CN107951812A - A kind of toner and preparation method thereof - Google Patents

Abstract

The invention discloses a toner and a preparation method thereof, belonging to the field of skin care products. The active substances in Sargassum schistosa are extracted by fermentation, and the fucoxanthin coated with nanoemulsion improves the storage stability of fucoxanthin. Acne bacteria exist on the skin hair follicles, and it will produce lipase during the growth process , and lipase will cause a series of inflammatory reactions, including the migration of white blood cells to the dermis of the skin, the release of inflammatory factors, inflammatory factors stimulate the skin, accelerate skin keratinization, thereby producing and worsening acne, the source of Sargassum split leaf extract It can inhibit the activation of lipase of acne bacteria in a concentration-dependent manner, so as to achieve anti-acne and anti-inflammatory effects. The present invention solves the problem that current toners mostly contain spices, alcohol, and heavy preservatives, which are likely to cause burdens on thin skin and skin that is prone to sensitive reactions to external stimuli. The nutritional ingredients are single, lack nourishing ingredients, and the moisturizing effect lasts. Short time issue.

Description

A kind of toner and preparation method thereof

technical field

The invention belongs to the field of skin care products, and in particular relates to a toner and a preparation method thereof.

Background technique

With the improvement of living standards, people pay more and more attention to skin care, but internal and external reasons lead to various skin problems. Internal reasons: Wrinkles, crow's feet, fine lines, and eye wrinkles are all caused by the uneven shrinkage and collapse of the epidermal layer of the skin. First of all, the skin is composed of three layers, namely the epidermis, dermis, and subcutaneous fat. The dermis contains collagen, elastin, and other fibers that form the skeleton that supports the skin. It is these elements that make the skin look smooth and young , These elements are also damaged by UVA, UVB, ozone or other oxidizing factors. External factors: Modern people are under a lot of pressure in life, working overtime and staying up late, long hours on the computer, smoking, lack of sleep, staying in an air-conditioned room for a long time, drinking alcohol, excessive eye use, etc. have become the norm in life, plus air pollution. According to the research of Dior Dior Beauty Science Center, every day, each layer of the skin will accumulate a large number of cell molecular toxins caused by internal or external factors, which will cause skin cells to suffocate and affect the skin's own ability to remove toxins, thus producing Dull complexion, lack of radiance, fatigue and other troubles increase the burden on the skin and accelerate skin aging.

"Lack of water" is one of the most important culprits of skin getting worse and aging. Moisturizing is not only a patent for sensitive skin. All kinds of skin will lack water due to factors such as environment, age, nutrition, and health. When human skin When the moisture content of the stratum corneum is lower than 10%, the skin will lose its softness and elasticity, and then become rough and dry, and various skin abnormalities will appear. If it is not corrected for a long time, the skin will age easily, and the spots will become sensitive. , Cosmetics for various problems of skin have also emerged at the historic moment. Toner is also called firming water, lotion, etc. Its function is to clean again to restore the pH value of the skin surface, and regulate the stratum corneum, so that the skin can better absorb it, and prepare for the use of skin care products. So after washing your face, use toner to replenish moisture quickly.

At present, the main ingredients of toner are water, moisturizer, emollient, synthetic fragrance, solubilizer, etc. In actual use, most of them contain fragrance, alcohol, and heavy preservatives, which are easy to affect thin skin and external skin. Stimulates sensitive skin and causes a burden. Especially the alcohol component will cause redness on sensitive skin after use, and the toner has a single nutrient component, lacks nourishing components, and the moisturizing effect lasts for a short time. Therefore, there is a great market demand for producing a toner that is effective and does not harm the skin.

Contents of the invention

The technical problem to be solved by the present invention: most of the current toners contain spices, alcohol, and heavy preservatives, which are likely to cause a burden on thin skin and skin that is prone to sensitive reactions to external stimuli, and the nutritional components are single and lack nourishment. Composition, the problem of short duration of moisturizing effect, provide a toner and a preparation method thereof.

In order to solve the problems of the technologies described above, the present invention adopts the following technical solutions:

A skin toner, in parts by mass, comprising 2 to 3 parts of citric acid, 3 to 5 parts of lysine, 2 to 3 parts of propylene glycol, 0.1 to 0.2 parts of grape flavor, 4 to 6 parts of honey, 30 to 40 parts of super The pure water is characterized in that it also includes 12-20 parts of water-retaining agent, 15-18 parts of whitening agent, and 8-12 parts of anti-acne agent.

