CN107815192A - 一种水性玻璃烤漆 - Google Patents
一种水性玻璃烤漆 Download PDFInfo
- Publication number
- CN107815192A CN107815192A CN201711146705.4A CN201711146705A CN107815192A CN 107815192 A CN107815192 A CN 107815192A CN 201711146705 A CN201711146705 A CN 201711146705A CN 107815192 A CN107815192 A CN 107815192A
- Authority
- CN
- China
- Prior art keywords
- water
- based glass
- baking paint
- glass baking
- wetting agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 239000011521 glass Substances 0.000 title claims abstract description 38
- 239000003973 paint Substances 0.000 title claims abstract description 34
- 239000000080 wetting agent Substances 0.000 claims abstract description 26
- 239000011347 resin Substances 0.000 claims abstract description 19
- 229920005989 resin Polymers 0.000 claims abstract description 19
- 239000003377 acid catalyst Substances 0.000 claims abstract description 16
- 239000006184 cosolvent Substances 0.000 claims abstract description 13
- 239000002562 thickening agent Substances 0.000 claims abstract description 13
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims description 10
- 239000004925 Acrylic resin Substances 0.000 claims description 8
- 229920000178 Acrylic resin Polymers 0.000 claims description 8
- -1 melmac Polymers 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 6
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 claims description 5
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical group CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 5
- 239000004593 Epoxy Substances 0.000 claims description 5
- 229920002401 polyacrylamide Polymers 0.000 claims description 5
- 229920002635 polyurethane Polymers 0.000 claims description 5
- 239000004814 polyurethane Substances 0.000 claims description 5
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 5
- 239000004952 Polyamide Substances 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
- 229920002647 polyamide Polymers 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- QBDAFARLDLCWAT-UHFFFAOYSA-N 2,3-dihydropyran-6-one Chemical compound O=C1OCCC=C1 QBDAFARLDLCWAT-UHFFFAOYSA-N 0.000 claims description 3
- OPKOKAMJFNKNAS-UHFFFAOYSA-N N-methylethanolamine Chemical class CNCCO OPKOKAMJFNKNAS-UHFFFAOYSA-N 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- 150000002009 diols Chemical class 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- CJMZLCRLBNZJQR-UHFFFAOYSA-N ethyl 2-amino-4-(4-fluorophenyl)thiophene-3-carboxylate Chemical compound CCOC(=O)C1=C(N)SC=C1C1=CC=C(F)C=C1 CJMZLCRLBNZJQR-UHFFFAOYSA-N 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- LJDSTRZHPWMDPG-UHFFFAOYSA-N 2-(butylamino)ethanol Chemical compound CCCCNCCO LJDSTRZHPWMDPG-UHFFFAOYSA-N 0.000 claims description 2
