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CN108085166A - Acidic ceramic cleaning agent specially used for cleaning precision ceramic bushings and preparation method thereof - Google Patents

Acidic ceramic cleaning agent specially used for cleaning precision ceramic bushings and preparation method thereof Download PDF

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Publication number
CN108085166A
CN108085166A CN201711421513.XA CN201711421513A CN108085166A CN 108085166 A CN108085166 A CN 108085166A CN 201711421513 A CN201711421513 A CN 201711421513A CN 108085166 A CN108085166 A CN 108085166A
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acid
cleaning
ceramic
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agent
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李文瀚
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Dalian Sandaaoke Chemistry Co Ltd
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Dalian Sandaaoke Chemistry Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0073Anticorrosion compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/042Acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/06Phosphates, including polyphosphates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/78Neutral esters of acids of phosphorus
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • C11D2111/24Mineral surfaces, e.g. stones, frescoes, plasters, walls or concretes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cleaning By Liquid Or Steam (AREA)

Abstract

The invention discloses an acidic ceramic cleaning agent special for cleaning precise ceramic sleeves, which comprises the following raw materials, by mass, 10% of phosphoric acid, 6% of hydrofluoric acid, 3% of citric acid, 18% of diethylene glycol, 10% of monobutyl ether, 3% of sodium tripolyphosphate, 3% of dodecylbenzene sulfonic acid, 3% of Ninol, 1% of TX-10 phosphate, 1.2% of a strong wetting agent, 0.1% of a fluorescent whitening agent and the balance of water.

Description

专用于清洗精密陶瓷套管的酸性陶瓷清洗剂及制备方法Acidic ceramic cleaning agent specially used for cleaning precision ceramic bushings and preparation method thereof

技术领域technical field

本发明涉及一种清洗剂及制备方法,尤其是一种可缩短清洗时间、提高清洗质量的专用于清洗精密陶瓷套管的酸性陶瓷清洗剂及制备方法。The invention relates to a cleaning agent and a preparation method, in particular to an acidic ceramic cleaning agent specially used for cleaning precision ceramic bushings, which can shorten the cleaning time and improve the cleaning quality, and the preparation method.

背景技术Background technique

精密陶瓷套管是精密光化学仪器制造中的主要器件,用于光纤连接器、光纤适配器及衰减器等的光线连接头。目前困扰生产企业的技术难题在对精密陶瓷套管抛光加工后,其表面残留大量抛光用的污物(凡士林及石蜡等)和黑粉(铁粉等),现有的清洗产品无法将污物彻底清除。Precision ceramic sleeves are the main components in the manufacture of precision photochemical instruments, and are used for optical fiber connectors, optical fiber adapters, and attenuators. The technical problem currently plaguing production enterprises is that after polishing the precision ceramic sleeve, a large amount of polishing dirt (Vaseline and paraffin, etc.) and black powder (iron powder, etc.) remain on the surface, and the existing cleaning products cannot remove the dirt Clean it up completely.

发明内容Contents of the invention

本发明是为了解决现有技术所存在的上述技术问题,提供一种可缩短清洗时间、提高清洗质量的专用于清洗精密陶瓷套管的酸性陶瓷清洗剂及制备方法。The purpose of the present invention is to solve the above-mentioned technical problems existing in the prior art, and provide an acidic ceramic cleaning agent specially used for cleaning precision ceramic bushings, which can shorten the cleaning time and improve the cleaning quality, and its preparation method.

本发明的技术解决方案是:一种专用于清洗精密陶瓷套管的酸性陶瓷清洗剂,所用原料及质量百分比如下:磷酸10~13%、氢氟酸3~6%、柠檬酸3~7%、二乙二醇10~18%、单丁醚10~18%、三聚磷酸钠1~3%、十二烷基苯磺酸3~7%、尼纳尔1~3%、TX-10磷酸酯1~9%、强效润湿剂0.1~1.2%、荧光增白剂0.1~0.3%、水余量。The technical solution of the present invention is: an acidic ceramic cleaning agent specially used for cleaning precision ceramic bushings, the raw materials and mass percentages used are as follows: phosphoric acid 10-13%, hydrofluoric acid 3-6%, citric acid 3-7% , diethylene glycol 10~18%, monobutyl ether 10~18%, sodium tripolyphosphate 1~3%, dodecylbenzenesulfonic acid 3~7%, Ninar 1~3%, TX-10 Phosphate ester 1~9%, strong wetting agent 0.1~1.2%, fluorescent whitening agent 0.1~0.3%, water balance.

