CN107817131A - A kind of deep sea water and dissolved gas harvester and method - Google Patents
A kind of deep sea water and dissolved gas harvester and method Download PDFInfo
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- 238000003860 storage Methods 0.000 claims abstract description 78
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- 238000007872 degassing Methods 0.000 claims abstract description 5
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- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
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Abstract
本发明公开了一种深海海水及溶解气体采集装置及方法,通过在取样瓶上设置气/水采集通道、真空阀和溢流孔,在取样瓶与高压密封舱连通的高压密封舱体的一端设置气/水采集入口和电磁阀,预先对样品储藏仓进行负压处理,实现采集样品,通过气/水采集入口以及打开的电磁阀再通过气/水采集通道快速进入取样瓶,采集完毕。在将采集装置上提取出的过程中,通过平衡活塞的自动移动改变样品储藏仓的容积进而改变其内压力来维持样品储藏仓内外压力的平衡,保证采集装置的安全卸压和取回。采集装置收回后,先通过真空阀将采集装置与脱气装置连,接收集水溶气体,之后再通过真空阀收集水体样品,实现采样完全。
The invention discloses a deep-sea seawater and dissolved gas collection device and method. By setting a gas/water collection channel, a vacuum valve and an overflow hole on the sampling bottle, one end of the high-pressure sealing cabin connected between the sampling bottle and the high-pressure sealing cabin Set up the air/water collection inlet and solenoid valve, and carry out negative pressure treatment on the sample storage bin in advance to realize sample collection, and then quickly enter the sampling bottle through the air/water collection inlet and the opened solenoid valve through the air/water collection channel, and the collection is completed. In the process of extracting the collection device, the volume of the sample storage chamber is changed by the automatic movement of the balance piston, and then the internal pressure is changed to maintain the balance of the pressure inside and outside the sample storage chamber, so as to ensure the safe pressure relief and retrieval of the collection device. After the collection device is retracted, the collection device is first connected to the degassing device through the vacuum valve to receive the water-soluble gas, and then the water body sample is collected through the vacuum valve to achieve complete sampling.
Description
技术领域technical field
本发明属于海洋探测设备技术领域,具体涉及一种深海海水及溶解气体采集装置及方法。The invention belongs to the technical field of marine detection equipment, and in particular relates to a deep-sea seawater and dissolved gas collection device and method.
背景技术Background technique
深海海水采集装置主要包括自锁式翻盖采水瓶和负压抽提式原位气密采水瓶两种主要类型,以及在这两种类型基础之上变化出来的一些类型。其中,自锁式翻盖采水瓶主体结构包括采水筒、球盖、释放器、固定架和钢丝绳槽及控制系统等几个部分,采水瓶根据压力自适应平衡原理,当采水器下放时,两个球盖保持敞开,当到达预定采水深度后,通过压力开关元件、电缆等方式控制采水器开关,使采水筒两端的两个球盖关闭,于是存在于圆筒中的海水便被保存下来。该类采水瓶每次可安装多个采水瓶组成一个多次海水采集系统,此类采水瓶的特点是装置整体体积比较大,采水量较多,一般2-8升,操作比较简单,但由于此类采水瓶采用的是弹力绳密封结构,所以采水瓶较难保存海水中存留的水溶气体,同时采水器采水还需要借助CTD采集系统、甲板供电、甲板控制系统、传输系统等辅助实现。Deep-sea seawater collection devices mainly include two main types: self-locking flip-cap water collection bottles and negative pressure extraction in-situ airtight water collection bottles, as well as some types based on these two types. Among them, the main structure of the self-locking flip-top water collection bottle includes several parts such as a water collection cylinder, a ball cover, a release device, a fixing frame, a wire rope groove, and a control system. The first spherical cover is kept open, and when the predetermined water collection depth is reached, the switch of the water collection device is controlled by means of pressure switch elements, cables, etc., so that the two spherical covers at both ends of the water collection cylinder are closed, and the seawater in the cylinder is preserved. . This type of water collection bottle can be installed with multiple water collection bottles each time to form a multiple seawater collection system. The characteristics of this type of water collection bottle are that the overall volume of the device is relatively large, and the water collection volume is large, generally 2-8 liters. The operation is relatively simple, but due to This type of water collection bottle adopts an elastic rope sealing structure, so it is difficult for the water collection bottle to preserve the water-soluble gas remaining in the seawater. At the same time, the water collection device needs to rely on CTD collection system, deck power supply, deck control system, transmission system, etc. .
