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CN107814587A - The preparation method of seven bright cloud ink stones - Google Patents

The preparation method of seven bright cloud ink stones Download PDF

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Publication number
CN107814587A
CN107814587A CN201710867689.1A CN201710867689A CN107814587A CN 107814587 A CN107814587 A CN 107814587A CN 201710867689 A CN201710867689 A CN 201710867689A CN 107814587 A CN107814587 A CN 107814587A
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China
Prior art keywords
coat enamel
ink
glaze
rid
preparation
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Pending
Application number
CN201710867689.1A
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Chinese (zh)
Inventor
殷波
张联炮
刘润鹏
张继通
陈维金
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong King Lion Ceramic Technology Co Ltd
Original Assignee
Shandong King Lion Ceramic Technology Co Ltd
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Priority to CN201710867689.1A priority Critical patent/CN107814587A/en
Publication of CN107814587A publication Critical patent/CN107814587A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61Coating or impregnation
    • C04B41/70Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • C04B41/71Coating or impregnation for obtaining at least two superposed coatings having different compositions at least one coating being an organic material

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Structural Engineering (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The present invention relates to a kind of preparation method of seven bright clouds ink stone, comprise the following steps:Shi Shui → applying ground-coat enamel → applies cover-coat enamel → get rid of a glaze → ink-jet → roller printing → and gets rid of mica sheet → firing → deburring.In terms of weight fraction, ground-coat enamel formula:Potassium feldspar 25% 30%, albite 15% 20%, quartz 15% 20%, calcined earth 5% 8%, pyrophillite 20% 25%, clay 15% 20%, talcum 5% 10%, trimerization 0.5% and cellulose 0.1%.It is simple, single that this technique solves common Antique Imitation Tiles pattern, seven bright cloud ink stone patterns of the invention be ink-jetting pattern is added with roller printing pattern get rid of a glaze handicraft, get rid of mica blade technolgy be combined, collocation naturally, the pattern of each tile is not easy, fantasy is natural, unparalleled.

