CN108254338A - Gas content in transformer oil on-Line Monitor Device based on spectral absorption method - Google Patents
Gas content in transformer oil on-Line Monitor Device based on spectral absorption method Download PDFInfo
- Publication number
- CN108254338A CN108254338A CN201810230077.6A CN201810230077A CN108254338A CN 108254338 A CN108254338 A CN 108254338A CN 201810230077 A CN201810230077 A CN 201810230077A CN 108254338 A CN108254338 A CN 108254338A
- Authority
- CN
- China
- Prior art keywords
- gas
- oil
- laser
- degassing
- air
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/39—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using tunable lasers
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/01—Arrangements or apparatus for facilitating the optical investigation
Landscapes
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Optics & Photonics (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
Abstract
Description
技术领域technical field
本发明涉及变压器油在线监测技术领域,尤其涉及一种基于光谱吸收法的变压器油中气体含量在线监测装置。The invention relates to the technical field of on-line monitoring of transformer oil, in particular to an on-line monitoring device for gas content in transformer oil based on spectral absorption method.
背景技术Background technique
变压器不仅是电力设施中最为昂贵和重要的设备,而且变压器故障或老化会造成非常严重的电网事故。所以对变压器运转状态和健康状态进行实时监测,有助于提高电力设施的安全性和稳定性。由于变压器发生故障时产生的特征气体种类较多,因此对单一组分气体进行监测只能对变压器故障进行初步分析。而通过对变压器油中溶解的多组分特征气体进行监测,则能够获知变压器故障的详细信息,从而更准确的判断变压器故障类型和原因。目前,变压器油中溶解气体含量的检测主要包括两个方面的技术,即油气分离和多组分气体检测。Transformers are not only the most expensive and important equipment in power facilities, but transformer failure or aging can cause very serious grid accidents. Therefore, real-time monitoring of the operating status and health status of transformers is helpful to improve the safety and stability of power facilities. Since there are many types of characteristic gases produced when a transformer fails, the monitoring of a single component gas can only be used for preliminary analysis of transformer faults. By monitoring the multi-component characteristic gas dissolved in the transformer oil, the detailed information of the transformer fault can be obtained, so as to judge the type and cause of the transformer fault more accurately. At present, the detection of dissolved gas content in transformer oil mainly includes two aspects of technology, namely oil-gas separation and multi-component gas detection.
油气分离方法从原理上区分主要有溶解平衡法和真空脱气法,真空脱气法的脱气效率最高,但是为保证脱气效果,需要严格控制系统的真空度,因此对系统的真空度和真空泵要求很高,造成其结构复杂、可靠性较差,不适合于在线检测应用。在线监测设备上采用的主要是溶解平衡法,溶解平衡法因为平衡手段的不同又分为机械振荡法、动态顶空法以及膜分离方法等,其中机械振荡法因其脱气率较高、重复性好,常被作为其他脱气方法脱气率标定的标准,但是操作过程和装置相对复杂,不适用于在线设备;膜分离方法装置简单,但是脱气时间较长,不能很好地满足在线监测的要求,目前仍处于研究阶段;动态顶空法是目前在线设备应用较多的脱气方法。目前,动态顶空法中常采用高纯N2吹扫,成本较高;另外,其采用在脱气瓶底部设搅拌装置或鼓泡装置的方式,使油中溶解气体分离到脱气瓶顶部的气室中,但分离效果有待提高。The principle of oil and gas separation methods mainly includes dissolution equilibrium method and vacuum degassing method. The vacuum degassing method has the highest degassing efficiency, but in order to ensure the degassing effect, the vacuum degree of the system needs to be strictly controlled. The vacuum pump has high requirements, resulting in its complex structure and poor reliability, which is not suitable for online detection applications. On-line monitoring equipment mainly adopts the dissolution balance method, which is divided into mechanical oscillation method, dynamic headspace method and membrane separation method due to different balance methods. Among them, the mechanical oscillation method has high degassing rate and repeated It has good performance and is often used as the standard for degassing rate calibration of other degassing methods, but the operation process and device are relatively complicated, and it is not suitable for online equipment; The monitoring requirements are still in the research stage; the dynamic headspace method is currently the most widely used degassing method for online equipment. At present, high-purity N2 is often used for purging in the dynamic headspace method, and the cost is relatively high; in addition, a stirring device or a bubbling device is installed at the bottom of the degassing bottle to separate the dissolved gas in the oil to the top of the degassing bottle. In the air chamber, but the separation effect needs to be improved.
目前,气体监测有两大类方法:化学分析法和光谱分析法,化学法主要有色谱分析法,质谱分析法以及色谱-质谱联用分析法等,具有很高的灵敏度,测量结果的可信度高,但响应速度慢,无法在线应用。光谱法包括傅立叶变换红外光谱技术(FTIR)、光声光谱技术(PAS)和可调谐激光吸收光谱法技术(TDLAS)等。傅里叶变换红外光谱法的设备比较庞大,响应速度也相对较慢;现有的光声气体测量装置主要是采用单端单光源入射到气体池中,其光源的单一性决定了测量气体的种类少,局限性很大。在某些研究中采用的是一个光源对应一个气体池的方式解决多光源耦合问题,但随着组分的增加,气室也要相应增加,装置的复杂性加大。At present, there are two types of gas monitoring methods: chemical analysis and spectroscopic analysis. Chemical methods mainly include chromatography, mass spectrometry and chromatography-mass spectrometry, etc., which have high sensitivity and reliable measurement results. The accuracy is high, but the response speed is slow and cannot be applied online. Spectroscopy includes Fourier Transform Infrared Spectroscopy (FTIR), Photoacoustic Spectroscopy (PAS) and Tunable Laser Absorption Spectroscopy (TDLAS). The equipment of Fourier transform infrared spectroscopy is relatively large, and the response speed is relatively slow; the existing photoacoustic gas measurement device mainly uses a single-ended single light source to enter the gas cell, and the singleness of the light source determines the accuracy of the measured gas. There are few types and great limitations. In some studies, one light source corresponds to one gas cell to solve the multi-light source coupling problem, but with the increase of components, the gas chamber will also increase accordingly, and the complexity of the device will increase.
发明内容Contents of the invention
本发明提供了一种基于光谱吸收法的变压器油中气体含量在线监测装置,解决了目前气体测量装置的被测气体受背景气体交叉干扰导致的测量精度低,测量时间长,装置复杂,测量气体单一,测量环境范围窄的问题;具有测量精度高,测量时间短,装置简单,可测量多种气体,且测量环境范围宽的优点。The invention provides an on-line monitoring device for gas content in transformer oil based on the spectral absorption method, which solves the problem of low measurement accuracy, long measurement time, complicated device and difficulty in measuring gas caused by the cross interference of the background gas in the current gas measurement device. The problem of singleness and narrow measurement environment range; it has the advantages of high measurement accuracy, short measurement time, simple device, can measure a variety of gases, and has the advantages of wide measurement environment range.
