CN107913649A - Thixotroping multiplication agent and the silicate cement dispersion gel containing it - Google Patents
Thixotroping multiplication agent and the silicate cement dispersion gel containing it Download PDFInfo
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- CN107913649A CN107913649A CN201610888313.4A CN201610888313A CN107913649A CN 107913649 A CN107913649 A CN 107913649A CN 201610888313 A CN201610888313 A CN 201610888313A CN 107913649 A CN107913649 A CN 107913649A
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- thixotroping
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- silicate
- multiplication agent
- multiplication
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 61
- 239000006185 dispersion Substances 0.000 title claims abstract description 20
- 239000003469 silicate cement Substances 0.000 title abstract description 5
- 239000000499 gel Substances 0.000 claims abstract description 45
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000004094 surface-active agent Substances 0.000 claims abstract description 13
- 238000002360 preparation method Methods 0.000 claims abstract description 10
- 239000003381 stabilizer Substances 0.000 claims abstract description 6
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 5
- 239000003755 preservative agent Substances 0.000 claims abstract description 4
- 230000002335 preservative effect Effects 0.000 claims abstract description 4
- 239000007788 liquid Substances 0.000 claims abstract description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 7
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 6
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims description 5
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical compound CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 claims description 4
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 4
- 239000013530 defoamer Substances 0.000 claims description 3
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical group CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 239000000839 emulsion Substances 0.000 claims description 2
- 125000005456 glyceride group Chemical group 0.000 claims description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 2
- 238000009413 insulation Methods 0.000 claims description 2
- 239000000787 lecithin Substances 0.000 claims description 2
- 235000010445 lecithin Nutrition 0.000 claims description 2
- 229940067606 lecithin Drugs 0.000 claims description 2
- 239000002480 mineral oil Substances 0.000 claims description 2
- 235000010446 mineral oil Nutrition 0.000 claims description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 229920000053 polysorbate 80 Polymers 0.000 claims description 2
- 229960004889 salicylic acid Drugs 0.000 claims description 2
- 239000000052 vinegar Substances 0.000 claims description 2
- 235000021419 vinegar Nutrition 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 239000001768 carboxy methyl cellulose Substances 0.000 claims 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims 1
- 230000009974 thixotropic effect Effects 0.000 abstract description 15
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 230000001681 protective effect Effects 0.000 abstract description 3
- 230000009967 tasteless effect Effects 0.000 abstract description 3
- 230000008929 regeneration Effects 0.000 description 5
- 238000011069 regeneration method Methods 0.000 description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 239000013008 thixotropic agent Substances 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229920000609 methyl cellulose Polymers 0.000 description 3
- 239000001923 methylcellulose Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000010008 shearing Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000007665 sagging Methods 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000012496 blank sample Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000006077 pvc stabilizer Substances 0.000 description 1
- 238000007634 remodeling Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/0052—Preparation of gels
- B01J13/0065—Preparation of gels containing an organic phase
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention belongs to field of gel, is related to thixotroping multiplication agent and the silicate cement dispersion gel containing it.The thixotroping multiplication agent is the slightly sticky thick liquid of aqueous milky, wherein containing by mass percentage：Surfactant 10 20%, stabilizer 2 5%, emulsifying agent 3 8%, preservative 0.5 1%.The silicate cement dispersion gel of the multiplication agent containing thixotroping contains the thixotroping multiplication agent for the silicate CM 20 and 0.2 2% that mass percent concentration is 1 6%.The thixotroping multiplication agent of the present invention is nonpoisonous and tasteless, and aqueous, environmental protective, is added in 20 water dispersion gels of silicate CM, addition is convenient, and the thixotropic property of gel can be substantially improved rapidly, without side-effects, the preparation process of 20 gels of silicate CM can be greatly simplified at the same time, reduce manufacturing cost.
Description
Technical field
The invention belongs to field of gel, is related to thixotroping multiplication agent and the silicate cement dispersion gel containing it.