The moisturizing agent is to take mussel shells according to the mass ratio of 1:10 and add them to 0.5% hydrochloric acid solution for soaking for 2~3 hours, take out the soaked mussel shells, dry them at 80~85°C for 1~2 hours, crush them, and pass through 100 mesh Sieve, collect the sieved particles A to get mussel shell powder, wash the wakame, dry, crush and pass through a 40-mesh sieve, collect the sieved particles B, add absolute ethanol at a mass ratio of 1:8, keep for 1~1.5h, and rotate Evaporate, take the rotary evaporator and mix it with distilled water at a mass ratio of 1:10, extract at 90-95°C for 2-3 hours, centrifuge, take the supernatant A and add a 15% trichloroacetic acid solution at a mass ratio of 1:5 and stir Mix, stand still for 12~15h, centrifuge, take the supernatant B and add activated carbon according to the mass ratio of 5:2, stir and decolorize for 1~2h, filter, take the filtrate to concentrate by rotary evaporation, dialyze for 12h, and freeze-dry to obtain the wakame extract. Take mussel shell powder and add it to wakame extract in a mass ratio of 1:3 and mix to obtain a moisturizing agent.

The whitening agent: collect white bougainvillea and rhodiola rosea, wash, dry at 50-60°C, crush and pass through an 80-mesh sieve, collect white bougainvillea and rhodiola sieve particles, and use a mass ratio of 1:2:10 ~12 Add absolute ethanol, reflux extraction at 35~45°C for 2~3h, filter, take the filtrate, rotary evaporate, and concentrate under reduced pressure to obtain the whitening agent.

The preparation method of described antiacne agent comprises the steps:

(1) Take Sargassum sargassum at a mass ratio of 1:4 and soak in water at 40-45°C for 30-40 minutes, take it out and dry it, crush it through an 80-mesh sieve, collect the sieved particles of Sargassum sargassum, and take Bacillus natto according to the mass ratio Inoculate into the activation medium at a ratio of 1:10, culture at 35-37°C and 150 r/min for 1-2 days to obtain a culture medium, take the sieved granules of Sargassum schizophrenia and add them to the culture medium at a mass ratio of 1:8. Ferment at 33~37°C for 3~4 days to obtain a fermentation liquid, take the fermentation liquid and add 60% ethanol solution at a mass ratio of 1:10, extract for 1~2 hours, centrifuge, take the supernatant, concentrate under reduced pressure, and obtain The concentrate was extracted with petroleum ether, and the extract was rotary evaporated and dried to obtain a dry product;

(2) Take the dry matter and add pine nut oil according to the mass fraction of 5:1, then add Tween-80 with 8~10% pine nut oil quality, stir and mix at 25~30°C for 40~50min, add 10% of the dry matter ~20% water, then stirred for 1~1.5h, sheared at 7500r/min for 4~5min, and homogenized 4 times at 120~130MPa by micro jet to obtain anti-acne agent.

The activation medium is calculated in parts by mass, including 0.5-0.8 parts of beef extract, 0.5-0.7 parts of peptone, 0.5-1 part of NaCl, 100 parts of deionized water, and the pH is natural.

The preparation method of the toner comprises the following steps: taking water-retaining agent, whitening agent, anti-acne agent, citric acid, lysine, propylene glycol, grape flavor, honey, and ultrapure water, stirring and mixing at 50-60°C for 1-2 hours , get toner.

Compared with other methods, the present invention has beneficial technical effects as follows:

(1) The present invention extracts active substances from mussel shells. On the one hand, mussel shell powder contains a variety of amino acids and trace elements, among which serine and valine can regulate human endocrine, enhance immunity and anti-aging, and leucine and Valine has the functions of repairing tissues and whitening skin. Mussel shell powder, similar to pearl powder, contains a variety of metal elements such as copper, iron, zinc, and strontium needed by the human body. Among them, copper element has anti-radiation effect, and zinc element has skin repairing effect. Function, on the other hand, it can adsorb other active substances, better play the role of toner, extract the seaweed polysaccharide in the crony, can inhibit the generation of active oxygen free radicals and promote their removal, and can effectively reduce the content of lipid peroxides. Improve the activity of peroxidase and superoxide dismutase, and the mycosporin-like amino acid is a kind of stable natural viscous polysaccharide small molecule hygroscopic agent, which shows different forms in different environments, low It is viscous at high concentration, elastic at high concentration, and has good moisture absorption and moisturizing effect on the skin;

