CN107473601A - A kind of ambetti and preparation method thereof - Google Patents
A kind of ambetti and preparation method thereof Download PDFInfo
- Publication number
- CN107473601A CN107473601A CN201710817867.XA CN201710817867A CN107473601A CN 107473601 A CN107473601 A CN 107473601A CN 201710817867 A CN201710817867 A CN 201710817867A CN 107473601 A CN107473601 A CN 107473601A
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- China
- Prior art keywords
- coating
- ambetti
- vacuum
- layer
- parts
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- Granted
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- 238000002360 preparation method Methods 0.000 title claims description 14
- 238000000576 coating method Methods 0.000 claims abstract description 127
- 239000011248 coating agent Substances 0.000 claims abstract description 123
- 239000011521 glass Substances 0.000 claims abstract description 82
- 239000000463 material Substances 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000010410 layer Substances 0.000 claims description 61
- 239000003795 chemical substances by application Substances 0.000 claims description 33
- 239000003973 paint Substances 0.000 claims description 25
- 238000007733 ion plating Methods 0.000 claims description 23
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 18
- 230000008595 infiltration Effects 0.000 claims description 12
- 238000001764 infiltration Methods 0.000 claims description 12
- 238000004381 surface treatment Methods 0.000 claims description 12
- 238000004140 cleaning Methods 0.000 claims description 10
- 239000004645 polyester resin Substances 0.000 claims description 10
- 229920001225 polyester resin Polymers 0.000 claims description 10
- 239000000047 product Substances 0.000 claims description 10
- 239000011247 coating layer Substances 0.000 claims description 9
- 239000000049 pigment Substances 0.000 claims description 9
- 235000015511 Liquidambar orientalis Nutrition 0.000 claims description 8
- 239000004870 Styrax Substances 0.000 claims description 8
- 235000000126 Styrax benzoin Nutrition 0.000 claims description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 8
- 230000003750 conditioning effect Effects 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 8
- 239000010936 titanium Substances 0.000 claims description 8
- 229910052719 titanium Inorganic materials 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 229910000838 Al alloy Inorganic materials 0.000 claims description 6
- 239000013530 defoamer Substances 0.000 claims description 6
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 6
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 4
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 4
- 238000007747 plating Methods 0.000 claims description 4
- 239000012466 permeate Substances 0.000 claims description 2
- 244000028419 Styrax benzoin Species 0.000 claims 1
- 238000009498 subcoating Methods 0.000 claims 1
- 239000002344 surface layer Substances 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract description 18
- 238000005187 foaming Methods 0.000 abstract description 18
- 239000000853 adhesive Substances 0.000 abstract description 13
- 230000001070 adhesive effect Effects 0.000 abstract description 13
- 230000000694 effects Effects 0.000 abstract description 4
- 238000005034 decoration Methods 0.000 abstract description 3
- 238000001771 vacuum deposition Methods 0.000 abstract description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- 238000007711 solidification Methods 0.000 description 16
- 230000008023 solidification Effects 0.000 description 16
- 241000736148 Styrax Species 0.000 description 7
- 238000005507 spraying Methods 0.000 description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 239000002318 adhesion promoter Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 239000007921 spray Substances 0.000 description 5
- 229920002799 BoPET Polymers 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- 239000002023 wood Substances 0.000 description 4
- OUPZKGBUJRBPGC-UHFFFAOYSA-N 1,3,5-tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound O=C1N(CC2OC2)C(=O)N(CC2OC2)C(=O)N1CC1CO1 OUPZKGBUJRBPGC-UHFFFAOYSA-N 0.000 description 3
- 229910052788 barium Inorganic materials 0.000 description 3
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 241000220317 Rosa Species 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000007590 electrostatic spraying Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical class CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000004506 ultrasonic cleaning Methods 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229920005372 Plexiglas® Polymers 0.000 description 1
- 229960000583 acetic acid Drugs 0.000 description 1
- UQZIWOQVLUASCR-UHFFFAOYSA-N alumane;titanium Chemical compound [AlH3].[Ti] UQZIWOQVLUASCR-UHFFFAOYSA-N 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid group Chemical group C(C1=CC=CC=C1)(=O)O WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000005337 ground glass Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/38—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal at least one coating being a coating of an organic material
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3639—Multilayers containing at least two functional metal layers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3649—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer made of metals other than silver
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
- C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
- C03C17/3684—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used for decoration purposes
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/25—Metals
- C03C2217/257—Refractory metals
- C03C2217/258—Ti, Zr, Hf
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/25—Metals
- C03C2217/27—Mixtures of metals, alloys
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/72—Decorative coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/11—Deposition methods from solutions or suspensions
- C03C2218/112—Deposition methods from solutions or suspensions by spraying
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/365—Coating different sides of a glass substrate
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention provides a kind of ambetti, belongs to architectural decoration material field, including the first vacuum ionic coating, glass basis, dope layer, patterned layer and the second vacuum ionic coating being cascading.The present invention has dope layer in the one side of glass basis, and dope layer causes ambetti to have good coating adhesion, so as to stronger attached pattern layer；Outermost layer is respectively arranged with the first vacuum ionic coating and the second vacuum-coating, improves the acid-alkali-corrosive-resisting performance of ambetti, and ambetti is had good pattern fidelity, splendid pearly-lustre or metal-like effect.The as shown by data of embodiment, ambetti hardness of the present invention reaches 2H, adhesive force grade reaches 0 grade, in water 120h without foaming, without obscission, the 240h in 3% hydrochloric acid solution, without foaming, without obscission, in 5% sodium hydroxide solution 168h without foaming, without obscission, there is excellent acid-alkali-corrosive-resisting performance.
