CN1082556C - Alloy used for purifying nutritive drinking water - Google Patents
Alloy used for purifying nutritive drinking water Download PDFInfo
- Publication number
- CN1082556C CN1082556C CN99119296A CN99119296A CN1082556C CN 1082556 C CN1082556 C CN 1082556C CN 99119296 A CN99119296 A CN 99119296A CN 99119296 A CN99119296 A CN 99119296A CN 1082556 C CN1082556 C CN 1082556C
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- Prior art keywords
- alloy
- water
- drinking water
- present
- alloy material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000000956 alloy Substances 0.000 title claims abstract description 19
- 235000020188 drinking water Nutrition 0.000 title claims abstract description 6
- 239000003651 drinking water Substances 0.000 title claims abstract description 6
- 230000000050 nutritive effect Effects 0.000 title claims description 3
- 229910045601 alloy Inorganic materials 0.000 title abstract description 11
- 229910052711 selenium Inorganic materials 0.000 claims abstract description 8
- 229910002058 ternary alloy Inorganic materials 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 238000005275 alloying Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 19
- 239000011669 selenium Substances 0.000 abstract description 16
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 abstract description 7
- 238000000034 method Methods 0.000 abstract description 5
- 229910052791 calcium Inorganic materials 0.000 abstract description 3
- 230000036541 health Effects 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 229910052759 nickel Inorganic materials 0.000 abstract description 2
- 235000015097 nutrients Nutrition 0.000 abstract description 2
- 229910052710 silicon Inorganic materials 0.000 abstract description 2
- 229910052709 silver Inorganic materials 0.000 abstract description 2
- 229910052719 titanium Inorganic materials 0.000 abstract description 2
- 239000011573 trace mineral Substances 0.000 abstract description 2
- 235000013619 trace mineral Nutrition 0.000 abstract description 2
- 235000016709 nutrition Nutrition 0.000 abstract 1
- 239000008399 tap water Substances 0.000 description 11
- 235000020679 tap water Nutrition 0.000 description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- 239000010949 copper Substances 0.000 description 6
- 229910017518 Cu Zn Inorganic materials 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229910017752 Cu-Zn Inorganic materials 0.000 description 4
- 229910017943 Cu—Zn Inorganic materials 0.000 description 4
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000011575 calcium Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 241000370738 Chlorion Species 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 238000009689 gas atomisation Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 229910001092 metal group alloy Inorganic materials 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- 206010003210 Arteriosclerosis Diseases 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 206010020772 Hypertension Diseases 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 229910001370 Se alloy Inorganic materials 0.000 description 1
- 229910000905 alloy phase Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 208000011775 arteriosclerosis disease Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 206010012601 diabetes mellitus Diseases 0.000 description 1
- 230000004064 dysfunction Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 208000019423 liver disease Diseases 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 235000008935 nutritious Nutrition 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 208000024691 pancreas disease Diseases 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000002560 therapeutic procedure Methods 0.000 description 1
- -1 thin slice Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
The present invention relates to an alloy material used for producing nutritional type clean drinking water, which is characterized in that a Cu-Zn-Se ternary alloy is produced by an ordinary method, and a multi-component alloy is formed by adding the elements including Si, Ca, Ae, Sn, Ag, Ti, Ni and Mg to the Cu-Zn-Se ternary alloy. After water passes through the alloy material of the present invention, not only can harmful substances in water be reduced and even removed, but also human body vital trace elements, such as selenium, are formed by dissolving in the clean drinking water; therefore, the drinking water with nutrients and health care value can be obtained by adopting the alloy material of the present invention.
Description
The invention belongs to the alloy material technology, a kind of material that is used for the Cu-Zn-Se ternary alloy of clean tap water for the basis of more specifically saying so.
At present, the material that is used for the tap water cleaning mainly contains activated carbon and ion exchange resin two big classes.Activated carbon relies on the surface adsorption reaction, remove chlorion and niff in the tap water, but can't remove toxic impurities such as lead in the water, mercury, and after filtering certain water gaging, will reach capacity and lose clean filteration, the water treating device of being made by the clean material of activated carbon of general family expenses can only filter 200 usually and promptly reach capacity after adding Cang Shui, for this reason, must change the water treating device fuse one time at about two months.The ion exchangeable resin, ion to be removed in ion in the application resin and the water carries out chemical reaction, and to reduce even to remove unnecessary composition in the water, its effect is more single, and the life-span is also shorter.
United States Patent (USP) 5,833,859; 5,599,454 have invented a kind of material of the clean usefulness of water of Cu-Zn binary alloy.Use this powdered alloy, can be simultaneously remove chlorion in anhydrating and each heavy metal species such as copper, mercury, iron, calcium etc., the more important thing is this metal-powder remove anhydrate in the process of impurity be by the redox chemistry reaction, therefore its life-span is very long, experimental results show that, this metal-powder is used for clean tap water, and its life-span is 10-100 a times of activated carbon.In addition, the Cu-Zn alloy both can be handled normal temps water, also can be used to handle the hot water that surpasses more than 50 ℃, and activated carbon can only be used for handling the tap water below 40 ℃, and range of application is just wide like this; In addition, the Cu-Zn alloy has a small amount of dissolved Zn and Cu ion in water, but they do not have big deleterious effect to human body, and is therefore favourable than other metal alloy.
The objective of the invention is to propose a kind of objectionable impurities that not only can reduce even remove in the water, and can produce alloy material human body beneficial's element.
Realize the main technical scheme of the object of the invention: the employing usual method is produced the material based on the Cu-Zn-Se ternary alloy.