(2) The present invention extracts whitening active substances from Bougainvillea and Rhodiola. Because Bougainvillea is rich in flavonoids and polyphenols, it is beneficial to inhibit the growth of bacteria and has good antibacterial and anti-inflammatory effects. Sedum sedum has a good ability to inhibit tyrosinase activity, prevent the deposition of melanin, and has whitening effect;

(3) The present invention extracts the active substances in Sargassum schizophrenia by fermentation, and fucoxanthin coated with nanoemulsion improves the storage stability of fucoxanthin. Acne bacteria exist on the skin hair follicles and use sebum as nutrition Source, it will produce lipase during the growth process, and lipase will cause a series of inflammatory reactions, including the migration of white blood cells to the dermis of the skin, release of inflammatory factors, inflammatory factors stimulate the skin, accelerate skin keratinization, resulting in and worsening acne, Sargassum schistophora extract has inhibitory effect on the activation of lipase derived from acne bacteria, and has a concentration-dependent effect, so as to achieve anti-acne and anti-inflammatory effects;

(4) The present invention enriches the nutritional ingredients of the toner by adding whitening, moisturizing, and anti-acne functional additives, and most of them are natural active extracts, which reduce skin irritation and will not burden the skin. In addition, the Antioxidant substances can protect some active substances from being oxidized and decomposed. Adsorbent substances are added to concentrate and absorb nutrients, which is beneficial to better effect on the skin, and nanoemulsions are added to stabilize the whole system to ensure the quality of toner.

Detailed ways

Bacillus natto: Store on refrigerated slopes.

Activation medium: in parts by mass, take 0.5-0.8 parts of beef extract, 0.5-0.7 parts of peptone, 0.5-1 part of NaCl, 100 parts of deionized water, and the pH is natural.

Pine nut oil: purchased from Yichun Zhongmeng Food Technology Co., Ltd.

Moisturizing agent: take mussel shells and add them to 0.5% hydrochloric acid solution at a mass ratio of 1:10 to soak for 2-3 hours, take out the soaked mussel shells, dry them at 80-85°C for 1-2 hours, crush them, and pass through a 100-mesh sieve. Collect sieved particles A to obtain mussel shell powder, wash wakame, dry, crush and pass through a 40-mesh sieve, collect sieved particles B, add absolute ethanol at a mass ratio of 1:8, keep for 1~1.5h, and rotate to evaporate , take the rotary evaporator and mix it with distilled water at a mass ratio of 1:10, extract at 90~95°C for 2~3 hours, centrifuge, take the supernatant A and add a 15% trichloroacetic acid solution at a mass ratio of 1:5, stir and mix , stand still for 12~15h, centrifuge, take the supernatant B and add activated carbon according to the mass ratio of 5:2, stir and decolorize for 1~2h, filter, take the filtrate, concentrate by rotary evaporation, dialyze for 12h, and freeze-dry to obtain the wakame extract. Take mussel shell powder and add it to wakame extract in a mass ratio of 1:3 and mix to obtain a moisturizing agent.

Whitening agent: collect Bougainvillea and Rhodiola rosea, take the young stems and leaves at the top, wash, dry at 50-60°C, crush and pass through an 80-mesh sieve, collect sieved granules of Bougainvillea and Rhodiola, press Mass ratio 1:2:10~12 Add absolute ethanol, reflux extraction at 35~45°C for 2~3h, filter, take the filtrate, rotary evaporate, and concentrate under reduced pressure to obtain the whitening agent.

Anti-acne agent: (1) Take Sargassum sargassum at a mass ratio of 1:4, soak in water at 40-45°C for 30-40 minutes, take it out and dry it, crush it through an 80-mesh sieve, collect the sieved particles of Sargassum sargassum, and take natto Bacteria were inoculated into the activation medium at a mass ratio of 1:10, cultured at 35-37°C and 150r/min for 1-2 days to obtain a culture medium, and the sieved particles of Sargassum schizophrenia were added to the culture medium at a mass ratio of 1:8 medium, fermented at 33-37°C for 3-4 days to obtain a fermented liquid, took the fermented liquid and added 60% ethanol solution at a mass ratio of 1:10, extracted for 1-2 hours, centrifuged, took the supernatant, and decompressed Concentrate to obtain a concentrate, extract with petroleum ether for 2 to 3 hours, take the extract by rotary evaporation, and dry to obtain a dry product;

(2) Take the dry matter and add pine nut oil according to the mass fraction of 5:1, then add Tween-80 with 8~10% pine nut oil quality, stir and mix at 25~30°C for 40~50min, add 10% of the dry matter ~20% water, then stirred for 1~1.5h, sheared at 7500r/min for 4~5min, and homogenized 4 times at 120~130MPa by micro jet to obtain anti-acne agent.