Description
Technical field
The present invention relates to technical field of construction and decoration materials, more particularly to a kind of ambetti and preparation method thereof.
Background technology
Ambetti is using glass as carrier, glass is processed obtained with aesthetic feeling, ornamental glass.
In existing market, traditional construction method be by hand, by way of digital spraying, special plastic film,
The printed thereon pattern such as sheet metal, facing paper, the mode on glass surface is then affixed to realize, such as Publication No. CN
1445109 A Chinese patent discloses a kind of manufacture method for the Decorative Plexiglass Plate for being compounded with pattern paper wood, its pattern
It is to be printed on pattern paper wood, is then sealed in again in glass plate；The A of CN 101301391 disclose a kind of patterned decoration
Glass, its pattern are directly printed on ground glass.In the prior art, ambetti has that coating adhesion is low, acid and alkali-resistance
The problem of corrosive nature is bad.
The content of the invention
In view of this, it is an object of the invention to provide a kind of ambetti, there is good coating adhesion and acidproof
Caustic corrosion performance.
In order to realize foregoing invention purpose, the present invention provides following technical scheme：
A kind of ambetti, including the first vacuum ionic coating, glass basis, dope layer, the pattern being cascading
Layer and the second vacuum ionic coating.
Preferably, the composition and thickness of the first vacuum ionic coating and the second vacuum ionic coating are identical；
The thickness of the first vacuum ionic coating and the second vacuum ionic coating is 0.01~10 μm；
The first vacuum ionic coating and the second vacuum ionic coating are plating titanium layer or titanizing aluminium alloy layer.
Preferably, the thickness of the dope layer is 2~100 μm.
Preferably, the dope layer is that powdery paints or the coating material solidified coatings of UV obtain.
Preferably, the powdery paints includes the component of following parts by weight：500~800 parts of polyester resin, curing agent 42.2
~102.2 parts, 3~13 parts of levelling agent, 1~5 part of styrax, 2~8 parts of adhesion promoter, 2~8 parts of curing catalysts, filler
116.8~316.8 parts, 0~70 part of pigment.
Preferably, the coating material solidified components for including following percetage by weight of the UV：Urethane acrylate 30~33%,
UV monomers 20~22%, light trigger 5~8%, butyl acetate 18~20%, ethyl acetate 18.5~24.7%, levelling agent 0.2
~0.3%, defoamer 0.1~0.2%.
Present invention also offers the preparation method of ambetti described in above-mentioned technical proposal, comprise the following steps：
(1) surface clean is carried out to glass basis；
(2) the glass basis one side after the step (1) cleaning be surface-treated successively, sprayed coating and coating
Solidification, dope layer is formed on the glass basis surface；
(3) the coating layer surface that product is obtained in the step (2) carries out pattern infiltration, is formed in the coating layer surface
Patterned layer；
(4) step (3) is obtained into the two-sided carry out vacuum ion plating of product, forms the first vacuum ionic coating and the
Two vacuum ionic coating, obtain ambetti.
Preferably, the solution that surface treatment uses in the step (2) includes the component of following percetage by weight：60~
90% absolute ethyl alcohol, 3~10% surface conditioning agent BL-01,0~3% water.
Preferably, the temperature that pattern permeates in the step (3) is 140~180 DEG C, and the time of the pattern infiltration is 1
~10min.
Preferably, the vacuum of vacuum ion plating is 0.0001~0.01Pa in the step (4), the vacuum ion plating
Temperature be 100~200 DEG C.