为了达到上述目的,本发明采用以下技术方案实现:In order to achieve the above object, the present invention adopts the following technical solutions to realize:
基于光谱吸收法的变压器油中气体含量在线监测装置,包括负压恒温的动态顶空脱气模块和基于TDLAS的多组分气体浓度检测模块;其中:An online monitoring device for gas content in transformer oil based on spectral absorption method, including a dynamic headspace degassing module with negative pressure and constant temperature and a multi-component gas concentration detection module based on TDLAS; where:
所述负压恒温的动态顶空脱气模块,包括脱气瓶、与脱气瓶相连的气路部分和油路部分;其特征在于,还包括油气混合器;所述气路部分包括连接在脱气瓶的顶部出气口与油气混合器的气体入口之间的气路管道,以及沿气体流动方向依次设置在气路管道上的油气过滤装置、压力传感器、气体吸收池、气泵、第一气阀、第二气阀和单向阀;其中第一气阀还设有排气口,第二气阀还设有洁净空气入口;所述油路部分包括连接在脱气瓶的进油口与变压器送油口之间的第一油路管道,以及连接在脱气瓶的出油口与变压器回油口之间的第二油路管道;第一油路管道上沿进油方向依次设有第三油阀、第一油阀及第一液位传感器;第二油路管道上沿出油方向依次设有第二油阀和第四油阀,第二油阀和第四油阀之间的第二油路管道通过油泵连接油气混合器的油入口;第一油阀和第三油阀之间的第一油路管道连接油气混合器的混合油气出口;脱气瓶内设第二液位传感器和温度传感器;The negative pressure and constant temperature dynamic headspace degassing module includes a degassing bottle, a gas circuit part connected to the degassing bottle and an oil circuit part; it is characterized in that it also includes an oil-gas mixer; the gas circuit part includes a The gas pipeline between the top gas outlet of the degassing bottle and the gas inlet of the oil-gas mixer, and the oil and gas filter device, pressure sensor, gas absorption pool, gas pump, first gas valve, a second air valve and a one-way valve; wherein the first air valve is also provided with an exhaust port, and the second air valve is also provided with a clean air inlet; the oil circuit part includes the oil inlet connected to the degassing bottle and The first oil pipeline between the oil delivery ports of the transformer, and the second oil pipeline connected between the oil outlet of the degasser and the oil return port of the transformer; The third oil valve, the first oil valve and the first liquid level sensor; the second oil pipeline is provided with the second oil valve and the fourth oil valve in sequence along the oil outlet direction, between the second oil valve and the fourth oil valve The second oil pipeline is connected to the oil inlet of the oil-gas mixer through the oil pump; the first oil pipeline between the first oil valve and the third oil valve is connected to the mixed oil-gas outlet of the oil-gas mixer; the degassing bottle is equipped with a second liquid position sensor and temperature sensor;
所述基于TDLAS的多组分气体浓度检测模块,包括信号发生器、锁相放大器、激光驱动器、激光器选择器、激光器底座、激光器、光纤耦合器、准直器、聚焦器、探测器、数据采集卡、控制模块、流量计和气泵;信号发生器通过输出信号线分别与锁相放大器、激光驱动器连接,激光驱动器与激光器选择器连接,激光器选择器与多只激光器底座连接,每只激光器底座上分别对应安装激光器;各激光器通过输出光纤连接光纤耦合器,光纤耦合器的输出尾纤连接准直器,准直器安装在气体吸收池的入射端口,气体吸收池的出射端口安装聚焦器,聚焦后的激光由探测器接收,探测器通过输出信号线连接锁相放大器,锁相放大器的输出端连接数据采集卡的输入端,数据采集卡的输出端通过数据线连接控制模块,控制模块连接信号发生器;气体吸收池的进气口连接流量计的输出端,气体吸收池的出气口通过气泵连接废气处理装置。The TDLAS-based multi-component gas concentration detection module includes a signal generator, a lock-in amplifier, a laser driver, a laser selector, a laser base, a laser, an optical fiber coupler, a collimator, a focuser, a detector, and a data acquisition card, control module, flow meter and air pump; the signal generator is respectively connected to the lock-in amplifier and the laser driver through the output signal line, the laser driver is connected to the laser selector, the laser selector is connected to multiple laser bases, each laser base The lasers are installed correspondingly; each laser is connected to the fiber coupler through the output fiber, and the output pigtail of the fiber coupler is connected to the collimator. The final laser is received by the detector, the detector is connected to the lock-in amplifier through the output signal line, the output end of the lock-in amplifier is connected to the input end of the data acquisition card, the output end of the data acquisition card is connected to the control module through the data line, and the control module is connected to the signal Generator; the gas inlet of the gas absorption pool is connected to the output end of the flowmeter, and the gas outlet of the gas absorption pool is connected to the exhaust gas treatment device through an air pump.
所述压力传感器、气泵、第一气阀、第二气阀、第三油阀、第一油阀、第一液位传感器、第二油阀、第四油阀、油泵、第二液位传感器和温度传感器分别连接控制系统。The pressure sensor, air pump, first air valve, second air valve, third oil valve, first oil valve, first liquid level sensor, second oil valve, fourth oil valve, oil pump, second liquid level sensor and the temperature sensor are respectively connected to the control system.
所述第二液位传感器设于脱气瓶的上部,温度传感器设于脱气瓶的下部。The second liquid level sensor is arranged on the upper part of the degassing bottle, and the temperature sensor is arranged on the lower part of the degassing bottle.
所述脱气瓶的外侧设有可控温电加热装置。The outside of the degassing bottle is provided with a temperature-controllable electric heating device.
所述油气过滤装置为聚四氟乙烯薄膜。The oil and gas filtering device is a polytetrafluoroethylene film.
所述油气混合器为静态混合管。The oil-gas mixer is a static mixing tube.
所述第二气阀的洁净空气入口通过空气过滤器与大气连通。The clean air inlet of the second air valve communicates with the atmosphere through an air filter.
所述气体吸收池为空心光纤气室、怀特池、赫里奥特池或长光程气室。The gas absorption cell is a hollow optical fiber gas cell, a White cell, a Herriot cell or a long optical path gas cell.
所述激光器为DFB激光器。The laser is a DFB laser.
所述探测器为光电探测器。The detectors are photodetectors.
