CN108085166A - Acidic ceramic cleaning agent specially used for cleaning precision ceramic bushings and preparation method thereof - Google Patents
Acidic ceramic cleaning agent specially used for cleaning precision ceramic bushings and preparation method thereof Download PDFInfo
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- 239000000919 ceramic Substances 0.000 title claims abstract description 30
- 238000004140 cleaning Methods 0.000 title claims abstract description 18
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 13
- 230000002378 acidificating effect Effects 0.000 title claims abstract description 11
- 238000002360 preparation method Methods 0.000 title claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 30
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims abstract description 24
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims abstract description 20
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 10
- 239000000080 wetting agent Substances 0.000 claims abstract description 10
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims abstract description 9
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 9
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 claims abstract description 9
- 239000010452 phosphate Substances 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 9
- 239000006081 fluorescent whitening agent Substances 0.000 claims abstract description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- -1 diethyl Diol Chemical class 0.000 claims description 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 3
- 229910017604 nitric acid Inorganic materials 0.000 claims description 3
- 229910001220 stainless steel Inorganic materials 0.000 claims description 3
- 239000010935 stainless steel Substances 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims 1
- 230000003287 optical effect Effects 0.000 claims 1
- 239000000243 solution Substances 0.000 description 11
- 238000005498 polishing Methods 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000013307 optical fiber Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 239000012224 working solution Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/042—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/78—Neutral esters of acids of phosphorus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/24—Mineral surfaces, e.g. stones, frescoes, plasters, walls or concretes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Cleaning By Liquid Or Steam (AREA)
Abstract
Description
技术领域technical field
本发明涉及一种清洗剂及制备方法,尤其是一种可缩短清洗时间、提高清洗质量的专用于清洗精密陶瓷套管的酸性陶瓷清洗剂及制备方法。The invention relates to a cleaning agent and a preparation method, in particular to an acidic ceramic cleaning agent specially used for cleaning precision ceramic bushings, which can shorten the cleaning time and improve the cleaning quality, and the preparation method.
背景技术Background technique
精密陶瓷套管是精密光化学仪器制造中的主要器件,用于光纤连接器、光纤适配器及衰减器等的光线连接头。目前困扰生产企业的技术难题在对精密陶瓷套管抛光加工后,其表面残留大量抛光用的污物(凡士林及石蜡等)和黑粉(铁粉等),现有的清洗产品无法将污物彻底清除。Precision ceramic sleeves are the main components in the manufacture of precision photochemical instruments, and are used for optical fiber connectors, optical fiber adapters, and attenuators. The technical problem currently plaguing production enterprises is that after polishing the precision ceramic sleeve, a large amount of polishing dirt (Vaseline and paraffin, etc.) and black powder (iron powder, etc.) remain on the surface, and the existing cleaning products cannot remove the dirt Clean it up completely.
发明内容Contents of the invention
本发明是为了解决现有技术所存在的上述技术问题,提供一种可缩短清洗时间、提高清洗质量的专用于清洗精密陶瓷套管的酸性陶瓷清洗剂及制备方法。The purpose of the present invention is to solve the above-mentioned technical problems existing in the prior art, and provide an acidic ceramic cleaning agent specially used for cleaning precision ceramic bushings, which can shorten the cleaning time and improve the cleaning quality, and its preparation method.
本发明的技术解决方案是:一种专用于清洗精密陶瓷套管的酸性陶瓷清洗剂,所用原料及质量百分比如下:磷酸10~13%、氢氟酸3~6%、柠檬酸3~7%、二乙二醇10~18%、单丁醚10~18%、三聚磷酸钠1~3%、十二烷基苯磺酸3~7%、尼纳尔1~3%、TX-10磷酸酯1~9%、强效润湿剂0.1~1.2%、荧光增白剂0.1~0.3%、水余量。The technical solution of the present invention is: an acidic ceramic cleaning agent specially used for cleaning precision ceramic bushings, the raw materials and mass percentages used are as follows: phosphoric acid 10-13%, hydrofluoric acid 3-6%, citric acid 3-7% , diethylene glycol 10~18%, monobutyl ether 10~18%, sodium tripolyphosphate 1~3%, dodecylbenzenesulfonic acid 3~7%, Ninar 1~3%, TX-10 Phosphate ester 1~9%, strong wetting agent 0.1~1.2%, fluorescent whitening agent 0.1~0.3%, water balance.