Background technology
Gel is a kind of special fluid, has good thixotropy.(no specified otherwise, refers to and just touches so-called thixotropy
Denaturation) refer to system when being acted on be subject to shearing force, system viscosity reduces, in favor of construction；After shearing force is removed, system
Viscosity higher was returned within several seconds, it is occurred without sagging in facade, top surface.Thixotropy is the importance of gel rubber system
Can, it directly influences the appearance of gel rubber system, the performance such as workability and storage stability.
Thixotropic agent is to provide thixotropic important substance for gel, and common thixotropic agent has：Silicate, organobentonite, two
Silica, polyamide wax, rilanit special etc..Wherein, silicate CM-20 is due to its particle diameter very little, and specific surface area is very big, surface
Strong adsorption force, surface energy is big, and performance is special, in water the dispersible colloid for forming transparence, thus frequently as thixotropic agent in crowd
More scientific domain extensive uses, the rheological equationm of state of formula system can greatly be changed by adding the appropriate material.
Research shows：Gel containing 1%, 2% silicate CM-20 is in fluidised form substantially, and mobility is preferable, and thixotropy is not strong,
Sag resistance is poor；Gel containing 3%, 4%, 5% silicate CM-20 has showed the state of gel, and poor fluidity, has one
Determine thixotropy, there is certain sag resistance；Gel containing more than 6% silicate CM-20 shows the characteristic of gel completely, does not have
Have mobility, thixotropy is very strong, can as the cream on birthday cake surface, keep thicker coating in facade and top surface and
Not sagging.
But containing the gel of more than 6% silicate CM-20, its prepare it is complex because the silicate that density is minimum
CM-20 powder volumes are very big, it is difficult to are mixed into water, and are uniformly mixed extremely difficult, it is necessary to which the mulser of tens thousand of rotating speeds divides
Dissipate.Since the other mulser price of laboratory level reaches tens thousand of members, the mulser of factory-level is even more to have reached hundreds thousand of members, this
Just huge human cost, financial cost are brought to experiment and production silicate CM-20 gels.
The content of the invention
The present invention primary and foremost purpose provide thixotroping multiplication agent, with nonpoisonous and tasteless at its, on the basis of aqueous, environmental protective, when by its
When being added in silicate CM-20 water dispersion gels, addition is convenient, and the thixotropic property of gel, no secondary work can be substantially improved rapidly
With, while the preparation process of silicate CM-20 gels can be greatly simplified, reduce manufacturing cost.
In order to achieve this, basis embodiment in, the present invention provide thixotroping multiplication agent, its for aqueous milky slightly
Thick liquid, wherein containing by mass percentage：Surfactant 10-20%, stabilizer 2-5%, emulsifying agent 3-8%, anti-corrosion
Agent 0.5-1%.
In a preferred embodiment, the present invention provides thixotroping multiplication agent, wherein the surfactant is selected from
One kind in lecithin, triethanolamine, turkey red oil or with the several of arbitrary proportion mixing.
In a preferred embodiment, the present invention provides thixotroping multiplication agent, wherein the stabilizer is selected from carboxylic first
Base cellulose, PVC stabilizers, one kind in phosphorous vinegar are mixed several with arbitrary proportion.
In a preferred embodiment, the present invention provides thixotroping multiplication agent, wherein the emulsifying agent is selected from fat
Sour monoglyceride, polyvinyl alcohol, one kind in modified turkey red oil are mixed several with arbitrary proportion.
In a preferred embodiment, the present invention provide thixotroping multiplication agent, wherein the preservative be selected from Kathon CG,
One kind in salicylic acid or two kinds with arbitrary proportion mixing.
In a preferred embodiment, the present invention provides thixotroping multiplication agent, it further contains mass percent 0-
15% other surfactant, the other surfactant are selected from fluorocarbon surfactant, Tween 80, aliphatic acid
One kind in glyceride or with the several of arbitrary proportion mixing.
