invention Make flow chart.
Specific embodiment
As shown in Figure 1, be a kind of schematic diagram of one embodiment of temperature induced color changing bar-code label of the present invention, the temperature mutagens Color bar-code label includes:Temperature induced color changing region, product information region, wherein, the temperature induced color changing region is by VVM thermal labels institute group Color change, the product occurs after being the solid-state polymerization of diacetylene (Diacetylene) monomer being substituted into, reaction principle Information area is bar code, includes the product informations such as product producer, production time, production address.
VVM is the developmental achievement of the World Health Organization and United Nations Children's Fund's long-term investment, for the first time should in 1996 For oral polio vaccine, and gradually it was applied to other vaccines in 2002.VVM has been conventionally applied to WHO at present On the vaccine of UNCIEF buyings, the main users of VVM are become, and more and more national governments will across vaccine giant It asks and VVM is used on the vaccine of its buying.
As shown in Fig. 2, the shape of VVM is similar with China's ancient money, round outside but spuare inside, 10 millimeters of diameter.It is intermediate rectangular to be Active surface, includes variable chemical composition, and this chemical composition is combined with two big element of time and temperature, shows third side The variation of shape surface color, it is this variation be it is slow, progressive, accumulation, it is contemplated that and it is irreversible, reaction principle is according to warp The color change occurred after the solid-state polymerization of substituted diacetylene (Diacetylene) monomer, and according to Arrhenius (Arrhenius) polymeric chemical reaction equation calculates.The circle of periphery is reference surface, and color is fixed.Active square Color can gradually change to the deep dark (deeper than with reference to circle) of terminal from the shallow light tone (lighter than with reference to circle) of starting point.Work as activity When square color is with reference to circle color, terminal just reaches.
As shown in Figure 1, in the present embodiment, the temperature induced color changing bar-code label is two-dimensional bar code QR codes, the temperature mutagens Color region is located at the center of the bar-code label.Because QR codes have higher level of error correction, even if intermediate region is hindered Gear still can identify, so its central area is nor affected on recognition as temperature induced color changing region.
In another embodiment, the temperature induced color changing region is located at around the bar-code label.At this time bar code in addition to It may include the more two-dimensional bar code of information, relatively simple ground bar code can also be selected, as long as bar code and institute's temperature indicating is kept to cause Color change interval is located at a visible planar and apart near.
The temperature induced color changing region includes color change interval and contrast district.
In one embodiment, the bar code region can directly be made of the off-color material of VVM thermal labels, and background colour is then Color is compared, while saving space again in this way, more intuitively.
The temperature induced color changing grade of the bar-code label is divided into four grades, is VVM2, VVM7, VVM14 and VVM30 respectively. 2,7,14,30 refer to reach the terminal required time under conditions of being exposed to 37 degrees Celsius.Different grades is for different It is required that VVM2 grades are to the more stringent vaccine of temperature requirement, just fail within two days more than 37 degree, VVM30 labels are then suitable for resistance to Vaccine is preserved, is exposed to 37 needs, 30 talent's failure.
A kind of reading method of temperature induced color changing bar-code label, includes the following steps:
S1:Scanning device scans temperature induced color changing bar-code label;
S2:Determine the bar code information region;
S3:It decodes image and obtains production information and temperature induced color changing grade;
S5:Determine the temperature induced color changing region where VVM thermal labels region;
S6:Identify VVM thermal label colors;
S7:It according to temperature induced color changing grade, determines whether current vaccines fail, and transmits information to host computer.
The temperature induced color changing bar-code label is distinguished using barcode scanner, shoots entire label area.For collecting Image Parallel Processing, decode bar code information using conventional algorithm all the way, while obtain under temperature induced color changing grade and present level Comparison gray value, another way is according to the anchor point of bar code, inside determining central hot induction region, analysis temperature induced color changing center Domain current color gray value compares this color gray value with the comparison color gray value set, if than comparison color It is shallow, then it also can be used, and plus " usable " label in the data of output, if with comparison solid colour or than basis Color depth, then it is unusable, plus discarded label in the data of output.In addition, in still workable vaccine data, it can also root According to correction data, use priority is marked, gray value is higher i.e. closer to failure time limit, and vaccine use priority is higher, reminds Operating personnel use or especially handle as early as possible.
The bar code information further includes VVM thermal labels region location information.In the present embodiment, by decoding bar code Information knows that the temperature induced color changing region is located at the center of entire label, by can directly take intermediate point after positioning bar code.Another In one embodiment, the temperature induced color changing region is located at the lower section of label, after positioning bar code, takes its lower edge certain area Color gray value as the temperature induced color changing area grayscale value.
In the S6 steps, the VVM thermal labels can be assisted in identifying currently used state by human eye.In the present embodiment, The VVM thermal labels include temperature induced color changing region and contrast district, can there is eye recognition.In another embodiment, in order to subtract Few interference, eliminates contrast district, is only compared with bar code scan equipment.
Obviously, the above embodiments are merely examples for clarifying the description, and is not intended to limit the embodiments.It is right For those of ordinary skill in the art, can also make on the basis of the above description it is other it is various forms of variation or It changes.There is no necessity and possibility to exhaust all the enbodiments.And the obvious variation thus extended out or Among changing still in the protection domain of the invention.