与现有技术相比,本发明的有益效果是:Compared with prior art, the beneficial effect of the present invention is:
1、负压恒温的动态顶空脱气模块与现有脱气装置相比:1. Compared with the existing degassing device, the dynamic headspace degassing module with negative pressure and constant temperature:
1)采用油气混合器代替常规的鼓泡或电磁搅拌装置,气体与油通过油气混合器混合,再通过油泵充分接触,使得油气混合效率更高,并且简化了装置结构;1) An oil-gas mixer is used to replace the conventional bubbling or electromagnetic stirring device. The gas and oil are mixed through the oil-gas mixer, and then fully contacted by the oil pump, which makes the oil-gas mixing more efficient and simplifies the device structure;
2)抽取洁净空气为载气,与用氮气吹扫相比,成本更低;2) Extract clean air as the carrier gas, which is cheaper than purging with nitrogen;
3)采用空心光纤气室、怀特(White)、池赫里奥特(Herriott)池、长光程气室等体积较小的气体吸收池,配合中红外激光器实现ppb级别检测,其需油量和需气量小,有利于简化脱气瓶结构,并使脱气时间变短;3) Smaller gas absorption cells such as hollow fiber optic cells, White cells, Herriott cells, and long optical path gas cells are used to achieve ppb-level detection with mid-infrared lasers. And the gas demand is small, which is beneficial to simplify the structure of the degassing bottle and shorten the degassing time;
4)脱气瓶采用负压高温环境,提高脱出气体的浓度,提高脱气速度;4) The degassing bottle adopts a negative pressure and high temperature environment to increase the concentration of the degassed gas and increase the degassing speed;
5)采用恒温恒压的脱气与气体检测环境,脱气重复性高,气体检测重复性和精度高;5) Adopt constant temperature and constant pressure degassing and gas detection environment, high degassing repeatability, high repeatability and precision of gas detection;
2、基于TDLAS的多组分气体浓度检测模块与现有多组分气体检测装置相比:2. Compared with the existing multi-component gas detection device, the multi-component gas concentration detection module based on TDLAS:
1)基于分时扫描的时分多路技术来实现对多组分气体的实时检测,实现同时检测多种成份气体的浓度;1) Real-time detection of multi-component gases based on time-division scanning time-division multiplexing technology, and simultaneously detect the concentration of multiple component gases;
2)利用光纤耦合器实现一个气体吸收池的设计,极大简化了多组分气体检测的装置体积;2) The design of a gas absorption cell is realized by using a fiber optic coupler, which greatly simplifies the volume of the multi-component gas detection device;
3)整套装置不需要消耗性载气和易污染老化的色谱柱和复杂的气路控制系统,可消除背景气体交叉干扰。3) The entire device does not require consumable carrier gas, chromatographic columns that are prone to contamination and aging, and a complicated gas path control system, which can eliminate background gas cross-interference.
附图说明Description of drawings
图1是本发明所述负压恒温的动态顶空脱气模块的结构框图。Fig. 1 is a structural block diagram of the negative pressure and constant temperature dynamic headspace degassing module of the present invention.
图2是本发明所述基于TDLAS的多组分气体浓度检测模块的结构框图。Fig. 2 is a structural block diagram of the TDLAS-based multi-component gas concentration detection module of the present invention.
图中:101.气体吸收池 102.气泵 103.第一气阀 104.第二气阀 105.空气过滤器106.单向阀 107.压力传感器 108.油气过滤装置 109.第一油阀 110.第二油阀 111.油泵112.油气混合器 113.第三油阀 114.第四油阀 115.脱气瓶 116.温度传感器 117.第一液位传感器 118.第二液位传感器 201.信号发生器 202.锁相放大器 203.激光驱动器 204.激光器选择器 205.激光器底座 206.激光器 207.光纤耦合器 208.准直器 101.气体吸收池 209.聚焦器 210.探测器 211.数据采集卡 212.控制模块 213.流量计 102.气泵In the figure: 101. Gas absorption pool 102. Air pump 103. First air valve 104. Second air valve 105. Air filter 106. One-way valve 107. Pressure sensor 108. Oil and gas filter device 109. First oil valve 110. Second oil valve 111. Oil pump 112. Oil-air mixer 113. Third oil valve 114. Fourth oil valve 115. Degassing bottle 116. Temperature sensor 117. First liquid level sensor 118. Second liquid level sensor 201. Signal Generator 202. Lock-in amplifier 203. Laser driver 204. Laser selector 205. Laser base 206. Laser 207. Fiber coupler 208. Collimator 101. Gas absorption cell 209. Focuser 210. Detector 211. Data acquisition Card 212. Control module 213. Flow meter 102. Air pump
具体实施方式Detailed ways
下面结合附图对本发明的具体实施方式作进一步说明:The specific embodiment of the present invention will be further described below in conjunction with accompanying drawing:
本发明所述基于光谱吸收法的变压器油中气体含量在线监测装置,包括负压恒温的动态顶空脱气模块和基于TDLAS的多组分气体浓度检测模块;其中:The on-line monitoring device for gas content in transformer oil based on spectral absorption method of the present invention includes a dynamic headspace degassing module with negative pressure and constant temperature and a multi-component gas concentration detection module based on TDLAS; wherein:
如图1所示,本发明所述负压恒温的动态顶空脱气模块,包括脱气瓶115、与脱气瓶115相连的气路部分和油路部分;还包括油气混合器112;所述气路部分包括连接在脱气瓶115的顶部出气口与油气混合器112的气体入口之间的气路管道,以及沿气体流动方向依次设置在气路管道上的油气过滤装置108、压力传感器107、气体吸收池101、气泵102、第一气阀103、第二气阀104和单向阀106;其中第一气阀103还设有排气口,第二气阀104还设有洁净空气入口;所述油路部分包括连接在脱气瓶115的进油口与变压器送油口之间的第一油路管道,以及连接在脱气瓶115的出油口与变压器回油口之间的第二油路管道;第一油路管道上沿进油方向依次设有第三油阀113、第一油阀109及第一液位传感器117;第二油路管道上沿出油方向依次设有第二油阀110和第四油阀114,第二油阀110和第四油阀114之间的第二油路管道通过油泵111连接油气混合器112的油入口;第一油阀109和第三油阀113之间的第一油路管道连接油气混合器112的混合油气出口;脱气瓶115内设第二液位传感器118和温度传感器116;As shown in Figure 1, the negative pressure and constant temperature dynamic headspace degassing module of the present invention includes a degassing bottle 115, a gas circuit part and an oil circuit part connected to the degassing bottle 115; it also includes an oil-gas mixer 112; The gas path part includes a gas path pipeline connected between the top gas outlet of the degassing bottle 115 and the gas inlet of the oil-gas mixer 112, and an oil-gas filter device 108 and a pressure sensor arranged sequentially on the gas path pipeline along the gas flow direction. 107, gas absorption pool 101, air pump 102, first air valve 103, second air valve 104 and one-way valve 106; wherein the first air valve 103 is also provided with an exhaust port, and the second air valve 104 is also provided with clean air Inlet; the oil circuit part includes the first oil circuit pipeline connected between the oil inlet of the degassing bottle 115 and the oil delivery port of the transformer, and is connected between the oil outlet of the degassing bottle 115 and the oil return port of the transformer The second oil pipeline; the first oil pipeline is sequentially provided with the third oil valve 113, the first oil valve 109 and the first liquid level sensor 117 along the oil inlet direction; the second oil pipeline is sequentially arranged along the oil outlet direction A second oil valve 110 and a fourth oil valve 114 are provided, and the second oil pipeline between the second oil valve 110 and the fourth oil valve 114 is connected to the oil inlet of the oil-air mixer 112 through an oil pump 111; the first oil valve 109 The first oil pipeline between the third oil valve 113 is connected to the mixed oil and gas outlet of the oil and gas mixer 112; the degassing bottle 115 is equipped with a second liquid level sensor 118 and a temperature sensor 116;
如图2所示,本发明所述基于TDLAS的多组分气体浓度检测模块,包括信号发生器201、锁相放大器202、激光驱动器203、激光器选择器204、激光器底座205、激光器206、光纤耦合器207、准直器208、聚焦器209、探测器210、数据采集卡211、控制模块212、流量计213和气泵102;信号发生器201通过输出信号线分别与锁相放大器202、激光驱动器203连接,激光驱动器203与激光器选择器204连接,激光器选择器204与多只激光器底座205连接,每只激光器底座205上分别对应安装激光器206;各激光器206通过输出光纤连接光纤耦合器207,光纤耦合器207的输出尾纤连接准直器208,准直器208安装在气体吸收池101的入射端口,气体吸收池101的出射端口安装聚焦器209,聚焦后的激光由探测器210接收,探测器210通过输出信号线连接锁相放大器202,锁相放大器202的输出端连接数据采集卡211的输入端,数据采集卡211的输出端通过数据线连接控制模块212,控制模块212连接信号发生器201;气体吸收池101的进气口连接流量计213的输出端,气体吸收池101的出气口通过气泵102连接废气处理装置。As shown in Figure 2, the TDLAS-based multi-component gas concentration detection module of the present invention includes a signal generator 201, a lock-in amplifier 202, a laser driver 203, a laser selector 204, a laser base 205, a laser 206, a fiber coupling Device 207, collimator 208, focuser 209, detector 210, data acquisition card 211, control module 212, flowmeter 213 and air pump 102; connection, the laser driver 203 is connected to the laser selector 204, and the laser selector 204 is connected to a plurality of laser bases 205, and each laser base 205 is correspondingly installed with a laser 206; each laser 206 is connected to a fiber coupler 207 through an output fiber, and the fiber coupling The output pigtail of device 207 is connected with collimator 208, and collimator 208 is installed on the incident port of gas absorption cell 101, and the exit port of gas absorption cell 101 is installed focuser 209, and the laser light after focusing is received by detector 210, and detector 210 is connected to the lock-in amplifier 202 by the output signal line, the output end of the lock-in amplifier 202 is connected to the input end of the data acquisition card 211, and the output end of the data acquisition card 211 is connected to the control module 212 by the data line, and the control module 212 is connected to the signal generator 201 The gas inlet of the gas absorption pool 101 is connected to the output end of the flow meter 213, and the gas outlet of the gas absorption pool 101 is connected to the exhaust gas treatment device through the air pump 102.