A preparation method of toner, comprising the following steps: in parts by mass, 12-20 parts of water-retaining agent, 15-18 parts of whitening agent, 8-12 parts of anti-acne agent, 2-3 parts of citric acid, 3-5 parts 1 part of lysine, 2~3 parts of propylene glycol, 0.1~0.2 part of grape flavor, 4~6 parts of honey, 30~40 parts of ultrapure water, stir and mix to obtain toner.

Example 1

Bacillus natto: Store on refrigerated slopes.

Activation medium: in parts by mass, take 0.5 parts of beef extract, 0.5 parts of peptone, 0.5 parts of NaCl, 100 parts of deionized water, and the pH is natural.

Pine nut oil: purchased from Yichun Zhongmeng Food Technology Co., Ltd.

Moisturizing agent: Take mussel shells and add them to 0.5% hydrochloric acid solution with a mass ratio of 1:10 to soak for 2 hours, take out the soaked mussel shells, dry them at 80°C for 1 hour, crush them, pass through a 100-mesh sieve, and collect the sieved particles A. To obtain mussel shell powder, take wakame, wash, dry, crush and pass through a 40-mesh sieve, collect sieved particles B, add absolute ethanol at a mass ratio of 1:8, keep for 1 hour, and rotate to evaporate, take the rotary evaporated product at a mass ratio of 1 : 10, add distilled water and mix, extract at 90°C for 2 hours, centrifuge, take supernatant A according to the mass ratio of 1:5, add 15% trichloroacetic acid solution, stir and mix, let stand for 12 hours, centrifuge, take supernatant B by Add activated carbon at a mass ratio of 5:2, stir and decolorize for 1 hour, filter, take the filtrate, concentrate by rotary evaporation, dialyze for 12 hours, and freeze-dry to obtain wakame extract, take mussel shell powder and add it to the wakame extract at a mass ratio of 1:3 and mix , get a moisturizer.

Whitening agent: collect Bougainvillea and Rhodiola rosea, take the young stems and leaves at the top, wash them, dry them at 50°C, crush them through an 80-mesh sieve, collect the sieved granules of Bougainvillea and Rhodiola rosea, and weigh them according to the mass ratio Add absolute ethanol at 1:2:10, reflux and extract at 35°C for 2 hours, filter, take the filtrate, rotary evaporate, and concentrate under reduced pressure to obtain the whitening agent.

Anti-acne agent: (1) Take Sargassum sargassum at a mass ratio of 1:4 and soak in 40°C water for 30 minutes, take it out and dry it, crush it through an 80-mesh sieve, collect Sargassum sargassum and sieve the granules, take Bacillus natto at a mass ratio Inoculate into the activation medium at a ratio of 1:10, culture at 35°C and 150r/min for 1 day to obtain a culture solution, take Sargassum sargassum sieve particles and add them to the culture solution at a mass ratio of 1:8, and ferment at 33°C for 3 days , to obtain a fermented liquid, take the fermented liquid and add an ethanol solution with a mass fraction of 60% at a mass ratio of 1:10, extract for 1 h, centrifuge, take the supernatant, concentrate under reduced pressure to obtain a concentrate, extract with petroleum ether for 2 h, and extract The liquid was rotary evaporated and dried to obtain a dried product;

(2) Take the dry matter and add pine nut oil at a mass fraction of 5:1, then add Tween-80 with 8% pine nut oil mass, stir and mix at 25°C for 40 minutes, add water with 10% mass of dry matter, and stir again Mix for 1 hour, shear at 7500r/min for 4 minutes, and homogenize for 4 times with micro jet at 120MPa to obtain the anti-acne agent.

