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CN107905038A - Package sheet material, preparation method and applications with recessive laser effect and flocking feel - Google Patents

Package sheet material, preparation method and applications with recessive laser effect and flocking feel Download PDF

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Publication number
CN107905038A
CN107905038A CN201711213553.5A CN201711213553A CN107905038A CN 107905038 A CN107905038 A CN 107905038A CN 201711213553 A CN201711213553 A CN 201711213553A CN 107905038 A CN107905038 A CN 107905038A
Authority
CN
China
Prior art keywords
feel
sheet material
package sheet
flocking
recessive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201711213553.5A
Other languages
Chinese (zh)
Other versions
CN107905038B (en
Inventor
张东亮
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUANGDONG XINRUI NEW MATERIAL TECHNOLOGY Co Ltd
Original Assignee
GUANGDONG XINRUI NEW MATERIAL TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Priority to CN201711213553.5A priority Critical patent/CN107905038B/en
Publication of CN107905038A publication Critical patent/CN107905038A/en
Application granted granted Critical
Publication of CN107905038B publication Critical patent/CN107905038B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/10Packing paper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/10Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/14Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30Multi-ply
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/10Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/26Polymeric coating

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Laminated Bodies (AREA)

Abstract

Be hidden the present invention provides a kind of laser effect and surface have flocking feel package sheet material, including body paper, glue-line, basement membrane, radium-shine dielectric layer, radium-shine dielectric layer includes the acrylate resin layer through molding and the zinc sulphide spacer material layer by the way that formation is deposited, covered with feel material layer on radium-shine dielectric layer, feel material layer includes aqueous polyurethane emulsion, 16 20% ethanol, 8 10% water and 2 4% aziridine that mass percent is 65 75%, and the latex particle average grain diameter of aqueous polyurethane emulsion is 80 120 μm;The package sheet material of the present invention can show radium-shine diffracting effect by scratching transparent gloss oil or stickup hinge in feel material layer, not only antifalse effect is good, and can solve the problems, such as that the strong radium-shine diffracting effect interference bar code scanner of the space of a whole page is read very well, it also avoid the increase of trouble and cost brought using local gilding technology.A kind of preparation method the present invention also provides above-mentioned package sheet material and its application on cigarette-brand, medicine, cosmetics.

