CN107857569A - A kind of environment-friendly type ceramic tile and preparation method thereof - Google Patents
A kind of environment-friendly type ceramic tile and preparation method thereof Download PDFInfo
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- CN107857569A CN107857569A CN201711250775.4A CN201711250775A CN107857569A CN 107857569 A CN107857569 A CN 107857569A CN 201711250775 A CN201711250775 A CN 201711250775A CN 107857569 A CN107857569 A CN 107857569A
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- 239000000919 ceramic Substances 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000002699 waste material Substances 0.000 claims abstract description 8
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 7
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 7
- 239000011230 binding agent Substances 0.000 claims abstract description 7
- 239000006229 carbon black Substances 0.000 claims abstract description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 22
- 238000003756 stirring Methods 0.000 claims description 16
- 238000000227 grinding Methods 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 8
- 239000002002 slurry Substances 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 238000005336 cracking Methods 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 6
- 238000010304 firing Methods 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 238000007688 edging Methods 0.000 claims description 4
- 239000000835 fiber Substances 0.000 claims description 4
- 238000003801 milling Methods 0.000 claims description 4
- 229910017604 nitric acid Inorganic materials 0.000 claims description 4
- 239000002244 precipitate Substances 0.000 claims description 4
- 239000010453 quartz Substances 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 4
- 229910021532 Calcite Inorganic materials 0.000 claims description 3
- 239000005457 ice water Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000004816 latex Substances 0.000 claims description 2
- 229920000126 latex Polymers 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims 1
- 235000019241 carbon black Nutrition 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 5
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 5
- 229910052726 zirconium Inorganic materials 0.000 abstract description 3
- -1 zirconium silicates Chemical class 0.000 abstract description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000006004 Quartz sand Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1324—Recycled material, e.g. tile dust, stone waste, spent refractory material
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/16—Lean materials, e.g. grog, quartz
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/36—Reinforced clay-wares
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
- C04B2235/422—Carbon
- C04B2235/424—Carbon black
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/442—Carbonates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/48—Organic compounds becoming part of a ceramic after heat treatment, e.g. carbonising phenol resins
- C04B2235/483—Si-containing organic compounds, e.g. silicone resins, (poly)silanes, (poly)siloxanes or (poly)silazanes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
- C04B2235/52—Constituents or additives characterised by their shapes
- C04B2235/5208—Fibers
- C04B2235/5216—Inorganic
- C04B2235/524—Non-oxidic, e.g. borides, carbides, silicides or nitrides
- C04B2235/5248—Carbon, e.g. graphite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
- C04B2235/963—Surface properties, e.g. surface roughness
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a kind of environment-friendly type ceramic tile and preparation method thereof, it is related to architectural pottery arts.It is prepared by following raw material：40 50 parts of waste ceramics, 15 20 parts of calcites, 8 15 parts of zirconium silicates, 5 10 parts of kaolin, 35 parts of quartzs, 5 10 parts of bamboo-carbon fibres, 35 parts of carbon blacks, 10 15 parts of binding agents, 24 parts of silester, 10 15 parts of latexes.The invention provides a kind of environment-friendly type ceramic tile and preparation method thereof, and technique is simple, energy-conserving and environment-protective, and does not influence the finish of ceramic tile surface again while ceramic tile surface frictional force is increased.
Description
Technical field
The present invention relates to architectural pottery arts, more particularly to a kind of environment-friendly type ceramic tile and preparation method thereof.
Background technology
Ceramic tile, also known as ceramic tile, are metal oxide and half-metal oxide with fire resisting, via grinding, mixing, compacting,
The processes such as glazing, firing, and a kind of porcelain of acid and alkali-resistance or the building and ornament materials of stone matter formed, referred to as ceramic tile.It is former
Material is mixed by clay, quartz sand etc. more.Often surface is extremely smooth for finished product ceramic tile, when ceramic tile surface be stained with water it
Afterwards, if pedestrian's walking is then easy to fall, great potential safety hazard be present.
The content of the invention
It is an object of the invention to provide a kind of environment-friendly type ceramic tile and preparation method thereof, to solve above-mentioned technical problem.
The present invention using following technical scheme in order to solve the above technical problems, realized：
A kind of environment-friendly type ceramic tile, it is characterised in that be prepared by following raw material：40-50 parts waste ceramic,
15-20 parts calcite, 8-15 parts zirconium silicate, 5-10 parts kaolin, 3-5 parts quartz, 5-10 parts bamboo-carbon fibre, 3-5 parts carbon black,
10-15 parts binding agent, 2-4 parts silester, 10-15 part latexes.