In a preferred embodiment, the present invention provides thixotroping multiplication agent, it further contains mass percent 0-
2% defoamer, one kind in mineral oil, n-octyl alcohol, silicone emulsion of the defoamer or with arbitrary proportion mixing
It is several.
Second object of the present invention is to provide the preparation method of the thixotroping multiplication agent, it is to be sufficiently mixed various groups
Into component, high-speed stirred be placed in after five minutes in 60 DEG C of incubators insulation 24 it is small when, afterwards with incubator together natural cooling.
The thixotroping multiplication agent prepared, it is salable to be stored in reagent bottle, in use, only needing appropriate thixotroping multiplication agent
It is added to and is not sufficiently stirred in silicate CM-20 gel semi-finished product, together completes subsequently to be uniformly mixed with silicate CM-20 gels
Step.
Third object of the present invention is to provide the silicate CM-20 water dispersion gels containing the thixotroping multiplication agent,
It is convenient to prepare, simplify preparation process, reduce manufacturing cost, thixotropic property is substantially improved rapidly.
In order to achieve this, in the embodiment on basis, the present invention provides the silicate CM-20 water of the multiplication agent containing thixotroping
Dispersion gel, wherein the thixotroping multiplication containing the silicate CM-20 and 0.2-2% that mass percent concentration is 1-6%
Agent.
In a preferred embodiment, the present invention provides the silicate CM-20 water dispersion gels of the multiplication agent containing thixotroping,
The thixotroping multiplication agent wherein containing the silicate CM-20 and 0.5-1% that mass percent concentration is 3-5%.
The thixotroping multiplication agent of the present invention is added to the silicon that the multiplication agent containing thixotroping is prepared in silicate CM-20 water dispersion gels
Hydrochlorate CM-20 water dispersion gels, specific advantage are：
1) thixotroping multiplication effect is obvious：Silicate CM-20 water dispersed gel systems more than 3% concentration, add 1% touch
Become multiplication agent, thixotropic property is double.
2) it is without side-effects：Only improve thixotropic property, influence is showed no on other physicochemical properties.
3) it is easy to use, it is quick：In use, being added directly in silicate CM-20 gels, fully mix, number
It can achieve the desired results after minute.
4) preparation process of silicate CM-20 gels is greatly simplified：After adding thixotroping multiplication agent, because silicate CM-20
Powder additive amount greatly reduces, and can be uniformly dispersed by simple agitation, without emulsification.；
5) cost is reduced：Silicate CM-20 is expensive, and addition thixotroping multiplication agent can reduce silicate CM-20 uses
Amount；In preparation process, reduce high speed emulsifying process, save installation cost and manpower and materials.
6) it is nonpoisonous and tasteless, do not injure staff；Aqueous, environmental protective, it is environmental-friendly.
Brief description of the drawings
Fig. 1 is the thixotropic loop figure that the around-France measure of thixotroping of embodiment 1 is drawn.
Fig. 2 is the thixotropic loop figure that the around-France measure of thixotroping of embodiment 2 is drawn.
Fig. 3 is the system thixotroping structure regeneration rate experimental result of embodiment 3.
Embodiment
The embodiment of the present invention is further illustrated below in conjunction with attached drawing, if the concentration in text does not have
Particularly point out, refer both to mass percent concentration.
Embodiment 1：Add preparation and the thixotropy of 3% silicate CM-20 water dispersion gels of not same amount thixotroping multiplication agent
It can examine
Preparing the silicate CM-20 water dispersion gel containing 3% silicate CM-20, (silicate CM-20 water dispersion gel is bought
From Guangzhou Xuan Ning Chemical Industry Science Co., Ltd), two parts are divided into, a copy of it adds 1% thixotroping multiplication agent and (contains：Triethanolamine
11%th, methylcellulose 4%, glycerine monofatty ester 4%, Kathon CG 0.5%, fluorocarbon surfactant 3%), another does not add
Add thixotroping multiplication agent, draw its thixotropic loop figure by the around-France measure of thixotroping respectively, acquired results are as shown in Figure 1.
