[go: up one dir, main page]

CN108164964A - The preparation method of cover material and upper cover on a kind of knob selector knob display screen - Google Patents

The preparation method of cover material and upper cover on a kind of knob selector knob display screen Download PDF

Info

Publication number
CN108164964A
CN108164964A CN201711489649.4A CN201711489649A CN108164964A CN 108164964 A CN108164964 A CN 108164964A CN 201711489649 A CN201711489649 A CN 201711489649A CN 108164964 A CN108164964 A CN 108164964A
Authority
CN
China
Prior art keywords
display screen
knob
upper cover
screen upper
selector knob
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711489649.4A
Other languages
Chinese (zh)
Inventor
陈建国
周志恒
王云玉
符耀明
黄善辉
彭程捷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GAC Component Co Ltd
Original Assignee
Guangzhou Automobile Group Component Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangzhou Automobile Group Component Co Ltd filed Critical Guangzhou Automobile Group Component Co Ltd
Priority to CN201711489649.4A priority Critical patent/CN108164964A/en
Publication of CN108164964A publication Critical patent/CN108164964A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2369/00Characterised by the use of polycarbonates; Derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2400/00Characterised by the use of unspecified polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/10Transparent films; Clear coatings; Transparent materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

The preparation method of cover material and upper cover on a kind of knob selector knob display screen, material include following components:Polycarbonate resin;Titanium dioxide;Polyethylene wax;Antioxidant;Dispersant;Middle colour carbon black;The melt index of the polycarbonate resin is 5 8g/10min;The knob selector knob display screen upper lid surface is coated with UV paints.The present invention is by injection molding molding disposable after the extruded granulation of each component, then carries out UV processing on surface.Avoid the low-grade sense problem that the prior art is brought, with certain technology sense, solve the problems, such as that prior art lamplight brightness is not up to standard so that light is more soft, meet automobile room lamp cursor alignment request, while ensure that the homogeneity of product quality improves production efficiency and reduces cost.