Description

Package sheet material, preparation method with recessive laser effect and flocking feel and its Using
Technical field
The present invention relates to a kind of packaging material, more particularly to a kind of package sheet material with laser effect, more specifically relate to And a kind of laser effect is hidden and package sheet material of the surface with flocking feel.The invention further relates to a kind of above-mentioned package sheet material Preparation method and its application on cigarette-brand, medicine, cosmetics.
Background technology
Package sheet material with laser effect, due to brilliant appearance and certain antiforge function, because But the first choice of the high-grade packaging such as cigarette-brand, medicine, cosmetics.The package sheet material with laser effect to circulate on the market at present, Typically for full page visually intuitively with regard to that can see the universaling packing sheet material of radium-shine diffracting effect, this universaling packing sheet material is usually to wrap Body paper, glue-line, basement membrane, radium-shine dielectric layer and light oil reservoir are included, radium-shine dielectric layer includes resin bed and vacuum evaporation shape through molding Into aluminium lamination or sulfurized layer, it is not only right since package sheet material is that to be covered with radium-shine dielectric layer and top surface be light oil reservoir to full page The adsorptivity commodity bar code that is poor, and printing in the above of ink is printed, can usually be spread out because of strong radium-shine of the space of a whole page Penetrate effect and disturb the accurate reading of bar code scanner, the situation that scanner can be caused when serious to be read occurs;In order to Solve the problems, such as this, a kind of package sheet material with local laser effect comes into being, this bag with local laser effect Packaging sheet is on the sheet material printed, is scalded in the reserved area for needing to show laser effect using local gilding technology Print, since local gilding technology flow is complicated, required precision is high, thus causes the package sheet material with local laser effect to be fabricated to This is higher.
The content of the invention
To overcome the problem present on, the object of the present invention is to provide one kind to have recessive laser effect and flocking feel Package sheet material.
It is a further object of the present invention to provide a kind of above-mentioned package sheet material with recessive laser effect and flocking feel Preparation method.
Third object of the present invention, which is to provide, a kind of above-mentioned there is recessive laser effect and flocking feel package sheet material to exist Cigarette bag, medicine, the application on cosmetics.
In order to achieve the above object, the package sheet material with recessive laser effect and flocking feel of the present invention, including body paper, Glue-line, basement membrane, radium-shine dielectric layer, it is characterised in that:The radium-shine dielectric layer includes the acrylate resin layer through molding and passes through The zinc sulphide spacer material layer formed is deposited, includes quality covered with feel material layer, feel material layer on radium-shine dielectric layer Percentage is the aqueous polyurethane emulsion of 65-75%, the ethanol of 16-20%, the water of 8-10% and the aziridine of 2-4%, water-based poly- ammonia The latex particle average grain diameter of ester lotion is 80-120 μm;The package sheet material in feel material layer by scratching transparent gloss oil Or pasting hinge can show radium-shine diffracting effect.
In order to make package sheet material that there is local laser effect, the above-mentioned packaging with recessive laser effect and flocking feel Sheet material has further included light oil reservoir, which is set in feel material layer.
In order to make it is radium-shine more there is diffractive and beautiful effect, the evaporation medium of above-mentioned zinc sulphide spacer material layer be by Zinc sulphide and silica are 8 in mass ratio:2 are formulated.
In order to avoid the loss of body paper water content, ensure the flatness of package sheet material, it is above-mentioned have recessive laser effect and The body paper of the package sheet material of flocking feel is coated with back coating in the side opposite with glue-line.
, should the present invention also provides a kind of above-mentioned preparation method with recessive laser effect and the package sheet material of flocking feel Method in turn includes the following steps:
(1)Basement membrane is coated with:An acrylate resin layer is uniformly coated in the one side of basement membrane;
(2)Molding:Molding processing carries out acrylate resin layer using moulding press, forms common laser hologram pattern or special edition figure Case;
(3)Evaporation:Zinc sulphide spacer material layer is deposited on the acrylate resin layer with mould pressed pattern;
(4)It is compound:It is for composite with body paper after the another side coating glue of basement membrane;
(5)Face applies:Used in the zinc sulphide spacer material layer of compound rear substrate 45 ° of twills, reticulate pattern mesh number for 170 mesh intaglio plate Steel rod coats feel material layer, and the cavity depth of intaglio plate steel rod is 35-45 μm, width is 40-80 μm, and feel material layer is by wrapping Mass percent is included to prepare for the aziridine of the aqueous polyurethane emulsion of 65-75%, the ethanol of 16-20%, the water of 8-10% and 2-4% Form, the latex particle average grain diameter of aqueous polyurethane emulsion is formulated for 80-120 μm.
In above-mentioned preparation method, step(5)The wet coating amount of feel material is 6-7g/m2, wet coating viscosity be 16-20 ", drying Temperature step formula is controlled between 85-125 DEG C, and machine speed control is in 90-110m/min.