A preparation method of skin toner, comprising the steps of: taking 12 parts of water-retaining agent, 15 parts of whitening agent, 8 parts of anti-acne agent, 2 parts of citric acid, 3 parts of lysine, 2 parts of propylene glycol, 0.1 parts by mass parts 1 part of grape flavor, 4 parts of honey, 30 parts of ultrapure water, stirred and mixed to obtain toner.

Example 2

Bacillus natto: Store on refrigerated slopes.

Activation medium: in parts by mass, take 0.8 parts of beef extract, 0.7 parts of peptone, 1 part of NaCl, 100 parts of deionized water, and the pH is natural.

Pine nut oil: purchased from Yichun Zhongmeng Food Technology Co., Ltd.

Moisturizing agent: Take mussel shells and add them to 0.5% hydrochloric acid solution at a mass ratio of 1:10 to soak for 3 hours, take out the soaked mussel shells, dry them at 85°C for 2 hours, crush them, pass through a 100-mesh sieve, and collect sieved particles A. To obtain mussel shell powder, take wakame, wash, dry, crush and pass through a 40-mesh sieve, collect the sieved particles B, add absolute ethanol at a mass ratio of 1:8, keep for 1.5h, and rotate to evaporate. Take the rotary evaporated product according to the mass ratio Add distilled water and mix at 1:10, extract at 95°C for 3 hours, centrifuge, take supernatant A according to the mass ratio of 1:5, add 15% trichloroacetic acid solution, stir and mix, let stand for 15 hours, centrifuge, take supernatant B Add activated carbon according to the mass ratio of 5:2, stir and decolorize for 2 hours, filter, take the filtrate, concentrate by rotary evaporation, dialyze for 12 hours, freeze-dry to obtain the wakame extract, take the mussel shell powder and add it to the wakame extract according to the mass ratio of 1:3 Mix for a moisturizer.

Whitening agent: collect Bougainvillea and Rhodiola rosea, take the young stems and leaves at the top, wash them, dry them at 60°C, crush them through an 80-mesh sieve, collect sieved granules of Bougainvillea and Rhodiola rosea, and weigh them according to the mass ratio Add absolute ethanol at 1:2:12, reflux and extract at 45°C for 3 hours, filter, take the filtrate, rotary evaporate, and concentrate under reduced pressure to obtain the whitening agent.

Anti-acne agent: (1) Take Sargassum sargassum at a mass ratio of 1:4, soak in 45°C water for 40 minutes, take it out and dry it, crush it through an 80-mesh sieve, collect Sargassum sargassum and sieve the granules, and take Bacillus natto at a mass ratio Inoculate into the activation medium at a ratio of 1:10, culture at 37°C and 150r/min for 2 days to obtain a culture solution, take Sargassum sargassum sieve particles and add them to the culture solution at a mass ratio of 1:8, and ferment at 37°C for 4 days , to obtain a fermented liquid, take the fermented liquid and add an ethanol solution with a mass fraction of 60% at a mass ratio of 1:10, extract for 2 hours, centrifuge, take the supernatant, concentrate under reduced pressure to obtain a concentrate, extract with petroleum ether for 3 hours, and extract The liquid was rotary evaporated and dried to obtain a dried product;

(2) Take the dry matter and add pine nut oil at a mass fraction of 5:1, then add Tween-80 with 10% pine nut oil mass, stir and mix at 30°C for 50 minutes, add water with 20% mass of dry matter, and stir again Mix for 1.5h, shear at 7500r/min for 5min, and homogenize 4 times with micro jet at 130MPa to obtain the anti-acne agent.

A method for preparing skin toner, comprising the steps of: taking 20 parts of water-retaining agent, 18 parts of whitening agent, 12 parts of anti-acne agent, 3 parts of citric acid, 5 parts of lysine, 3 parts of propylene glycol, and 0.2 parts by mass. 1 part of grape flavor, 6 parts of honey, 40 parts of ultrapure water, stirred and mixed to obtain toner.

Example 3

Bacillus natto: Store on refrigerated slopes.

Activation medium: in parts by mass, take 0.65 parts of beef extract, 0.6 parts of peptone, 0.75 parts of NaCl, 100 parts of deionized water, and the pH is natural.

Pine nut oil: purchased from Yichun Zhongmeng Food Technology Co., Ltd.