所述压力传感器107、气泵102、第一气阀103、第二气阀104、第三油阀113、第一油阀109、第一液位传感器117、第二油阀110、第四油阀114、油泵111、第二液位传感器118和温度传感器116分别连接控制系统。The pressure sensor 107, air pump 102, first air valve 103, second air valve 104, third oil valve 113, first oil valve 109, first liquid level sensor 117, second oil valve 110, fourth oil valve 114 , the oil pump 111 , the second liquid level sensor 118 and the temperature sensor 116 are respectively connected to the control system.
所述第二液位传感器118设于脱气瓶115的上部,温度传感器116设于脱气瓶115的下部。The second liquid level sensor 118 is arranged on the upper part of the degassing bottle 115 , and the temperature sensor 116 is arranged on the lower part of the degassing bottle 115 .
所述脱气瓶115的外侧设有可控温电加热装置。The outside of the degassing bottle 115 is provided with a temperature-controllable electric heating device.
所述油气过滤装置108为聚四氟乙烯薄膜。The oil and gas filtering device 108 is a polytetrafluoroethylene membrane.
所述油气混合器112为静态混合管。The oil-air mixer 112 is a static mixing tube.
所述第二气阀104的洁净空气入口通过空气过滤器105与大气连通。The clean air inlet of the second air valve 104 communicates with the atmosphere through an air filter 105 .
所述气体吸收池101为空心光纤气室、怀特池、赫里奥特池或长光程气室。The gas absorption cell 101 is a hollow fiber optic cell, a White cell, a Herriott cell or a long optical path gas cell.
所述激光器为DFB激光器。The laser is a DFB laser.
所述探测器为光电探测器。The detectors are photodetectors.
本发明所述基于光谱吸收法的变压器油中气体含量在线监测装置的工作原理为:信号发生器201产生高频正弦信号,与激光驱动器203产生的低频三角波信号相叠加,共同加载到激光器206上,在低频三角波进行线性扫描的同时,激光器206的输出光功率也伴随着高频正弦调制,于是,激光器206的波长得到调制,这样的高频调制可以抑制低频段的背景噪声干扰,提高系统的测量灵敏度。激光器206输出待测气体吸收谱线波长的激光,经过气体吸收池101,由探测器210接收,由放大电路放大后,经锁相放大器202解调出含有浓度信息的二次谐波信号;锁相放大器202的输出信号再经由A/D转换电路采集到控制模块212中,进行数据的处理、显示、存储等。The working principle of the on-line monitoring device for gas content in transformer oil based on the spectral absorption method of the present invention is as follows: the signal generator 201 generates a high-frequency sinusoidal signal, which is superimposed with the low-frequency triangular wave signal generated by the laser driver 203, and is jointly loaded on the laser 206 , while the low-frequency triangular wave is linearly scanning, the output optical power of the laser 206 is also accompanied by high-frequency sinusoidal modulation, so the wavelength of the laser 206 is modulated. Such high-frequency modulation can suppress background noise interference in the low-frequency band and improve the system performance. Measurement sensitivity. The laser 206 outputs the laser light with the wavelength of the absorption line of the gas to be measured, passes through the gas absorption cell 101, is received by the detector 210, and after being amplified by the amplifier circuit, the second harmonic signal containing the concentration information is demodulated by the lock-in amplifier 202; The output signal of the phase amplifier 202 is collected into the control module 212 through the A/D conversion circuit, and the data is processed, displayed, stored and so on.
本发明所述负压恒温的动态顶空脱气模块,采用油气混合器112对变压器油样中的油气进行混合均化,然后将油气混合物引入负压高温的脱气瓶115中,提高油气分离效率,同时采用体积较小的气体吸收池101,使装置整体结构更加简化;采用恒温恒压环境,使脱气时间短,脱气重复性高。The negative pressure and constant temperature dynamic headspace degassing module of the present invention uses the oil and gas mixer 112 to mix and homogenize the oil and gas in the transformer oil sample, and then introduces the oil and gas mixture into the negative pressure and high temperature degassing bottle 115 to improve oil and gas separation efficiency, while using a smaller gas absorption cell 101 to simplify the overall structure of the device; using a constant temperature and pressure environment to shorten the degassing time and high degassing repeatability.
本发明所述基于TDLAS的多组分气体浓度检测模块,与负压恒温的动态顶空脱气模块共用一个气体吸收池101,基于分时扫描的时分多路技术来实现对多组分气体的实时检测。它通过控制模块212来控制和切换激光驱动器203的工作状态,从一系列的激光器206中依次选择测量光束导入到检测光路,实现对多组分气体的分时顺序检测。利用光纤耦合器同时检测多种气体的浓度,极大的简化了装置的结构。整套装置不需要消耗性载气和易污染老化的色谱柱和复杂的气路控制系统,可消除背景气体交叉干扰、可同时检测多种成份气体的浓度、测量精度高、测量时间短。The TDLAS-based multi-component gas concentration detection module of the present invention shares a gas absorption cell 101 with the negative pressure and constant temperature dynamic headspace degassing module, and realizes the multi-component gas detection based on the time-division scanning time-division multiplexing technology. Real-time detection. It controls and switches the working state of the laser driver 203 through the control module 212, and sequentially selects the measurement beam from a series of lasers 206 to be introduced into the detection optical path, so as to realize the time-sharing sequential detection of multi-component gases. The use of optical fiber couplers to simultaneously detect the concentration of multiple gases greatly simplifies the structure of the device. The whole set of equipment does not require consumable carrier gas, easy-to-contaminate and aging chromatographic columns and complex gas path control system, which can eliminate background gas cross-interference, can detect the concentration of multiple component gases at the same time, has high measurement accuracy and short measurement time.