另一种采水瓶是负压抽提式原位气密采水瓶,此类采水瓶主体结构包括抽提活塞、缓冲活塞、工作腔、排气口、外压口、储水室、进水口、出水口等几个部分,采水瓶主体材料为不锈钢,根据负压抽提原理,工作腔预先装满水,抽提活塞保持平衡密封,当采水器下放到达预定采水深度时,采水系统中负压仓开放,工作腔中预装的水流向负压仓,同时平衡活塞向工作腔方向移动,样品储藏仓同时出现负压,此时外界的海水根据负压抽提原理随着活塞的移动,进入到样品储藏仓中,当工作腔中预装的水流完,平衡活塞完全移动至工作腔,样品储藏仓中已经装满海水,样品储藏仓中的海水便被得以保存。此类采水瓶的特点是操作比较复杂,系统工作不够稳定,采水量少。每次采水前需预先通过压力泵将工作腔充满水,采水瓶工作还需要高压舱、电源、水下计算机、控制系统、预设软件、负压桶、平衡仓、连接结构等多个组件组成采集系统才能实现采水,采水量为200ml。Another kind of water collection bottle is a negative pressure extraction type in-situ airtight water collection bottle. The main structure of this type of water collection bottle includes an extraction piston, a buffer piston, a working chamber, an exhaust port, an external pressure port, a water storage chamber, a water inlet, The water outlet and other parts, the main material of the water collection bottle is stainless steel. According to the principle of negative pressure extraction, the working chamber is pre-filled with water, and the extraction piston is kept balanced and sealed. When the water collection device is lowered to the predetermined water collection depth, the water collection system The medium negative pressure chamber is opened, the pre-installed water in the working chamber flows to the negative pressure chamber, and at the same time, the balance piston moves towards the working chamber, and the sample storage chamber has negative pressure at the same time. When the preloaded water in the working chamber runs out, the balance piston moves completely to the working chamber, the sample storage chamber is filled with seawater, and the seawater in the sample storage chamber is preserved. The characteristics of this type of water collection bottle are that the operation is more complicated, the system work is not stable enough, and the water collection volume is small. The working cavity needs to be filled with water through the pressure pump before each water collection. The work of the water collection bottle also requires multiple components such as a hyperbaric chamber, power supply, underwater computer, control system, preset software, negative pressure tank, balance chamber, and connection structure. Water collection can only be realized by forming a collection system, and the water collection volume is 200ml.
现有的自锁式翻盖采水瓶体积较大,适用于多个层位的分层海水的采集,通常要借助探测海水温度、盐度、深度等信息的温盐深仪(CTD)的控制系统及吊架架,可同时安装多个采水瓶,但此类采水瓶采用的是弹力绳密封结构,较难完全保存海水中存留的水溶气体,该采水瓶主要应用于不关注水中气体组分含量的、水样需求比较大的海洋区域地质调查、海洋环境调查中。对于特别专注于水中气体含量且不需要特别多的水的资源调查或科学考察等项目,不适合使用该采水瓶。The existing self-locking flip-top water collection bottle is relatively large in size, and is suitable for collecting stratified seawater in multiple layers. Usually, it is necessary to rely on the control system of the temperature, salinity and depth instrument (CTD) to detect information such as seawater temperature, salinity, and depth. And hanger frame, can install multiple water sampling bottles at the same time, but this type of water sampling bottle adopts elastic rope sealing structure, it is difficult to completely preserve the water-soluble gas remaining in seawater, this water sampling bottle is mainly used for not paying attention to the content of gas components in water Geological surveys and marine environmental surveys in marine areas where there is a relatively large demand for water samples. For projects such as resource surveys or scientific investigations that focus on the gas content in water and do not require a lot of water, it is not suitable to use this water collection bottle.
负压抽提式原位气密采水瓶结构相对复杂一些,采水瓶还需要高压舱、电源、水下计算机、控制系统、预设软件、负压桶、平衡仓、连接结构等多个组件组成采集系统才能实现海水的气密采集,由于采水瓶是依据负压抽提的工作原理,所以每次采水前需预先通过真空泵将负压桶抽成真空来制造负压,并用高压水泵将工作腔充满水以便预留活塞的移动空间,现场操作程序比较繁琐,通常需要专业人员操作。The structure of the negative pressure extraction type in-situ airtight water collection bottle is relatively complicated. The water collection bottle also needs multiple components such as a hyperbaric chamber, power supply, underwater computer, control system, preset software, negative pressure barrel, balance chamber, and connection structure. The collection system can realize the airtight collection of seawater. Since the water collection bottle is based on the working principle of negative pressure extraction, it is necessary to evacuate the negative pressure barrel into a vacuum through the vacuum pump to create a negative pressure before each water collection, and use a high-pressure water pump. The cavity is filled with water to reserve the space for the piston to move, and the on-site operation procedures are cumbersome and usually require professional personnel to operate.
综上,现有类型采水瓶存在以下缺点:1)操作步骤繁琐,不适合船载现场使用;2)体积过大,不利用携带和使用;3)较难保存海水中存留的水溶气体;4)需要专业人员操作。To sum up, the existing types of water collection bottles have the following disadvantages: 1) The operation steps are cumbersome and are not suitable for on-site use on board; 2) The volume is too large to be carried and used; 3) It is difficult to preserve the water-soluble gas remaining in seawater; 4 ) requires professionals to operate.
发明内容Contents of the invention
本发明的目的在于提供一种深海海水及溶解气体采集装置及方法,能够实现对采集区的水溶气体以及水体进行安全快速的采集和气密保存,而且采集设备体积小、操作便利。The purpose of the present invention is to provide a deep-sea seawater and dissolved gas collection device and method, which can realize safe and fast collection and airtight storage of water-soluble gas and water in the collection area, and the collection equipment is small in size and easy to operate.
