CN107662154A - A kind of vibropolish technique of domestic ceramics tableware - Google Patents
A kind of vibropolish technique of domestic ceramics tableware Download PDFInfo
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- CN107662154A CN107662154A CN201710773882.9A CN201710773882A CN107662154A CN 107662154 A CN107662154 A CN 107662154A CN 201710773882 A CN201710773882 A CN 201710773882A CN 107662154 A CN107662154 A CN 107662154A
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- Prior art keywords
- abrasive material
- vibropolish
- crockery
- technique
- polishing
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- 239000000919 ceramic Substances 0.000 title claims abstract description 37
- 238000000034 method Methods 0.000 title claims abstract description 28
- 239000003082 abrasive agent Substances 0.000 claims abstract description 52
- 238000005498 polishing Methods 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 31
- 238000009413 insulation Methods 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 18
- 230000008569 process Effects 0.000 claims description 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 13
- 239000000843 powder Substances 0.000 claims description 12
- 108010020346 Polyglutamic Acid Proteins 0.000 claims description 11
- 229920002643 polyglutamic acid Polymers 0.000 claims description 11
- 229910000278 bentonite Inorganic materials 0.000 claims description 8
- 239000000440 bentonite Substances 0.000 claims description 8
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 8
- 238000010304 firing Methods 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 7
- 238000007517 polishing process Methods 0.000 claims description 7
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- 150000001768 cations Chemical class 0.000 claims description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 1
- 238000005469 granulation Methods 0.000 claims 1
- 230000003179 granulation Effects 0.000 claims 1
- 239000007921 spray Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 4
- 239000004575 stone Substances 0.000 abstract description 4
- 238000000227 grinding Methods 0.000 abstract description 2
- 230000017525 heat dissipation Effects 0.000 abstract description 2
- 235000012216 bentonite Nutrition 0.000 description 13
- 238000002156 mixing Methods 0.000 description 11
- 239000003595 mist Substances 0.000 description 10
- 230000004048 modification Effects 0.000 description 7
- 238000012986 modification Methods 0.000 description 7
- 235000010215 titanium dioxide Nutrition 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 239000002808 molecular sieve Substances 0.000 description 5
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 5
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 5
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 4
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- UUORTJUPDJJXST-UHFFFAOYSA-N n-(2-hydroxyethyl)prop-2-enamide Chemical class OCCNC(=O)C=C UUORTJUPDJJXST-UHFFFAOYSA-N 0.000 description 4
- 229910052573 porcelain Inorganic materials 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- JMWGZSWSTCGVLX-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol;2-methylprop-2-enoic acid Chemical class CC(=C)C(O)=O.CC(=C)C(O)=O.CC(=C)C(O)=O.CCC(CO)(CO)CO JMWGZSWSTCGVLX-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- -1 polypropylene Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- ZLXYJUZXHDRQMJ-UHFFFAOYSA-N 2-ethyl-2-(hydroxymethyl)propane-1,3-diol prop-1-ene Chemical group C=CC.C=CC.C=CC.C(O)C(CC)(CO)CO ZLXYJUZXHDRQMJ-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
- B24B31/00—Machines or devices designed for polishing or abrading surfaces on work by means of tumbling apparatus or other apparatus in which the work and/or the abrasive material is loose; Accessories therefor
- B24B31/06—Machines or devices designed for polishing or abrading surfaces on work by means of tumbling apparatus or other apparatus in which the work and/or the abrasive material is loose; Accessories therefor involving oscillating or vibrating containers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/02—Polishing compositions containing abrasives or grinding agents
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Insulating Bodies (AREA)
Abstract
The invention discloses a kind of vibropolish technique of domestic ceramics tableware, it is related to domestic ceramics technical field, including following operation:(1) prepared by abrasive material, (2) abrasive material humidification, (3) crockery vibropolish.The present invention is to make abrasive material by oneself as crockery vibropolish grinding-material, and made abrasive size is in 2mm, relative to routinely using having the characteristics of rapid heat dissipation, polishing efficiency is high for grinding stone, greatling save and polish the used time;As little as 0.03 μm of the Ra values of crockery after polishing can be made by the vibropolish technique, the feel and glossiness of crockery are effectively improved, so as to improve the outgoing of crockery.