与其他同类装置相比,本发明的优势在于:在脱气方面,抽取洁净空气为载气,无需耗材;采用体积较小的气体吸收池101,如空心光纤气室、White怀特池、Herriott赫里奥特池、长光程气室等,这类气体吸收池的需油量和需气量小,方便简化脱气瓶结构,使得脱气时间变短;同时采用负压高温环境,提高脱出气体的浓度,提高脱气速度;恒温恒压的脱气与气体检测环境使得装置脱气重复性高,气体检测重复性和精度高;用静态混合管代替鼓泡加电磁搅拌装置,使得油气混合效率更高,简化装置结构。在气体检测方面,取缔传统的多气室检测方法,只要选择不同波长的激光器206,通过控制模块212来控制和切换激光驱动器203的工作状态,因而从一系列的激光器206中依次选择测量光束导入到检测光路,实现对多组分气体的分时顺序检测。Compared with other similar devices, the present invention has the advantages of: in terms of degassing, clean air is extracted as carrier gas without consumables; a gas absorption cell 101 with a smaller volume is used, such as a hollow fiber optic cell, a White cell, a Herriott cell Riot cells, long optical path gas chambers, etc. These gas absorption cells require less oil and gas, which facilitates the simplification of the degassing bottle structure and shortens the degassing time; The degassing and gas detection environment with constant temperature and pressure make the degassing repeatability of the device high, and the gas detection repeatability and precision are high; the static mixing tube is used instead of bubbling and electromagnetic stirring device to make the oil and gas mixing efficiency Higher, simplifying the device structure. In terms of gas detection, the traditional multi-gas chamber detection method is banned, as long as lasers 206 with different wavelengths are selected, the working state of the laser driver 203 is controlled and switched through the control module 212, so that the measurement beams are sequentially selected from a series of lasers 206 and introduced into To the detection optical path, the time-sharing sequential detection of multi-component gases is realized.
如图1所示,本发明所述基于光谱吸收法的变压器油中气体含量在线监测装置中,负压恒温的动态顶空脱气模块具有如下几个工作状态:As shown in Figure 1, in the online monitoring device for gas content in transformer oil based on spectral absorption method according to the present invention, the dynamic headspace degassing module with negative pressure and constant temperature has the following working states:
1)系统初始状态:1) The initial state of the system:
油路部分,第一油阀109断;第二油阀断110;第三油阀113断;第四油阀114断。In the oil circuit part, the first oil valve 109 is off; the second oil valve 110 is off; the third oil valve 113 is off; the fourth oil valve 114 is off.
气路部分,第一气阀103的1口、3口连通;第二气阀104的4口、6口连通。In the gas path, port 1 and port 3 of the first air valve 103 are connected; port 4 and port 6 of the second air valve 104 are connected.
气泵102停止,油泵111停止。The air pump 102 is stopped, and the oil pump 111 is stopped.
2)注油状态:2) Oil filling status:
在系统初始状态下,将第二油阀110的状态变为通;第三油阀113通;油泵111运行至油位达到第二液位传感器118的位置停止。In the initial state of the system, the state of the second oil valve 110 is turned on; the third oil valve 113 is turned on; the oil pump 111 runs until the oil level reaches the position of the second liquid level sensor 118 and stops.
3)排油状态:3) Oil discharge state:
在系统初始状态下,第一油阀109通;第四油阀114通;油泵111运行至油位达到第一液位传感器117的位置停止。In the initial state of the system, the first oil valve 109 is open; the fourth oil valve 114 is open; the oil pump 111 runs until the oil level reaches the position of the first liquid level sensor 117 and stops.
4)气路外吹扫状态:4) Purge status outside the gas path:
在系统初始状态下,第一油阀109通;将第一气阀103的1口、3口连通变更为1口、2口连通;将第二气阀104的4口、6口连通变更为5口、6口连通;气泵102运行。In the initial state of the system, the first oil valve 109 is connected; the connection of port 1 and port 3 of the first air valve 103 is changed to the connection of port 1 and port 2; the connection of port 4 and port 6 of the second air valve 104 is changed to Ports 5 and 6 are connected; the air pump 102 is in operation.
5)气路内吹扫状态:5) Purge status in the gas circuit:
在系统初始状态下,第一油阀109通;气泵102运行。In the initial state of the system, the first oil valve 109 is open; the air pump 102 is running.
6)抽负压状态:6) Negative pressure state:
在系统初始状态下,将第一气阀103的1口、3口连通变更为1口、2口连通;气泵102运行,当压力传感器107测定的压力值达到设定值时停止。In the initial state of the system, the connection between port 1 and port 3 of the first air valve 103 is changed to port 1 and port 2; the air pump 102 runs and stops when the pressure value measured by the pressure sensor 107 reaches the set value.
7)气室切入样气测量脱气状态:7) The gas chamber cuts into the sample gas to measure the degassed state:
系统初始状态下,第一油阀109通;第二油阀110通;气泵102运行;油泵111运行。In the initial state of the system, the first oil valve 109 is open; the second oil valve 110 is open; the air pump 102 is running; the oil pump 111 is running.
8)排油前油处理状态:8) Oil treatment status before oil discharge:
在系统初始状态下,第一油阀109通;第一气阀103的1口、3口连通变更为1口、2口连通;气泵102运行。In the initial state of the system, the first oil valve 109 is connected; the connection of port 1 and port 3 of the first air valve 103 is changed to the connection of port 1 and port 2; the air pump 102 is running.
上述工作状态中各油阀、气阀、油泵、气泵的通断情况如表1所示。The on-off status of each oil valve, air valve, oil pump, and air pump in the above working state is shown in Table 1.
表1Table 1
负压恒温的动态顶空脱气模块的工作过程分为以下八个步骤:第一步,初始化;第二步,油路冲洗;第三步,吹扫;第四步,气路抽负压;第五步,进样油;第六步,脱气取样;第七步,排油前的油处理;第八步,排油。共有13个工作过程即:初始状态→抽负压→排油→注油→排油→气路外吹扫→气路内吹扫→气路外吹扫→抽负压→注油→脱气取样→油处理→默认。其中:The working process of the dynamic headspace degassing module with negative pressure and constant temperature is divided into the following eight steps: the first step, initialization; the second step, oil circuit flushing; the third step, purging; the fourth step, gas circuit pumping negative pressure ; The fifth step, sample oil; the sixth step, degassing and sampling; the seventh step, oil treatment before oil discharge; the eighth step, oil discharge. A total of 13 working processes are: initial state → negative pressure pumping → oil discharge → oil injection → oil discharge → purge outside the gas path → purge inside the gas path → purge outside the gas path → negative pressure pumping → oil injection → degassing and sampling → Oil Handling → Default. in:
初始化过程是为了应对系统运行时发生异常状况,如气室内压力不稳定或仍有残油时,通过抽负压可以防止油样污染,主要包括一次抽负压和一次排油过程。The initialization process is to deal with abnormal conditions when the system is running. For example, when the pressure in the air chamber is unstable or there is still residual oil, the oil sample contamination can be prevented by pumping negative pressure. It mainly includes a negative pressure pumping and an oil discharge process.