Description

The preparation method of seven bright cloud ink stones
Technical field
The present invention relates to a kind of preparation method of seven bright clouds ink stone.
Background technology
Common Antique Imitation Tiles texture on the market is stiff, pattern is single, and one kind is ink-jetting pattern, another screen printing map brushing Case.Brick face effect solid feel is not strong, is easily copied by other producers, and brick surface hardness is not high, cut easily occurs;Antifouling grade Low (highest only has three-level), its manufacture craft are as follows:
Common Antique Imitation Tiles typically have two kinds of manufacture crafts, and step is as follows:
The first:Shi Shui-→ applies cover-coat enamel-→ ink-jet turk-→ firing-→ deburring
Second:Shi Shui-→ applies cover-coat enamel-→ screen printing-→ firing-→ deburring.
The content of the invention
It is an object of the invention to provide a kind of preparation method of seven bright clouds ink stone, and it is simple, single to solve common Antique Imitation Tiles pattern One, seven bright cloud ink stone patterns of the invention are to add ink-jetting pattern with roller printing pattern get rid of a glaze handicraft, get rid of mica blade technolgy phase With reference to, arrange in pairs or groups naturally, the pattern of each tile is not easy, fantasy is natural, unparalleled.
The preparation method of seven bright cloud ink stones of the invention, comprises the following steps:
Shi Shui → applying ground-coat enamel → applies cover-coat enamel → get rid of a glaze → ink-jet → roller printing → and gets rid of mica sheet → firing → deburring.
In terms of weight fraction, ground-coat enamel formula:Potassium feldspar 25%-30%, albite 15%-20%, quartzy 15%-20%, Calcined earth 5%-8%, pyrophillite 20%-25%, clay 15%-20%, talcum 5%-10%, trimerization 0.5% and cellulose 0.1%.
In terms of weight fraction, cover-coat enamel formula:Potassium feldspar 10-18%, albite 20-25%, calcite 10-18%, oxidation Zinc 3-5%, barium carbonate 3-5%, diamond spar 15-20%, calcined earth 3-5%, clay 13-18%, mullite 2-5%, trimerization 0.1- 0.5% and cellulose 0.1-0.3%.
In terms of weight fraction, cover-coat enamel formula:Potassium feldspar 15%, albite 22%, calcite 15%, zinc oxide 4%, carbonic acid Barium 4%, diamond spar 18%, calcined earth 4%, clay 15%, mullite 3%, trimerization 0.3% and cellulose 0.15%.
In terms of weight fraction, glaze formula is put:Potassium feldspar 40%-50%, frit 20%-25%, zinc 3%-5%, calcite 3%-6%, clay 10%-15%, quartzy 5%-10%, calcined earth 5%-10%.
In terms of weight fraction, glaze formula is put:Potassium feldspar 50%, frit 20%, zinc 5%, calcite 5%, clay 10%, stone English 5%, calcined earth 5%.
In terms of weight fraction, roller printing formula:Cellulose 1.0-2.0%, water 98.0-99.0%.
In terms of weight fraction, roller printing formula:Cellulose 1.5%, water 98.5%.
In terms of weight fraction, mica slice prescription is got rid of:Cellulose 0.3-0.8%, water 99.0-99.5% and mica sheet 0.2- 0.4%.
In terms of weight fraction, mica slice prescription is got rid of:Cellulose 0.5%, water 99.2% and mica sheet 0.3%.
The preparation method of seven described bright cloud ink stones, step are as follows:
(1) ground-coat enamel is applied after applying water:Ground-coat enamel raw mill fineness is crossed into 30-350 mesh sieves, sinks rotten 20-25 hours, ground-coat enamel is used Cover clock slip shower is poured on the base substrate after having applied water;
(2) cover-coat enamel is applied:Cover-coat enamel raw mill fineness is crossed into 300-350 mesh sieves, after heavy rotten 20-25 hours, by cover-coat enamel clock Cover slip shower is poured on the brick face for having applied ground-coat enamel;
(3) glaze is got rid of:A glaze raw mill fineness is crossed into 300-350 mesh sieves, sinks after rotten 20-25 hours, a glaze is thrown to Apply on the brick face of cover-coat enamel;
(4) ink-jet:Pattern is sprayed onto on the brick face with a glaze with ink jet printer;
(5) roller printing:The additional color of roller printing, stir, fancy glaze is printed onto to the figure of ink-jet with roller printing machine In case;
(6) mica sheet is got rid of:Stirred with a mixing bowl, mica glaze is thrown on the brick face of the completion of roller printing with case is got rid of;
(7) fire;
(8) deburring.
During applying ground-coat enamel, applying cover-coat enamel, get rid of a glaze, husky lost what raw material crossed that fineness of grind crosses after 300-350 mesh sieves respectively For 0.4-0.6 grams/100ml.