Description
Technical field:
The present invention relates to domestic ceramics technical field, and in particular to a kind of vibropolish technique of domestic ceramics tableware.
Background technology:
Domestic ceramics, tableware or family's porcelain are also referred to, as the term suggests refer to that life essential in people's daily life is used
Porcelain.Most important one kind is exactly crockery in domestic ceramics, is widely used in daily life, demand is big.
Crockery is needed by polishing after the completion of base substrate firing, to improve its surface flatness, is gone chamfering, is gone
Flash, gloss polishing, so as to improve feel and surface gloss, and beneficial to the progress of follow-up glazing process.At present, typically adopt
Vibropolish is carried out to crockery surface with vibratory finishing machine, vibratory finishing machine is built with grinding-material, in order to reduce cost,
Many Ceramic manufacturing factories are put into crockery in vibratory finishing machine, the stone under effect of vibration using stone as grinding-material
Tableware surface rub to reach the effect of polishing.Although the cost of this mode is relatively low, polishing efficiency is also low, and easily damages
Bad crockery, increase scrappage.
The content of the invention:
The technical problems to be solved by the invention are that providing one kind can distribute quickly heat produced by polishing and improve
Polishing efficiency, enhancing polishing effect and the vibropolish technique for mitigating the domestic ceramics tableware of polishing scrappage.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of vibropolish technique of domestic ceramics tableware, including following operation:
(1) prepared by abrasive material:By ceramic, bentonite, polyglutamic acid, molecular screen primary powder, nanometer titanium dioxide, cation
Polyacrylamide, water are fitted into vacuum bag after being sufficiently mixed in proportion, and evacuated processing is after standing 5- in -15 DEG C of environment
8h, 110-120 DEG C of insulation is then heated to 5-10 DEG C/min programming rate and mixes to moisture and volatilizes, gained mixture is sent into
In granulator, particle diameter 2mm abrasive material is made;
(2) abrasive material humidifies:Above-mentioned made abrasive material is added in vibratory finishing machine, and into abrasive material, discontinuity is sprayed by nozzle
Enter clear water, abrasive material mass water content in polishing process is controlled 0.5%;
(3) crockery vibropolish:Crockery after firing is put into vibratory finishing machine, vibropolish acc power
1.5-5.5kW, motor speed 1400-1450r/min, reach after polishing requires and take out crockery.
The ceramic, bentonite, polyglutamic acid, molecular screen primary powder, nanometer titanium dioxide, cation polypropylene acyl
Amine, the weight ratio of water are 55-65:5-10:5-10:1-5:1-5:1-5:50-150.
The polyglutamic acid selects water process level.
The ceramic passes through modification before using, and its method of modifying is:Ceramic is first heated to 120-130
DEG C insulation mixing 10min, add allyl glycidyl ether and allyl polyethenoxy ether, continue 120-130 DEG C insulation
30min is mixed, 120-130 DEG C of insulation mixing 30min, gained mixture natural cooling are again heated to after being stored at room temperature 15min
To room temperature, micro mist most is made through micronizer afterwards, produces modified ceramic micro mist.
The weight ratio of the ceramic, allyl glycidyl ether and allyl polyethenoxy ether is 55-65:5-10:
5-10。
Atlapulgite is made in the modified processing of bentonite, and its preparation method is:First by bentonite at 450-500 DEG C
3h is calcined, after naturally cool to being taken out after 115-125 DEG C, and adds N- hydroxyethyl acrylamides and trimethylolpropane tris propylene
Acid esters, microwave treater microwave treatment 10min is utilized after being sufficiently mixed, continue microwave treatment 10min after standing 10min, stand
Microwave treatment 10min again after 10min, gained mixture is transferred to sealing and standing 2h in 0-5 DEG C of environment immediately, then with 5-10
DEG C/min programming rate is heated to 115-125 DEG C of insulation mixing 15min, through naturally cooling to room temperature, finally utilize Ultramicro-powder
Micro mist is made in broken machine, produces atlapulgite.