为了达到上述目的,本发明的具体技术方案如下:In order to achieve the above object, the concrete technical scheme of the present invention is as follows:
一种深海海水及溶解气体采集装置,包括:高压密封舱和取样瓶;所述取样瓶包括封闭外壳和内部的样品储藏仓,所述样品储藏仓的末端设有平衡活塞,在所述平衡活塞所在空腔的侧壁上设有与其连通的溢流孔,所述样品储藏仓的侧壁上设有与外界连通的真空阀;A deep-sea seawater and dissolved gas collection device, comprising: a high-pressure sealed cabin and a sampling bottle; the sampling bottle includes a closed shell and an internal sample storage bin, the end of the sample storage bin is provided with a balance piston, and the balance piston The side wall of the cavity is provided with an overflow hole communicating with it, and the side wall of the sample storage bin is provided with a vacuum valve communicating with the outside world;
所述高压密封舱包括高压密封舱体及内部的变压器、电路板和电磁阀,所述变压器设在所述高压密封舱体的末端,其一侧设有电路板固定架,所述电路板设在所述电路板固定架上,所述高压密封舱体的另一端设有所述电磁阀,在所述电磁阀与所述电路板固定架之间设有对所述电磁阀进行限位的限位环,所述高压密封舱体的末端设有水密接插件;The high-pressure sealed cabin includes a high-voltage sealed cabin body and an internal transformer, a circuit board and a solenoid valve. The transformer is arranged at the end of the high-pressure sealed cabin body, and one side thereof is provided with a circuit board fixing frame, and the circuit board is provided with On the circuit board fixing frame, the other end of the high-pressure sealed cabin is provided with the electromagnetic valve, and a position limiting mechanism for the electromagnetic valve is provided between the electromagnetic valve and the circuit board fixing frame. A limit ring, the end of the high-pressure sealed cabin is provided with a watertight connector;
所述样品储藏仓的入口端设有与其内腔连通的气/水采集通道,所述气/ 水采集通通道内设有单向阀;所述电磁阀与所述气/水采集通道连通、进而和所述样品储藏仓连通;The inlet end of the sample storage bin is provided with an air/water collection channel communicated with its inner cavity, and a one-way valve is arranged in the air/water collection channel; the solenoid valve communicates with the air/water collection channel, And then communicate with the sample storage bin;
所述高压密封舱体与所述取样瓶连接的一端设有螺纹连接件,所述取样瓶的封闭外壳通过所述螺纹连接件与所述高压密封舱体连接;所述取样瓶的封闭外壳上设有气/水采集入口,所述气/水采集入口的一端与外部连通,其另一端与所述电磁阀连通;One end of the high-pressure sealed cabin body connected to the sampling bottle is provided with a threaded connector, and the closed shell of the sampling bottle is connected with the high-pressure sealed cabin body through the threaded connector; An air/water collection inlet is provided, one end of the air/water collection inlet communicates with the outside, and the other end communicates with the solenoid valve;
所述取样瓶和所述高压密封舱体的末端均封闭设置。Both ends of the sampling bottle and the high-pressure sealed cabin are sealed.
进一步地,所述真空阀包括两个,分别设在所述样品储藏仓的侧壁的两侧。Further, the vacuum valve includes two, which are respectively arranged on both sides of the side wall of the sample storage bin.
进一步地,所述样品储藏仓与活塞之间采用聚四氟乙烯包覆的O形圈密封。Further, an O-ring coated with polytetrafluoroethylene is used for sealing between the sample storage chamber and the piston.
进一步地,所述平衡活塞包括弹簧压簧和活塞体,所述弹簧压簧位于所述活塞体和所述封闭外壳的末端之间。Further, the balance piston includes a compression spring and a piston body, and the compression spring is located between the piston body and the end of the closed casing.
本发明还提供了利用所述的深海海水及溶解气体采集装置进行采集的方法,包括以下步骤:The present invention also provides the method that utilizes described deep-sea seawater and dissolved gas collection device to collect, comprising the following steps:
a.通过高压水密电缆将所述采集装置的电路系统与船载电源接通;a. connect the circuit system of the acquisition device with the on-board power supply through a high-voltage watertight cable;
b.通过所述真空阀将所所述采集装置与船载真空泵连接,将所述样品储藏仓抽至真空;b. Connect the collection device to the on-board vacuum pump through the vacuum valve, and evacuate the sample storage bin to a vacuum;
c.利用船载搭载设施将所述采集装置下放至采集区的指定层位深度;c. Lowering the collection device to the specified layer depth in the collection area by using the ship-borne carrying facilities;
d.通过甲板电路控制打开所述电磁阀,所述取样瓶外面的海水通过所述电磁阀从所述气/水采集入口进入所述样品储藏仓中,采集预设时间后,关闭所述电磁阀,采集样品保存在样品储藏仓中,采集完毕;d. Open the electromagnetic valve through the control of the deck circuit, the seawater outside the sampling bottle enters the sample storage bin from the air/water collection inlet through the electromagnetic valve, and close the electromagnetic valve after collecting the preset time. valve, the collected sample is stored in the sample storage bin, and the collection is completed;
e.将所述采集装置从采集区上提,所述平衡活塞因压力差和压簧弹性而自动移动,改变所述样品储藏仓的容积维持所述样品储藏仓内外压力的平衡;e. Lifting the collection device from the collection area, the balance piston automatically moves due to the pressure difference and the elasticity of the compression spring, changing the volume of the sample storage bin to maintain the balance of pressure inside and outside the sample storage bin;
f.装置上提至至船舱甲板后,通过所述真空阀连接脱气装置,分别将所述样品储藏仓内的样品进行采集,依次获得水溶气体样品和水体样品。f. After the device is lifted to the deck of the cabin, the degassing device is connected through the vacuum valve, and the samples in the sample storage bin are respectively collected to obtain water-soluble gas samples and water body samples in sequence.