- GVNHOISKXMSMPX-UHFFFAOYSA-N 2-[butyl(2-hydroxyethyl)amino]ethanol Chemical compound CCCCN(CCO)CCO GVNHOISKXMSMPX-UHFFFAOYSA-N 0.000 claims description 2
- GOJUJUVQIVIZAV-UHFFFAOYSA-N 2-amino-4,6-dichloropyrimidine-5-carbaldehyde Chemical group NC1=NC(Cl)=C(C=O)C(Cl)=N1 GOJUJUVQIVIZAV-UHFFFAOYSA-N 0.000 claims description 2
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims description 2
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 2
- 229960002887 deanol Drugs 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- 229940043237 diethanolamine Drugs 0.000 claims description 2
- 239000012972 dimethylethanolamine Substances 0.000 claims description 2
- 125000001153 fluoro group Chemical class F* 0.000 claims description 2
- 239000004584 polyacrylic acid Substances 0.000 claims description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 2
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 claims 1
- FEWFXBUNENSNBQ-UHFFFAOYSA-N 2-hydroxyacrylic acid Chemical compound OC(=C)C(O)=O FEWFXBUNENSNBQ-UHFFFAOYSA-N 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 229910021529 ammonia Inorganic materials 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N n-propyl alcohol Natural products CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 6
- 239000000049 pigment Substances 0.000 abstract description 6
- 239000000853 adhesive Substances 0.000 abstract description 4
- 230000001070 adhesive effect Effects 0.000 abstract description 4
- 238000007711 solidification Methods 0.000 abstract description 4
- 230000008023 solidification Effects 0.000 abstract description 4
- 238000004132 cross linking Methods 0.000 abstract description 3
- 239000011159 matrix material Substances 0.000 abstract description 3
- 150000003839 salts Chemical class 0.000 abstract description 3
- 235000019441 ethanol Nutrition 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000002966 varnish Substances 0.000 description 3
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical group CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- UOQYWMZLTNEIFI-UHFFFAOYSA-N 2-[3-aminopropyl(methyl)amino]ethanol Chemical group OCCN(C)CCCN UOQYWMZLTNEIFI-UHFFFAOYSA-N 0.000 description 1