Alloying element of the present invention comprises Cu, Zn, and Se, ternary alloy can be represented by the formula: Cu
x-Zn
y-Se
z, x, y, z is atomic ratio, should satisfy following condition: o＜x＜1; O＜y＜1; O＜z＜0.3; X+y+z=1.
Cu-Zn-Se alloy of the present invention also can add and is selected from Si, Ca, Fe, Al, Sn, Ag, Ti, Ni, a kind of among the Mg.Two or more element, its add-on form the multi-element metal alloy less than 10% of alloying element gross weight sum.
Alloy of the present invention adopts the ordinary method preparation promptly to make ingot casting by vacuum melting, and then uses gas atomization or mechanical means and make and comprise powder, thin slice, particle, the shape of silk screen.
Major advantage of the present invention and effect: with Cu-Zn alloy phase ratio, can reduce in addition remove anhydrate in more detrimental impurity, what is more important is owing to contain selenium in the alloy, solubilized produces the elemental selenium of the nutritious value of human body in clean tap water.Selenium is one of trace element of the definite needed by human of the World Health Organization, a large amount of medical researches both at home and abroad confirm: human body lacks selenium can cause vitals dysfunction, appropriate supplement selenium has prevention and assisting therapy effect preferably to cancer, arteriosclerosis, hypertension, diabetes, liver and pancreas disease, therefore alloy of the present invention is used for clean tap water, can obtain having the tap water of health nutrient effect.
Further specify characteristics of the present invention below by specific examples.
Example 1-5
With Cu, Zn, the Se element is made ingot casting with different atomic ratios by usual method, and then the application gas atomization is prepared into 100 order powder.See Table 1.
Table 1
| Element atomic ratio example | Cu | Zn | Se |
| 1 | 0.718 | 0.199 | 0.083 |
| 2 | 0.508 | 0.484 | 0.008 |
| 3 | 0.106 | 0.723 | 0.171 |
| 4 | 0.498 | 0.494 | 0.008 |
| 5 | 0.162 | 0.577 | 0.261 |
Example 6
This example is an application example.
It is 75mm, high in the 300mm cylinder flask that the powder that example 2 and example 4 are obtained is encapsulated in two diameters made of plastic respectively, get two kinds of water and all add the flow velocity in storehouse respectively by these two boxes by per minute one, stripping is filtered the water quality of box and analyze, its result sees Table 2 and table 3 respectively.
The application result of table 2 example 2 powdered alloys
| Chemical substance | Flow into water (mg/L) | Flow out water (mg/L) |
| Al | 1.25 | 0.03 |
| As | 1.10 | ＜0.05 |
| Cd | 1.3 | 0.02 |
| Cl | 3.0 | ＜0.02 |
| Fe | 1.5 | 0.06 |
| Pb | 1.4 | ＜0.05 |
| Hg | 1.3 | ＜0.05 |
| Se | ＜0.02 | 0.07 |
The application result of table 3 example 4 powdered alloys
| Chemical substance | Flow into water (mg/L) * | Flow out water (mg/L) |
| Fe | 0.25 | 0.016 |
| Mn | 0.03 | 0.001 |
| Cu | 0.170 | 0.10 |
| F | 0.5 | 0 |
| Mg | 160 | 90.0 |
| Zn | 0.101 | 0.12 |
| Ca | 76.0 | 45.0 |
| Se | 0.05 | 0.065 |
* home-use tap water.
By table 2 and table 3 data as can be known, alloy of the present invention not only can reduce chlorine and other objectionable impurities in the tap water significantly, and can increase selenium content in the tap water.
Claims (2)
1. an alloy material that is used for purifying nutritive drinking water is characterized in that alloying element comprises Cu, Zn, and Se, its ternary alloy is represented with following formula: Cu
x-Zn
y-Se
z, x, y, z is atomic ratio, should satisfy following condition: o＜x＜1, o＜y＜1, o＜z＜0.3, x+y+z=1.
2. according to the described alloy material of claim 1, it is characterized in that making the shape that comprises powder, particle, thin slice, silk screen.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99119296A CN1082556C (en) | 1999-08-31 | 1999-08-31 | Alloy used for purifying nutritive drinking water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN99119296A CN1082556C (en) | 1999-08-31 | 1999-08-31 | Alloy used for purifying nutritive drinking water |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1286316A CN1286316A (en) | 2001-03-07 |
| CN1082556C true CN1082556C (en) | 2002-04-10 |
Family
ID=5280820
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN99119296A Expired - Lifetime CN1082556C (en) | 1999-08-31 | 1999-08-31 | Alloy used for purifying nutritive drinking water |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1082556C (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105177352B (en) * | 2015-09-03 | 2017-11-03 | 北京银河欣源科技有限公司 | The core component of efficient water process |
| CN113737056B (en) * | 2021-09-09 | 2022-05-27 | 湘潭大学 | A kind of Zn-Se based alloy material and its preparation method and application |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5833859A (en) * | 1984-04-30 | 1998-11-10 | Kdf Fluid Treatment, Inc. | Method for treating fluids |
| US5994544A (en) * | 1994-12-22 | 1999-11-30 | Ligand Pharmaceuticals Incorporated | Steroid receptor modulator compounds and methods |
-
1999
- 1999-08-31 CN CN99119296A patent/CN1082556C/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5833859A (en) * | 1984-04-30 | 1998-11-10 | Kdf Fluid Treatment, Inc. | Method for treating fluids |
| US5994544A (en) * | 1994-12-22 | 1999-11-30 | Ligand Pharmaceuticals Incorporated | Steroid receptor modulator compounds and methods |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1286316A (en) | 2001-03-07 |
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| C14 | Grant of patent or utility model | ||
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Granted publication date: 20020410 |
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