进一步地,步骤d中,所述采集预设时间为2-3分钟。Further, in step d, the preset collection time is 2-3 minutes.
本发明提供的一种深海海水及溶解气体采集装置及方法,通过在取样瓶上设置气/水采集通道、真空阀和溢流孔,在取样瓶与高压密封舱连通的高压密封舱体的一端设置气/水采集入口和电磁阀。通过真空阀对样品储藏仓预先进行负压处理,采样时根据能量最低原理,实现采集样品;通过气/水采集入口以及打开的电磁阀、再通过气/水采集通道快速进入取样瓶,并通过气/水采集通道内的单向阀控制样品保存在样品储藏仓内不会倒流。采集完毕,在将采集装置上提取出的过程中,平衡活塞一侧通过溢流孔与外界海水相通,依据压力自适应平衡原理,平衡活塞因压力差和压簧弹性的双重作用而自动移动,进而通过改变所述样品储藏仓的容积改变所述样品储藏仓内压力来维持样品储藏仓内外压力的平衡,该过程能够保证采集装置的安全卸压和取回。采集装置收回后,先通过真空阀将采集装置与脱气装置连接,收集水溶气体,之后再通过真空阀收集水体样品,实现采样完全。A device and method for collecting deep-sea seawater and dissolved gas provided by the present invention, by setting a gas/water collection channel, a vacuum valve and an overflow hole on the sampling bottle, at one end of the high-pressure sealed cabin connected between the sampling bottle and the high-pressure sealed cabin Set the air/water collection inlet and solenoid valve. Negative pressure treatment is performed on the sample storage bin in advance through the vacuum valve, and the sample is collected according to the principle of the lowest energy during sampling; the sample is quickly entered into the sampling bottle through the gas/water collection inlet and the opened solenoid valve, and then through the gas/water collection channel, and passed through The one-way valve in the air/water collection channel controls the sample to be stored in the sample storage bin without backflow. After the collection is completed, in the process of extracting the collection device, one side of the balance piston communicates with the external seawater through the overflow hole. According to the principle of pressure self-adaptive balance, the balance piston moves automatically due to the dual effects of pressure difference and compression spring elasticity. Furthermore, the pressure inside and outside the sample storage bin is maintained by changing the volume of the sample storage bin to change the internal pressure of the sample storage bin. This process can ensure safe pressure relief and retrieval of the collection device. After the collection device is retracted, the collection device is first connected to the degassing device through the vacuum valve to collect water-soluble gas, and then the water body sample is collected through the vacuum valve to achieve complete sampling.
附图说明Description of drawings
图1本发明提供的一种深海海水及溶解气体采集装置的结构示意图;Fig. 1 is a schematic structural view of a deep-sea seawater and dissolved gas collection device provided by the present invention;
1.高压密封舱,11.高压密封舱体,12.变压器,13.电磁阀,131.电磁阀阀芯,14.电路板固定架,15.限位环,16.水密接插件,17.螺纹连接件;1. High-pressure sealed cabin, 11. High-pressure sealed cabin, 12. Transformer, 13. Solenoid valve, 131. Solenoid valve spool, 14. Circuit board fixing frame, 15. Limit ring, 16. Watertight connector, 17. threaded connectors;
2.取样瓶,21.封闭外壳,22.样品储藏仓,23.平衡活塞,231.压簧,24. 溢流孔,25.真空阀,26.气/水采集入口,27.单向阀。2. Sampling bottle, 21. Closed shell, 22. Sample storage bin, 23. Balance piston, 231. Compression spring, 24. Overflow hole, 25. Vacuum valve, 26. Air/water collection inlet, 27. One-way valve .
具体实施方式Detailed ways
下面结合附图对本发明的实施方式进行说明。Embodiments of the present invention will be described below in conjunction with the accompanying drawings.
