CN107815516B - External heating type coal-based vertical furnace for producing direct reduced iron - Google Patents
External heating type coal-based vertical furnace for producing direct reduced iron Download PDFInfo
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 239000003245 coal Substances 0.000 title claims abstract description 18
- 238000010438 heat treatment Methods 0.000 title claims abstract description 4
- 239000000112 cooling gas Substances 0.000 claims abstract description 89
- 238000001816 cooling Methods 0.000 claims abstract description 65
- 238000002485 combustion reaction Methods 0.000 claims abstract description 53
- 238000005338 heat storage Methods 0.000 claims abstract description 10
- 239000011449 brick Substances 0.000 claims description 15
- 239000007789 gas Substances 0.000 claims description 15
- 229910001220 stainless steel Inorganic materials 0.000 claims description 3
- 239000010935 stainless steel Substances 0.000 claims description 3
- 238000006722 reduction reaction Methods 0.000 abstract description 47
- 229910052742 iron Inorganic materials 0.000 abstract description 12
- 238000000034 method Methods 0.000 abstract description 12
- 239000002994 raw material Substances 0.000 abstract description 7
- 238000006243 chemical reaction Methods 0.000 abstract description 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract description 4
- 239000003546 flue gas Substances 0.000 abstract description 3
- 239000000446 fuel Substances 0.000 abstract description 3
- 238000002309 gasification Methods 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 3
- 239000002918 waste heat Substances 0.000 abstract description 3
- 239000012141 concentrate Substances 0.000 abstract 1
- 238000005192 partition Methods 0.000 description 7
- 238000007789 sealing Methods 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000002912 waste gas Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000003723 Smelting Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000012261 overproduction Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/02—Making spongy iron or liquid steel, by direct processes in shaft furnaces
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/10—Reduction of greenhouse gas [GHG] emissions
- Y02P10/143—Reduction of greenhouse gas [GHG] emissions of methane [CH4]
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- Vertical, Hearth, Or Arc Furnaces (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
Abstract
Description
技术领域technical field
本发明涉及直立炉技术领域,尤其涉及一种用于生产直接还原铁的外热式煤基直立炉。The invention relates to the technical field of vertical furnaces, in particular to an externally heated coal-based vertical furnace for producing direct reduced iron.
背景技术Background technique
直接还原炼铁工艺(DRI)是指在低于铁矿石的熔化温度下,通过在固态下还原,把铁矿石炼制成金属铁的工艺过程,其产物叫做海绵铁。海绵铁是冶炼优特钢的必需原料,优质的优特钢产品广泛应用于电站、冶金、石油化工、航空及船用设备领域,需求量增加迅速。然而,我国直接还原铁的产量不及百万吨,不到世界直接还原铁产量的1%,远低于世界平均水平。低端产品生产过剩、高端产品产量不足成为我国钢铁行业亟需解决的问题。The direct reduction ironmaking process (DRI) refers to the process of refining iron ore into metallic iron through reduction in the solid state at a temperature lower than the melting temperature of iron ore, and its product is called sponge iron. Sponge iron is an essential raw material for smelting high-quality special steel. High-quality high-quality special steel products are widely used in power station, metallurgy, petrochemical, aviation and marine equipment fields, and the demand is increasing rapidly. However, the output of direct reduced iron in my country is less than one million tons, less than 1% of the world's direct reduced iron output, far below the world average level. Overproduction of low-end products and insufficient production of high-end products have become problems that my country's steel industry needs to solve urgently.
直接还原炼铁按工艺分成气基直接还原和煤基直接还原两种,按主体设备分为回转窑、转底炉、反应罐、管式炉和流化床等。目前,世界上90%以上的直接还原铁都是用气基还原法生产出来的,但是我国天然气资源有限、价格较高,气基还原不适合我国多煤少气的国情,而传统的煤基回转窑工艺、转底炉工艺、隧道窑工艺都存在能耗高、生产过程不易控制、产品质量品位低等问题。Direct reduction ironmaking is divided into gas-based direct reduction and coal-based direct reduction according to the process, and is divided into rotary kiln, rotary hearth furnace, reaction tank, tube furnace and fluidized bed according to the main equipment. At present, more than 90% of the direct reduced iron in the world is produced by the gas-based reduction method. However, my country's natural gas resources are limited and the price is high. Gas-based reduction is not suitable for my country's national conditions of more coal and less gas. Rotary kiln technology, rotary hearth furnace technology, and tunnel kiln technology all have problems such as high energy consumption, difficult control of the production process, and low product quality.