In step (5), mixing time is 25-40 minutes.
In step (6), mixing time is 25-40 minutes.
The antifouling grade of ceramic tile can be improved by applying ground-coat enamel.The general common antifouling grade three-level of Antique Imitation Tiles highest;The present invention seven Bright cloud ink stone adds applies ground-coat enamel technique together, and its antifouling grade reaches level Four.Because having the covering of ground-coat enamel by the most exhaust pore pressures of base substrate Below, so brick face steam vent is less, antifouling higher grade.
The bright cloud ink stone cover-coat enamel of this technique seven, because in formula add 15-20wt% diamond spar, cover-coat enamel hardness can reach seven grades with On.Common Antique Imitation Tiles cover-coat enamel intensity is at maximum up to Pyatyi.
This technique uses and gets rid of the concave-convex sense that a glaze mode improves brick face, not only three-dimensional but also anti-skidding.
This technique adds gets rid of mica blade technolgy together, because mica sheet is after 1000 DEG C of -1200 DEG C of firings of high temperature, can be formed black Color, the sparklet to glitter, by mica sheet with getting rid of on the pattern of the random NATURAL DISTRIBUTION of case, by the natural pattern brocade of fantasy Add flower, it is more perfect, show the work of the work of nature of the Nature fully.
Compared with prior art, the invention has the advantages that:
It is simple, single that this technique solves common Antique Imitation Tiles pattern, seven bright cloud ink stone patterns of the invention be by ink-jetting pattern with Roller printing pattern, which adds, to be got rid of a glaze handicraft, gets rid of mica blade technolgy and be combined, arrange in pairs or groups naturally, and the pattern of each tile is not easy, fantasy It is natural, unparalleled.
Embodiment
With reference to embodiment, the present invention is described further.
Mass fraction is mass fraction in the following example.
Embodiment 1
The preparation method of seven bright cloud ink stones of the invention, comprises the following steps:
Shi Shui → applying ground-coat enamel → applies cover-coat enamel → get rid of a glaze → ink-jet → roller printing → and gets rid of mica sheet → firing → deburring.
Wherein, ground-coat enamel formula:It is potassium feldspar 25%, albite 20%, quartz 20%, calcined earth 5%, pyrophillite 25%, viscous Soil 15%%, talcum 10%, trimerization 0.5% and cellulose 0.1%.
Cover-coat enamel formula:Potassium feldspar 15%, albite 22%, calcite 15%, zinc oxide 4%, barium carbonate 4%, diamond spar 18%th, calcined earth 4%, clay 15%, mullite 3%, trimerization 0.3% and cellulose 0.15%.
Point glaze formula:Potassium feldspar 50%, frit 20%, zinc 5%, calcite 3%, clay 15%, quartz 5%, calcined earth 10%.
Roller printing formula:Cellulose 1.5%, water 98.5%.
Get rid of mica slice prescription:Cellulose 0.5%, water 99.2%, mica sheet 0.3%.
The preparation method of seven bright cloud ink stones, step are as follows:
(1) ground-coat enamel is applied after applying water:By ground-coat enamel raw mill fineness cross 325 mesh sieves, 0.6 gram/100ml, sink rotten 24 hours, will Ground-coat enamel is poured on the base substrate after having applied water with cover clock slip shower;
(2) cover-coat enamel is applied:By cover-coat enamel raw mill fineness cross 325 mesh sieves, 0.4 gram/100ml, after sinking rotten 24 hours, by cover-coat enamel Poured with bell jar slip shower on the brick face for having applied ground-coat enamel;
(3) glaze is got rid of:Will the mesh of point glaze fineness of grind 325,0.5 gram/100ml, sink it is rotten 24 hours after, a glaze is thrown to and applied On the brick face of cover-coat enamel;
(4) ink-jet:Pattern is sprayed onto on the brick face with a glaze with ink jet printer;
(5) roller printing:Roller prints the additional colorant of glaze, is stirred with a mixing bowl, is printed onto fancy glaze with roller printing machine On the pattern of ink-jet;
(6) mica sheet is got rid of:Stirred with a mixing bowl, mica glaze is thrown on the brick face of the completion of roller printing with case is got rid of;
(7) fire;
(8) deburring.
In step (5), mixing time is 30 minutes.
In step (6), mixing time is 30 minutes.
Embodiment 2
The preparation method of seven bright cloud ink stones of the invention, comprises the following steps:
Shi Shui → applying ground-coat enamel → applies cover-coat enamel → get rid of a glaze → ink-jet → roller printing → and gets rid of mica sheet → firing → deburring.
Wherein, ground-coat enamel formula:It is potassium feldspar 25%, albite 20%, quartz 20%, calcined earth 5%, pyrophillite 25%, viscous Soil 15%%, talcum 10%, trimerization 0.5% and cellulose 0.1%.
Cover-coat enamel formula:Potassium feldspar 15%, albite 22%, calcite 15%, zinc oxide 4%, barium carbonate 4%, diamond spar 18%th, calcined earth 4%, clay 15%, mullite 3%, trimerization 0.3% and cellulose 0.15%.
Point glaze formula:Potassium feldspar 50%, frit 20%, zinc 5%, calcite 3%, clay 15%, quartz 5%, calcined earth 10%.
Roller printing formula:Cellulose 1.2%, water 98.8%.
Get rid of mica slice prescription:Cellulose 0.6%, water 99.0%, mica sheet 0.4%.
The preparation method of seven bright cloud ink stones, step are as follows:
(1) ground-coat enamel is applied after applying water:By ground-coat enamel raw mill fineness cross 300 mesh sieves, 0.6 gram/100ml, sink rotten 25 hours, will Ground-coat enamel is poured on the base substrate after having applied water with cover clock slip shower;
(2) cover-coat enamel is applied:By cover-coat enamel raw mill fineness cross 300 mesh sieves, 0.4 gram/100ml, after sinking rotten 25 hours, by cover-coat enamel Poured with bell jar slip shower on the brick face for having applied ground-coat enamel;
(3) glaze is got rid of:Will the mesh of point glaze fineness of grind 300,0.5 gram/100ml, sink it is rotten 25 hours after, a glaze is thrown to and applied On the brick face of cover-coat enamel;
(4) ink-jet:Pattern is sprayed onto on the brick face with a glaze with ink jet printer;
(5) roller printing:Roller prints the additional colorant of glaze, is stirred with a mixing bowl, is printed onto fancy glaze with roller printing machine On the pattern of ink-jet;
(6) mica sheet is got rid of:Stirred with a mixing bowl, mica glaze is thrown on the brick face of the completion of roller printing with case is got rid of;
(7) fire;
(8) deburring.
In step (5), mixing time is 40 minutes.
In step (6), mixing time is 40 minutes.
Embodiment 3
The preparation method of seven bright cloud ink stones of the invention, comprises the following steps:
Shi Shui → applying ground-coat enamel → applies cover-coat enamel → get rid of a glaze → ink-jet → roller printing → and gets rid of mica sheet → firing → deburring.
Wherein, ground-coat enamel formula:It is potassium feldspar 25%, albite 20%, quartz 20%, calcined earth 5%, pyrophillite 25%, viscous Soil 15%%, talcum 10%, trimerization 0.5% and cellulose 0.1%.
Cover-coat enamel formula:Potassium feldspar 15%, albite 22%, calcite 15%, zinc oxide 4%, barium carbonate 4%, diamond spar 18%th, calcined earth 4%, clay 15%, mullite 3%, trimerization 0.3% and cellulose 0.15%.
Point glaze formula:Potassium feldspar 50%, frit 20%, zinc 5%, calcite 3%, clay 15%, quartz 5%, calcined earth 10%.
Roller printing formula:Cellulose 1.5%, water 98.5%.
Get rid of mica slice prescription:Cellulose 0.5%, water 99.2%, mica sheet 0.3%.
The preparation method of seven bright cloud ink stones, step are as follows:
(1) ground-coat enamel is applied after applying water:By ground-coat enamel raw mill fineness cross 350 mesh sieves, 0.6 gram/100ml, sink rotten 20 hours, will Ground-coat enamel is poured on the base substrate after having applied water with cover clock slip shower;
(2) cover-coat enamel is applied:By cover-coat enamel raw mill fineness cross 350 mesh sieves, 0.5 gram/100ml, after sinking rotten 20 hours, by cover-coat enamel Poured with bell jar slip shower on the brick face for having applied ground-coat enamel;
(3) glaze is got rid of:Will the mesh of point glaze fineness of grind 350,0.4 gram/100ml, sink it is rotten 20 hours after, a glaze is thrown to and applied On the brick face of cover-coat enamel;
(4) ink-jet:Pattern is sprayed onto on the brick face with a glaze with ink jet printer;
(5) roller printing:Roller prints the additional colorant of glaze, is stirred with a mixing bowl, is printed onto fancy glaze with roller printing machine On the pattern of ink-jet;
(6) mica sheet is got rid of:Stirred with a mixing bowl, mica glaze is thrown on the brick face of the completion of roller printing with case is got rid of;
(7) fire;
(8) deburring.
In step (5), mixing time is 25 minutes.
In step (6), mixing time is 25 minutes.