Moisturizing agent: take mussel shells and add them to 0.5% hydrochloric acid solution at a mass ratio of 1:10 and soak for 2.5 hours, take out the soaked mussel shells, dry them at 83°C for 1.5 hours, crush them, pass through a 100-mesh sieve, and collect the sieved particles A, to obtain mussel shell powder, wash wakame, dry, crush and pass through a 40-mesh sieve, collect the sieved particles B, add absolute ethanol at a mass ratio of 1:8, keep for 1.25h, and rotate to evaporate. Mix with distilled water at a mass ratio of 1:10, extract at 93°C for 2.5 hours, centrifuge, take the supernatant A at a mass ratio of 1:5, add 15% trichloroacetic acid solution, stir and mix, let stand for 13.5 hours, centrifuge, and take Add activated carbon to the supernatant B at a mass ratio of 5:2, stir and decolorize for 1.5 hours, filter, take the filtrate, concentrate by rotary evaporation, dialyze for 12 hours, and freeze-dry to obtain wakame extract, take mussel shell powder and add at a mass ratio of 1:3 Mix in wakame extract for a moisturizer.

Whitening agent: collect Bougainvillea and Rhodiola rosea, take the young stems and leaves at the top, wash them, dry them at 55°C, crush them through an 80-mesh sieve, collect sieved granules of Bougainvillea and Rhodiola rosea, and weigh them according to the mass ratio Add absolute ethanol at 1:2:11, reflux and extract at 40°C for 2.5 hours, filter, take the filtrate, rotary evaporate, and concentrate under reduced pressure to obtain the whitening agent.

Anti-acne agent: (1) Take Sargassum sargassum at a mass ratio of 1:4 and soak in 43°C water for 35 minutes, take it out and dry it, crush it through an 80-mesh sieve, collect Sargassum sargassum and sieve the granules, take Bacillus natto at a mass ratio Inoculate into the activation medium at a ratio of 1:10, culture at 36°C and 150r/min for 1.5 days to obtain a culture medium, take Sargassum sargassum sieve particles and add them to the culture medium at a mass ratio of 1:8, and ferment at 35°C for 3.5 days , to obtain a fermented liquid, take the fermented liquid and add an ethanol solution with a mass fraction of 60% at a mass ratio of 1:10, extract for 1.5 h, centrifuge, take the supernatant, concentrate under reduced pressure to obtain a concentrate, extract with petroleum ether for 2.5 h, The extract was rotary evaporated and dried to obtain a dried product;

(2) Take the dry matter and add pine nut oil at a mass fraction of 5:1, then add Tween-80 with 9% pine nut oil mass, stir and mix at 27°C for 45 minutes, add water with 15% mass of dry matter, and stir again Mix for 1.3h, cut at 7500r/min for 4.5min, and homogenize 4 times with micro jet at 125MPa to obtain the anti-acne agent.

A preparation method of skin toner, comprising the steps of: taking 16 parts of water-retaining agent, 16.5 parts of whitening agent, 10 parts of anti-acne agent, 2.5 parts of citric acid, 4 parts of lysine, 2.5 parts of propylene glycol, 0.15 parts by mass parts 1 part of grape flavor, 5 parts of honey, 35 parts of ultrapure water, stirred and mixed to obtain toner.

Comparative example 1

The preparation method is basically the same as that of Example 1, except that it lacks a water-retaining agent.

Comparative example 2

The preparation method is basically the same as that of Example 1, except that it lacks the whitening agent.

Comparative example 3

The preparation method is basically the same as that of Example 1, except that the anti-acne agent is lacking.

Comparative example 4

A toner produced by a company in Guangzhou.

According to QB/T4256-2011, the use of capacitance method to measure the moisture content of human skin stratum corneum is based on the significant difference in the dielectric constant of water and other substances. According to the different moisture content of skin stratum corneum, the measured skin capacitance value is different. The parameter may represent skin moisture content. Select 100 healthy volunteers, use the samples of the example and the control example to apply on the inner side of the left forearm (3cm×3cm) and the inner side of the right forearm (3cm×3cm) of the test subjects at the same time, and let the subjects evaluate, full marks 10 points, and the test results are shown in Table 1.

Table 1:

From the data of Examples 1 to 3, it can be seen that Example 1 is the optimal embodiment, and the obtained toner has the best effect. Based on the above, the toner of the present invention has a good effect and is worthy of promotion and use.