- 229920003270 Cymel® Polymers 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- WRLRISOTNFYPMU-UHFFFAOYSA-N [S].CC1=CC=CC=C1 Chemical compound [S].CC1=CC=CC=C1 WRLRISOTNFYPMU-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09D161/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C09D161/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D177/00—Coating compositions based on polyamides obtained by reactions forming a carboxylic amide link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
本发明公开了一种水性玻璃烤漆，按重量百分比计，包括：水性树脂60‑80％，酸催化剂0.3‑0.8％，pH调节剂0.7‑5.5％，增稠剂0.1‑0.5％，助溶剂1‑8％，润湿剂0.1‑1％，成膜助剂1‑9％，颜料0‑20％，水5‑25％。发明综合考虑各种组分的选择和用量，所选用的水性树脂能够确保漆膜的高光泽度、高硬度和强耐候性；酸催化剂的使用能够促进基体树脂快速交联，降低固化温度，提高固化程度；此外，本发明提供的一种水性玻璃烤漆对环境无污染，对操作人员无毒害，涂膜附着力强、柔韧性好，具有较高的硬度、优异的耐磨性、耐水性、耐醇性及耐盐雾性，可广泛用于酒瓶、香水瓶等玻璃制品上。
Description
技术领域
本发明涉及涂料化工技术领域，尤其涉及一种水性玻璃烤漆。
背景技术
水性玻璃烤漆因其分散介质的不同而划分为油性玻璃烤漆与水性玻璃烤漆，油性玻璃烤漆是目前市场上比较常用的材料，广泛应用于酒瓶、香水瓶、灯饰、家装玻璃制品和玻璃仪器等都需要在表面涂覆保护层和装饰涂层，相对成熟而普及，使用油性玻璃烤漆时，需要加入50％以上的有机溶剂(甲苯、二甲苯、工业酒精等)，这些溶剂容易挥发，有刺激性气味且对人体存在着不同程度的毒害，在生产过程、应用过程及干燥过程中不断挥发到空气中或被人体吸收，严重地破坏环境，伤害人体健康。水性玻璃烤漆以水为分散介质，彻底消除了有机溶剂对人体的危害，具有传统油性涂料不可比拟的优势，诸如健康环保、低碳节能、利用率高、安全性好等，在世界各国得到了迅速发展。
然而，现有的水性玻璃烤漆在玻璃底材上存在附着力、耐醇性、耐水性、耐磨耗性差及硬度低等缺点。
发明内容
本发明提供了一种水性玻璃烤漆，以解决现有水性玻璃烤漆在玻璃底材上存在附着力、耐醇性、耐水性、耐磨耗性差及硬度低等问题。
本发明提供的一种水性玻璃烤漆，按重量百分比计，包括：
根据本发明的一个实施例，所述水性树脂为羟基丙烯酸树脂、环氧丙烯酸树脂、三聚氰胺树脂、聚酰胺树脂和无机硅树脂中的一种或几种的混合物。
根据本发明的一个实施例，所述酸催化剂为对甲基苯磺酸、十二烷基苯磺酸、二壬基萘磺酸和二壬基萘二磺酸的一种。
根据本发明的一个实施例，所述pH调节剂为2-氨基-2-甲基-1-丙醇、N-甲基乙醇胺、二甲基乙醇胺、单乙醇胺、二乙醇胺、三乙醇胺、丁基乙醇胺、N-氨丙基一甲基乙醇胺、2-氨基-2-乙基-1,3丙二醇、丁基二乙醇胺和氨水中的一种。
根据本发明的一个实施例，所述增稠剂为聚氨酯、聚丙烯酰胺、聚乙烯醇、聚丙烯酸、聚丙烯酸酯共聚乳液、缔合型聚氨酯和聚醚型聚氨酯中的一种或几种的混合物。
根据本发明的一个实施例，所述助溶剂为乙二醇丁醚、二乙二醇丁醚、丙二醇甲醚、丙二醇甲醚醋酸酯和丙二醇二丁醚中的一种或两种的混合物。
根据本发明的一个实施例，所述润湿剂为有机硅类润湿剂、炔二醇类润湿剂、丙烯酸类润湿剂和氟类润湿剂中的一种或几种的混合物。
根据本发明的一个实施例，所述成膜助剂为丙二醇丁醚和丙二醇甲醚醋酸酯中的一种或两种的混合物。
本发明还提供了一种玻璃瓶，采用上述水性玻璃烤漆涂装。
本发明提供的一种水性玻璃烤漆可以包括以下有益效果：
本发明综合考虑各种组分的选择和用量，所选用的水性树脂能够确保漆膜的高光泽度、高硬度和强耐候性；酸催化剂的使用能够促进基体树脂快速交联，降低固化温度，提高固化程度；此外，本发明提供的一种水性玻璃烤漆对环境无污染，对操作人员无毒害，涂膜附着力强、柔韧性好，具有较高的硬度、优异的耐磨性、耐水性、耐醇性及耐盐雾性，可广泛用于酒瓶、香水瓶等玻璃制品上。
具体实施方式
实施例1
一种水性玻璃烤漆，按重量百分比计，包括以下组分：水性树脂80％，酸催化剂0.8％，pH调节剂5％，增稠剂0.1％，助溶剂1％，润湿剂0.1％，成膜助剂2％，颜料0，水11％。
水性树脂为羟基丙烯酸树脂和环氧丙烯酸树脂1:1混合，酸催化剂为对甲基苯磺酸，pH调节剂为2-氨基-2-甲基-1-丙醇，增稠剂为聚氨酯和聚丙烯酰胺1:1混合，助溶剂为乙二醇丁醚，润湿剂为有机硅类润湿剂，成膜助剂为丙二醇丁醚。
实施例2
一种水性玻璃烤漆，按重量百分比计，包括以下组分：水性树脂75％，酸催化剂0.7％，pH调节剂3.2％，增稠剂0.3％，助溶剂2.6％，润湿剂0.5％，成膜助剂4％，颜料10％，水3.7％。
水性树脂为环氧丙烯酸树脂和三聚氰胺树脂1:1混合，酸催化剂为十二烷基苯磺酸，pH调节剂为N-甲基乙醇胺，增稠剂为聚丙烯酰胺和聚乙烯醇1:1混合，助溶剂为乙二醇丁醚和二乙二醇丁醚1:1混合，润湿剂为炔二醇类润湿剂，成膜助剂为丙二醇甲醚醋酸酯。