The weight ratio of the bentonite, N- hydroxyethyl acrylamides and trimethylolpropane trimethacrylate is 5-10:
0.5-2:0.5-2。
The condition of work of the microwave treater is microwave frequency 2450MHz, power output 700W.
The modification of ceramic and the preparation of atlapulgite all refer to chemical crosslink reaction, including the self-crosslinking of monomer and
With being cross-linked with each other for another monomer, the product for being chemically crosslinked formation merges with ceramic or bentonite immediately, with enhancing
The polishing performance and ceramic of made modified ceramic micro mist and the comixing compatibility of abrasive material shaping assistant, and strengthen active white
Processability of the soil as abrasive material shaping assistant.
The beneficial effects of the invention are as follows:The present invention is to make abrasive material by oneself as crockery vibropolish grinding-material, institute
Abrasive size processed is in 2mm, relative to routinely using having the characteristics of rapid heat dissipation, polishing efficiency is high for grinding stone, saving significantly
Save the polishing used time;And caused heat in process of lapping is dispersed by the control of abrasive material water content immediately, and play lubrication abrasive material
Effect, avoid overmastication of the abrasive material to crockery;The Ra of crockery after polishing can be made by the vibropolish technique
As little as 0.03 μm of value, the feel and glossiness of crockery are effectively improved, so as to improve the outgoing of crockery.
Embodiment:
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below
Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
(1) prepared by abrasive material:By 65kg ceramics, 5kg bentonites, 10kg water process levels polyglutamic acid, 1kg molecular sieves
Former powder, 2kg nanometer titanium dioxides, 1kg PAMCs, 84kg water are fitted into vacuum bag after being sufficiently mixed in proportion, warp
Then vacuumize process is heated to 110-120 DEG C of insulation after standing 8h in -15 DEG C of environment with 5-10 DEG C/min programming rate
Mix to moisture and volatilize, gained mixture is sent into granulator, and particle diameter 2mm abrasive material is made;
(2) abrasive material humidifies:Above-mentioned made abrasive material is added in vibratory finishing machine, and into abrasive material, discontinuity is sprayed by nozzle
Enter clear water, abrasive material mass water content in polishing process is controlled 0.5%;
(3) crockery vibropolish:Crockery after firing is put into vibratory finishing machine, vibropolish acc power
3.0kW, motor speed 1450r/min, reach after polishing requires and take out crockery.
Embodiment 2
(1) prepared by abrasive material:By 65kg ceramics, 10kg bentonites, 5kg water process levels polyglutamic acid, 2kg molecular sieves
Former powder, 1kg nanometer titanium dioxides, 2kg PAMCs, 85kg water are fitted into vacuum bag after being sufficiently mixed in proportion, warp
Then vacuumize process is heated to 110-120 DEG C of insulation after standing 8h in -15 DEG C of environment with 5-10 DEG C/min programming rate
Mix to moisture and volatilize, gained mixture is sent into granulator, and particle diameter 2mm abrasive material is made;
(2) abrasive material humidifies:Above-mentioned made abrasive material is added in vibratory finishing machine, and into abrasive material, discontinuity is sprayed by nozzle
Enter clear water, abrasive material mass water content in polishing process is controlled 0.5%;
(3) crockery vibropolish:Crockery after firing is put into vibratory finishing machine, vibropolish acc power
3.0kW, motor speed 1450r/min, reach after polishing requires and take out crockery.