The invention provides a kind of ambetti, including be cascading the first vacuum ionic coating, glass basis,
Dope layer, patterned layer and the second vacuum ionic coating.Ambetti provided by the invention has in the one side of glass basis to be applied
The bed of material, dope layer cause ambetti to have good coating adhesion, so as to stronger attached pattern layer；Outermost layer
The first vacuum ionic coating and the second vacuum-coating are respectively arranged with, improves the acid-alkali-corrosive-resisting performance of ambetti.Moreover,
In the present invention, the setting of the first vacuum ionic coating and the second vacuum ionic coating, ambetti is made to have well
Pattern fidelity, while there is splendid pearly-lustre or metal-like effect.The test data of embodiment shows, provided by the invention
Ambetti hardness reaches 2H, and adhesive force grade has reached 0 grade, in water 120h without foaming, without obscission, in 3% salt
In acid solution 240h without foaming, without obscission, in 5% sodium hydroxide solution 168h without foaming, without obscission, have
Excellent acid-alkali-corrosive-resisting performance.
Also, surface clean is carried out the invention provides the preparation method of ambetti, including to glass basis, in glass
Matrix one side is surface-treated successively, sprayed coating and paint solidification, then carries out pattern infiltration, finally by vacuum ionic
Plating, obtains ambetti.The present invention combines sprayed coating, pattern infiltration and vacuum ion plating, and by glass
Glass is surface-treated, and further increases the application uniformity and coating adhesion of ambetti.It is and provided by the invention
Preparation method is easy, quick, suitable for industrial applications.
Brief description of the drawings
The present invention is further detailed explanation with reference to the accompanying drawings and detailed description.
Fig. 1 is the structural representation of ambetti provided by the invention, wherein 1 is the first vacuum ionic coating, 2 be glass
Matrix, 3 be dope layer, and 4 be patterned layer, and 5 be the second vacuum ionic coating.
Embodiment
The invention provides a kind of ambetti, including be cascading the first vacuum ionic coating, glass basis,
Dope layer, patterned layer and the second vacuum ionic coating.
In the present invention, the composition and thickness of the first vacuum ionic coating and the second vacuum ionic coating are identical；Institute
The thickness for stating the first vacuum ionic coating and the second vacuum ionic coating is preferably 0.01~10 μm, more preferably 0.1~5 μm,
Most preferably 2~3 μm；The first vacuum ionic coating and the second vacuum ionic coating are to plate titanium layer or titanizing aluminium alloy layer,
When the first vacuum ionic coating and the second vacuum ionic coating for plating titanium layer when, golden or illusion-colour color is presented, when described the
When one vacuum ionic coating and the second vacuum ionic coating are titanizing aluminium alloy layer, rose golden is presented.
The present invention does not have special restriction to the thickness of the glass basis, using well known to those skilled in the art commercially available
Glass.The present invention does not have special restriction, preferably glass disk, glass plate or glass to the shape of the glass basis
Container.
In the present invention, the thickness of the dope layer is preferably 2~100 μm.In the present invention, the dope layer is powder
Coating or the coating material solidified coatings of UV obtain, and when the dope layer is that powdery paints coats to obtain, the thickness of the dope layer is excellent
Select 40~100 μm, more preferably 60~80 μm, most preferably 65~75 μm；When the dope layer is that the coating material solidified coatings of UV obtain
When, the thickness of the dope layer is preferably 2~15 μm, more preferably 5~10 μm, most preferably 6~8 μm.
In the present invention, the powdery paints preferably includes the component of following parts by weight：500~800 parts of polyester resin, consolidate
42.2~102.2 parts of agent, 3~13 parts of levelling agent, 1~5 part of styrax, 2~8 parts of adhesion promoter, curing catalysts 2~
8 parts, 116.8~316.8 parts of filler, 0~70 part of pigment.
In the present invention, the powdery paints includes 500~800 parts of polyester resin, preferably 600~700 parts, more excellent
Elect 650 parts as.In the present invention, the polyester resin is the organic binder matter of powdery paints, ensures the machinery of powdery paints
Performance.The present invention does not have special restriction to the source of the polyester resin, is applied using powder well known to those skilled in the art
Material polyester resin, specifically, the polyester resin DSM such as the production of DSM group.
In the present invention, the powdery paints includes 42.2~102.2 parts of curing agent, preferably 50~80 parts, more excellent
Elect 72.2 parts as.In the present invention, the powdery paints includes 3~13 parts of levelling agent, preferably 5~10 parts, more preferably 8
Part.In the present invention, the powdery paints includes 1~5 part of styrax, preferably 3 parts.In the present invention, the styrax
Defoaming effect is provided.The present invention does not have special restriction to the curing agent, levelling agent and benzoic source, using ability
Commercial goods known to field technique personnel, specifically, as curing agent is produced using Huangshan Huahui Technology Co., Ltd.
