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CN107936809A - A kind of pavement material and preparation method - Google Patents

A kind of pavement material and preparation method Download PDF

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Publication number
CN107936809A
CN107936809A CN201711238195.3A CN201711238195A CN107936809A CN 107936809 A CN107936809 A CN 107936809A CN 201711238195 A CN201711238195 A CN 201711238195A CN 107936809 A CN107936809 A CN 107936809A
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CN
China
Prior art keywords
titanium dioxide
methyl
nano
particle diameter
covering agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711238195.3A
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Chinese (zh)
Inventor
樊晓军
关有俊
熊永强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHENZHEN JIADA HIGH-TECH INDUSTRY DEVELOPMENT Co Ltd
Original Assignee
SHENZHEN JIADA HIGH-TECH INDUSTRY DEVELOPMENT Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHENZHEN JIADA HIGH-TECH INDUSTRY DEVELOPMENT Co Ltd filed Critical SHENZHEN JIADA HIGH-TECH INDUSTRY DEVELOPMENT Co Ltd
Priority to CN201711238195.3A priority Critical patent/CN107936809A/en
Publication of CN107936809A publication Critical patent/CN107936809A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1656Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662Synthetic film-forming substance
    • C09D5/1675Polyorganosiloxane-containing compositions
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0806Silver
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Road Paving Structures (AREA)

Abstract

The present invention provides a kind of pavement material, which includes the component of following mass fraction:Water 8~10%, aqueous polyurethane 70~75%, covering agent 13~15%, nano-titanium dioxide 4~5%, alcohol ester 12~0.5%, hydroxypropyl methyl cellulose 0.05~0.1%, nano silver 1~3%, propane diols 0.2~0.5%, 2 amino, 2 methyl, 1 propyl alcohol 0.05~0.1%, dimethyl silicone polymer 0.05~0.1%, dispersant 0.2~0.5% and mould inhibitor 0.05~0.1%, wherein, the covering agent is particle diameter for the titanium dioxide more than 1 micron.By using aqueous polyurethane as film forming matrix, using nano-titanium dioxide, a kind of hydrophilic layer can be formed in film layer under the ultraviolet excitation of sunlight, in this way, the spot on surface can or can not remain in road surface for a long time.