油路冲洗过程是为了消除上一次测量完毕后,脱气瓶115以及2个油路管道内残存的样油对本次测量的影响,主要包括注油和排油各一次。The oil circuit flushing process is to eliminate the impact of the sample oil remaining in the degassing bottle 115 and the two oil circuit pipelines on this measurement after the last measurement, mainly including oil injection and oil discharge once each.
吹扫过程主要在气路部分进行,包括第一次外吹扫、内吹扫和第二次外吹扫,外吹扫时空气经过空气过滤器105从大气进入气路部分,对整个装置进行吹扫后再流入大气;内吹扫时只有气泵102工作,整个系统仍是封闭的。The purging process is mainly carried out in the gas path, including the first external purging, internal purging and the second external purging. During the external purging, the air passes through the air filter 105 and enters the gas path from the atmosphere to clean the entire device. After purging, it flows into the atmosphere; during internal purging, only the air pump 102 works, and the whole system is still closed.
气路抽负压过程,是为了使系统保持负压状态。The negative pressure process of the air circuit is to keep the system in a negative pressure state.
进样油过程由油路部分实现,通过第二液位传感器118控制油泵111停止,包括一次注油过程。The oil injection process is realized by the oil circuit part, and the oil pump 111 is controlled to stop by the second liquid level sensor 118, including an oil injection process.
脱气取样过程由脱气瓶115与气路部分共同实现,气体与油通过油气混合器112混合后,再通过油泵111,使油气充分接触。The degassing and sampling process is jointly realized by the degassing bottle 115 and the gas path. After the gas and oil are mixed through the oil-gas mixer 112, they are then passed through the oil pump 111 to fully contact the oil and gas.
排油前油处理过程在取样之后进行,目的是排出样油中的多余气体。The pre-drainage oil treatment process is carried out after sampling, and the purpose is to discharge excess gas in the sampled oil.
排油过程通过第一液位传感器117控制油泵111停止,排油后回到系统初始状态,准备进行下一个工作循环。During the oil discharge process, the first liquid level sensor 117 controls the oil pump 111 to stop, and returns to the initial state of the system after the oil discharge, ready for the next working cycle.
如图2所示,本发明所述基于光谱吸收法的变压器油中气体含量在线监测装置中,基于TDLAS的多组分气体浓度检测模块以设置4个激光器,同时检测6种气体为例;表2为所选用激光器的详细参数。As shown in Figure 2, in the on-line monitoring device for gas content in transformer oil based on spectral absorption method according to the present invention, the multi-component gas concentration detection module based on TDLAS is set with 4 lasers and simultaneously detects 6 kinds of gases as an example; the table 2 is the detailed parameters of the selected laser.
表2Table 2
检测方法如下:The detection method is as follows:
1)将待测气体通过流量计213充入气体吸收池101中,流量计213用于监测气体吸收池内的气体流量。1) Fill the gas to be measured into the gas absorption cell 101 through the flow meter 213, and the flow meter 213 is used to monitor the gas flow rate in the gas absorption cell.
2)控制模块212通过控制信号发生器201产生两路信号,一路参考信号送至锁相放大器202的参考端,一路调制信号送至激光驱动器203。控制模块主要用于处理采集到的数据,并且控制信号发生器201产生不同的信号,进而切换激光驱动器203的工作状态,实现分时多路扫描。2) The control module 212 generates two signals through the control signal generator 201 , one reference signal is sent to the reference terminal of the lock-in amplifier 202 , and one modulation signal is sent to the laser driver 203 . The control module is mainly used to process the collected data, and control the signal generator 201 to generate different signals, and then switch the working state of the laser driver 203 to realize time-division multiplex scanning.
3)激光驱动器203配合激光器选择器204以及激光器底座205来调制激光器206的输出;通过不同的激光器206切换,产生不同波长的光,进行分时扫描。3) The laser driver 203 cooperates with the laser selector 204 and the laser base 205 to modulate the output of the laser 206; different lasers 206 are switched to generate light of different wavelengths for time-sharing scanning.
4)激光器206的输出尾纤经光纤耦合器207耦合,经准直器208准直后形成的准直光斑,在气体吸收池101内顺序对6种气体分别进行扫描,出射光由聚焦器209汇聚于探测器210上。4) The output pigtail of the laser 206 is coupled through the fiber coupler 207, and the collimated spot formed after being collimated by the collimator 208 scans the six gases sequentially in the gas absorption cell 101, and the outgoing light is sent by the focuser 209 Converged on the detector 210.
5)探测器210输出的信号输入到锁相放大器202的信号端,锁相放大器202获得的谐波信号送入数据采集卡211中。5) The signal output by the detector 210 is input to the signal terminal of the lock-in amplifier 202 , and the harmonic signal obtained by the lock-in amplifier 202 is sent to the data acquisition card 211 .
6)将数据采集卡211中的所有数据传送至控制模块212中进行处理和运算;控制模块212对气体吸收池101的环境温度和压力的变化引起的测量误差进行修正,得出准确的浓度值。6) Send all the data in the data acquisition card 211 to the control module 212 for processing and calculation; the control module 212 corrects the measurement error caused by the change of the ambient temperature and pressure of the gas absorption cell 101 to obtain an accurate concentration value .
7)通过气泵102将检测后的气体送入废气处理装置进行废气处理。7) Send the detected gas to the waste gas treatment device through the gas pump 102 for waste gas treatment.
所述控制模块采用单片机或PLC即可。The control module can adopt single-chip microcomputer or PLC.
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。The above is only a preferred embodiment of the present invention, but the scope of protection of the present invention is not limited thereto, any person familiar with the technical field within the technical scope disclosed in the present invention, according to the technical solution of the present invention Equivalent replacements or changes to the concepts thereof shall fall within the protection scope of the present invention.