实施例3
一种水性玻璃烤漆，按重量百分比计，包括以下组分：水性树脂70％，酸催化剂0.5％，pH调节剂4.1％，增稠剂0.2％，助溶剂1.5％，润湿剂0.6％，成膜助剂1.5％，颜料5％，水16.6％。
水性树脂为三聚氰胺树脂和聚酰胺树脂1:1混合，酸催化剂为二壬基萘磺酸，pH调节剂为三乙醇胺，增稠剂为聚丙烯酰胺、聚乙烯醇和聚丙烯酸1:1:1混合，助溶剂为丙二醇二丁醚，润湿剂为有机硅类润湿剂，成膜助剂为丙二醇丁醚。
实施例4
一种水性玻璃烤漆，按重量百分比计，包括以下组分：水性树脂65％，酸催化剂0.3％，pH调节剂5.5％，增稠剂0.4％，助溶剂7.5％，润湿剂0.9％，成膜助剂9％，颜料5％，水6.4％。
水性树脂为无机硅树脂，酸催化剂为二壬基萘二磺酸，pH调节剂为2-氨基-2-乙基-1,3丙二醇，增稠剂为聚丙烯酸酯共聚乳液，助溶剂为丙二醇甲醚醋酸酯和丙二醇二丁醚1:1混合，润湿剂为丙烯酸类润湿剂，成膜助剂为丙二醇甲醚醋酸酯。
实施例5
一种水性玻璃烤漆，按重量百分比计，包括以下组分：水性树脂60％，酸催化剂0.8％，pH调节剂5.5％，增稠剂0.5％，助溶剂8％，润湿剂1％，成膜助剂9％，颜料5，水10.2％。
水性树脂为羟基丙烯酸树脂、环氧丙烯酸树脂、三聚氰胺树脂和聚酰胺树脂等比例混合，酸催化剂为二壬基萘磺酸，pH调节剂为N-氨丙基一甲基乙醇胺，增稠剂为缔合型聚氨酯，助溶剂为二乙二醇丁醚，润湿剂为丙烯酸类润湿剂，成膜助剂为丙二醇丁醚。
本发明实施例还提供了一种玻璃瓶，采用上述水性玻璃烤漆涂装。
综上所述，本发明实施例提供的一种水性玻璃烤漆综合考虑各种组分的选择和用量，所选用的水性树脂能够确保漆膜的高光泽度、高硬度和强耐候性；酸催化剂的使用能够促进基体树脂快速交联，降低固化温度，提高固化程度；此外，本发明提供的一种水性玻璃烤漆对环境无污染，对操作人员无毒害，涂膜附着力强、柔韧性好，具有较高的硬度、优异的耐磨性、耐水性、耐醇性及耐盐雾性，可广泛用于酒瓶、香水瓶等玻璃制品上。
尽管本发明已作了详细说明并引证了实施例，但对于本领域的普通技术人员来说，显然可以按照上述说明而做出的各种方案、修改和改动，都应该包括在本发明权利要求的范围之内。
Claims (9)
1.一种水性玻璃烤漆，其特征在于，按重量百分比计，包括：
2.根据权利要求1所述的水性玻璃烤漆，其特征在于，所述水性树脂为羟基丙烯酸树脂、环氧丙烯酸树脂、三聚氰胺树脂、聚酰胺树脂和无机硅树脂中的一种或几种的混合物。
3.根据权利要求1所述的水性玻璃烤漆，其特征在于，所述酸催化剂为对甲基苯磺酸、十二烷基苯磺酸、二壬基萘磺酸和二壬基萘二磺酸的一种。
4.根据权利要求1所述的水性玻璃烤漆，其特征在于，所述pH调节剂为2-氨基-2-甲基-1-丙醇、N-甲基乙醇胺、二甲基乙醇胺、单乙醇胺、二乙醇胺、三乙醇胺、丁基乙醇胺、N-氨丙基一甲基乙醇胺、2-氨基-2-乙基-1,3丙二醇、丁基二乙醇胺和氨水中的一种。
5.根据权利要求1所述的水性玻璃烤漆，其特征在于，所述增稠剂为聚氨酯、聚丙烯酰胺、聚乙烯醇、聚丙烯酸、聚丙烯酸酯共聚乳液、缔合型聚氨酯和聚醚型聚氨酯中的一种或几种的混合物。
6.根据权利要求1所述的水性玻璃烤漆，其特征在于，所述助溶剂为乙二醇丁醚、二乙二醇丁醚、丙二醇甲醚、丙二醇甲醚醋酸酯和丙二醇二丁醚中的一种或两种的混合物。
7.根据权利要求1所述的水性玻璃烤漆，其特征在于，所述润湿剂为有机硅类润湿剂、炔二醇类润湿剂、丙烯酸类润湿剂和氟类润湿剂中的一种或几种的混合物。
8.根据权利要求1所述的水性玻璃烤漆，其特征在于，所述成膜助剂为丙二醇丁醚和丙二醇甲醚醋酸酯中的一种或两种的混合物。
9.一种玻璃瓶，其特征在于，采用权利要求1-8任一项所述的水性玻璃烤漆涂装。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711146705.4A CN107815192A (zh) | 2017-11-17 | 2017-11-17 | 一种水性玻璃烤漆 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711146705.4A CN107815192A (zh) | 2017-11-17 | 2017-11-17 | 一种水性玻璃烤漆 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107815192A true CN107815192A (zh) | 2018-03-20 |
Family
ID=61608686
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711146705.4A Pending CN107815192A (zh) | 2017-11-17 | 2017-11-17 | 一种水性玻璃烤漆 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107815192A (zh) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3775067A4 (en) * | 2018-03-27 | 2021-06-02 | Sun Chemical Corporation | AQUATIC INKS WITH RENEWABLE MATERIALS |
| CN113667330A (zh) * | 2021-09-02 | 2021-11-19 | 广汉市科思诺新材料科技有限公司 | 一种高耐磨玻璃烤漆涂料及其制备方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103937360A (zh) * | 2013-01-17 | 2014-07-23 | 深圳市莱莉雅环保科技有限公司 | 一种低温固化水性玻璃烤漆的制备方法 |