国内研究者对外热式煤基直接还原也做了一定的研究,如公开号为CN101832706A的专利《外燃管式直接还原竖炉》、公开号为CN201166513的专利《煤基直接还原铁外热式竖炉》,公开号为CN 204529897 U的《一种生产直接还原铁的外热式煤基竖炉》等。上述已公开的技术,其炉体结构均过于简单,竖炉内仅包括燃料燃烧的氧化反应、原料的气化反应和原料的还原反应,炉体寿命短、热工效率低、难于工程化,而且均采用将高温的海绵铁在炉外用水冷设备降温的冷却方式,对排料设备和水冷设备耐高温要求高、设备投资大。Domestic researchers have also done some research on external thermal direct reduction of coal, such as the patent "External Combustion Tube Type Direct Reduction Shaft Furnace" with publication number CN101832706A, and the patent "External Thermal Direct Reduction of Coal-based Direct Reduction of Iron" with publication number CN201166513. Shaft Furnace", the publication number is CN 204529897 U "A kind of external heating type coal-based shaft furnace for producing direct reduced iron", etc. The above disclosed technologies all have a too simple structure of the furnace body. The shaft furnace only includes the oxidation reaction of fuel combustion, the gasification reaction of raw materials and the reduction reaction of raw materials. The life of the furnace body is short, the thermal efficiency is low, and it is difficult to engineer. Moreover, they all adopt the cooling method of cooling the high-temperature sponge iron outside the furnace with water-cooled equipment, which requires high temperature resistance for the discharge equipment and water-cooled equipment, and requires a large investment in equipment.
发明内容Contents of the invention
本发明提供了一种用于生产直接还原铁的外热式煤基直立炉,将直接还原炼铁过程中的燃料燃烧的氧化反应、原料的气化反应、原料的还原反应、所生成海绵铁的冷却过程及回收高温烟气余热的过程集中在直立炉内进行,具有炉体结构合理、炉体寿命长、热工效率高、附属设备投资低、易于实现工程化等特点。The invention provides an externally heated coal-based vertical furnace for producing direct reduced iron, the oxidation reaction of fuel combustion in the direct reduction ironmaking process, the gasification reaction of raw materials, the reduction reaction of raw materials, the generated sponge iron The cooling process and the process of recovering high-temperature flue gas waste heat are concentrated in the vertical furnace, which has the characteristics of reasonable furnace structure, long furnace life, high thermal efficiency, low investment in auxiliary equipment, and easy engineering.
为了达到上述目的,本发明采用以下技术方案实现:In order to achieve the above object, the present invention adopts the following technical solutions to realize:
一种用于生产直接还原铁的外热式煤基直立炉,包括还原室、燃烧室、炉顶、蓄热室和冷却室;燃烧室和还原室、冷却室占据炉体一侧,蓄热室占据炉体另一侧;燃烧室和还原室相间分布,冷却室位于还原室的下方,冷却室的顶部与还原室连通;炉顶位于燃烧室的上部;蓄热室包括上部蓄热室和下部蓄热室,上部蓄热室、下部蓄热室的一端与燃烧室相通,另一端与废气开闭器相连,上部蓄热室和下部蓄热室内均设有格子砖;所述冷却室两侧的冷却室墙内分别设有冷却气体通道,多个冷却气体通道沿冷却室高向均匀设置,每个冷却气体通道沿冷却室长向均匀设有多个冷却气体出口或冷却气体入口,冷却气体出口、冷却气体入口与冷却室内部空间连通;所述上部蓄热室的顶部设顶部汇合气道连通燃烧室的顶部,底部设上部蓄热室小烟道;所述下部蓄热室的顶部设下部蓄热室小烟道,底部设底部汇合气道连通燃烧室的底部。An externally heated coal-based vertical furnace for the production of direct reduced iron, including a reduction chamber, a combustion chamber, a furnace roof, a regenerator and a cooling chamber; the combustion chamber, the reduction chamber, and the cooling chamber occupy one side of the furnace body, and the heat storage The chamber occupies the other side of the furnace body; the combustion chamber and the reduction chamber are distributed alternately, the cooling chamber is located below the reduction chamber, and the top of the cooling chamber communicates with the reduction chamber; the furnace top is located on the upper part of the combustion chamber; the regenerator includes the upper regenerator and The lower regenerator, one end of the upper regenerator and the lower regenerator communicate with the combustion chamber, and the other end is connected with the waste gas switch. Both the upper regenerator and the lower regenerator are equipped with checkered bricks; Cooling gas passages are respectively arranged in the cooling chamber wall on the side, and multiple cooling gas passages are uniformly arranged along the height of the cooling chamber, and each cooling gas passage is uniformly provided with multiple cooling gas outlets or cooling gas inlets along the The gas outlet and the cooling gas inlet are connected to the inner space of the cooling chamber; the top of the upper regenerator is provided with a top converging air passage to communicate with the top of the combustion chamber, and the bottom is provided with a small flue in the upper regenerator; the top of the lower regenerator A small flue is provided in the lower regenerator, and a bottom converging air passage is provided at the bottom to communicate with the bottom of the combustion chamber.