TGIC, levelling agent use the HL988 of Huangshan Huahui Technology Co., Ltd.'s production, and styrax uses Huangshan Huahui Technology Co., Ltd.
The HA501 of production.
In the present invention, the powdery paints includes 2~8 parts of adhesion promoter, preferably 3~7 parts, more preferably
5 parts.In the present invention, the adhesion promoter can improve the adhesive force of dope layer.The present invention promotes the adhesive force
The source of agent does not have special restriction, using commercial goods well known to those skilled in the art, specifically, such as DOW CORNING
Z6040。
In the present invention, the powdery paints includes 2~8 parts of curing catalysts, preferably 3~7 parts, more preferably 5
Part.In the present invention, the curing catalysts are advantageous to powdery paints rapid curing.The present invention comes to the curing catalysts
Source does not have special restriction, using commercial goods well known to those skilled in the art, specifically, such as Suzhou sky sail biology stock
The DBU of part Co., Ltd production.
In the present invention, the powdery paints includes 116.8~316.8 parts of filler, preferably 150~250 parts, more excellent
Elect 216.8 parts as.In the present invention, the filler provides skeletal support effect.It is special that the present invention does not have to the source of filler
Limit, using commercial goods well known to those skilled in the art, specifically, as Guangxi Xiangzhou Lianzhuang Chemical Co., Ltd. gives birth to
The precipitation barium of production.
In the present invention, the powdery paints includes 0~70 part of pigment, preferably 30~50 parts, more preferably 40 parts.
Present invention preferably employs different pigment to be made the ambetti with different colours, such as white, grey, gold, colour.
In the present invention, when the powdery paints does not include pigment, the first vacuum ionic coating and is only presented in obtained ambetti
The color of two vacuum ionic coating.The present invention does not have special restriction to the source of the pigment, using those skilled in the art
Well known commercial goods, specifically, such as Du Pont titanium dioxide R-706.
In the present invention, the UV is coating material solidified including following percetage by weight component：Urethane acrylate 30~
33%th, UV monomers 20~22%, light trigger 5~8%, butyl acetate 18~20%, ethyl acetate 18.5~24.7%, levelling
Agent 0.2~0.3%, defoamer 0.1~0.2%.
In the present invention, the coating material solidified layers of the UV preferably include the polyurethane acroleic acid of 30~33% percetages by weight
Ester, preferably 32%.The present invention does not have special restriction to the source of the urethane acrylate, using people in the art
Commercial goods known to member.
In the present invention, the coating material solidified light triggers for including 5~8% percetages by weight of the UV, preferably 6~7%.
In the present invention, the light trigger enables to UV monomers to solidify under illumination condition.The present invention is to the light trigger
Source does not have special restriction, using commercial goods well known to those skilled in the art, specifically, such as Tianjin long day 184.
In the present invention, the coating material solidified butyl acetates for including 18~20% percetages by weight of the UV, preferably 19%.
In the present invention, the coating material solidified layers of the UV include the ethyl acetate of 18.5~24.7% percetages by weight, preferably 19~
22%, more preferably 20~21%.
In the present invention, the coating material solidified levelling agents for including 0.2~0.3% percetage by weight of the UV, it is preferably
0.25%.The present invention does not have special restriction to the source of the levelling agent, using commercially available business well known to those skilled in the art
Product, specifically, such as Bi Ke companies BYK333.
In the present invention, the coating material solidified defoamers for including 0.1~0.2% percetage by weight of the UV, it is preferably
0.15%.The present invention does not have special restriction to the source of the defoamer, using commercially available business well known to those skilled in the art
Product, specifically, such as Bi Ke companies BYK141.
Present invention also offers the preparation method of ambetti described in above-mentioned technical proposal, comprise the following steps：
(1) surface clean is carried out to glass basis；
(2) the glass basis one side after the step (1) cleaning be surface-treated successively, sprayed coating and coating
Solidification, dope layer is formed on the glass basis surface；
(3) the coating layer surface that product is obtained in the step (2) carries out pattern infiltration, is formed in the coating layer surface
Patterned layer；
(4) step (3) is obtained into the two-sided carry out vacuum ion plating of product, forms the first vacuum ionic coating and the
Two vacuum ionic coating, obtain ambetti.
The present invention carries out surface clean to glass basis.In the present invention, the surface clean is preferably to be cleaned by ultrasonic.This
Invention does not have special restriction to the power of the ultrasonic cleaning, time, and use is well known to those skilled in the art, can remove
Glass basis Superficial Foreign Body.In the present invention, the ultrasonic cleaning is preferably that glass is washed with supersonic cleaning machine.