Description

The preparation method of cover material and upper cover on a kind of knob selector knob display screen
Technical field
The present invention relates to a kind of automobile rotary knobs to show screen material, more particularly to a kind of light transmittance and the moderate knob of brightness The preparation method of cover material and the upper cover on selector knob display screen.
Background technology
Knob selector is a kind of form of electric gear change bar, compared to such as other selectors, such as electronic gear, The forms such as console button, the time that knob selector occurs is later, and more save space, it appears that also more attractive, air.Mesh The preceding automobile using knob selector belongs to high-grade car mostly.
Knob selector can be divided into knob portion and control panel part.Wherein there are one the upper surfaces of knob portion meeting Knob display screen, can be in knob display screen upper cover there are one covers in display screen outer surface.For its knob display screen upper cover, due to Display screen is internally provided with light-emitting component, and the light sent out needs to be shown to driver or passenger across knob display screen upper cover, Therefore to the optical property meeting of knob display screen upper cover, there are three require:
First, light transmittance is suitable:If light transmittance is too high, light-emitting component of the user in display screen can be caused not shine When can also be directed through knob display screen upper cover and see its internal structure, give that user's class is relatively low, technology sense is not strong Psychological feelings, and when the light-emitting component shines, then the brightness that can make knob display screen upper cover is too high, generates hereafter " its Two " the problem of, and glare effect is strong, easy visual fatigue, generates the security risk of driving;If light transmittance is too low, institute When stating light-emitting component and shining, luminance shortage that knob display screen upper cover shows, driver needs the long period could during driving Notice the content of display screen.
Secondly:Brightness is suitable:If brightness is too high, vision can be caused uncomfortable and reduce the visual condition of object visibility, Visual fatigue is caused, security risk is generated to driver;If brightness is too low, it is difficult to meet the requirement of automotive interior standard again, Driver needs the long period just it will be noted that the content of display screen during driving.
Thirdly:Wide chromaticity range:Since its light-emitting component can be set to different colors, wide chromaticity range energy The different colours of the light source sent out are effectively distinguished, user is contributed to be distinguished in first time.
In the prior art, the material for the light mask of knob selector knob display screen upper cover is generally light transmission Resin, such as PC (makrolon), PMMA (acrylic, polymethacrylates, organic glass), production method usually has following Two kinds of processing methods:
The first is to carry out injection molding with pure light-transmissive resin, and pitch-dark, formation is then coated in the one side by close to sources Lightproof area, then the intermediate part for showing light is carried out laser carving processing, form transmission region.
Be for second that injection molding is carried out with pure light-transmissive resin, ash paint then coated in the one side by close to sources, not into The processing of row laser carving.
Using the first processing method, the substantially impervious light of lightproof area, and the optical property of transmission region is substantially equal to it The optical property of pure light-transmissive resin raw material.Its transmission region can be straight when light-emitting component of the user in display screen does not shine It connects and sees internal structure through upper cover, glare effect is strong when shining.
Using second of processing method, the optical property of entire knob display screen upper cover is uniform, in display screen When light-emitting component does not shine, the internal structure of knob can be effectively blocked, but since the covering power of ash paint is stronger, it can be caused The problems such as light transmittance, brightness, chromaticity range decline to a great extent, and display light unobvious, color are difficult to differentiate between is allowed to not meet corresponding The requirement of authority file.
Therefore, it is necessary to find a kind of knob selector knob display screen upper cover that can be solved the above problems simultaneously and Preparation method.
Invention content
First purpose of the present invention is to provide a kind of material especially suitable for knob selector knob display screen upper cover Material, at work, the brightness that is presented, light transmittance are moderate, and coloration is also suitable for this material.
Second object of the present invention is to provide the preparation of above-mentioned knob selector knob display screen upper cover moulding material Method, this preparation method simple process, without doing spray painting processing and the processing of laser carving again.
The object of the invention can be realized by following technical solution:
A kind of material of knob selector knob display screen upper cover, is made of by weight following component:
The melt index of the polycarbonate resin is 5-8g/10min (3.2Kg, 300 DEG C);
The present invention can do and improve further below:
The present invention in order to not generate aberration as far as possible after shaping, and through the present inventor's experimental study, the titanium dioxide is excellent Choosing is using the titanium dioxide after the screening of 1000 mesh.
The present invention in injection in order to not only have good lubricant effect, but also be conducive to act synergistically with other components, through this Inventor's experimental study, the polyethylene wax preferably use the good lubricant of XH-202 light.
Present invention upper cover described in order to prevent is oxidized easily decomposition in use, influences service life, while energy It acts synergistically with other components, through the present inventor's experimental study, the antioxidant preferably uses antioxidant 1010.
The present invention in order to when enabling to mix each component in process each component more disperse uniform, and do not influence each group / synergistic effect, through the present inventor's experimental study, the dispersant preferably use 65# white oils.