一种上述专用于清洗精密陶瓷套管的酸性陶瓷清洗剂的制备方法,按照如下步骤进行:A kind of preparation method of the above-mentioned acidic ceramic cleaning agent specially used for cleaning the precision ceramic bushing is carried out according to the following steps:

a. 将计算称量的磷酸、氢氟酸和部分计量的水混合搅拌至充分溶解,制成①号溶液;a. Mix and stir the calculated and weighed phosphoric acid, hydrofluoric acid and part of the measured water until fully dissolved to make solution ①;

b. 将计算称量的柠檬酸、三聚磷酸钠和部分计量的水混合搅拌至充分溶解,制成②号溶液;b. Mix and stir the calculated and weighed citric acid, sodium tripolyphosphate and part of the measured water until fully dissolved to make solution ②;

c. 将剩余的水加入到不锈钢反应釜中,启动搅拌器,设定转速为60转/分钟,再将计算称量的二乙二醇、单丁醚、十二烷基苯磺酸、尼纳尔、TX-10磷酸酯、强效润湿剂、荧光增白剂、①号溶液、②号溶液依次徐徐加入到反应釜中,边加入边搅拌,直至呈浅黄色透明溶液。c. Add the remaining water into the stainless steel reaction kettle, start the agitator, set the rotating speed to 60 rpm, and then add the calculated and weighed diethylene glycol, monobutyl ether, dodecylbenzenesulfonic acid, nitric acid Nar, TX-10 phosphate, powerful wetting agent, fluorescent whitening agent, No. ① solution, and No. ② solution are slowly added into the reaction kettle in sequence, and stirred while adding, until the light yellow transparent solution is formed.

本发明是专用于清洗精密陶瓷套管的酸性陶瓷清洗剂,可有效去除精密陶瓷套管抛光加工后表面残留的污物和黑粉。与现有技术相比,清洗后的精密陶瓷套管工件表面的光洁度、光亮度、白度及表面的耐蚀性等均有较大提高,清洗时间缩短了一半,极大的提高了工作效率。The invention is an acidic ceramic cleaning agent specially used for cleaning precision ceramic bushings, which can effectively remove dirt and black powder remaining on the surface of the precision ceramic bushings after polishing. Compared with the existing technology, the surface smoothness, brightness, whiteness and surface corrosion resistance of the cleaned precision ceramic sleeve workpiece are greatly improved, the cleaning time is shortened by half, and the work efficiency is greatly improved. .

具体实施方式Detailed ways

实施例1:Example 1:

本发明的专用于清洗精密陶瓷套管的酸性陶瓷清洗剂,所用原料及质量百分比如下:磷酸10%、氢氟酸6%、柠檬酸3%、二乙二醇18%、单丁醚10%、三聚磷酸钠3%、十二烷基苯磺酸3%、尼纳尔3%、TX-10磷酸酯1%、强效润湿剂1.2%、荧光增白剂0.1%、水余量。The acidic ceramic cleaning agent specially used for cleaning precision ceramic bushings of the present invention has the following raw materials and mass percentages: 10% phosphoric acid, 6% hydrofluoric acid, 3% citric acid, 18% diethylene glycol, and 10% monobutyl ether , sodium tripolyphosphate 3%, dodecylbenzenesulfonic acid 3%, Ninar 3%, TX-10 phosphate ester 1%, strong wetting agent 1.2%, fluorescent whitening agent 0.1%, water balance .

