CN1081455C - Hair dyeing agent with sorghum red as dyestuff - Google Patents
Hair dyeing agent with sorghum red as dyestuff Download PDFInfo
- Publication number
- CN1081455C CN1081455C CN98117231A CN98117231A CN1081455C CN 1081455 C CN1081455 C CN 1081455C CN 98117231 A CN98117231 A CN 98117231A CN 98117231 A CN98117231 A CN 98117231A CN 1081455 C CN1081455 C CN 1081455C
- Authority
- CN
- China
- Prior art keywords
- hair
- dye
- dyestuff
- hair dye
- red
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000975 dye Substances 0.000 title claims abstract description 26
- 235000011684 Sorghum saccharatum Nutrition 0.000 title claims abstract description 9
- 240000006394 Sorghum bicolor Species 0.000 title claims description 6
- 210000004209 hair Anatomy 0.000 title abstract description 29
- 239000000118 hair dye Substances 0.000 claims abstract description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 9
- -1 iron ions Chemical class 0.000 claims abstract description 8
- 229910052742 iron Inorganic materials 0.000 claims abstract description 7
- 150000001455 metallic ions Chemical class 0.000 claims abstract 3
- 239000001054 red pigment Substances 0.000 claims abstract 3
- 239000000203 mixture Substances 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 229930003935 flavonoid Natural products 0.000 claims description 3
- 235000017173 flavonoids Nutrition 0.000 claims description 3
- 229910021645 metal ion Inorganic materials 0.000 claims description 2
- KZNIFHPLKGYRTM-UHFFFAOYSA-N apigenin Chemical compound C1=CC(O)=CC=C1C1=CC(=O)C2=C(O)C=C(O)C=C2O1 KZNIFHPLKGYRTM-UHFFFAOYSA-N 0.000 claims 2
- 239000003431 cross linking reagent Substances 0.000 claims 2
- 230000002378 acidificating effect Effects 0.000 claims 1
- 238000004043 dyeing Methods 0.000 abstract description 9
- 238000002360 preparation method Methods 0.000 abstract description 8
- 239000002994 raw material Substances 0.000 abstract description 5
- 239000002537 cosmetic Substances 0.000 abstract description 2
- 241000209072 Sorghum Species 0.000 abstract 3
- 238000009472 formulation Methods 0.000 description 5
- 239000000049 pigment Substances 0.000 description 4
- 241000723353 Chrysanthemum Species 0.000 description 3
- 235000007516 Chrysanthemum Nutrition 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 210000000952 spleen Anatomy 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 1
- QLHSZVGLSUHUOI-UHFFFAOYSA-N 3,5,6-trihydroxy-2-phenylchromen-4-one Chemical compound OC=1C(=O)C2=C(O)C(O)=CC=C2OC=1C1=CC=CC=C1 QLHSZVGLSUHUOI-UHFFFAOYSA-N 0.000 description 1
- 206010049865 Achromotrichia acquired Diseases 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 206010013082 Discomfort Diseases 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 1
- 244000018633 Prunus armeniaca Species 0.000 description 1
- 235000009827 Prunus armeniaca Nutrition 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 150000001557 benzodiazepines Chemical class 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 208000032839 leukemia Diseases 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 229910001437 manganese ion Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000004989 p-phenylenediamines Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
The present invention relates to novel hair dye which uses sorghum red as the raw material and belongs to the technical field of cosmetic industry. The hair dye which can dye hair to be red series can also be prepared from new color development molecules produced by the action between sorghum red pigment and metallic ions, for example, black dye is produced by the action between the sorghum red pigment and iron ions, and black hair dye is prepared. In order to shorten the time of hair dyeing, hair is softened when dyed, and hair softening preparation is prepared. During storage, the hair softening preparation and the hair dye are respectively packaged and stored, but used together during hair dyeing. In addition, the hair dye can also be used for carrying out cold dyeing on some animal fur.