Material prescription principle explanation of the present invention:
Polycarbonate resin is the main component of the present invention, and the mechanical performance of makrolon is superior, is five big general engineerings Uniquely there is the thermoplastic engineering plastic of good transparency in plastics.In automobile lighting system, current all vehicles are almost complete Portion uses impact resistance and the good makrolon material of translucency, and makes full use of the characteristic of its easily molded processing, by vehicle For all molds such as lamp head, connection sheet and lamp body in lens, design flexibility is big, easy to process, is that glass is irreplaceable.
The effect of titanium dioxide is for color homogenization, to prevent aberration.
Lubricant of the polyethylene wax as the knob display screen upper cover in squeezing out, rolling, injection is processed, can improve and add Work efficiency rate prevents and overcomes film, tubing, sheet material bonding, improves the smoothness and glossiness of finished product, improve finished appearance.
Antioxidant is used to delay or inhibit the progress of polymer oxidation process, so as to prevent the aging of polymer and extend it Service life.
Dispersant be it is a kind of in the molecule while there is the interfacial agents of two kinds of opposite natures of lipophile and hydrophily, Purpose in the present invention is that each component is uniformly dispersed at the time of molding, prevents from agglomerating.
Colour carbon black is utilized in the carbon black for being used as coloring pigment in the products such as ink, paint, coating, plastics, according to color Intensity and particle size are generally divided into four kinds of high-carbon black pigment, middle colour carbon black, ordinary carbon black pigment and low colour carbon black.This hair Bright preferred oil absorption is relatively low, blackness is medium, the colouring preferably middle colour black of power.
The method of upper cover includes the following steps described in the material preparation of above-mentioned knob selector knob display screen upper cover:
(1) dried polycarbonate resin, titanium dioxide, polyethylene wax, antioxidant and middle colour carbon black are added in proportion Enter to premixing 2-3 minutes in mixing machine;Then, it is mixed again 5-8 minutes after adding in dispersant;
Mixed raw material is through double-screw extruding pelletizing machine extruding pelletization;
(2) the above-mentioned material after granulation is disposably molded the upper cover to be molded in injection molding machine;
(3) it by knob selector knob display screen upper cover after injection molding spraying UV paints, is then irradiated by UV lamp, UV paints is made to be converted into solid-state by liquid;
The thickness of the UV paints is 15-25 μm;
(4) after tested, it is packaged into finished product after qualification.The present invention can do and improve further below:
Preparation method of the present invention can be done and improve further below:
Preferably, test passes standard is:Light transmittance is 85-90%, brightness 80-100cd/m2, coloration is in standard colorimetric Map reference ranging from (X, Y)=(0.3 ± 0.03,0.3 ± 0.03);
Compared with prior art, the invention has the advantages that:
1) knob selector knob display screen upper cover light transmittance, brightness, chromaticity index made of the present invention are in industry In critical field, meet the requirement of relevant criterion file, surface light transmittance is consistent, not only avoid the prior art bring it is saturating Light region and the significantly low-grade sense problem of non-transparent area differentiation, and solve that prior art lamplight brightness is not up to standard to ask Topic so that light is more soft, meets automobile room lamp cursor alignment request.Therefore, present invention gained display screen upper cover finished product is not But with high-grade appearance, and excellent comfortable using effect can also be reached.
2) preparation process of the invention is simple, injection molding disposable after the extruded granulation of each component is molded, Ran Hou Surface carries out UV processing.Preparation process is not only enormously simplified, is omitted after display screen upper cover molding in the prior art also The process of japanning and laser carving is needed, and avoids the fraction defective brought by extra process.
3) present invention carries out UV processing to the outer surface of product, makes its scratch-resistant, prevents knob display screen high spot from easily making Into collision and friction, so as to avoid the problem that influencing mask translucent effect because its surface scrapes.
4) good using effect possessed by the present invention, neither easily causes driver's visual fatigue, and can allow driving Personnel are quickly obtained the information that the knob display screen is shown, to make appropriate driver behavior in time, so as to improve The safety of driving.
Specific embodiment
The invention will be further described for example below, so that those skilled in the art can be better understood from the present invention And it can be practiced, but illustrated embodiment is not as a limitation of the invention.
Comparative example one
This comparative example one is that plastic is carried out injection molding with pure makrolon material, and the spraying of the lid back side is thick on a display screen Spend the blacking for 15-25 μm;Then light transmission part will be needed to carry out laser carving, finally assembled, tested, be packaged into after qualified Finished product.
Comparative example two
This comparative example with pure makrolon material by plastic second is that carry out injection molding, and the spraying of the lid back side is thick on a display screen Spend the grey paint for 15-25 μm;It finally assembled, tested, finished product is packaged into after qualified.
Embodiment one
Cover material on a kind of knob selector knob display screen, is made of by weight following component:
The melt index of polycarbonate resin is 5-8g/10min;
Knob selector knob display screen upper lid surface is coated with UV paints.
Titanium dioxide is the titanium dioxide after the screening of 1000 mesh, and polyethylene wax is the good lubricant of XH-202 light.Antioxidant is Antioxidant 1010, dispersant are 65# white oils.
Preparation method includes the following steps:
(1) it is polycarbonate resin is 3 hours dry at a temperature of 140 DEG C;By weight by dried polycarbonate resin Premix is carried out in fat, titanium dioxide, polyethylene wax, antioxidant and middle colour carbon black addition mixing machine after 2 minutes, then by weight to add Enter the dispersant accurately measured to mix again 5 minutes,
It is added in after mixing to double-screw extruding pelletizing machine;It is squeezed out, drawn by the abundant fusion plastification of double-screw extruding pelletizing machine Granular feedstock is made in item, cooling, pelletizing, homogenizing;
(2) mold is made in the shape of the knob selector knob display screen upper cover needed for installation;
(3) granular feedstock by injection molding machine is disposably molded to mold, knob selector knob display screen is made Upper cover semi-finished product;
(4) it by semi-finished product spraying UV paints (thickness is 15-25 μm) made of step (3), is then irradiated by UV lamp, makes it Solid-state is converted by liquid;
(5) it is packaged into finished product.
Embodiment two
Cover material on a kind of knob selector knob display screen, is made of by weight following component:
The melt index of polycarbonate resin is 5-8g/10min;
Knob selector knob display screen upper lid surface is coated with UV paints.
Titanium dioxide is the titanium dioxide after the screening of 1000 mesh, and polyethylene wax is the good lubricant of XH-202 light.Antioxidant is Antioxidant 1010, dispersant are 65# white oils.
Preparation method includes the following steps:
(1) it is polycarbonate resin is 4 hours dry at a temperature of 140 DEG C;By weight by dried polycarbonate resin Premix is carried out in fat, titanium dioxide, polyethylene wax, antioxidant and middle colour carbon black addition mixing machine after 2 minutes, then by weight to add Enter the dispersant accurately measured to mix again 6 minutes,
It is added in after mixing to double-screw extruding pelletizing machine;It is squeezed out, drawn by the abundant fusion plastification of double-screw extruding pelletizing machine Granular feedstock is made in item, cooling, pelletizing, homogenizing;
(2) mold is made in the shape of the knob selector knob display screen upper cover needed for installation;
(3) granular feedstock by injection molding machine is disposably molded to mold, knob selector knob display screen is made Upper cover semi-finished product;
(4) it by semi-finished product spraying UV paints (thickness is 15-25 μm) made of step (3), is then irradiated by UV lamp, makes it Solid-state is converted by liquid;
(5) it is packaged into finished product.
Embodiment three
Cover material on a kind of knob selector knob display screen, is made of by weight following component:
The melt index of polycarbonate resin is 5-8g/10min;
Knob selector knob display screen upper lid surface is coated with UV paints.
Titanium dioxide is the titanium dioxide after the screening of 1000 mesh, and polyethylene wax is the good lubricant of XH-202 light.Antioxidant is Antioxidant 1010, dispersant are 65# white oils.
Preparation method includes the following steps:
(1) it is polycarbonate resin is 5 hours dry at a temperature of 140 DEG C;By weight by dried polycarbonate resin Premix is carried out in fat, titanium dioxide, polyethylene wax, antioxidant and middle colour carbon black addition mixing machine after 3 minutes, then by weight to add Enter the dispersant accurately measured to mix again 8 minutes,
It is added in after mixing to double-screw extruding pelletizing machine;It is squeezed out, drawn by the abundant fusion plastification of double-screw extruding pelletizing machine Granular feedstock is made in item, cooling, pelletizing, homogenizing;
(2) mold is made in the shape of the knob selector knob display screen upper cover needed for installation;
(3) granular feedstock by injection molding machine is disposably molded to mold, knob selector knob display screen is made Upper cover semi-finished product;
(4) it by semi-finished product spraying UV paints (thickness is 15-25 μm) made of step (3), is then irradiated by UV lamp, makes it Solid-state is converted by liquid;
(5) it is packaged into finished product.
Optical performance test is carried out to embodiment one to three, comparative example one and two, test passes standard is:Range of transmittance For 85%-90%, brightness 80-100cd/m2, coloration on standard chromatic diagram coordinate range for (X, Y)=(0.3 ± 0.03, 0.3±0.03)。
After tested, the light transmittance of display screen upper cover, brightness are all higher than testing standard value made of comparative example one, in light not Upper cover can be directed through when bright and sees internal structure, gives the psychological feelings that user's class is relatively low, technology sense is not strong;It is if another long Using this product, light is too strong excessively bright, and vision can be caused uncomfortable and reduce the visual condition of object visibility, cause vision Fatigue generates security risk to driver.
The light transmittance of display screen upper cover, brightness, coloration are respectively less than standard value made of comparative example two, though when light does not work Its internal structure can be blocked, but its translucent effect and lamplight brightness are difficult to meet the requirement of automotive interior standard, when driving drives Personnel need the long period just it will be noted that the content of display screen.
And the defects of then solving comparative example one, comparative example two simultaneously of the invention, manufactured product light transmittance, brightness, coloration In standard value range, the low-grade sense problem that comparative example one is brought is not only avoided, with certain technology sense, and Solving the problems, such as that two lamplight brightness of comparative example is not up to standard so that light is more soft, meets automobile room lamp cursor alignment request, It ensure that the homogeneity of product quality improves production efficiency and reduces cost simultaneously.
The above embodiment of the present invention is not limiting the scope of the present invention, and embodiments of the present invention are not limited to This, all this kind the above according to the present invention according to the ordinary technical knowledge and customary means of this field, is not departing from this Under the premise of inventing above-mentioned basic fundamental thought, the modification of other diversified forms, replacement or the change made to above structure of the present invention More, it should all fall within the scope and spirit of the invention.