一种深海海水及溶解气体采集装置,如图1所示,包括:高压密封舱1和取样瓶2;取样瓶2包括封闭外壳21和内部的样品储藏仓22,样品储藏仓 22的末端设有平衡活塞23,在平衡活塞23所在的空腔侧壁上设有与其连通的溢流孔24,样品储藏仓22的侧壁上设有与外界连通的真空阀25;A kind of deep-sea seawater and dissolved gas acquisition device, as shown in Figure 1, comprises: high-pressure sealed cabin 1 and sampling bottle 2; The balance piston 23 is provided with an overflow hole 24 communicating with it on the side wall of the cavity where the balance piston 23 is located, and a vacuum valve 25 communicating with the outside is provided on the side wall of the sample storage bin 22;
高压密封舱1包括高压密封舱体11及内部的变压器12、电路板和电磁阀,变压器12设在高压密封舱体11的末端,其一侧设有电路板固定架14,电路板设在电路板固定架14上,高压密封舱体11的另一端设有电磁阀,在电磁阀与电路板固定架14之间设有对电磁阀进行限位的限位环15,高压密封舱体11的末端设有水密接插件16;High-pressure airtight cabin 1 comprises high-pressure airtight cabin body 11 and internal transformer 12, circuit board and electromagnetic valve, and transformer 12 is located at the end of high-pressure airtight cabin body 11, and one side thereof is provided with circuit board holder 14, and circuit board is located at circuit board. On the board fixing frame 14, the other end of the high-pressure sealing cabin body 11 is provided with a solenoid valve, and between the solenoid valve and the circuit board fixing bracket 14 is provided with a limit ring 15 for limiting the solenoid valve, and the high-pressure sealing cabin body 11 The end is provided with a watertight connector 16;
样品储藏仓22的入口端设有与其内腔连通的气/水采集通道,气/水采集通道内设有单向阀27;电磁阀13与气/水采集通道连通,电磁阀阀芯131进入气/水采集通道,进而和样品储藏仓22连通;The inlet end of the sample storage bin 22 is provided with an air/water collection channel communicating with its inner cavity, and a one-way valve 27 is arranged in the air/water collection channel; the solenoid valve 13 is connected with the air/water collection channel, and the solenoid valve spool 131 enters the The gas/water collection channel communicates with the sample storage bin 22;
高压密封舱体11与取样瓶连接的一端设有螺纹连接件17,取样瓶的封闭外壳21通过螺纹连接件17与高压密封舱体11连接;取样瓶2的封闭外壳 21上设有气/水采集入口26,气/水采集入口26的一端与外部连通,其另一端与电磁阀13连通;One end that the high-pressure sealed cabin body 11 is connected with the sampling bottle is provided with a threaded connector 17, and the closed shell 21 of the sampling bottle is connected with the high-pressure sealed cabin body 11 through the threaded connector 17; the closed shell 21 of the sampling bottle 2 is provided with an air/water Collection inlet 26, one end of the gas/water collection inlet 26 communicates with the outside, and the other end communicates with the solenoid valve 13;
取样瓶2和高压密封舱体11的末端均封闭设置。The ends of the sampling bottle 2 and the high-pressure sealed cabin body 11 are all sealed.
真空阀25包括两个,分别设在样品储藏仓22的侧壁的两侧。本方案中样品储藏仓22与活塞之间优选采用聚四氟乙烯包覆的O形圈密封。Two vacuum valves 25 are provided on both sides of the side wall of the sample storage chamber 22 respectively. In this solution, an O-ring coated with polytetrafluoroethylene is preferably used for sealing between the sample storage bin 22 and the piston.
平衡活塞23包括弹簧压簧231和活塞体,弹簧压簧231位于活塞体和封闭外壳21的末端之间。The balance piston 23 includes a spring compression spring 231 and a piston body, the spring compression spring 231 is located between the piston body and the end of the closed casing 21 .
其中,高压密封舱:用于存放电路板、电磁阀13、变压器12、电路板固定架14、水密接插件16等电子元件,可保证其内的电子元件在高压水下保持密封。Among them, the high-pressure airtight compartment: used to store electronic components such as circuit boards, solenoid valves 13, transformers 12, circuit board fixing frames 14, watertight connectors 16, etc., can ensure that the electronic components inside remain sealed under high-pressure water.
电路板固定架14:设置于高压密封舱体11内部的中央,用于固定电路板,保证电路板在高压密封舱体11内位置固定。Circuit board fixing frame 14: arranged in the center of the high-pressure sealed cabin 11, used to fix the circuit board to ensure that the position of the circuit board in the high-pressure sealed cabin 11 is fixed.
变压器12:存放于高压密封舱体11内部,用于将船载220v电压转换为适合取样瓶2工作的24v电压。Transformer 12: Stored inside the high-voltage sealed cabin 11, it is used to convert the 220v voltage onboard to the 24v voltage suitable for the sampling bottle 2 to work.
限位环15:位于高压密封舱体11内靠近取样瓶2的一端,主要用于固定高压电磁阀13的位置,限制高压电磁阀13在高压密封舱体11内随意移动。Limiting ring 15: located at the end of the high-pressure sealed cabin 11 close to the sampling bottle 2, mainly used to fix the position of the high-pressure solenoid valve 13 and limit the free movement of the high-pressure solenoid valve 13 in the high-pressure sealed cabin 11.
电磁阀13:是控制外界海水流入样品储藏仓22的开关,通过电路板以及船载电源、控制系统控制其开闭。平常处于关闭状态,一旦打开,外界海水通过气/水采集入口26立刻进入相对负压的样品储藏仓22。Solenoid valve 13: it is a switch to control the flow of external seawater into the sample storage bin 22, and its opening and closing is controlled by the circuit board, the on-board power supply and the control system. Normally it is in the closed state, once it is opened, the external seawater enters the relatively negative pressure sample storage chamber 22 through the air/water collection inlet 26 immediately.
气/水采集通道:位于样品储藏仓22靠近高压密封舱1的一端,气/水采集通道内设有单向阀27,与高压密封舱体11端部的电磁阀13连通。未采水前,电磁阀13关闭,气/水采集通道及样品储藏仓22都处于真空状态,外界的海水无法进入管道通过单向阀27流入样品储藏仓22;需要采水时,电磁阀13打开,气/水采集通道与单向阀27及样品储藏仓22即处于连通状态,根据能量最低原理,外界的水立刻通过该通道进入样品储藏仓22。Air/water collection channel: located at the end of the sample storage bin 22 close to the high-pressure sealed cabin 1, a check valve 27 is provided in the gas/water collection channel, which communicates with the solenoid valve 13 at the end of the high-pressure sealed cabin 11. Before the water is collected, the electromagnetic valve 13 is closed, the air/water collection channel and the sample storage bin 22 are in a vacuum state, and the seawater from the outside cannot enter the pipeline and flow into the sample storage bin 22 through the one-way valve 27; when it is necessary to collect water, the electromagnetic valve 13 Open, the air/water collection channel is in communication with the one-way valve 27 and the sample storage bin 22. According to the principle of the lowest energy, the water from the outside immediately enters the sample storage bin 22 through the channel.