In above-mentioned preparation method, step(3)The evaporation medium of zinc sulphide spacer material layer is by zinc sulphide and silica It is 8 in mass ratio:2 are formulated, during evaporation zinc sulphide and silica dioxide medium using it is alternate put side by side by the way of.
Above-mentioned preparation method further includes step(6), which is to be printed in feel material layer according to design requirement subregion Brush transparent light oil reservoir.
It is even closer in order to enable evaporation medium to be combined with the water-based acrylic resin layer of molding, above by mold pressing procedure Product afterwards is deposited again after sided corona treatment and rewinding.
It is above-mentioned have recessive laser effect and the package sheet material of flocking feel as cigarette-brand, medicine, cosmetics packing timber Material uses.
The present invention's has recessive laser effect and the package sheet material of flocking feel, and the radium-shine diffracting effect of full page is hidden Under feel material layer, need to show the region of radium-shine diffracting effect by feel material layer printing varnish layer make it Show, not only antifalse effect is good, but also can solve the strong radium-shine diffracting effect interference bar code scanner of the space of a whole page very well and read The problem of, it also avoid the increase of trouble and cost brought using local gilding technology;In addition, the package sheet material of the present invention, Surface has the feel of Flocked fabric, and not only printability is good, ink absorption flow leveling and post-processing processability are excellent, but also Its matte effect can more protrude the class and quality of product.The preparation method of package sheet material of the present invention, technique is simple, cost of manufacture It is low, it is a kind of new anti-counterfeiting packing material being worth of widely use.
Brief description of the drawings
Fig. 1 is the structure diagram that the present invention has recessive laser effect and the package sheet material of flocking feel.
Fig. 2 is the flow chart of the preparation method of package sheet material of the invention with recessive laser effect and flocking feel.
Embodiment
Technical scheme is described further below by specific embodiment, but the embodiment is not intended to Limit the scope of the invention, on the premise of theory of the present invention is not departed from, to basement membrane, radium-shine dielectric layer or body paper material Change, be within the scope of protection of the invention.
Embodiment
It is that the present invention has recessive laser effect and the package sheet material of flocking feel as shown in Figure 1, the package sheet material is under To it is upper be back coating 1, body paper 2, glue-line 3, basement membrane 4, radium-shine dielectric layer 5, feel material layer 6 and light oil reservoir 7 successively, radium-shine medium Layer includes the acrylate resin layer 51 through molding and the zinc sulphide spacer material layer 52 by the way that formation is deposited.
The present invention's has the preparation method of recessive laser effect and the package sheet material of flocking feel as shown in Fig. 2, successively Including:(1)Basement membrane is coated with, and the PET basement membranes that the low thickness of selection thermal deformation, percent thermal shrinkage is 16um-20um are as coating base Material, coats water-based acrylic resin on a face of PET basement membranes, and the wet coating amount of water-based acrylic resin is controlled in 6.5g/ ㎡, in 1.2g/ ㎡, drying temperature stair like control strategy is adjusted using absolute ethyl alcohol and applied between 85-160 DEG C for dry-coated amount control Expect viscosity, viscosity is controlled between 16-20 "(Examine No. 2 cups of grace), machine speed control is in 100m/min;(2)Molding, using moulding press Molding processing is carried out to water-based acrylic resin layer, forms common laser hologram pattern or special edition pattern;(3)Sided corona treatment;(4) Rewinding;(5)Evaporation, is situated between on the water-based acrylic resin layer with mould pressed pattern using silica and zinc sulphide as evaporation The proportioning of matter formation spacer material layer, silica and zinc sulphide is 2:8, zinc sulphide and silica dioxide medium use phase during evaporation Between the mode put side by side, form radium-shine dielectric layer;(6)It is compound, answered after the another side coating glue of basement membrane with body paper Close, the body paper it is compound it is preceding in advance carried out the back of the body painting processing;(7)Face applies:In the zinc sulphide spacer material layer of compound rear substrate 45 ° of twills, reticulate pattern mesh number are used to coat feel material layer for the intaglio plate steel rod of 170 mesh, the cavity depth of intaglio plate steel rod is 35 μm, Width is 40-50 μm, and the control of wet coating amount is controlled 18 in 6.5g/ ㎡, wet coating viscosity "(Examine No. 2 cups of grace), drying temperature staged Control between 85-125 DEG C, machine speed control in 100m/min, feel material layer be by including mass percent be 70% it is water-based Polyaminoester emulsion, 18% ethanol, 9% water and 3% aziridine are formulated, and the latex particle of aqueous polyurethane emulsion is averaged Particle diameter is 100 μm.
The package sheet material of the present invention, during applied on cigarette-brand, medicine, cosmetics, can need to show radium-shine diffraction effect The region of fruit coats light oil reservoir in advance, and the region that shows radium-shine diffracting effect can also will be first needed in printing word, pattern Hollow out, then in hollow out position chromatography oil polish, you can show required security pattern.