所述冷却气体入口或冷却气体出口的开口方向分别朝向冷却室内侧斜下方。The opening direction of the cooling gas inlet or the cooling gas outlet faces obliquely downward inside the cooling chamber respectively.
所述冷却气体入口和冷却气体出口相对设置;即冷却室内一侧冷却室墙内的冷却气体通道上均设冷却气体入口,另一侧冷却室墙内的冷却气体通道上均设冷却气体出口。The cooling gas inlet and the cooling gas outlet are arranged oppositely; that is, cooling gas inlets are provided on the cooling gas passages in the cooling chamber wall on one side of the cooling chamber, and cooling gas outlets are provided on the cooling gas passages in the cooling chamber wall on the other side.
所述冷却室内两侧冷却室墙下部的冷却气体通道上均设冷却气体入口,两侧冷却室墙上部的冷却气体通道上均设冷却气体出口。Cooling gas inlets are provided on the cooling gas passages at the bottom of the cooling chamber walls on both sides of the cooling chamber, and cooling gas outlets are provided on the cooling gas passages at the top of the cooling chamber walls on both sides.
所述冷却气体通道、冷却气体入口及冷却气体出口分别由耐火砖砌筑而成,或由穿设在耐火砖中的不锈钢管组成。The cooling gas channel, the cooling gas inlet and the cooling gas outlet are respectively built by refractory bricks, or are composed of stainless steel pipes pierced in the refractory bricks.
所述还原室为单排还原室、双排还原室或三排还原室,还原室沿宽度方向上口窄下口宽,且还原室下口宽度大于还原室上口宽度10mm~200mm;冷却室上口的宽度与还原室下口的宽度相同。The reduction chambers are single-row reduction chambers, double-row reduction chambers or three-row reduction chambers. The upper opening of the reduction chamber is narrow along the width direction and the lower opening is wider, and the width of the lower opening of the reduction chamber is 10 mm to 200 mm wider than the width of the upper opening of the reduction chamber; the cooling chamber The width of the upper opening is the same as that of the lower opening of the reduction chamber.
所述上部蓄热室和下部蓄热室组成一个单元蓄热室,每个单元蓄热室与燃烧室一一对应设置。The upper regenerator and the lower regenerator form a unit regenerator, and each unit regenerator corresponds to the combustion chamber one by one.
与现有技术相比,本发明的有益效果是:Compared with prior art, the beneficial effect of the present invention is:
1)直立炉炉体结构合理,传热条件好,炉体寿命长;1) The structure of the vertical furnace body is reasonable, the heat transfer condition is good, and the life of the furnace body is long;
2)蓄热室能够回收烟气的余热预热燃烧用的空气,直立炉热工效率高;2) The regenerator can recover the waste heat of the flue gas to preheat the air for combustion, and the thermal efficiency of the vertical furnace is high;
3)操作方便、气流流量可调,易于控制燃烧温度和速度,减少高温点,从而降低NOx的生成,更利于环保;3) Easy to operate, adjustable air flow, easy to control combustion temperature and speed, reduce high temperature points, thereby reducing the generation of NOx, which is more conducive to environmental protection;
4)冷却室可实现产品海绵铁在炉内快速冷却,减少了对炉外冷却设备的耐超高温要求、可降低附属设备投资,同时提高了生产效率。4) The cooling chamber can realize the rapid cooling of the product sponge iron in the furnace, which reduces the ultra-high temperature resistance requirements for the cooling equipment outside the furnace, reduces the investment in auxiliary equipment, and improves production efficiency at the same time.