Embodiment 3
(1) prepared by abrasive material:By 65kg ceramics, 10kg bentonites, 5kg water process levels polyglutamic acid, 2kg molecular sieves
Former powder, 1kg nanometer titanium dioxides, 2kg PAMCs, 85kg water are fitted into vacuum bag after being sufficiently mixed in proportion, warp
Then vacuumize process is heated to 110-120 DEG C of insulation after standing 8h in -15 DEG C of environment with 5-10 DEG C/min programming rate
Mix to moisture and volatilize, gained mixture is sent into granulator, and particle diameter 2mm abrasive material is made;
(2) abrasive material humidifies:Above-mentioned made abrasive material is added in vibratory finishing machine, and into abrasive material, discontinuity is sprayed by nozzle
Enter clear water, abrasive material mass water content in polishing process is controlled 0.5%;
(3) crockery vibropolish:Crockery after firing is put into vibratory finishing machine, vibropolish acc power
3.0kW, motor speed 1450r/min, reach after polishing requires and take out crockery.
Alta-mud modification:10kg bentonites are first calcined into 3h at 450-500 DEG C, after naturally cool to 115-125 DEG C
After take out, and 1kg N- hydroxyethyl acrylamides and 2kg trimethylolpropane trimethacrylates are added, using micro- after being sufficiently mixed
Wave frequency rate 2450MHz, power output 700W microwave treater microwave treatment 10min, continue microwave treatment after standing 10min
Microwave treatment 10min, gained mixture are transferred to sealing and standing 2h in 0-5 DEG C of environment immediately again after 10min, standing 10min, so
115-125 DEG C of insulation mixing 15min, through naturally cooling to room temperature, last profit are heated to 5-10 DEG C/min programming rate afterwards
Micro mist is made with micronizer, produces atlapulgite.
Embodiment 4
(1) prepared by abrasive material:By 65kg ceramics, 10kg bentonites, 5kg water process levels polyglutamic acid, 2kg molecular sieves
Former powder, 1kg nanometer titanium dioxides, 2kg PAMCs, 85kg water are fitted into vacuum bag after being sufficiently mixed in proportion, warp
Then vacuumize process is heated to 110-120 DEG C of insulation after standing 8h in -15 DEG C of environment with 5-10 DEG C/min programming rate
Mix to moisture and volatilize, gained mixture is sent into granulator, and particle diameter 2mm abrasive material is made;
(2) abrasive material humidifies:Above-mentioned made abrasive material is added in vibratory finishing machine, and into abrasive material, discontinuity is sprayed by nozzle
Enter clear water, abrasive material mass water content in polishing process is controlled 0.5%;
(3) crockery vibropolish:Crockery after firing is put into vibratory finishing machine, vibropolish acc power
3.0kW, motor speed 1450r/min, reach after polishing requires and take out crockery.
The modification of ceramic:65kg ceramics are first heated to 120-130 DEG C of insulation mixing 10min, add 5kg
Allyl glycidyl ether and 5kg allyl polyethenoxy ethers, continue, in 120-130 DEG C of insulation mixing 30min, to be stored at room temperature
120-130 DEG C of insulation mixing 30min is again heated to after 15min, gained mixture naturally cools to room temperature, most afterwards through Ultramicro-powder
Micro mist is made in broken machine, produces modified ceramic micro mist.
Embodiment 5
(1) prepared by abrasive material:By 65kg ceramics, 10kg bentonites, 5kg water process levels polyglutamic acid, 2kg molecular sieves
Former powder, 1kg nanometer titanium dioxides, 2kg PAMCs, 85kg water are fitted into vacuum bag after being sufficiently mixed in proportion, warp
Then vacuumize process is heated to 110-120 DEG C of insulation after standing 8h in -15 DEG C of environment with 5-10 DEG C/min programming rate
Mix to moisture and volatilize, gained mixture is sent into granulator, and particle diameter 2mm abrasive material is made;
(2) abrasive material humidifies:Above-mentioned made abrasive material is added in vibratory finishing machine, and into abrasive material, discontinuity is sprayed by nozzle
Enter clear water, abrasive material mass water content in polishing process is controlled 0.5%;
(3) crockery vibropolish:Crockery after firing is put into vibratory finishing machine, vibropolish acc power
3.0kW, motor speed 1450r/min, reach after polishing requires and take out crockery.