一种上述专用于清洗精密陶瓷套管的酸性陶瓷清洗剂的制备方法,按照如下步骤进行:A kind of preparation method of the above-mentioned acidic ceramic cleaning agent specially used for cleaning the precision ceramic bushing is carried out according to the following steps:
a. 将计算称量的磷酸、氢氟酸和部分计量的水混合搅拌至充分溶解,制成①号溶液;a. Mix and stir the calculated and weighed phosphoric acid, hydrofluoric acid and part of the measured water until fully dissolved to make solution ①;
b. 将计算称量的柠檬酸、三聚磷酸钠和部分计量的水混合搅拌至充分溶解,制成②号溶液;b. Mix and stir the calculated and weighed citric acid, sodium tripolyphosphate and part of the measured water until fully dissolved to make solution ②;
c. 将剩余的水加入到不锈钢反应釜中,启动搅拌器,设定转速为60转/分钟,再将计算称量的二乙二醇、单丁醚、十二烷基苯磺酸、尼纳尔、TX-10磷酸酯、强效润湿剂、荧光增白剂、①号溶液、②号溶液依次徐徐加入到反应釜中,边加入边搅拌,直至呈浅黄色透明溶液。c. Add the remaining water into the stainless steel reaction kettle, start the agitator, set the rotating speed to 60 rpm, and then add the calculated and weighed diethylene glycol, monobutyl ether, dodecylbenzenesulfonic acid, nitric acid Nar, TX-10 phosphate, powerful wetting agent, fluorescent whitening agent, No. ① solution, and No. ② solution are slowly added into the reaction kettle in sequence, and stirred while adding, until the light yellow transparent solution is formed.
本发明是专用于清洗精密陶瓷套管的酸性陶瓷清洗剂,可有效去除精密陶瓷套管抛光加工后表面残留的污物和黑粉。与现有技术相比,清洗后的精密陶瓷套管工件表面的光洁度、光亮度、白度及表面的耐蚀性等均有较大提高,清洗时间缩短了一半,极大的提高了工作效率。The invention is an acidic ceramic cleaning agent specially used for cleaning precision ceramic bushings, which can effectively remove dirt and black powder remaining on the surface of the precision ceramic bushings after polishing. Compared with the existing technology, the surface smoothness, brightness, whiteness and surface corrosion resistance of the cleaned precision ceramic sleeve workpiece are greatly improved, the cleaning time is shortened by half, and the work efficiency is greatly improved. .
具体实施方式Detailed ways
实施例1:Example 1:
本发明的专用于清洗精密陶瓷套管的酸性陶瓷清洗剂,所用原料及质量百分比如下:磷酸10%、氢氟酸6%、柠檬酸3%、二乙二醇18%、单丁醚10%、三聚磷酸钠3%、十二烷基苯磺酸3%、尼纳尔3%、TX-10磷酸酯1%、强效润湿剂1.2%、荧光增白剂0.1%、水余量。The acidic ceramic cleaning agent specially used for cleaning precision ceramic bushings of the present invention has the following raw materials and mass percentages: 10% phosphoric acid, 6% hydrofluoric acid, 3% citric acid, 18% diethylene glycol, and 10% monobutyl ether , sodium tripolyphosphate 3%, dodecylbenzenesulfonic acid 3%, Ninar 3%, TX-10 phosphate ester 1%, strong wetting agent 1.2%, fluorescent whitening agent 0.1%, water balance .
制备方法按照如下步骤进行:The preparation method is carried out according to the following steps:
a. 将计算称量的磷酸、氢氟酸和部分计量的水混合搅拌至充分溶解,制成①号溶液;a. Mix and stir the calculated and weighed phosphoric acid, hydrofluoric acid and part of the measured water until fully dissolved to make solution ①;
b. 将计算称量的柠檬酸、三聚磷酸钠和部分计量的水混合搅拌至充分溶解,制成②号溶液;b. Mix and stir the calculated and weighed citric acid, sodium tripolyphosphate and part of the measured water until fully dissolved to make solution ②;
c. 将剩余的水加入到不锈钢反应釜中,启动搅拌器,设定转速为60转/分钟,再将计算称量的二乙二醇、单丁醚、十二烷基苯磺酸、尼纳尔、TX-10磷酸酯、强效润湿剂、荧光增白剂、①号溶液、②号溶液依次徐徐加入到反应釜中,边加入边搅拌,直至呈浅黄色透明溶液。c. Add the remaining water into the stainless steel reaction kettle, start the agitator, set the rotating speed to 60 rpm, and then add the calculated and weighed diethylene glycol, monobutyl ether, dodecylbenzenesulfonic acid, nitric acid Nar, TX-10 phosphate, powerful wetting agent, fluorescent whitening agent, No. ① solution, and No. ② solution are slowly added into the reaction kettle in sequence, and stirred while adding, until the light yellow transparent solution is formed.