附图说明Description of drawings
图1是本发明所述直立炉的炉体纵向剖视图。Fig. 1 is a longitudinal sectional view of the furnace body of the vertical furnace of the present invention.
图2是图1中的A-A视图。Fig. 2 is a view of A-A in Fig. 1 .
图3是本发明所述冷却气体入口与冷却气体出口分布示意图一。Fig. 3 is a first schematic diagram of the distribution of cooling gas inlets and cooling gas outlets according to the present invention.
图4是本发明所述冷却气体入口与冷却气体出口分布示意图二。Fig. 4 is a second schematic diagram of the distribution of cooling gas inlets and cooling gas outlets according to the present invention.
图中:1.炉顶装料口2.炉顶3.燃烧室4.还原室5.冷却室6.冷却气体通道7.燃烧室墙8.冷却室墙9.上部蓄热室封墙10.上部蓄热室内的格子砖11.蓄热室与燃烧室之间隔墙12.上部蓄热室小烟道13.下部蓄热室小烟道14.下部蓄热室封墙15.下部蓄热室内的格子砖16.燃烧室中部隔墙17.立火道隔墙18.立火道19.燃烧室封墙20.冷却气体入口21.冷却气体出口22.冷却室上口In the figure: 1. Furnace
具体实施方式detailed description
下面结合附图对本发明的具体实施方式作进一步说明:The specific embodiment of the present invention will be further described below in conjunction with accompanying drawing:
如图1、图2所示,本发明所述一种用于生产直接还原铁的外热式煤基直立炉,包括还原室4、燃烧室3、炉顶2、蓄热室和冷却室5;燃烧室3和还原室4、冷却室5占据炉体一侧,蓄热室占据炉体另一侧;燃烧室3和还原室4相间分布,冷却室5位于还原室4的下方,冷却室5的顶部与还原室4连通;炉顶2位于燃烧室3的上部;蓄热室包括上部蓄热室和下部蓄热室,上部蓄热室、下部蓄热室的一端与燃烧室3相通,另一端与废气开闭器相连,上部蓄热室和下部蓄热室内均设有格子砖10/15;所述冷却室5两侧的冷却室墙8内分别设有冷却气体通道6,多个冷却气体通道6沿冷却室5高向均匀设置,每个冷却气体通道6沿冷却室5长向均匀设有多个冷却气体出口21或冷却气体入口20,冷却气体出口21、冷却气体入口20与冷却室5内部空间连通;所述上部蓄热室的顶部设顶部汇合气道连通燃烧室3的顶部,底部设上部蓄热室小烟道12;所述下部蓄热室的顶部设下部蓄热室小烟道13,底部设底部汇合气道连通燃烧室3的底部。As shown in Figures 1 and 2, an externally heated coal-based vertical furnace for producing direct reduced iron according to the present invention includes a reduction chamber 4, a
所述冷却气体入口20或冷却气体出口21的开口方向分别朝向冷却室5内侧斜下方。The opening direction of the cooling
如图3所示,所述冷却气体入口20和冷却气体出口21相对设置;即冷却室5内一侧冷却室墙8内的冷却气体通道6上均设冷却气体入口20,另一侧冷却室墙8内的冷却气体通道6上均设冷却气体出口21。As shown in Figure 3, the cooling
如图4所示,所述冷却室5内两侧冷却室墙8下部的冷却气体通道6上均设冷却气体入口20,两侧冷却室墙8上部的冷却气体通道6上均设冷却气体出口21。As shown in Figure 4, cooling
所述冷却气体通道6、冷却气体入口20及冷却气体出口21分别由耐火砖砌筑而成,或由穿设在耐火砖中的不锈钢管组成。The cooling
所述还原室4为单排还原室、双排还原室或三排还原室,还原室4沿宽度方向上口窄下口宽,且还原室下口宽度大于还原室上口宽度10mm~200mm;冷却室上口22的宽度与还原室下口的宽度相同。The reduction chamber 4 is a single-row reduction chamber, a double-row reduction chamber or a three-row reduction chamber. The reduction chamber 4 has a narrow upper opening and a wider lower opening along the width direction, and the width of the lower opening of the reduction chamber is 10 mm to 200 mm larger than the width of the upper opening of the reduction chamber; The width of the