Claims (8)

1. a kind of material of knob selector knob display screen upper cover, which is characterized in that be made of by weight following component:
The melt index of the polycarbonate resin is 5-8g/10min.
2. the material of knob selector knob display screen upper cover according to claim 1, it is characterised in that:The titanium White powder is the titanium dioxide after the screening of 1000 mesh.
3. the material of knob selector knob display screen upper cover according to claim 2, it is characterised in that:The poly- second Alkene wax is the good lubricant of XH-202 light.
4. the material of knob selector knob display screen upper cover according to claim 3, it is characterised in that:The antioxygen Agent is antioxidant 1010.
5. the material of knob selector knob display screen upper cover according to any one of claims 1 to 4, it is characterised in that: The dispersant is 65# white oils.
6. the material of knob selector knob display screen upper cover according to claim 1, it is characterised in that:The knob Formula selector knob display screen upper lid surface is coated with UV paints.
7. it is a kind of according to the material preparation of any knob selector knob display screen upper cover of claim 1 to 6 on The method of lid, which is characterized in that include the following steps:
(1) it is polycarbonate resin is 3-5 hours dry at >=140 DEG C;
Dried polycarbonate resin, titanium dioxide, polyethylene wax, antioxidant and middle colour carbon black are proportionally added into mixing Premix 2-3 minutes in machine;Dispersant is added to mix again 5-8 minutes;
Mixed raw material is through double-screw extruding pelletizing machine extruding pelletization;
(2) by the above-mentioned one-time injection molding in injection molding machine of the material after granulation;
(3) it by knob selector knob display screen upper cover after injection molding spraying UV paints, is then irradiated by UV lamp, makes UV Paint is converted into solid-state by liquid;
It is 15-25 μm that the thickness of the UV paints, which is thickness,;
(5) after tested, it is packaged into finished product after qualification.
8. the method for upper cover described in the material preparation of knob selector knob display screen upper cover according to claim 7, It is characterized in that:Test passes standard is:Range of transmittance is 85%-90%, brightness 80-100cd/m2, coloration is in reference colour Spend map reference ranging from (X, Y)=(0.3 ± 0.03,0.3 ± 0.03).
CN201711489649.4A 2017-12-29 2017-12-29 The preparation method of cover material and upper cover on a kind of knob selector knob display screen Pending CN108164964A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711489649.4A CN108164964A (en) 2017-12-29 2017-12-29 The preparation method of cover material and upper cover on a kind of knob selector knob display screen