Claims (10)

1. a kind of preparation method of seven bright clouds ink stone, it is characterised in that comprise the following steps:
Shi Shui → applying ground-coat enamel → applies cover-coat enamel → get rid of a glaze → ink-jet → roller printing → and gets rid of mica sheet → firing → deburring.
2. the preparation method of seven bright clouds ink stone according to claim 1, it is characterised in that in terms of weight fraction, ground-coat enamel is matched somebody with somebody Side:Potassium feldspar 25%-30%, albite 15%-20%, quartzy 15%-20%, calcined earth 5%-8%, pyrophillite 20%- 25%th, clay 15%-20%, talcum 5%-10%, trimerization 0.5% and cellulose 0.1%.
3. the preparation method of seven bright clouds ink stone according to claim 1, it is characterised in that in terms of weight fraction, cover-coat enamel is matched somebody with somebody Side:Potassium feldspar 10-18%, albite 20-25%, calcite 10-18%, zinc oxide 3-5%, barium carbonate 3-5%, diamond spar 15- 20%th, calcined earth 3-5%, clay 13-18%, mullite 2-5%, trimerization 0.1-0.5% and cellulose 0.1-0.3%.
4. the preparation method of seven bright clouds ink stone according to claim 1, it is characterised in that in terms of weight fraction, point glaze is matched somebody with somebody Side:Potassium feldspar 40%-50%, frit 20%-25%, zinc 3%-5%, calcite 3%-6%, clay 10%-15%, quartz 5%-10%, calcined earth 5%-10%.
5. the preparation method of seven bright clouds ink stone according to claim 1, it is characterised in that in terms of weight fraction, roller print Flower formula:Cellulose 1.0-2.0%, water 98.0-99.0%;In terms of weight fraction, mica slice prescription is got rid of:Cellulose 0.3- 0.8%th, water 99.0-99.5% and mica sheet 0.2-0.4%.
6. the preparation method of seven bright clouds ink stone according to claim 1, it is characterised in that in terms of weight fraction, get rid of mica Slice prescription:Cellulose 0.5%, water 99.2% and mica sheet 0.3%.
7. the preparation method of seven bright clouds ink stone according to claim 1, it is characterised in that step is as follows:
(1) ground-coat enamel is applied:Ground-coat enamel raw mill fineness is crossed 30-350 mesh sieves by Shi Shuihou, is sunk rotten 20-25 hours, by ground-coat enamel cover clock Slip shower is poured on the base substrate after having applied water;
(2) cover-coat enamel is applied:Cover-coat enamel raw mill fineness is crossed into 300-350 mesh sieves, sinks after rotten 20-25 hours, cover-coat enamel is drenched with bell jar Enamal organ is poured on the brick face for having applied ground-coat enamel;
(3) glaze is got rid of:A glaze raw mill fineness is crossed into 300-350 mesh sieves, sinks after rotten 20-25 hours, a glaze is thrown to and applied On the brick face of cover-coat enamel;
(4) ink-jet:Pattern is sprayed onto on the brick face with a glaze with ink jet printer;
(5) roller printing:Fancy glaze, is printed onto on the pattern of ink-jet by the additional color of roller printing, stirring with roller printing machine;
(6) mica sheet is got rid of:Stirred with a mixing bowl, mica glaze is thrown on the brick face of the completion of roller printing with case is got rid of;
(7) fire;
(8) deburring.
8. the preparation method of seven bright clouds ink stone according to claim 7, it is characterised in that apply ground-coat enamel, apply cover-coat enamel, get rid of a glaze During, it is 0.4-0.6 grams/100ml that raw material is crossed into husky lose that fineness of grind crossed after 300-350 mesh sieves respectively.
9. the preparation method of seven bright clouds ink stone according to claim 7, it is characterised in that in step (5), mixing time is 25-40 minutes.
10. the preparation method of seven bright clouds ink stone according to claim 7, it is characterised in that in step (6), mixing time For 25-40 minutes.
CN201710867689.1A 2017-09-22 2017-09-22 The preparation method of seven bright cloud ink stones Pending CN107814587A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110550958A (en) * 2019-09-17 2019-12-10 广东新润成陶瓷有限公司 Fine, soft and matte black brick and preparation method thereof

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US8628611B2 (en) * 2010-03-05 2014-01-14 Lamberti Spa Rheology modifier for ceramic glazes
CN105565907A (en) * 2015-12-23 2016-05-11 蒙娜丽莎集团股份有限公司 Production method of flambe crystal pattern seeding color-fixing ceramic tile
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Publication number Priority date Publication date Assignee Title
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US8628611B2 (en) * 2010-03-05 2014-01-14 Lamberti Spa Rheology modifier for ceramic glazes
CN105565907A (en) * 2015-12-23 2016-05-11 蒙娜丽莎集团股份有限公司 Production method of flambe crystal pattern seeding color-fixing ceramic tile
CN105801175A (en) * 2016-03-04 2016-07-27 浙江根根陶瓷有限公司 Antibacterial ceramic tiles and production method thereof
CN105801176A (en) * 2016-03-15 2016-07-27 佛山市三水凯利莱工艺制品有限公司 Once-fired metal glaze surface deep-processing method

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110550958A (en) * 2019-09-17 2019-12-10 广东新润成陶瓷有限公司 Fine, soft and matte black brick and preparation method thereof

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Application publication date: 20180320