单向阀27:单向阀27的设置在于保证气/水样品的流向,可以确保采集到的气/水样品不会倒流。One-way valve 27: the setting of the one-way valve 27 is to ensure the flow direction of the gas/water sample, so as to ensure that the collected gas/water sample will not flow back.
平衡活塞23:由弹簧压簧231和活塞体组成。用于调节样品储藏仓22 内外压力平衡,平衡活塞23通过溢流孔24与外界相连通,压力时刻与外界相同,取样瓶2下水之前,由于样品储藏仓22抽成了真空,活塞向样品储藏仓22方向移动到极致,但受限位点的限制,活塞最大只能移动到限位位置。取样瓶2回收过程中,样品储藏仓22处于较高压状态,随着活塞一侧外界水压的不断减小,根据压力自适应平衡原理,平衡活塞23缓慢向远离气/水采集入口26方向移动,样品储藏仓22内的容积不断增加,压力逐渐降低,加之另一侧弹簧压簧231的作用,样品储藏仓22内外压力得以保持平衡。Balance piston 23: is made up of spring compression spring 231 and piston body. It is used to adjust the internal and external pressure balance of the sample storage bin 22. The balance piston 23 communicates with the outside world through the overflow hole 24, and the pressure moment is the same as that of the outside world. The direction of the warehouse 22 moves to the extreme, but limited by the limit point, the piston can only move to the limit position at most. During the recovery process of the sampling bottle 2, the sample storage bin 22 is in a relatively high pressure state. With the continuous decrease of the external water pressure on one side of the piston, according to the pressure self-adaptive balance principle, the balance piston 23 slowly moves away from the gas/water collection inlet 26 , the volume inside the sample storage bin 22 is continuously increasing, and the pressure is gradually decreasing. In addition to the action of the spring compression spring 231 on the other side, the internal and external pressure of the sample storage bin 22 can be kept in balance.
溢流孔24:活塞与外界保持连通的窗口,溢流孔24使得活塞一侧的压力时刻与外界保持相同。Overflow hole 24: a window for the piston to communicate with the outside world. The overflow hole 24 keeps the pressure on one side of the piston the same as the outside world at all times.
水密接插件16:是高压密封舱体11内的变压器12、电路板与高压水密电缆相连接的纽带,是取样瓶2与船载电源连接的桥梁。Watertight connector 16: it is the bond that the transformer 12 in the high-voltage sealed cabin body 11, the circuit board are connected with the high-voltage watertight cable, and is the bridge that the sampling bottle 2 is connected with the on-board power supply.
本发明还提供了利用所述的深海海水及溶解气体采集装置进行采集的方法:The present invention also provides the method that utilizes described deep-sea seawater and dissolved gas collection device to collect:
a.通过高压水密电缆将采集装置的电路系统与船载电源接通。a. Connect the circuit system of the acquisition device with the on-board power supply through a high-voltage watertight cable.
b.通过真空阀25将所采集装置与船载真空泵连接,将样品储藏仓22抽至真空。b. Connect the collection device to the on-board vacuum pump through the vacuum valve 25, and pump the sample storage bin 22 to a vacuum.
c.利用船载钢缆、绞车或其他搭载设施将采集装置下放至采集区的指定层位深度。c. Use ship-borne steel cables, winches or other carrying facilities to lower the collection device to the specified layer depth in the collection area.
d.通过甲板电路控制打开电磁阀13,取样瓶2外面的海水通过电磁阀13 从气/水采集入口26进入样品储藏仓22中,采集预设时间后,关闭电磁阀 13,采集样品保存在样品储藏仓22中,采集完毕;通常预设采集时间为2-3 分钟。d. Open the electromagnetic valve 13 through the control of the deck circuit, and the seawater outside the sampling bottle 2 enters the sample storage bin 22 from the air/water collection inlet 26 through the electromagnetic valve 13. After collecting the preset time, close the electromagnetic valve 13, and the collected samples are stored in the In the sample storage bin 22, the collection is completed; usually the preset collection time is 2-3 minutes.
e.将采集装置从采集区上提,平衡活塞23因压力差和弹簧压簧231弹性而自动移动,改变样品储藏仓22的容积维持样品储藏仓22内外压力的平衡。e. Lift the collection device from the collection area, the balance piston 23 will automatically move due to the pressure difference and the elasticity of the spring compression spring 231, and change the volume of the sample storage bin 22 to maintain the balance of the internal and external pressure of the sample storage bin 22.
f.装置上提至至船舱甲板后,通过真空阀25连接脱气装置,分别将样品储藏仓22内的样品进行采集,依次获得水溶气体样品和水体样品。f. After the device is lifted to the deck of the cabin, the degassing device is connected through the vacuum valve 25, and the samples in the sample storage bin 22 are respectively collected to obtain water-soluble gas samples and water body samples in sequence.
在取样瓶2下水之前,通过真空阀25与真空泵相连接,预先将样品储藏仓22抽成真空,人为地制造出负压,并直接将样品储藏仓22作为负压仓。Before the sampling bottle 2 is launched into the water, the vacuum valve 25 is connected to the vacuum pump, and the sample storage bin 22 is evacuated in advance to artificially create a negative pressure, and the sample storage bin 22 is directly used as a negative pressure bin.