所述上部蓄热室和下部蓄热室组成一个单元蓄热室,每个单元蓄热室与燃烧室3一一对应设置。The upper regenerator and the lower regenerator form a unit regenerator, and each unit regenerator corresponds to the
直立炉的燃烧室3由立火道18、立火道隔墙17、燃烧室中部隔墙16、还原室墙、燃烧室墙7及燃烧室封墙19组成;还原室4由两侧还原室墙、蓄热室墙、封墙、装料口护炉铁件和排料口护炉铁件合围起来组成,冷却室5由两侧冷却室墙、蓄热室墙、封墙和排料口护炉铁件合围起来组成。上部蓄热室与下部蓄热室之间设蓄热室隔墙,上部蓄热室、下部蓄热室与燃烧室相邻一侧设蓄热室与燃烧室之间隔墙11,另一侧分别设上部蓄热室封墙9和下部蓄热室封墙14。炉顶设炉顶装料口1。The
本发明中,由对应冷却气体通道6输送的冷却气体由冷却气体入口20进入冷却室5,冷却气体在冷却室5内沿水平方向或向上流动,与向下流动的高温海绵铁直接换热,可将800℃~1000℃的高温海绵铁冷却到100℃~350℃范围内,换热后的冷却气体由冷却气体出口21通过对应冷却气体通道6离开冷却室5。冷却气体为直接还原炼铁反应的生成气,主要为一氧化碳和二氧化碳的混合气,也可采用氮气等惰性气体。In the present invention, the cooling gas transported by the corresponding cooling
设有冷却气体入口20的冷却气体通道6分别与入炉气管道(风机正压出口端)连接,设有冷却气体出口21的冷却气体通道6分别与吸气管道(风机负压入口端)连接。The cooling
上部蓄热室和下部蓄热室组成一个单元蓄热室,每个单元蓄热室与燃烧室3一一对应设置,燃烧室立火道18温度可调节性强。The upper regenerator and the lower regenerator form a unit regenerator, and each unit regenerator is set in one-to-one correspondence with the
在第一个交换周期内,空气通过废气开闭器进入上部蓄热室小烟道12,经过上部蓄热室内的格子砖10预热后,经顶部汇合气道进入燃烧室立火道18参与燃烧,燃烧后的热废气通过燃烧室3底部进入底部汇合气道,与下部蓄热室内的格子砖15进行热交换后,通过下部蓄热室的小烟道13经废气开闭器进入烟囱;In the first exchange cycle, the air enters the
在第二个交换周期内,空气通过废气开闭器进入下部蓄热室的小烟道13,经过下部蓄热室内的格子砖15预热后,经底部汇合气道进入燃烧室立火道18参与燃烧,燃烧后的热废气通过燃烧室3顶部进入顶部汇合气道,与上部蓄热室内的格子砖10进行热交换后,通过上部蓄热室的小烟道12经废气开闭器进入烟囱;In the second exchange cycle, the air enters the small flue 13 of the lower regenerator through the waste gas switch, and after being preheated by the
在不同交换周期内,通过上部蓄热室和下部蓄热室的气流阻力相同或相近,立火道18内压力分布更加稳定,生产过程中温度波动可控性强,有利于减少氮氧化物排放量。In different exchange cycles, the airflow resistance through the upper regenerator and the lower regenerator is the same or similar, the pressure distribution in the
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其发明构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。The above is only a preferred embodiment of the present invention, but the scope of protection of the present invention is not limited thereto, any person familiar with the technical field within the technical scope disclosed in the present invention, according to the technical solution of the present invention Any equivalent replacement or change of the inventive concepts thereof shall fall within the protection scope of the present invention.
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