Description

A kind of pavement material and preparation method
Technical field
The invention belongs to ornament materials preparing technical field, more particularly to a kind of pavement material and preparation method.
Background technology
With progress of the epoch, people increasingly focus on living environment.
At present, city square, go slowly road and people's walking along the street are mainly mated formation using cement or pavior brick, decorative effect list One, and easily there is phenomena such as surface comes off or fades, road surface easily forms spot, it is necessary to clean daily, adds The workload of road upkeep.
The content of the invention
The present invention provides a kind of pavement material and preparation method, it is intended to and it is single to solve existing road surface decorative effect, Easily there is surface to come off or fade, and easily caused by formation spot the problem of road upkeep heavy workload.
The present invention provides a kind of pavement material, and the material includes the component of following mass fraction:
Water 8~10%, aqueous polyurethane 70~75%, covering agent 13~15%, nano-titanium dioxide 4~5%, alcohol ester ten 2 0.3~0.5%, hydroxypropyl methyl cellulose 0.05~0.1%, nano silver 1~3%, propane diols 0.2~0.5%, 2- ammonia Base -2- methyl isophthalic acids-propyl alcohol 0.05~0.1%, dimethyl silicone polymer 0.05~0.1%, dispersant 0.2~0.5% and mould proof Agent 0.05~0.1%, wherein, the covering agent is particle diameter for the titanium dioxide more than 1 micron.
The present invention provides a kind of preparation method of material, it is characterised in that the described method includes:According to mass fraction by water 8~10%, aqueous polyurethane 70~75%, titanium dioxide 13~15%, nano-titanium dioxide 4~5%, alcohol ester 12~ 0.5%th, hydroxypropyl methyl cellulose 0.05~0.1%, nano silver 1~3%, propane diols 0.2~0.5%, 2- amino -2- first Base -1- propyl alcohol 0.05~0.1%, dimethyl silicone polymer 0.05~0.1%, dispersant 0.2~0.5% and mould inhibitor 0.05~ 0.1% mixing, stirring, obtains the pavement material.
A kind of pavement material provided by the invention and preparation method, by using aqueous polyurethane as film forming matrix, profit With nano-titanium dioxide, a kind of hydrophilic layer can be formed in film layer under the ultraviolet excitation of sunlight, in this way, the dirt on surface Stain can or can not remain in road surface for a long time.
Embodiment
Goal of the invention, feature, advantage to enable the present invention is more obvious and understandable, below will be to of the invention real The technical solution applied in example is clearly and completely described, it is clear that described embodiment is only that a present invention part is implemented Example, and not all embodiments.Based on the embodiments of the present invention, those skilled in the art are not making creative work premise Lower all other embodiments obtained, belong to the scope of protection of the invention.
The present invention provides a kind of pavement material, which includes the component of following mass fraction:
Water 8~10%, aqueous polyurethane 70~75%, covering agent 13~15%, nano-titanium dioxide 4~5%, alcohol ester ten 2 0.3~0.5%, hydroxypropyl methyl cellulose 0.05~0.1%, nano silver 1~3%, propane diols 0.2~0.5%, 2- ammonia Base -2- methyl isophthalic acids-propyl alcohol 0.05~0.1%, dimethyl silicone polymer 0.05~0.1%, dispersant 0.2~0.5% and mould proof Agent 0.05~0.1%, wherein, the covering agent is particle diameter for the titanium dioxide more than 1 micron.
A kind of pavement material provided by the invention and preparation method, by using aqueous polyurethane as film forming matrix, profit With nano-titanium dioxide, a kind of hydrophilic layer can be formed in film layer under the ultraviolet excitation of sunlight, in this way, the dirt on surface Stain can or can not remain in road surface for a long time.
Specifically, dispersant is at least one of the methoxy of methyl -3 radical siloxane and the ethoxy radical siloxane of methyl -3.It is anti- Mould dose is hexadecyltrimethylammonium chloride, methyl tricapryl ammonium chloride, ten alkyl front three collection ammonium bromides and two allyl of dimethyl At least one of ammonium chloride.
Specifically, the particle diameter of nano-titanium dioxide is less than 100 nanometers.Preferably, the particle diameter of nano-titanium dioxide for 30~ 100 nanometers.
Particle diameter preferably as the titanium dioxide of covering agent is 30~100 microns.
In actual use, aqueous polyurethane can improve the physical mechanical property of film layer, wherein aqueous polyurethane It is used in conjunction with each other with alcohol ester 12, uniformity of the film layer in material surface can be increased.In addition, it is micro- that covering agent, which selects particle diameter, Meter level titanium dioxide, can improve the covering performance of material.Select nano-titanium dioxide to add, since it is nanoscale, compare table Area is big, one layer of hydrophilic layer can be formed, so as to add self-cleaning function under the irradiation of ultraviolet light.
In the embodiment of the present invention, in the material, adding mould inhibitor makes material have anti-mold effect, adds neutralizer 2- ammonia Base -2- methyl isophthalic acids-propyl alcohol can adjust the pH value of material, improve stability, and adding -3 methoxy radical siloxane of dispersant methyl can To disperse titanium dioxide, prevent from reuniting, add nano silver as fungicide, add hydroxypropyl methyl cellulose and be mainly used for Water retention, increases the application property of material, adds defoamer and is used to eliminate the bubble produced in whipping process, adds propane diols and make For antifreezing agent, the use function of material can be increased.
The present invention provides a kind of preparation method of pavement material, and this method includes:
According to mass fraction by water 8~10%, aqueous polyurethane 70~75%, covering agent 13~15%, nanometer titanium dioxide Titanium 4~5%, alcohol ester 12~0.5%, hydroxypropyl methyl cellulose 0.05~0.1%, nano silver 1~3%, propane diols 0.2~0.5%, 2-amino-2-methyl-1-propanol 0.05~0.1%, dimethyl silicone polymer 0.05~0.1%, dispersant 0.2~0.5% and mould inhibitor 0.05~0.1% mix, stirring, obtain pavement material, wherein, covering agent be particle diameter be more than 1 The titanium dioxide of micron.
Embodiment 1
By water 10kg, aqueous polyurethane 70kg, the titanium dioxide 13kg that particle diameter is 50 microns, the nanometer that particle diameter is 50 nanometers Titanium dioxide 4kg, 12 0.3kg of alcohol ester, hydroxypropyl methyl cellulose 0.1kg, nano silver 1kg, propane diols 0.4kg, 2- amino- 2- methyl isophthalic acids-propyl alcohol 0.05kg, dimethyl silicone polymer 0.1kg, the methoxy radical siloxane 0.2kg of methyl -3 and cetyl front three Ammonium chloride 0.05kg is mixed, and stirring, obtains pavement material.
Embodiment 1
By water 7kg, aqueous polyurethane 60kg, the titanium dioxide 13kg that particle diameter is 90 microns, the nanometer that particle diameter is 70 nanometers Titanium dioxide 5kg, 12 0.4kg of alcohol ester, hydroxypropyl methyl cellulose 0.4kg, nano silver 0.8kg, propane diols 0.3kg, 2- ammonia Base -2- methyl isophthalic acids-propyl alcohol 0.07kg, dimethyl silicone polymer 0.07kg, the ethoxy radical siloxane 0.12kg of methyl -3 and methyl three Octyl group ammonium chloride 0.06kg is mixed, and stirring, obtains pavement material.
Embodiment 3
By water 9kg, aqueous polyurethane 75kg, the titanium dioxide 11kg that particle diameter is 100 microns, the nanometer that particle diameter is 60 nanometers Titanium dioxide 3kg, 12 0.5kg of alcohol ester, hydroxypropyl methyl cellulose 0.06kg, nano silver 0.5kg, propane diols 0.3kg, 2- ammonia Base -2- methyl isophthalic acids-propyl alcohol 0.08kg, dimethyl silicone polymer 0.06kg, the ethoxy radical siloxane 0.3kg of methyl -3 and ten alkyl three First collection ammonium bromide 0.08kg is mixed, and stirring, obtains pavement material.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention All any modification, equivalent and improvement made within refreshing and principle etc., should all be included in the protection scope of the present invention.