本发明所用原料均为外购,其中强效润湿剂购于巴斯夫,所用磷酸质量浓度为80%,氢氟酸质量浓度为40%,柠檬酸质量浓度为90%。The raw materials used in the present invention are all purchased from outside, wherein the strong wetting agent is purchased from BASF, the mass concentration of phosphoric acid used is 80%, the mass concentration of hydrofluoric acid is 40%, and the mass concentration of citric acid is 90%.
实施例2:Example 2:
本发明的专用于清洗精密陶瓷套管的酸性陶瓷清洗剂,所用原料及质量百分比如下:磷酸13%、氢氟酸3%、柠檬酸7%、二乙二醇10%、单丁醚18%、三聚磷酸钠1%、十二烷基苯磺酸7%、尼纳尔1%、TX-10磷酸酯9%、强效润湿剂0.1%、荧光增白剂0.3%、水余量。The acidic ceramic cleaning agent specially used for cleaning precision ceramic bushings of the present invention has the following raw materials and mass percentages: 13% phosphoric acid, 3% hydrofluoric acid, 7% citric acid, 10% diethylene glycol, and 18% monobutyl ether , sodium tripolyphosphate 1%, dodecylbenzenesulfonic acid 7%, Ninar 1%, TX-10 phosphate ester 9%, strong wetting agent 0.1%, fluorescent whitening agent 0.3%, water balance .
所用原料及制备方法同实施例1。The raw materials used and the preparation method are the same as in Example 1.
实施例:Example:
本发明的专用于清洗精密陶瓷套管的酸性陶瓷清洗剂,所用原料及质量百分比如下:磷酸12%、氢氟酸5%、柠檬酸5%、二乙二醇14%、单丁醚15%、三聚磷酸钠2%、十二烷基苯磺酸4%、尼纳尔2%、TX-10磷酸酯5%、强效润湿剂0.6 %、荧光增白剂0.2 %、水余量。The acidic ceramic cleaning agent specially used for cleaning precision ceramic bushings of the present invention has the following raw materials and mass percentages: 12% phosphoric acid, 5% hydrofluoric acid, 5% citric acid, 14% diethylene glycol, and 15% monobutyl ether , sodium tripolyphosphate 2%, dodecylbenzenesulfonic acid 4%, Ninar 2%, TX-10 phosphate ester 5%, strong wetting agent 0.6%, fluorescent whitening agent 0.2%, water balance .
所用原料及制备方法同实施例1。The raw materials used and the preparation method are the same as in Example 1.
使用方法及效果:How to use and effect:
将本发明实施例1~3加水配制质量百分比为3~8%的工作液,超声波清洗精密陶瓷套管5~10分钟,取出水洗干燥。精密陶瓷套管工件表面的光洁度、光亮度、白度及表面的耐蚀性等符合标准要求。Add water to prepare a working solution with a mass percentage of 3-8% in Examples 1-3 of the present invention, ultrasonically clean the precision ceramic sleeve for 5-10 minutes, take it out, wash it and dry it. The surface finish, brightness, whiteness and surface corrosion resistance of the precision ceramic sleeve workpiece meet the standard requirements.
Claims (2)
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| WO2021015632A1 (en) * | 2019-07-24 | 2021-01-28 | Quispe Muniz Wilber | Composition for cleaning vehicle bodywork, rims, motors and accessories without damaging the paintwork, and preparation method |
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| CN103103033A (en) * | 2012-12-10 | 2013-05-15 | 苏州丰儒软件有限公司 | Ceramic craft cleaning agent and preparation method thereof |
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|---|---|---|---|---|
| CN1248615A (en) * | 1999-09-22 | 2000-03-29 | 赵中夏 | Descaling agent for cleaning |
| CN1978616A (en) * | 2005-12-09 | 2007-06-13 | 安徽铜都特种环保设备股份有限公司 | Detergent for cleaning ceramic filtering plate |
| CN102925298A (en) * | 2012-11-26 | 2013-02-13 | 华阳新兴科技(天津)集团有限公司 | Water-based cleaning agent for soldering flux and preparation method thereof |
| CN103103033A (en) * | 2012-12-10 | 2013-05-15 | 苏州丰儒软件有限公司 | Ceramic craft cleaning agent and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021015632A1 (en) * | 2019-07-24 | 2021-01-28 | Quispe Muniz Wilber | Composition for cleaning vehicle bodywork, rims, motors and accessories without damaging the paintwork, and preparation method |
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