制备方法按照如下步骤进行:The preparation method is carried out according to the following steps:

a. 将计算称量的磷酸、氢氟酸和部分计量的水混合搅拌至充分溶解,制成①号溶液;a. Mix and stir the calculated and weighed phosphoric acid, hydrofluoric acid and part of the measured water until fully dissolved to make solution ①;

b. 将计算称量的柠檬酸、三聚磷酸钠和部分计量的水混合搅拌至充分溶解,制成②号溶液;b. Mix and stir the calculated and weighed citric acid, sodium tripolyphosphate and part of the measured water until fully dissolved to make solution ②;

c. 将剩余的水加入到不锈钢反应釜中,启动搅拌器,设定转速为60转/分钟,再将计算称量的二乙二醇、单丁醚、十二烷基苯磺酸、尼纳尔、TX-10磷酸酯、强效润湿剂、荧光增白剂、①号溶液、②号溶液依次徐徐加入到反应釜中,边加入边搅拌,直至呈浅黄色透明溶液。c. Add the remaining water into the stainless steel reaction kettle, start the agitator, set the rotating speed to 60 rpm, and then add the calculated and weighed diethylene glycol, monobutyl ether, dodecylbenzenesulfonic acid, nitric acid Nar, TX-10 phosphate, powerful wetting agent, fluorescent whitening agent, No. ① solution, and No. ② solution are slowly added into the reaction kettle in sequence, and stirred while adding, until the light yellow transparent solution is formed.

本发明所用原料均为外购,其中强效润湿剂购于巴斯夫,所用磷酸质量浓度为80%,氢氟酸质量浓度为40%,柠檬酸质量浓度为90%。The raw materials used in the present invention are all purchased from outside, wherein the strong wetting agent is purchased from BASF, the mass concentration of phosphoric acid used is 80%, the mass concentration of hydrofluoric acid is 40%, and the mass concentration of citric acid is 90%.

实施例2:Example 2:

本发明的专用于清洗精密陶瓷套管的酸性陶瓷清洗剂,所用原料及质量百分比如下:磷酸13%、氢氟酸3%、柠檬酸7%、二乙二醇10%、单丁醚18%、三聚磷酸钠1%、十二烷基苯磺酸7%、尼纳尔1%、TX-10磷酸酯9%、强效润湿剂0.1%、荧光增白剂0.3%、水余量。The acidic ceramic cleaning agent specially used for cleaning precision ceramic bushings of the present invention has the following raw materials and mass percentages: 13% phosphoric acid, 3% hydrofluoric acid, 7% citric acid, 10% diethylene glycol, and 18% monobutyl ether , sodium tripolyphosphate 1%, dodecylbenzenesulfonic acid 7%, Ninar 1%, TX-10 phosphate ester 9%, strong wetting agent 0.1%, fluorescent whitening agent 0.3%, water balance .

所用原料及制备方法同实施例1。The raw materials used and the preparation method are the same as in Example 1.

实施例:Example:

本发明的专用于清洗精密陶瓷套管的酸性陶瓷清洗剂,所用原料及质量百分比如下:磷酸12%、氢氟酸5%、柠檬酸5%、二乙二醇14%、单丁醚15%、三聚磷酸钠2%、十二烷基苯磺酸4%、尼纳尔2%、TX-10磷酸酯5%、强效润湿剂0.6 %、荧光增白剂0.2 %、水余量。The acidic ceramic cleaning agent specially used for cleaning precision ceramic bushings of the present invention has the following raw materials and mass percentages: 12% phosphoric acid, 5% hydrofluoric acid, 5% citric acid, 14% diethylene glycol, and 15% monobutyl ether , sodium tripolyphosphate 2%, dodecylbenzenesulfonic acid 4%, Ninar 2%, TX-10 phosphate ester 5%, strong wetting agent 0.6%, fluorescent whitening agent 0.2%, water balance .

所用原料及制备方法同实施例1。The raw materials used and the preparation method are the same as in Example 1.

使用方法及效果:How to use and effect:

将本发明实施例1~3加水配制质量百分比为3~8%的工作液,超声波清洗精密陶瓷套管5~10分钟,取出水洗干燥。精密陶瓷套管工件表面的光洁度、光亮度、白度及表面的耐蚀性等符合标准要求。Add water to prepare a working solution with a mass percentage of 3-8% in Examples 1-3 of the present invention, ultrasonically clean the precision ceramic sleeve for 5-10 minutes, take it out, wash it and dry it. The surface finish, brightness, whiteness and surface corrosion resistance of the precision ceramic sleeve workpiece meet the standard requirements.