After glass basis after being cleaned, glass basis one side of the present invention after the step (1) cleaning enters successively
Row surface treatment, sprayed coating and paint solidification, dope layer is formed on the glass basis surface.
Glass basis one side of the present invention after the cleaning is surface-treated, the glass basis being surface-treated.
In the present invention, the component for being surface-treated the solution used and preferably including following percetage by weight：60~90% it is anhydrous
Ethanol, 3~10% surface conditioning agent BL-01,0~3% water.In the present invention, the coating of the surface processing solution is thick
Degree is preferably 2~15 μm, more preferably 5~10 μm, most preferably 6~8 μm.The present invention does not have to the concrete mode of the coating
Special restriction, using coating method well known to those skilled in the art, specifically, as brushed.In the present invention, it is described
Surface treatment can improve cohesive force between resinous coat and base material, adhesion, adherence, and the angle of wetting of substrate surface,
Improve the adhesive force between coating and base material.In the present invention, the surface conditioning agent BL-01 is the new enlightening in Zhejiang in long paint science and technology
The commercial goods of Co., Ltd.
After the completion of surface treatment, the present invention preferably dries the glass basis of surface treatment.The present invention is to the drying
Concrete mode does not have special restriction, using drying mode well known to those skilled in the art, specifically, as done naturally
It is dry.In invention, the drying can remove the organic solvent and moisture used in surface treatment process.
After the glass basis being surface-treated, the present invention applies in the surface treated one side spraying of the glass basis
Material, obtain the glass basis with coating.In the present invention, when the dope layer is that powdery paints coats to obtain, the painting
Preferably 40~100 μm of the coating thickness of the bed of material, most preferably more preferably 60~80 μm, 65~75 μm；When the dope layer is UV
When coating material solidified coating obtains, the coating thickness of the dope layer is preferably 2~15 μm, more preferably 5~10 μm, is most preferably
6~8 μm.In the present invention, the coating is preferably and is mixed with according to each component of dope layer described in above-mentioned technical proposal
Arrive, the present invention does not have special restriction to the preparation method of the coating, using composition well known to those skilled in the art
Preparation method.In the present invention, the distance on the glass basis surface during spraying after the surface treatment of spray gun pipette tips distance
Preferably 100~300mm, more preferably 150~250mm, most preferably 180~200mm.In the present invention, the spraying energy
Enough so that coating is evenly distributed in glass basis surface after surface treatment.
After the glass basis surface spraying coating, the present invention solidifies the glass basis for being attached with coating wet film, obtains
To the glass with dope layer.When the coating used is powdery paints, the solidification is preferably to be heating and curing, and the heating is solid
The temperature of change is preferably 150~200 DEG C, more preferably 160~180 DEG C；Time for being heating and curing is preferably 10~
30min, more preferably 15~20min.When the coating used is UV coating material solidified, the solidification is preferably ultraviolet light solidification,
The power of the ultraviolet light solidification is preferably 300~500W, more preferably 400~450W；The main peak ripple of the ultraviolet light solidification
Long is preferably 300~400nm, more preferably 365nm；The dose of radiation of the ultraviolet light solidification is preferably 30~50mW/cm2,
More preferably 40mW/cm2；The radiation of the ultraviolet light solidification is preferably dimensioned to be (50~150) * (400~800) mm, more preferably
For 100 × 600mm.The present invention does not have special restriction to the concrete mode of ultraviolet light solidification, using people in the art
Ultraviolet light curing mode known to member, specifically, carrying out ultraviolet light solidification using high pressure Hg lamps as described.
In the present invention, it is preferred to it is enterprising that the glass basis of the wet film with coating is placed on into horizontal transport conveyer chain
Row solidification, the chain speed of the horizontal transport conveyer chain is preferably 2~4m/min, more preferably 2.5~3m/min.
After forming dope layer on the glass basis surface, the present invention carries out figure in the coating layer surface for obtaining product
Case is permeated, and patterned layer is formed in the coating layer surface.In the present invention, the temperature of the pattern infiltration is preferably 140~180
DEG C, more preferably 165~175 DEG C, most preferably 170 DEG C；The time of the pattern infiltration is preferably 1~10min, more preferably
6~8min.In the present invention, with figuratum paper or PET film, the pattern is preferably wood for the pattern infiltration preferably use
Line, bag, landscape or personage.Concrete operations of the present invention to pattern infiltration do not have special restriction, using this area skill
Penetration mode known to art personnel, specifically, the dope layer table as described in will be covered with figuratum paper or PET film
Face.In the present invention, the patterned layer is penetrated into the dope layer.