| CN103937354A (zh) * | 2013-01-17 | 2014-07-23 | 深圳市莱莉雅环保科技有限公司 | 一种高硬度水性玻璃烤漆的制备方法 |
| CN105505093A (zh) * | 2015-12-18 | 2016-04-20 | 宁波高新区夏远科技有限公司 | 一种环保型玻璃烤漆及其制备方法 |
| CN105949914A (zh) * | 2016-06-16 | 2016-09-21 | 中山市汉艺涂料有限公司 | 一种水性玻璃烤漆及其制备方法 |
-
2017
- 2017-11-17 CN CN201711146705.4A patent/CN107815192A/zh active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103937360A (zh) * | 2013-01-17 | 2014-07-23 | 深圳市莱莉雅环保科技有限公司 | 一种低温固化水性玻璃烤漆的制备方法 |
| CN103937354A (zh) * | 2013-01-17 | 2014-07-23 | 深圳市莱莉雅环保科技有限公司 | 一种高硬度水性玻璃烤漆的制备方法 |
| CN105505093A (zh) * | 2015-12-18 | 2016-04-20 | 宁波高新区夏远科技有限公司 | 一种环保型玻璃烤漆及其制备方法 |
| CN105949914A (zh) * | 2016-06-16 | 2016-09-21 | 中山市汉艺涂料有限公司 | 一种水性玻璃烤漆及其制备方法 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3775067A4 (en) * | 2018-03-27 | 2021-06-02 | Sun Chemical Corporation | AQUATIC INKS WITH RENEWABLE MATERIALS |
| US12031056B2 (en) | 2018-03-27 | 2024-07-09 | Sun Chemical Corporation | Water-based inks with renewable materials |
| CN113667330A (zh) * | 2021-09-02 | 2021-11-19 | 广汉市科思诺新材料科技有限公司 | 一种高耐磨玻璃烤漆涂料及其制备方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103937354B (zh) | 一种高硬度水性玻璃烤漆的制备方法 | |
| CN104877514A (zh) | 一种含水性丙烯酸改性醇酸树脂的氨基树脂烤漆及其制备方法 | |
| CN102719163A (zh) | 一种水性单组份哑光清漆 | |
| CN103937360A (zh) | 一种低温固化水性玻璃烤漆的制备方法 | |
| CN106947367A (zh) | 一种环保型水性金属防锈漆及其制备方法 | |
| CN103614062A (zh) | 一种皮革表面涂饰用环保涂料及制备方法 | |
| CN106118334B (zh) | 水性有机-无机杂化防腐涂料及其使用方法 | |
| CN105754442B (zh) | 耐水透气水包水多彩涂料配方及其制作方法 | |
| CN107619628A (zh) | 一种水性双组份丙烯酸锤纹漆及其制备方法 | |
| CN109439090A (zh) | 一种耐腐蚀快干环保水性漆及其制备方法 | |
| CN106957572A (zh) | 一种浸涂用水性木器高光清漆及其制备方法 | |
| CN106634382A (zh) | 一种环保防腐快干型的底面合一自干漆及其制备方法 | |
| CN107815192A (zh) | 一种水性玻璃烤漆 | |
| CN104559687A (zh) | 一种抗涂鸦面漆 | |
| CN104530868B (zh) | 一种水性环保玻璃漆及其制备方法 | |
| CN105482587A (zh) | 一种环境友好型水性纳米结构木器漆及其制备方法 | |
| CN108192437A (zh) | 一种可用于湿碰湿免中涂体系的水性高温金属漆及其施工工艺 | |
| CN111073407A (zh) | 一种适应于快速下线包装的水性丙烯酸涂料及其制备方法 | |
| CN104804492A (zh) | 一种防刮擦高性能水性木器涂料 | |
| CN105754411A (zh) | 白板笔墨水及其制作方法 | |
| CN103897540A (zh) | 高光亮表观的可吸收弱溶剂墨的涂层配方 | |
| CN105418825A (zh) | 水性涂料用丙烯酸酯乳液及其制备方法 | |
| CN108570266A (zh) | 一种耐化学型水性涂料组合物及其制备方法 | |
| CN109594094A (zh) | 一种通用易处理环保型水基乳化防锈剂及其制备方法 | |
| CN107022264A (zh) | 高硬度水性耐刮哑光油 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180320 |
|
| RJ01 | Rejection of invention patent application after publication |