A kind of preparation method of environment-friendly type ceramic tile, it is characterised in that comprise the following steps：
A, waste ceramic, calcite, zirconium silicate, quartz, kaolin, carbon black are put into ball mill and carries out grinding, directly
To material grinding to 500-600 mesh, gained is put into 3-4 hours are reacted in cracking still；
B, resulting material in A is put into mixed acid, and uniform stirring is carried out under ultrasonic vibration auxiliary, mixing time is
15-20 minutes, after stirring terminates, by material by centrifuge, taking precipitate, produce base material；
C, latex, bamboo-carbon fibre, silester are uniformly mixed, and uniform stirring is carried out under the conditions of ice-water bath, stirred
Time is 10-20 minutes, after stirring terminates, changes water-bath into, and it is 40-50 DEG C to set temperature, continues to stir 10-20 minutes, water
Bathe auxiliary in whipping process and, with microwave irradiation, produce modified additive；
D, base material, modified additive are uniformly mixed with binding agent, and puts into grinder and be ground, milling time
For 30-40 minutes, synthetic slurry is produced；
E, synthetic slurry is produced into environment-friendly type ceramic tile by drying, glazing, firing, edging.
Preferably, in described step A, the temperature in cracking still is 380-400 DEG C.
Preferably, in described step B, mixed acid be by mass fraction 98% the concentrated sulfuric acid and mass fraction 68% it is dense
Nitric acid by volume 1:3 are uniformly mixed.
Preferably, in described step C, it is irradiated using high-frequency microwave.
Preferably, in described step D, the rotating speed of grinder is 120-180r/min.
The manufacture craft of the present invention is simple, and effectively make use of waste ceramic as raw material, energy-conserving and environment-protective, this hair
It is bright by preparing modified formulation, so as to change the physical property of ceramic tile in itself, be allowed to increasing ceramic tile surface frictional force
The finish of ceramic tile surface is not influenceed again simultaneously.
The beneficial effects of the invention are as follows：The invention provides a kind of environment-friendly type ceramic tile and preparation method thereof, technique is simple, section
Energy is environmentally friendly, and does not influence the finish of ceramic tile surface again while ceramic tile surface frictional force is increased.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below
Specific embodiment is closed, the present invention is expanded on further, but following embodiments are only the preferred embodiments of the present invention, and it is not all.
Based on the embodiment in embodiment, those skilled in the art obtain other realities on the premise of creative work is not made
Example is applied, belongs to protection scope of the present invention.Experimental method in following embodiments, it is conventional method unless otherwise specified,
Material used, reagent etc., unless otherwise specified, are commercially obtained in following embodiments.
Embodiment 1
By 40 parts of waste ceramics, 15 parts of calcites, 8 parts of zirconium silicates, 3 parts of quartzs, 5 parts of kaolin, 3 parts of carbon blacks put into
Ball mill carries out grinding, until material grinding will react 3 hours, the temperature in cracking still to 500 mesh in gained input cracking still
For 380 DEG C；
By resulting material input by the concentrated sulfuric acid of mass fraction 98% and the concentrated nitric acid by volume 1 of mass fraction 68%:3
In the mixed acid being uniformly mixed, and uniform stirring is carried out under ultrasonic vibration auxiliary, mixing time is 15 minutes, stirring knot
Shu Hou, by material by centrifuge, taking precipitate, produce base material；
10 parts of latexes, 5 parts of bamboo-carbon fibres, 2 parts of silester are uniformly mixed, and uniformly stirred under the conditions of ice-water bath
Mix, mixing time is 10 minutes, after stirring terminates, changes water-bath into, and it is 40 DEG C to set temperature, continues stirring 10 minutes, water-bath
Auxiliary is irradiated with high-frequency microwave in whipping process, produces modified additive；
Base material, modified additive are uniformly mixed with 10 parts of binding agents, and put into grinder and be ground, grinder
Rotating speed be 120r/min, milling time is 30 minutes, produces synthetic slurry；
By synthetic slurry by drying, glazing, firing, edging, environment-friendly type ceramic tile is produced.
Embodiment 2
By 50 parts of waste ceramics, 20 parts of calcites, 15 parts of zirconium silicates, 5 parts of quartzs, 10 parts of kaolin, 5 parts of carbon black inputs
Grinding is carried out to ball mill, until material grinding will react 4 hours, the temperature in cracking still to 550 mesh in gained input cracking still
Spend for 400 DEG C；
By resulting material input by the concentrated sulfuric acid of mass fraction 98% and the concentrated nitric acid by volume 1 of mass fraction 68%:3
In the mixed acid being uniformly mixed, and uniform stirring is carried out under ultrasonic vibration auxiliary, mixing time is 20 minutes, stirring knot
Shu Hou, by material by centrifuge, taking precipitate, produce base material；
Base material is uniformly mixed with 15 parts of binding agents, and puts into grinder and is ground, the rotating speed of grinder is
180r/min, milling time are 40 minutes, produce synthetic slurry；
By synthetic slurry by drying, glazing, firing, edging, environment-friendly type ceramic tile is produced.