After the coating layer surface forms patterned layer, the two-sided carry out vacuum ion plating of the invention by obtained product,
The first vacuum ionic coating and the second vacuum ionic coating are formed, obtains ambetti.In the present invention, the vacuum ion plating
Vacuum be preferably 0.0001~0.01Pa；The temperature of the vacuum ion plating is preferably 100~200 DEG C, more preferably 110
~150 DEG C, most preferably 120~130 DEG C；The time of the vacuum ion plating is preferably 1~5min, more preferably 2~4min.
In the present invention, the vacuum ion plating is carried out preferably in oxygen.In the present invention, target base when passing through vacuum ion plating is not
With different vacuum ionic coating is obtained, specifically, such as titanium target or titanium-aluminum alloy target.
Ambetti provided by the invention and preparation method thereof is described in detail with reference to embodiment, but not
They can be interpreted as limiting the scope of the present invention.
Fig. 1 is the structural representation of ambetti provided by the invention, wherein 1 is the first vacuum ionic coating, 2 be glass
Matrix, 3 are dope layer, and 4 be patterned layer, and 5 be the second vacuum ionic coating.
Embodiment 1
Carry out ultrasonic wave cleaning to glass container (the long wide * thickness of * is 100mm*200mm*4mm), glass container surface is clean,
Foreign；To clean glass container surface coating surface processing solution, and spontaneously dry, coating thickness is 2 μm, surface treatment
Solution includes 90wt% absolute ethyl alcohol, 8wt% surface conditioning agent BL-01,2wt% water, then to coating surface processing
One face electrostatic spraying powder coating of solution, spray gun pipette tips are 100mm apart from glass pane surface distance, and coating thickness is 2 μm, powder
Last formulation for coating material mass parts are as follows：650 parts of polyester resin DSM, curing agent (Huangshan Huahui Technology Co., Ltd. TGIC) 72.2
Part, 8 parts of levelling agent (Huangshan Huahui Technology Co., Ltd. HL988), 3 parts of styrax (Huangshan Huahui Technology Co., Ltd. HA501),
5 parts of adhesion promoter (DOW CORNING Z6040), 5 parts of curing catalysts (Suzhou Hao Fan Biological Co., Ltd. DBU), filler
216.8 parts of (precipitation barium), 40 parts of pigment (Du Pont titanium dioxide R-706), then powdery paints heated baking solidification at 150 DEG C
30min, glass container, which is placed in the horizontal transport conveyer chain that chain speed is 2m/min, to be solidified to obtain the glass with dope layer
Glass, is then printed on blue and white paper in dope layer covering, and pattern is carried out at 160 DEG C and is permeated 10 minutes, then overall to glass
Vacuum ion plating is done, forms ion plating：Titanium target is pushed into, is evacuated to 0.0001Pa, heats 120 DEG C, is filled with oxygen, maintains 3
Minute, that is, obtain the ambetti of blue and white illusion-colour color.
Determination of Hardness is carried out according to GB/T 6739 to ambetti made from embodiment 1, as a result hardness is 2H, according to GB/
T 9286 carries out adhesive force measure, and as a result adhesive force is 0 grade, carries out water resistance according to GB/T 9274, acid-alkali-corrosive-resisting is surveyed
It is fixed, as a result in water 120h without foaming, without obscission, in 3% HCl solution 240h without foaming, without obscission,
In 5% NaOH solution 168h without foaming, without obscission, show that ambetti made from embodiment 1 has good attachment
Power and acid-alkali-corrosive-resisting performance.
Embodiment 2
Carry out ultrasonic wave cleaning to glass container (the long wide * thickness of * is 100mm*200mm*4mm), glass container surface is clean,
Foreign；To clean glass container surface coating surface processing solution, and spontaneously dry, coating thickness is 15 μm, at surface
Reason solution includes 85wt% absolute ethyl alcohol, 10wt% surface conditioning agent BL-01,5wt% water, then to coating surface at
A face electrostatic spraying powder coating of solution is managed, spray gun pipette tips are 300mm apart from glass pane surface distance, and coating thickness is 15 μ
M, powder coating formulation mass parts are as follows：500 parts of polyester resin DSM, curing agent (Huangshan Huahui Technology Co., Ltd. TGIC)
42.2 parts, 13 parts of levelling agent (Huangshan Huahui Technology Co., Ltd. HL988), styrax (Huangshan Huahui Technology Co., Ltd.
HA501) 5 parts, 8 parts of adhesion promoter (DOW CORNING Z6040), curing catalysts (Suzhou Hao Fan Biological Co., Ltd.