Claims (8)

1. a kind of pavement material, it is characterised in that the material includes the component of following mass fraction:
Water 8~10%, aqueous polyurethane 70~75%, covering agent 13~15%, nano-titanium dioxide 4~5%, alcohol ester 12 0.3~0.5%, hydroxypropyl methyl cellulose 0.05~0.1%, nano silver 1~3%, propane diols 0.2~0.5%, 2- amino- 2- methyl isophthalic acids-propyl alcohol 0.05~0.1%, dimethyl silicone polymer 0.05~0.1%, dispersant 0.2~0.5% and mould inhibitor 0.05~0.1%, wherein, the covering agent is particle diameter for the titanium dioxide more than 1 micron.
2. material according to claim 1, it is characterised in that the dispersant includes:The methoxy of methyl -3 radical siloxane and At least one of ethoxy radical siloxane of methyl -3.
3. material according to claim 2, it is characterised in that the mould inhibitor includes:Hexadecyltrimethylammonium chloride, At least one of methyl tricapryl ammonium chloride, ten alkyl front three collection ammonium bromides and dimethyl diallyl ammonium chloride.
4. material according to claim 1, it is characterised in that the particle diameter of the nano-titanium dioxide is less than 100 nanometers.
A kind of 5. preparation method of pavement material, it is characterised in that the described method includes:According to mass fraction by water 8~10%, Aqueous polyurethane 70~75%, covering agent 13~15%, nano-titanium dioxide 4~5%, alcohol ester 12~0.5%, hydroxypropyl Ylmethyl cellulose 0.05~0.1%, nano silver 1~3%, propane diols 0.2~0.5%, 2-amino-2-methyl-1-propanol 0.05~0.1%, dimethyl silicone polymer 0.05~0.1%, dispersant 0.2~0.5% and mould inhibitor 0.05~0.1% are mixed To close, stirring, obtains the pavement material, wherein, the covering agent is particle diameter for the titanium dioxide more than 1 micron.
6. according to the method described in claim 5, it is characterized in that, the dispersant includes:The methoxy of methyl -3 radical siloxane and At least one of ethoxy radical siloxane of methyl -3.
7. according to the method described in claim 5, it is characterized in that, the mould inhibitor includes:Hexadecyltrimethylammonium chloride, At least one of methyl tricapryl ammonium chloride, ten alkyl front three collection ammonium bromides and dimethyl diallyl ammonium chloride.
8. according to the method described in claim 5, it is characterized in that, the particle diameter of the nano-titanium dioxide is less than 100 nanometers.
CN201711238195.3A 2017-11-30 2017-11-30 A kind of pavement material and preparation method Pending CN107936809A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711238195.3A CN107936809A (en) 2017-11-30 2017-11-30 A kind of pavement material and preparation method

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Application Number Priority Date Filing Date Title
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CN107936809A true CN107936809A (en) 2018-04-20

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Country Status (1)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108822716A (en) * 2018-06-28 2018-11-16 上海应用技术大学 A kind of microwave ice removing pavement material and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101260256A (en) * 2007-03-05 2008-09-10 张明德 Nano Road Coating Additives
CN101284957A (en) * 2007-04-13 2008-10-15 张明德 Noctilucent nano road traffic marking paint and preparation method thereof
CN101517010A (en) * 2006-09-20 2009-08-26 默克专利股份有限公司 Photocatalytically active coating
CN105968918A (en) * 2016-07-19 2016-09-28 合肥鼎亮光学科技有限公司 Antibacterial waterborne polyurethane luminescent reflective road marking coating and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101517010A (en) * 2006-09-20 2009-08-26 默克专利股份有限公司 Photocatalytically active coating
CN101260256A (en) * 2007-03-05 2008-09-10 张明德 Nano Road Coating Additives
CN101284957A (en) * 2007-04-13 2008-10-15 张明德 Noctilucent nano road traffic marking paint and preparation method thereof
CN105968918A (en) * 2016-07-19 2016-09-28 合肥鼎亮光学科技有限公司 Antibacterial waterborne polyurethane luminescent reflective road marking coating and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
沈春林等: "《建筑防水涂料》", 30 September 2003, 化学工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108822716A (en) * 2018-06-28 2018-11-16 上海应用技术大学 A kind of microwave ice removing pavement material and preparation method thereof

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Application publication date: 20180420

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