Claims (8)

1. a kind of temperature induced color changing bar-code label, including:Temperature induced color changing region, product information region;
It is characterized in that, the temperature induced color changing region is made of VVM thermal labels, reaction principle is the diacetylene being substituted (Diacetylene) color change occurs after the solid-state polymerization of monomer, the product information region is bar code, includes production Quotient, production time produce the product informations such as address, temperature induced color changing grade.
A kind of 2. temperature induced color changing bar-code label according to claim 1, which is characterized in that the temperature induced color changing bar-code label For two-dimensional bar code QR codes, the temperature induced color changing region is located at the center of the bar-code label.
3. a kind of temperature induced color changing bar-code label according to claim 1, which is characterized in that the temperature induced color changing region is located at Around the bar-code label.
A kind of 4. temperature induced color changing bar-code label according to Claims 2 or 3, which is characterized in that the temperature induced color changing region Include color change interval and contrast district.
A kind of 5. temperature induced color changing bar-code label according to claim 4, which is characterized in that the warm mutagens of the bar-code label Colour gradation is divided into four grades, is VVM2, VVM7, VVM14 and VVM30 respectively.2,7,14,30 refer to be exposed to 37 degrees Celsius Under the conditions of reach the terminal required time.
6. a kind of reading method of temperature induced color changing bar-code label, includes the following steps:
S1:Scanning device scans temperature induced color changing bar-code label;
S2:Determine the bar code information region;
S3:It decodes image and obtains production information and temperature induced color changing grade;
S5:Determine the temperature induced color changing region where VVM thermal labels region;
S6:Identify VVM thermal label colors;
S7:It according to temperature induced color changing grade, determines whether current vaccines fail, and transmits information to host computer.
A kind of 7. reading method of temperature induced color changing bar-code label according to claim 6, which is characterized in that the bar code letter Breath further includes VVM thermal labels region location information.
A kind of 8. reading method of temperature induced color changing bar-code label according to claim 7, which is characterized in that the S6 steps In, the VVM thermal labels can be assisted in identifying currently used state by human eye.
CN201611236018.7A 2016-12-28 2016-12-28 A kind of temperature induced color changing bar-code label and its reading method Pending CN108256607A (en)

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WO2021021938A1 (en) * 2019-07-30 2021-02-04 Temptime Corporation A two dimensional barcode provided with dynamic environmental indicator provided within a gap
WO2021068697A1 (en) * 2019-10-09 2021-04-15 陈浩能 Coding indication label, precise recognition method, and intelligent processing system
US11182579B2 (en) 2015-03-30 2021-11-23 Temptime Corporation Two dimensional barcode with dynamic environmental data system, method, and apparatus
CN113686071A (en) * 2021-07-05 2021-11-23 李苗 Cold chain interruption color development early warning type vaccine refrigeration device
US11241902B1 (en) 2020-09-17 2022-02-08 Temptime Corporation Environmental history monitor with positional displacement and security features
CN114511054A (en) * 2022-01-07 2022-05-17 西安理工大学 Multi-dimensional information label applicable to readable temperature/time/illumination of vaccine products
US11455483B2 (en) 2015-03-30 2022-09-27 Temptime Corporation Two dimensional barcode with dynamic environmental data system, method, and apparatus
US11615280B2 (en) 2020-08-31 2023-03-28 Temptime Corporation Barcodes with security material and readers for same
US11734539B2 (en) 2021-04-05 2023-08-22 Temptime Corporation Dynamic optical property windows in indicia with sensors
US11951761B2 (en) 2020-09-17 2024-04-09 Temptime Corporation Environmental history monitor with security features
WO2025107052A1 (en) * 2023-11-23 2025-05-30 Biehl Hamerschmidt Marcio Thermochromic barcode

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Cited By (16)

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Publication number Priority date Publication date Assignee Title
US11455483B2 (en) 2015-03-30 2022-09-27 Temptime Corporation Two dimensional barcode with dynamic environmental data system, method, and apparatus
US11182579B2 (en) 2015-03-30 2021-11-23 Temptime Corporation Two dimensional barcode with dynamic environmental data system, method, and apparatus
WO2021021938A1 (en) * 2019-07-30 2021-02-04 Temptime Corporation A two dimensional barcode provided with dynamic environmental indicator provided within a gap
GB2600340B (en) * 2019-07-30 2024-02-21 Temptime Corp A two dimensional barcode provided with dynamic environmental indicator provided within a gap
GB2600340A (en) * 2019-07-30 2022-04-27 Temptime Corp A two dimensional barcode provided with dynamic environmental indicator provided within a gap
WO2021068697A1 (en) * 2019-10-09 2021-04-15 陈浩能 Coding indication label, precise recognition method, and intelligent processing system
US11941468B2 (en) 2020-08-31 2024-03-26 Temptime Corporation Barcodes with security material and readers for same
US11615280B2 (en) 2020-08-31 2023-03-28 Temptime Corporation Barcodes with security material and readers for same
US11738587B2 (en) 2020-09-17 2023-08-29 Temptime Corporation Environmental history monitor with positional displacement and security features
US11241902B1 (en) 2020-09-17 2022-02-08 Temptime Corporation Environmental history monitor with positional displacement and security features
US11951761B2 (en) 2020-09-17 2024-04-09 Temptime Corporation Environmental history monitor with security features
US11734539B2 (en) 2021-04-05 2023-08-22 Temptime Corporation Dynamic optical property windows in indicia with sensors
US12056552B2 (en) 2021-04-05 2024-08-06 Temptime Corporation Dynamic optical property windows in indicia with sensors
CN113686071A (en) * 2021-07-05 2021-11-23 李苗 Cold chain interruption color development early warning type vaccine refrigeration device
CN114511054A (en) * 2022-01-07 2022-05-17 西安理工大学 Multi-dimensional information label applicable to readable temperature/time/illumination of vaccine products
WO2025107052A1 (en) * 2023-11-23 2025-05-30 Biehl Hamerschmidt Marcio Thermochromic barcode

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Application publication date: 20180706