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711489649.4A CN108164964A (en) 2017-12-29 2017-12-29 The preparation method of cover material and upper cover on a kind of knob selector knob display screen

Publications (1)

Publication Number Publication Date
CN108164964A true CN108164964A (en) 2018-06-15

Family

ID=62516672

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711489649.4A Pending CN108164964A (en) 2017-12-29 2017-12-29 The preparation method of cover material and upper cover on a kind of knob selector knob display screen

Country Status (1)

Country Link
CN (1) CN108164964A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20060056534A (en) * 2004-11-22 2006-05-25 주식회사 선진화학 Light diffusion composition containing light diffusing agent in porous or hollow form
CN102985471A (en) * 2010-05-10 2013-03-20 拜耳知识产权有限责任公司 Polymer compositions with heat absorption and improved color properties
CN106321803A (en) * 2016-10-25 2017-01-11 奇瑞汽车股份有限公司 Self-locking type automobile rotary knob gear shifting device
CN107501889A (en) * 2017-08-19 2017-12-22 广东圆融新材料有限公司 A kind of high black high glaze easy processing polycarbonate compositions and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20060056534A (en) * 2004-11-22 2006-05-25 주식회사 선진화학 Light diffusion composition containing light diffusing agent in porous or hollow form
CN102985471A (en) * 2010-05-10 2013-03-20 拜耳知识产权有限责任公司 Polymer compositions with heat absorption and improved color properties
CN106321803A (en) * 2016-10-25 2017-01-11 奇瑞汽车股份有限公司 Self-locking type automobile rotary knob gear shifting device
CN107501889A (en) * 2017-08-19 2017-12-22 广东圆融新材料有限公司 A kind of high black high glaze easy processing polycarbonate compositions and preparation method thereof

Similar Documents

Publication Publication Date Title
EP1456581B1 (en) Illuminative device
CN105001609A (en) Light diffusion plate masterbatch, light diffusion plate and manufacturing method thereof
CN113771456A (en) Soft touch luminous ornament material and preparation method and application thereof
CN108164963A (en) A kind of knob selector shifting control panel and mode button material and preparation method thereof
CN103242616A (en) Aesthetics resin composition with fantasy colors and preparation method thereof
CN108164964A (en) The preparation method of cover material and upper cover on a kind of knob selector knob display screen
JP2020125376A (en) Resin composition, resin molded product, and method for producing resin composition
CN106433063A (en) Mixture containing blue light barrier additives
US10656314B2 (en) Molded article, thermoplastic resin composition, and display device
EP2057418B1 (en) Appliance cover
CN110283396B (en) Color masterbatch for improving light transmission display, preparation method and application
CN107726247A (en) A kind of LED automobile tail lamp and automobile
CN112280086B (en) Novel transparent superconducting automotive interior material and preparation method thereof
JPH04249288A (en) Multilayer blank-out sign using light diffuser
JP7805424B1 (en) resin molded products
CN109082094A (en) PC frosted resin and preparation method thereof
JP7805425B1 (en) resin molded products
CN113121858B (en) A new light-transmitting superconducting automotive interior material and its preparation method
CN109825052B (en) Resin composition with high metal texture for vehicle lamp and preparation method thereof
DE102023125595B3 (en) Light-emitting system with homogeneous and diffused light; vehicle comprising the same and manufacturing method therefor
CN111218084A (en) Novel modified ABS (acrylonitrile butadiene styrene) automobile material and preparation method thereof
CN110240754A (en) Modified polypropene and preparation method thereof
CN214396630U (en) Light-transmitting decorative plate for vehicle
KR102875388B1 (en) Color shifting sheet and lighting device having the same
CN205910360U (en) Optical function board

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20180615

RJ01 Rejection of invention patent application after publication