样品储藏仓22一端密封,另一端连接一个可自由移动的活塞,该活塞另一侧安装一合适的弹簧压簧231,并通过溢流孔24与外界海水相通,活塞的移动可以间接扩大样品储藏仓22的空间,进而实现压力的安全释放。在取样瓶2回收的过程中,伴随着取样瓶2的缓慢升高,取样瓶2外界的水压也随之逐渐降低,根据压力自适应平衡原理,样品储藏仓22内的高压海水样品会推动活塞轻微移动,活塞的移动扩大了样品储藏仓22的容积,仓内压力则随之减小。取样瓶2逐渐升高、活塞逐渐移动、样品储藏仓22内压力逐渐降低,至海面时样品仓内压力已完全释放。如此可实现安全释放样品储藏仓22内高压。One end of the sample storage bin 22 is sealed, and the other end is connected to a freely movable piston. A suitable spring compression spring 231 is installed on the other side of the piston, and communicates with the external seawater through the overflow hole 24. The movement of the piston can indirectly expand the sample storage. The space of the warehouse 22, thereby realizing the safe release of pressure. During the recovery process of the sampling bottle 2, with the slow rise of the sampling bottle 2, the water pressure outside the sampling bottle 2 gradually decreases. The piston moves slightly, and the movement of the piston expands the volume of the sample storage chamber 22, and the pressure in the chamber decreases accordingly. The sampling bottle 2 rises gradually, the piston moves gradually, the pressure in the sample storage bin 22 gradually decreases, and the pressure in the sample bin 22 is completely released when it reaches the sea surface. In this way, the high pressure in the sample storage bin 22 can be safely released.
本发明提供的深海海水及溶解气体采集装置,取样瓶2内部设置了一个预先抽成真空的样品储藏仓22,即负压仓,取样瓶2外部为具有一定高压的深海环境,两者之间存在较大的压力差,负压仓与外界海水通过电磁阀 13的开闭来实现互通或闭合,一旦电磁阀13打开,负压仓与外界深海环境相连通,根据能量最低原理,外界相对高压的海水会进入到相对低压的负压仓内,如此便实现海水的采集。另外,样品储藏仓22与活塞之间通过聚四氟乙烯包覆O形圈进行密封,可以使采集的海水样品实现气密保存。In the deep-sea seawater and dissolved gas collection device provided by the present invention, a pre-evacuated sample storage bin 22 is arranged inside the sampling bottle 2, that is, a negative pressure bin. The outside of the sampling bottle 2 is a deep-sea environment with a certain high pressure. There is a large pressure difference, and the negative pressure chamber and the external seawater communicate or close through the opening and closing of the solenoid valve 13. Once the solenoid valve 13 is opened, the negative pressure chamber is connected with the external deep sea environment. According to the principle of minimum energy, the external environment is relatively high pressure The seawater will enter the relatively low-pressure negative pressure chamber, so as to realize the collection of seawater. In addition, the seal between the sample storage bin 22 and the piston is sealed by an O-ring coated with polytetrafluoroethylene, so that the collected seawater samples can be stored airtight.
与现有技术相比具有的优点:Advantages compared with existing technologies:
气体密封保存的优势:自锁式翻盖采水瓶采用的是弹力绳密封结构,密封度不够高,较难实现完全保存海水中存留的水溶气体,而本装置采用聚四氟乙烯包覆O形圈的密封方式,密封效果更好,更有利于海水样品中水溶气体的保存。Advantages of gas-sealed storage: the self-locking flip-cap water collection bottle adopts an elastic rope sealing structure, the sealing degree is not high enough, and it is difficult to completely preserve the water-soluble gas retained in seawater, and this device uses Teflon-coated O-rings The sealing method is better, and it is more conducive to the preservation of water-soluble gas in seawater samples.
负压仓结构的设计优势:真空抽提式采水瓶是通过另外设置一个负压桶来充当负压仓,本装置是预先将样品储藏仓22抽成真空,并直接将样品储藏仓22作为负压仓,相比之下,本装置的结构更简单、系统更稳定、设计更巧妙,且体积更小巧,操作和携带都更加便利。The design advantage of the negative pressure chamber structure: the vacuum extraction type water collection bottle is used as a negative pressure chamber by setting an additional negative pressure barrel. This device is to vacuumize the sample storage chamber 22 in advance, and directly use the sample storage chamber 22 as a negative pressure chamber. Compared with the ballast, the structure of this device is simpler, the system is more stable, the design is more ingenious, and the volume is smaller, so it is more convenient to operate and carry.
样品仓高压释放方案的优势:真空抽提式采水瓶是通过另外悬挂一个平衡桶来释放样品仓内的高压,而本装置是根据压力自适应平衡原理,依靠活塞、弹簧压簧231、溢流孔24等结构设计,使活塞随外界压力变化而移动,样品储藏仓22随之改变容积,进而实现样品储藏仓22压力的安全释放。通过活塞的自由移动来实现样品储藏仓22压力的安全释放。相比之下,本装置的结构更简单、更安全、更稳定、体积更小、重量更轻,操作和携带更加便利。Advantages of the high-pressure release scheme of the sample chamber: the vacuum extraction water bottle releases the high pressure in the sample chamber by suspending a balance barrel, and this device is based on the principle of pressure self-adaptive balance, relying on the piston, spring compression spring 231, overflow The structural design of the hole 24 makes the piston move with the change of external pressure, and the volume of the sample storage bin 22 changes accordingly, thereby realizing the safe release of the pressure of the sample storage bin 22 . The safe release of the pressure of the sample storage chamber 22 is realized by the free movement of the piston. In contrast, the structure of the device is simpler, safer, more stable, smaller in size, lighter in weight, and more convenient to operate and carry.