Description
Present technique belongs to cosmetics industry, the hair dye of selling on the market at present, and be divided into two big classes by its raw material that uses: a class is the oxidized form dyestuff, another kind of is acid stain.
The primary raw material of oxidized form dyestuff hair dye is the mixture of p-phenylenediamine (PPD) compounds and Benzodiazepines compounds, through oxidant (hydrogen peroxide or perborate, percarbonate etc.) oxidation, can show black and redness.Cooperation according to different proportion can dye colors such as black, brown, brown, red, apricot yellow.Certainly also there is other dyestuff can dye various chromatic hairs.This class hair dye has easy to use, fast advantage.But their toxicity is bigger, and is very easily irritated, the disease that causes discomforts such as red swelling of the skin, twinge, and What is more, can cause canceroderm and leukemia, and this has the investigation of many hygiene departments and reported in the whole nation.
The acid stain hair dye: the raw material of this class hair dye mostly is the intermediate of natural extract (as Galla Chinensis extract) or chemical products, they and iron ion action produce black color, this class hair dye is nontoxic or little toxic, but generally the hair dyeing time is grown or operates loaded down with trivial details, what have need give processing (softening hair) to hair, and for example the bright spleen natural type one of China's production is washed black this class that promptly belongs to.
Seek a kind of raw material and be easy to get, price is lower, and non-toxic dye easy to use is imperative, and the purpose that we develop the chrysanthemum dyestuff also is this.
The main component derivatives of flavonoids compounds of red sorghum pigment, for example 5,7,4 ' one trihydroxyflavone (molecular formula: C
15H
10O
5, structural formula
With 2,5,3 ', 4 '-kaempferol-7-glucoside (molecular formula C
21H
20O
12Structural formula is
Mixture.
The outward appearance of red sorghum pigment is a red powder, and it can make the hair red coloration, also can produce new colour developing molecule with metal ion (as sodium ion magnesium ion calcium ion iron ion manganese ion) effect.
Because the speed that the chrysanthemum dye molecule enters in the hair is slower, we have also taked hair is carried out remollescent method, make the molecule of dyestuff be easy to enter the hair dyeing time whole like this in the hair and can shorten the better effects if of hair dyeing.
The characteristics of our technology are that softening hair and hair dyeing are carried out simultaneously, and the preparation and the dye formulations of softening hair are packed respectively when depositing, and deposit.Lump together during use, spread upon jointly on the hair, poliosis promptly can be dyed the hair of red series.
If dye red wash again with the iron ion preparation immediately and dye, just obtain hair color.
The softening preparation of hair wherein can adopt popular preparation on the market (as bright spleen natural type one wash black the 1. agent get final product)
Dye formulations, for red sorghum pigment is equipped with common thickening agent and surfactant gets final product, the two consumption is controlled with the viscosity of preparation, as long as hair dropping liquid down not during hair dyeing.
Metallo-ion formulations is that example is that the ionic chemical compound of metallic iron is equipped with thickening agent and surfactant (how many same dye formulations of amount) with the iron ion preparation
The temperature that this hair dye uses is best about 40 ℃.This hair dye can be used for dying fur.
The chrysanthemum dyestuff can be used (for example Galla Chinensis extract: tannin and gallic acid) with other natural extract but surpass when a certain amount of at Galla Chinensis extract when hair that dyes black and fur, the order of hair dyeing must be to use earlier the inorganic agent treatment of hair, and then dye, and can not lump together usefulness to softening agent and dye formulations.