The modification of ceramic:65kg ceramics are first heated to 120-130 DEG C of insulation mixing 10min, add 5kg
Allyl glycidyl ether and 5kg allyl polyethenoxy ethers, continue, in 120-130 DEG C of insulation mixing 30min, to be stored at room temperature
120-130 DEG C of insulation mixing 30min is again heated to after 15min, gained mixture naturally cools to room temperature, most afterwards through Ultramicro-powder
Micro mist is made in broken machine, produces modified ceramic micro mist.
Alta-mud modification:10kg bentonites are first calcined into 3h at 450-500 DEG C, after naturally cool to 115-125 DEG C
After take out, and 1kg N- hydroxyethyl acrylamides and 2kg trimethylolpropane trimethacrylates are added, using micro- after being sufficiently mixed
Wave frequency rate 2450MHz, power output 700W microwave treater microwave treatment 10min, continue microwave treatment after standing 10min
Microwave treatment 10min, gained mixture are transferred to sealing and standing 2h in 0-5 DEG C of environment immediately again after 10min, standing 10min, so
115-125 DEG C of insulation mixing 15min, through naturally cooling to room temperature, last profit are heated to 5-10 DEG C/min programming rate afterwards
Micro mist is made with micronizer, produces atlapulgite.
Embodiment 6
Technique described in embodiment 1-5 is utilized respectively to carrying out vibropolish processing, mill with 20 crockeries of batch same specification
Expect that dosage is identical, polishing time 20min, the Ra values of crockery, and average after measure polishing, as shown in table 1, set with
Reference examples of the alumina porcelain of same specification as abrasive material.
Polishing effect of the technique to crockery described in the embodiment 1-5 of table 1
| Measure project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Reference examples |
| Ra/μm | 0.10 | 0.09 | 0.07 | 0.05 | 0.03 | 0.15 |
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (3)
1. a kind of vibropolish technique of domestic ceramics tableware, it is characterised in that including following operation:
(1) prepared by abrasive material:By ceramic, bentonite, polyglutamic acid, molecular screen primary powder, nanometer titanium dioxide, cation poly- third
Acrylamide, water are fitted into vacuum bag after being sufficiently mixed in proportion, and evacuated processing is after standing 5-8h in -15 DEG C of environment, so
It is heated to 110-120 DEG C of insulation afterwards with 5-10 DEG C/min programming rate to mix to moisture and volatilize, gained mixture is sent into granulation
In machine, particle diameter 2mm abrasive material is made;
(2) abrasive material humidifies:Above-mentioned made abrasive material is added in vibratory finishing machine, and into abrasive material, discontinuity sprays into clearly by nozzle
Water, abrasive material mass water content in polishing process is set to control 0.5%;
(3) crockery vibropolish:Crockery after firing is put into vibratory finishing machine, vibropolish acc power 1.5-
5.5kW, motor speed 1400-1450r/min, reach after polishing requires and take out crockery.
2. the vibropolish technique of domestic ceramics tableware according to claim 1, it is characterised in that:The ceramic,
Bentonite, polyglutamic acid, molecular screen primary powder, nanometer titanium dioxide, PAMC, the weight ratio of water are 55-65:5-
10:5-10:1-5:1-5:1-5:50-150。
3. the vibropolish technique of domestic ceramics tableware according to claim 1, it is characterised in that:The polyglutamic acid
From water process level.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112192431A (en) * | 2020-10-09 | 2021-01-08 | 中至商贸(杭州)有限公司 | Tableware grinding device of stainless steel |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112192431A (en) * | 2020-10-09 | 2021-01-08 | 中至商贸(杭州)有限公司 | Tableware grinding device of stainless steel |
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Application publication date: 20180206 |