天然气水合物作为未来的清洁能源,得到了全世界的广泛重视。国际上对天然气水合物地球化学异常的研究主要集中于沉积物、孔隙水和底层海水的烃类气体浓度异常以及C、O同位素组成及其与天然气水合物的关系等方面。海水中烃类气体(如甲烷)及其它气体(如H2S)的异常是识别天然气水合物存在的重要标识之一,CH4/C2H6或C1/(C2+C3)的比值和CH4中δ 13C可用于判别天然气水合物的来源和成因;深海海水中气体的含量可以在一定程度上标识深海资源蕴藏量,通过对海水中CH4、H2S等气体的异常分布的检测,能够为快速、高效地探查天然气水合物资源提供线索和依据,深海海水及海水中气体研究也是当前海洋科学研究的前沿课题,如何快速地采集到能真实反映原位气体成分组成信息的海水样品,是近几年来海洋技术领域研究的热点,深海海水的气密采集意义重大。现有常规的采水器大多用于单纯采集水样,较少考虑气体的保存,不能满足深海海水中的气体研究的需要。部分采水瓶如负压抽提式采水瓶,虽能采集到保气的海水,但采水装置和操作过程非常复杂和繁琐,不利于船载现场样品的快速采集。As a clean energy source in the future, natural gas hydrate has received extensive attention all over the world. International research on the geochemical anomalies of gas hydrates mainly focuses on the anomalies of hydrocarbon gas concentrations in sediments, pore water and bottom seawater, as well as the composition of C and O isotopes and their relationship with gas hydrates. The abnormality of hydrocarbon gas (such as methane) and other gases (such as H 2 S) in seawater is one of the important signs to identify the existence of natural gas hydrate, CH 4 /C 2 H 6 or C 1 /(C 2 +C 3 ) The ratio of δ 13C in CH 4 and δ 13C can be used to identify the source and origin of natural gas hydrate; the gas content in deep-sea seawater can identify the reserves of deep-sea resources to a certain extent . The detection of distribution can provide clues and basis for fast and efficient exploration of natural gas hydrate resources. The study of gas in deep seawater and seawater is also a frontier topic in current marine scientific research. How to quickly collect information that can truly reflect the composition of in-situ gas The seawater sample is a research hotspot in the field of marine technology in recent years, and the airtight collection of deep seawater is of great significance. Most of the existing conventional water sampling devices are used to simply collect water samples, and less consideration is given to the preservation of gas, which cannot meet the needs of gas research in deep sea water. Some water collection bottles, such as negative pressure extraction water collection bottles, can collect gas-holding seawater, but the water collection device and operation process are very complicated and cumbersome, which is not conducive to the rapid collection of on-site samples on board.
本装置依据能量最低原理和压力自适应平衡原理,通过设置高压密封舱 1、变压器12、高压水密电缆、电路板、限位环15、电磁阀13、单向阀27、样品储藏仓22、平衡活塞23、真空阀25、弹簧压簧231等,实现了船载现场海水及溶解气体样品的快速采集。实现了对深海海水的气密采样。装置具有尺寸小、重量低、操作简单、易于携带与维护等特点,该发明进一步补充完善了船载现场深海海水及水溶气体的快速采集方法,弥补了水合物资源调查中对于现场快速采集水气化学异常标志识别的不足,为我国海域天然气水合物资源勘探分析提供了必要的技术支撑。Based on the principle of minimum energy and self-adaptive pressure balance, the device is equipped with a high-pressure sealed cabin 1, a transformer 12, a high-pressure watertight cable, a circuit board, a limit ring 15, a solenoid valve 13, a one-way valve 27, a sample storage bin 22, a balance Piston 23, vacuum valve 25, spring compression spring 231, etc. realize the rapid collection of on-site seawater and dissolved gas samples on board. Airtight sampling of deep sea water is realized. The device has the characteristics of small size, low weight, simple operation, easy to carry and maintain, etc. This invention further supplements and improves the rapid collection method of deep-sea seawater and water-soluble gas carried by ships, and makes up for the rapid collection of water and gas on site in the investigation of hydrate resources. The lack of identification of chemical anomaly signs provides necessary technical support for the exploration and analysis of natural gas hydrate resources in my country's sea areas.
以上,虽然说明了本发明的几个实施方式,但是这些实施方式只是作为例子提出的,并非用于限定本发明的范围。对于这些新的实施方式,能够以其他各种方式进行实施,在不脱离本发明的要旨的范围内,能够进行各种省略、置换、及变更。这些实施方式和其变形,包含于本发明的范围和要旨中的同时,也包含于权利要求书中记载的发明及其均等范围内。Although some embodiments of the present invention have been described above, these embodiments are presented as examples and are not intended to limit the scope of the present invention. These new embodiments can be implemented in various other forms, and various omissions, substitutions, and changes can be made without departing from the gist of the present invention. These embodiments and modifications thereof are included in the scope and gist of the present invention, and are also included in the invention described in the claims and their equivalents.
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