Claims (10)

1. a kind of have recessive laser effect and the package sheet material of flocking feel, including body paper, glue-line, basement membrane and radium-shine medium Layer, it is characterised in that:The zinc sulphide that the radium-shine dielectric layer includes the acrylate resin layer through molding and formed by being deposited hinders Barrier material layer, covered with feel material layer on radium-shine dielectric layer, feel material layer includes the water that mass percent is 65-75% Property polyaminoester emulsion, the ethanol of 16-20%, the aziridine of the water of 8-10% and 2-4%, the latex particle of aqueous polyurethane emulsion are put down Equal particle diameter is 80-120 μm;The package sheet material can be made by scratching transparent gloss oil in feel material layer or pasting hinge Radium-shine diffracting effect shows.
2. according to claim 1 have recessive laser effect and the package sheet material of flocking feel, it is characterised in that:It is described It is 8 in mass ratio by zinc sulphide and silica that the evaporation medium of zinc sulphide spacer material layer, which is,:2 are formulated.
3. according to claim 1 or 2 have recessive laser effect and the package sheet material of flocking feel, it is characterised in that: The package sheet material has further included light oil reservoir, which is set in feel material layer.
4. according to claim 3 have recessive laser effect and the package sheet material of flocking feel, it is characterised in that:It is special Sign is:The body paper of the package sheet material is coated with back coating in the side opposite with glue-line.
5. there is the preparation method of recessive laser effect and the package sheet material of flocking feel, this method described in a kind of claim 1 In turn include the following steps:
(1)Basement membrane is coated with:An acrylate resin layer is uniformly coated in the one side of basement membrane;
(2)Molding:Molding processing carries out acrylate resin layer using moulding press, forms common laser hologram pattern or special edition figure Case;
(3)Evaporation:Zinc sulphide spacer material layer is deposited on the acrylate resin layer with mould pressed pattern;
(4)It is compound:It is for composite with body paper after the another side coating glue of basement membrane;
(5)Face applies:Used in the zinc sulphide spacer material layer of compound rear substrate 45 ° of twills, reticulate pattern mesh number for 170 mesh intaglio plate Steel rod coats feel material layer, and the cavity depth of intaglio plate steel rod is 35-45 μm, width is 40-80 μm, and feel material layer is by wrapping Mass percent is included to prepare for the aziridine of the aqueous polyurethane emulsion of 65-75%, the ethanol of 16-20%, the water of 8-10% and 2-4% Form, the latex particle average grain diameter of aqueous polyurethane emulsion is formulated for 80-120 μm.
6. the preparation method with recessive laser effect and the package sheet material of flocking feel according to claim 5, it is special Sign is:In the preparation method, step(5)The wet coating amount of feel material is 6-7g/m2, wet coating viscosity be 16-20 ", drying Temperature step formula is controlled between 85-125 DEG C, and machine speed control is in 90-110m/min.
7. the preparation method with recessive laser effect and the package sheet material of flocking feel according to claim 6, it is special Sign is:In the preparation method, step(3)The evaporation medium of zinc sulphide spacer material layer be by zinc sulphide and silica by Mass ratio is 8:2 are formulated, during evaporation zinc sulphide and silica dioxide medium using it is alternate put side by side by the way of.
8. the preparation method with recessive laser effect and the package sheet material of flocking feel according to claim 5, it is special Sign is:The preparation method further includes step(6), which is to be printed in feel material layer according to design requirement subregion Transparent light oil reservoir.
9. the preparation method with recessive laser effect and the package sheet material of flocking feel according to claim 5, it is special Sign is:The product by after mold pressing procedure is deposited again after sided corona treatment and rewinding.
10. a kind of any package sheet materials with recessive laser effect and flocking feel of claim 1-4 are in cigarette-brand, medicine Application on product, cosmetics.
CN201711213553.5A 2017-11-28 2017-11-28 Packaging sheet with recessive laser effect and flocking hand feeling, and preparation method and application thereof Active CN107905038B (en)