Thixotroping ring test is to characterize a kind of common method of fluid thixotropic, three cycles of experiment point：Period 1 and
Shear rate linear scan is improved and reduced respectively by three cycles, and shear rate is maintained at higher level by second round.Measure
Whole shear stress curve, uplink curve and downlink curve can iris out a hysteresis area, and the area is with destroying thixotroping structure
Required energy is directly proportional, and the value of this area is called thixotroping energy, can representation system to a certain extent thixotropy size.
Thixotroping can be bigger, and system thixotropy is stronger.
As seen from Figure 1, the system after 1% thixotroping multiplication agent is added, its thixotropy has very big change.Test result shows：
The system of thixotroping multiplication agent is not added with, thixotroping can be 531.24J；The system of 1% thixotroping multiplication agent is added, thixotroping can reach
1224.85J.As it can be seen that the addition of thixotroping multiplication agent, effectively improves system thixotropic property.
Embodiment 2：Add preparation and the thixotropy of 5% silicate CM-20 water dispersion gels of not same amount thixotroping multiplication agent
It can examine
The silicate CM-20 water dispersion gels containing 5% silicate CM-20 are prepared, three parts is divided into, adds 0% respectively,
0.5%, (composition is for 1.0% thixotroping multiplication agent：Triethanolamine 11%, methylcellulose 4%, glycerine monofatty ester 4%, card
Pine 0.5%, fluorocarbon surfactant 3%), it is uniformly mixed, draws the thixotropic loop figure of three samples by the around-France measure of thixotroping respectively
Shape, acquired results are as shown in Figure 2.
From Figure 2 it can be seen that the sample of addition 0.5% thixotroping multiplication agent, thixotropic property have been lifted than blank sample, added
The sample of 1.0% thixotroping multiplication agent, thixotropy are obviously improved.
Embodiment 3：Add the thixotroping structural remodeling experiment of the silicate CM-20 water dispersion gels of thixotroping multiplication agent
After the addition of viscosity recovery curve test characterization not same amount thixotroping multiplication agent, the reconstruction of gel rubber system thixotroping structure
Speed.
In producing and living, what people focused more on is the sag resistance that coating or glue coat system later, i.e. body
It is the regeneration rate of thixotroping structure (viscosity).Generally gel rubber system is destroyed as far as possible in laboratory using higher shear rate to touch
Structure changes, then stop shearing, system are measured using alap shear rate (as long as can measure valid data)
Viscosity recovery situation.System viscosity recovers more high faster, then system thixotropy is better.
(contain to provide thixotropic glue system with silicate CM-20 gels：Silicate CM-20 4%, citric acid
5%th, polyurethane 6%, castor oil 3.5%, n-octyl alcohol 0.5%, methyl hydroxybenzoate 0.5%, remaining be water) in, with the addition of difference
(composition is for the thixotroping multiplication agent of content：Triethanolamine 11%, methylcellulose 4%, glycerine monofatty ester 4%, Kathon CG
0.5%th, fluorocarbon surfactant 3%), using above method appraisement system thixotroping structure regeneration rate, the results are shown in Figure 3.
As seen from Figure 3, the glue system of thixotroping multiplication agent is with the addition of, thixotroping structure regeneration rate has very big lifting, especially
It is the system for adding 1% and the above, not only regeneration rate improves, and attainable highest viscosity is greatly enhanced, this is right
Construction is very favorable.
By above example 1-3 as it can be seen that the thixotroping multiplication agent of the present invention, can effectively lift silicate CM-20 gels
Thixotropic property, reduces silicate CM-20 usage amounts, so as to simplify preparation process, saves every cost.Therefore, it is of the invention to touch
Change multiplication agent is a kind of for all kinds of very effective thixotropings multiplication agent using silicate CM-20 as the system of thixotropic agent.