Embodiment 3
Take market sale routine ceramic tile.
Take and physical property detection carried out as the ceramic tile prepared by embodiment 1-3, and take ceramic tile to be placed in 24h in closed container,
Benzene concentration is measured, as a result such as following table：
As can be seen from the above table, ceramic tile provided by the invention does not influence porcelain again while ceramic tile surface frictional force is increased
The finish on brick surface, and concentration of narmful substance is relatively low.
General principle, principal character and the advantages of the present invention of the present invention has been shown and described above.The technology of the industry
For personnel it should be appreciated that the present invention is not limited to the above embodiments, that described in above-described embodiment and specification is only the present invention
Preference, be not intended to limit the present invention, without departing from the spirit and scope of the present invention, the present invention also have it is various
Changes and improvements, these changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention is by institute
Attached claims and its equivalent thereof.
Claims (6)
1. a kind of environment-friendly type ceramic tile, it is characterised in that be prepared by following raw material：40-50 parts waste ceramic, 15-
20 parts of calcites, 8-15 parts zirconium silicate, 5-10 parts kaolin, 3-5 parts quartz, 5-10 parts bamboo-carbon fibre, 3-5 parts carbon black, 10-
15 parts of binding agents, 2-4 parts silester, 10-15 part latexes.
2. a kind of preparation method of environment-friendly type ceramic tile, it is characterised in that comprise the following steps：
A, waste ceramic, calcite, zirconium silicate, quartz, kaolin, carbon black are put into ball mill and carries out grinding, until thing
Feed powder is milled to 500-600 mesh, gained is put into 3-4 hours are reacted in cracking still；
B, resulting material in A is put into mixed acid, and uniform stirring, mixing time 15- is carried out under ultrasonic vibration auxiliary
20 minutes, after stirring terminates, by material by centrifuge, taking precipitate, produce base material；
C, latex, bamboo-carbon fibre, silester are uniformly mixed, and uniform stirring, mixing time is carried out under the conditions of ice-water bath
For 10-20 minutes, after stirring terminates, water-bath is changed into, and it is 40-50 DEG C to set temperature, continues to stir 10-20 minutes, water-bath is stirred
Auxiliary produces modified additive with microwave irradiation during mixing；
D, base material, modified additive are uniformly mixed with binding agent, and puts into grinder and be ground, milling time is
30-40 minutes, produce synthetic slurry；
E, synthetic slurry is produced into environment-friendly type ceramic tile by drying, glazing, firing, edging.
3. the preparation method of a kind of environment-friendly type ceramic tile according to claim 2, it is characterised in that in described step A, split
It is 380-400 DEG C to solve the temperature in kettle.
4. the preparation method of a kind of environment-friendly type ceramic tile according to claim 2, it is characterised in that in described step B, mix
Close the concentrated nitric acid by volume 1 that acid is the concentrated sulfuric acid by mass fraction 98% and mass fraction 68%:3 are uniformly mixed.
5. the preparation method of a kind of environment-friendly type ceramic tile according to claim 2, it is characterised in that in described step C, adopt
It is irradiated with high-frequency microwave.
6. the preparation method of a kind of environment-friendly type ceramic tile according to claim 2, it is characterised in that in described step D, grind
The rotating speed of grinding machine is 120-180r/mi n.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711250775.4A CN107857569A (en) | 2017-12-01 | 2017-12-01 | A kind of environment-friendly type ceramic tile and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711250775.4A CN107857569A (en) | 2017-12-01 | 2017-12-01 | A kind of environment-friendly type ceramic tile and preparation method thereof |
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| CN107857569A true CN107857569A (en) | 2018-03-30 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108863403A (en) * | 2018-07-19 | 2018-11-23 | 合肥广民建材有限公司 | A kind of Environment-friendlywear-resistant wear-resistant type ceramic tile and preparation method thereof |
-
2017
- 2017-12-01 CN CN201711250775.4A patent/CN107857569A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108863403A (en) * | 2018-07-19 | 2018-11-23 | 合肥广民建材有限公司 | A kind of Environment-friendlywear-resistant wear-resistant type ceramic tile and preparation method thereof |
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