Claims (6)

1. a kind of toner, according to the mass fraction, including 2 ~ 3 parts of citric acids, 3 ~ 5 parts of lysines, 2 ~ 3 parts of propane diols, 0.1 ~ 0.2 Part grape flavor, 4 ~ 6 parts of honey, 30 ~ 40 parts of ultra-pure waters, it is characterised in that further include 12 ~ 20 parts of water-retaining agent, 15 ~ 18 parts of whitenings Agent, 8 ~ 12 parts of anti-acne agent.

2. toner according to claim 1, it is characterised in that the moisturizer is to take mussel shell in mass ratio 1：10 add Enter mass fraction to soak 2 ~ 3h in 0.5% hydrochloric acid solution, take out the mussel shell after immersion, in 80 ~ 85 DEG C of dry 1 ~ 2h, crush, 100 mesh sieves are crossed, sieving particle A is collected, obtains mussel shell powder, take undaria pinnitafida cleaning, drying, crushed 40 mesh sieves, collect sieving Particle B in mass ratio 1：8 add absolute ethyl alcohol, keep 1 ~ 1.5h, rotary evaporation, takes rotary evaporation thing in mass ratio 1：10 add Distilled water mixes, and 2 ~ 3h is extracted in 90 ~ 95 DEG C, centrifugation, takes supernatant A in mass ratio 1：5 add three chloroethenes of mass fraction 15% Acid solution is stirred, and stands 12 ~ 15h, centrifugation, takes supernatant B in mass ratio 5：2 add activated carbon, stirring 1 ~ 2h of decoloration, mistake Filter, takes filtrate rotary evaporation to concentrate, and dialyse 12h, and freeze-drying, obtains undaria pinnitafida extract, take mussel shell powder in mass ratio 1：3 Add in undaria pinnitafida extract and mix, obtain moisturizer.

3. toner according to claim 1, it is characterised in that the whitening agent：Collection Bai le and rhodiola root are cleaned, in 50 ~ 60 DEG C dry, pulverize 80 mesh sieves, collect Bai le sieving particle and rhodiola root sieving particle, and in mass ratio 1：2：10 ~ 12 add Enter absolute ethyl alcohol, in 35 ~ 45 DEG C of 2 ~ 3h of refluxing extraction, filtering, takes filtrate, rotary evaporation, is concentrated under reduced pressure, and obtains whitening agent.

4. toner according to claim 1, it is characterised in that the preparation method of the anti-acne agent includes the following steps：

（1）Take decomposite leaf sargassum in mass ratio 1：4, which add 40 ~ 45 DEG C of water, soaks 30 ~ 40min, and taking-up dry, pulverize 80 mesh Sieve, collects decomposite leaf sargassum sieving particle, takes Bacillus natto in mass ratio 1：10 are seeded in activation medium, in 35 ~ 37 DEG C, 150 r/min are cultivated 1 ~ 2 day, obtain nutrient solution, take decomposite leaf sargassum sieving particle in mass ratio 1：8 add in nutrient solutions, in 33 ~ 37 DEG C ferment 3 ~ 4 days, obtain zymotic fluid, take zymotic fluid in mass ratio 1：10 add mass fraction as 60% ethanol solution, and extraction 1 ~ 2h, centrifugation, takes supernatant, is concentrated under reduced pressure, obtain concentrate, with petroleum ether extraction, take extract rotary evaporation, dry, obtains drying Thing；

（2）Dried object is taken by mass fraction 5：1 adds pine-seed oil, the Tween-80 of pine nut oil quality 8 ~ 10% is added, in 25 ~ 30 40 ~ 50min DEG C is stirred, adds the water of dried object amount of substance 10 ~ 20%, is stirred for mixed 1 ~ 1.5h, 4 are sheared with 7500r/min ~ 5min, through microjet with 120 ~ 130MPa, homogeneous 4 times anti-acne agent.

5. toner according to claim 4, it is characterised in that the activation medium is according to the mass fraction, to take 0.5 ~ 0.8 portion of beef extract, 0.5 ~ 0.7 part of peptone, 0.5 ~ 1 part of NaCl, 100 parts of deionized waters, pH are natural.

6. a kind of preparation method of toner as claimed in claim 1, it is characterised in that the preparation method includes following step Suddenly：Go bail for aqua, whitening agent, anti-acne agent, citric acid, lysine, propane diols, grape flavor, honey, ultra-pure water, in 50 ~ 60 DEG C 1 ~ 2h is stirred, obtains toner.