DBU) 2 parts, 316.8 parts of filler (precipitation barium), 70 parts of pigment (Du Pont titanium dioxide R-706), then powdery paints at 200 DEG C plus
Hot baking-curing 10min, glass container are placed on to be solidified in the horizontal transport conveyer chain that chain speed is 4m/min and carried
The glass of dope layer, is then printed on the PET film of bag in dope layer covering, pattern infiltration 5 minutes is carried out at 180 DEG C, then
Vacuum ion plating is integrally done to glass, forms ion plating：Titanium-aluminum alloy target is pushed into, is evacuated to 0.01Pa, heats 100 DEG C,
Oxygen is filled with, is maintained 5 minutes, that is, obtains the ambetti of bag rose golden.
Determination of Hardness is carried out according to GB/T 6739 to ambetti made from embodiment 2, as a result hardness is 2H, according to GB/
T 928 carries out adhesive force measure, and as a result adhesive force is 1 grade, and water resistance, acid-alkali-corrosive-resisting measure are carried out according to GB/T 9274,
As a result be in water 120h without foaming, without obscission, in 3% HCl solution 240h without foaming, without obscission, 5%
NaOH solution in 168h without foaming, without obscission, show that ambetti made from embodiment 2 has good coating attachment
Power and acid-alkali-corrosive-resisting performance.
Embodiment 3
Ultrasonic wave cleaning is carried out to glass disk (diameter * thickness is 300mm*4mm), glass container surface is clean, is no different
Thing；To clean glass container surface coating surface processing solution, and spontaneously dry, coating thickness is 10 μm, and surface treatment is molten
Liquid includes 86wt% absolute ethyl alcohol, and 9wt% surface conditioning agent BL-01,5wt% water are then molten to coating surface processing
The one side spraying UV of liquid is coating material solidified, and spray gun pipette tips are 150mm apart from glass pane surface distance, and coating thickness is 10 μm, and UV is solid
It is as follows to change formulation for coating material：Urethane acrylate 30wt%, UV monomer 20wt%, light trigger (Tianjin long day 184) 5wt%,
Butyl acetate 20wt%, ethyl acetate 24.7wt%, levelling agent (BYK333) 0.2wt%, defoamer (BYK141) 0.1wt%,
Then UV is coating material solidified in using 400W high pressure Hg lamps, peak wavelength 365nm, dose of radiation 40mW/cm2, radiate size
Solidified for 100 × 600mm, glass container is placed in the horizontal transport conveyer chain that chain speed is 2.5m/min and solidify
To the glass with dope layer, grained paper then is printed in dope layer covering, pattern is carried out at 170 DEG C and is permeated 6 minutes,
Then vacuum ion plating is integrally done to glass, forms ion plating：Titanium target is pushed into, is evacuated to 0.0001Pa, heats 105 DEG C,
Oxygen is filled with, is maintained 2 minutes, that is, obtains the ambetti of wood grain illusion-colour color.
Determination of Hardness is carried out according to GB/T 6739 to ambetti made from embodiment 3, as a result hardness is 2H, according to GB/
T 928 carries out adhesive force measure, and as a result adhesive force is 0 grade, and water resistance, acid-alkali-corrosive-resisting measure are carried out according to GB/T 9274,
As a result be in water 120h without foaming, without obscission, in 3% HCl solution 240h without foaming, without obscission, 5%
NaOH solution in 168h without foaming, without obscission, show that ambetti made from embodiment 3 has good coating attachment
Power and acid-alkali-corrosive-resisting performance.
Embodiment 4
Ultrasonic wave cleaning is carried out to glass plate (the long wide * thickness of * is 400mm*400mm*5mm), glass container surface is clean, nothing
Foreign matter；To clean glass container surface coating surface processing solution, and spontaneously dry, coating thickness is 6 μm, and surface treatment is molten
Liquid includes 90wt% absolute ethyl alcohol, and 7wt% surface conditioning agent BL-01,3wt% water are then molten to coating surface processing
The one side spraying UV of liquid is coating material solidified, and spray gun pipette tips are 250mm apart from glass pane surface distance, and coating thickness is 6 μm, UV solidifications
Formulation for coating material is as follows：Urethane acrylate 30wt%, UV monomer 20wt%, light trigger (Tianjin long day 184) 5wt%, vinegar
Acid butyl ester 20wt%, ethyl acetate 24.7wt%, levelling agent (BYK333) 0.2wt%, defoamer (BYK141) 0.1wt%, so
UV is coating material solidified in using 300W high pressure Hg lamps, peak wavelength 400nm, dose of radiation 30mW/cm afterwards2, radiating size is
50 × 800mm is solidified, and glass container, which is placed in the horizontal transport conveyer chain that chain speed is 2.5m/min, to be solidified to obtain
Glass with dope layer, is then printed on the PET film of landscape in dope layer covering, and pattern is carried out at 175 DEG C and is permeated 8 minutes,
Then vacuum ion plating is integrally done to glass, forms ion plating：Titanium target is pushed into, is evacuated to 2.0Pa, 115 DEG C is heated, is filled with
Nitrogen, maintain 3 minutes, that is, obtain the golden ambetti of landscape.