Obviously, various changes and modifications can be made to the invention without departing from essence of the invention by those skilled in the art
God and scope.If in this way, belong to the model of the claims in the present invention and its equivalent technology to these modifications and changes of the present invention
Within enclosing, then the present invention is also intended to comprising including these modification and variations.Above-described embodiment or embodiment are simply to the present invention
For example, the present invention can also be implemented with other ad hoc fashions or other particular form, without departing from the present invention's
Main idea or substantive characteristics.Therefore, it is regarded as from the point of view of the embodiment of description is in terms of any illustrative and non-limiting.This
The scope of invention should be illustrated that any change equivalent with the intention of claim and scope should also be included by appended claims
Within the scope of the invention.
Claims (10)
- The agent 1. thixotroping is doubled, it is characterized in that it is the slightly sticky thick liquid of aqueous milky, wherein containing by mass percentage：Live on surface Property agent 10-20%, stabilizer 2-5%, emulsifying agent 3-8%, preservative 0.5-1%.
- The agent 2. thixotroping according to claim 1 is doubled, it is characterized in that the surfactant is selected from lecithin, three ethanol One kind in amine, turkey red oil or with the several of arbitrary proportion mixing.
- The agent 3. thixotroping according to claim 1 is doubled, it is characterized in that the stabilizer is selected from carboxymethyl cellulose, PVC Mixed with one kind in stabilizer, phosphorous vinegar or with arbitrary proportion several.
- The agent 4. thixotroping according to claim 1 is doubled, it is characterized in that the emulsifying agent is selected from glycerine monofatty ester, gathers Vinyl alcohol, one kind in modified turkey red oil are mixed several with arbitrary proportion.
- The agent 5. thixotroping according to claim 1 is doubled, it is characterized in that the preservative in Kathon CG, salicylic acid one Two kinds for planting or being mixed with arbitrary proportion.
- The agent 6. thixotroping according to claim 1 is doubled, it is characterized in that further containing mass percent 0-15% in addition Surfactant, the other surfactant is in fluorocarbon surfactant, Tween 80, fatty glyceride It is a kind of or with arbitrary proportion mixing it is several.
- The agent 7. thixotroping according to claim 1 is doubled, it is characterized in that the defoaming further containing mass percent 0-2% Agent, one kind in mineral oil, n-octyl alcohol, silicone emulsion of the defoamer or with the several of arbitrary proportion mixing.
- 8. according to the preparation method of any thixotroping multiplication agent of claim 1-7, it is characterized in that being sufficiently mixed various compositions Component, high-speed stirred be placed in after five minutes in 60 DEG C of incubators insulation 24 it is small when, afterwards with incubator together natural cooling.
- 9. the silicate CM-20 water dispersion gels of the multiplication agent containing thixotroping, it is characterized in that being 1- wherein containing mass percent concentration Any thixotroping multiplication agent of claim 1-7 of 6% silicate CM-20 and 0.2-2%.
- 10. water dispersion gel according to claim 9, it is characterized in that being 3-5%'s wherein containing mass percent concentration Any thixotroping multiplication agent of claim 1-7 of silicate CM-20 and 0.5-1%.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610888313.4A CN107913649A (en) | 2016-10-11 | 2016-10-11 | Thixotroping multiplication agent and the silicate cement dispersion gel containing it |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610888313.4A CN107913649A (en) | 2016-10-11 | 2016-10-11 | Thixotroping multiplication agent and the silicate cement dispersion gel containing it |
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| CN107913649A true CN107913649A (en) | 2018-04-17 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109799528A (en) * | 2019-01-17 | 2019-05-24 | 中国辐射防护研究院 | Oxidation gel and preparation method thereof for the sampling of radioactive pollution metal shallow-layer |
| CN109799528B (en) * | 2019-01-17 | 2022-08-19 | 中国辐射防护研究院 | Oxidized gel for sampling radioactive contaminated metal shallow layer and preparation method thereof |
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