Priority Applications (1)

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CN201711213553.5A CN107905038B (en) 2017-11-28 2017-11-28 Packaging sheet with recessive laser effect and flocking hand feeling, and preparation method and application thereof

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CN201711213553.5A CN107905038B (en) 2017-11-28 2017-11-28 Packaging sheet with recessive laser effect and flocking hand feeling, and preparation method and application thereof

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CN107905038A true CN107905038A (en) 2018-04-13
CN107905038B CN107905038B (en) 2020-01-24

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108951294A (en) * 2018-07-27 2018-12-07 绍兴虎彩激光材料科技有限公司 A kind of antistatic gold and silver card number paper and its manufacture craft
CN109117920A (en) * 2018-09-25 2019-01-01 上海宏盾防伪材料有限公司 A kind of two dimensional code with antiforge laser holographic pattern
CN113774714A (en) * 2021-09-16 2021-12-10 深圳市美弘信息技术有限公司 Packaging sheet with flocking hand feeling, preparation method and application thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR970070337A (en) * 1996-04-09 1997-11-07 김기춘 OPP film wrapping paper
US20040241404A1 (en) * 2003-06-02 2004-12-02 Klaser Technology Inc. Paper with holographic pattern and manufacture of it
JP2012077424A (en) * 2010-10-05 2012-04-19 Saikyosha:Kk Light shielding paper with toughness
CN103320004A (en) * 2013-06-17 2013-09-25 上海良虹印务有限公司 Water-based soft-feel matt varnishing and method for preparing soft-feel membrane by using same
CN104441878A (en) * 2014-11-11 2015-03-25 福建泰兴特纸有限公司 Double-sided laser compound local transfer anti-counterfeiting film with hand feeling, and preparation method of anti-counterfeiting film
CN204509866U (en) * 2015-03-30 2015-07-29 上海紫江喷铝环保材料有限公司 A kind of holographic transfer paper with Various Complex texture

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR970070337A (en) * 1996-04-09 1997-11-07 김기춘 OPP film wrapping paper
US20040241404A1 (en) * 2003-06-02 2004-12-02 Klaser Technology Inc. Paper with holographic pattern and manufacture of it
JP2012077424A (en) * 2010-10-05 2012-04-19 Saikyosha:Kk Light shielding paper with toughness
CN103320004A (en) * 2013-06-17 2013-09-25 上海良虹印务有限公司 Water-based soft-feel matt varnishing and method for preparing soft-feel membrane by using same
CN104441878A (en) * 2014-11-11 2015-03-25 福建泰兴特纸有限公司 Double-sided laser compound local transfer anti-counterfeiting film with hand feeling, and preparation method of anti-counterfeiting film
CN204509866U (en) * 2015-03-30 2015-07-29 上海紫江喷铝环保材料有限公司 A kind of holographic transfer paper with Various Complex texture

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108951294A (en) * 2018-07-27 2018-12-07 绍兴虎彩激光材料科技有限公司 A kind of antistatic gold and silver card number paper and its manufacture craft
CN109117920A (en) * 2018-09-25 2019-01-01 上海宏盾防伪材料有限公司 A kind of two dimensional code with antiforge laser holographic pattern
CN109117920B (en) * 2018-09-25 2024-05-24 上海宏盾防伪材料有限公司 Two-dimensional code with laser holographic anti-counterfeiting pattern
CN113774714A (en) * 2021-09-16 2021-12-10 深圳市美弘信息技术有限公司 Packaging sheet with flocking hand feeling, preparation method and application thereof

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