Determination of Hardness is carried out according to GB/T 6739 to ambetti made from embodiment 4, as a result hardness is 2H, according to GB/
T 928 carries out adhesive force measure, and as a result adhesive force is 1 grade, and water resistance, acid-alkali-corrosive-resisting measure are carried out according to GB/T 9274,
As a result be in water 120h without foaming, without obscission, in 3% HCl solution 240h without foaming, without obscission, 5%
NaOH solution in 168h without foaming, without obscission, show that ambetti made from embodiment 4 has good coating attachment
Power and acid-alkali-corrosive-resisting performance.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (10)
1. a kind of ambetti, including be cascading the first vacuum ionic coating, glass basis, dope layer, patterned layer
And the second vacuum ionic coating.
2. ambetti according to claim 1, it is characterised in that the first vacuum ionic coating and the second vacuum from
The composition and thickness of sub- coating are identical；
The thickness of the first vacuum ionic coating and the second vacuum ionic coating is 0.01~10 μm；
The first vacuum ionic coating and the second vacuum ionic coating are plating titanium layer or titanizing aluminium alloy layer.
3. ambetti according to claim 1 or 2, it is characterised in that the thickness of the dope layer is 2~100 μm.
4. ambetti according to claim 1, it is characterised in that the dope layer is that powdery paints or UV are coating material solidified
Coating obtains.
5. ambetti according to claim 4, it is characterised in that the powdery paints includes the group of following parts by weight
Point：500~800 parts of polyester resin, 42.2~102.2 parts of curing agent, 3~13 parts of levelling agent, 1~5 part of styrax, attachment are made every effort to promote
Enter 2~8 parts of agent, 2~8 parts of curing catalysts, 116.8~316.8 parts of filler, 0~70 part of pigment.
6. ambetti according to claim 4, it is characterised in that the UV is coating material solidified including following percetage by weight
Component：Urethane acrylate 30~33%, UV monomers 20~22%, light trigger 5~8%, butyl acetate 18~20%,
Ethyl acetate 18.5~24.7%, levelling agent 0.2~0.3%, defoamer 0.1~0.2%.
7. the preparation method of ambetti, comprises the following steps described in claim 1~6 any one：
(1) surface clean is carried out to glass basis；
(2) the glass basis one side after the step (1) cleaning is surface-treated successively, sprayed coating and coating are consolidated
Change, dope layer is formed on the glass basis surface；
(3) the coating layer surface that product is obtained in the step (2) carries out pattern infiltration, and pattern is formed in the coating layer surface
Layer；
(4) step (3) is obtained into the two-sided carry out vacuum ion plating of product, forms the first vacuum ionic coating and second true
Empty ion plating, obtains ambetti.
8. preparation method according to claim 7, it is characterised in that the solution that surface treatment uses in the step (2)
Include the component of following percetage by weight：60~90% absolute ethyl alcohol, 3~10% surface conditioning agent BL-01,0~3%
Water.
9. preparation method according to claim 7, it is characterised in that the temperature that pattern permeates in the step (3) is 140
~180 DEG C, the time of the pattern infiltration is 1~10min.
10. preparation method according to claim 7, it is characterised in that the vacuum of vacuum ion plating in the step (4)
For 0.0001~0.01Pa, the temperature of the vacuum ion plating is 100~200 DEG C.
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| CN110196263A (en) * | 2019-06-20 | 2019-09-03 | 江苏秀强玻璃工艺股份有限公司 | Ambetti and its detection, production method |
| CN110104960A (en) * | 2019-07-02 | 2019-08-09 | 佛山宜可居新材料有限公司 | A kind of environmental-protection decoration glass and preparation method thereof |
| CN110408249A (en) * | 2019-07-22 | 2019-11-05 | 佛山宜可居新材料有限公司 | A kind of preparation method of macromolecule laminated film |
| CN110408250A (en) * | 2019-07-22 | 2019-11-05 | 佛山宜可居新材料有限公司 | A kind of preparation method of macromolecule laminated film |
| CN115326702A (en) * | 2022-08-24 | 2022-11-11 | 青岛啤酒股份有限公司 | Glass bottle decoration firing quality detection method |
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