Claims (2)
1. natural acidic dyestuff hair dye, comprise softening inorganic agent, metallic-ion crosslinking agent and dyestuff, it is characterized in that, described dyestuff is a red pigment of sorghum, its main component is the mixture of derivatives of flavonoids compounds, described derivatives of flavonoids compounds comprises: 5,7,4 '-trihydroxyflavone, molecular formula are C
15H
10O
5, structural formula is
And 2,5,3 ', 4 '-kaempferol-7-glucoside, molecular formula is C
21H
20O
12, structural formula is:
2. according to the described hair dye of claim 1, the metal ion in the described metallic-ion crosslinking agent is an iron ion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98117231A CN1081455C (en) | 1998-08-07 | 1998-08-07 | Hair dyeing agent with sorghum red as dyestuff |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN98117231A CN1081455C (en) | 1998-08-07 | 1998-08-07 | Hair dyeing agent with sorghum red as dyestuff |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1209992A CN1209992A (en) | 1999-03-10 |
| CN1081455C true CN1081455C (en) | 2002-03-27 |
Family
ID=5225423
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN98117231A Expired - Fee Related CN1081455C (en) | 1998-08-07 | 1998-08-07 | Hair dyeing agent with sorghum red as dyestuff |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1081455C (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2811555B1 (en) * | 2000-07-12 | 2002-09-13 | Oreal | COMPOSITIONS COMPRISING AT LEAST ONE SINGLE OR POLYCARBONYL SELF-TANNER AND A NON-SUBSTITUTED FLAVYLIUM SALT COMPOUND IN POSITION 3 FOR SKIN COLORING AND USES THEREOF |
| FR2811558B1 (en) * | 2000-07-12 | 2002-09-13 | Oreal | COMPOSITIONS COMPRISING NON-SUBSTITUTED FLAVYLIUM SALT TYPE COMPOUNDS IN POSITION 3 FOR SKIN COLORING AND USES THEREOF |
| FR2811554B1 (en) * | 2000-07-12 | 2002-09-13 | Oreal | COMPOSITION COMPRISING AT LEAST ONE UV FILTER AND A NON-SUBSTITUTED FLAVYLIUM SALT IN POSITION 3 FOR SKIN COLORING AND USES THEREOF |
| FR2827512B1 (en) * | 2001-07-17 | 2003-09-26 | Oreal | COMPOSITIONS COMPRISING NON-SUBSTITUTED FLAVYLIUM SALT TYPE COMPOUNDS IN POSITION 3 FOR SKIN COLORING AND USES THEREOF |
| FR2834454B1 (en) * | 2002-01-10 | 2006-05-19 | Oreal | SKIN COLORING COMPOSITIONS COMPRISING SORGHUM EXTRACT AND USES |
| ATE326214T1 (en) | 2002-01-10 | 2006-06-15 | Oreal | SKIN DYE CONTAINING SORGHUM EXTRACT AND USE THEREOF |
| FR2834455B1 (en) * | 2002-01-10 | 2006-03-03 | Oreal | SKIN COLORING COMPOSITION COMPRISING AT LEAST ONE SINGLE OR POLYCARBONYL SELF-TANNER AND SORGHO EXTRACT AND USES THEREOF |
| CN102973467A (en) * | 2012-12-21 | 2013-03-20 | 贵州阿斯科科技开发有限公司 | Brown-red plant ecological hair dye and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1065079A (en) * | 1991-03-15 | 1992-10-07 | 陕西省粮油科学研究所 | The method of extracting Chinese sorghum red pigment by use of water |
-
1998
- 1998-08-07 CN CN98117231A patent/CN1081455C/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1065079A (en) * | 1991-03-15 | 1992-10-07 | 陕西省粮油科学研究所 | The method of extracting Chinese sorghum red pigment by use of water |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1209992A (en) | 1999-03-10 |
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Address after: 100013 building 14, 7 District, Beijing, Dongcheng District, Hepingli Patentee after: Beijing three Fine Chemical Co. Ltd. Address before: 100013 building 14, 7 District, Beijing, Dongcheng District, Hepingli Patentee before: Sanjing Chinese Medicine Daily Chemistry Co., Ltd., Beijing |
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Granted publication date: 20020327 Termination date: 20170807 |