Claims (10)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810230077.6A CN108254338B (en) | 2018-03-20 | 2018-03-20 | Online monitoring device for gas content in transformer oil based on spectral absorption method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810230077.6A CN108254338B (en) | 2018-03-20 | 2018-03-20 | Online monitoring device for gas content in transformer oil based on spectral absorption method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108254338A true CN108254338A (en) | 2018-07-06 |
| CN108254338B CN108254338B (en) | 2023-10-13 |
Family
ID=62747107
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810230077.6A Active CN108254338B (en) | 2018-03-20 | 2018-03-20 | Online monitoring device for gas content in transformer oil based on spectral absorption method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108254338B (en) |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109115721A (en) * | 2018-09-14 | 2019-01-01 | 国家海洋局第海洋研究所 | There is the gas remote measurement device of self-calibration function based on tunable laser |
| CN110186867A (en) * | 2019-06-19 | 2019-08-30 | 国家电网有限公司 | A kind of acetylene on-line monitoring system and method suitable for few oily equipment |
| CN110426465A (en) * | 2019-07-08 | 2019-11-08 | 长园深瑞监测技术有限公司 | A kind of transformer oil chromatographic degasser and its control method |
| CN110879214A (en) * | 2019-11-06 | 2020-03-13 | 北京四方继保自动化股份有限公司 | SF6 electrical equipment running state detection device based on TDLAS |
| CN111562237A (en) * | 2020-05-26 | 2020-08-21 | 中国科学院合肥物质科学研究院 | CO based on double-beam cavity enhanced spectroscopy technology2、N2O stable isotope simultaneous detection device and method |
| CN112213266A (en) * | 2020-09-29 | 2021-01-12 | 湖北鑫英泰系统技术股份有限公司 | Laser monitoring device with laser instrument function that adjusts temperature |
| CN112213270A (en) * | 2020-09-29 | 2021-01-12 | 湖北鑫英泰系统技术股份有限公司 | A method and device for controlling stirring speed based on viscosity |
| CN112525843A (en) * | 2021-02-07 | 2021-03-19 | 湖北鑫英泰系统技术股份有限公司 | Method and system for identifying mixture of gas methane and ethylene in transformer oil |
| CN112881290A (en) * | 2021-01-19 | 2021-06-01 | 福建师范大学 | Gas distribution system for laser online gas detection and application method |
| CN113092410A (en) * | 2021-04-07 | 2021-07-09 | 清华大学 | Multilayer multi-optical-path cavity and electrical insulation equipment running state monitoring system |
| CN113289381A (en) * | 2021-06-24 | 2021-08-24 | 湖南五凌电力科技有限公司 | Oil-gas separation equipment and method thereof |
| CN113567393A (en) * | 2021-07-29 | 2021-10-29 | 湖南五凌电力科技有限公司 | An online monitoring system for dissolved gas in oil by laser spectroscopy |
| CN113567223A (en) * | 2021-07-29 | 2021-10-29 | 湖南五凌电力科技有限公司 | Constant-temperature negative-pressure dynamic headspace oil-gas separation device and method |
| CN113740288A (en) * | 2021-08-05 | 2021-12-03 | 南京工业大学 | An online monitoring method for dissolved gas in transformer oil based on model prediction |
| CN114486810A (en) * | 2022-02-11 | 2022-05-13 | 迈射智能科技(上海)有限公司 | Oil sample oil mixing system based on multi-component standard gas system and detection method |
| CN114509395A (en) * | 2022-02-18 | 2022-05-17 | 哈尔滨工业大学 | Online monitoring device and method for gas in transformer oil |
| CN114965312A (en) * | 2022-05-11 | 2022-08-30 | 河南中分仪器股份有限公司 | Degassing device, spectrum detector for dissolved gas in insulating oil and control method of spectrum detector |
| CN115901681A (en) * | 2022-11-24 | 2023-04-04 | 天津光电通信技术有限公司 | System and method for identifying gas components based on tuned laser absorption spectroscopy |
| CN116046719A (en) * | 2022-12-21 | 2023-05-02 | 湖南五凌电力科技有限公司 | Method and system for detecting concentration of dissolved gas in transformer oil |
| CN118392944A (en) * | 2024-06-25 | 2024-07-26 | 南方电网数字电网研究院股份有限公司 | Transformer insulating oil dissolved gas detection system and method |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2025242962A1 (en) * | 2024-05-24 | 2025-11-27 | Mayak Oy | Gas analyser |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1546473A2 (en) * | 1988-03-21 | 1990-02-28 | Центральное Проектное Конструкторско-Технологическое Бюро "Электротехмонтаж" | Device for treating transformer oil |
| JPH07181175A (en) * | 1993-12-22 | 1995-07-21 | Hitachi Ltd | Oil gas analyzer |
| US20040129633A1 (en) * | 2003-01-07 | 2004-07-08 | Edmondson Jerry M. | Oil, water and gas separator for swaying service |
| CN201297999Y (en) * | 2008-09-23 | 2009-08-26 | 余金海 | Oil-gas separating three-phase measuring device |
| KR100990648B1 (en) * | 2010-02-02 | 2010-10-29 | 이명수 | Apparatus and method for measuring mixed transformer insulation oil |
| CN204679268U (en) * | 2015-06-09 | 2015-09-30 | 哈尔滨工程大学 | Oil and gas multiphase flow Pump Characteristic Test System |
| US20160166751A1 (en) * | 2014-12-10 | 2016-06-16 | Medtronic, Inc. | Degassing system for dialysis |
| CN205374298U (en) * | 2016-01-15 | 2016-07-06 | 鞍山哈工激光科技有限公司 | Trace gas concentration detection apparatus based on TDLAS |
| CN106178608A (en) * | 2016-08-27 | 2016-12-07 | 南瑞通用电气智能监测诊断(武汉)有限公司 | Dynamic headspace degasser |
| CN207992053U (en) * | 2018-03-20 | 2018-10-19 | 哈工大鞍山工业技术研究院有限公司 | Gas content in transformer oil on-Line Monitor Device based on spectral absorption method |
-
2018
- 2018-03-20 CN CN201810230077.6A patent/CN108254338B/en active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU1546473A2 (en) * | 1988-03-21 | 1990-02-28 | Центральное Проектное Конструкторско-Технологическое Бюро "Электротехмонтаж" | Device for treating transformer oil |
| JPH07181175A (en) * | 1993-12-22 | 1995-07-21 | Hitachi Ltd | Oil gas analyzer |
| US20040129633A1 (en) * | 2003-01-07 | 2004-07-08 | Edmondson Jerry M. | Oil, water and gas separator for swaying service |
| CN201297999Y (en) * | 2008-09-23 | 2009-08-26 | 余金海 | Oil-gas separating three-phase measuring device |
| KR100990648B1 (en) * | 2010-02-02 | 2010-10-29 | 이명수 | Apparatus and method for measuring mixed transformer insulation oil |
| US20160166751A1 (en) * | 2014-12-10 | 2016-06-16 | Medtronic, Inc. | Degassing system for dialysis |
| CN204679268U (en) * | 2015-06-09 | 2015-09-30 | 哈尔滨工程大学 | Oil and gas multiphase flow Pump Characteristic Test System |
| CN205374298U (en) * | 2016-01-15 | 2016-07-06 | 鞍山哈工激光科技有限公司 | Trace gas concentration detection apparatus based on TDLAS |
| CN106178608A (en) * | 2016-08-27 | 2016-12-07 | 南瑞通用电气智能监测诊断(武汉)有限公司 | Dynamic headspace degasser |
| CN207992053U (en) * | 2018-03-20 | 2018-10-19 | 哈工大鞍山工业技术研究院有限公司 | Gas content in transformer oil on-Line Monitor Device based on spectral absorption method |
Non-Patent Citations (2)
| Title |
|---|
| 毛知新 等: "变压器油中溶解气体光声光谱检测技术研究", 电工技术学报, vol. 30, no. 7, pages 135 - 143 * |
| 黄剑斌 等: "变压器油顶空脱气法", 电力科学与技术学报, vol. 28, no. 2, pages 89 - 93 * |
Cited By (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109115721B (en) * | 2018-09-14 | 2024-05-28 | 国家海洋局第一海洋研究所 | Gas remote sensing device with self-calibration function based on tunable laser |
| CN109115721A (en) * | 2018-09-14 | 2019-01-01 | 国家海洋局第海洋研究所 | There is the gas remote measurement device of self-calibration function based on tunable laser |