Claims (2)

1.一种专用于清洗精密陶瓷套管的酸性陶瓷清洗剂,其特征在于所用原料及质量百分比如下:磷酸10~13%、氢氟酸3~6%、柠檬酸3~7%、二乙二醇10~18%、单丁醚10~18%、三聚磷酸钠1~3%、十二烷基苯磺酸3~7%、尼纳尔1~3%、TX-10磷酸酯1~9%、强效润湿剂0.1~1.2%、荧光增白剂0.1~0.3%、水余量。1. An acidic ceramic cleaning agent specially used for cleaning precision ceramic bushings, characterized in that the raw materials used and their mass percentages are as follows: phosphoric acid 10-13%, hydrofluoric acid 3-6%, citric acid 3-7%, diethyl Diol 10~18%, Monobutyl Ether 10~18%, Sodium Tripolyphosphate 1~3%, Dodecyl Benzene Sulfonic Acid 3~7%, Neal 1~3%, TX-10 Phosphate 1 ~9%, strong wetting agent 0.1~1.2%, optical brightener 0.1~0.3%, water balance. 2.一种权利要求1所述专用于清洗精密陶瓷套管的酸性陶瓷清洗剂的制备方法,其特征在于按照如下步骤进行:2. a kind of preparation method that is specially used in cleaning the acid ceramic cleaning agent of precision ceramic bushing as claimed in claim 1 is characterized in that carrying out according to the following steps: a. 将计算称量的磷酸、氢氟酸和部分计量的水混合搅拌至充分溶解,制成①号溶液;a. Mix and stir the calculated and weighed phosphoric acid, hydrofluoric acid and part of the measured water until fully dissolved to make solution ①; b. 将计算称量的柠檬酸、三聚磷酸钠和部分计量的水混合搅拌至充分溶解,制成②号溶液;b. Mix and stir the calculated and weighed citric acid, sodium tripolyphosphate and part of the measured water until fully dissolved to make solution ②; c. 将剩余的水加入到不锈钢反应釜中,启动搅拌器,设定转速为60转/分钟,再将计算称量的二乙二醇、单丁醚、十二烷基苯磺酸、尼纳尔、TX-10磷酸酯、强效润湿剂、荧光增白剂、①号溶液、②号溶液依次徐徐加入到反应釜中,边加入边搅拌,直至呈浅黄色透明溶液。c. Add the remaining water into the stainless steel reaction kettle, start the agitator, set the rotating speed to 60 rpm, and then add the calculated and weighed diethylene glycol, monobutyl ether, dodecylbenzenesulfonic acid, nitric acid Nar, TX-10 phosphate, powerful wetting agent, fluorescent whitening agent, No. ① solution, and No. ② solution are slowly added into the reaction kettle in sequence, and stirred while adding, until the light yellow transparent solution is formed.
CN201711421513.XA 2017-12-25 2017-12-25 Acidic ceramic cleaning agent specially used for cleaning precision ceramic bushings and preparation method thereof Pending CN108085166A (en)

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Cited By (1)

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Publication number Priority date Publication date Assignee Title
WO2021015632A1 (en) * 2019-07-24 2021-01-28 Quispe Muniz Wilber Composition for cleaning vehicle bodywork, rims, motors and accessories without damaging the paintwork, and preparation method

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CN103103033A (en) * 2012-12-10 2013-05-15 苏州丰儒软件有限公司 Ceramic craft cleaning agent and preparation method thereof

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CN1978616A (en) * 2005-12-09 2007-06-13 安徽铜都特种环保设备股份有限公司 Detergent for cleaning ceramic filtering plate
CN102925298A (en) * 2012-11-26 2013-02-13 华阳新兴科技(天津)集团有限公司 Water-based cleaning agent for soldering flux and preparation method thereof
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