| CN110186867A (en) * | 2019-06-19 | 2019-08-30 | 国家电网有限公司 | A kind of acetylene on-line monitoring system and method suitable for few oily equipment |
| CN110426465A (en) * | 2019-07-08 | 2019-11-08 | 长园深瑞监测技术有限公司 | A kind of transformer oil chromatographic degasser and its control method |
| CN110879214A (en) * | 2019-11-06 | 2020-03-13 | 北京四方继保自动化股份有限公司 | SF6 electrical equipment running state detection device based on TDLAS |
| CN111562237A (en) * | 2020-05-26 | 2020-08-21 | 中国科学院合肥物质科学研究院 | CO based on double-beam cavity enhanced spectroscopy technology2、N2O stable isotope simultaneous detection device and method |
| CN112213270A (en) * | 2020-09-29 | 2021-01-12 | 湖北鑫英泰系统技术股份有限公司 | A method and device for controlling stirring speed based on viscosity |
| CN112213266B (en) * | 2020-09-29 | 2021-05-14 | 湖北鑫英泰系统技术股份有限公司 | Laser monitoring device with laser instrument function that adjusts temperature |
| CN112213266A (en) * | 2020-09-29 | 2021-01-12 | 湖北鑫英泰系统技术股份有限公司 | Laser monitoring device with laser instrument function that adjusts temperature |
| CN112881290A (en) * | 2021-01-19 | 2021-06-01 | 福建师范大学 | Gas distribution system for laser online gas detection and application method |
| CN112881290B (en) * | 2021-01-19 | 2023-06-23 | 福建师范大学 | Gas distribution system and application method for laser on-line detection of gas |
| CN112525843A (en) * | 2021-02-07 | 2021-03-19 | 湖北鑫英泰系统技术股份有限公司 | Method and system for identifying mixture of gas methane and ethylene in transformer oil |
| CN112525843B (en) * | 2021-02-07 | 2021-05-04 | 湖北鑫英泰系统技术股份有限公司 | Method and system for identifying mixture of gas methane and ethylene in transformer oil |
| CN113092410A (en) * | 2021-04-07 | 2021-07-09 | 清华大学 | Multilayer multi-optical-path cavity and electrical insulation equipment running state monitoring system |
| CN113289381A (en) * | 2021-06-24 | 2021-08-24 | 湖南五凌电力科技有限公司 | Oil-gas separation equipment and method thereof |
| CN113567223A (en) * | 2021-07-29 | 2021-10-29 | 湖南五凌电力科技有限公司 | Constant-temperature negative-pressure dynamic headspace oil-gas separation device and method |
| CN113567393A (en) * | 2021-07-29 | 2021-10-29 | 湖南五凌电力科技有限公司 | An online monitoring system for dissolved gas in oil by laser spectroscopy |
| CN113740288A (en) * | 2021-08-05 | 2021-12-03 | 南京工业大学 | An online monitoring method for dissolved gas in transformer oil based on model prediction |
| CN114486810A (en) * | 2022-02-11 | 2022-05-13 | 迈射智能科技(上海)有限公司 | Oil sample oil mixing system based on multi-component standard gas system and detection method |
| CN114486810B (en) * | 2022-02-11 | 2024-03-15 | 迈射智能科技(上海)有限公司 | Oil sample oil mixing system based on multicomponent gas marking system and detection method |
| CN114509395A (en) * | 2022-02-18 | 2022-05-17 | 哈尔滨工业大学 | Online monitoring device and method for gas in transformer oil |
| CN114509395B (en) * | 2022-02-18 | 2023-01-03 | 哈尔滨工业大学 | Online monitoring device and method for gas in transformer oil |
| CN114965312A (en) * | 2022-05-11 | 2022-08-30 | 河南中分仪器股份有限公司 | Degassing device, spectrum detector for dissolved gas in insulating oil and control method of spectrum detector |
| CN115901681A (en) * | 2022-11-24 | 2023-04-04 | 天津光电通信技术有限公司 | System and method for identifying gas components based on tuned laser absorption spectroscopy |
| CN116046719A (en) * | 2022-12-21 | 2023-05-02 | 湖南五凌电力科技有限公司 | Method and system for detecting concentration of dissolved gas in transformer oil |
| CN116046719B (en) * | 2022-12-21 | 2025-03-04 | 湖南五凌电力科技有限公司 | Method and system for detecting concentration of dissolved gas in transformer oil |
| CN118392944A (en) * | 2024-06-25 | 2024-07-26 | 南方电网数字电网研究院股份有限公司 | Transformer insulating oil dissolved gas detection system and method |
| CN118392944B (en) * | 2024-06-25 | 2024-11-12 | 南方电网数字电网研究院股份有限公司 | Transformer insulating oil dissolved gas detection system and method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108254338B (en) | 2023-10-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108254338B (en) | Online monitoring device for gas content in transformer oil based on spectral absorption method | |
| CN207992053U (en) | Gas content in transformer oil on-Line Monitor Device based on spectral absorption method | |
| CN101782514B (en) | Online monitoring device for concentration of hydrogen sulfide by laser | |
| US5494824A (en) | Apparatus for measuring aldehye | |
| US9212993B2 (en) | Determination of sulphur dioxide in a liquid | |
| EP2185914B1 (en) | Carbon measurement in aqueous samples using oxidation at elevated temperatures and pressures | |
| CN111307984B (en) | On-site calibration system for dissolved gas on-line monitoring device in insulating oil | |
| CN104819958B (en) | Method and device for automatically eliminating water vapor interference in Fourier transform infrared spectroscopy gas detection | |
| US8128874B2 (en) | Pressurized detectors substance analyzer | |
| CN112697747A (en) | Device and method for detecting decomposer, moisture and purity in sulfur hexafluoride gas | |
| US11060971B2 (en) | Method and device for monitoring the quality of gaseous media | |
| US6138497A (en) | Method and apparatus for simultaneously measuring CO2, O2 and N2 dissolved in liquid | |
| CN110186867A (en) | A kind of acetylene on-line monitoring system and method suitable for few oily equipment | |
| CN116499980A (en) | Lunar soil water ice content and oxyhydrogen isotope calibration system and measurement system | |
| CN102527094B (en) | Oil-gas separation device for transformer insulation oil | |
| CN110057779B (en) | Method and device for measuring gas concentration based on automatic temperature compensation TDLAS technology | |
| EP1840557A1 (en) | Determination of Components of Liquids | |
| CN210322778U (en) | An acetylene online monitoring system suitable for low oil equipment | |
| CN109239008A (en) | A kind of oil-immersed transformer fault detection means based on micro-nano optical fiber evanescent field | |
| CN114136883B (en) | Detection system and method of multivalent plutonium in nuclear fuel reprocessing | |
| CN213933714U (en) | High-sensitivity liquid chromatography detection system | |
| JP5300668B2 (en) | Method for identifying benzene and toluene concentrations in liquid samples | |
| US2879140A (en) | Fluid blending | |
| RU2823517C1 (en) | Gas analyser | |
| WO2025242962A1 (en) | Gas analyser |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20200925 Address after: 150000 Harbin, Nangang, West District, large straight street, No. 92 Applicant after: HARBIN INSTITUTE OF TECHNOLOGY Address before: 114000 Liaoning city of Anshan province high tech Zone Mountain Road No. 260 Applicant before: HIT ANSHAN INDUSTRIAL TECHNOLOGY INSTITUTE Co.,Ltd. |
|
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20201111 Address after: No.188 Wuling Road, Tianxin District, Changsha City, Hunan Province Applicant after: HUNAN WULING POWER TECHNOLOGY Co.,Ltd. Address before: 150000 Harbin, Nangang, West District, large straight street, No. 92 Applicant before: HARBIN INSTITUTE OF TECHNOLOGY |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant |